Mixed With Polycarboxylic Acid Or Derivative And Polyhydroxy Reactant Or Polymer Therefrom Patents (Class 525/425)
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Patent number: 5750232Abstract: This invention relates to a plastic composite material which comprises:a thermoplastic plastic sheet and, bonded to one side thereof,a thermoplastic spun felt comprising a hot-melt adhesive, to a method of producing it and to its use.Type: GrantFiled: June 27, 1995Date of Patent: May 12, 1998Assignee: Elf Atochem Deutschland GmbHInventors: Roland Eugen Steenblock, Joachim Buhrmann
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Patent number: 5747591Abstract: A combination of polymeric components provides desired characteristics in forming medical instruments such as catheters and balloons for dilatation catheters. For example, a balloon material is formed from a blend of polymeric components, including a first crystalline polymeric component and a second softening polymeric component. Where the first two components are generally incompatible, the balloon material can also include a third compatibilizing agent to facilitate blending the first two polymeric components together. The first polymeric component can be a branched or straight chain polyamide having a molecular weight of at least about 5000, or a polyester prepared from aromatic dicarboxylic acids having 8 to 14 carbon atoms or aliphatic dicarboxylic acids having from 2 to 12 carbon atoms, and at least one glycol having the formula HO(CH.sub.2).sub.n OH, where n is an integer from 2 to 10, neopentyl glycol and cyclohexane dimethanol.Type: GrantFiled: October 31, 1996Date of Patent: May 5, 1998Assignee: Advanced Cardiovascular Systems, Inc.Inventors: Ziyun Chen, Tai Cheng, Ketan Muni, Udayan Patel, Robert Saltman
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Patent number: 5726285Abstract: Condensation and addition polymers which comprise as structural repeating unit N,N'-bridged bistetramethylpiperidyloxy groups of the formula I ##STR1## in which m is 2 or 3 are suitable as light stabilizers and other stabilizers for organic materialType: GrantFiled: August 2, 1996Date of Patent: March 10, 1998Assignee: BASF AktiengesellschaftInventors: Alexander Aumuller, Hubert Trauth
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Patent number: 5703177Abstract: This invention relates to biologically degradable, partially crystalline block copolyester-polyamides comprising at least two chemically differently structured segments of which at least one is a polyester (PES) block or a copolyester (coPES) block, preferably with a number average molecular mass of 340 to 10,000 g/mole, and at least one is a polyamide (PA) block or a copolyamide (coPA) block, preferably with a number average molecular mass of 400 to 3,000 g/mole. In addition, copolyester-amide (coPEA) blocks can be employed, preferably with a number average molecular mass of 500 to 5,000 g/mole. The invention also relates to a polycondensation process for the manufacture of these partially crystalline block copolyester-polyamides. The block copolymers described are useful for the manufacture of fibers, foils, molded articles and hot melt-type adhesives. Molded components manufactured from the copolymers in accordance with the invention are biologically degradable and are capable of being composted.Type: GrantFiled: December 15, 1995Date of Patent: December 30, 1997Assignee: Ems-Inventa AGInventor: Heinz Hoff
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Patent number: 5696208Abstract: Polyamide resins characterized in melt state by high sensitivity to shear forces and high visco-elasticity, obtained by polycondensation/polyaddition in the solid state in presence of polyfunctional compounds capable of reacting with resin terminal groups and/or in presence of polyester resins employed in quantity up to about 40% by weight of the resin mixtures.Type: GrantFiled: December 18, 1995Date of Patent: December 9, 1997Assignee: Sinco Engineering S.p.A.Inventors: Hussain Ali Kashif Al Ghatta, Sandro Cobror
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Patent number: 5691412Abstract: A polyamide/aliphatic polyester block copolymer (A) comprising a polyamide block and an aliphatic polyester block, (B) satisfying the expression, T.sub.1 -T<100-C (in which T is the melting point (.degree.C.) of the above block copolymer, T.sub.1 is the melting point (.degree.C.) of a polyamide composed of the polyamide block and C is the content (wt. %) of the polyamide block), (C) exhibiting the extraction amount which satisfies the expression, when extracted in tetrahydrofuran, E<(100-C).times.0.4 (in which E is the extraction amount (wt. %) when the block copolymer is refluxed in tetrahydrofuran, and C is the content (wt. %) of the polyamide block) and (D) having an intrinsic viscosity, measured at 35.degree. C., in the range of from 0.5 to 5; a process for the production thereof; a fiber formed therefrom; and an intimate blend comprising a thermoplastic resin having no or poor compatibility with polyamide and the block copolymer.Type: GrantFiled: May 25, 1995Date of Patent: November 25, 1997Assignee: Teijin LimitedInventors: Shunichi Matsumura, Takashi Ito, Takanori Miyoshi
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Patent number: 5677394Abstract: A melt-processable block copolyesterimide comprising the repeating units (I), (II) and (III) and, optionally, a repeating unit (IV), wherein (I) is a repeating unit of the formula ##STR1## wherein R is an aliphatic polyether chain and/or a polysiloxane chain; (II) and (III) are repeating units of the formulas ##STR2## wherein Z is hydrogen, alkyl, alkoxy, aryl, halogen and w is zero or one; and (IV) is a repeating unit of the formula ##STR3## wherein Z' is hydrogen, alkyl, alkoxy, aryl or halogen and the phenylene ring is substituted in by Z' in the m- or p-positions. The repeating unit of formula (I) is present in an amount of 5 to 50 mole-%, the repeating unit of formula (II) is present in an amount of 10 to 80 mole-%, the repeating unit of formula (III) is present in an mount of 5 to 50 mole-% and the repeating unit of formula (IV) is present in an amount of 0 to 45 mole-% of the block copolyesterimide.Type: GrantFiled: April 28, 1995Date of Patent: October 14, 1997Assignee: Neste OYInventors: Frank Bohme, Doris Pospiech, Manfred Ratzsch, Christer Bergstrom, Mika Harkonen, Heli Alanko, Pentti Passiniemi
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Patent number: 5660932Abstract: Polymer blend for insulating electrical wires comprises a first polymer (polyester) having an inherent L.O.I. not higher than 21% and up to 40% by weight of a polyimide-siloxane (PIS) copolymer. Preferred polyesters are polybutylene terephthalate or polyester-ester block copolymers. Preferred wire constructions have core insulation layer of polyethylene or polyester overlaid with jacket of the polyester/PIS copolymer blend.Type: GrantFiled: November 8, 1995Date of Patent: August 26, 1997Assignee: Raychem LimitedInventor: David John Durston
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Patent number: 5656221Abstract: Process for direct production of shaped packaging material made of thermoplastic polyesters with no effect on the taste of foods packaged in them, where the diol component of the polyester consists of at least 70 wt % ethylene glycol, and the polyester is produced in the presence of the usual catalysts plus additional cobalt or cobalt and manganese compounds and phosphorus compounds. An inert gas is introduced into the polyester melt and distributed uniformly in the melt immediately after its discharge from the polycondensation reactor, 0.05 to 1.0 wt % of an amide compound with a low volatility is added to the polyester melt directly next to the gas inlet. Finally, the polyester melt is subjected to a vacuum degassing immediately before the shaping apparatus and the melt is sent directly to the shaping apparatus within a maximum of 30 minutes after its discharge from the reactor at a maximum temperature of 35.degree. C. above the crystallite melting point of the polyester.Type: GrantFiled: August 23, 1995Date of Patent: August 12, 1997Assignee: Zimmer AktiengesellschaftInventors: Heinz-Dieter Schumann, Ulrich Thiele
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Patent number: 5654381Abstract: Synthetic, functionalized, graft copolymers of polyesters and amino acids are provided. The copolymers are formed in one embodiment by providing a linear polyester-poly(amino acid) copolymer, and reacting the amino acid groups in the linear polymer with an amino acid derivative in a polymerization reaction to form a comb-like, graft copolymer including a polyester-amino acid backbone and polyamino acid side chains extending from the amino acid groups in the backbone. The poly(amino acid) includes functional groups which permit the covalent or ionic attachment of a biological molecule to the graft copolymer. The functionalized graft copolymers can be used in a wide range of biomedical applications including tissue engineering and drug delivery.Type: GrantFiled: June 16, 1995Date of Patent: August 5, 1997Assignee: Massachusetts Institute of TechnologyInventors: Jeffrey S. Hrkach, Robert S. Langer, Noah Lotan
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Patent number: 5652283Abstract: A process for preparing finely divided mixtures of amphiphilic polymers and polycarboxylates, which comprises mixing(a) aqueous dispersions or colloidal aqueous solutions with at least one amphiphilic polymer, and(b) an aqueous solution of a polycarboxylatein a weight ratio of (a):(b) of from 1:1 to 1:20, each based on the solids, or dispersing at least one amphiphilic polymer in an aqueous solution of a polycarboxylate, and spray-drying the dispersions thus obtainable to form finely divided polymer mixtures, use of the finely divided polymer mixtures as ingredient of detergent and as laundry aftertreatment, and finely divided polymer mixtures having a particle size from 20 .mu.m to 3 mm prepared by the above-indicated process.Type: GrantFiled: February 8, 1996Date of Patent: July 29, 1997Assignee: BASF AktiengesellschaftInventors: Dieter Boeckh, Hans-Ulrich Jager, Alexander Kud, Wolfgang Trieselt, Wolfgang Buhler
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Patent number: 5652326Abstract: A polyetheresteramide having good heat resistance, permanent antistatic property and superior compatibility with thermoplastic resins and a resin composition containing of the polyetheresteramide are disclosed, wherein the polyetherester-amide consists essentially of a polyamide oligomer with carboxylic chain ends having a number average molecular weight between 200 and 5,000 and a bisphenol compound with oxyalkylene units having a number average molecular weight between 300 and 3,000. Antistatic resin compositions with good antistatic property and heat resistance are obtained from compositions comprising 3 to 40% by weight of the polyetheresteramide and 60 to 97% by weight of thermoplastic resins. The antistatic resin compositions can contain as compatibilizers vinyl polymers having functional groups such as carboxyl and epoxy groups or block polymers containing polyolefin blocks and aromatic vinyl polymer blocks.Type: GrantFiled: March 1, 1994Date of Patent: July 29, 1997Assignee: Sanyo Chemical Industries, Ltd.Inventors: Yasuhiro Ueda, Eiichi Senda, Yoshitsugu Takai, Tokiko Kokubu, Toshiaki Okamoto, Eiji Ichihara
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Patent number: 5650469Abstract: The present invention comprises polyester blend compositions having improved flavor retaining properties and color, comprising:(A) 98.0 to 99.95 weight percent of a polyester which comprises(1) a dicarboxylic acid component comprising repeat units from at least 85 mole percent terephthalic acid or naphthalenedicarboxylic acid derived from terephthalic acid or naphthalenedicarboxylic acid respectively; and(2) a diol component comprising repeat units from at least 85 mole percent ethylene glycol, based on 100 mole percent dicarboxylic acid and 100 mole percent diol; and(B) 2.0 to 0.05 weight percent of a polyamide; wherein the combined weights of (A) and (B) total 100 percent.Type: GrantFiled: October 25, 1995Date of Patent: July 22, 1997Assignee: Eastman Chemical CompanyInventors: Timothy Edward Long, Harold Blake Sprayberry, Steven Lee Stafford, Sam Richard Turner
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Patent number: 5648433Abstract: This invention relates to:a visually clear blend of thermoplastic polymers comprising:(A) a polyetherimide,(B) a mixture of polyesters comprising:(1) a polyester comprising repeat units from:(a) 2,6-naphthalene dicarboxylic acid and(b) ethylene glycol(2) a polyester comprising repeat units from:(a) an acid selected from the group consisting of terephthalic acid and isophthalic acid or mixtures thereof, and(b) a glycol selected from the group consisting of ethylene glycol, 1,4-cyclohexanedimethanol or a mixture thereof.Type: GrantFiled: November 15, 1995Date of Patent: July 15, 1997Assignee: Eastman Chemical CompanyInventor: Christopher E. Scott
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Patent number: 5645850Abstract: The present invention describes an aliphatic polyoxaamide polymer and blends thereof that may be used to produce surgical devices such as sutures, sutures with attached needles, molded devices, and the like. The aliphatic polyoxaamide of the present invention have a first divalent repeating unit of formula I:[X--C(O)--C(R.sub.1) (R.sub.2)--O--(R.sub.3)--O--C(R.sub.1) (R.sub.2)--C(O)--] Iand a second repeating unit selected from the group of formulas consisting of:[--Y--R.sub.17 --].sub.T, I[--O--R.sub.5 --C(O)--].sub.B, and III([--O--R.sub.9 --C(O)].sub.P --O--) XIand combinations thereof, wherein X and Y are selected from the group consisting of --O-- and --N(R)--, provided both X and Y are not both --O-- and may be blended with a second polymer that is preferably biocompatable.Type: GrantFiled: August 7, 1996Date of Patent: July 8, 1997Assignee: Ethicon, Inc.Inventors: Rao S. Bezwada, Dennis D. Jamiolkowski
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Patent number: 5639833Abstract: The invention is directed to molding materials containingA) from 1 to 99% by weight of polyarylene ethers having repeating units I ##STR1## where t and q may each be an integer 0, 1, 2 or 3,T, Q and Z may each be a chemical bond or --O--, --S--, --SO.sub.2 --, S.dbd.O, C.dbd.O, --N.dbd.N--, R.sup.a C.dbd.CR.sup.b -- or --CR.sup.c R.sup.d --, with the proviso that at least one of the groups T, Q and Z is --SO.sub.2 -- or C.dbd.O,R.sup.a and R.sup.b,R.sup.c and R.sup.d, andAr and Ar.sup.1 are as defined in the specification,B) from 1 to 99% by weight of copolyamides containingb.sub.1) from 30 to 44 mol % of units which are derived from terephthalic acid,b.sub.2) from 6 to 20 mol % of units which are derived from isophthalic acid,b.sub.3) from 43 to 49.5 mol % of units which are derived from hexamethylenediamine,b.sub.4) from 0.5 to 7 mol % of units which are derived from aliphatic cyclic diamines of 6 to 30 carbon atoms andb.sub.5) from 0 to 4 mol % of further polyamide-forming monomers which differ from b.sub.Type: GrantFiled: August 10, 1995Date of Patent: June 17, 1997Assignee: BASF AktiengesellschaftInventors: Martin Weber, Herbert Fisch, Gunter Pipper, Axel Gottschalk
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Patent number: 5639832Abstract: Process for the preparation of products of the reaction of polyaspartimides and amino acids by reaction of amino acids with polyaspartimides in aqueous medium at pH values at which at least 5% of the amino groups in the amino acids are in non-protonated form in equilibrium with the protonated form, and use of the reaction products obtainable in this way and of products of the reaction of polyaspartimides with alkanolamines or aminated C.sub.1 -C.sub.30 -fatty alcohol alkoxylates which contain as copolymerized units up to 50 mol % of ethylene oxide and/or propylene oxide per mol of fatty alcohol, as additive to detergents and cleaners, as scale inhibitor and as dispersant.Type: GrantFiled: September 6, 1995Date of Patent: June 17, 1997Assignee: BASF AktiengesellschaftInventors: Matthias Kroner, Gunnar Schornick, Dieter Boeckh, Richard Baur, Birgit Potthoff-Karl, Volker Schwendemann, Christian Schade, Alexander Kud
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Patent number: 5633319Abstract: Non-delaminating resinous compositions are prepared by blending at least one polyetherimide, at least one liquid crystalline polyester in an amount to provide lower melt viscosity, and a compatibilizing amount of at least one polyepoxy compound. The compositions may also contain a minor proportion of at least one non-liquid crystalline polyester such as poly(ethylene terephthalate) or poly(ethylene 2,6-naphthalenedicarboxylate).Type: GrantFiled: January 16, 1996Date of Patent: May 27, 1997Assignees: General Electric Company, E. I. Du pont de Nemours & CompanyInventors: Norberto Silvi, Sterling B. Brown, Mark H. Giammattei, King L. Howe
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Patent number: 5633340Abstract: This invention relates to a molded object prepared from a copolyester having an inherent viscosity of 0.4 to 1.1 dL/g,wherein the acid component comprises repeat units from 90 to 40 mole % terephthalic acid and from 10 to 60 mole % of one or more additional dibasic acids selected from the group consisting of isophthalic acid, cyclohexanedicarboxylic acid, naphthalenedicarboxylic acid, diphenyldicarboxylic acid, and stilbenedicarboxylic acid;wherein the glycol component comprises repeat units from 1,4-cyclohexanedimethanol.Type: GrantFiled: September 21, 1995Date of Patent: May 27, 1997Assignee: Eastman Chemical CompanyInventors: Douglas C. Hoffman, Thomas J. Pecorini, James P. Dickerson, Joseph A. DeLoach
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Patent number: 5629381Abstract: In a method for curing a resin by utilizing an intermolecular crosslinking reaction, the improvement wherein the crosslinking reaction is a a ring opening addition reaction between a lactone structure and an active hydrogen-containing functional group.Type: GrantFiled: May 24, 1996Date of Patent: May 13, 1997Assignee: Kansai Paint Co., Ltd.Inventor: Osamu Isozaki
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Patent number: 5625011Abstract: The invention relates to molecular composites including a rigid reinforcing thermoplastic polymer dispersed on a molecular scale in a flexible organosiloxane/thermoplastic polymer copolymer, to a process for the preparation of the said composites and to a material with a surface enriched in siloxane, obtained from the said molecular siloxane composites, and to the uses of said composites and of the said material, in particular for aerospace construction.Type: GrantFiled: June 29, 1994Date of Patent: April 29, 1997Assignee: Agence Spatiale EuropeenneInventor: Sanjay Palsule
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Patent number: 5602210Abstract: A molecular composite material includes a liquid crystal polymer such as polyazomethine, a thermoplastic polymer such as a polyamide and a compatibilizing agent such as .epsilon.-caprolactam having at least one functional group showing compatibility and/or reactivity to the liquid crystal polymer and/or the thermoplastic polymer.Type: GrantFiled: July 3, 1996Date of Patent: February 11, 1997Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Tatsuya Hattori, Kazuhiro Kagawa
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Patent number: 5599658Abstract: A highly useful photographic film base comprises a miscible blend of poly(ethylene naphthalate) and a poly(ether imide) in specified proportions. Photographic elements prepared with this film base have a lesser tendency to take core-set and post process curl than do elements prepared with poly(ethylene naphthalate) film base.Type: GrantFiled: December 19, 1995Date of Patent: February 4, 1997Assignee: Eastman Kodak CompanyInventors: Jehuda Greener, Wen-Li A. Chen
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Patent number: 5591809Abstract: The present invention provides novel one-step processes for preparing highly branched macromolecule polymers that have highly controlled molecular architectures. The process comprises the reaction of a branching monomer such as a substituted phenyl compound having the formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 are defined herein, with a core monomer and an end-capping monomer, such as a phenolic ester, for a sufficient period of time and at a sufficient temperature to directly produce the highly branched polymer, in a single processing step.Type: GrantFiled: August 18, 1995Date of Patent: January 7, 1997Assignee: Hoechst Celanese CorporationInventors: Richard Vicari, Kathleen N. Juneau, Carl D. Murphy
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Patent number: 5582913Abstract: An improved polyester/polyamide composite fiber is provided. The composite fiber includes a polyamide component generally considered to lack compatibility with a polyester component. Advantageously, the composite fiber includes an adhesion-promoting polymer in an amount effective to provide adhesion of the polyamide component to the polyester component. The composite fiber beneficially provides strength and cost advantages.Type: GrantFiled: August 23, 1995Date of Patent: December 10, 1996Assignee: Hoechst Celanese CorporationInventor: F. Holmes Simons
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Patent number: 5571874Abstract: A molecular composite material having excellent properties such as mechanical strength, heat resistance, solvent resistance, etc. is produced by dissolving a prepolymer of a rigid aromatic polymer in a monomer of a matrix polymer to form a homogeneous solution and then heating the homogeneous solution to cause a thiazole ring closure reaction of the prepolymer and a polymerization reaction of the monomer.Type: GrantFiled: August 22, 1994Date of Patent: November 5, 1996Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Tatsuya Hattori, Kazuhiro Kagawa, Hiroshi Akita, Hiroto Kobayashi
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Patent number: 5571875Abstract: A molding resin composition comprising 99.9 to 50% by weight of polyimide represented by the formula: ##STR1## and 0.1 to 50% by weight of polyether ketone resin and/or polyester resin, and more particularly comprising the polyester resin capable of forming an anisotropical molten phase at a temperature of 420.degree. C. or less, and a polyimide-based molding resin composition which comprises the said resins and other additives such as phenolic resin, fluororesin, graphite, carbon fibers, aromatic polyamide fibers, potassium titanate fibers and a crystallization accelerator, and is excellent in thermal resistance, chemical resistance, mechanical strength and processability.Type: GrantFiled: June 7, 1995Date of Patent: November 5, 1996Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Toshihiko Tsutsumi, Toshiyuki Nakakura, Shuichi Morikawa, Toshiaki Takahashi, Atsushi Morita, Yoshihisa Gotoh
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Patent number: 5565523Abstract: A combination of polymeric components provides desired characteristics in forming medical instruments such as catheters and balloons for dilatation catheters. For example, a balloon material is formed from a blend of polymeric components, including a first crystalline polymeric component and a second softening polymeric component. Where the first two components are generally incompatible, the balloon material can also include a third compatibilizing agent to facilitate blending the first two polymeric components together. The first polymeric component can be a branched or straight chain polyamide having a molecular weight of at least about 5000, or a polyester prepared from aromatic dicarboxylic acids having 8 to 14 carbon atoms or aliphatic dicarboxylic acids having from 2 to 12 carbon atoms, and at least one glycol having the formula HO(CH.sub.2).sub.n OH, where n is an integer from 2 to 10, neopentyl glycol and cyclohexane dimethanol.Type: GrantFiled: June 7, 1995Date of Patent: October 15, 1996Assignee: Advanced Cardiovascular Systems, Inc.Inventors: Ziyun Chen, Tai Cheng, Ketan Muni, Udayan Patel, Robert Saltman
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Patent number: 5543474Abstract: There is provided a resin composition having well balanced moldability, heat resistance and mechanical strength, which comprises (A) all aromatic polyamideimide resin and (B) a Polyester resin, (C) a polyphenylene sulfide resin or (D) a resin capable of forming an anisotropic molten phase, said aromatic polyamideimide resin containing 5 to 95 mol % of a recurring unit of the formula (1) and 5 to 95 mol % of at least one of a recurring unit of the formula (2) and a recurring unit of the formula (3). Said aromatic polyamideimide resin is prepared by conducting a polymerization reaction of an aromatic tricarboxylic acid anhydride and at least any one of all aromatic dicarboxylic acid and an aliphatic dicarboxylic acid with a diisocyanate compound in plural steps in which in the first step the polymerization reaction is conducted in a temperature range of 50.degree. to 110.degree. C. and in the second and subsequent steps the polymerization reaction is conducted in a temperature range of higher than 110.degree.Type: GrantFiled: October 17, 1994Date of Patent: August 6, 1996Assignee: Mitsubishi Gas Company, Inc.Inventors: Takao Kawaki, Akikazu Amagai, Toshiaki Yamada, Hidefumi Harada, Hajime Ban, Yuji Takeda, Koji Yamamoto
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Patent number: 5541240Abstract: Blends of thermotropic liquid crystalline polymers and isotropic melt-processable polymers are made by extruding a molten stream of either a thermotropic liquid crystalline polymer or an isotropic polymer through a heated mixing zone and feeding the other of the two polymers into the stream of the first polymer in the mixing zone. The polymers are mixed under shearing conditions for a time sufficient to yield a uniform blend. Blends made according to this method exhibit improved properties in comparison with blends obtained by feeding the two polymers simultaneously into a heated mixing zone.Type: GrantFiled: March 15, 1994Date of Patent: July 30, 1996Assignee: Hoechst Celanese Corp.Inventors: Subhash Makhija, George L. Lundberg, James B. Stamatoff
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Patent number: 5541244Abstract: The invention relates to polymer mixtures comprising a first polyalkylene phthalate and a second polyalkylene phthalate and/or a thermoplastic elastomer. Certain compounds, namely phosphates, have been found to be good transesterification inhibitors. An important advantage of the said inhibitors is that they do not condense, or hardly condense, to polyphosphates and that they do not negatively influence the impact strength of the polymer mixture.Type: GrantFiled: October 10, 1995Date of Patent: July 30, 1996Assignee: General Electric CompanyInventors: Roelof van der Meer, Constantinus L. J. A. Verbraak, Jan W. Heuseveldt, Johannes van Helmond, Hendrikus H. T. M. Ketels
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Patent number: 5536785Abstract: A thermosetting powder coating composition resistant to overspray incompatibility defects that comprises solid particulates of a uniform mixture of (a) a polyester resin having an average of two or more carboxyl groups, (b) a first crosslinker that is reactive toward the carboxyl groups of the polyester resin, (c) from 1% to 20% of a reactive acrylic copolymer having a weight average molecular weight of from 10,000 to 40,000, and (d) a second crosslinker that is reactive toward the reactive functionality of the acrylic copolymer is described.Type: GrantFiled: April 7, 1995Date of Patent: July 16, 1996Assignee: BASF CorporationInventors: Richard J. Foukes, Cynthia A. Stants
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Patent number: 5532053Abstract: The present invention relates to a laminate film useful as a material from which to manufacture surgical and other protective garments. The laminate film comprises at least one layer formed from a first polyetherester copolymer produced from the condensation reaction of dimethyl-1,4-cyclo hexane dicarboxylate and 1,4-cyclo hexane dimethanol and poly(tetramethylene ether glycol) and a second layer comprising a material selected from the group consisting of an ethylene-vinyl acetate copolymer, an ethylene methacrylate copolymer, a second polyetherester copolymer, an anhydride modified polyolefin copolymer, and a polyether block amide copolymer. The total amount of the first polyetherester copolymer present in the laminate is greater than or equal to 35 wt. % of the total weight of the laminate film to provide strength to the laminate film. The laminate film may be bonded to one or more layers of polyesters, polyolefins, polyamides, and non-woven fabrics.Type: GrantFiled: March 1, 1994Date of Patent: July 2, 1996Assignee: W. R. Grace & Co.-Conn.Inventor: Walter B. Mueller
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Patent number: 5532334Abstract: A process for preparing polyamideimide resins having high molecular weights as described wherein major problems of prior art processes such as low heat resistance and low melt flowability are improved. Polyamideimide resins having an intrinsic viscosity of 0.4 to 1.50 dl/g as measured on a solution of dimethylacetamide as a solvent at a concentration of 0.5 g/dl at 30.degree. C., are prepared by reacting an aromatic tricarboxylic acid anhydride with an aromatic diamine in N-methyl pyrrolidone solvent in the presence of a first catalyst selected from a group consisting of thionyl chloride, p-toluenesulphonly chloride, sulfuryl chloride, cyanuric chloride and phosphorus trichloride at a temperature of 50.degree. C. to 130.degree. C. over a period of 1 to 5 hours and further reacting the resultant reaction mixture in the presence of a second catalyst which is a compound of the formula (RO).sub.Type: GrantFiled: November 14, 1994Date of Patent: July 2, 1996Assignee: Korea Research Institute of Chemical TechnologyInventors: Kil-Yeong Choi, Dong-Hack Suh, Mi-Hie Yi, Young-Taik Hong, Jong-Chan Won
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Patent number: 5521258Abstract: Compositions which comprise blends of a poly(ester-carbonate) resin and a polyetherimide or a poly(ether sulfone) resin are provided. The compositions are useful for preparing articles that are resistant to autoclave sterilization conditions.Type: GrantFiled: November 14, 1994Date of Patent: May 28, 1996Assignee: General Electric CompanyInventors: Stephen M. Cooper, Ronald A. Greenberg, Darryl Nazareth
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Patent number: 5516837Abstract: A molding resin composition comprising 99.9 to 50% by weight of polyimide represented by the formula: ##STR1## and 0.1 to 50% by weight of polyether ketone resin and/or polyester resin, and more particularly comprising the polyester resin capable of forming an anisotropical molten phase at a temperature of 420.degree. C. or less, and a polyimide-based molding resin composition which comprises the said resins and other additives such as phenolic resin, fluororesin, graphite, carbon fibers, aromatic polyamide fibers, potassium titanate fibers and a crystallization accelerator, and is excellent in thermal resistance, chemical resistance, mechanical strength and processability.Type: GrantFiled: March 2, 1994Date of Patent: May 14, 1996Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Toshihiko Tsutsumi, Toshiyuki Nakakura, Toshiaki Takahashi, Atsushi Morita, Yoshihisa Gotoh, Hiroyasu Oochi
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Patent number: 5516855Abstract: Copolymers comprising amide units and ester units are prepared by melt phase interchange of diaryl esters of dicarboxylic acids and diamines with dihydric alcohols and diesters of aromatic dicarboxylic acids. The products are tough resins, useful per se as molding compounds, and to compatibilize and toughen other thermoplastic polymers.Type: GrantFiled: July 27, 1995Date of Patent: May 14, 1996Assignee: General Electric CompanyInventors: Donald C. Clagett, Daniel W. Fox, Louis M. Maresca, Sheldon J. Shafer
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Patent number: 5514739Abstract: An improved synthetic resin composition is provided that consists essentially of 100 parts by weight of a resin component composed of 50 to 99 (preferably 50 to 90) parts by weight of a melt-processable polyester that does not form an anisotropic melt phase and 1 to 50 (preferably 10 to 50) parts by weight of a liquid crystal polyester that is capable of forming an anisotropic melt phase, to which has been added 0.01 to 0.5 part by weight of a phosphorus compound. The presence of the phosphorus compound has been found to facilitate the fibrillation of the liquid crystal polyester component during molding so as to form fibrils within the resulting molded article having an aspect ratio of 6 or more. The resulting molded article accordingly exhibits significantly enhanced mechanical properties.Type: GrantFiled: November 9, 1994Date of Patent: May 7, 1996Assignee: Polyplastics Co., Ltd.Inventors: Tomoyuki Aketa, Takayuki Ishikawa
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Patent number: 5514748Abstract: A molding resin composition comprising 99.9 to 50% by weight of polyimide represented by the formula: ##STR1## and 0.1 to 50% by weight of polyether ketone resin and/or polyester resin, and more particularly comprising the polyester resin capable of forming an anisotropical molten phase at a temperature of 420.degree. C. or less, and a polyimide-based molding resin composition which comprises the said resins and other additives such as phenolic resin, fluororesin, graphite, carbon fibers, aromatic polyamide fibers, potassium titanate fibers and a crystallization accelerator, and is excellent in thermal resistance, chemical resistance, mechanical strength and processability.Type: GrantFiled: June 7, 1995Date of Patent: May 7, 1996Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Toshihiko Isutsumi, Toshiyuki Nakakura, Shuichi Morikawa, Katsunori Shimamura, Toshiaki Takahashi, Atsushi Morita, Nobuhito Koga, Akihiro Yamaguchi, Masahiro Ohta, Yoshihisa Gotoh, Masaki Amano, Hiroyasu Oochi, Kayako Ito
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Patent number: 5512339Abstract: This invention relates to decomposable polyamide masses for packaging materials containing 5 to 25% by weight of an addition of linear, oligomeric aliphatic polyesters or polycarbonates with molecular weights from 800 to 4000. These additives preferably consist of polyesters of aliphatic diols and dicarboxylic acids having up to 10 carbon atoms or aliphatic carbonates having up to 10 carbon atoms.The use of such mixtures for easily degradable, decomposable polyamide packages is also claimed, in particular in the form of films or thin walled injection moulded parts for (food) packaging.Type: GrantFiled: October 22, 1993Date of Patent: April 30, 1996Assignee: Bayer AGInventors: Ralf Dujardin, Rolf Dhein, Martin Wandel
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Patent number: 5512632Abstract: The invention relates to mixtures of special polyesters and/or special polyester carbonates with amorphous thermoplastics and/or with partly crystalline thermoplastics and/or with rubbers and/or with graft polymers useful for molding articles.Type: GrantFiled: March 3, 1993Date of Patent: April 30, 1996Assignee: Bayer AktiengesellschaftInventors: Volker Serini, Dieter Freitag, Ulrich Grigo
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Patent number: 5506283Abstract: Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.Type: GrantFiled: November 23, 1994Date of Patent: April 9, 1996Assignee: Composite Particles, Inc.Inventors: Edwin L. McInnis, Bernard D. Bauman, Mark A. Williams
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Patent number: 5498783Abstract: A thermosetting powder coating composition resistant to overspray incompatibility defects that comprises solid particulates of a uniform mixture of (a) a polyester resin having an average of two or more carboxyl groups, (b) a first crosslinker that is reactive toward the carboxyl groups of the polyester resin, (c) from 1% to 20% of a reactive acrylic copolymer having a weight average molecular weight of from 10,000 to 40,000, and (d) a second crosslinker that is reactive toward the reactive functionality of the acrylic copolymer is described.Type: GrantFiled: August 22, 1994Date of Patent: March 12, 1996Assignee: BASF CorporationInventors: Richard J. Foukes, Cynthia A. Stants
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Patent number: 5494964Abstract: Polyester resins suitable as binders for electrophotographic toners and for acceptor layers for the thermal diffusion printing process based on hydroxyl-containing prepolymers of olefinically unsaturated monomers obtained by(1) polymerization of a mixture of(a) from 60 to 90% by weight of styrene or of a styrene derivative,(b) from 0 to 40% by weight of one or more C.sub.1 -C.sub.Type: GrantFiled: September 30, 1994Date of Patent: February 27, 1996Assignee: BASF AktiengesellschaftInventors: Georg Meichsner, Thomas Wuensch, Rainer Dyllick-Brenzinger
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Patent number: 5493002Abstract: Arylethynyl phthalic anhydrides have been synthesized and shown to have particular application as endcappers or pendant groups in high performance/high temperature thermosets which include amine terminal or amine pendant groups.Type: GrantFiled: July 6, 1994Date of Patent: February 20, 1996Assignees: Virginia Tech Intellectual Properties, Inc., Virginia Polytechnic Institute and State UniversityInventors: James E. McGrath, Gerald W. Meyer
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Patent number: 5489667Abstract: Poly(ether ester amides) consisting of 60% to 80% by weight of a polyamide block obtainable from the following monomers:20 to 40% by weight of caprolactam or aminocaproic acid30 to 50% by weight of 11-aminoundecanoic acid20 to 40% by weight of the adduct of hexamethylenediamine anddecanedicarboxylic acidthe total amount of these polyamide-forming monomers adding up to 100% by weight, and of 20 to 40% by weight of a polyether diol/dicarboxylic acid block obtainable from equimolar amounts of polyethylene glycol with an M.sub.n molecular weight of 400 to 2,000 and one or several saturated aliphatic dicarboxylic acids with 6 to 36 carbon atoms, methods for their synthesis, spunbonded nonwovens from these poly(ether ester amides) and the use of the poly(ether ester amides) for the heat sealing of textiles.Type: GrantFiled: November 29, 1993Date of Patent: February 6, 1996Assignee: Atochem Deutschland GmbHInventors: Helmut Knipf, Karl-Heinz Hapelt, Eduard De Jong
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Patent number: 5478887Abstract: A polymer blend comprising an aliphatic polyamide matrix and a dispersed phase of a polycarbonate and a compatibilizing agent having pendant succinic anhydride groups or epoxide groups, made under such blending conditions that the polymer stock melt temperature is 290.degree.-350.degree. C., has a combination of excellent toughness and stiffness properties.Type: GrantFiled: July 26, 1993Date of Patent: December 26, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventor: Gia Huynh-Ba
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Patent number: 5478888Abstract: The present invention relates to a process for the preparation of a thermoplastic resin composite comprising conducting polycondensation of a monomer material in a solution of an organic solvent containing an organic solvent soluble polymer to form an aromatic condensation polymer which is insoluble in said organic solvent and a thermoplastic resin composite prepared by the process.Type: GrantFiled: March 15, 1994Date of Patent: December 26, 1995Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Naoya Ogata, Takehisa Nakanishi, Tadashi Asanuma
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Patent number: 5470922Abstract: Polymeric blends of polyimide precursor resins and polyamides or polyesters, preferably in the form of liquid crystal polymers, provide polyimide products with excellent physical characteristics and injection molding capability.Type: GrantFiled: May 10, 1994Date of Patent: November 28, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: Mureo Kaku, Robert R. Luise
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Patent number: RE35759Abstract: A thermosetting powder paint coating containing a polymeric binder comprising a polyester graft acrylic copolymer and a low molecular weight crystalline polyester. The coatings can be pigmented or non-pigmented. The polyester-graft-acrylic copolymer can be self-crosslinking by the inclusion of beta-hydroxy ester groups or crosslinked by an external crosslinker.Type: GrantFiled: September 26, 1996Date of Patent: March 31, 1998Assignee: Ferro CorporationInventors: Henry J. DeGraaf, Susan M. Sobek