Abstract: Disclosed herein are polyesters and articles made therefrom. The article comprising a substrate comprising a first surface and a second surface, the second surface in contact with an outside environment, wherein the substrate comprises a polymer comprising poly(trimethylene furandicarboxylate) (PTF), and wherein the polymer provides an improvement in gas barrier properties of the substrate as compared to a substrate comprising nascent polyethylene terephthalate) (PET).

Abstract: Disclosed are polymer blends prepared by melt blending a fluorinated block copolyester with a non-fluorinated polyester wherein the fluorinated block copolyester comprises blocks of fluoroether modified aromatic polyester and blocks of unmodified polyester. Suitable block copolyesters have a blockiness index, B, in the range of 0.25 to 1.0. Shaped articles prepared from the blends exhibit oil and soil resistance with high fluorine efficiency.

Abstract: In one aspect, methods of promoting bone growth are described herein. In some embodiments, a method of promoting bone growth described herein comprises promoting cell differentiation or phenotype progression in a population of bone cells by providing a citrate-presenting composition to the population of bone cells. In some embodiments, the citrate-presenting composition is provided to the bone cells at a first stage of cell development selected to obtain a first cell differentiation or phenotype progression. Additionally, in some cases, a second citrate-presenting composition is further provided to the bone cells at a second stage of cell development selected to obtain a second cell differentiation or phenotype progression.

Abstract: Disclosed is a method for manufacturing a polyester film with low thermal expansion. 95 wt % to 55 wt % of crystalline polyester and 5 wt % to 45 wt % of amorphous polyester are mixed. The blend is then melt extruded to form a sheet. The sheet is then biaxially stretched to obtain a film. The biaxially stretched film is then treated with a heat-setting procedure.

Abstract: The invention relates to compositions based on polyethylene terephthalate and polybutylene terephthalate with optimized crystallization behavior and consequently with optimized processing behavior in the injection molding process, and also to products to be produced therefrom, in particular with optimized crystallinity.

Abstract: The present invention relates to a polyester resin composition comprising: (A) a polyester resin containing 5% by mole or more and not more than 86% by mole of a succinic acid unit in the whole of an aliphatic dicarboxylic acid unit; (B) a polyester resin containing 5% by mole or more and not more than 95% by mole of an aromatic dicarboxylic acid unit in all of dicarboxylic acid units; and (C) a polyester resin containing an aliphatic oxycarboxylic acid, wherein the polyester resin composition contains from 10 to 89% by weight of the resin (A) and from 11 to 90% by weight of the resin (B) relative to a total sum of the resins (A) and (B) and contains from 1 to 40% by weight of the resin (C) relative to a total sum of the resins (A), (B) and (C).

Abstract: Bag made of a breathable biodegradable uniform film having thickness from 10 to 40 ?m and with permeability to water greater than 950 g 30 ?m/m2 24 h in which the biodegradable film comprises starch and possibly a thermoplastic polymer insoluble in water with melting temperature between 60° C. and 150° C.

Abstract: A resin composed of a particular polymer, the particular polymer including a repeating unit containing a structure derived from a dehydroabietic acid, a specific structural unit, and a specific aromatic ring-containing structural unit in the main chain.

Abstract: Disclosed are crosslinked copolymers comprising a copolymer with crosslinks between olefinically unsaturated positions in the backbone of one type of repeat unit and a second repeat unit that is a fluorovinylether functionalized aromatic repeat unit. The crosslinked copolymers are useful for imparting improved soil, water, and oil resistance to materials including fibers, fabrics, carpets, films, plaques, and shaped articles.

Abstract: A polyester film has excellent resistance to hydrolysis, excellent heat resistance in high temperatures and low humidity, and mechanical strength. The polyester film satisfies a stress heat resistant coefficient f(125)?3 and a wet thermo retention (=100×S(120)/S(0)) of 30% or more. f(125) is a value obtained by substituting t=125° C. in an approximation represented by f(t); t represents a temperature (° C.) at thermo processing; f(t) represents a stress heat resistant coefficient f at the thermo temperature t and represents an approximation to a straight line obtained by linear approximation by a least squares method of values plotted from a relationship between the thermo temperature t and a logarithm (log T(t)) of time T at which a rupture stress is 50% when t is 150° C., 160° C., 170° C., or 180° C.; T(t) is a time (hr) at which the maximum stress in a tensile test after thermo processing at t° C.

Abstract: Disclosed are articles made from crosslinked copolymers comprising crosslinks between olefinically unsaturated positions in the backbone of one type of repeat unit and a second repeat unit that is a fluorovinylether functionalized aromatic repeat unit. The articles have enhanced surface fluorine that imparts improved soil, water, and oil resistance to the articles.

Abstract: Disclosed are copolymers comprising a backbone with olefinic unsaturation and fluorovinylether functionalized aromatic repeat units, and methods to make the copolymers. The copolymers are useful for imparting improved soil, water, and oil resistance to materials including fibers, fabrics, carpets, films, plaques, and shaped articles. The copolymers can be crosslinked and used to form shaped articles with the improved properties.

Abstract: Disclosed is a heat shrinkable polyester film formed from a polyester resin that is mainly composed of ethylene terephthalate and contains 3-12% by mole (inclusive) of one or more monomer components, which can be amorphous components, relative to all the polyester resin components, in which the heat shrinkable polyester film has a main shrinkage direction which is the width direction. The heat shrinkable polyester film is characterized in that the shrinkage in 80° C. glycerin, the shrinkage in 130° C. glycerin and the tensile breaking strength in the longitudinal direction are controlled within specific ranges.

Abstract: Disclosed are shaped articles fabricated from polymer blends comprising a fluorinated block copolyester and a non-fluorinated polyester wherein the fluorinated block copolyester comprises blocks of fluoroether modified aromatic polyester and blocks of unmodified polyester. Suitable block copolyesters have a blockiness index, B, in the range of 0.25 to 1.0. Shaped articles that can be made from the copolyesters include films, fibers, and molded parts.

Abstract: The invention aims at providing a heat-shrinkable polyester film which is excellent in tearability along perforations and in break resistance after storage when used as labels of beverage bottles. The invention relates to a heat-shrinkable polyester film which is made of a polyester resin comprising ethylene terephthalate as the main constituent and containing at least 13 mol % of at least one monomer capable of forming an amorphous component in the whole polyester resin component and which has specific heat shrinkage characteristics and exhibits specific mechanical characteristics after heat shrinking treatment. The film can be produced by a sequential biaxial orientation process comprising longitudinal orientation step, intermediate heat treatment step, positive cooling step, transverse orientation step, and final heat treatment step.

Abstract: The invention relates to oligomers (O2) having a terminal group comprising at least one epoxide function, to their preparation method, to their uses as an additive in a polymeric composition for fluidifying and/or improving stability of said composition.

Abstract: Film bags or film tubes formed from biaxially oriented film including less than 10 ppm of antimony and having a haze of less than 10% are provided. The films have an ultimate tensile strength of more than 100 N/mm2; have a difference in the ultimate tensile strength in MD and TD of less than 180 N/mm2; have a tensile strain at break of more than 50%; a tensile strain at break of more than 260%; have a yellowness index b* of less than 2.5; have a lightness L*>85; include from 50 to 15 000 ppm of free-radical scavenger; have an SV of at least 600 after ovening; have a tensile strain at break of >5% after ovening; have a film thickness of from 6 to 26 ?m; and include more than 90% by weight of polyester.

Abstract: The object of the present invention is to provide a thermoplastic polymer composition which is excellent in the impact resistance, a fracture morphology and rigidity, as well as has a possibility of the effect for reducing environmental load. The thermoplastic resin composition comprises 15 to 85% by mass of aliphatic polyester-based resin (A) comprising the following (AI) and (AII) components, and 15 to 85% by mass of styrene-based resin (B) which is at least one selected from the group consisting of the following (BI) to (BIII). The above (AI) is an aliphatic polyester-based resin having units formed from an aliphatic diol and/or an alicyclic diol and an aliphatic dicarboxylic acid (including derivatives thereof) and/or an alicyclic dicarboxylic (including derivatives thereof) as repeating units, and the above (AII) is a polylactic acid-based aliphatic polyester resin having not less than 70 mol % of lactic acid unit content.

Abstract: A sulfopolyester containing residues of 2,2,4,4-tetralkylcyclobutane-1,3-diol such as 2,2,4,4-tetramethylcyclobutane-1,3-diol is highly dispersible in water. This allows one to reduce the content of sulfonate groups or reduce the amount of ethylene glycol or other hydrophilic glycols to retain good water resistance in cured coatings. The sulfopolyester may also be a reaction product of a 2,2,4,4-tetralkylcyclobutane-1,3-diol along with 1,4-cyclohexanedimethanol, neopentyl glycol, or a mixture thereof with an acid component. Coating compositions may also contain these sulfopolyesters along with water and a polymer resin.

Abstract: Disclosed are ternary polyester blends that contain at least one polyester comprising terephthalic or isophthalic acid, ethylene glycol, and 1,4-cyclohexanedimethanol residues, and at least one polyester comprising terephthalic or isophthalic acid, 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 1,4-cyclohexanedimethanol residues. The ternary polyester blends have improved clarity, toughness, and fabrication characteristics and are useful for the preparation of flat or shaped articles. Of special interest are ternary blends where one of the three components compatibilizes the blend of two otherwise immiscible polyesters.

Abstract: A process for producing an IPA/PET copolymer fiber that is homogenous having a substantially level, single IPA copolymer content, said fiber having improved pilling resistance and dye uptake.

Abstract: The present invention relates to a polyester resin composition comprising: (A) a polyester resin containing 5% by mole or more and not more than 86% by mole of a succinic acid unit in the whole of an aliphatic dicarboxylic acid unit; (B) a polyester resin containing 5% by mole or more and not more than 95% by mole of an aromatic dicarboxylic acid unit in all of dicarboxylic acid units; and (C) a polyester resin containing an aliphatic oxycarboxylic acid, wherein the polyester resin composition contains from 10 to 89% by weight of the resin (A) and from 11 to 90% by weight of the resin (B) relative to a total sum of the resins (A) and (B) and contains from 1 to 40% by weight of the resin (C) relative to a total sum of the resins (A), (B) and (C).

Abstract: The present invention is an electroconductive endless belt used in an image forming apparatus in which a decrease with use in the gloss value caused by frictions and the like with papers and cleaning blade is suppressed. In the electroconductive endless belt, the base resin of the electroconductive endless belt comprises a polyalkylene terephthalate resin in combination with a naphthalene ring-containing thermoplastic resin and/or a naphthalene ring-containing thermoplastic elastomer having a melting point higher than that of the polyalkylene terephthalate resin, and the mass ratio of the polyalkylene terephthalate resin to the naphthalene ring-containing thermoplastic resin and/or the naphthalene ring-containing thermoplastic elastomer in the base resin is in the range of 90/10 to 50/50.

Abstract: A polyetherimide having an OH content that is greater than 0 and equal or less than 100 ppm; and a chlorine content that is greater than 0 ppm is disclosed herein. A method for preparing the polyetherimide is also disclosed.

Abstract: The present invention is directed to a multilayer film having, as its main component, a hydroxy acid polymer with improved gas barrier and optional heat sealability. The oriented film of predominately hydroxy acid polymer having controlled shrink can be produced by melting and coextruding a hydroxy acid polymer with a much thinner layer of an amorphous aromatic copolyester to form a multilayer film that is quench cooled, then biaxially stretched at a process temperature above the glass transition and below the cold crystallization temperature of the hydroxy acid polymer. A heat-setting treatment with a controlled relaxation of the film above the hydroxy acid polymer glass transition temperature and below its melt temperature may be used to control shrinkage. The films thus obtained are vacuum metallized on the aromatic copolyester surface to produce environmentally friendly packaging from predominately renewable resources having improved gas barrier properties.

Abstract: Embodiments relate to a relatively rapid transesterification process including transesterifying condensation polymers such as polyethylene terephthalate (PET), or other polyesters used in commerce, with a modifying monomer mix containing other monomers to manufacture new polymers containing the pre-condensed moieties. The process preferably only involves transesterification as a reaction mechanism. The process preferably produces a rapid buildup of molecular weight and/or polymer uniformity by the high temperature transesterification of the condensation polymer with the modifying monomer mixture. The process can be performed in any suitable vessel including an extrusion line, and it has the advantage of greatly reduced cycle times over currently used condensation polymer utilization processes such as the recycling of PET into other materials.

Abstract: Yarns comprising fibers comprising a fluorinated polyester blend are prepared by melt blending a fluorovinyl ether functionalized polyester with a non-fluorinated polyester. The fluoroether functionalized polyester can be a homopolymer or a copolymer. The yarns and fibers, and the textile and carpet goods produced therefrom, exhibit durable soil, oil, and water repellency.

Abstract: Thermoplastic resin compositions for a light reflector contain 2 to 45 parts by mass per 100 parts by mass of a thermoplastic resin (A) of an inorganic filler (B1) treated with a fatty acid type surface treating agent and having an average particle diameter of not more than 3 ?m, or 2 to 45 parts by mass of an inorganic filler (B2) having a refractive index ? of 1.61???2.5 and having an average particle diameter of not more than 3 ?m, 0.01 to 3 parts by mass of glycerol triester of a fatty acid and/or a glycerol diester of a fatty acid (C1), and 0.01 to 3 parts by mass of a glycerol monoester of a fatty acid (C2). A molded article for a light reflector and a light reflector in which a light reflecting metal layer is directly formed on at least a part of the surface of the molded article is produced from one of such thermoplastic resin compositions.

Abstract: Biodegradable compositions containing an aliphatic-aromatic copolyester derived from aromatic polyesters. Methods of making the compositions and articles made from the compositions.

Abstract: The present invention relates to a polyester comprising repeat units based on at least one aliphatic dicarboxylic acid or an ester-forming derivative thereof (component A1), at least one aromatic dicarboxylic acid or an ester-forming derivative thereof (component A2), at least one diol (component B), optionally at least one sulfo-containing compound (component A3) and optionally at least one trifunctional crosslinking agent as component C1 and/or at least one difunctional chain extender as component C2, component A1 comprising 2-methylsuccinic acid or an ester-forming derivative thereof, to a process for preparing the inventive polyester, to the mixtures comprising the inventive polyester, to the use of the inventive polyesters or of the inventive mixtures for production of moldings, films, adhesives, foams or fibers, and to moldings, films, adhesives, foams or fibers comprising at least one inventive polyester or at least one inventive mixture.

Abstract: The present invention provides a polyester resin composition having improved physical properties and a molded body thereof.

Abstract: The invention relates to a biodegradable polyester, particularly suitable for extrusion coating, comprising units deriving from at least a diacid and at least a diol, with long chain branches (isometric with respect to the main chains of the polyester) and essentially gel-free, characterized by optimum adhesion to paper, excellent sealability and processability in extrusion coating systems. Said biodegradable polyester is obtainable through a reactive extrusion process starting from a substantially linear polyester precursor with defined viscosity and concentration of reactive sites which allow transformation of a few chains of the polyester precursor into isometric branches of this polyester. A further object of the present invention is a laminate product composed of at least a backing, preferably paper, and of at least a first layer composed of polyester according to the invention.

Abstract: The present disclosure relates to biodegradable and biocompatible elastomeric polymers that are amorphous and have a glass transition temperature below both room temperature and body temperature, and which will homogenously degrade to water soluble by-products with no reported toxicity.

Abstract: A method for preparing poly(butylene terephthalate-co-adipate) copolymer by polymerizing 1,4-butane diol, an adipic acid component and an aromatic dicarboxy compound derived from polyethylene terephthalate, and a polyester component residue in the presence of a catalyst under conditions effective to form poly(butylene terephthalate-co-adipate) oligomers; adding a quencher; and reacting the quenched poly(butylene terephthalate-co-adipate) oligomers with a chain extender.

Abstract: The invention relates to an optical film containing polymers having different repeating units, and methods for production thereof. Further, the invention also relates to an optical laminate, a polarizing plate, and an image display device each using the optical film. The optical film of the invention advantageously has not only high solubility in solvents but also a high level of transparency since the polymers used in the optical film are compatible with each other. Further, wavelength dispersion of the birefringence of the optical film can be controlled by merely changing a ratio of polymers.

Abstract: This invention relates to a biodegradable polyester which is particularly suitable for use for the manufacture of wrapping films for packaging, comprising units deriving from at least one diacid and at least one diol, characterised by a high static friction coefficient in comparison with conventional biodegradable polyesters. A further object of this invention is a wrapping film comprising the said biodegradable polyester.

Abstract: A multilayer film suitable for sealing containers such as used for food packaging, and methods of making the film, are described. The film is particularly suitable for sealing containers made from polylactic acid (PLA). The multilayer film includes a) a substrate that includes a polymeric base layer; and b) on the substrate, a heatseal layer containing a PLA homopolymer or copolymer. The heatseal layer further includes dispersed therein an adhesion promoter, or alternatively the substrate further includes the adhesion promoter in a layer on a surface of the polymeric base layer between and adjacent the base layer and the heatseal layer. An antifog agent may also be included in the heatseal layer or on the surface of the heatseal layer opposite the substrate.

Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and cyclohexanedimethanol residues. The polyesters have a desirable combination of inherent viscosity and glass transition temperature (“Tg”). The polyesters can have an inherent viscosity from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C. and a Tg of 85 to 115° C. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.

Abstract: The invention is generally directed to baby bottles and other articles produced by blow molding from polymeric materials having glass transition temperatures ranging from 100° C. to 130° C., as well as to processes for producing them. These articles can be exposed to boiling water and can be produced by using a suitable combination of a stretch ratio of less than 3 and a preform temperature at least 20° C. greater than the glass transition temperature (Tg) of the polymeric material.

Abstract: The present invention discloses aromatic polyester polyols suitable for blending with other polyols or other materials mutually compatible with the polyester polyols to achieve polyurethane and polyisocyanurate products. In particular the present invention discloses polyester polyols comprising the reaction of: A) an aromatic component comprising 80 mole percent or greater of terephthalic acid; B) a polyether polyol having a nominal functionality greater than 2 and less than or equal to 4, a molecular weight of 250 to 1000 and has a polyoxypropylene content of at least 70% by weight of the polyol; and C) a glycol other than B having a molecular weight from 60 to 250; wherein A, B, and C are present in the reaction on a percent weight bases of 20 to 60 weight percent A); 15 to 70 weight percent of B); and 10 to 50 weight percent of C).

Abstract: Embodiments relate to a relatively rapid transesterification process including transesterifying condensation polymers such as polyethylene terephthalate (PET), or other polyesters used in commerce, with a modifying monomer mix containing other monomers to manufacture new polymers containing the pre-condensed moieties. The process preferably only involves transesterification as a reaction mechanism. The process preferably produces a rapid buildup of molecular weight and/or polymer uniformity by the high temperature transesterification of the condensation polymer with the modifying monomer mixture. The process can be performed in any suitable vessel including an extrusion line, and it has the advantage of greatly reduced cycle times over currently used condensation polymer utilization processes such as the recycling of PET into other materials.

Abstract: [Problems] To provide a resin-coated metal sheet that exhibits excellent trimming property at the time of being formed into a seamless can, and is capable of providing a seamless can that closely adheres to the printing ink and exhibits excellent abrasion resistance. [Means for Solution] A resin-coated metal sheet including a metal sheet and a layer of a polyester resin which chiefly comprises an ethylene terephthalate unit formed on at least one surface of the metal sheet, wherein the polyester resin is a blend of a lowly crystalline polyester resin and a highly crystalline polyester resin.

Abstract: Disclosed is a method for manufacturing a polyester film with low thermal expansion. 95 wt % to 55 wt % of crystalline polyester and 5 wt % to 45 wt % of amorphous polyester are mixed. The blend is then melt extruded to form a sheet. The sheet is then biaxially stretched to obtain a film. The biaxially stretched film is then treated with a heat-setting procedure.

Abstract: Disclosed is a polycondensation process for preparing block copolyesters comprising blocks of fluoroether functionalized aromatic polyester and blocks of unmodified polyester. According to the process, a non-fluorinated poly(alkylene arylate) first homopolymer and a fluoroether functionalized poly(alkylene arylate) second homopolymer are combined to form a reaction mixture; the reaction mixture is heated to a temperature above the melting temperatures of each said homopolymer to prepare a molten reaction mixture; and the reaction is continued until the desired molecular weight is achieved. The block copolymers incorporated into blends with unmodified aromatic polyester impart oil and soil resistance to shaped articles prepared from the blends.

Abstract: Process for production of multicomponent moldings, which comprises producing a molding of which at least one layer is composed of a thermoplastic molding composition composed of A) from 10 to 99.99% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, and C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.

Abstract: Disclosed is a polycondensation process for preparing block copolyesters comprising blocks of fluoroether functionalized aromatic polyester and blocks of unmodified polyester. According to the process, a non-fluorinated poly(alkylene arylate) first homopolymer and a fluoroether functionalized poly(alkylene arylate) second homopolymer are combined to form a reaction mixture; the reaction mixture is heated to a temperature above the melting temperatures of each said homopolymer to prepare a molten reaction mixture; and the reaction is continued until the desired molecular weight is achieved. The block copolymers incorporated into blends with unmodified aromatic polyester impart oil and soil resistance to shaped articles prepared from the blends.

Abstract: Disclosed are shaped articles fabricated from polymer blends comprising a fluorinated block copolyester and a non-fluorinated polyester wherein the fluorinated block copolyester comprises blocks of fluoroether modified aromatic polyester and blocks of unmodified polyester. Suitable block copolyesters have a blockiness index, B, in the range of 0.25 to 1.0. Shaped articles that can be made from the copolyesters include films, fibers, and molded parts.

Abstract: Disclosed are polymer blends prepared by melt blending a fluorinated block copolyester with a non-fluorinated polyester wherein the fluorinated block copolyester comprises blocks of fluoroether modified aromatic polyester and blocks of unmodified polyester. Suitable block copolyesters have a blockiness index, B, in the range of 0.25 to 1.0. Shaped articles prepared from the blends exhibit oil and soil resistance with high fluorine efficiency.

Abstract: Disclosed are block copolyesters comprising blocks of fluoroether functionalized aromatic polyester and blocks of unmodified aromatic polyester, the block copolyesters having a blockiness index, B, in the range of 0.25 to 1.0. The block copolymers incorporated into blends with unmodified aromatic polyester impart oil and soil resistance to shaped articles prepared from the blends.

Abstract: Described are polyester compositions comprising at least one polyester which comprises terephthalic acid residues, 2,2,4,4-tetramethyl-l,3-cyclobutanediol, and 1,4-cyclohexanedimethanol, wherein the inherent viscosity of said polyester is from 0.55 to 0.68 dL/g as determined in 60/40(wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; wherein said polyester has a Tg from 110 to 160° C.; wherein the polyester composition comprises no polycarbonate; wherein the melt viscosity of the polyester is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C.; and wherein the polyester has a notched Izod impact strength, of at least 7.5 ft-lb/in.ch at 23° C. according to ASTM D256 with a 10-mil notch in a ? inch thick bar. The polyesters may be manufactured into articles of manufacture as fibers, films, bottles or sheets.