Mixed With Polycarboxylic Acid Or Derivative And Polyhydroxy Reactant Or Polymer Thereof Patents (Class 525/444)
  • Patent number: 6111033
    Abstract: A biodegradable polyester prepared from lactic acid, and, optionally, other hydroxy acid or acids. The polyester contains 4-100 carboxyl groups and has an average molecular weight of 1,000 to 200,000 g/mol. Also disclosed are methods of making such polyesters.
    Type: Grant
    Filed: January 15, 1999
    Date of Patent: August 29, 2000
    Assignee: Kinerton, Limited
    Inventors: Thomas Ciaran Loughman, Ruth Mary Russell, Franck Jean-Claude Touraud
  • Patent number: 6110592
    Abstract: Method for the preparation of a polymeric mixture for cable insulators and coatings and sheaths for optic fiber cables; polymeric mixture thus produced and the cables containing it.The method is characterized in that one completely mixes, up to the obtainment of a homogeneous composition, (i) from 50 to 80 parts (w/w) of a first thermoplastic polymer which is amorphous, highly resistant to flames and combustion, and consists of an aromatic polyester of isophthalic and terephthalic acid with bisphenol A, and (ii) from 20 to 50 parts (w/w) of at least a second thermoplastic polymer consisting of an elastomeric polyether-ester block copolymer, having a Shore D hardness greater than 50 and a Vicat softening point greater than 170.degree. C., for a mixing time less than 10 minutes.
    Type: Grant
    Filed: October 15, 1992
    Date of Patent: August 29, 2000
    Assignee: Pirelli Cavi S.p.A.
    Inventors: Redondo Eduardo Grizante, Antonio Zaopo, Luca Castellani
  • Patent number: 6103835
    Abstract: An epoxy-functional polyester storage-stable at temperatures of up to 40.degree. C. and having a Tg of more than 40.degree. C. is prepared by the reaction of an epoxy-functional polyester intermediate (III) produced by glycidating a carboxyl-functional polyester derived from (a) at least one secondary carboxyl groups-containing aromatic or cycloaliphatic dicarboxylic acid (anhydride), (b) at least one aliphatic hydroxyl groups-containing diol, (c) optionally, a compound containing one primary or secondary hydroxyl group, or a compound comprising one primary or secondary hydroxyl group and one tertiary aliphatic carboxyl group, (d) optionally, a compound comprising a tertiary aliphatic carboxyl group and two aliphatic hydroxyl groups and (e) optionally, a trihydroxyalkane or tetrahydroxyalkane; with (IV) a carboxyl-functional polyester obtained from (a) and (b) above, or (a) alone.
    Type: Grant
    Filed: November 11, 1998
    Date of Patent: August 15, 2000
    Assignee: Shell Oil Company
    Inventors: Edward John Marx, Simon Ming-kung Li, Petrus G. Kooijmans
  • Patent number: 6099778
    Abstract: The present invention discloses a process for producing molded, shaped or extruded articles comprising the steps of:a) melt reacting, in the presence of a catalyst which is substantially free of Co compounds, at least one glycol and at least one dicarboxylic acid to form a polyester having an I.V. of at least about 0.5 dL/g, wherein said at least one glycol is selected from the group consisting of glycols having up to 10 carbon atoms and mixtures thereof and said dicarboxylic is selected from the group consisting of alkyl dicarboxylic acids having 2 to 16 carbon atoms, aryl dicarboxylic acids having 8 to 16 carbon atoms and mixtures thereof;b) adding an acetaldehyde reducing additive to said polyester to form a reduced acetaldehyde polyester; andc) forming said reduced acetaldehyde polyester into articles directly from step b.Thus, the present invention provides a process for directly producing from the melt article having extremely low acetaldehyde content.
    Type: Grant
    Filed: October 23, 1997
    Date of Patent: August 8, 2000
    Assignee: Eastman Chemical Company
    Inventors: Gregory Wayne Nelson, Vincent Alvin Nicely, Sam Richard Turner
  • Patent number: 6093777
    Abstract: A partially or fully cured thermosetting product which includes a cured and molded product of a thermosetting composition. The composition includes 70% to 99% by weight of at least one thermosetting resin or compound and 1% to 30% by weight of at least one toughening agent. The toughening agent is at least one hyperbranched dendritic macromolecule formed of ester units, optionally in combination with ether units.
    Type: Grant
    Filed: November 3, 1997
    Date of Patent: July 25, 2000
    Assignee: Perstorp AB
    Inventors: Kent Sorensen, Bo Pettersson, Louis Boogh, Jan-Anders Edvin Manson
  • Patent number: 6090898
    Abstract: A polyester film, comprising a non-liquid crystal polyester (A) and a copolyester (B) containing mesogen groups in the main chain to form a phase separated structure in the non-liquid crystal polyester (A), and the dispersed domains of the copolyester (B), having forms to satisfy the following formulae (1) and (2):0.02<(I/J)<50 (1)K<1/2.times.S[I, J] (2)where I, J and K are form indicators expressing the average form of the plurality of domains existing in the film: I is the average length of the dispersed domains of the copolyester (B) in the machine direction of the film; J, that in the transverse direction; and K, that in the normal direction: and S is a function for selecting the shorter value of the lengths I and J; if I>J, S[I, J] means J, and if I<J, S[I, J] means I. If the copolyester (B) has such geometrical forms, the polyester film obtained is excellent in rigidity, high toughness, heat shrinkage, clarity, surface properties, long-time thermostability, electric properties, etc.
    Type: Grant
    Filed: February 24, 1998
    Date of Patent: July 18, 2000
    Assignee: Toray Industries, Inc.
    Inventors: Tetsuya Tsunekawa, Masaaki Kotoura, Kenji Tsunashima
  • Patent number: 6074660
    Abstract: The present invention describes a polyoxaester copolymers containing amines and/or amido groups and blends thereof with other polymers that may be used to produce surgical devices such as sutures, sutures with attached needles, molded devices, and the like. The polyoxaesters copolymer of the present invention is formed from a first divalent repeating unit of formula IA:[--C(O)--R.sub.30 --C(O)--] IAa second divalent repeating unit of the formula IB:[O--C(O)--C(R.sub.1)(R.sub.2)--O--(R.sub.3)--O--C(R.sub.1)(R.sub.2)--C(O)-- ]Iand a third repeating unit of the formula:[--O--R.sub.12 --].sub.U, XVIand optionally a fourth repeating unit with a formula selected from the group consisting of:[--O--R.sub.4 --].sub.A, II[--O--R.sub.5 --C(O)--].sub.B, III([--O--R.sub.5 --C(O)].sub.P --O--).sub.L G XIand combinations thereof wherein R.sub.12 contains an internal amine or internal amide group.
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: June 13, 2000
    Assignee: Ethicon, Inc.
    Inventors: Dennis D. Jamiolkowski, Rao S. Bezwada
  • Patent number: 6074758
    Abstract: A poly(hydroxy ester ether) is prepared by reacting a) a diacid containing a hetero moiety of the formula:HO.sub.2 CCH.sub.2 X(RX).sub.y CH.sub.2 CO.sub.2 Hwherein X is selected from the group consisting of --O--, --S--, and NH; y is the whole number 0 or 1; and R is selected from the group consisting of an aromatic moiety and a heterocyclic moiety having from 6 to 30 carbon atoms; andb) a diglycidyl ether generally represented by the formula: ##STR1## wherein R.sup.2 is an aromatic moiety or divalent aliphatic hydrocarbon having 2 to 20 carbon atoms. Films, articles and laminations made from the composition exhibit an oxygen permeability of less than about 8 cc-mil/100 in.sup.2 -24 hour-atmosphere. The present invention is further directed to a miscible blend having the poly(hydroxy ester ether) of the present invention and a second component selected from a saturated polyester of an aromatic diacid, such as PET and PEN.
    Type: Grant
    Filed: November 4, 1999
    Date of Patent: June 13, 2000
    Assignee: Eastman Chemical Company
    Inventor: Robert Boyd Barbee
  • Patent number: 6066694
    Abstract: A thermoplastic resin composition comprising:(a) Alkylene aryl polyester copolymers having metal sulfonate units represented by the formula IA: ##STR1## or the formula IB:(M.sup.+n O.sub.3 S).sub.d --A--(OR"OH).sub.pwhere p=1-3, d=1-3, p+d=2-6, n=1-5, and A is an aryl group containing one or more aromatic rings where the sulfonate substituent is directly attached to an aryl ring, R" is a divalent alkyl group and the metal sulfonate group is bound to the polyester through ester linkages;(b) An essentially amorphous polycarbonate, polyester carbonate or polyarylate polymer containing recurring units of the formula II: ##STR2## wherein Ar is divalent aromatic residue of a dicarboxylic acid or mixture of dicarboxylic acids and Ar' is the divalent aromatic residue of a dihydric phenol or mixture of dihydric phenols. The composition may further comprise acidic phosphorus based quenchers, rubbery impact modifiers, mineral fillers or reinforcements.
    Type: Grant
    Filed: March 4, 1998
    Date of Patent: May 23, 2000
    Assignee: General Electric Company
    Inventors: Bret Ja Chisholm, Robert R. Gallucci, William P. England, Patricia A. Hubbard, William D. Richards, Jenny Z. Bu
  • Patent number: 6054209
    Abstract: A tearable film comprising a resin blend which is: (1) a blend of a first polymer which is a styrenic polymer and a second polymer selected from the group consisting of a polyester and a polyamide; or (2) a first polymer which is a polyester and a second polymer selected from the group consisting of a polycarbonate, an acrylic polymer and a polyamide. The film has an continuous phase and a dispersed phase, thereby forming an islands-sea structure, wherein the continuous phase constitutes 35-98 wt % and the dispersed phase constitutes 2-65 wt % of the film.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: April 25, 2000
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Shinichiro Imanishi, Kenji Ueda, Katsuhiko Sumida
  • Patent number: 6051664
    Abstract: A thermoplastic resin composition includes (a) 1 to 99% by weight of a liquid crystalline polyester and (b) 99 to 1% by weight of a polyester as indispensable components, wherein the polyester is composed of the repeating units represented by the following formulas I, II and III in a specific ratio, ##STR1## wherein, X is --SO.sub.2 --, --CO--, --O--, --S--, --CH.sub.2 --, --CH.sub.2 --CH.sub.2 --, --C(CH.sub.3).sub.2 --, or a single bond; R.sub.1 represents an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 3 to 10 carbon atoms, a phenyl group, or a halogen atom; p is an integer of 0 to 4; m and n are integers of 1 to 4; a plurality of R.sub.1 on the same or different nuclei may be the same or different, and each p may be the same or different.
    Type: Grant
    Filed: June 18, 1997
    Date of Patent: April 18, 2000
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tohru Nagashima, Hideo Nomura
  • Patent number: 6048936
    Abstract: Acrylate copolymers AB obtainable by polymerization of a monomer mixture A in an organic solvent or in bulk, the monomer mixture A comprising proportions by mass of from 25 to 80% of C.sub.1 -C.sub.20 -alkyl (meth)acrylates whose alkyl radicals can be linear, branched or cyclic, from 1 to 28% of C.sub.2 -C.sub.20 -hydroxyalkyl (meth)acrylates whose hydroxyalkyl radicals can be linear, branched or cyclic, from 0.5 to 20% of .alpha.,.beta.-unsaturated carboxylic acids and from 0 to 55% of aromatic vinyl compounds or aliphatic vinyl esters and vinyl ethers, vinyl halides, olefinically unsaturated ketones or aldehydes, esters of glycidyl alcohol or methylglycidyl alcohol with olefinically unsaturated carboxylic acids, or nitriles of .alpha.,.beta.
    Type: Grant
    Filed: August 7, 1998
    Date of Patent: April 11, 2000
    Assignee: Vianova Resins AG
    Inventors: Ulrich Epple, Gert Dworak, Ulrike Kuttler, Claudia Pietsch
  • Patent number: 6048948
    Abstract: There is a provided a method to produce a polymer composite material in which the rigid polymer (R.sub.m).sup.n is dispersed uniformly at the molecular level in the flexible polymer (M), preferably by both polymerization with no solvent in the molten and mixed state and subsequent polymerization in the solid state. According to the preferred embodiment of the present invention, the polymer composite material is produced by polymerization with no solvent in the molten and mixed state. In the case that the rigid polymer is polymerized from the monomer having a slow polymerization rate, in order to prevent roughness of the rigid polymer during polymerization, the polymerization in the molten state is stopped at the polymerization degree equal to that of an oligomer and the resulting composite is subsequently polymerized in the solid state to increase the polymerization degree of the rigid polymer.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: April 11, 2000
    Assignee: Mazda Motor Corporation
    Inventor: Takahiro Tochioka
  • Patent number: 6048626
    Abstract: A polyester composition, comprising a thermoplastic polyester resin and hydroxy apatite particles with an average particle diameter of 0.01 to 10 .mu.m and a specific surface area of 50 to 500 m.sup.2 /g and represented by the following chemical formula, and a film made thereof. A polyester film excellent in such basic properties as slipperiness and abrasion resistance, and also in electric properties, perforability, processability as a laminate with a metallic sheet, flavor properties, etc. can be obtained.Ca(PO.sub.4).sub.l (OH).sub.m (CO.sub.3).sub.n Y.sub.x(where Y stands for any optional anions other than phosphate group, hydroxyl group and carbonate group, l=0.4.about.0.6, m=0.1.about.0.4, n=0.about.0.2, x=0.about.0.2, 3.times.l+m+2.times.n+z.times.
    Type: Grant
    Filed: April 29, 1999
    Date of Patent: April 11, 2000
    Assignee: Toray Industries, Inc.
    Inventors: Toshihiro Tsuzuki, Yuzo Shimizu, Takashi Ueda, Tsutomu Morimoto
  • Patent number: 6046248
    Abstract: Biodegradable polyether esters are obtained by reacting a mixture of(a1) from 95 to 99.9% by weight of polyether ester obtained by reacting(b1) a mixture comprising20-95 mol % of adipic acid or ester-forming derivatives thereof or mixtures thereof,5-80 mol % of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and0-5 mol % of a compound which contains sulfonate groups, and(b2) a mixture of dihydroxy compounds,(a2) from 0.1 to 5% by weight of a divinyl ether C1 and(a3) from 0 to 5 mol %, based on component (b1) from the preparation of P1, of compound D,and other biodegradable polymers and thermoplastic molding compositions, processes for the preparation thereof, the use thereof for producing biodegradable moldings, and adhesives, biodegradable moldings, foams and blends with starch obtainable from the polymers and molding compositions according to the invention.
    Type: Grant
    Filed: November 20, 1997
    Date of Patent: April 4, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Warzelhan, Frank Braun, Matthias Kroner, Ursula Seeliger, Motonori Yamamoto, Rainer Buschl
  • Patent number: 6046265
    Abstract: A crystalline resin molded article with a non-uniform appearance, or a process for making such an article, comprising a molded blend of a granular crystalline resin base resin and a granular crystalline resin colored concentrate which has contrasting color properties. The granular color concentrate comprising a crystalline resin carrier resin having a melting temperature sufficiently higher than the base resin for non-uniformly dispersing the granular color concentrate into the base resin during molding to produce a non-uniform appearance in said molded article.
    Type: Grant
    Filed: January 21, 1998
    Date of Patent: April 4, 2000
    Assignee: General Electric Company
    Inventors: Angelika H. Clark, James A. Catelotti, Robert R. Gallucci, Parfait J. M. Likibi
  • Patent number: 6037420
    Abstract: The polymer composite material is produced using no solvent and includes a rigid polymer (B) dispersed uniformly into a matrix (A) at the molecular level in a state of a copolymer (A/B and/or A'/B) thereby enhancing the interface bonding of the rigid polymer (B) to the matrix (A). The non-solvent method includes a step of polymerizing a thermoplastic polymer (A) and a monomer to form a rigid polymer (B) with no solvent in the molten and kneaded state to provide a copolymer (A/B and/or A'/B) in which the flexible molecular chains (A and/or A') are made up of the thermoplastic polymer to the rigid polymer (B) to reduce the stress concentrating sources of the rigid polymer dispersed microscopically at the molecular level in the thermoplastic polymer matrix and enhance the interface bonding between the rigid polymer (B) and the matrix (A).
    Type: Grant
    Filed: December 1, 1995
    Date of Patent: March 14, 2000
    Assignee: Mazda Motor Corporation
    Inventor: Takahiro Tochioka
  • Patent number: 6030571
    Abstract: A method of molding which comprises preparing a molding material by compounding a filler and a curable composition, the filler being in an amount of 0 to 800 weight parts based on 100 weight parts of the curable composition and optionally aging the molding material at room temperature or by heating, followed by casting the molding material into a mold and curing the molding material under atmospheric pressure or higher, and articles molded by such method.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: February 29, 2000
    Assignee: NOF Corporation
    Inventors: Yoshinori Nakane, Hiroki Mizutani, Hayato Ishibashi, Masahiro Ishidoya
  • Patent number: 6024943
    Abstract: Perfume is absorbed within organic polymer particles which have a further polymer at their exterior. The further polymer incorporates free hydroxyl groups and serves to promote deposition of the particles from a wash or rinse liquor. The further polymer may be part of an encapsulating shell, but more conveniently is used as a stabiliser during polymerisation of the particles. Highly hydrolysed polyvinyl alcohol is preferred.
    Type: Grant
    Filed: December 23, 1997
    Date of Patent: February 15, 2000
    Inventors: Jeremy Nicholas Ness, Pamela Virginia Irving, Marcus James Goodall, Kenneth Charles Symes, Bryan David Grey
  • Patent number: 6010760
    Abstract: A thermoplastic resin composition comprising a thermoplastic resin (A) not forming an anisotropic melt phase and a liquid crystal polymer (B) capable of forming an anisotropic melt phase, an injection molding method thereof and an injection molded article capable of providing a thin molded article having excellent mechanical strength. A thermoplastic resin composition (C) comprises 99 to 50 wt. % of the thermoplastic resin (A) and 1 to 50 wt. % of the liquid crystal polymer (B). The liquid crystal polymer (B) is microscopically dispersed in an island form in the matrix phase of the thermoplastic resin (A) so that when the composition (C) is heat-treated at a temperature not lower than the melting point of the liquid crystal polymer (B) under a non-load state and is then cooled, the liquid crystal polymer (B) has a weight average particle diameter within the range of 10 to 40 micrometers and at least 80 wt. % thereof has a particle diameter within the range of 0.5 to 60 micrometers.
    Type: Grant
    Filed: June 17, 1997
    Date of Patent: January 4, 2000
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hirotaka Miyazaki, Tomoyuki Aketa, Haruji Murakami, Takayuki Ishikawa, Kazuhito Kobayashi, Ayako Migita
  • Patent number: 6008182
    Abstract: A process for preventing dye redeposition during the washing of a dyed fabric or garment made from natural fibers, which process incorporates as a dye redeposition inhibiting agent, a water-soluble or water-dispersible polyester resin composition comprising a reaction product of 20%-50% by weight of terephthalate polymer or waste terephthalate polymer, 10-40% by weight of at least one glycol and 5-25% by weight of at least one oxyalkylated polyol.
    Type: Grant
    Filed: June 22, 1998
    Date of Patent: December 28, 1999
    Assignee: Seydel Research, Inc.
    Inventors: Robert Keith Salsman, Brian J. Clark
  • Patent number: 5998552
    Abstract: A composition comprising a polylactide polymer with improved extensional viscosity and methods of making the same are disclosed. The polylactide polymer composition is prepared by providing in the composition polylactide polymer molecules which have been modified, relative to linear non-substituted polylactide, to provide increased molecular interaction among polylactide backbone chains in the composition. The preferred polylactide polymer composition has a number average molecular weight of at least about 10,000 (preferably at least 50,000) and a polydispersity of at least about 2.5. In addition, the polylactide polymer composition should have a neck-in ratio of less than about 0.8.
    Type: Grant
    Filed: July 20, 1998
    Date of Patent: December 7, 1999
    Assignee: Cargill, Incorporated
    Inventors: Patrick Richard Gruber, Jeffrey John Kolstad, David Roy Witzke, Mark Henry Hartmann, Andrea Lee Brosch
  • Patent number: 5994478
    Abstract: Hydroxyterminated PHA is produced by cultivating a PHA-producing microorganism in the presence of an aliphatic diol or an aliphatic polyol. High molecular weight hydroxy-terminated PHA is obtainable by the disclosed process, and is useful in the production of graft, block and random polymers and copolymers with other monomers, oligomers and polymers containing appropriate functionality and end group compatibility.
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: November 30, 1999
    Assignee: Monsanto Company
    Inventors: Jawed Asrar, Devang T. Shah, Minhtien Tran
  • Patent number: 5990265
    Abstract: Disclosed herein is a novel physical form of low molecular weight poly(trimethylene terephthalate). This form may be produced from molten low molecular weight poly(trimethylene terephthalate) material by means of rapid heat transfer from the material. The poly(trimethylene terephthalate) composition is suitable for use as a starting material for solid-state polymerization in order to produce polymers of higher molecular weight.
    Type: Grant
    Filed: June 22, 1998
    Date of Patent: November 23, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Elwood Neal Blanchard, Craig Robert Gochanour, Kenneth Wayne Leffew, Jan M. Stouffer
  • Patent number: 5989758
    Abstract: There are provided liquid crystalline polyesters comprising 4'-hydroxy-4-stilbenecarboxylic acid type units, dicarboxylic acid units acting as a mesogen such as 4,4'-stilbenecarboxylic acid and catechol units as essential ingredients, and a liquid crystalline polyester composition comprising said polyesters and optically active liquid crystalline polyesters consisting essentially of 4,4'-stilbenedicarboxylic acid type units and aliphatic diol units having asymmetric carbons.
    Type: Grant
    Filed: September 30, 1998
    Date of Patent: November 23, 1999
    Assignee: Nippon Oil Company, Limited
    Inventors: Shinichi Komatsu, Suzushi Nishimura, Akira Takagi, Shinichiro Suzuki
  • Patent number: 5990248
    Abstract: The present invention relates to a polyethylene-2,6-naphthalate film comprising a resin composed mainly of polyethylene-2,6-naphthalate and having an intrinsic viscosity .eta. in the range of from 0.31 to 0.6, said film having stretch ratios of 1 to 3 times and 1 to 3 times or 3 to 6 times and 1 to 1.8 times respectively in substantially mutually perpendicular directions and a thickness in the range of from 5 to 150 .mu.m;a polyethylene-2,6-naphthalate resin comprising a blend composed mainly of two components of: a polyethylene-2,6-naphthalate resin having an intrinsic viscosity in the range of from 0.3 to 0.5 dl/g and prepared by an esterification reaction of a dicarboxylic acid having a 2,6-naphthalenedicarboxylic acid content of not less than 90% by mole with a glycol having an ethylene glycol content of not less than 90% by mole, or a transesterification and a polyethylene-2,6-naphthalate resin having an intrinsic viscosity in the range of from 0.5 to 0.
    Type: Grant
    Filed: September 9, 1998
    Date of Patent: November 23, 1999
    Assignees: NKK Corporation, DAI Nippon Printing Co., Ltd.
    Inventors: Shinichiro Mori, Katsuhiko Sasada, Kayo Hasegawa, Yasuhiro Harada, Chikao Kumaki, Masahisa Yamaguchi, Yasuki Suzuura, Rikiya Yamashita, Toshiyuki Suzuki, Isao Inoue
  • Patent number: 5981007
    Abstract: The present invention relates to articles of manfacture, such as films, tubes, and coatings, comprising a multiaxially oriented film having a planar morphology, wherein the article of manfacture comprises at least one thermoplastic flexible polymer, at least one thermotropic liquid crystalline polymer, or a blend thereof. Recyclable articles of manufacture having improved barrier properties are also provided.
    Type: Grant
    Filed: February 1, 1996
    Date of Patent: November 9, 1999
    Assignee: Foster-Miller, Inc.
    Inventors: Leslie S. Rubin, Kent G. Blizard, Ross R. Haghighat, Richard W. Lusignea
  • Patent number: 5980777
    Abstract: A liquid crystalline resin which comprises at least one kind of liquid crystalline polymer selected from liquid crystalline polyester and liquid crystalline polyester amide, both forming an anisotropic molten phase, and an inorganic phosphorus compound, said liquid crystalline resin having an absorbance of 0.5 or less at 380 nm when measured over an optical path length of 10 mm in a 0.5 wt % solution in a 1:1 mixed solvent of pentafluorophenol and chloroform (by weight). It is useful as engineering plastics because of improved color, heat resistance, and hydrolytic resistance.
    Type: Grant
    Filed: December 24, 1997
    Date of Patent: November 9, 1999
    Assignee: Toray Industries, Inc.
    Inventors: Hideyuki Umetsu, Yoshiki Makabe, Toshihide Inoue
  • Patent number: 5981690
    Abstract: Poly(alkylene arylates) having excellent optical properties are disclosed and can be prepared using an organic titanate-ligand catalyst solution containing organic silicates and/or zirconates and, preferably, certain phosphorus compounds.
    Type: Grant
    Filed: April 15, 1999
    Date of Patent: November 9, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Steven Raymond Lustig, Robert Ray Burch
  • Patent number: 5976654
    Abstract: Polyester resins containing up to 5% by weight of a polymeric liquid crystal and an upgrading agent capable of increasing the I.V. of the resin by polyaddition reaction in the solid state with the end groups of the resin. Fibers, films and biaxially oriented articles obtained from the resins.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: November 2, 1999
    Assignee: Sinco Engineering S.p.A.
    Inventors: Hussain Ali Kashif Al Ghatta, Tonino Severini, Sandro Cobror
  • Patent number: 5976406
    Abstract: A resin composition comprising an inorganic filler in the form of fiber or plate compounded in a liquid crystal polyester resin composition obtained by compounding 10 to 150 parts by weight of a liquid crystal polyester (B) into 100 parts by weight of a liquid crystal polyester (A), wherein the liquid crystal polyester (A) has a flow temperature of from 310 to 400.degree. C., the liquid crystal polyester (B) has a flow temperature of from 270 to 370.degree. C., the difference between the flow temperature of the liquid crystal polyester (A) and the flow temperature of the liquid crystal polyester (B) is from 10 to 60.degree. C., and the content of the inorganic filler is from 15 to 180 parts by weight based on 100 parts by weight of the total amount of the liquid crystal polyester (A) and the liquid crystal polyester (B).The resin composition is excellent in thin-wall flowability and can provide a molded article having excellent heat resistance and low warpage, and can provide a super thin-wall molded article.
    Type: Grant
    Filed: February 3, 1998
    Date of Patent: November 2, 1999
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoshi Nagano, Hideo Nomura
  • Patent number: 5976706
    Abstract: Polyesterdiols having low viscosities of less than 3500 cps, high content of non-volatile matter in excess of 96 wt %, and narrow molecular weight distribution of less than about 1.4 are prepared by esterification of one or more aliphatic dicarboxylic acids or ester derivatives thereof using at least a 1.5 molar excess of one or more aliphatic diols until an acid number of less than 20 is achieved, and stripping excess diol from the polyesterdiol reaction product. Where esterification catalyst is used, catalyst is substantially removed prior to stripping excess unreacted diol from polyesterdiol reaction product. The polyesterdiols so produced are useful as (i) curable components in thermosettable resin compositions, particularly compositions essentially free of volatile organic solvent and also containing a crosslinking agent and a reactive hardening agent: and/or (ii) useful as coatings, paints and adhesives, providing coatings with very low content of volatile organic compounds.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: November 2, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Albert Ilya Yezrielev, Konstantinos R. Rigopoulos, Richard William Ryan, Karen K. Kuo, George Andrew Knudsen
  • Patent number: 5972439
    Abstract: A novel polyester film and a process for its preparation are disclosed wherein said film is composed of (a) liquid crystal polyester; (b) non-liquid crystal polyester; and (c) fiberizer capable of substantially fiberizing said liquid crystal polyester (a). Said polyester film shows remarkable improvements in various properties compared with the prior art polyester films: polyester film according to the present invention exhibits: (a) a high modulus of elasticity; (b) a high toughness; (c) a small content of: (1) oligomer, (2) thermal decomposition products and (3) gelation products; and (d) excellent electrical properties, so that this film can be used as a base film for electrical insulating material, capacitors, magnetic recording mediums, etc.
    Type: Grant
    Filed: June 25, 1996
    Date of Patent: October 26, 1999
    Assignee: Toray Industries Inc.
    Inventors: Kenji Tsunashima, Tetsuya Tsunekawa, Masaaki Kotoura
  • Patent number: 5972446
    Abstract: The refillable polyester bottle of the invention has a mean crystallinity of 32 to 70% at the bottle body, a methanol adsorption of 1,500 ppm or less at the same portion and a paraxylene adsorption of 300 ppm or less at the same portion. Therefore, the bottle is excellent in non-adsorptivity and heat resistance. According to the method of removing adsorbates on a polyester bottle of the invention, the adsorbates can be rapidly desorbed by holding the bottle in air of 40 to 150.degree. C. or bringing the bottle into contact with water or water vapor heated at 40 to 150.degree. C.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: October 26, 1999
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hidenori Kaya, Hiroji Niimi, Susumu Hatabu, Kunio Tomita
  • Patent number: 5972445
    Abstract: The present invention relates to a multilayer polyester sheet comprising:a base layer comprising a thermoplastic polyester resin (A) having a glass transition temperature of not less than 80.degree. C., anda sealing layer comprising a thermoplastic polyester resin (B) having a glass transition temperature at least 5.degree. C. lower than that of the base layer and laminated on at least one side of the base layer,said multilayer polyester sheet being a substantially non-stretched transparent sheet.
    Type: Grant
    Filed: July 20, 1998
    Date of Patent: October 26, 1999
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Hisashi Kimura, Koichi Tamura
  • Patent number: 5969056
    Abstract: A process for the preparation of an esterification product comprises reacting a polyfunctional organic acid or anhydride and a cyclic organic carbonate compound in the presence of a catalyst to form an esterification product. The catalyst comprises a quaternary ammonium salt and a component selected from the group consisting of a metal, a salt of a metal, and mixtures thereof.
    Type: Grant
    Filed: January 14, 1999
    Date of Patent: October 19, 1999
    Assignee: Reichhold, Inc.
    Inventor: Hildeberto Nava
  • Patent number: 5958601
    Abstract: This invention relates to the synthesis from PET (virgin, recycled, post consumer, or precursor raw materials) of novel water dispersible or water emulsifiable polyester resins having improved hydrophobicity or non-polar characteristics. These characteristics give the applied film of these dispersions or emulsions much improved water repellency while at the same time retaining their redispersible or reemulsifiable properties. Such resins can be used for many applications in the paper, textile, coatings, paint, construction, and other industries.
    Type: Grant
    Filed: October 22, 1998
    Date of Patent: September 28, 1999
    Assignee: Seydel Companies, Inc.
    Inventor: Robert Keith Salsman
  • Patent number: 5948525
    Abstract: A biaxially stretched polyester film for forming a container, characterized by being formed of a polyester substantially consisting of an ethylene terephthalate unit and an ethylene naphthalate unit, the refractive index in the direction of thickness of the film being 1.5 or greater. This film is not only excellent in the formability during formation into cans or the like, but has excellent properties in taste property, particularly, the taste property after the retorting, and may be suitably used for containers produced by forming process and, particularly, for metallic cans.
    Type: Grant
    Filed: January 26, 1998
    Date of Patent: September 7, 1999
    Assignee: Toray Industries, Inc.
    Inventors: Masahiro Kimura, Kohzo Takahashi, Hiroji Kojima, Koichi Abe
  • Patent number: 5948864
    Abstract: Novel golf ball compositions which contain liquid crystalline polymers and liquid crystalline polymer blends. These compositions can be foamed or unfoamed. Golf balls that employ at least one layer of these blends in any of the golf ball cover, core, or a mantle situated between the cover and the core provide ball properties and performance similar to and in some cases better than the state of the art ionomer based golf balls.
    Type: Grant
    Filed: February 11, 1998
    Date of Patent: September 7, 1999
    Assignee: Acushnet Company
    Inventor: Murali Rajagopalan
  • Patent number: 5939497
    Abstract: Visually clear thermoplastic resin compositions include a polyetherimide resin, a first polyester resin and a second polyester resin, wherein from 50 to 100 mole percent of the structural units of the first polyester resin include an alicyclic hydrocarbon radical as the diol residue of the structural unit, and wherein less than 50 mole percent of the structural units of the second polyester include an alicyclic hydrocarbon radical as the diol residue of the structural unit, exhibit resistance to elevated temperature and improved impact properties.
    Type: Grant
    Filed: September 5, 1997
    Date of Patent: August 17, 1999
    Assignee: General Electric Company
    Inventors: Jun Liao, Darryl Nazareth, Yimin Jin
  • Patent number: 5936045
    Abstract: Biodegradable polymers comprising a polyether ester P1 obtained by reactinga first mixture of20-95 mol% of adipic acid or ester-forming derivatives thereof or mixtures thereof,5-80 mol% of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and0-5 mol% of a compound containing sulfonate groups,and a second mixture of15-99.8 mol% of a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,85-0.2 mol% of a dihydroxy compound IHO--?(CH.sub.2).sub.n --O!.sub.m --H(n=2, 3 or 4, m=2-250)with0-5 mol%, based on the first mixture, of a compound D having at least three groups capable of ester formation,and a bisoxazoline C1, their preparation and their use in the manufacture of biodegradable molding materials.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: August 10, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Warzelhan, Gunter Pipper, Ursula Seeliger, Peter Bauer, Dieter Bernhard Beimborn, Motonori Yamamoto
  • Patent number: 5932666
    Abstract: This invention is a thermoplastic saturated polyester low profile additive (low profile additive) useful in sheet molding compounds for parts, especially vehicle parts. The additive has a major component derived from aromatic compounds such as terephthalic acid including recycled polyethylene terephthalate. Asymmetrical glycols are an important ingredient and can be used to digest recycled PET to make oligomeric glycols which are reacted with acids having fewer than 12 carbon atoms to make one of the low profile additives of this invention.
    Type: Grant
    Filed: March 25, 1998
    Date of Patent: August 3, 1999
    Assignee: Ashland Inc.
    Inventor: Dennis Herbert Fisher
  • Patent number: 5919872
    Abstract: Polyester blends of polyethylene terephthalate and polyethylene isophthalate coated with an alkylene carbonate such as ethylene carbonate or propylene carbonate crystallize more quickly and at lower temperature than uncoated pellets, reducing the tendency of the pellets to stick together during the crystallization process prior to solid-state polymerization.
    Type: Grant
    Filed: June 12, 1997
    Date of Patent: July 6, 1999
    Assignee: Shell Oil Company
    Inventors: William C. T. Tung, Joseph P. Schirmer, Patrick J. Pesata
  • Patent number: 5917010
    Abstract: The invention relates to a preparation process of aliphatic polyester, comprising using an ion exchange resin as a drying agent and after the dehydration polycondensation reaction, regenerating and drying the used ion exchange resin and repeatedly using said ion exchange resin in the next dehydration polycondensation reaction, in a process for preparing aliphatic polyester from one or more aliphatic compound (A) by heating in an organic solvent in the presence of a catalyst, distilling a generated water containing organic solvent out of the reaction system, treating the distilled organic solvent with a drying agent, and returning the treated solvent to the reaction system to progress a dehydration polycondensation reaction. The process of the invention enables one to steadily and efficiently prepare in industry an aliphatic polyester having an excellent color tone, high molecular weight and high quality.
    Type: Grant
    Filed: August 26, 1997
    Date of Patent: June 29, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Kenichi Goto, Yukiko Mori, Michihiko Miyamoto
  • Patent number: 5912060
    Abstract: A biaxial oriented polyester film which is obtained by using as a main raw material a mixture comprising a thermoplastic polyester resin (i) wherein an acid component is mainly composed of a terephthalic or naphthalenedicarboxylic acid component and a thermoplastic polyester resin (ii) having substantially a phase-separated form to the resin (i), and orienting an unoriented sheet of the mixture wherein an illuminance anisotropic ratio (IAR) of transmitted scattering light satisfies the following condition of 0.1.ltoreq.IAR.ltoreq.1.0.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: June 15, 1999
    Assignee: Unitika Ltd.
    Inventors: Minoru Kishida, Masanobu Hioki, Atsuhiro Ishikawa
  • Patent number: 5912307
    Abstract: Polyester compositions containing terephthalate, 2,6-naphthalate and/or isophthalate moieties, and showing improved properties are disclosed.
    Type: Grant
    Filed: May 2, 1997
    Date of Patent: June 15, 1999
    Assignee: BP Amoco Corporation
    Inventors: Edward E. Paschke, Charles W. Bauer, Frank C. Robertson, James M. Tibbitt
  • Patent number: 5910363
    Abstract: This invention relates to a polyester composition comprising:(A) 95 to 99.90% by weight of a polyester comprising from about 85 to 100 mole % of 2,6-naphthalenedicarboxylic acid and 85 to 100 mole % of at least one aliphatic glycol having from 2 to 16 carbon atoms, based on the total mole percentage for the glycol portion and for the acid portion of said polyester each equalling 100 mole %, and(B) 0.1 to 5.0% by weight of one or more polymeric carbodiimides.These polyester compositions result in improved hydrolytic stability in end products such as fiber, monofilament, films, thermoformed articles, containers and sheeting based on naphthalenedicarboxylic acid and ethylene glycol.
    Type: Grant
    Filed: May 6, 1998
    Date of Patent: June 8, 1999
    Assignee: Eastman Chemical Company
    Inventors: Martin Emerson Rogers, Sarah Jayne Webb
  • Patent number: 5910545
    Abstract: Disclosed is a thermoplastic composition comprising an unreacted mixture of a poly(lactic acid) polymer; a polybutylene succinate polymer or a polybutylene succinate adipate polymer, or a mixture of such polymers; and a wetting agent. The thermoplastic composition exhibits substantial biodegradable properties yet is easily processed. The thermoplastic composition is useful in making multicomponent fibers or nonwoven structures that may be used in a disposable absorbent product intended for the absorption of fluids such as body fluids.
    Type: Grant
    Filed: October 31, 1997
    Date of Patent: June 8, 1999
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Fu-Jya Tsai, Brian T. Etzel
  • Patent number: 5902539
    Abstract: Process for controlling the rate of change of intrinsic viscosity and transesterification during solid stating of a polyethylene terephthalate (PET) and polyethylene naphthalate (PEN) blend, with an effective amount of an ethylene glycol compound. The process enables the production of a copolymer based on predefined initial and final IV's and final transesterification level, by varying the solid-stating time and/or effective amount of ethylene glycol. In one embodiment, a relatively greater amount of post-consumer PET (e.g., 70%) having an IV of on the order of 0.72-0.73, is incorporated in the blend to provide a final IV on the order of 0.80-0.85, and a moderate, controlled level of transesterification; the blend is used to injection mold a sleeve layer of a preform. In another embodiment, a substantially transparent neck finish for a preform is made from a PEN/PET blend having an amount of ethylene glycol which enables substantial transesterification, without excessive increase in IV.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: May 11, 1999
    Assignee: Continental Pet Technologies, Inc.
    Inventors: Steven L. Schmidt, Bryan Lynch, Amit Suresh Agrawal
  • Patent number: 5902709
    Abstract: A polyester resin for a toner whereina ratio of insoluble material in THF is comprised at 5 weight % or less,a ratio of soluble polymer having a molecular weight of 1.times.10.sup.6 or greater in THF is comprised at a range of 1 weight % to 10 weight %,a soluble polymer having a molecular weight greater than 1.times.10.sup.5 in THF is comprised in a range of 10 weight % to 20 weight %, and the following relationship is satisfied W1>W2wherein a ratio of a soluble polymer having a molecular weight less than 1.times.10.sup.4 in THF is shown by W1, a ratio of a soluble polymer having a molecular weight greater than 1.times.10.sup.4 and less than 1.times.10.sup.5 in THF is shown by W2.
    Type: Grant
    Filed: April 24, 1997
    Date of Patent: May 11, 1999
    Assignee: Tomoegawa Paper Co., Ltd.
    Inventors: Koji Nakayama, Haruo Okutani