With Additional Aldehyde Or Aldehyde-type Reactant Or Polymer Therefrom Which Is Distinct From Aldehyde Or Aldehyde-type Reactant Used In Forming Solid Polymer Or Sicp; Or With Nitrogen-containing Reactant Patents (Class 525/489)
Abstract: Water-dilutable resinous products are obtained by reacting(A) a resin having at least one phenolic hydroxyl group and a free position ortho and/or para to a phenolic hydroxyl group, and containing a residue formed by polymerization of a vinyl monomer in the resin or in a precursor thereof,(B) an aldehyde, and(C) sulphurous acid or an organic acid containing a primary or secondary amino group or a mercaptan group and a carboxylic, sulphonic or phosphonic acid group, or a water-soluble salt thereof.Aqueous compositions containing the resinous products and, if required, and aminoplast, a phenoplast or a blocked polyisocyanate, usually together with a minor amount of an organic solvent, are useful in the formation of surface coatings.
Type:
Grant
Filed:
March 11, 1985
Date of Patent:
March 25, 1986
Assignee:
Ciba-Geigy Corporation
Inventors:
Christopher G. Demmer, Roderick D. Hathaway
Abstract: A method for curing 1,2-epoxy resins wherein a 1,2-epoxy resin is mixed with an effective amount of an amine curing agent comprising a solution of a normally solid cured polyurethane elastomer in a 1,2-epoxy-interactive polyamine curing agent, whereby reaction of the amino hydrogens of the said polyamine with the epoxy groups in the epoxy resin will result in curing of the epoxy resin.
Abstract: This invention relates to a composition comprising (1) a phenoxy resin and (2) at least two compositions selected from (a) phenolic resins, (b) melamine resins and (c) polyisocyanates; to the cured products thereof; and to an electrical conductor coated with said cured products.
Type:
Grant
Filed:
December 1, 1983
Date of Patent:
July 2, 1985
Assignees:
The P. D. George Co., Industrie Vernici Italiane S.p.A.
Abstract: Curable mixtures containing (a) epoxide compounds with on average more than one 1,2-epoxide group per molecule, (b) the condensates prepared from certain phenols, certain amines and aldehydes or ketones in an acid medium and, where relevant, (c) curing accelerators. The novel curable mixtures have a good storage stability and give shaped substances with outstanding resistance to chemicals.
Abstract: Disclosed is a solvent-free wire enamel cement coat which is curable to the B-stage with ultraviolet light. The wire can then be formed into a coil and cured with heat to the C-stage. The cement coat composition comprises a mixture of a UV photosensitizer and a curing agent with either an acrylated epoxy or an amine terminated acrylated epoxy or an acrylated urethane, or mixtures thereof, all dissolved in a monoacrylate. The composition can also include an end-blocked urethane, an acrylated hexamethoxymethyl melamine, or a low molecular weight cresol formaldehyde resin.
Abstract: Disclosed is an improved method for coating a substrate with a film of a coating composition rapidly curable at room temperature in the presence of a vaporous tertiary-amine catalyst. The pot life of the coating composition is substantially increased without deleterious loss of properties of the ultimately cured film wherein the coating composition comprises three components. The first component is a phenol-functional condensation product of (a) a phenol-aldehyde reaction product bearing a plurality of methylol and phenol groups, and (b) a polyol, polycarboxylic acid, or polyepoxide, wherein the condensation product is reacted with a selective transmethylolating agent for substantially transforming residual methylol groups into non-active hydrogen groups. The second component is a multi-isocyanate cross-linking agent and the third component is an organic solvent. The coating composition is applied to a substrate and cured by exposure of the coated substrate to a vaporous tertiary amine catalyst.
Abstract: The present invention comprises a low-cost, convenient to use anti-punking binder system for use in bonding entangled masses of mineral fibers such as glass. The binder system comprises a phenolic-formaldehyde resin mixed with a water soluble urea-formaldehyde resin; the urea-formaldehyde resin content in the binder system comprising an amount of about 5 to 50% by weight of the binder solids content. The urea-formaldehyde resin comprises about 59% urea, about 19% formaldehyde and about 22% water by weight. Silane, ammonia and ammonium sulfate may also be added.
Abstract: The present invention relates to a process for the preparation of phenol-formaldehyde foams by mixing a resol phase having a viscosity of between 8 and 60 poises and a novolac phase comprising a true novolac, a blowing agent, phenolsulphonic acid and, optionally, phenol, the relative amounts of resol phase and of novolac phase being such that the resol phase represents 45 to 75% by weight of the mixture.
Abstract: A moulding composition consisting of an epoxy resin adduct of a low molecular diglycidyl ether of bisphenols and an aromatic diamine together with a filler, an accelerator, and an aromatic polyol as hardener. Mouldings having excellent resistance to cracking can be obtained from this moulding composition.
Abstract: A process for producing a furan-epoxy powder-like binder comprising reaction of an epoxy diane resin (100 parts by weight) with a ketone of the furan series (40 to 500 parts by weight) and a modifying agent (60 to 500 parts by weight). As the ketone of the furan series use is made of monofurfurylideneacetone, difurfurylideneacetone, difurfurylidenecyclohexanone, a mixture of monofurfurylidenacetone with difurfurylidenacetone, 1,9-di-(.alpha.-furyl)-nonanetetraene-1,3,6,8-one-5, or 1,5-di-(.alpha.-furyl)-2,4-dimethylpentadiene-1,4-one-3. As the modifying agent use is made of a phenolformaldehyde resin or anhydrides of dibasic carboxylic acids. The reaction is carried out at a temperature within the range of from 130.degree. to 180.degree. C. in the presence, when required, of trifurylborate (10 to 30 parts by weight). The resulting product is cooled to a temperature of at most 30.degree. C. and disintegrated to a powder-like condition.
Type:
Grant
Filed:
August 7, 1978
Date of Patent:
March 11, 1980
Inventors:
Gennady D. Varlamov, Juldash Mamatov, Ildgam A. Bekbulatov, Shavkat Madaliev
Abstract: Cathodic electrocoating binders based on polycondensation products which contain amino groups and which are, at least partially, in the form of their ammonium salts or quaternary ammonium salts.The polycondensation products containing amino groups are obtained by adduct formation of p-hydroxyacetophenone with polymers containing epoxide groups, followed by reaction of these adducts with formaldehyde and a secondary amine.The electrocoating binders of the invention may be used for coating metallic substrates and give coatings which are particularly corrosion-resistant and adhere particularly firmly.