With Solid Polymer Derived From At Least One Nitrogen-containing Reactant Wherein At Least One Of The Reactants Forming The Solid Polymer Is Saturated; Or With Spfi Wherein At Least One Of The Necessary Ingredients Contains A Nitrogen Atom Or With A Reaction Product Thereof; Or With Nitrogen-containing Sicp Patents (Class 525/66)
  • Patent number: 11186712
    Abstract: The present disclosure provides an ultralow-glossiness, ultralow-temperature resistant ASA resin composition and preparation method thereof. The composition includes the following components in parts by weight: 20˜60 parts of an acrylonitrile-styrene-acrylate graft copolymer, 40˜80 parts of an acrylonitrile-styrene copolymer, 1˜20 parts of an ultralow-glossiness, low temperature resistant modifier, and 0.1˜5 parts of a processing aid. The ultralow-glossiness, low temperature resistant modifier includes a carrier copolymer, a fluorinated copolymer, a low-temperature flexibilizer, a coupling agent, fumed silica and an assistant.
    Type: Grant
    Filed: December 30, 2016
    Date of Patent: November 30, 2021
    Assignee: SHANGHAI KUMHOSUNNY PLASTICS CO., LTD.
    Inventors: Tao Meng, Ting Zhou, Minghua Luo, Minqi Xin
  • Patent number: 11180642
    Abstract: A conjugated diene-based copolymer composition is provided. The conjugated diene-based copolymer composition includes a first conjugated diene-based copolymer having 20 wt % to 60 wt % of an aromatic vinyl monomer-derived repeating unit, 35 wt % to 75 wt % of a first conjugated diene-based monomer-derived repeating unit, and 1 wt % to 10 wt % of a hydroxyalkyl (meth)acrylate monomer-derived repeating unit. The first conjugated diene-based copolymer has a Mooney viscosity (MV) at 100° C. of 30 to 120. The conjugated diene-based copolymer composition also includes a second conjugated diene-based copolymer having 20 wt % to 60 wt % of an ?-methylstyrene monomer-derived repeating unit and 40 wt % to 80 wt % of a second conjugated diene-based monomer-derived repeating unit. The second conjugated copolymer has a Mooney viscosity (MV) at 100° C. of more than 120 and equal to or less than 200. A method for preparing the conjugated diene-based copolymer is also provided.
    Type: Grant
    Filed: November 13, 2018
    Date of Patent: November 23, 2021
    Inventors: Se Eun Lee, Byoung Yun Kim, Hyung Woon Yoon, Jae Min Lee, Woo Seok Choi
  • Patent number: 11142641
    Abstract: The invention relates to a composition comprising: (A) an amorphous or quasi-amorphous copolymer containing polyamide blocks and containing polyether blocks, the polyamide blocks comprising cycloaliphatic units; (B) a semicrystalline polymer or copolymer comprising amide units; (C) another polymer or copolymer comprising amide units; and (D) a multilayer polymer comprising at least a layer (D1) and a layer (D2). This composition has advantageous properties of transparency and impact strength, especially for the manufacture of sports articles.
    Type: Grant
    Filed: May 17, 2017
    Date of Patent: October 12, 2021
    Assignee: ARKEMA FRANCE
    Inventors: Frédéric Malet, Mathieu Sabard, Philippe Blondel, Yves Deyrail
  • Patent number: 11034836
    Abstract: Provided is a resin composition which comprises 100 parts by weight of a polyamide resin comprising a structural unit derived from diamine and a structural unit derived from dicarboxylic acid, in which 70 mol % or more of the structural unit derived from diamine is derived from xylylenediamine, and in which 70 mol % or more of the structural unit derived from dicarboxylic acid is derived from a straight-chain aliphatic ?,?-dicarboxylic acid having 4 to 20 carbon atoms; 3 to 17 parts by weight of an acid-modified polyolefin having an acid modification ratio of 0.3 to 5.0% by weight; and 1 to 15 parts by weight of a compound represented by formula (1), wherein R1 represents an alkyl group having 1 to 10 carbon atoms, R2 represents an alkyl group having 2 to 12 carbon atoms, and n represents an integer of 1 to 3.
    Type: Grant
    Filed: November 6, 2017
    Date of Patent: June 15, 2021
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Kazuya Sato, Tomonori Kato, Jin Nakamura
  • Patent number: 11002886
    Abstract: Provided are a polarizer protection film, a polarizing plate comprising the same, and a liquid crystal display device comprising the polarizing plate. The polarizer protection film has: a moisture permeability ranging from approximately 0 g/m2/24 hr to approximately 100 g/m2/24 hr; a value for a MD-direction shrinkage rate/a TD-direction shrinkage rate, ranging from 0.8 to 1.3; an in-plane phase difference (Re) ranging from approximately 0 nm to approximately 350 nm; a thickness-direction phase difference (Rth) ranging from approximately 2500 nm to approximately 8000 nm; and a thickness of approximately 10 ?m to approximately 60 ?m.
    Type: Grant
    Filed: December 23, 2016
    Date of Patent: May 11, 2021
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Ran Kim, So Hee Yu, Seung Kyu Lee
  • Patent number: 10968564
    Abstract: The present disclosure is relates to an artificial leather and a method of manufacturing the same. The manufacturing method of the artificial leather includes steps in which TPU particles are provided. The method continues with step in which the TPU particles are heated to be melted. The method continues with step in which a first TPU mesh layer is formed by meltblowing the melted TPU. The method continues with step in which a second TPU mesh layer is meltblown on the first TPU mesh layer so as to form a multi-layer TPU mesh layer structure. The method continues with step in which the multilayer TPU mesh layer structure is heat pressed to form the artificial leather.
    Type: Grant
    Filed: August 6, 2019
    Date of Patent: April 6, 2021
    Assignee: SAN FANG CHEMICAL INDUSTRY CO., LTD.
    Inventors: Chih-Yi Lin, Kuo-Kuang Cheng, Kao-Lung Yang, Yung-Yu Fu, Wei-Jie Liao
  • Patent number: 10906278
    Abstract: There is provided a multilayered tube for transporting liquid chemicals containing an outermost layer and an innermost layer, the innermost layer containing a polyamide (A), an impact modifier (B), and a carbon nanotube (C), wherein the number of projections each having a height of 5 ?m or more and a longitudinal width of 20 ?m or more, which are present on the surface of the innermost layer, is 2 or less per 1 mm2 of surface area; and the number of agglomerates each having a longitudinal width of 5 ?m or more, which are present in the cross section of the innermost layer, is 15 or less per 1 mm2 of cross-sectional area. There is also provided a polyamide resin composition constituting the innermost layer of the multilayered tube for transporting liquid chemicals.
    Type: Grant
    Filed: December 22, 2015
    Date of Patent: February 2, 2021
    Assignee: KURARAY CO., LTD.
    Inventors: Go Tazaki, Toshiaki Hasegawa
  • Patent number: 10829628
    Abstract: A thermoplastic resin composition of the present invention is characterized by comprising: about 100 parts by weight of a thermoplastic resin containing a rubber-modified vinyl-based graft copolymer and an aromatic vinyl-based copolymer resin; about 10 to about 30 parts by weight of an antistatic agent; and about 0.01 to about 2 parts by weight of zinc oxide, wherein the antistatic agent comprises at least one of a polyether ester amide block copolymer, a polyalkylene glycol, and a polyamide. The thermoplastic resin composition is excellent in antibacterial properties, antistatic properties, impact resistance, and the like.
    Type: Grant
    Filed: December 22, 2017
    Date of Patent: November 10, 2020
    Assignee: Lotte Chemical Corporation
    Inventors: Cheon Seok Yang, Yoen Kyoung Kim, Seung Yong Bae, Ju Sung Kim
  • Patent number: 10780670
    Abstract: The present invention pertains to a carbon fiber reinforced plastic, and provides a carbon fiber reinforced plastic laminated body that is low cost and superior in moldability, mechanical characteristic balance, and impact resistance. The laminated body has three or more layers, and has the following (B) layer between two layers of a fiber reinforced resin sheet, (B) layer: A resin sheet in which the displacement, in an S-S curve waveform obtained by the following high-speed punching test, from a peak value of the test force (kN) to an 85%—attenuation value is not less than 22 mm. High-speed punching test: Impact absorption energy is calculated by using an impact testing machine in compliance with ISO6603-2 standard. A 100 mm×100 mm test piece is cut out from a sheet having a thickness of 2 mm. The diameter of a striker is 12 mm. the diameter of an opening section of a holding tool is 76 mm, and the impact speed is set to 5 m/sec.
    Type: Grant
    Filed: April 1, 2016
    Date of Patent: September 22, 2020
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masahiko Nagasaka, Takeshi Ishikawa, Hayato Ogasawara
  • Patent number: 10661541
    Abstract: A multilayered laminate film containing dispersed pigment which is suitable as a back cover for a solar module is provided. The film comprises, in the order listed: a) a layer of a moulding composition which comprises: at least 35% by weight, of polyamide; and from 1 to 65% by weight of a light-reflecting filler; b) optionally, a layer of a thermoplastic moulding composition; and c) a layer of a moulding composition which comprises at least 35% by weight, of polyamide; and from 1 to 65% by weight of a light-reflecting filler; wherein at least one of layers a) and c) further comprises from 1 to 25% by weight of the layer composition of a polyamide elastomer which is a polyetheresteramide, a polyetheramide or a combination thereof. A solar module containing the multilayered laminate film is also provided.
    Type: Grant
    Filed: October 11, 2012
    Date of Patent: May 26, 2020
    Assignee: Evonik Operations GmbH
    Inventors: Andreas Pawlik, Martin Wielpuetz, Michael Beyer
  • Patent number: 10385154
    Abstract: The present invention relates to a method for preparing a diene-based rubber polymer having relatively low gel content and high swelling index while having high polymerization conversion rate, a diene-based rubber polymer prepared therefrom and an acrylonitrile-butadiene-styrene graft copolymer with a core-shell structure comprising the same as a core. Accordingly, the method for preparing a diene-based rubber polymer and the acrylonitrile-butadiene-styrene graft copolymer with a core-shell structure comprising the diene-based rubber polymer prepared therefrom can be easily applied to the industries requiring them, in particular, an impact reinforcing agent industry.
    Type: Grant
    Filed: December 15, 2015
    Date of Patent: August 20, 2019
    Assignee: LG CHEM, LTD.
    Inventors: Yoo Vin Kim, Young Min Kim, Jin Hyoung Lee, Su Jeong Han, Young Hwan Jeong, Sun Haeng Chung, Jae Min Suk
  • Patent number: 9809706
    Abstract: The present invention relates to a process for the separation of enantiomers or resolution of racemic mixtures using high surface area core-shell polymer beads. The present invention further relates to a core-shell functionalized polymer comprising a core which comprises copolymer made from monomers selected from non-aromatic acrylate, ethylene dimethacrylate and divinyl-benzene, a shell which comprises monomers selected from glycidyl ethers of methacrylate and a chiral selector selected from tartaric acid derivatives and amino acids.
    Type: Grant
    Filed: September 1, 2014
    Date of Patent: November 7, 2017
    Assignee: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH
    Inventors: Sachin Tanaji Mane, Siona Virgil Daniels, Sarika Babasaheb Deokar, Smita Atmaram Mule, Surendra Ponrathnam, Nayaku Nivrati Chavan
  • Patent number: 9765218
    Abstract: The present invention provides a polymer composition having a low water absorption (i.e. being dampproof), excellent electrical insulation, high adhesion to various substrates, and excellent thermal stability. The present invention relates to a polymer composition comprising (A) a dimer acid-based polyamide and (B) an olefin-based-modified polymer, wherein the olefin-based-modified polymer (B) comprises a chemical structure derived from an olefin and a chemical structure derived from an amide.
    Type: Grant
    Filed: November 18, 2014
    Date of Patent: September 19, 2017
    Assignee: Henkel AG & Co. KGaA
    Inventor: Yukio Isobe
  • Patent number: 9752026
    Abstract: A composition including at least two grafted copolymers, having a polyolefin trunk and polyamide grafts, the polyamide grafts being 15% to 25% by weight of the composition. Also, a multilayered structure including a plurality of adjacent layers, at least one of which has the above composition. The first grafted copolymer is a polyolefin backbone containing a residue of at least one unsaturated monomer (X) and a plurality of polyamide grafts, the polyamide grafts are attached to the polyolefin backbone by the residue of the unsaturated monomer (X). The second copolymer is a grafted elastomeric copolymer of a polyolefin backbone.
    Type: Grant
    Filed: March 17, 2014
    Date of Patent: September 5, 2017
    Assignee: ARKEMA FRANCE
    Inventors: Mathieu Sabard, Stephane Bizet, Jean-Jacques Flat
  • Patent number: 9708438
    Abstract: Compositions for forming molded articles, particularly, shells for automotive applications are made up of melt blends of aliphatic thermoplastic urethane elastomer and an olefin-containing block copolymer crosslinked to a gel content of from 5 to 95%. These compositions may be blended to form a powder, pellets, microspheres or minibeads which may then be cast to form air bag door and instrument panel cover skins which may meet automotive deployment and weathering requirements.
    Type: Grant
    Filed: August 8, 2008
    Date of Patent: July 18, 2017
    Assignee: Covestro LLC
    Inventors: William M. Humphrey, Paul Drago, Jeffrey S. Armour, Jim E. Ingram, James R. Charron
  • Patent number: 9546271
    Abstract: A thermoplastic molding compound that has proved to be extremely weather-resistant and low-emission containing the following components: A) 3-77% by weight of one or more styrene copolymers, component A; B) 15-89% by weight of one or more polyamides, component B; C) 5-50% by weight of two or more graft rubbers without olefinic double bonds in the rubber phase, component C; D) 1-25% by weight of a terpolymer of styrene, acrylonitrile and maleic anhydride, component D; E) 2-30% by weight of rubber based on olefinic monomers, component E; F) 0-50% by weight of fibrous or particulate filler or mixtures thereof, component F; G) 0-40% by weight of further additives, component G.
    Type: Grant
    Filed: December 28, 2012
    Date of Patent: January 17, 2017
    Assignee: STYROLUTION EUROPE GMBH
    Inventors: Martin Weber, Marko Blinzler
  • Patent number: 9447276
    Abstract: Residual lactam monomer is reduced from compounds containing polyamide by adding a minor amount of polycarbodiimide during melt-mixing.
    Type: Grant
    Filed: August 21, 2013
    Date of Patent: September 20, 2016
    Assignee: PolyOne Corporation
    Inventors: Maziyar Bolourchi, Roger W. Avakian
  • Patent number: 9371443
    Abstract: A continuous process for the production of a dynamically vulcanized thermoplastic elastomer comprising a thermoplastic resin and a non-halogenated elastomer with a multiolefin content of greater than 3.5 mol % that has been modified in situ with a carboxylic anhydride. The process provides materials with improved elongation at break and ultimate tensile strength that can be produced economically and with reduced environmental impact.
    Type: Grant
    Filed: September 28, 2012
    Date of Patent: June 21, 2016
    Assignee: ARLANXEO Singapore Pte. Ltd.
    Inventors: Conrad Siegers, Ralf-Ingo Schenkel, Rayner Krista
  • Patent number: 9315625
    Abstract: The invention relates to a polyamide comprising units derived from: A. a diamine comprising in its structure at least one cyclohexane fragment according to Structure I, in which the substituents are in the 1,4-trans-position (Structure I), with n a positive integer of at least 1, and the proviso that when n is 2 or higher the cyclohexane rings are connected to each other through the 1,4-trans position, B. an aliphatic dicarboxylic acid with at least 13 carbon atoms and optionally comprising units derived from: C. one or more aliphatic dicarboxylic acids other than B, D. one or more diamines other than A, E. one or more monofunctional carboxylic acids or monofunctional amines, F. one or more polyfunctional monomers comprising carboxylic acid and/or amine groups, G. one or more lactams or corresponding amino acids. The invention further relates to a composition comprising such a polyamide and its uses.
    Type: Grant
    Filed: May 24, 2013
    Date of Patent: April 19, 2016
    Assignee: DSM IP ASSETS B.V.
    Inventors: Rudy Rulkens, Atze Jan Nijenhuis
  • Patent number: 9303157
    Abstract: This invention relates to a mixture of a polydiorganosiloxane polyamide-containing material and an organic polymer.
    Type: Grant
    Filed: June 4, 2015
    Date of Patent: April 5, 2016
    Assignee: 3M Innovative Properties Company
    Inventors: Audrey A. Sherman, David S. Hays, Stephen A. Johnson, Timothy J. Hebrink, Jeffrey O. Emslander, Danny L. Fleming
  • Patent number: 9206316
    Abstract: Disclosed is a thermoplastic elastomer composition comprising (i) about 10-60 wt % of at least one aliphatic polyamide; (ii) about 0.8-15 wt % of at least one graft-modified ethylene-olefin elastomeric copolymer; (iii) about 0.8-15 wt % of at least one graft-modified ethylene-propylene elastomeric copolymer, and (iv) about 35-85 wt % of at least one polyether-ester-amide block copolymer having a shore D of about 50-60 (as measured in accordance with ASTM D2240), with the total wt % of all components in the composition totaling to 100 wt %. Further disclosed herein is an article made from the thermoplastic elastomer composition disclosed above.
    Type: Grant
    Filed: December 21, 2012
    Date of Patent: December 8, 2015
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: David D Zhang, Zhongyu Wang
  • Patent number: 9123892
    Abstract: The present invention relates to a polymer blend composition comprising a dielectric elastomer, an actuator film manufactured using the same, and an actuator comprising the film. The polymer blend composition according to the present invention comprises a block copolymer having excellent compatibility with the dielectric elastomer and excellent dielectric properties, and thus displacement values suitable for the purpose can be obtained by a simple method of adjusting a composition of the polymer blend. Moreover, the film manufactured using the same has high dielectric constant, low dielectric loss and high electromechanical displacement, and thus the film exhibits excellent dielectric properties when it is applied in a dielectric layer for an actuator.
    Type: Grant
    Filed: May 8, 2012
    Date of Patent: September 1, 2015
    Assignee: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Chong-Min Koo, Soon-Man Hong, Kyung-Youl Baek, Seung-Sang Hwang, Youn-Duk Park, Kyung-Ho Min, Jin-Hong Lee, Yun-Jae Lee, Ji-Young Jung, Jang-Woo Lee
  • Patent number: 9050505
    Abstract: Improved synthetic lacrosse stick heads that have more consistent performance characteristics under variable temperature and playing conditions.
    Type: Grant
    Filed: May 29, 2012
    Date of Patent: June 9, 2015
    Inventors: Jonathan Bond, Christopher Morea
  • Publication number: 20150148488
    Abstract: The present invention provides for a thermoplastic composition that includes from about 40 to about 95 wt. % of a polyamide, and from about 5 to about 30 wt. % of at least one functionalized, selectively hydrogenated block copolymer, including at least one polymer block A, the A block being at least predominantly a polymerized alkenyl arene block, and at least one selectively hydrogenated polymer block B, the B block prior to hydrogenation being at least predominantly a polymerized conjugated diene block to which grafted thereto on the average an effective amount of monomer acids or their derivatives, including maleic acid, succinic acid, itaconic acid, fumaric acid, and acrylic acid. The composition optionally includes from about 5 to about 50 wt. % of a selectively hydrogenated block copolymer.
    Type: Application
    Filed: November 25, 2013
    Publication date: May 28, 2015
    Applicant: KRATON POLYMERS U.S. LLC
    Inventors: Marcus GREGER, Hendrik DE GROOT
  • Patent number: 9012026
    Abstract: The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.
    Type: Grant
    Filed: April 1, 2014
    Date of Patent: April 21, 2015
    Assignee: Arkema France
    Inventors: Thierry Briffaud, Philippe Blondel
  • Publication number: 20150104598
    Abstract: A thermoplastic composition comprising from about 50 to about 99 by weight percent of a nylon 6,6 resin, from about 1 to about 50 by weight percent of a polymer performance modifier and about from 0.01 to about 25 by weight percent of a silicone based additive, wherein the silicone based additive comprises an ultrahigh molecular weight siloxane polymer that is unfunctionalized and non-reactive with the polyamide resin, wherein the thermoplastic composition has an impact strength value which is greater than the combination of the polyamide resin and the polymer performance modifier or the combination of the polyamide resin and the silicone based additive and wherein the thermoplastic composition has an ultimate tensile strength that is at least 80% that of the combination of the polyamide resin and the polymer performance modifier.
    Type: Application
    Filed: December 19, 2014
    Publication date: April 16, 2015
    Applicant: INVISTA North America S.a.r.l.
    Inventor: Rajeev S. BHATIA
  • Patent number: 8993677
    Abstract: Provided is a polyamide resin composition comprising an elastomer etc, and a reactive polyamide resin excellent in reactivity. The polyamide resin composition comprises 0.5 to 100 parts by mass of an elastomer per 100 parts by mass of a reactive polyamide resin, wherein the reactive polyamide resin obtained by polycondensing a diamine (A) containing 70 mol % or more of a diamine structural unit derived from xylylenediamine and a dicarboxylic acid (B) containing 50 mol % or more of a dicarboxylic acid structural unit derived from sebacic acid, and has a concentration of reactive functional groups of 100 ?eq/g or more and a molar ratio of reacted diamine to reacted dicarboxylic acid (the number of moles of reacted diamine/the number of moles of reacted dicarboxylic acid) of 1.0 or more.
    Type: Grant
    Filed: May 18, 2012
    Date of Patent: March 31, 2015
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Jun Mitadera, Shinichi Ayuba, Nobuhiko Matsumoto, Kosuke Otsuka
  • Publication number: 20150087784
    Abstract: A thermoplastic moulding compound that has proved to be extremely weather-resistant and low-emission containing the following components: A) 3-77% by weight of one or more styrene copolymers, component A; B) 15-89% by weight of one or more polyamides, component B; C) 5-50% by weight of two or more graft rubbers without olefinic double bonds in the rubber phase, component C; D) 1-25% by weight of a terpolymer of styrene, acrylonitrile and maleic anhydride, component D; E) 2-30% by weight of rubber based on olefinic monomers, component E; F) 0-50% by weight of fibrous or particulate filler or mixtures thereof, component F; G) 0-40% by weight of further additives, component G.
    Type: Application
    Filed: December 28, 2012
    Publication date: March 26, 2015
    Inventors: Martin Weber, Marko Blinzler
  • Patent number: 8945694
    Abstract: Filled phase-separated blends of polyaryl ether ketones, polyaryl ketones, polyether ketones, polyether ether ketones and mixtures thereof with at least one polysulfone etherimide, wherein the polysulfone etherimide has greater than or equal to 50 mole % of the polymer linkages contain at least one aryl sulfone group are described. Such filled blends have improved load-bearing capability at high temperature. In another aspect the filled blends have a higher crystallization temperature, especially at fast cooling rates.
    Type: Grant
    Filed: March 19, 2007
    Date of Patent: February 3, 2015
    Assignee: Sabic Global Technologies B.V.
    Inventors: Ashish Aneja, Robert Russell Gallucci, Roy Ray Odle, Kapil Chandrakant Sheth
  • Publication number: 20150017451
    Abstract: There is described a polymer blend of a first and second polymer comprising: a) a first polymer of: vinyl (co)polymer; alkyd; urethane acrylic copolymer; polyurethane and/or polyester; b) a second copolymer from: b1) optionally at least 10 wt-% of one or derivatives of itaconic acid and/or isomers thereof; b2) up to 20 wt-% of one or more acid functional (or potentially acid functional) monomer(s) and b3) vinyl monomer(s) where wt % of each monomer (b1 to b3) is based on total (b) and where at least one of the first and second polymer is obtained from an itacon-functional monomer such as itaconic acid and/or its derivatives.
    Type: Application
    Filed: February 4, 2013
    Publication date: January 15, 2015
    Inventors: Tijs Nabuurs, Jeffrey Stubbs, Matthew Stewart Gebhard, Gerardus Cornelis Overbeek
  • Patent number: 8927651
    Abstract: A high-viscosity polyamide composition including a branched polyamide is described. Also described, is a relationship between a high-viscosity polyamide composition and a composition including a copolyamide of a statistical tree type resulting from a reaction between a multifunctional monomer including at least three reactive functions in order to form an amide function. Further described, are three reactive functions of two different types and bifunctional monomers used in the manufacture of linear polyamides. A resulting copolyamide can have a very low melt flow index relative to the linear polyamide and improved impact resistance properties. Lastly, use of such a composition for extrusion blow-molding articles is described.
    Type: Grant
    Filed: April 4, 2011
    Date of Patent: January 6, 2015
    Assignee: Rhodia Operations
    Inventors: Magali Davezac, Wojciech Bzducha
  • Patent number: 8921483
    Abstract: In order to improve fatigue durability of a thermoplastic elastomer composition composed of a matrix phase of a thermoplastic resin and dispersed phases of a rubber, the thermoplastic elastomer composition comprises (A) 100 parts by weight of a halogenated poly(isoolefin-co-p-alkylstyrene) rubber, (B) 40 to 120 parts by weight of a polyamide resin, and (C) 0.5 to 10 parts by weight of an amine having at least one hydroxyl group. The amine (C) having at least one hydroxyl group is preferably a compound represented by formula (1): where R1 is a C1-30 alkyl; R2 is —(C2H4O)n—H, where n is an integer of 1 to 30; and R3 is —(C2H4O)m—H, where m is an integer of 1 to 30, a C1-30 alkyl, or hydrogen.
    Type: Grant
    Filed: April 21, 2011
    Date of Patent: December 30, 2014
    Assignees: The Yokohama Rubber Co., Ltd., ExxonMobil Chemical Patents Inc.
    Inventor: Shusaku Tomoi
  • Patent number: 8889767
    Abstract: The thermoplastic molding composition comprises a) as component A, from 3 to 78% by weight of one or more styrene copolymers which have no units derived from maleic anhydride, b) as component B, from 15 to 90% by weight of one or more polyamides, c) as component C, from 5 to 50% by weight of one or more impact-modifying graft rubbers without olefinic double bonds in the rubber phase, d) as component D, from 1 to 25% by weight of one or more styrene copolymers which have, based on the entire component D, from 0.5 to 5% by weight of units derived from maleic anhydride, e) as component E, from 1 to 30% by weight of one or more further rubbers based on olefinic monomers without core-shell structure, and having at least 0.1% by weight of functional monomers, f) as component F, from 0 to 50% by weight of one or more fibrous or particulate fillers, g) as component G, from 0 to 40% by weight of further additives, where the entire amount of components A to E and, if appropriate, F and G is 100% by weight.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: November 18, 2014
    Assignee: Styrolution GmbH
    Inventors: Martin Weber, Marko Blinzler, Christian Schweiger, Christoph Schneidereit
  • Patent number: 8871865
    Abstract: Disclosed is a thermoplastic composition comprising a polycarbonate terpolymer comprising structures derived from structures (I), (II) and (III), wherein (I) is a dihydroxy compound having the structure (A): wherein n is 0 to 4 and Rf is independently a halogen atom, a C1-10 hydrocarbon group, or a C1-10 halogen substituted hydrocarbon group; (II) comprises a second dihydroxy compound derived from Formula (A) and different from (I) and wherein n and Rf are as previously defined; and (III) a third dihydroxy compound not derived from Formula (A), wherein the sum of the mol percent of all of structures (I) and (II) is greater than 45% relative to the sum of the molar amounts of all of structures (I), (II) and (III) in the polycarbonate terpolymer and wherein said polycarbonate terpolymer is amorphous; an impact modifier; an ungrafted rigid copolymer; and a flame retardant. The thermoplastic composition has improved chemical resistance and flame retardance.
    Type: Grant
    Filed: June 12, 2007
    Date of Patent: October 28, 2014
    Assignee: Sabic Global Technologies B.V.
    Inventors: Bernardus Johannes Paulus Jansen, Christiaan Henricus Johannes Koevoets, Edward Kung, Wilhelmus Johannes Daniel Steendam
  • Patent number: 8858839
    Abstract: A thermoplastic composition comprises: a compatibilized blend of a poly(arylene ether), an aliphatic-aromatic polyamide and a polymeric compatibilizer; and an impact modifier; wherein the aliphatic-aromatic polyamide is composed of units derived from a dicarboxylic acid and units derived from a diamine and the units derived from a dicarboxylic acid comprise 60 to 100 mol % of units derived from terephthalic acid and the units derived from a diamine comprise 60 to 100 mol % of units derived from 1,9-nonanediamine, 2-methyl-1,8-octanediamine, or a combination of 1,9-nonanediamine and 2-methyl-1,8-octanediamine.
    Type: Grant
    Filed: October 28, 2013
    Date of Patent: October 14, 2014
    Assignee: SABIC Global Technologies B.V.
    Inventors: Shabarinath Kutti Gounder, Roshan Kumar Jha, Mark D. Elkovitch
  • Patent number: 8852747
    Abstract: The invention relates to coextrusion binders including renewable and/or biodegradable polymers having good adhesion properties: at least one renewable and/or biodegradable polymer (A) grafted with a functional monomer including at least one reactive function, the grafting ratio being <1% in weight of the grafted polymer (A); at least one non-grafted renewable and/or biodegradable polymer (B) identical to (A) or compatible with (A) optionally a softener (C); and optionally a starch-based material (D). The invention also relates to multilayered structures including the binder of the present invention, in which the layers are preferably made of renewable and/or biodegradable compounds. The multilayered structures are advantageously useful in the field of food packaging.
    Type: Grant
    Filed: May 14, 2008
    Date of Patent: October 7, 2014
    Assignee: Arkema France
    Inventors: Fabrice Chopinez, Johann Laffargue, Jeau-Laurent Pradel, Damien Rauline, Samuel Devisme
  • Publication number: 20140238939
    Abstract: The present invention discloses antimicrobial water treatment membranes, comprising a water treatment membrane, covalently attached to one or more antimicrobial polymers or derivatives thereof, either directly or via one or more tether molecules. There are also provided a process for preparing these antimicrobial membranes, and uses thereof in water treatment applications.
    Type: Application
    Filed: June 14, 2012
    Publication date: August 28, 2014
    Applicants: WISCONSIN ALUMNI RESEARCH FOUNDATION, BENIGURION UNIVERSITY OF THE NEGEV RESEARCH AND DEVELOPMENT AUTHORITY
    Inventors: Ron Kasher, Shani Avneri, Marina Yamit Lutsky, Jihua Zhang, Samuel Helmer Gellman, Shannon Stahl
  • Patent number: 8816008
    Abstract: The invention relates to an impact modified thermoplastic resin comprising a polymeric impact modifier with a core-shell structure comprising 2-octylacrylate.
    Type: Grant
    Filed: September 20, 2011
    Date of Patent: August 26, 2014
    Assignee: Arkema France
    Inventors: Rosangela Pirri, Stephane Girois, Pascale Dargelos, Magali Bergeret-Richaud
  • Patent number: 8816004
    Abstract: Oxazolinyl-containing compounds having a single oxazolinyl group plus a first polymeric group are described. Grafted compounds are also described that are the product of a reaction of an oxazolinyl-containing compound with a second compound that has one or more acidic groups to form a grafted compound. In some embodiments, the second compound is a polymeric material having at least one acidic group and the reaction product is a grafted copolymer. Blended compositions of the grafted copolymer with a polyamide are also described.
    Type: Grant
    Filed: December 7, 2011
    Date of Patent: August 26, 2014
    Assignee: 3M Innovative Properties Company
    Inventors: Jason D. Clapper, Kevin M. Lewandowski
  • Patent number: 8808862
    Abstract: A resin composition includes (A) 100 parts by weight of epoxy resin; (B) 20 to 100 parts by weight of polybutadiene styrene divinylbenzene graft terpolymer resin; (C) 2 to 20 parts by weight of di-tert-butylhydroquinone (DTBHQ); (D) 5 to 50 parts by weight of polyphenyl ether modified cyanate ester resin; and at least one of (E) inorganic filler, (F) chain extending sealing agent, and (G) catalyst. The resin composition is characterized by specific ingredients and proportions thereof to attain high heat resistance, low dielectric constant Dk, and low dielectric dissipation factor Df, and being halogen-free, and therefore is applicable to protective film of printed circuit boards, insulating protective film of electronic components, and resin insulation film of leadframes.
    Type: Grant
    Filed: December 28, 2012
    Date of Patent: August 19, 2014
    Assignee: Elite Material Co., Ltd.
    Inventors: Chen-Yu Hsieh, Yi-Fei Yu
  • Patent number: 8809455
    Abstract: A dynamically vulcanized alloy contains at least one isobutylene-containing elastomer and at least one thermoplastic resin, wherein the elastomer is present as a dispersed phase of small vulcanized or partially vulcanized particles in a continuous phase of the thermoplastic resin. The dynamically vulcanized alloy also contains an anhydride functionalized oligomer. The alloy maintains a high Shore A hardness value while obtaining improved flowability for processing.
    Type: Grant
    Filed: August 27, 2009
    Date of Patent: August 19, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Maria D. Ellul, Anthony Jay Dias, Rodney May
  • Patent number: 8809428
    Abstract: The present disclosure relates to golf balls having components including intermediate layers and outer cover layers prepared from blends of polyamides mixed with one or more functional polymer modifiers. The functional polymer modifier incorporates a copolymer or a terpolymer having a glycidyl group, hydroxyl group, maleic anhydride group or carboxylic group, or a mixture of these. When used in golf ball covers or mantles, these materials exhibit improved impact durability when compared to analogous balls but having ionomeric- or polyurethane-based layers of similar hardness.
    Type: Grant
    Filed: December 22, 2009
    Date of Patent: August 19, 2014
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Publication number: 20140170356
    Abstract: The present invention discloses a single layer rotomoulded article prepared from a blend of polyethylene, functionalised polyolefin and one or more resins selected from polyetherester or saturated polyester or polycarbonate or polyamide.
    Type: Application
    Filed: February 24, 2014
    Publication date: June 19, 2014
    Applicant: TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventor: Eric Maziers
  • Patent number: 8748004
    Abstract: The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.
    Type: Grant
    Filed: August 6, 2009
    Date of Patent: June 10, 2014
    Assignee: Arkema France
    Inventors: Thierry Briffaud, Philippe Blondel
  • Patent number: 8742014
    Abstract: An object of the invention is to provide a liquid resin composition with low viscosity while containing polymer particles. Further, another object of the invention is to provide a liquid resin composition containing a large quantity of polymer particles without increasing the viscosity of the liquid resin composition. A liquid resin composition of the invention is comprising a liquid resin component and polymer particles each having an elastic core layer, an intermediate layer formed with a monomer having two or more double bonds and coated on the core layer, and a shell layer coated on the intermediate layer; wherein the polymer particles are dispersed at a ratio of their volume average particle diameter (Mv) to their number average particle diameter (Mn) of 3 or lower.
    Type: Grant
    Filed: September 9, 2008
    Date of Patent: June 3, 2014
    Assignee: Kaneka Corporation
    Inventor: Shinya Hongo
  • Publication number: 20140135427
    Abstract: A process for the production of a solid dispersant for a hydraulically binding composition includes the steps of: providing at least one first polymer, which is a comb polymer having a polymer backbone comprising carboxyl groups; providing at least one second polymer, which is a condensate of, at least, an aromatic compound and formaldehyde; or a lignosulfonate; preparing an aqueous solution comprising the first and the second polymer; and spray-drying the aqueous solution to obtain the solid dispersant.
    Type: Application
    Filed: July 31, 2012
    Publication date: May 15, 2014
    Applicant: SIKA TECHNOLOGY AG
    Inventors: Pedro Gallegos, Lili Arancibia, Hugo Olivares, Ernesto Croquevielle, Thomas Haack
  • Patent number: 8703293
    Abstract: Provided herein re a composition and a coating or a device (e.g., absorbable stent) that includes a PEGylated hyaluronic acid and a PEGylated non-hyaluronic acid biocompatible polymer and the methods of use thereof.
    Type: Grant
    Filed: April 1, 2010
    Date of Patent: April 22, 2014
    Assignee: Advanced Cardiovascular Systems, Inc.
    Inventors: Lothar W. Kleiner, Connie S. Kwok
  • Patent number: 8691913
    Abstract: A polylactic acid composition is provided having a polymer matrix and a compatibilizer. The polymer matrix includes polylactic acids and acrylonitrile-butadiene-styrene[s]. The compatibilizer is at least one compound selected from the group consisting of: a poly (styrene-ethylene-butadiene-styrene) copolymer grafted with maleic anhydrides, an acrylonitrile-butadiene-styrene copolymer grafted with maleic anhydrides, a polystyrene grafted with maleic anhydrides, and an ethylene-ethyl acrylate-glycidyl methacrylate.
    Type: Grant
    Filed: March 28, 2012
    Date of Patent: April 8, 2014
    Assignee: BYD Company Limited
    Inventors: Xueyuan Zhu, Jianghong Dou, Xiaobin He, Jianghui Li
  • Patent number: 8686082
    Abstract: A nylon 11 composite has significantly improved flexural modulus while keeping or even increasing the impact strength. This composite system may comprise a nylon 11/filler/modifier. The “ball” portion of badminton shuttlecocks made by this type of composite more closely emulate the flight capabilities of natural feather shuttlecocks than neat nylon 11.
    Type: Grant
    Filed: August 25, 2011
    Date of Patent: April 1, 2014
    Assignee: Applied Nanotech Holdings, Inc.
    Inventors: Xueping Li, Dongsheng Mao, Zvi Yaniv
  • Publication number: 20140088253
    Abstract: The present invention generally relates to polyamide compositions having improved anti-delamination. More specifically, the present invention relates to novel polyamide compositions demonstrating improved anti-delamination, which have at least one low purity polyamide.
    Type: Application
    Filed: March 15, 2013
    Publication date: March 27, 2014
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventor: Avelino F. Lima