With Solid Polymer Derived From At Least One Hal-c(=o)-hal, O-c(=o)-o Or Hal-c(=o)-o- Reactant Wherein At Least One Of The Reactants Forming The Solid Polymer Is Saturated; Or With Spfi Wherein At Least One Of The Necessary Ingredients Is A Hal-c(=o)-hal, O-c(=o)-o, Or Hal-c(=o)-o Containing Reactant Or Reaction Product Thereof; Or With A Sicp Containing A Hal-c(=o)- Or O-c(=o)-o- Group Patents (Class 525/67)
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Publication number: 20140187688Abstract: A (meth)acrylic copolymer is a copolymer of a monomer mixture including a phosphorus-based (meth)acrylic monomer represented by Formula 1, and a monofunctional unsaturated monomer. The (meth)acrylic copolymer can have improved refractive index, excellent flame resistance, transparency, scratch resistance and/or environment-friendliness: wherein R1 is hydrogen or methyl, R2 is a substituted or unsubstituted C1-C20 hydrocarbon group, R3 and R4 are the same or different and are each independently a substituted or unsubstituted C6-C20 cyclic hydrocarbon group, m is an integer from 1 to 10, and n is an integer from 0 to 5.Type: ApplicationFiled: June 27, 2013Publication date: July 3, 2014Inventors: Joo Hyun JANG, Kee Hae KWON, Bo Eun KIM, Yong Hee KANG, Ja Kwan GOO, Man Suk KIM, Il Jin KIM, Kwang Soo PARK, Natarajan Senthilkumar, Jo Won LEE
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Publication number: 20140187717Abstract: A thermoplastic resin composition comprises (A) about 30 to about 98 wt % of a polycarbonate resin, (B) about 1 to about 50 wt % of a rubber modified acrylic-based graft copolymer, and (C) about 1 to about 69 wt % of a branched copolymer including silicon-based compound. A molded article can be made using the same.Type: ApplicationFiled: December 5, 2013Publication date: July 3, 2014Applicant: Cheil Industries Inc.Inventors: Kee-Hae KWON, In-Chol KIM, Bo-Eun KIM, Joo-Hyun JANG, Chang-Min HONG
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Publication number: 20140187718Abstract: Disclosed is a resin composition including (A) a polycarbonate resin and (B) a rubber modified vinyl-based graft copolymer, and (C) about 1 to about 9 parts by weight of a random copolymer of a compound represented by the following Chemical Formula 1, an aromatic vinyl monomer, and a vinyl cyanide monomer, based on about 100 parts by weight of the polycarbonate resin (A) and the rubber-modified vinyl-based graft copolymer (B): wherein, in the above chemical formula, m is an integer ranging from 0 to 10, and X is phenyl, methylphenyl, methylethylphenyl, methoxyphenyl, cyclohexylphenyl, chlorophenyl, bromophenyl, phenylphenyl group, or benzylphenyl.Type: ApplicationFiled: December 27, 2013Publication date: July 3, 2014Applicant: Cheil Industries Inc.Inventors: Jung-Eun PARK, Kee-Hae KWON, Jin-Young HUH, Chang-Min HONG
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Patent number: 8765240Abstract: The invention relates to a molding compound including a polyester resin composition, ABS components, waxes, matting agents and optionally vegetable oil, which is used to produce films with a low luster, improved thermal resistance of the film and/or of the surface structure and an increased shrinking onset temperature, in addition to a modified shrinkage progression in comparison to films without the aforementioned additives. The fraction of the polyester resin composition is between 30 and 97 wt. % and the fraction of the additives between 1.5 and 70 wt. %, in relation to the total weight of the molding compound. The films are used as shrink-wrapping and packaging films and films for furniture and printed circuit boards.Type: GrantFiled: March 28, 2006Date of Patent: July 1, 2014Assignee: Kloeckner Pentaplast GmbH & Co. KGInventors: Thorsten Grigo, Max Niegl, Guenter Deiringer
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Publication number: 20140147660Abstract: Provided is a thermoplastic resin composition having excellent weather resistance, impact resistance, and fluidity and also excellent color developing properties and residence heat stability. A graft copolymer (A) prepared by graft polymerization of a certain amount of a specific monomer (a2) onto a certain amount of composite rubber (a1) composed of a conjugated diene rubber polymer and a cross-linked acrylic ester polymer. The tetrahydrofuran-soluble portion of the composite rubber (a1) has a weight-average molecular weight of 50000 or more in terms of polystyrene and a degree of swelling in toluene of 7.0 or more, or in the composite rubber contained in the graft copolymer, the number of particles having an equivalent-circle diameter of 150 nm or less is 50% or less of the total number of the composite rubber particles.Type: ApplicationFiled: July 11, 2012Publication date: May 29, 2014Applicant: NIPPON A&L INC.Inventors: Takumi Miyahiro, Masanori Ito, Seiji Tamai, Fumitoshi Takeda, Kazunori Takahashi, Tomoyoshi Akiyama, Hajime Tomita, Haruki Okuno, Shunsaku Kubota, Masaaki Okada, Atsushi Hashimoto, Yoshiaki Takada, Nobuyuki Nakashima, Jiichiro Yoshida, Takayoshi Fujiwara, Shouta Kosaka
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Patent number: 8735456Abstract: A process for producing a thermoplastic resin composition includes kneading a mixture obtained by combining a rubber component with a ground product, the ground product being formed by grinding a thermoplastic resin molded article having an alloy resin of a polycarbonate and an ABS, and then molding the mixture after kneading. The mixture has 0.5 wt % or more and 1.5 wt % or less of the rubber component based on 100 wt % of the mixture.Type: GrantFiled: November 7, 2008Date of Patent: May 27, 2014Assignee: Canon Kabushiki KaishaInventors: Kenichiro Iuchi, Daishi Saiki, Isao Hagiwara, Shunichiro Nishida, Tomomi Tsutsumi
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Patent number: 8735459Abstract: Provided are a composition for preparing expandable polypropylene carbonate and an expandable polypropylene carbonate prepared therefrom, and more particularly, to a composition for preparing expandable polypropylene carbonate capable of using supercritical carbon dioxide as a foaming agent and producing a foam having excellent moldability by using an appropriate foaming method. By using the composition according to the present invention, highly magnificated expandable polypropylene carbonate capable of having excellent thermal stability and dimensional stability can be prepared.Type: GrantFiled: October 10, 2011Date of Patent: May 27, 2014Assignee: SK Innovations Co., Ltd.Inventors: Minho Jeon, Younghyo Park, Kwangjin Chung, Myungahn Ok
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Patent number: 8703869Abstract: The invention relates to impact-modified polycarbonate compositions which are distinguished by high heat resistance and good melt flow behavior. In addition, the moldings produced from the compositions according to the invention in an injection-molding process can be metallised, the resulting metallised moldings having a surface with a particularly high and, in particular, homogeneous gloss. The invention thus also provides the metallised moldings produced from the compositions according to the invention.Type: GrantFiled: March 23, 2010Date of Patent: April 22, 2014Assignee: Bayer Materialscience AGInventors: Andreas Seidel, Eckhard Wenz, Hans-Jü{umlaut over ( )}rgen Klankers
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Publication number: 20140107276Abstract: Disclosed are an ASA graft copolymer having a structure including a seed which comprises at least one compound of an aromatic vinyl compound, a vinyl cyan compound and an alkyl (meth)acrylate compound, a core which surrounds the seed and comprises alkyl acrylate, and a shell which surrounds the core, comprises an aromatic vinyl compound, a vinyl cyan compound and a crosslinking agent, and having suitably controlled thicknesses and refractive indexes of the respective layers, and an ASA graft copolymer composition comprising the ASA graft copolymer.Type: ApplicationFiled: February 1, 2013Publication date: April 17, 2014Inventors: Min Jung Kim, Yong Yeon Hwang, Chun Ho Park, Hye Kyung Han, Sang Mi Lee
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Patent number: 8680201Abstract: The present invention relates to a compounding method for producing impact-modified thermoplastic compositions with a low content of volatile organic compounds (hereinafter VOCs), wherein relatively inexpensive polymer raw materials with a comparatively elevated initial VOC content may be used, resulting in lowered production costs for producing such VOC-reduced polymer compositions.Type: GrantFiled: February 18, 2010Date of Patent: March 25, 2014Assignee: Bayer Materialscience AGInventors: Andreas Seidel, Hans-Jürgen Thiem
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Patent number: 8674007Abstract: A flame retardant thermoplastic composition comprising in combination a polycarbonate homopolymer or copolymer comprising repeat carbonate units having the following structure: wherein R1 and R2 are independently at each occurrence a C1-C4 alkyl, n and p are each an integer having a value of 1 to 4, and T is selected from the group consisting of C5-C10 cycloalkanes attached to the aryl groups at one or two carbons, C1-C5 alkyl groups, C6-C13 aryl groups, and C7-C12 aryl alkyl groups; an impact modifier, wherein the impact modifier comprises wherein the impact modifier comprises a rubber modified thermoplastic resin comprising a discontinuous elastomeric phase dispersed in a rigid thermoplastic phase, and wherein the impact modifier has a specific mean particle size and Q value; and a flame retardant.Type: GrantFiled: July 12, 2006Date of Patent: March 18, 2014Assignee: Sabic Innovative Plastics IP B.V.Inventors: Srinivas Siripurapu, Naveen Agarwal, Jan Pleun Lens
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Patent number: 8653188Abstract: The object of the present invention is to provide a thermoplastic polymer composition which is excellent in the impact resistance, a fracture morphology and rigidity, as well as has a possibility of the effect for reducing environmental load. The thermoplastic resin composition comprises 15 to 85% by mass of aliphatic polyester-based resin (A) comprising the following (AI) and (AII) components, and 15 to 85% by mass of styrene-based resin (B) which is at least one selected from the group consisting of the following (BI) to (BIII). The above (AI) is an aliphatic polyester-based resin having units formed from an aliphatic diol and/or an alicyclic diol and an aliphatic dicarboxylic acid (including derivatives thereof) and/or an alicyclic dicarboxylic (including derivatives thereof) as repeating units, and the above (AII) is a polylactic acid-based aliphatic polyester resin having not less than 70 mol % of lactic acid unit content.Type: GrantFiled: May 8, 2008Date of Patent: February 18, 2014Assignee: Techno Polymer Co., Ltd.Inventors: Tatsuya Toneri, Masaaki Mawatari
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Patent number: 8642700Abstract: A thermoplastic composition suitable for making articles having low gloss and good impact resistance at low temperatures is disclosed. The composition contains (A) 10 to 90 percent relative to the weight of the composition (pbw) of an aromatic (co)poly(ester)carbonate, (B) 10 to 90 pbw of first graft (co)polymer containing a graft base selected from the group consisting of polyurethane, ethylene vinyl acetate, silicone, ethylene-propylene diene rubbers, ethylene propylene rubbers, acrylate rubbers, diene rubbers, and polychloroprene, and a grafted phase, (C) 1 to 20 pbw of a linear glycidyl ester functional polymer comprising repeating units derived from one or more glycidyl ester monomers and (D) 1 to 20 pbw of a second graft (co)polymer containing a core and shell wherein the core contains an interpenetrated network of poly(meth)alkyl acrylate and polyorganosiloxane, and wherein the shell contains poly(meth)acrylate.Type: GrantFiled: November 3, 2006Date of Patent: February 4, 2014Assignee: Bayer MaterialScience LLCInventors: Marina Rogunova, James P. Mason, Xiangyang Li
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Publication number: 20140031494Abstract: The present invention relates to a polycarbonate resin composition, comprising: a polycarbonate resin containing a structural unit derived from a dihydroxy compound having a moiety represented by the following formula (1) [provided that a case where the moiety represented by formula (1) is a moiety constituting —CH2—O—H is excluded]; and an elastomer composed of a core•shell structure, wherein a core layer of the elastomer is at least one member selected from the group consisting of an alkyl (meth)acrylate and a (meth)acrylic acid, and a polycarbonate resin molded article obtained by molding the polycarbonate resin composition: ?CH2—O???(1)Type: ApplicationFiled: September 30, 2013Publication date: January 30, 2014Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Haruo Sasaki, Tomohiko Tanaka
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Publication number: 20140031493Abstract: The present invention relates to a polycarbonate resin composition, comprising: a polycarbonate resin containing a structural unit derived from a dihydroxy compound having a moiety represented by the following formula (1) [provided that a case where the moiety represented by formula (1) is a moiety constituting —CH2—O—H is excluded]; and an elastomer composed of a core?shell structure, wherein a core layer of the elastomer is composed of a butadiene-styrene copolymer, and a polycarbonate resin molded article obtained by molding the polycarbonate resin composition: ?CH2—O???(1)Type: ApplicationFiled: September 30, 2013Publication date: January 30, 2014Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Haruo SASAKI, Tomohiko Tanaka
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Patent number: 8557912Abstract: An aromatic vinyl-based thermoplastic resin composition includes a rubber-modified acrylic graft copolymer and a branched aromatic vinyl copolymer resin including a silicon compound.Type: GrantFiled: December 7, 2010Date of Patent: October 15, 2013Assignee: Cheil Industries Inc.Inventors: Jin Hwa Chung, Kee Hae Kwon, Il Jin Kim, Kwang Soo Park, Ja Kwan Koo
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Publication number: 20130231414Abstract: Provided are a polycarbonate resin composition that includes (A) a polycarbonate resin, (B) a first rubber modified vinyl-based graft copolymer including a first rubber having an average particle diameter of about 6 to about 20 ?m and a span of about 0.8 to about 2.8 and (C) a second rubber modified vinyl-based graft copolymer including a second rubber having an average particle diameter of about 0.1 to about 0.5 ?m, and a molded product using the same.Type: ApplicationFiled: April 19, 2013Publication date: September 5, 2013Applicant: Cheil Industries Inc.Inventors: Jung-Eun PARK, Doo-Han HA
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Publication number: 20130184409Abstract: An uncoated, highly reflective, impact-resistant injection-molded article which comprises a rubber ingredient (A) and a thermoplastic resin (B), characterized in that (1) the rubber ingredient (A) has been dispersed in the thermoplastic resin (B), (2) the rubber ingredient (A) has a coefficient of linear expansion of 12.5×10?5 to 19×10?5/° C., (3) the surface of the injection-molded article has a reflected-image clarity of 60-100%, and (4) the injection-molded article has a notched Charpy impact strength of 5-60 kJ/m2.Type: ApplicationFiled: September 30, 2011Publication date: July 18, 2013Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Tomoyuki Fujisawa, Mihoko Yamamoto, Hiroharu Itaya
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Publication number: 20130172469Abstract: Disclosed is a thermoplastic resin composition that includes (A) a polycarbonate resin; (B) a graft copolymer including an aromatic vinyl compound and a vinyl cyanide compound grafted on a conjugated diene-based rubbery polymer; and (C) a copolymer of an aromatic vinyl compound and a vinyl cyanide compound, wherein the copolymer (C) of an aromatic vinyl compound and a vinyl cyanide compound includes a repeating unit derived from the vinyl cyanide compound in an amount of about 18 wt % to about 22 wt %, based on the total amount of the copolymer (C). A molded product prepared using the thermoplastic resin composition is also provided.Type: ApplicationFiled: October 15, 2012Publication date: July 4, 2013Applicant: CHEIL INDUSTRIES INC.Inventor: CHEIL INDUSTRIES INC.
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Patent number: 8466214Abstract: Processes for making a core and core-shell copolymers are provided herein. Processes for making crosslinked elastomeric core particles includes emulsion polymerizing, in the presence of a radical polymerization initiator, a polymerization mixture containing at least one ethylenic elastomeric monomer, at least one crosslinking agent, and at least one sulfur-containing additive of the formula I below, where R and Z are defined herein. The core-shell copolymers formed are useful for example as additives in polymer matrices such as for modifying impact strength and improving optical properties.Type: GrantFiled: August 4, 2009Date of Patent: June 18, 2013Assignee: Arkema FranceInventors: Rosangela Pirri, Philippe Hajji
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Patent number: 8445581Abstract: The present invention provides a biocompatible prepolymer comprising hydrophilic and hydrophobic segments, wherein the hydrophobic segments have at least one ethylenically unsaturated functional group and at least 5% of the segments have two or more ethylenically unsaturated functional groups and water. The invention further provides a biocompatible prepolymer composition comprising hydrophilic and hydrophobic prepolymers, wherein at least one of the hydrophobic prepolymers has at least one ethylenically unsaturated functional group and at least 5% of the prepolymers have two or more ethylenically unsaturated functional groups and water. The invention further provides use of the prepolymer or prepolymer compositions of the invention in biomedical applications such as tissue engineering, as bone substitutes or scaffolds, and in wound treatment.Type: GrantFiled: August 2, 2007Date of Patent: May 21, 2013Assignee: Polynovo Biomaterials Pty LimitedInventors: Pathiraja Arachchillage Gunatillake, Roshan Tyrrel Anton Mayadunne, Raju Adhikari, Heng Chy Taing, Tam Phuong Thi Le, Jerome Anthony Werkmeister, John Alan Maurice Ramshaw, Jacinta Frances White, Tracy Ann Tebb
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Patent number: 8420736Abstract: An object of the present invention is to provide a thermoplastic resin composition capable of improving impact resistance and surface gloss of a molded article, and a molded article thereof. A thermoplastic resin composition of the present invention is comprising 100 parts by weight of a thermoplastic resin (a) and 0.5 to 30 parts by weight of a core-shell polymer composition (b), wherein the core-shell polymer composition (b) is obtained by polymerizing the shell-constituting components in the presence of a core obtained by polymerizing a monomer mixture (100% by weight in total) of 70% to 99.95% by weight of an alkyl acrylate having an alkyl group of 2 to 18 carbon atoms, 0.05% to 10% by weight of a polyfunctional monomer, and 0% to 20% by weight of a monomer copolymerizable with the alkyl acrylate and the polyfunctional monomer, and the polyfunctional monomers contains at least a compound having a plurality of same radically polymerizable functional groups in the molecule thereof.Type: GrantFiled: June 25, 2010Date of Patent: April 16, 2013Assignee: Kaneka CorporationInventors: Fuminobu Kitayama, Kouhei Fujimoto, Yuya Manabe
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Patent number: 8415428Abstract: The present invention provides a thermoplastic elastomer composition obtained by dynamically crosslinking, under a melting condition, 100 parts by mass of a block copolymer (I), 1 to 1,000 parts by mass of a polar resin (II), 1 to 500 parts by mass of a modified polymer (III), and 0.01 to 50 parts by mass of a crosslinking agent (IV), wherein the block copolymer (I) comprises at least one polymer block (A) comprising as a main component an alkylene unit, and/or at least one copolymer block (B) comprising as main components an alkylene unit (b-1) and a vinyl aromatic monomer unit (b-2), and comprises at least one unsaturated block (C) comprising as a main component a conjugated diene monomer unit having 5 or more carbon atoms at an end.Type: GrantFiled: February 4, 2009Date of Patent: April 9, 2013Assignee: Asahi Kasei Chemicals CorporationInventors: Daisuke Shimizu, Yasuhiro Kusanose, Yoshifumi Araki, Masahiro Fujiwara
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Patent number: 8410227Abstract: Thermoplastic molding compositions comprising A) from 10 to 99.99% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of a hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.Type: GrantFiled: May 29, 2012Date of Patent: April 2, 2013Assignee: BASF SEInventors: Andreas Eipper, Bernd Bruchmann, Dietrich Scherzer, Jean-Francois Stumbe, Carsten Weiβ, Freddy Gruber
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Patent number: 8410214Abstract: The present invention provides a thermoplastic resin composition comprising 100 mass parts of a polycarbonate resin composition comprising 50 to 95 mass % of (A) a polycarbonate resin and 50 to 5 mass % of (B) a polylactic acid based resin and 5 to 65 mass parts of (C) a vinyl based graft copolymer. The above thermoplastic resin composition comprising the polycarbonate resin and the lactic acid based resin and endowed with a mechanical characteristic of polycarbonate and an excellent fluidity of polylactic acid in combination is improved in a hydrolysis resistance and provides a molded article further improved in an impact resistance and a thin-walled falling weight impact strength.Type: GrantFiled: December 27, 2005Date of Patent: April 2, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventors: Yusuke Hayata, Akio Nodera
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Patent number: 8383726Abstract: Disclosed is a thermoplastic resin composition having excellent impact resistance at a low temperature, while maintaining high transparency; this thermoplastic resin composition is obtained by compounding an impact resistance improver into a thermoplastic resin, the impact resistance improver being composed of a graft copolymer which is obtained by polymerizing a vinyl monomer component in the presence of a polymer mixture containing a polymer having butadiene units as an essential component and a polymer having styrene units as an essential component, the polymer mixture containing 45 to 65% by mass of the butadiene units and 35 to 55% by mass of the styrene units.Type: GrantFiled: August 29, 2007Date of Patent: February 26, 2013Assignees: Mitsubishi Rayon Co., Ltd., Cheil Industries Inc.Inventors: Osamu Okunaka, Hiroyuki Nishii, Takashi Shouji, Keiji Nakamura, Tae Uk Kim, Byung Choon Lee
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Patent number: 8362146Abstract: Thermoplastic molding compositions, comprising A) from 10 to 98% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 1 to 40% by weight of an impact-modifying polymer, D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.Type: GrantFiled: August 2, 2005Date of Patent: January 29, 2013Assignee: BASF SEInventors: Andreas Eipper, Bernd Bruchmann, Carsten Weiβ, Jean-Francois Stumbe
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Patent number: 8362136Abstract: A thermoplastic molding composition, comprising 10 to 98.99% of a thermoplastic polyester, 0.01 to 20% of a hyperbranched polycarbonate, and/or hyperbranched AxBy polyester, wherein Ax and By are different monomers and indices x and y are functional groups in A and B, x is at least 1.1 and y at least 2.1; 1 to 60% of a graft polymer comprising 20 to 80% of a graft base comprising an elastomeric polymer based on alkyl acrylates, 20 to 80% of a graft of 60 to 95% of styrene or of substituted styrenes of formula 1 R is an alkyl radical or hydrogen, R1 is an alkyl radical, n is 1-3, and 5 to 40% by weight of an unsaturated nitrite, 0 to 60% of a copolymer comprising, 60 to 95 of styrene and/or substituted styrenes of formula 1, 5 to 40% of an unsaturated nitrile, 0 to 60% of other additives.Type: GrantFiled: August 2, 2005Date of Patent: January 29, 2013Assignee: BASF SEInventors: Andreas Eipper, Bernd Bruchmann, Carsten Weiβ, Jean-Francois Stumbe
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Patent number: 8318857Abstract: The present invention relates to filled, impact-modified polycarbonate compositions containing A) aromatic polycarbonate and/or aromatic polyester carbonate, B) a first graft polymer of B.1 from 0.1 to 30 wt. % of at least one vinyl monomer on B.2 from 99.9 to 70 wt. % of one or more graft bases having glass transition temperatures <10° C., the graft base consisting of at least 50 wt. % of a silicone rubber, C) a second graft polymer, which is different from component B, of C.1 from 5 to 95 wt. % of at least one vinyl monomer on C.2 from 95 to 5 wt. % of one or more graft bases having glass transition temperatures <10° C., the graft base consisting of at least 50 wt.Type: GrantFiled: January 17, 2008Date of Patent: November 27, 2012Assignee: Bayer MaterialScience AGInventors: Andreas Seidel, Achim Feldermann
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Patent number: 8314181Abstract: A method of making resin composition having excellent wear properties that includes 50 to 99 wt. % of a polycarbonate resin and from 1 to 50 wt. % of a polyolefin that has been modified with at least one functional group selected from a carboxyl, an acid anhydride, an epoxy groups or mixtures containing at least one of the foregoing functional groups, each based on the total combined weight of the resin composition, exclusive of any filler. The resin composition optionally contains an unmodified polyolefin and/or a bi-functional monomer. The resin composition can be molded into articles having improved wear characteristics. The process is a one-step process that improves the efficiency and/or yield of the resin composition as compared to prior-art two-step processes.Type: GrantFiled: September 20, 2011Date of Patent: November 20, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Ye-Gang Lin, Donghai Sun, David Xiangping Zou
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Publication number: 20120289655Abstract: The present invention seeks to provide a resin composition which contains an aromatic polycarbonate resin and a polyester resin and which has excellent mechanical strength, flowability and thermal stability and also has excellent moist heat resistance together. The present invention is a resin composition containing 50 to 99 parts by weight of an aromatic polycarbonate resin (component A) and 1 to 50 parts by weight of a polyester resin (component B), the component B being a polyester resin polymerized in the presence of a titanium-phosphorus catalyst obtained by reacting titanium tetrabutoxide, etc., with monolauryl phosphate, etc.Type: ApplicationFiled: January 13, 2011Publication date: November 15, 2012Inventors: Atsushi Sumita, Daisuke Takahashi, Fumihiro Togashi, Tomoyuki Hirano
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Patent number: 8293839Abstract: Disclosed herein is a polycarbonate-polysiloxane copolymer resin composition comprising: (A) about 100 parts by weight of a thermoplastic polycarbonate resin; and (B) about 0.1 to about 30 parts by weight of an organo-siloxane polymer having an epoxy group. The polycarbonate-polysiloxane copolymer resin composition has high impact strength at low temperature and high mechanical strength.Type: GrantFiled: June 16, 2009Date of Patent: October 23, 2012Assignee: Cheil Industries Inc.Inventors: Bo Young Kim, Jong Cheol Lim, Tae Gon Kang
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Patent number: 8288456Abstract: The present invention relates to a process for the production of impact-modified filled polycarbonate compositions and molding compositions. A process of the present invention involves: (i) mixing the CNT (component C) with rubber-containing vinyl copolymer (component B) and/or rubber-free vinyl copolymer (component D) on a twin screw extruder, to obtain a CNT masterbatch, (ii) mixing the CNT masterbatch with polycarbonate (component A) and optionally with Component B and/or Component D and optionally with an additive on a twin screw extruder. A polycarbonate composition prepared according to the present invention does not experience degradation of the molecular weight of the polycarbonate during compounding a compared to processes known in the art.Type: GrantFiled: August 27, 2008Date of Patent: October 16, 2012Assignee: Bayer Materialscience AGInventors: Achim Feldermann, Andreas Seidel, Michael Bierdel, Reiner Rudolf
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Patent number: 8278377Abstract: A resin composition which is excellent in appearance, impact strength, hydrolysis resistance and drip prevention properties. The resin composition comprises (A) 100 parts by weight of an aromatic polycarbonate resin (component A), (B) 0.01 to 6 parts by weight of a polymer mixture (component B) obtained by suspension polymerizing a styrene monomer, a maleic anhydride monomer and an acrylic monomer in the presence of polytetrafluoroethylene particles, and (C) 0.01 to 30 parts by weight of a flame retardant (component C).Type: GrantFiled: May 26, 2009Date of Patent: October 2, 2012Assignee: Teijin Chemicals, Ltd.Inventor: Takuya Tomoda
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Patent number: 8273825Abstract: A method of making resin composition having excellent wear properties that includes 50 to 99 wt. % of a polycarbonate resin and from 1 to 50 wt. % of a polyolefin that has been modified with at least one functional group selected from a carboxyl, an acid anhydride, an epoxy groups or mixtures containing at least one of the foregoing functional groups, each based on the total combined weight of the resin composition, exclusive of any filler. The resin composition optionally contains an unmodified polyolefin and/or a bi-functional monomer. The resin composition can be molded into articles having improved wear characteristics. The process is a one-step process that improves the efficiency and/or yield of the resin composition as compared to prior-art two-step processes.Type: GrantFiled: March 20, 2007Date of Patent: September 25, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Ye-Gang Lin, Donghai Sun, David Xiangping Zou
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Patent number: 8252867Abstract: The present invention relates to an impact strength modifier for thermoplastic polyester resin and a thermoplastic polyester resin composition containing the same, more precisely an impact strength modifier for thermoplastic polyester resin prepared by graft-polymerization of a) 20-80 weight % of multilayered rubber latex in which the ratio of particle diameter (Pb/Pa) of an inner layer (Pa) to outer layer is 1.05-1.5, and glass transition temperature of the inner layer or the outer layer is up to ?30° C.; and b) 20-80 weight % of vinyl monomer. According to the present invention, a thermoplastic polyester resin composition having excellent transparency and improved impact strength can be provided by containing an impact strength modifier for thermoplastic polyester resin having multilayered structure in which content of rubber latex, glass transition temperature, particle diameter and refraction index are regulated.Type: GrantFiled: December 24, 2008Date of Patent: August 28, 2012Assignee: LG Chem, Ltd.Inventors: Yoon-Ho Kim, Geon-Soo Kim, Sang-Il Nam
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Publication number: 20120178860Abstract: The reinforced thermoplastic resin composition of the present invention includes: 50 to 90% by weight of a polycarbonate resin (A); 10 to 50% by weight of a graft copolymer mixture (B) (provided that a total amount of the component (A) and the component (B) accounts for 100% by weight) which is obtained by graft-polymerizing an aromatic alkenyl compound monomer unit (a) and a vinyl cyanide compound monomer unit (b) onto a rubber polymer (B1); and 6 to 22 parts by weight of an inorganic filler (D) which has been surface-treated with a water-soluble polyamide, relative to the total of 100 parts by weight of the polycarbonate resin (A) and the graft copolymer mixture (B). There is provided a reinforced thermoplastic resin composition exhibiting excellent moldability, generates a minimal amount of gas during molding, and also being capable of improving the rigidity of the resulting molded article and the impact resistance when dropping the product.Type: ApplicationFiled: September 24, 2010Publication date: July 12, 2012Inventors: Masahito Nakamoto, Koichi Tezuka
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Publication number: 20120165425Abstract: A polycarbonate resin composition including (A) a mixed resin including (A1) a polycarbonate resin; (A2) a polybutylene terephthalate resin; and (A3) a polycarbonate-polysiloxane copolymer; and (B) a graft copolymer including an unsaturated compound including an acrylic-based compound graft-polymerized into a rubber.Type: ApplicationFiled: July 27, 2011Publication date: June 28, 2012Applicant: CHEIL INDUSTRIES INC.Inventors: Jung-Eun PARK, Doo-Han HA
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Publication number: 20120157629Abstract: The present invention relates to new impact modifiers and a process for making these new impact modifiers and their use in polymeric compositions. More particularly the present invention relates to a new polymeric impact modifier with a core-shell structure made by a multistage polymerization process comprising at least one gradient polymer. The present invention relates as well to a process preparing such an impact modifier, especially its recovery process after the end of the polymerization. The present invention also relates to a thermoplastic composition comprising the new impact modifier.Type: ApplicationFiled: December 14, 2011Publication date: June 21, 2012Applicant: Arkema FranceInventors: Christophe Navarro, Stephane Girois, Elisabeth Bay, Jean-Claude Saint-Martin
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Publication number: 20120157628Abstract: The present invention relates to, amongst other things, a process for manufacturing an impact modifier, concerns impact modified thermoplastic molding compositions and in particular a process for manufacturing and recovering the impact modifiers and their use in polymeric thermoplastic compositions. More particularly the present invention relates to a polymeric impact modifier with a core-shell structure manufactured by a multistage process comprising a special recovery process so that the composition of the thermoplastic polymer containing the impact modifier has a high fluidity while keeping its high impact strength.Type: ApplicationFiled: December 14, 2011Publication date: June 21, 2012Applicant: Arkema FranceInventors: Christophe Navarro, Stephane Girois, Elisabeth Bay, Jean-Claude Saint-Martin, Magali Bergeret-Richaud
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Publication number: 20120157630Abstract: The present invention relates to thermoplastic compositions comprising as impact modifier a rubber containing graft polymer prepared by the process of emulsion polymerization and recovered by a special process controlling and adjusting the value, the use of the thermoplastic compositions in the production of molded bodies, and to the molded, bodies themselves. The present invention relates also to thermoplastic compositions comprising a polymeric impact modifier with a core-shell structure made by a multistage process and recovered by a special process controlling and adjusting the pH value comprising at least one gradient polymer the use of the thermoplastic compositions in the production of molded bodies, and to the molded, bodies themselves.Type: ApplicationFiled: December 14, 2011Publication date: June 21, 2012Applicant: Arkema FranceInventors: Christophe Navarro, Stephane Girois, Elisabeth Bay, Jean-Claude Saint-Martin, Magali Bergeret-Richaud
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Patent number: 8202938Abstract: Disclosed is a thermoplastic resin composition that includes (A) a polycarbonate resin, (B) a modified acryl-based copolymer resin, (C) a polysiloxane copolymer including an aryl group, and (D) a core-shell graft copolymer.Type: GrantFiled: November 5, 2009Date of Patent: June 19, 2012Assignee: Cheil Industries Inc.Inventors: Byung-Choon Lee, Doo-Han Ha, Tae-Uk Kim, Jae-Hoon Jeong, Il-Jin Kim
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Patent number: 8198366Abstract: The present invention provides a thermoplastic resin composition containing (A) a resin mixture including (a-1) a polycarbonate resin in an amount of 45 to 97% by mass and (a-2) a fatty acid polyester in an amount of 55 to 3 % by mass, and (B) a rubber-like elastomer in an amount of 0.5 to 20 parts by mass per 100 parts by mass of the resin mixture, wherein component (B) is dispersed in an interface between ingredient (a-1) and ingredient (a-2) or in domains of ingredient (a-2). The composition has high impact characteristics and high fluidity and overcomes appearance defects such as pearl-like gloss and jetting marks.Type: GrantFiled: October 25, 2005Date of Patent: June 12, 2012Assignee: Idemitsu Kosan Co., Ltd.Inventors: Yusuke Hayata, Akio Nodera
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Patent number: 8158701Abstract: Polycarbonate compositions are disclosed that have high flame retardance, good mechanical properties, and low halogen content. The compositions comprise a polycarbonate, a grafted butadiene rubber, a phosphorous-containing flame retardant, and a combination of a silicone-containing functionality with fumed silica.Type: GrantFiled: February 2, 2011Date of Patent: April 17, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Robert Russell Gallucci, Srinivas Siripurapu, Amit S. Kulkarni
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Publication number: 20120065318Abstract: A polyester/polycarbonate alloy resin composition that includes (A) a base resin including (A-1) a polyester resin and (A-2) a polycarbonate resin; (B) a copolymer of a vinyl cyanide compound and an aromatic vinyl compound; and (C) a modified acrylic-based polymer is provided.Type: ApplicationFiled: November 21, 2011Publication date: March 15, 2012Applicant: CHEIL INDUSTRIES INC.Inventors: Jung-Eun PARK, In-Sik SHIM, Bang-Duk KIM, Doo-Han HA
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Publication number: 20120053271Abstract: The present invention relates to impact-modified polyester/polycarbonate compositions containing: A) 41 to 80 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of aromatic polycarbonate, B) 5 to 40 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of polyester with a content of isophthalic acid building blocks, C) 1 to 15 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of rubber-modified graft polymer, D) 0 to 25 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of a flame retardant, E) 0 to 20 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D=100, of vinyl (co)polymer, F) 0 to 50 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D=100, of additives, wherein all the stated parts by weights in the present application are normalised such thatType: ApplicationFiled: August 22, 2011Publication date: March 1, 2012Applicant: BAYER MATERIALSCIENCE AGInventors: Achim FELDERMANN, Eckhard WENZ
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Patent number: 8124683Abstract: A polycarbonate resin composition of the present invention comprises (A) about 30 to about 95 parts by weight of thermoplastic polycarbonate resin; (B) about 1 to about 50 parts by weight of rubber-modified-vinyl graft copolymer; (C) about 0 to about 50 parts by weight of vinyl copolymer; and (D) about 1 to about 50 parts by weight of amorphous thermoplastic polyester copolymer. The resin composition of the present invention can have excellent physical properties such as weld line strength, fluidity, impact resistance, and heat resistance.Type: GrantFiled: November 10, 2009Date of Patent: February 28, 2012Assignee: Cheil Industries Inc.Inventors: Hyuk Jin Jung, Jong Cheol Lim
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Patent number: 8119735Abstract: A golf ball having a cover having a pearlescent effect is disclosed. The cover comprises a first thermoplastic and a second thermoplastic having an index of refraction that differs from an index of refraction of the first thermoplastic by at least about 0.5 percent. The cover further comprises a compatibilizer.Type: GrantFiled: January 26, 2009Date of Patent: February 21, 2012Assignee: Acushnet CompanyInventors: Edmund A. Hebert, Murali Rajagopalan
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Patent number: 8114928Abstract: Disclosed is a transparent/translucent molding composition and process for making prepared from an impact modifier and a resin blend of polycarbonate and a cycloaliphatic polyester having a matching index of refraction.Type: GrantFiled: June 21, 2010Date of Patent: February 14, 2012Assignee: SABIC Innovative Plastics IP BVInventors: Satish Kumar Gaggar, Johannes Jacobus de Moor, Paul Honigfort, Gabrie Hoogland, Mark van Heeringen, Eelco M. S. van Hamersveld
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Patent number: 8114522Abstract: Disclosed is a resin composition forming an adhesive layer between a polylactic acid resin substrate layer and a polyolefin resin substrate layer. The resin composition includes a modified polyolefin resin (A) and a terpene resin (B), and the mass ratio (A)/(B) between the both resins (A) and (B) is 20/80 to 99/1. Alternatively, the resin composition may be a resin composition including 10 to 90% by mass of a polylactic acid resin (C), 5 to 89% by mass of the modified polyolefin resin (A) and 1 to 80% by mass of a hydrogenated petroleum resin (D), with the total amount of these resins constrained to be 100% by mass.Type: GrantFiled: February 16, 2009Date of Patent: February 14, 2012Assignee: Unitika Ltd.Inventors: Yuji Kitora, Mitsuhiro Kawahara, Kazue Ueda