From Carboxylic Acid Amide-containing Monomer Patents (Class 526/303.1)
  • Patent number: 8138290
    Abstract: An ophthalmic device is disclosed that is a polymerization product of a monomeric mixture comprising (a) a major amount of a non-silicone-containing hydrophilic monomer; (b) a hydrophobic monomer; and (c) a crosslinking agent, wherein the ophthalmic device has an equilibrium water content of at least about 70 weight percent and further wherein the ophthalmic device has an evaporative dehydration barrier layer on the surface thereof. A method for the mitigation of evaporative corneal dehydration employing the high water content ophthalmic device is also disclosed.
    Type: Grant
    Filed: January 8, 2009
    Date of Patent: March 20, 2012
    Assignee: Bausch & Lomb Incorporated
    Inventors: Richard I. Blackwell, Joseph C. Salamone, Jay F. Kunzler
  • Publication number: 20120065676
    Abstract: The present disclosure relates to compositions comprising a copolymer that includes a first monomer and a second monomer that is different from the first monomer, wherein both the first and second monomer are selected from the group consisting of 3-sulfopropyl acrylate potassium salt, sodium acrylate, N-(tris(hydroxyl methyl)methyl)acrylamide, and 2-acrylamideo-2-methyl-1-propane sulfonic acid. The present disclosure further relates to methods for preparing the copolymer compositions and shaped articles comprising the copolymers.
    Type: Application
    Filed: November 21, 2011
    Publication date: March 15, 2012
    Applicant: Tyco Healthcare Group LP
    Inventors: Ahmad R. Hadba, Brian Cuevas, Frank R. Schiretz, Joshua B. Stopek
  • Patent number: 8129442
    Abstract: A hydrophilic polysiloxane macromonomer containing polyoxyethylene as a hydrophilic side chains pendant to a polysiloxane main chain for imparting transparency, oxygen permeability, and hydrophilic properties to a contact lens is disclosed. The properties of the material are controlled by regulating the length of the polysiloxane main chain, the length of the hydrophilic polyoxyethylene side chains, and the number of the side chains.
    Type: Grant
    Filed: February 6, 2009
    Date of Patent: March 6, 2012
    Assignee: CooperVision International Holding Company, LP
    Inventors: Hiroyuki Ueyama, Seiichiro Ikawa, Junichi Iwata
  • Patent number: 8124229
    Abstract: A process for preparing water-absorbing polymer beads with high permeability by polymerizing droplets of a monomer solution in a gas phase surrounding the droplets, wherein the monomer solution comprises at least 0.5% by weight of a crosslinker, based on the monomer, the polymerization in the droplet takes place in homogeneous phase, and the polymer beads have a mean diameter of at least 150 ?m.
    Type: Grant
    Filed: July 11, 2007
    Date of Patent: February 28, 2012
    Assignee: BASF SE
    Inventors: Uwe Stueven, Matthias Weismantel, Wilfried Heide, Marco Krüger, Volker Seidl, Stefan Blei, Dennis Loesch, Rüdiger Funk, Annemarie Hillebrecht
  • Patent number: 8114936
    Abstract: The invention relates to polymers useful as a papermaking additives. The invention also relates to methods for making and using such additives.
    Type: Grant
    Filed: April 6, 2011
    Date of Patent: February 14, 2012
    Inventors: Lucyna Pawlowska, Robert Proverb
  • Patent number: 8105503
    Abstract: It is intended to provide an aqueous solution of a thermoresponsive polymer, which shows an upper critical solution temperature (UCST) and is capable of maintaining a dissolved state, even if it is stored for a long period of time at a temperature at which a ligand such as an antibody or an antigen is not inactivated. A UCST lowering agent is incorporated in a predetermined amount in an aqueous solution of a thermoresponsive polymer which shows a UCST in a state of containing water, thereby lowering the UCST of the aqueous solution to less than the storage temperature, and the resulting aqueous solution is stored.
    Type: Grant
    Filed: May 31, 2011
    Date of Patent: January 31, 2012
    Assignee: Chisso Corporation
    Inventors: Masaru Eguchi, Noriyuki Ohnishi
  • Patent number: 8097126
    Abstract: The present invention relates to an aqueous composition comprising at least one finely divided filler and at least one water-soluble amphoteric copolymer, a process for the preparation of such a composition and its use as an additive in the production of paper, cardboard and board.
    Type: Grant
    Filed: July 15, 2005
    Date of Patent: January 17, 2012
    Assignee: BASF SE
    Inventors: Hans-Joachim Haehnle, Anton Esser, Volker Braig, Rainer Blum, Peter Baumann, Jacques Dupuis, Josef Neutzner
  • Patent number: 8088252
    Abstract: A solution with a salt-sensitive polymer binder for use in fibrous webs, where the binder contains a copolymer comprising repeat units derived from butyl acrylate, methyl methacrylate and amino functionalized alkyl acrylate or methacrylate or amino functionalized alkyl acrylamide or methacrylamide optionally including monomers such as vinyl acetate and/or vinyl acetate/ethylene. The binder solution is prepared by emulsion-polymerizing a copolymer and then neutralizing the copolymer with acid to make it water soluble. The binders are particularly suitable for strengthening nonwoven fibrous webs in disposable articles such as wet-wipes, personal care products, diapers, and the like and retain their salt-sensitivity with or without divalent metal scavengers.
    Type: Grant
    Filed: March 2, 2009
    Date of Patent: January 3, 2012
    Inventors: Rajeev Farwaha, Philip Confalone
  • Patent number: 8076432
    Abstract: Described herein are methods for producing phosphonic compounds and compounds thereof. Stable compositions of unsaturated phosphonic acid monomers are also described. Additionally, the synthesis and use of new polymers produced from phosphonic acid monomers are presented.
    Type: Grant
    Filed: September 10, 2008
    Date of Patent: December 13, 2011
    Assignee: Unichem Technologies, Inc.
    Inventor: Atif Dabdoub
  • Publication number: 20110294974
    Abstract: The present invention relates to an N-(1-hydroxyethyl)carboxamide compound represented by formula (1) (in the formula, RA and RB represent independently from each other a hydrogen atom or an alkyl group having 1 to 4 carbon atoms except for a case where RA and RB represent a hydrogen atom at the same time) and a method for producing the same; a method for producing an N-(1-alkoxyethyl)carboxamide compound; a method for producing an N-vinyl carboxylic acid amide compound; and a method for producing an N-vinyl carboxylic acid amide (co)polymer. An N-(1-alkoxyethyl)carboxamide compound can be obtained by reacting N-(1-hydroxyethyl)carboxamide compound with alcohol in the presence of an acid catalyst, and an N-vinyl carboxylic acid amide compound, which is a monomer of the N-vinyl carboxylic acid amide (co)polymer, can be obtained by thermally decomposing or catalytically decomposing the N-(1-alkoxyethyl)carboxamide compound.
    Type: Application
    Filed: January 5, 2010
    Publication date: December 1, 2011
    Applicant: SHOWA DENKO K.K.
    Inventors: Keisuke Ohta, Syunichi Nagamatsu, Tetsuya Ishii
  • Publication number: 20110288255
    Abstract: A method for producing an amide compound from a nitrile compound in an aqueous medium in the presence of a catalyst having a nitrile hydratase activity wherein the concentration of benzene in the aqueous medium is 4.0 ppm or less and a method for producing an amide-based polymer excellent in quality from the amide compound. Also provided are a method for more efficiently producing an acrylamide with higher quality by a microbial catalyst containing a nitrile hydratase and the like and a method for producing an acrylamide-based polymer, which is excellent in hue, has a good balance between water solubility and high molecular weight and is excellent in quality.
    Type: Application
    Filed: August 3, 2011
    Publication date: November 24, 2011
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Hiroko Shibamoto, Toshikazu Aikawa, Teruo Arii, Masanori Muramoto, Takeshi Fukuda, Kiyoshi Ito, Takeya Abe, Souichi Hazama
  • Patent number: 8057698
    Abstract: The invention relates to mixtures of methacrylamide and aqueous N-methylolmethacrylamide solution.
    Type: Grant
    Filed: October 31, 2006
    Date of Patent: November 15, 2011
    Assignee: Evonik Röhm GmbH
    Inventors: Wolfgang Klesse, Joachim Knebel
  • Patent number: 8053497
    Abstract: The invention concerns the polymers obtained by the use of sulfur compounds in a process for controlled radical polymerization in water of acrylic acid and/or acrylic acid with hydrosoluble monomers. It concerns also their uses as dispersant agents or agents to aid grinding and/or co-grinding of mineral matters in aqueous suspensions, and as dispersant agents incorporated directly in aqueous formulations containing mineral matters. Finally, the invention concerns the formulations of mineral matters obtained in this manner.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: November 8, 2011
    Assignee: Coatex S.A.S.
    Inventors: Jean-Marc Suau, Christian Jacquemet
  • Patent number: 8048968
    Abstract: The invention provides an actinically-crosslinkable linear polysiloxane copolymer. The actinically-crosslinkable polysiloxane copolymer can be used to prepare a silicone hydrogel contact lens having a hydrophilic surface without post-curing surface treatment. The invention is also related to a silicone hydrogel contact lens obtained from a lens-forming material including an actinically-crosslinkable polysiloxane copolymer of the invention and to a method for making an actinically-crosslinkable polysiloxane copolymer of the invention. In addition, the invention provides a non-crosslinkable linear polysiloxane copolymer capable of being used as a internal wetting agent which can render the surface of a silicone hydrogel contact lens hydrophilic.
    Type: Grant
    Filed: November 11, 2009
    Date of Patent: November 1, 2011
    Assignee: Novartis AG
    Inventors: John Christopher Phelan, Yongxing Qiu, Robert Scott, Lynn Cook Winterton
  • Patent number: 8043423
    Abstract: A pigment dispersion liquid capable of stably recording images having high fastness and excellent quality for a long term in any cases has been provided. A pigment dispersion liquid mainly containing a polymer dispersant, a pigment and water, wherein the polymer dispersant is a copolymer comprised of at least a hydrophobic unit and a hydrophilic unit, the hydrophobic unit has a block portion comprised of at least one hydrophobic monomer, the hydrophilic unit has at least a repeating unit structure of an acrylamide structure of the following general formula (1), and the segment number (A) of the block portion comprised of a hydrophobic monomer to the number (B) of all segments of the polymer dispersant is in a range of 0.07 to 0.85 in terms of A/B ratio.
    Type: Grant
    Filed: December 16, 2008
    Date of Patent: October 25, 2011
    Assignee: Canon Finetech Inc.
    Inventors: Junko Chizuwa, Tomoya Yamamoto, Takayuki Ookawa, Suzuka Ueno
  • Patent number: 8044156
    Abstract: Disclosed are multi-purpose polymers that are the polymerization product of a monomer mixture comprising at least one amino-substituted vinyl monomer; at least one nonionic vinyl monomer; at least one associative vinyl monomer; at least one semihydrophobic vinyl surfactant monomer; and, optionally, comprising one or more hydroxy-substituted nonionic vinyl monomer, crosslinking monomer, chain transfer agent or polymeric stabilizer. These vinyl addition polymers have a combination of substituents, including amino substituents that provide cationic properties at low pH, hydrophobic substituents, hydrophobically modified polyoxyalkylene substituents, and hydrophilic polyoxyalkylene substituents. The polymers provide surprisingly beneficial rheological properties in acidic aqueous compositions, and are compatible with cationic materials. The multi-purpose polymers are useful in a variety of products for personal care, health care, household care, institutional and industrial care, and industrial applications.
    Type: Grant
    Filed: May 22, 2008
    Date of Patent: October 25, 2011
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventors: Krishnan Tamareselvy, Thomas A. Barker, James E. Mullee, Charles T. Greenslade, Julie F. Schmucker-Castner, Deborah S. Filla
  • Patent number: 8039568
    Abstract: The present invention relates to copolymers which comprise ethyl methacrylate, at least one ?,?-ethylenically unsaturated amide group-containing compound and at least one monoethylenically unsaturated carboxylic acid in copolymerized form, to cosmetic and pharmaceutical compositions which comprise at least one such copolymer, and to the use of these copolymers.
    Type: Grant
    Filed: October 19, 2005
    Date of Patent: October 18, 2011
    Assignee: BASF SE
    Inventors: Son Nguyen-Kim, Gabi Winter, Matthias Laubender
  • Patent number: 8030422
    Abstract: Disclosed herein are novel polymer-tethered ligands, metal complexes comprising these ligands, and the use of these complexes as chain transfer catalysts to control the molecular weight of oligomeric and polymeric materials produced in a radical polymerization process. The materials made by the processes disclosed herein have significantly reduced color, making them suitable for a wide range of color-critical end-uses, including automotive coatings.
    Type: Grant
    Filed: August 16, 2006
    Date of Patent: October 4, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Henry Edward Brynzda, Michael Charles Grady, Sigridur Soley Kristjansdottir, Christina M. Older, Matthew Arthur Page, Joachim C. Ritter, Wilson Tam
  • Patent number: 8030423
    Abstract: Multi-armed macromonomers containing multiple side chains attached to a siloxy-containing core terminated on each end with one or more first substantially linear polysiloxane radicals having a polymerizable ethylenically unsaturated-containing terminal group, wherein each side chain comprises a second substantially linear polysiloxane radical having a polymerizable ethylenically unsaturated-containing terminal group are disclosed. Biomedical devices such as contact lenses formed from the multi-armed macromonomers are also disclosed.
    Type: Grant
    Filed: January 13, 2009
    Date of Patent: October 4, 2011
    Inventors: Joseph C. Salamone, Jay F. Kunzler
  • Patent number: 8026315
    Abstract: The present invention relates to a process for producing water-absorbing polymeric particles by polymerizing a monomer solution, which comprises removing the polymer gel from the reactor when the gel temperature is at least 50° C. and the monomer conversion is not more than 90 mol %, and also to a process for producing hygiene articles.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: September 27, 2011
    Assignee: Basf Aktiengesellschaft
    Inventors: Ulrich Riegel, Thomas Daniel, Dieter Hermeling, Mark Elliott
  • Patent number: 8022158
    Abstract: The present invention relates to biomedical devices, and particularly contact lenses comprising a polymer having entangled therein at least one acyclic polyamide.
    Type: Grant
    Filed: February 23, 2010
    Date of Patent: September 20, 2011
    Assignee: Johnson & Johnson Vision Care, Inc.
    Inventors: Osman Rathore, Shivkumar Mahadevan, Frank Molock, Azaam Alli, David Turner, Douglas G. Vanderlaan, Kevin P. McCabe
  • Patent number: 8017682
    Abstract: Linear acrylamide copolymer compounds which can comprise monomeric components comprising at least one N-substituted moiety capable of physical cross-linking, and related compositions and methods of use.
    Type: Grant
    Filed: May 14, 2007
    Date of Patent: September 13, 2011
    Assignee: Northwestern University
    Inventors: Thomas N. Chiesl, Annelise E. Barron
  • Patent number: 8017706
    Abstract: The present invention relates to a novel iron complex having a cyclic amine compound as a ligand and a method for producing polymers by polymerizing a radical polymerizable monomer in the presence of the iron complex and a radical generator. The problem for the present invention is providing a method capable of producing a polymer or block copolymer having a chemically convertible functional group at the end from a radical polymerizable monomer and providing a method for recovering the iron complex in a solvent with a high recovery rate after the polymerization reaction. This problem is solved by providing a novel iron complex, a method for producing a polymer in the presence of a radical polymerization initiator that uses the iron complex as a polymerization catalyst and a method for simply and easily recovering the iron complex.
    Type: Grant
    Filed: March 10, 2008
    Date of Patent: September 13, 2011
    Assignee: DIC Corporation
    Inventors: Hidetomo Kai, Akane Sasamoto, Hitoshi Hayakawa
  • Publication number: 20110218312
    Abstract: A novel process is described which allows N-isopropyl(meth)acrylamide to be obtained in high purity and yield in a simple manner, by reacting methacrylic anhydride with isopropylamine, optionally in a solvent.
    Type: Application
    Filed: November 19, 2009
    Publication date: September 8, 2011
    Applicant: EVONIK ROEHM GmbH
    Inventors: Joachim Knebel, Wilhelm Karnbrock, Volker Kerscher
  • Patent number: 8013092
    Abstract: A waterborne coating produced form a composition containing a binder resin having post crosslinking groups, an associative thickener having post crosslinking groups, a dispersant having post crosslinking groups, and a reactive diluent having post crosslinking groups.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: September 6, 2011
    Assignee: The Sherwin-Williams Company
    Inventors: John M. Krajnik, Peter J. Mackulin, Pietro J. Ragone
  • Patent number: 8007678
    Abstract: Temporary sizing agent for natural and/or artificial individualized textile fibers comprises a water-soluble homopolymer or copolymer of at least one acrylamide monomer having a molecular weight not less than one million, advantageously more than three millions.
    Type: Grant
    Filed: December 16, 2005
    Date of Patent: August 30, 2011
    Assignees: EMZ Trek, SNF S.A.S.
    Inventors: Milton Faria, Charles Cordier
  • Publication number: 20110207206
    Abstract: A composite including a cross-linked interpenetrating network of an organic polymer including an alcohol adduct of, for example, a glycidyl ether substituted acrylate or epoxy substituted acrylate; and a sol-gel polymer. The composite having a low or no-shrinkage characteristic, and a method for making and using the composite, as defined herein.
    Type: Application
    Filed: May 25, 2010
    Publication date: August 25, 2011
    Inventor: Nikita Sergeevich Shelekhov
  • Patent number: 8003079
    Abstract: Nanoparticles having an average particle size of less than 2000 nm, wherein said nanoparticles comprise a polymer having pendant cleavable iodine substituted groups are provided. Processes for preparing the nanoparticles and their use as a contrast agent for X-ray imaging are also described.
    Type: Grant
    Filed: April 4, 2006
    Date of Patent: August 23, 2011
    Assignee: Bar-Ilan University
    Inventors: Shlomo Margel, Anna Galperin
  • Patent number: 7999050
    Abstract: A method of making a composition comprising reacting, in a reactor, a non-halogenated acetoacetate group containing monomer, at least one additional monomer, and a base, wherein at least a portion of the base is fed to the reactor during reaction. Also, a composition comprising an aqueous polymer dispersion that is a product of a method comprising reacting a non-halogenated acetoacetate moiety containing monomer, at least one additional monomer, and a base, wherein the base is fed to the reaction during reaction, wherein the composition has a lower viscosity than a second composition, wherein the second composition is prepared from the same materials as the composition, and the second composition is made by a method wherein the base is added to the second composition after a reaction to form the second composition.
    Type: Grant
    Filed: August 10, 2006
    Date of Patent: August 16, 2011
    Assignee: BASF SE
    Inventor: Cheng-Le Zhao
  • Patent number: 7994265
    Abstract: In a method of preparing an aqueous dispersion selected from drilling fluids, hydraulic cement compositions, mineral pigment containing coatings, and papermaking furnishes or in a method of preparing a melt extrudate, the improvement comprising: a) producing a copolymer of vinyl alcohol (VOH) and 2-acrylamido-2-methyl propane sulfonic acid or a salt of such acid (AMPS) by steps including continuously feeding with agitation, vinyl acetate (VAM) and AMPS as comonomers, a free radical yielding polymerization initiator, and a solvent for said comonomers, initiator, and copolymer resulting from the copolymerization of said comonomers, maintaining the resulting reaction mass in said first reaction zone under polymerization conditions for a residence time sufficient for a major proportion of AMPS fed to said first reaction zone to polymerize, continuously feeding reaction mass from said first reaction zone with an additional supply of AMPS to a second reaction zone, maintaining the reaction mass in the second reacti
    Type: Grant
    Filed: August 13, 2010
    Date of Patent: August 9, 2011
    Assignee: Sekisvi Specialty Chemicals America, LLC
    Inventor: Richard Vicari
  • Patent number: 7989572
    Abstract: UV-absorbing polymers and copolymers suitable for Composition into sunscreens for the protection of human skin. The UV-absorbing chromophoric monomers chosen are simple and easily synthesized. With the correct choice of chromophoric monomer or mixture of monomers, protection against UV-A radiation or against both UV-A and UV-B radiation can be achieved. With the correct choice of comonomer, copolymers produced as aqueous latex emulsions or as Polyethylene Glycol solutions can also be achieved.
    Type: Grant
    Filed: January 17, 2008
    Date of Patent: August 2, 2011
    Assignee: Eastman Chemical Company
    Inventors: Robert Joseph Maleski, Ramesh Chand Munjal, Max Allen Weaver, Jean Carroll Fleischer, Michael Gale Ramsey, Greg Alan King, Edward Enns McEntire
  • Patent number: 7976728
    Abstract: It is intended to provide an aqueous solution of a thermoresponsive polymer and an aqueous dispersion of a thermoresponsive particle, which show an upper critical solution temperature (UCST) and are capable of maintaining a dissolved state and a dispersed state, respectively, even if they are stored for a long period of time at a temperature at which a ligand such as an antibody or an antigen is not inactivated. A UCST lowering agent is incorporated in a predetermined amount in an aqueous solution of a thermoresponsive polymer which shows a UCST in a state of containing water or an aqueous dispersion of a thermoresponsive particle containing the polymer, thereby lowering the UCST of the aqueous solution or aqueous dispersion to less than the storage temperature, and the resulting aqueous solution or aqueous dispersion is stored.
    Type: Grant
    Filed: June 26, 2008
    Date of Patent: July 12, 2011
    Assignee: JNC Corporation
    Inventors: Masaru Eguchi, Noriyuki Ohnishi
  • Publication number: 20110166308
    Abstract: The present invention provides polymers resulting from polymerization of at least one reactive vinyl monomer moiety and a multifunctional N-vinylformamide crosslinking moiety; polymers resulting from polymerization of at least one reactive vinyl monomer moiety and a hybrid N-vinylformamide crosslinking moiety having at least one N-vinylformamide functionality and at least one other reactive vinyl functionality; polymers resulting from polymerization of at least one hybrid reactive N-vinylformamide monomer moiety having one N-vinylformamide functionality and at least one other reactive non-vinyl functionality and a multifunctional N-vinylformamide crosslinking moiety; and polymers resulting from polymerization of at least one hybrid reactive N-vinylformamide monomer moiety having one N-vinylformamide functionality and at least one other reactive non-vinyl functionality and a hybrid N-vinylformamide crosslinking moiety having at least one N-vinylformamide functionality and at least one other reactive vinyl func
    Type: Application
    Filed: January 5, 2011
    Publication date: July 7, 2011
    Inventors: Osama M. Musa, Ilya Makarovsky, Lei Cuiyue
  • Patent number: 7973117
    Abstract: A continuous production process, for producing an (meth)acrylic ester (co)polymer comprises the step of continuously feeding an organoaluminum compound-containing polymerization initiator solution and an (meth)acrylic ester into a reactor to continuously obtain a living polymer-containing polymer reaction liquid. The {[molar quantity of methacrylic ester or acrylic ester]/([molar quantity of organoaluminum compound]?[molar quantity of polymerization initiator])} fed into the reactor is regulated to be 15 to 80, and the content of the (meth)acrylic ester in the total feed amount of a polymerization initiator solution and an (meth)acrylic ester fed into the reactor is regulated to not more than 5% by mass.
    Type: Grant
    Filed: August 11, 2005
    Date of Patent: July 5, 2011
    Assignee: Kuraray Co., Ltd.
    Inventors: Kenichi Hamada, Yoshihiro Morishita, Tatsufumi Watanabe, Kazushige Ishiura
  • Publication number: 20110128023
    Abstract: Disclosed are a probe inspecting method for confirming the state of a probe for inspecting electric characteristics of an object to be inspected; and a curable resin composition for use in the method. The method is applied to repeat inspections and comprises the steps of bringing a cured resin of a curable resin composition into contact with a probe for inspecting electric characteristics of an object to be inspected, transferring a probe mark of the probe to the cured resin, confirming the state of the probe based on the transferred probe mark, and, after the transfer of the probe mark of the probe, heating the cured resin to a temperature at or above the glass transition temperature of the cured resin to erase the probe mark of the probe.
    Type: Application
    Filed: February 20, 2009
    Publication date: June 2, 2011
    Applicant: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Gosuke Nakajima, Yoshitsugu Goto, Kazuhiro Oshima, Jun Watanabe
  • Patent number: 7947790
    Abstract: A porous membrane of vinylidene fluoride resin excellent in hydrophilicity and having a good balance among strength, elongation and water permeation rate, which is thus useful as a microfiltration membrane or a separator of battery. The porous membrane is formed from a copolymer of 100 mols of a vinylidene fluoride monomer and 0.01-10.0 mols of a hydrophilic monomer having at least one species of hydrophilic group selected from epoxy group, hydroxy group, carboxy group, ester group, amide group and acid anhydride group.
    Type: Grant
    Filed: April 9, 2004
    Date of Patent: May 24, 2011
    Assignee: Kureha Corporation
    Inventors: Takumi Katsurao, Tomoaki Kawakami, Toshio Hosokawa
  • Patent number: 7943713
    Abstract: Polymeric compounds of formula I comprising boronic acid are provided. These polymeric compounds are prepared either by grafting boronic acid containing compounds (e.g. 4-carboxyphenylboronic acid) to hydrolysed poly(N-vinylformamide) or hydrolysing copolymer(s) obtained by copolymerizing vinyl group containing boronic acid monomers (e.g. -vinylphenyl boronic acid) and N-vinylformamide. These polymeric compounds are used in increasing the wet strength of paper in paper-making processes. Formula (I).
    Type: Grant
    Filed: July 29, 2005
    Date of Patent: May 17, 2011
    Assignee: BASF Aktiengesellschaft
    Inventors: Robert H. Pelton, Chen Lu
  • Patent number: 7935773
    Abstract: The present disclosure relates to compositions comprising a copolymer that includes a first monomer and a second monomer that is different from the first monomer, wherein both the first and second monomer are selected from the group consisting of 3-sulfopropyl acrylate potassium salt, sodium acrylate, N-(tris(hydroxyl methyl)methyl)acrylamide, and 2-acrylamideo-2-methyl-1-propane sulfonic acid. The present disclosure further relates to methods for preparing the copolymer compositions and shaped articles comprising the copolymers.
    Type: Grant
    Filed: August 16, 2005
    Date of Patent: May 3, 2011
    Assignee: Tyco Healthcare Group LP
    Inventors: Ahmad R. Hadba, Brian Cuevas, Frank R. Schiretz, Joshua B. Stopek
  • Patent number: 7935757
    Abstract: A process is described for making an aqueous coating composition comprising a cationic vinyl oligomer comprising the following steps: I. preparation of a cationic vinyl oligomer by solution or bulk polymerization of components: i) 2 to 50 wt % of vinyl monomers bearing amine functional groups selected from the group consisting of non-ionic amine functional groups (a), permanent quaternary ammonium functional groups (b), neutralized amine functional groups (c) and mixtures thereof; and ii) 20 to 98 wt % of Ci to Ci8 alkyl (meth)acrylates; and II. dispersion of the cationic vinyl oligomer in an aqueous medium and neutralization of non-ionic amine functional groups.
    Type: Grant
    Filed: June 24, 2008
    Date of Patent: May 3, 2011
    Assignee: DSM IP Assets B.V.
    Inventors: Jurgen Scheerder, Emilio Martin, Gerardus Cornelis Overbeek
  • Patent number: 7932328
    Abstract: A product comprising a cold water soluble film wherein: a) the film comprises a copolymer of vinyl alcohol (VOH) with a minor amount of 2-acrylamido-2-methyl propane sulfonic acid in free acid form or as a salt of the free acid (AMPS); and b) the film has a harsh chemical dissolution time of less than about 80 seconds measured by the harsh chemical dissolution test method after 8 weeks.
    Type: Grant
    Filed: August 11, 2010
    Date of Patent: April 26, 2011
    Assignee: Sekisui Specialty Chemicals America, LLC
    Inventor: Richard Vicari
  • Patent number: 7932338
    Abstract: The present invention provides a polymer, an aqueous suspension of a polymer, methods for obtaining them, and fire-retardant products comprising a polymer and antimony oxide. The polymer of the invention is made of (i) at least one non-brominated monomer and (ii) at least one brominated monomer having the structure A-B-C, wherein A is a phenyl, substituted with 3-5 bromine atoms, B is a C1 to C4 alkyl, optionally substituted with 1 to 8 bromine atoms, and C is an acrylic or methacrylic group. An example of a suitable brominated monomer is penta bromo methyl acrylate. Preferable polymers have at least 20% w/w bromine. Preferable aqueous suspensions have at least 40% solid content. Fire-retardant products according to the invention comprise a polymer made of at least one bromine-containing monomer and at least one non-brominated monomer. Preferable fire-retardant products include polymers according to the invention.
    Type: Grant
    Filed: January 25, 2005
    Date of Patent: April 26, 2011
    Assignees: Bromine Compounds Ltd., B.G. Polymers A.C.A. Ltd.
    Inventor: Yifat Bareket
  • Patent number: 7932339
    Abstract: Method for producing a comb-shaped copolymer whose skeleton is of an acrylamide, acrylic acid, acryloyl aminoethanol or dimethyl acrylamide type and on which poly(N-alkyl acrylamide) or poly(N,N-5 dialkyl acrylamide lateral segments are grafted, includes (a) producing a telomer poly(N-alkyl acrylamide) or poly(N,N-dialkyl acrylamide) of formula (I) H2N—R1-Z-{CH2—C(R2) [C(?O)N(R3) (R4)]—}n—H (I) 10 by reacting in water a compound of formula (II) CH2?C(R2)—C(?O)—N(R3) (R4) (II) with a chain limiting compound of formula (III) Z-R1—NH2; (b) isolating the telomer of formula (I) obtained at a stage (a); (c) reacting in water the telomer of formula (I) obtained at stage (b) with an acid chloride of formula (IV) CH2?C(R5)—C(?O)—C1 at a molar ratio (IV)/(III) equal to or less than 10 and equal to or greater than 1 so that a macro monomer of formula (V) 20 CH2?C(R5)—C(?O)NH—R1-Z-{CH2—C(R2) [C(?O)N(R3) (R4)]—}n—H (V) is obtained; (d) isolating the macro monomer of formula (V) obtained at stage (c); (e) copolymerizing in
    Type: Grant
    Filed: May 18, 2006
    Date of Patent: April 26, 2011
    Assignees: Centre National de la Recherche Scientifique, Institut Curie, Societe d'Exploitation de Produits pour les Industries Chimiques SEPPIC
    Inventors: Olivier Braun, Paul Mallo, Jean-Louis Viovy, Jérémie Weber
  • Publication number: 20110092634
    Abstract: The present invention relates to novel polymeric microgels and to a method suitable for the preparation thereof. The novel microgels comprise cationic units.
    Type: Application
    Filed: June 12, 2008
    Publication date: April 21, 2011
    Applicant: Rhodia Operations
    Inventors: Inigo Gonzalez, David James Wilson, Mathias Destarac, Katerina Karagianni
  • Patent number: 7915323
    Abstract: The present invention relates to polymeric compositions useful in the manufacture of biocompatible medical devices. More particularly, the present invention relates to certain monoethylenically unsaturated polycarbosiloxane monomers capable of polymerization to form polymeric compositions having desirable physical characteristics useful in the manufacture of ophthalmic devices.
    Type: Grant
    Filed: July 9, 2009
    Date of Patent: March 29, 2011
    Assignee: Bausch & Lamb Incorporated
    Inventors: Alok Kumar Awasthi, Jason K. Stanbro, Jay F. Kunzler, Jeffrey G. Linhardt
  • Patent number: 7901559
    Abstract: It is intended to provide a method for easily detecting a phosphorylated peptide (protein) in a test sample by using SDS-polyacrylamide gel electrophoresis (SDS-PAGE) which has been conventionally employed in analyzing a protein; a polyacrylamide gel for electrophoresis to be used in the method; a method of producing the gel; and a synthesizing intermediate in producing the gel. The polyacrylamide gel for electrophoresis to be used in the method of the invention is characterized in that at least a part of the structure thereof has a structure represented by the following formula (I); wherein M2+represents a transition metal ion; and X represents a linker group.
    Type: Grant
    Filed: August 1, 2005
    Date of Patent: March 8, 2011
    Assignee: Nard Institute, Ltd.
    Inventors: Tohru Koike, Akihiko Kawasaki, Tatsuhiro Kobashi
  • Patent number: 7897797
    Abstract: Azidoaryl-substituted cyclooctene monomers and synthesized and used in the preparation of various copolymers. Among these copolymers are those prepared from ring-opening metathesis polymerization of cyclooctene, polyethylene glycol-substituted cyclooctene, and azidoaryl-substituted cyclooctene. These copolymers are useful in the formation of crosslinked films that reduce fouling of water purification membranes.
    Type: Grant
    Filed: April 16, 2010
    Date of Patent: March 1, 2011
    Assignees: The University of Massachusetts, The University of Texas Board of Regents
    Inventors: Todd Shannon Emrick, Kurt Breitenkamp
  • Patent number: 7879962
    Abstract: Powders or hydrophilic manufactured articles of E/CTFE and/or E/TFE thermoprocessable polymers, or of CTFE copolymers, wherein, on the surface of the powder or the manufactured article, one or more of the following hydrophilic units are present: —C(COOH)H—CH2—; —C(COOM)H—CH2—; —C(OCOOH)H—CH2—; —C(OCOOM)H—CH2—; with M=alkaline ion.
    Type: Grant
    Filed: March 21, 2006
    Date of Patent: February 1, 2011
    Assignee: Solvay Solexis S.p.A
    Inventors: Julio A. Abusleme, Gabriella Carignano
  • Patent number: 7863395
    Abstract: A method for preparing a cationic polyacrylamide composition particularly suitable for making a glyoxylated polyacrylamide composition useful as a temporary wet-strengthening agent and the composition resulting from that method, along with the use of the composition for adding temporary wet strength to paper and the resulting strengthened paper products.
    Type: Grant
    Filed: December 20, 2006
    Date of Patent: January 4, 2011
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Cornel Hagiopol, Yuping Luo, David F. Townsend, James W. Johnston
  • Publication number: 20100317816
    Abstract: Biomedical devices such as contact lenses formed from a comprising a polymerization product of a mixture comprising an ethylenically unsaturated-containing non-amphiphilic macromonomer comprising hydrophilic units or hydrophobic units derived from a living radical polymerization of one or more ethylenically unsaturated hydrophilic monomers or one or more ethylenically unsaturated hydrophobic monomers are disclosed.
    Type: Application
    Filed: June 16, 2009
    Publication date: December 16, 2010
    Applicant: Bausch & Lomb Incorporated
    Inventors: Jeffrey G. Linhardt, Jay F. Kunzler, Devon A. Shipp
  • Patent number: 7851572
    Abstract: The invention concerns the polymers obtained by the use of sulphur compounds in a process for controlled radical polymerization in water of acrylic acid and/or acrylic acid with hydrosoluble monomers. It concerns also their uses as dispersant agents or agents to aid grinding and/or co-grinding of mineral matters in aqueous suspensions, and as dispersant agents incorporated directly in aqueous formulations containing mineral matters. Finally, the invention concerns the formulations of mineral matters obtained in this manner.
    Type: Grant
    Filed: March 23, 2005
    Date of Patent: December 14, 2010
    Assignee: Coatex S.A.S.
    Inventors: Jean-Marc Suau, Christian Jacquemet