Abstract: The invention is directed to organometallic catalysts prepared by a process comprising a) combining nucleophilic group-containing particulate support material with an arylboron or arylaluminum Lewis acid compound in the presence of a Lewis base compound; b) contacting the product of a) with a trialkylaluminum compound before combining said product with a metal precursor compound capable of activation for olefin polymerization by said product a); and, c) combining the product of b) with said metal precursor compound. These catalyst compositions are suitable for addition reactions of ethylenically and acetylenically unsaturated monomers. The invention includes a polymerization process of combining or contacting olefinically unsaturated monomers with the invention catalyst composition. Use of the invention catalyst to polymerize &agr;-olefins is exemplified.
Abstract: The present invention is to offer a rubber material composition excellent in an abrasion resistance and less to cause heat by friction, and is suitably used to sealing members of rolling devises to be used with grease lubrication under severe circumstances allowing water or dusts to much exist. The rubber material composition is fabricated with carboxylated acrylonitrile-butadiene rubber.
Abstract: This invention discloses an emulsion styrene-butadiene rubber (SBR) that can be employed in manufacturing tire tread formulations that have rolling resistance and treadwear characteristics that are similar to those made with solution SBR but with improved traction characteristics. Thus, the emulsion SBR of this invention is superior in many respects for use in tire tread compounds to conventional solution SBR and conventional emulsion SBR. This invention more specifically discloses a styrene-butadiene rubber composition which is comprised of repeat units which are derived from styrene, 1,3-butadiene, and a hydroxy alkyl acrylate monomer, wherein the styrene-butadiene rubber composition has a number average molecular weight as determined by field flow fractionation which is within the range of about 50,000 to 150,000, and wherein the styrene-butadiene rubber has a light scattering to refractive index ratio which is within the range of 1.8 to 3.9.
Type:
Application
Filed:
July 25, 2001
Publication date:
May 23, 2002
Inventors:
Howard Allen Colvin, Michael Leslie Senyek
Abstract: The present invention provides an olefin/cycloolefin/alkylstyrene copolymer which is non-functionalized, functionalized, or grafted. By the functionalization of the benzylic protons of the alkylstyrene unit, the copolymer can be functionalized. The functionalized or grafted olefin/cycloolefin/alkylstyrene copolymer has good adhesion to a substrate and good compatibility with other polymers compared with the non-functionalized copolymer.
Type:
Application
Filed:
December 28, 2001
Publication date:
May 23, 2002
Applicant:
INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
Inventors:
Shu-Hua Chan, Chi-Lan Li, Ching Ting, Joung-Yei Frank Chen
Abstract: Compounds and metal complexes comprising a polycyclic, fused ring ligand or inertly substituted derivative thereof having up to 60 atoms other than hydrogen, said ligand comprising at least: (1) a cyclopentadienyl ring, (2) a 6,7,or 8 membered ring other than a 6-carbon aromatic ring, and (3) an aromatic ring, with the proviso that said 6, 7, or 8 membered ring (2), is fused to both the cyclopentadienyl ring (1), and the aromatic ring (3), polymerization catalysts, a process to prepare the novel compounds and complexes, and olefin polymerization processes using the same are disclosed.
Type:
Application
Filed:
June 12, 2001
Publication date:
May 23, 2002
Inventors:
Richard E. Campbell,, Jerzy Klosin, Ravi B. Shankar, Francis J. Timmers, Robert K. Rosen
Abstract: A process for production of diene rubber polymers wherein, during production of a diene rubber polymer by emulsion polymerization, the polymerization is initiated using a portion of the starting material and the polymerization is continued with either continuous or intermittent dropwise addition of the remainder of the starting material during the polymerization, and wherein at least ½ of the total amount of the water and of the monomer in the starting material used is added dropwise during the polymerization, and the temperature of the dropwise added water and monomer is kept to at least 20° C. below the polymerization temperature. The process can produce industrially useful diene rubber polymer latexes at a high productivity rate.
Abstract: A conjugated diene polymer is produced by continuously polymerizing a conjugated diene monomer with a catalyst consisting essentially of components (1): a lanthanoid compound, (2): an aluminoxane and (3): a halogenated organometal compound, a halogenated metal compound or a halogenated organic compound in a hydrocarbon solvent containing 5-50% by weight of an aromatic hydrocarbon to obtain a conjugated diene polymer having a ratio (Mw/Mn) of weight average molecular weight (Mw) to number average molecular weight (Mn) of not more than 4.
Abstract: The present invention relates to a metal-free cyclopentadienide compound which, in conjunction with a metallocene, is able to form a catalyst system that can be used for the polymerization of olefins. It is thus possible to dispense with the use of methylaluminoxane (MAO) or boron-containing compounds as co-catalyst and nevertheless achieve a high degree of catalytic activity. The invention relates also to a process for the preparation of the metal-free cyclopentadienide compound and to the use thereof as a catalyst component in the preparation of polyolefins.
Abstract: A catalyst composition comprising (a) an iron-containing compound, (b) an organomagnesium compound and (c) a dihydrocarbyl hydrogen phosphite is disclosed for polymerizing 1,3-butadiene into syndiotactic 1,2-polybutadiene. The use of the catalyst composition of this disclosure avoids the use of environmentally detrimental components such as carbon disulfide and halogenated solvents. The melting temperature of the syndiotactic 1,2-polybutadiene can be varied from about 100 to about 190° C. by variations in the catalyst components and the component ratios. The ability to vary the melting temperature with a single catalyst composition is very desirable. The syndiotactic 1,2-polybutadiene can be used as a plastic or as an additive for rubber compositions wherein it can crosslink with conventional rubbers using conventional crosslinking agents.
Abstract: A process for the reaction of an organic compound in the presence of a catalyst comprising, as active metal, ruthenium alone or together with at least one Group Ib, VIIb, or VIIIb metal in an amount of from 0.01 to 30 wt %, based on the total weight of the catalyst, applied to a support, wherein from 10 to 50% of the pore volume of the support comprises macropores having a pore diameter in the range of from 50 nm to 10,000 nm and from 50 to 90% of the pore volume of the support comprises mesopores having a pore diameter in the range of from 2 to 50 nm, the sum of said pore volumes being 100%, and said catalyst as such.
Type:
Grant
Filed:
November 30, 2000
Date of Patent:
May 14, 2002
Assignee:
BASF Aktiengesellschaft
Inventors:
Thomas Rühl, Boris Breitscheidel, Jochem Henkelmann, Andreas Henne, Rolf Lebkücher, Konrad Knoll, Paul Naegele, Hermann Gausepohl, Sabine Weiguny, Norbert Niessner
Abstract: The invention provides olefin polymerization catalyst exhibiting excellent polymerization activities, a process for olefin polymerization using the catalyst, a novel transition metal compound useful for the catalyst, and an &agr;-olefin/conjugated diene copolymer having specific properties. The olefin polymerization catalyst of the invention comprises (A) a transition metal compound of formula (I) or (II), and (B) an organometallic compound, an oranoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compound of the invention is a compound of formula (I) wherein M is a transition meal atom of Group 3 or 4 of the periodic table; m is an integer of 1 to 3; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc.
Abstract: The present invention is directed, in part, to improved polymer compositions and processes for preparing same. Specifically, in one embodiment, there is provided a process for preparing a polymer, wherein the process comprises: providing a reaction mixture comprising a portion of at least one polar monomer and at least one multivalent cation; adding the remaining portion of the polar monomer to the reaction mixture; and polymerizing the monomer to form the polymer. In certain embodiments, the reaction mixture in the providing step comprises at least two molar equivalents or greater of the total amount of polar monomer with respect to one molar equivalent of multivalent cation.
Abstract: A process for producing polymer in a gas phase reactor by introducing a stream of monomer and gas into a polymerization zone while providing at least one liquid component in the polymerization zone.
Type:
Grant
Filed:
April 5, 2000
Date of Patent:
May 7, 2002
Assignee:
Union Carbide Chemicals & Plastics Technology
Corporation
Inventors:
Robert Joseph Noel Bernier, Robert Lorenz Boysen, Robert Cecil Brown, Mark Gregory Goode, John Henry Moorhouse, Robert Darrell Olson, Leonard Sebastian Scarola, Thomas Edward Spriggs, Duan-Fan Wang, Gary Harry Williams, Kevin Joseph Cann, Maria Angelica Apecetche, Natarajan Muruganandam, Gregory George Smith
Abstract: The invention relates to new catalysts based on compounds of the rare earth metals containing a compound of the rare earth metals, a cyclopentadiene, and an alumoxane, as well as the use of new catalysts for the polymerisation of unsaturated compounds, particularly conjugated dienes. With the new catalyst system it is possible in the polymerisation of conjugated dienes to obtain a substantially higher proportion of laterally bound vinyl groups in the polymers.
Abstract: A method is provided to monitor, detect and correct local defluidization and channeling in fluidized-bed reactors for polymerization of olefin and/or diolefin polymers. The detection is preferably conducted by (i) continuously and/or intermittently comparing a signal which is a function of the currently measured fluidization bulk density with a signal which is a function of the time-averaged baselines of fluidized bulk density.
Type:
Grant
Filed:
May 16, 2000
Date of Patent:
May 7, 2002
Assignee:
Union Carbide Chemicals & Plastics Technology
Corporation
Inventors:
Ping Cai, Ivan Jeremy Hartley, Kiu Hee Lee, Lance Lyle Jacobsen
Abstract: The present invention provides a process for preparing a branched diene elastomer having a high proporation of starred chains comprising anionically polymerizing at least one conjugated diene monomer having 4 to 12 carbons in a polymerization medium comprising a hydrocarbon solvent, such as cyclohexane, and an organometallic initiator, such as n-butyllithium, wherein tris-(2,4-di-tert-butylphenyl)phosphite is added to the polymerization medium as a starring agent during or at the end of polymerization in an amount such that the molar ratio of the starring agent to the initiator is between 0.1 and 1.5, preferably between 0.2 and 0.5. The process produces a branched diene elastomer having a high proportion of starred chains. The elastomer can be a homopolymer, such as polybutadiene or polyisoprene or a copolymer, such as polystyrene/polybutadiene.
Abstract: An objective of the invention is to provide a conjugated diene-based rubber having a specific composition and a method of producing the same, an oil extended rubber using the same, as well as a rubber composition capable of being converted into a vulcanized rubber which has a low rolling resistance, an excellent wearing resistance and the like, and is useful, for example, as a tire or the like. A conjugated diene-based rubber in the invention has a glass transition point of −60 to 0° C., an olefinically unsaturated nitrile monomer unit randomly contains in its molecular chain, its repeating units consists of 9 to 30% by mass of an olefinically unsaturated nitrile monomer unit such as acrylonitrile, 10 to 50% by mass of an aromatic vinyl monomer unit such as styrene and 20 to 81% by mass of a conjugated diene monomer unit such as 1,3-butadiene, and its Mooney viscosity [ML1+4(100° C.)] is 20 to 200.
Abstract: Organosilicon compounds of general formula (I)
R1R2R3Si—R4—S—Zn—S—R4—SiR1R2R3 (I)
wherein
R1, R2, R independently, represent H, a halogen, alkyl or alkoxy and R4 represents an alkylidene group, their preparation and their use in rubber mixtures.
Type:
Grant
Filed:
October 20, 2000
Date of Patent:
April 30, 2002
Assignee:
Degussa-Huls AG
Inventors:
Hans-Detlef Luginsland, Christoph Batz-Sohn, Jörg Münzenberg, Gerd Rainhard Zezulka
Abstract: A catalyst system and a method for preparing polymers using the catalyst system is provided. The catalyst system includes a complex represented by the formula: [MLy(HSR)ñ]n, wherein M is a transition metal cation preferably in a lower oxidation state, L is a ligand, Y is a whole number between 0 and 5, ñ is a whole number between 1 and 6, n is the charge of the complex (preferably between −4 to 3), H is Hydrogen, S is sulphur and R is an organic group or hydrogen. The catalyst system advantageously has high hydrolytic stability which allows it to be used in a variety of polymerization systems including mass, solution, suspension and emulsion. In many cases only a small amount of the catalyst is required to promote polymerization.
Abstract: The process and catalyst system of this invention can be utilized to synthesize a highly random styrene-butadiene rubber having a high trans content by solution polymerization. The styrene-butadiene rubber made by the process of this invention can be utilized in tire tread rubbers that exhibit improved wear characteristics. This invention more specifically reveals a catalyst system for use in isothermal polymerizations which consists essentially of (a) an organolithium compound, (b) a calcium alkoxide and (c) a lithium alkoxide. The subject invention further discloses a process for synthesizing a random styrene-butadiene rubber having a low vinyl content by a process which comprises copolymerizing styrene and 1,3-butadiene under isothermal conditions in an organic solvent in the presence of a catalyst system which consists essentially of (a) an organolithium compound, (b) a calcium alkoxide and (c) a lithium alkoxide.
Type:
Application
Filed:
November 7, 2001
Publication date:
April 18, 2002
Applicant:
The Goodyear Tire & Rubber Company
Inventors:
Adel Farhan Halasa, Wen-Liang Hsu, John Robert Zuppo
Abstract: An objective of the invention is to provide a conjugated diene-based rubber having a specific composition and an oil extended rubber using the same, as well as a rubber composition capable of being converted into a vulcanized rubber which has a low rolling resistance, an excellent wearing resistance and the like, and is useful for a tire or the like. A conjugated diene-based rubber in the invention has repeating units consisting of 1 to 30% by mass of an olefinically unsaturated nitrile monomer unit such as acrylonitrile, 10 to 50% by mass of an aromatic vinyl monomer unit such as styrene, 19.9 to 88.9% by mass of a conjugated diene monomer unit such as 1,3-butadiene and 0.1 to 10% by mass of a monomer unit having one polymerizable unsaturated group and at least one functional group selected from the group consisting of an amino group, a hydroxyl group, an epoxy group, a carboxyl group and an alkoxysilyl group, and has a specific glass transition point and a Mooney viscosity [ML1+4(100° C.
Abstract: A method for preparing polybutadiene having controlled molecular weight and high 1,4-cis content over 95% in the presence of a diethylzinc compound as a cocatalyst (i.e., alkylating agent) and molecular-weight-controlling agent, in which the molecular weight of the polybutadiene is controlled by variating the added amount of the diethylzinc compound without deterioration of 1,4-cis content nor polymerization yield, thus guaranteeing the optimum processability and physical properties of polymer according to the use purpose.
Type:
Application
Filed:
June 14, 2001
Publication date:
April 18, 2002
Inventors:
Young-Chan Jang, Pil-Sung Kim, Gwang-Hoon Kwag, A-Ju Kim, Seung-Hwon Lee
Abstract: This invention discloses a process for synthesizing random styrene-butadiene rubber comprising: (1) continuously charging 1,3-butadiene, styrene, an initiator, and a solvent into a first polymerization zone, (2) allowing the 1,3-butadiene and styrene to copolymerize in the first polymerization zone to total conversion of 60 to 90 percent to produce a polymer cement containing living styrene-butadiene chains, (3) continuously charging the polymer cement containing living styrene-butadiene chains and additional 1,3-butadiene monomer into a second polymerization zone, wherein from 20 to 40 percent of the total amount of 1,3-butadiene changed is charged into the second polymerization zone, (4) allowing the copolymerization to continue in the second polymerization zone to a conversion of the 1,3-butadiene monomer of at least 90 percent, wherein the total conversion of styrene and 1,3-butadiene in the second polymerization zone is limited to a maximum of 95 percent, (5) withdrawing a polymer cement of random styren
Type:
Grant
Filed:
July 18, 2000
Date of Patent:
April 16, 2002
Assignee:
The Goodyear Tire & Rubber Company
Inventors:
Michael Lester Kerns, Zhengfang Xu, Scott McDowell Christian
Abstract: Amorphous polymers, including homopolymers and co-polymers, containing residues of vinyl cyclohexane and/or substituted vinyl cyclohexane are described. The polymers of the present invention have a syndiotactic configuration in which the quantity of diads is greater than 50.1% and less than 74%. The polymers of the invention have high transparency, low birefringence and high heat defection temperature, and can be used to prepare molded articles (e.g., optical data storage media and lenses) and films.
Type:
Grant
Filed:
August 8, 2000
Date of Patent:
April 2, 2002
Assignee:
Bayer Aktiengesellschaft
Inventors:
Volker Wege, Ralf Dujardin, Yun Chen, Johann Rechner, Friedrich-Karl Bruder
Abstract: An improved catalyst composition for addition polymerizations comprising: (A) a Group 4 metal complex the includes an anionic, polycyclic, fused ring ligand system containing at least 4 fused rings, and bonded to M by means of delocalized &pgr;-electrons, (B) a cocatalyst, and (C) a C4-5 conjugated diene.
Type:
Application
Filed:
September 17, 2001
Publication date:
March 28, 2002
Inventors:
Daniel J. Arriola, Marilyn Bokota, Francis J. Timmers
Abstract: A process for making an allylic copolymer is disclosed. The process is a free radical copolymerization of a mono-ethylenic monomer, a multi-ethylenic monomer, and a mono-allylic monomer. The copolymer produced has a high molecular weight and a broad molecular weight distribution, and it is particularly useful as a toner resin.
Abstract: An oil extended rubber comprising 100 parts by weight of (A) an amino group-containing copolymer rubber of a conjugated diolefin and an aromatic vinyl compound which contains bonded amino groups in the amount of 0.0025-0.20 mmol/g polymer, and 10-100 parts by weight of (B) an extensible oil. Carbon black, silica, a mixture of carbon black and silica, or a carbon-silica dual-phase-filler can be homogeneously dispersed in the oil extended rubber. Vulcanized products obtained by vulcanizing the rubber exhibits well-balanced improved properties such as wet skid properties, low hysteresis loss properties, abrasion resistance, and breaking strength, and are useful as a tread material for low fuel consumption tires, large tires, and high performance tires.
Abstract: The invention relates to a process for the preparation of polybutadienes with a reduced solution viscosity/Mooney viscosity ratio by using polydienyl compounds, the polybutadienes which can be prepared in this process, the use of the polybutadienes according to the present invention for the preparation of rubber mixtures, the use of the rubber mixtures for the production of all types of shaped articles, and the compound dimethyldi-2,4-pentadienyl-(E,E)-silane as an intermediate product.
Abstract: The invention provides solid supported anionic catalysts, suitable for gas phase anionic polymerization of conjugated diene monomers, that are useful for anionically producing very high molecular weight branched diene polymers, such as styrene butadiene rubber, polybutadiene rubber, polyisoprene rubber, and the like. The catalysts comprise a metalatable particle, such as a bound rubber, a thermoplastic polymer or a cured elastomer, that is multiply metalated with Group IA alkali metal atoms. The multi-branched diene polymers obtained by gas phase anionic polymerization employing the catalysts exhibit desirable properties, such as an extremely high molecular weight, a controlled molecular weight distribution, Tg and vinyl content, and the ability to readily absorb hydrocarbon solvents and oils. The polymers are easily compounded to form vulcanizable elastomeric compounds and articles, such as tires, that have excellent resistance to wear and tear and exhibit reduced hysteresis properties.
Type:
Grant
Filed:
November 23, 1999
Date of Patent:
March 19, 2002
Assignee:
Bridgestone Corporation
Inventors:
William M. Cole, William L. Hergenrother, Theodore J. Knutson, Georg G. A. Böhm
Abstract: A process for manufacturing an adsorbent for reducing the concentration of fibrinogen and/or fibrin in blood or blood plasma in which a carrier material, which is preferably a copolymer derived from (meth)acrylates and or (meth)acrylic acid amides, is activated by amination, and subsequently undergoes thermal treatment at a temperature of over 100° C. An adsorber for the purpose of reducing the concentration of fibrinogen and/or fibrin in blood or blood plasma may be produced from the adsorbent.
Type:
Application
Filed:
March 9, 2001
Publication date:
March 7, 2002
Inventors:
Hans-Peter Leinenbach, Heike Mitschulat, Wolfgang Metzger, Veit Otto, Martin Hepper
Abstract: Star polymers obtainable by polymerization of vinylaromatic monomers with a branching monomer unit containing at least two vinylaromatic functional radicals in the presence of a catalyst obtainable from A) a transition-metal complex from sub-group II to VIII, B) a cation-forming agent and C), if desired, an aluminum compound.
Abstract: The present invention relates to compounds in which a transition metal is complexed with two ligand systems and the two systems are reversibly connected to one another by at least one bridge consisting of a donor and an acceptor. The resultant co-ordination bond between the donor atom and the acceptor atom produces a positive (partial) charge in the donor group and a negative (partial)charge in the acceptor group:
The invention also relates to the use of these supported catalysts with a donor-acceptor interaction as polymerization catalysts.
Abstract: A process for making an allylic copolymer is disclosed. The process is a free radical copolymerization of a mono-ethylenic monomer, a multi-ethylenic monomer, and a mono-allylic monomer. The copolymer produced has a high molecular weight and a broad molecular weight distribution, and it is particularly useful as a toner resin.
Abstract: Disclosed is a method of preparing a stable composition of radically copolymerizable monomers, said composition containing firstly at least one monomer which has at least one urea function in its formula and secondly at least one monomer which does not have an isocyanate function in its formula, said method comprising preparing said monomer(s) having urea function(s) by reaction of two types of reagent: at least one radically copolymerizable monomer which has at least one isocyanate function in its formula with at least one amine selected from primary and secondary amines, and incorporating said monomer(s) which does(do) not have an isocyanate function in its(their) formula, prior to said reaction, together with one of said reagents, before adding the other of said reagents, and/or during the addition of said reagents, and/or after said reaction.
Abstract: The invention concerns a method for preparation of a liquid polymer composition, where ethylenically unsaturated monomers are polymerized by means of initiators that have a transferable atomic group, and one or more catalysts that contain at least one transition metal, in the presence of ligands that can form a coordination compound with the metallic catalysts, the catalyst is oxidized after the polymerization and then the catalyst is separated by filtration, where the composition contains a solvent with a dielectric constant less than or equal to 4.
Type:
Grant
Filed:
November 30, 1999
Date of Patent:
February 19, 2002
Assignee:
RohMax Additives GmbH
Inventors:
Sebastian Roos, Boris Eisenberg, Michael Mueller
Abstract: A catalyst composition that is the combination of or the reaction product of ingredients including (a) a molybdenum-containing compound, (b) a hydrogen phosphite, and (c) a blend of two or more sterically distinct organoaluminum compounds. This catalyst composition is particularly useful for polymerizing conjugated dienes. When this catalyst composition is used to polymerize 1,3-butadiene into syndiotactic 1,2-polybutadiene, the ratio of the organoaluminum compounds can be adjusted to vary the melting temperature and molecular weight of the polymer product.
Abstract: The present invention pertains to a substantially linear olefin polymer which has long chain branches, a high melt flow ratio, a narrow molecular weight distribution and critical shear rate at onset of surface melt fracture of a least 50 percent greater than the critical shear rate at the onset of melt fracture which is substantially higher than that of a linear olefin polymer having about the same molecular weight and molecular weight distribution. The novel polymer is an interpolymer of ethylene with at least one C3-C20 alpha-olefin and at least one unsaturated monomer.
Type:
Grant
Filed:
April 22, 1997
Date of Patent:
February 19, 2002
Assignee:
The Dow Chemical Company
Inventors:
Shih-Yaw Lai, John R. Wilson, George W. Knight, James C. Stevens
Abstract: A method for catalytic polymerization of alpha-olefin monomers using an ultra-high activity non-metallocene pre-catalyst featuring an amine bis(phenolate) ligand-metal chelate, having general formulas of [{(O)1R1R2R3R4(C6)1(CH2)1(RnY—T)N(CH2)2(C6)2R5R6R7R8(O)2}MX1X2] and [{(O)1R1R2R3R4(C6)1(CH2)1(RnY—T)N(CH2)2(C6)2R5R6R7R8(O)2}MX3], where, M, O, and N, are metal, oxygen, and, nitrogen; X1, X2, and X3, are ligands bonded to M; R1 through R8 are radicals; (RnY—T) is an optional non-donor or donor group bonded to N. The relatively stable and simply synthesized pre-catalyst is activated by a co-catalyst under mild reaction conditions, producing exceptionally reactive polymerization of a wide variety of alpha-olefin monomers, and forming a variety of poly(alpha-olefin) products, having high molecular weight and low molecular weight distribution (PDIs close to 1).
Type:
Application
Filed:
July 13, 2001
Publication date:
February 14, 2002
Applicant:
RAMOT UNIVERSITY AUTHORITY FOR APPLIED RESEARCH
Inventors:
Moshe Kol, Edit Y. Tshuva, Zeev Goldschmidt
Abstract: A process for making an allylic copolymer is disclosed. The process is a free radical copolymerization of a mono-ethylenic monomer, a multi-ethylenic monomer, and a mono-allylic monomer. The copolymer produced has a high molecular weight and a broad molecular weight distribution, and it is particularly useful as a toner resin.
Abstract: Disclosed is a process of controlling the degree of branch of high 1,4-cis polybutadiene without any alternation in the 1,4-cis content and the polymerization yield, in which a dialkylzinc compound represented by the following formula I is added in a controlled amount as an agent for controlling the degree of branch of high 1,4-cis polybutadiene, thus guaranteeing the optimum processability and physical properties of polymer according to the use purpose.
Type:
Application
Filed:
March 27, 2001
Publication date:
February 7, 2002
Inventors:
Young-Chan Jang, Pil-Sung Kim, Gwang-Hoon Kwag, A-Ju Kim, Seung-Hwon Lee
Abstract: This invention relates to a process for the production of polydienes having controlled Mooney viscosity, carried out by means of catalysts based on rare earth compounds, which is characterized in that the conjugated dienes used are polymerized in the presence of from 0.005 to 80 wt. % of 1,2-dienes, based on the sum of conjugated dienes used and of 1,2-dienes used. The polydienes thus produced are used particularly in the manufacture of car tires.
Abstract: The invention relates to a process and a device that are suitable for the preparation of a polymer based on an olefinic monomer and optionally one or more comonomers that are copolymerisable therewith, in a horizontal reactor, divided into at least two zones and fitted with a stirring mechanism, which is operated under subfluidization conditions, the polymer formed being discharged from the reactor separately from other reactor effluent, it being possible to vary the composition of the overall feed to be supplied to a zone between two zones at least and the reactor effluent separated from polymer leaving the reactor as a single stream, at least part of this stream being returned to the reactor as feed after one or more separating steps.
Type:
Application
Filed:
April 12, 2001
Publication date:
January 31, 2002
Inventors:
Leo Smit, Frits P. Moens, Stanislaus M. P. Mutsers
Abstract: The co-polymerization reaction of one or more olefin monomers, such as propylene, with &agr;,&ohgr;-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99.999 weight percent of olefins and from 0.001 to 2.000 weight percent of &agr;,&ohgr;-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature in the range from 115° C. to 135° C. and a melt flow rate in the range from 0.1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations.
Type:
Application
Filed:
February 20, 2001
Publication date:
January 31, 2002
Inventors:
Pawan Kumar Agarwal, Weiqing Weng, Aspy K. Mehta, Armenag H. Dekmezian, Main Chang, Rajan K. Chudgar, Christopher R. Davey, Charlie Y. Lin, Michael C. Chen, Galen C. Richeson
Abstract: The present invention provides a process for preparing a branched diene elastomer having a high proporation of starred chains comprising anionically polymerizing at least one conjugated diene monomer having 4 to 12 carbons in a polymerization medium comprising a hydrocarbon solvent, such as cyclohexane, and an organometallic initiator, such as n-butyllithium, wherein tris-(2,4-di-tert-butylphenyl)phosphite is added to the polymerization medium as a starring agent during or at the end of polymerization in an amount such that the molar ratio of the starring agent to the initiator is between 0.1 and 1.5, preferably between 0.2 and 0.5. The process produces a branched diene elastomer having a high proportion of starred chains. The elastomer can be a homopolymer, such as polybutadiene or polyisoprene or a copolymer, such as polystyrene/polybutadiene.
Abstract: An object of the present invention is to provide a novel poly(cyclic conjugated diene) and a process for producing the same; and a modifying product, a hydrogenated product, and a poly(cyclic conjugated diene) comprising phenylene thereof.
Type:
Application
Filed:
May 6, 1999
Publication date:
January 17, 2002
Inventors:
MITSURU NAKANO, ARIMITSU USUKI, QING YAO
Abstract: This invention relates to olefin polymerization processes suitable for limiting or eliminating aromatic solvents or diluents. The invention processes can be conducted by contacting polymerizable olefin monomers with catalyst complexes of Group 3-11 metal cations and noncoordinating or weakly coordinating anions bound directly to the surfaces of finely divided substrate particles or to polymer chains capable of effective suspension or solvation in polymerization solvents or diluents under polymerization conditions. These processes minimize problems associated with using largely insoluble organometallic or organometalloid catalysts and cocatalysts in aliphatic, solution, or diluent polymerization processes.
Abstract: This invention relates to olefin polymers particularly suited to satisfying the dielectric properties required in electrical device use. The olefin polymers can be prepared by contacting polymerizable olefin monomers with catalyst complexes of Group 3-11 metal cations and noncoordinating or weakly coordinating anion compounds bound directly to the surfaces of finely divided substrate particles or to polymer chains capable of effective suspension or solvation in polymerization solvents or diluents under solution polymerization conditions. Thus, the invention includes polyolefin products prepared by the invention processes, particularly ethylene-containing copolymers, having insignificant levels of mobile, negatively charged particles as detectable by Time of Flight SIMS.
Abstract: Disclosed is a low modulus of elasticity-rubber composition, which is useful for sealing a telecommunication cable closure even in low temperature range, utilizing an ethylene-propylene-diene rubber. Said low modulus of elasticity-rubber composition comprising (1) an ethylene-propylene-diene rubber [Mooney viscosity (100° C.): 90 to 130° C., diene: ethylidenenorbornene, iodine value: not more than 20, ethylene content: not more than 55% based on the total amount of ethylene and propylene] and (2) a softener [pour point: not more than −40° C.
Abstract: Maghnia or Mostaganem bentonites, are activated by contacting the Maghnia or Mostaganem bentonite with an acid solution of selected concentration and then drying the Maghnia or Mostaganem bentonite to form an activated bentonite catalyst. This activated bentonite catalyst may be used to polymerize a vinyl, acrylic, cyclic ether, aldehyde, lactone or olefin monomer. In a further embodiment, a perflourinated amine or diamine is synthesized by contacting a Maghnia or Mostaganem bentonite with an acid solution of selected concentration, drying the Maghnia or Mostaganem bentonite, and absorbing a secondary amine with the Maghnia or Mostaganem bentonite to form a perflouroamide iodide salt. The perflouramide idodide salt can then be extracted with a polar solvent and neutralized by the use of a basic solution.
Abstract: Ethylene copolymers with octene and/or ethylene terpolymers with alpha-olefins from 3 to 12 carbon atoms, optionally in the presence of other comonomers containing more than one unsaturation, usable as additives to increase the gas oil properties at low temperatures, obtainable by polymerization of the monomers in the presence of catalysts comprising: a bis-cyclopentadienyl derivative having the general formula:
Type:
Application
Filed:
June 22, 2001
Publication date:
January 3, 2002
Applicant:
SOCIETA' ITALIANA ADDITIVI PERCARBURANTI S.R.L.