From Propylene Only Patents (Class 526/351)
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Patent number: 11795282Abstract: A polypropylene film has an excellent long-term operating reliability in a high temperature environment when used in a high-voltage capacitor, which is suitable for use in such capacitor applications and the like, and which has an excellent structural stability to heat; and a metal film-laminated film and a film capacitor including the same. The polypropylene film, wherein the relationship between the sum (E?135 (MD+TD)) of the storage moduli in the machine direction and the transverse direction of the film, as determined by solid viscoelasticity measurement at 135° C., and the sum (E?125(MD+TD)) of the storage moduli, as determined by solid viscoelasticity measurement at 125° C., satisfies formula (1): E?135(MD+TD)/E?125(MD+TD)>0.7??(1).Type: GrantFiled: August 20, 2019Date of Patent: October 24, 2023Assignee: Toray Industries, Inc.Inventors: Yasuyuki Imanishi, Masatoshi Ohkura, Yuta Nakanishi
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Patent number: 11549006Abstract: A polypropylene comprising within a range from 0.1 wt % to 4 wt % ethylene and/or C4 to C12 ?-olefin derived units, one or more clarifiers, or both; wherein the polypropylene has a flexural modulus of at least 200 kpsi (0.05 in/min ASTM D790(A)) and an Mz/Mw of at least 4. The polypropylenes may be made by combining propylene and a comonomer with a Ziegler-Natta catalyst and at least two external electron donors, wherein the concentration of the electron donors is within a range from 1 to 100 ppm. The concentration of electron donors may be decreased to control the haze level of the polypropylene, and/or the level of comonomer derived units may be controlled to reduce the haze level of the polypropylene.Type: GrantFiled: April 27, 2018Date of Patent: January 10, 2023Assignee: ExxonMobil Chemical Patents Inc.Inventors: Caitlin A. Spofford, George J. Pehlert, Anthony Poloso, Adrian G. Barry, John M. Donahue
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Patent number: 11459453Abstract: Provided is a reactor grade polypropylene suitable for injection molding applications comprising within a range from 0 wt % to 4 wt % ethylene and/or C4 to C12 ?-olefin derived units, the polypropylene produced from a single catalyst and single stage polymerization process, and having a melt flow rate (MFR, 230° C./2.16 kg) greater than 10 g/10 min, and a 1% secant flexural modulus of at least 250 kpsi (1720 MPa).Type: GrantFiled: May 9, 2018Date of Patent: October 4, 2022Assignee: ExxonMobil Chemical Patents Inc.Inventors: George J. Pehlert, David K. Brown
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Patent number: 11384231Abstract: Provided is a propylene polymer composition capable of implementing a molded article containing excellent impact resistance. Provided is a propylene polymer composition containing components (A) to (C), satisfying all of requirements (1) to (5), (A) a propylene polymer containing 90 wt % or more of a propylene structural unit; (B) an ethylene-?-olefin copolymer or hydrogenated conjugated diene polymer containing more than 10 wt % and 99 wt % or less of an ethylene structural unit; (C) a propylene block copolymer or graft copolymer containing a propylene polymer segment and an ethylene-?-olefin copolymer segment or a hydrogenated conjugated diene polymer segment; (1) an intrinsic viscosity being 0.5 dl/g or more; (2) CXIS having a number average molecular weight of 40,000 or more; (3) a ratio of the number average molecular weight of CXIS to a number average molecular weight of CXS being 0.Type: GrantFiled: July 2, 2019Date of Patent: July 12, 2022Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Kenichi Seno, Yohei Kashiwame, Kazuya Inoue
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Patent number: 11248072Abstract: The present disclosure relates to a polypropylene for injection having a high content of ultra-high molecular weight and excellent rigidity, and a method for preparing the same.Type: GrantFiled: November 1, 2018Date of Patent: February 15, 2022Inventors: Seok Hwan Kim, Hyunsup Lee, Seong Min Chae, Taejin Kim, Dae Sik Hong, Sang Jin Jeon, Hee Kwang Park
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Patent number: 11220558Abstract: A method and arrangement of producing polymer comprising polymerizing in reactor having a top zone having a generally conical shape, a middle zone in direct contact with and below said top zone having a generally cylindrical shape, a bottom zone having a generally conical shape thereby polymerizing at least one olefin, in the presence of a polymerization catalyst and fluidization gas to obtain (i) a first stream comprising fluidization gas and particles of olefin polymer, (ii) a second stream comprising fluidization gas and agglomerates of olefin polymer, (iii) a third olefin polymer product stream, —directing the first stream comprising fluidization gas and olefin polymer particles to a series of at least three cyclones connected to the fluidized bed reactor, —separating agglomerates of olefin polymer from the second stream, withdrawing from the fluidized bed polymerization reactor the third olefin polymer product stream.Type: GrantFiled: June 15, 2018Date of Patent: January 11, 2022Assignee: BOREALIS AGInventors: Vasileios Kanellopoulos, Apostolos Krallis, Klaus Nyfors, Erno Elovainio
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Patent number: 11208510Abstract: The invention relates to high purity polypropylenes and polypropylene compositions suitable for injection molding in which the polypropylene is characterized by a percentage of 2,1-insertions, relative to the total number of propylene molecules in the polymer chain, of at least 0.2%; a melting temperature Tm ranging from 140° C. to 160° C. as determined according to ISO 3146; a ratio of frequencies at fixed modulus of 1000 Pa for storage shear modulus (G?) and loss shear modulus (G?) greater than 4.7; a molecular weight distribution (MWD) of at least 2.5; a number average molecular weight (Mn) of at most 45 kg/mol and Carreau-Yasuda parameters ?0, b and ? complying with the relationship: 2.18?1.715(b)?0.015(Ln ?0)2+0.944(b)2+0.0149(Ln ?0)(Ln ?)+0.0095(Ln ?)2>1 when fitted to the CY equation, said CY parameters ?0, b and ? are determined from a dynamic rheology analysis (RDA).Type: GrantFiled: January 12, 2018Date of Patent: December 28, 2021Assignee: Total Research & Technology FeluyInventors: Alain Standaert, Davy Francois, Geoffroy Terlinden
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Patent number: 11104783Abstract: A process to prepare a polypropylene, and the polypropylene and films therefrom, comprising combining a high melt strength polypropylene comprising at least 50 mol % propylene, and having a molecular weight distribution (Mw/Mn) greater than 6, a branching index (g?vis) of at least 0.95, and a melt strength of at least 20 cN determined using an extensional rheometer at 190° C., and within the range from 20 to 1000 ppm of a long half-life organic peroxide, and isolating the polypropylene, wherein the polypropylene thus formed has a molecular weight distribution (Mw/Mn) within a range of from 7 to 22, a z-average molecular weight of less than 1,600,000 g/mole, a branching index (g?vis) of at least 0.95; and a melt strength less than 20 cN.Type: GrantFiled: September 16, 2016Date of Patent: August 31, 2021Assignee: ExxonMobil Chemical Patents Inc.Inventors: George J. Pehlert, Stefan B. Ohlsson, Edward F. Allen, Jr., Juliet B. Wagner, Edward Y. Bylina
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Patent number: 10138335Abstract: Injection molded article for healthcare applications based on propylene homopolymer having a melt flow rate in the range of 40 to 120 g/10 min, a pentad isotacticity of more than 92.5%, and meso sequence length of 91.0 to 160.Type: GrantFiled: November 17, 2015Date of Patent: November 27, 2018Assignee: Borealis AGInventors: Klaus Bernreitner, Martina Sandholzer, James Stern, Joanne Belshaw
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Patent number: 10066066Abstract: The invention relates to a multilayer blown film for producing labels, having a layer construction formed by coextrusion. In accordance with the invention, the layer construction comprises two outer layers of polyethylene, a core layer of polyethylene, and, on either side of the core layer, an interlayer of polypropylene with a melt flow index of more than 4.0 g/10 min as measured to ISO 1133 at 230° C. with 2.16 kg.Type: GrantFiled: March 16, 2015Date of Patent: September 4, 2018Assignee: MONDI GRONAU GMBHInventors: Norbert Denis, Christian Kuckertz, Ralf Niepelt
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Patent number: 9969820Abstract: Films or sheets of polypropylene, particularly biaxially oriented polypropylene (BOPP) films, exhibiting excellent physical and mechanical properties combined with good processing characteristics can be prepared from propylene polymers prepared in the presence of Ziegler-Natta catalysts comprising a succinate and a diether compound.Type: GrantFiled: June 21, 2012Date of Patent: May 15, 2018Assignee: Basell Poliolefine Italia S.r.l.Inventors: Monica Galvan, Roberto Pantaleoni, Ofelia Fusco, Benedetta Gaddi, Andreas Neumann, Antonio Mazzucco, Gianni Collina
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Patent number: 9765162Abstract: Disclosed are an apparatus and a method for removing halogens generated during the preparation of polybutene, which are capable of improving the utilization of polybutene and light polymers by removing halogen components contained in the polybutene and the light polymers. The method for removing halogens generated during the preparation of polybutene comprises the steps of: preparing a reaction product by supplying a catalyst and a reaction raw material to a reactor and polymerizing; removing a catalyst component from the reaction product and neutralizing; separating the reaction product into an organic compound and impurities comprising the catalyst component; heating the organic compound to distill an unreacted material; and removing a halogen component in a remaining polymerization mixture after the distillation using a halogen removing catalyst, or removing a halogen component in polybutene and light polymers obtained from the polymerization mixture using the halogen removing catalyst.Type: GrantFiled: August 28, 2014Date of Patent: September 19, 2017Assignee: DAELIM INDUSTRIAL CO., LTD.Inventors: Myeong Seok Kim, Min Sup Park, Hyung Jae Seo, Se Hyun Lee
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Patent number: 9586357Abstract: A consumable material for use in an extrusion-based digital manufacturing system, the consumable material comprising a length and a cross-sectional profile of at least a portion of the length that is axially asymmetric. The cross-sectional profile is configured to provide a response time with a non-cylindrical liquefier of the extrusion-based digital manufacturing system that is faster than a response time achievable with a cylindrical filament in a cylindrical liquefier for a same thermally limited, maximum volumetric flow rate.Type: GrantFiled: June 22, 2012Date of Patent: March 7, 2017Assignee: Stratasys, Inc.Inventors: J. Samuel Batchelder, William J. Swanson, S. Scott Crump
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Patent number: 9587334Abstract: Provided is a non-woven fabric produced by using a polypropylene-based resin composition containing a specific low-crystalline polypropylene. The non-woven fabric is a non-woven fabric obtained by achieving reductions in denier values of fibers, the non-woven fabric being excellent in dispersibility of the fibers.Type: GrantFiled: January 20, 2011Date of Patent: March 7, 2017Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Tomoaki Takebe, Yutaka Minami, Yohei Koori
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Patent number: 9550132Abstract: The present invention relates to a process for treating polyolefin granules in a treatment vessel comprising the steps of: —Providing a bed of granules in liquid in said treatment vessel —Withdrawing a first stream of liquid from said treatment vessel, wherein said first stream of liquid contains hydrocarboneous compounds —introducing a first stream of vapor into said treatment vessel —Withdrawing a second stream of vapor from said treatment vessel wherein said second stream of vapor contains volatile hydrocarboneous compounds —Recovering the granules from said treatment vessel wherein said first stream of vapor has a temperature from Tb to Tb+10° C., wherein Tb is the boiling point of the liquid at the applied pressure, and said first stream of vapor produces an upwards rising vapor stream in said treatment vessel, the superficial vapor velocity of which is no more than 0.2 m/s, and a plant suitable for conducting said process.Type: GrantFiled: November 12, 2012Date of Patent: January 24, 2017Assignee: Borealis AGInventors: Michiel Bergstra, Kai Hagane, Manfred Jarzombek, Pablo Ivan Aguayo Arellano
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Patent number: 9284388Abstract: Disclosed herein is a method comprising masticating a molten polymer; where the polymer is semicrystalline polymer prior to melting; where the masticating polymer is conducted at an elevated temperature of Tm?15K to Tm+90K; where Tm is the crystalline melting point of the polymer; masticating the molten polymer while it is cooled from the elevated temperature to a temperature of Ta; where Ta is a temperature that is greater than Tc?10K, where Tc is the crystallization temperature of the polymer; and masticating the polymer at the temperature of Ta for a time period of 0.1 to 50 minutes.Type: GrantFiled: April 30, 2015Date of Patent: March 15, 2016Assignee: THE UNIVERSITY OF MASSACHUSETTSInventors: Alan J. Lesser, Brian M. Cromer, Edward B. Coughlin
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Patent number: 9169406Abstract: Embodiments of the present disclosure are directed towards coating compositions comprising from 50 to 85 percent of an aqueous dispersion based on a total weight of the coating composition, an abrasion reducing composition, a solvent, a basic water composition, and a crosslinker.Type: GrantFiled: January 8, 2013Date of Patent: October 27, 2015Assignee: Dow Global Technologies LLCInventors: Jeffrey Wilbur, Dharakumar Metla, Denise Lindenmuth, Ray Drumright, David L. Malotky, Bernhard Kainz
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Publication number: 20150148506Abstract: A gas-phase polyolefin reactor system for rapidly transitioning from one polyolefin product to another is disclosed. The reactor system comprises a control valve, a high-flow valve, a polyolefin reactor, a flow meter, a totalizer and an empirical model. During a transition, the empirical model predicts a required amount based upon an initial concentration and a selected ending concentration, the flow meter measures a flow rate, the totalizer determines a totalized amount when the flow rate of the first stream reaches the required amount based upon the measured flow rate and outputs the totalized amount to the empirical model, and the empirical model compares the required amount to the totalized amount and determines a transition endpoint. A method of rapidly transitioning the reactor system from one polyolefin product to another is also disclosed.Type: ApplicationFiled: February 4, 2015Publication date: May 28, 2015Applicant: Ineos USA, LLCInventors: Gregory Dudish, Ernest Chan
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Publication number: 20150148502Abstract: Provided is a non-cyclopentadienyl-based chromium-ligand complex, preferably a chromium-ligand complex of formula (J): LCr(RA)m(D)k (J), wherein L is a non-Cp monoanionic ligand; Cr (chromium) is in a formal oxidation state of +3 or +2; when Cr formally is Cr+3, either m is 1 and RA is hydrocarbylene (a hydrocarbylene chromium-ligand complex of formula (J)) or m is 2 and each RA independently is hydrocarbyl (a dihydrocarbyl chromium-ligand complex of formula (J)), wherein each hydrocarbyl or hydrocarbylene of RA independently is unsubstituted or substituted by from 1 to 5 RAS; each RAS independently is a neutral aprotic heteroalkyl, neutral aprotic heterocycloalkyl, neutral aprotic heteroaryl, or neutral aprotic aryl; when Cr formally is Cr+2, m is 1 and RA is hydrocarbyl (a hydrocarbyl chromium-ligand complex of formula (J)); k is an integer of 0 or 1; D is absent when k is 0 or D is a neutral ligand when k is 1; wherein the chromium-ligand complex of formula (J) is overall neutral and lacks a cyclopentadienType: ApplicationFiled: May 11, 2012Publication date: May 28, 2015Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Matthew D. Christianson, Timothy S. De Vries, Robert D. Froese, Matthias S. Ober, Jasson T. Patton, Duane R. Romer, Gordon R. Roof, Lixin Sun, Endre Szuromi, Curt N. Theriault, Dean M. Welsh, Timothy T. Wenzel, Paul H. Moran
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Publication number: 20150141605Abstract: Processes for forming propylene from methanol are disclosed. The processes involve converting methanol to a product mixture comprising ethylene and propylene, separating the ethylene from the propylene, dimerizing a first portion of the ethylene to form a product mixture comprising 1-butylene, isomerizing the 1-butylene to form a mixture of cis and trans 2-butylene, and performing olefin metathesis on a second portion of the ethylene and the mixture of cis and trans 2-butylene. In one embodiment, the methanol is produced by converting syngas to methanol, and in one aspect of this embodiment, the syngas, or a portion thereof, is produced from renewable feedstocks. In this aspect, renewable propylene is produced. The propylene can be polymerized to form polypropylene or co- or terpolymers thereof, and when the propylene is made from renewable resources, the resulting polymer is a renewable polymer.Type: ApplicationFiled: May 3, 2013Publication date: May 21, 2015Inventor: David Bradin
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Publication number: 20150140266Abstract: A biaxially stretched polypropylene film for a capacitor containing an isotactic polypropylene. The weight average molecular weight (Mw) of the isotactic polypropylene as measured by gel permeation chromatography (GPC) is 250,000 to 450,000, the molecular weight distribution Mw/Mn is 7 to 12 and Mz/Mn is 20 to 40, and the value of a difference obtained by subtracting a differential distribution value when the logarithmic molecular weight Log(M)=6 from a differential distribution value when Log(M)=4.5 on a molecular weight distribution curve thereof is 8% to 20%. The ultrathin biaxially stretched polypropylene film for a capacitor has superior heat resistance performance and withstands voltage performance.Type: ApplicationFiled: January 8, 2013Publication date: May 21, 2015Applicant: OJI Holdings CorporationInventors: Tadakazu Ishiwata, Yuichi Shishido
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Patent number: 9029284Abstract: A solid particulate catalyst free from an external carrier comprising: (i) a complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R?2C—, —R?2C—CR?2—, —R?2Si—, —R?2Si—SiR?2—, —R?2Ge—, wherein each R? is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 independently is hydrogen or a linear or branched C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms from groups 14-16 of the Periodic Table of the Elements; each R2 and R3 taken together form a 4-7 membered ring condensed to the benzene ring of the indenyl moiety, said ring optionally containing heteroatoms from groups 14-16, each atom forming said ring being optionally substituted with at least one R18 radical; each R18 is the same or different and may be a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atoType: GrantFiled: December 21, 2010Date of Patent: May 12, 2015Assignee: Borealis AGInventors: Luigi Resconi, Pascal Castro, Lauri Huhtanen
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Publication number: 20150119543Abstract: A polypropylene molded article has a crystallinity degree of 48% or more by wide-angle X-ray diffraction measurement. The half width of an orientation peak in an azimuth angular distribution obtained by wide-angle X-ray diffraction measurement on the polypropylene molded article is 5.5° or less, and the long period of the polypropylene molded article obtained by small-angle X-ray scattering measurement is 12 nm or more and 16 nm or less.Type: ApplicationFiled: October 27, 2014Publication date: April 30, 2015Inventors: MOTOHIRO SUZUKI, HIRONOBU MACHIDA, HIROMU SAITO, TSUBASA HOSOI, AKIRA YANAGIDA
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Patent number: 9018328Abstract: The invention provides a solution polymerization process comprising: A) polymerizing one or more monomers in the presence of a solvent that comprises a heavy hydrocarbon solvent and a light hydrocarbon solvent, to form a polymer solution; B) transferring the polymer solution to a Liquid-Liquid Separator, without adding heat to the solution, and wherein the pressure of the polymer solution is actively reduced in a controlled manner prior to, or within, the Liquid-Liquid Separator, to induce at least two liquid phases, a polymer-rich phase and a solvent-rich phase, and wherein the concentration of polymer in the polymer-rich phase is higher than that in the polymer solution transferred to the Liquid-Liquid Separator; and C) removing the solvent-rich phase.Type: GrantFiled: July 15, 2010Date of Patent: April 28, 2015Assignee: Dow Global Technologies LLCInventors: Prasanna K. Jog, Robert D. Swindoll, Nile A. Mead, Pradeep Jain, Alec Y. Wang, Job D. Guzman
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Publication number: 20150087031Abstract: The present invention relates to methods of processing lignocellulosic material to obtain hemicellulose sugars, cellulose sugars, lignin, cellulose and other high-value products. Also provided are hemicellulose sugars, cellulose sugars, lignin, cellulose, and other high-value products.Type: ApplicationFiled: May 3, 2013Publication date: March 26, 2015Inventors: Robert Jansen, Claire Gregoire, philip Travisano, Lee Madsen, Neta Matis, Yael Har-Tal, Shay Eliahu, James Alan Lawson, Noa Lapidot, Luke Burke, Aharon M. Eyal, Timothy Allen Bauer, Hagit Sade, Paul Mcwilliams, Ziv-Vladimir Belman, Bassem Hallac, Michael Zviely, Yelena Gershinksy, Adam Carden
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Patent number: 8987400Abstract: Polypropylene having a melting temperature (Tm) of at least 151.0° C., a melt flow rate MFR2 (230° C.) of more than 2.0 g/10 min, a xylene cold soluble fraction (XCS) of not more than 1.5 wt.-%, <2,1> regiodefects of equal or more than 0.4 mol.-% determined by 13C-spectroscopy, and a number average molecular weight (Mn) of not more than 110 kg/mol.Type: GrantFiled: December 21, 2010Date of Patent: March 24, 2015Assignee: Borealis AGInventors: Dietrich Gloger, Katja Klimke, Joachim Fiebig
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Patent number: 8986590Abstract: Provided are a polymer article excellent in mechanical strength, toughness, and stretchability and a production method of the polymer article. The polymer article of the present invention is formed of a polymer material and is a polymer blank or a formed polymer body. The polymer article of the present invention has a crystallinity of not less than 50% but less than 90% and a tensile strain at fracture of not less than 60%. A method for producing a polymer article of the present invention includes: a heating step of heating the polymer material to a temperature of not lower than (Tm?70)° C. but lower than Tm(° C.) where Tm is the melting point (° C.) of the polymer material; and a compression step of cooling the polymer material heated in the heating step and compressing the polymer material in the course of the cooling to obtain a polymer article having a crystallinity of not less than 50% but less than 90% and a tensile strain at fracture of not less than 60%.Type: GrantFiled: May 24, 2011Date of Patent: March 24, 2015Assignee: Sekisui Chemical Co., Ltd.Inventors: Hironori Tabata, Hiroyuki Hirano, Kazuho Uchida, Akira Nakasuga
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Patent number: 8981028Abstract: Copolymers, especially multi-block copolymer containing therein two or more segments or blocks differing in tacticity, are prepared by polymerizing propylene, 4-methyl-1-pentene, or another C4-8 ?-olefin in the presence of a composition comprising the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in tacticity from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.Type: GrantFiled: January 30, 2006Date of Patent: March 17, 2015Assignee: Dow Global Technologies LLCInventor: Phillip D. Hustad
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Patent number: 8975354Abstract: A polypropylene-based resin composition including 100 parts by weight of the following component (A), 18 parts by weight or more and 65 parts by weight or less of the following component (B), 6 parts by weight or more and 45 parts by weight or less of the following component (C), 25 parts by weight or more and 60 parts by weight or less of the following component (D), 0.1 part by weight or more and 6.5 parts by weight or less of the following component (E) and 0.15 part by weight or more and 5.0 parts or less by weight of the following component (F): (A) a specific propylene-ethylene block copolymer A: (B) a specific propylene-ethylene block copolymer B: (C) an ethylene-?-olefin copolymer having a melt flow rate (230° C., under the load of 2.16 kg) of 0.5 g/10 min or more and 20 g/10 min or less; (D) an inorganic filler having an average particle diameter of 1 ?m or more and 14 ?m or less; (E) an acid-modified polypropylene; and (F) a lubricant.Type: GrantFiled: January 27, 2012Date of Patent: March 10, 2015Assignee: Prime Polymer Co., Ltd.Inventors: Tatsuya Kusumoto, Yoshio Sugimoto, Mitsuru Fujisawa
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Patent number: 8957166Abstract: A method for producing a propylene-based polymer, including polymerizing propylene or propylene and an ?-olefin except propylene in the presence of a catalyst with a horizontal polymerization reactor equipped with stirring vanes rotating around a horizontal axis therein by a continuous vapor-phase polymerization, which removes heat of polymerization by heat of vaporization of a liquefied propylene, wherein the reactor can set a plurality of area sections different in temperature in a horizontal direction inside the reactor, and satisfies at least one of i) a temperature difference, ?T1=T??T?, between an area section including an upstream end of the reactor (T?) and a downstream end (T?) thereof is 0.1 to 20° C. and ii) a temperature difference, ?T2=Tx?Tz, between an area section including a catalyst feed part (Tx) and dew point (Tz) of a mix gas in the reactor is 0 to 5° C.Type: GrantFiled: October 29, 2010Date of Patent: February 17, 2015Assignee: Japan Polypropylene CorporationInventors: Yoshitaka Kobayashi, Takanori Nakashima, Kiyoshi Yukawa, Yusuke Yamada, Hajime Aoyama, Nobuhiro Iwai
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Publication number: 20150045469Abstract: An oriented polymer composition (OPC) article comprising a body having a length, which is greater than any perpendicular dimension, comprised of an OPC having a softening temperature, the body having an outer surface extending the length of the body, having polymer strands aligned in the lengthwise direction of the body, wherein the length dimension stability is greater than 99% when tested by heating the article for 24 hours at temperatures at least up to and including 71 degrees Celsius after completion of the manufacture of the article and processes for forming said article.Type: ApplicationFiled: August 6, 2014Publication date: February 12, 2015Inventors: Kevin L. Nichols, Brett M. Birchmeier
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Patent number: 8946363Abstract: Solid, particulate catalysts comprising bridged bis indenyl ?-ligands are disclosed, together with methods for the preparation and use thereof, for example, in olefin polymerization.Type: GrantFiled: April 27, 2011Date of Patent: February 3, 2015Assignee: Borealis AGInventors: Luigi Resconi, Pascal Castro, Lauri Huhtanen
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Publication number: 20150031842Abstract: A method is provided for polymerizing an olefin monomer in a reactor with a highly active polyolefin polymerization catalyst system. The method includes introducing a catalyst system comprising a catalyst and a catalyst activator into the reactor containing the olefin monomer with less than 10 seconds or no pre-contacting time of the catalyst and the catalyst activator prior to introducing the catalyst and the catalyst activator into the reactor. The catalyst system may have a standard adjusted catalyst activity of greater than 10 gPgcat?1hr?1.Type: ApplicationFiled: June 5, 2014Publication date: January 29, 2015Inventors: Todd S. Edwards, Kevin W. Lawson
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Patent number: 8937137Abstract: Catalysts comprising Salan ligands with bridged or unbridged diphenyl amine moieties. Also, catalyst systems comprising the catalyst and an activator; methods to prepare the ligands, catalysts and catalyst systems; processes to polymerize olefins using the catalysts and/or catalyst systems; and the olefin polymers prepared according to the processes.Type: GrantFiled: November 11, 2013Date of Patent: January 20, 2015Assignees: ExxonMobil Chemical Patents Inc., Ramot at Tel-Aviv University Ltd.Inventors: Matthew W. Holtcamp, Meagan E. Evans, David A. Cano, Eric D. Whetmore, Gregory S. Day, Moshe Kol
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Publication number: 20150018504Abstract: The present invention discloses an active metallocene catalyst system prepared with a hafnium-based metallocene catalyst system and an activating agent comprising an aluminoxane and a sterically hindered Lewis base.Type: ApplicationFiled: September 26, 2014Publication date: January 15, 2015Inventors: Vincenzo Busico, Roberta Cipullo, Roberta Pellecchia, Abbas Razavi
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Publication number: 20150005462Abstract: A gas-phase polyolefin reactor system for rapidly transitioning from one polyolefin product to another is disclosed. The reactor system comprises a steady-state control valve, a high-flow valve, a polyolefin reactor, a flow meter, a totalizer, an online analyzer and an empirical model. During a transition, the on-line analyzer measures an initial concentration of a reaction component, the empirical model predicts a required amount based upon the measured initial concentration and a selected ending concentration, the flow meter measures a flow rate, the totalizer determines a totalized amount when the flow rate of the first stream reaches the required amount based upon the measured flow rate and outputs the totalized amount to the empirical model, and the empirical model compares the required amount to the totalized amount and determines a transition endpoint. A method of rapidly transitioning the reactor system from one polyolefin product to another is also disclosed.Type: ApplicationFiled: June 28, 2013Publication date: January 1, 2015Applicant: Ineos USA, LLCInventors: Gregory Dudish, Ernest Chan
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Patent number: 8921466Abstract: A process of modifying propylene polymers via melt grafting of polyfunctional monomer (PFMs) involving pre-initiative step thereby facilitating perfect absorption of PFMs on polymer matrix and initiate their grafting prior to reactive extrusion without using free radical initiators so that branching can be introduced in propylene polymer matrix. The modified propylene polymers showed enhanced shear sensitivity, increase in molecular weight, broadening of molecular weight distribution and strain hardening.Type: GrantFiled: January 14, 2011Date of Patent: December 30, 2014Assignee: Reliance Industries LimitedInventors: Uma Sankar Satpathy, Shashikant, Ajit Behari Mathur
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Publication number: 20140378633Abstract: Catalysts comprising long-bridged salen ligands comprising an imino-phenylene-alkylene-imino or an imino-napthalenylene-alkylene-imino bridged salen compound. Also, catalyst systems comprising the catalyst and an activator; methods to prepare the ligands, catalysts and catalyst systems; processes to polymerize olefins using the catalysts and/or catalyst systems; and the olefin polymers prepared according to the processes.Type: ApplicationFiled: June 6, 2014Publication date: December 25, 2014Inventors: Moshe Kol, Matthew W. Holtcamp, Garth R. Giesbrecht, Gregory S. Day, Konstantin Press
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Patent number: 8916644Abstract: [Object] To provide a polypropylene resin composition for use in the formation of a microporous membrane having excellent heat resistance and strength. [Solution] A polypropylene resin composition for use in the formation of a microporous membrane according to the present invention comprises as an essential component an ultra-high-molecular-weight propylene homopolymer (A) that satisfies the following requirements (1) to (4): (1) the intrinsic viscosity [?] is 7 dl/g or more and less than 25 dl/g; (2) the mesopentad fraction ranges from 90.0% to 99.5%; (3) the melting point ranges from 153° C. to 167° C.; and (4) in an elution temperature-elution volume curve measured by temperature-rising elution fractionation (TREF), the maximum peak has a peak top temperature in the range of 116° C. to 125° C. and a half-width of 7.0° C. or less.Type: GrantFiled: January 7, 2010Date of Patent: December 23, 2014Assignees: Toray Battery Separator Film Co., Ltd, Prime Polymer Co., Ltd.Inventors: Satoshi Tamura, Ryoichi Tsunori
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Publication number: 20140370551Abstract: This disclosure provides a business method and system for generating sugars and recycling a non-biomass component from a waste stream. In some embodiments, a waste stream comprising cellulose and a non-biomass component is saccharified to produce glucose, followed by recovery of the glucose and non-biomass component, which may be recycled to another site associated with production of a cellulose-containing product that contains the non-biomass component. In certain scenarios, the waste stream is generated at a first location, cellulose pretreatment (if desired) and hydrolysis are conducted at a second location, and the non-biomass component is recycled to the first location or a third location. The non-biomass component may include metals, metal oxides, salts, organic compounds, inorganic compounds, oligomers, or polymers, for example.Type: ApplicationFiled: June 16, 2014Publication date: December 18, 2014Inventors: Theodora RETSINA, Kimberly NELSON
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Publication number: 20140364577Abstract: Solid-state shear pulverization of semi-crystalline polymers and copolymers thereof and related methods for enhanced crystallization kinetics and physical/mechanical properties.Type: ApplicationFiled: May 16, 2014Publication date: December 11, 2014Inventors: John M. Torkelson, Cynthia Pierre, Amanda Flores
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Patent number: 8901259Abstract: Heterophasic polypropylene copolymers having an MFR (2.16 kg, 230° C.) of 15 to 200 g/10 min, determined according to ISO 1133 comprising a propylene homo- or copolymer matrix with an MFR (2.16 kg, 230° C.) of 80 to 500 g/10 min, determined according to ISO 1133 (A) and an ethylene or C4-C10-alpha-olefin propylene rubber phase (B) dispersed within the matrix, wherein the heterophasic polypropylene resin has a fraction soluble in p-xylene at 25° C. (XCS), having an intrinsic viscosity of 2.85 to 4.00 dl/g, determined according to DIN EN ISO 1628-1 and -3 and being composed of propylene monomer units in an amount of 70 wt % to 90 wt %, with optimum balance of impact resistance and low amount of hexane extractables; a process for their preparation and their use.Type: GrantFiled: June 15, 2011Date of Patent: December 2, 2014Assignee: Borealis AGInventors: Klaus Bernreiter, Petar Doshev, Gregory Potter, Martina Sandholzer
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Patent number: 8901240Abstract: [Object] To provide a polypropylene resin composition for use in the formation of a microporous membrane having excellent heat resistance and low thermal shrinkage ratio. [Solution] A polypropylene resin composition for use in the formation of a microporous membrane according to the present invention comprises as an essential component a propylene homopolymer (A) that satisfies the following requirements (1) to (4) and (7): (1) the intrinsic viscosity [?] is 1 dl/g or more and less than 7 dl/g; (2) the mesopentad fraction ranges from 94.0% to 99.5%; (3) the integral elution volume during heating to 100° C. is 10% or less; (4) the melting point ranges from 153° C. to 167° C.; and (7) in an elution temperature-elution volume curve, the maximum peak has a peak top temperature in the range of 105° C. to 130° C. and a half-width of 7.0° C. or less.Type: GrantFiled: January 6, 2010Date of Patent: December 2, 2014Assignees: Mitsui Chemicals Inc., Prime Polymer Co., Ltd.Inventors: Satoshi Tamura, Keita Itakura, Ryoichi Tsunori, Satoshi Hashizume
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Publication number: 20140346107Abstract: Polymer compositions that may be used to form fibers for a fiber web are generally described. In some embodiments, certain properties of the polymer compositions (e.g., molecular weight distribution, melt flow index, melt elasticity, and/or melt toughness) may allow the formation of fiber webs having fine fibers and a relatively low amount of process defects. In some instances, these properties of the polymer composition may be achieved by combining two or more polymer components. Fiber webs formed using the polymer composition may have increased performance and/or better structural characteristics compared to fibers webs formed using a single polymer component.Type: ApplicationFiled: May 24, 2013Publication date: November 27, 2014Applicant: Hollingsworth & Vose CompanyInventors: Nagendra Anantharamaiah, William S. Freeman, Bruce Smith
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Patent number: 8895685Abstract: Polypropylene composition comprising a polypropylene base resin whereby the polypropylene base resin has a MFR (2.16 kg, 230° C., ISO 1133) of 8 to 24 g/10 min and a LAOS-NLF>2.8 whereby LAOS?NLF=|G?1/G?3| where G?1—first order Fourier Coefficient, G?3—third order Fourier Coefficient.Type: GrantFiled: January 21, 2011Date of Patent: November 25, 2014Assignee: Borealis AGInventors: Katja Klimke, Juha Yli-Peltola, Elke Pachner, Doris Machl, Hermann Braun, Susana Filipe, Anh Tuan Tran
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Patent number: 8889804Abstract: The present invention relates to a preparation method for polypropylene that comprises polymerizing a propylene monomer in the presence of a catalyst comprising a novel transition metal compound. Using the novel transition metal compound as a catalyst, the preparation method for polypropylene according to the present invention can not only acquire high catalytic activity for polymerization to achieve high efficiency of the process but allow it to easily control the fine-structure characteristics of the polymer, thereby providing polypropylene having desired properties with ease.Type: GrantFiled: April 12, 2011Date of Patent: November 18, 2014Assignee: Lotte Chemical CorporationInventors: Bun-Yeoul Lee, Ji-Hae Park, Seung-Hyun Do, Hwa-Kyu Kim, Jae-Young Park, Seung-Woong Yoon
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Patent number: 8889750Abstract: Polypropylene resin expanded particles comprises a polypropylene resin as a base material resin, the polypropylene resin having at least three melting peaks on a DSC curve for a second temperature rise measured at a heating rate of 10 g/min with use of a heat flux differential scanning calorimeter (DSC), the at least three melting peaks including (i) a lowest temperature melting peak of 100° C. to 130° C. and (ii) a highest temperature melting peak of 140° C. to 160° C., the polypropylene resin having a resin DSC ratio change rate of 0.5%/° C. to 3.0%/° C., the expanded particles having two melting peaks in a DSC measurement made at a first temperature rise at the heating rate of 10 g/min, the two melting peaks including, (i) on a lower temperature side, a melting peak temperature of 100° C. to 130° C. and, (ii) on a higher temperature side, a melting peak temperature of 140° C. to 160° C.Type: GrantFiled: February 1, 2012Date of Patent: November 18, 2014Assignee: Kaneka CorporationInventor: Kenichi Senda
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Publication number: 20140335634Abstract: A mold release film, which is adapted to be disposed on the cavity surface of a mold to form a resin-encapsulated portion by encapsulating a semiconductor element of a semiconductor device with a curable encapsulation resin, has a tensile modulus of elasticity of from 10 to 24 MPa at 132° C. as measured in accordance with JIS K 7127, and a peak peel resistance of at most 0.8 N/25 mm.Type: ApplicationFiled: July 29, 2014Publication date: November 13, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Wataru KASAI, Yoshiaki HIGUCHI, Masakazu ATAKU, Daisuke TAGUCHI, Satoshi OTSUGU
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Publication number: 20140336346Abstract: A process for producing a purified hydrocarbon stream can include contacting a hydrocarbon stream contaminated with one or more organoaluminum compounds with a chemical agent that is capable of reacting with the one or more organoaluminum compounds.Type: ApplicationFiled: January 24, 2013Publication date: November 13, 2014Inventors: Karel Eeckhout, Marc Richet
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Publication number: 20140316084Abstract: The present invention relates to a catalyst system for polymerization of propylene, process for preparing polypropylene and to polypropylene prepared by said process. The dual external donor composition of present invention has synergistic effects. It improves the efficiency of polymerization process and product properties for homo grade of polypropylene.Type: ApplicationFiled: May 8, 2012Publication date: October 23, 2014Applicant: Reliance Industries LimitedInventors: Harshad Ramdas Patil, Priyanshu Bharatkumar Vyas, Virendrakumar Gupta