From Propylene Only Patents (Class 526/351)
-
Publication number: 20130072653Abstract: The present invention relates to the degassing of polymer powder, and in particular provides an interlock for use in a process for degassing of a polymer powder in a degassing vessel, which interlock comprises: a. measuring the temperature of the vapour phase resulting from a liquid-vapour separation, which vapour phase is used as a purge gas in a degassing vessel, b. comparing said measured temperature to a threshold value, and b. in the event that the measured temperature is above the threshold value then the use of the vapour as purge gas is stopped or reduced.Type: ApplicationFiled: June 28, 2011Publication date: March 21, 2013Inventors: Jean-Louis Chamayou, Stephen Kevin Lee
-
Patent number: 8399588Abstract: The invention is a novel family of polyolefins characterized by chain-walking defects of the type that add extra backbone carbons per monomer. These polyolefins display a large decrease in crystallinity relative to polyolefins known in the art. Specifically, the reduction in crystallinity is much greater than for earlier polypropylenes with a matched content of stereo or 1-alkene type defects. The claimed polyolefins can be an alkene-based copolymer. The defects in the polyolefin backbone are generated by a chain walking mechanism in which three or more carbons per monomer are added to the polymer backbone instead of two, as in conventional polymerization or copolymerization methods of alpha olefins. The novel polyolefins can be used in applications such as plastic wrapping, thin films, co-extrusion layers or molded parts in the absence of polymer blending or copolymerization. The cost of materials production can be reduced.Type: GrantFiled: October 4, 2012Date of Patent: March 19, 2013Assignees: The Florida State University Research Foundation, Inc., Cornell University Cornell Center for Technology, Enterprise & CommercializationInventors: Rufina Alamo, Geoffrey Coates, Carolina Ruiz-Orta
-
Patent number: 8399725Abstract: This invention relates to a functionalized co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(?0.94(mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)?83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a functionalized homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making functionalized homo- or co-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.Type: GrantFiled: June 19, 2009Date of Patent: March 19, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Patrick Brant, Donna J. Crowther
-
Patent number: 8399589Abstract: The invention is a novel family of polyolefins characterized by chain-walking defects of the type that add extra backbone carbons per monomer. These polyolefins display a large decrease in crystallinity relative to polyolefins known in the art. Specifically, the reduction in crystallinity is much greater than for earlier polypropylenes with a matched content of stereo or 1-alkene type defects. The claimed polyolefins can be made by a late metal catalyst. The defects in the polyolefin backbone are generated by a chain walking mechanism in which three or more carbons per monomer are added to the polymer backbone instead of two, as in conventional polymerization or copolymerization methods of alpha olefins. The novel polyolefins can be used in applications such as plastic wrapping, thin films, co-extrusion layers or molded parts in the absence of polymer blending or copolymerization. The cost of materials production can be reduced.Type: GrantFiled: October 4, 2012Date of Patent: March 19, 2013Assignees: The Florida State University Research Foundation, Inc., Cornell University Cornell Center for Technology, Enterprise & CommercializationInventors: Rufina Alamo, Geoffrey Coates, Carolina Ruiz-Orta
-
Patent number: 8399586Abstract: A process for feeding ethylene into a polymerization system includes providing a low-pressure ethylene stream, one or more low-pressure C3 to C20 monomer streams, an optional low-pressure inert solvent/diluent stream, and one or more reactors; metering the low-pressure ethylene stream, the one or more low-pressure C3 to C20 monomer streams, and the optional low-pressure inert solvent/diluent stream; blending the metered low-pressure ethylene stream, the metered one or more low-pressure C3 to C20 monomer streams, and the metered low-pressure optional inert solvent/diluent stream to form an ethylene-carrying low-pressure blended liquid feed stream; pressurizing the ethylene-carrying low-pressure blended liquid feed stream to the polymerization system pressure with one or more high-pressure pumps to thrm an ethylene-carrying high-pressure blended reactor feed stream; and feeding the ethylene-carrying high-pressure blended reactor feed stream to the one or more reactors.Type: GrantFiled: September 3, 2009Date of Patent: March 19, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Gabor Kiss, Robert Patrick Reynolds, Jr., John W. Chu, James Richardson Lattner, Gary D. Mohr
-
Patent number: 8399582Abstract: The present invention relates to the field of single site catalyst systems based on pyridine-iminophenol, pyridine-iminoalcohol or pyridine-iminoamine complexes and suitable for oligomerising or homo- or co-polymerising ethylene and alpha-olefins.Type: GrantFiled: April 17, 2007Date of Patent: March 19, 2013Assignee: Total Petrochemicals Research FeluyInventors: Caroline Hillairet, Guillaume Michaud, Sabine Sirol
-
Publication number: 20130066032Abstract: The present invention provides a process for preparing ethylene and/or propylene, comprising providing a hydrocarbon stream, comprising C4+ normal and C4+ iso-olefins; subjecting the hydrocarbon stream to an etherification process wherein the iso-olefins are converted with alcohol to an tert-alkyl ether, and retrieving a first etherification product stream; separating the first etherification product stream into a first ether-enriched stream and an iso-olefin-depleted hydrocarbon stream; converting the normal olefins in the iso-olefin-depleted hydrocarbon stream to ethylene and/or propylene with a molecular sieve-comprising catalyst and retrieving an olefinic product; decomposing the tert-alkyl ether in the ether-enriched stream into alcohol and an iso-olefin; isomerising the obtained iso-olefins to normal-olefins and retrieving an normal-olefin-enriched hydrocarbon stream; and converting the normal olefins in the normal-olefin-enriched hydrocarbon stream to ethylene and/or propylene by contacting the normal-Type: ApplicationFiled: September 7, 2012Publication date: March 14, 2013Applicant: SHELL OIL COMPANYInventors: Leslie Andrew CHEWTER, Rajaram RAMESH, Sivakumar SADASIVAN VIJAYAKUMARI, Jeroen VAN WESTRENEN
-
Publication number: 20130065052Abstract: A new class of high modulus polypropylene multifilament fiber and/or yarn is provided. Such a multifilament fiber and/or yarn exhibits an exceptional combination of high strength and toughness with low weight and density. The inventive fibers thus permit replacement of expensive polymeric fibers within certain applications with lower cost alternatives, or replacement of high density components with such low density fibers, without sacrificing strength or durability. Such multifilament fibers are produced through melt-spinning processes and exhibit highly unique microstructures therein, including significant void volumes, interspersed and crossed voids, and nanofilament bridges within such voids. Such microstructural characteristics appear to impart the exceptional properties noted above.Type: ApplicationFiled: November 8, 2012Publication date: March 14, 2013Applicant: Innegra Technologies, LLCInventor: Innegra Technologies, LLC
-
Patent number: 8394908Abstract: The invention is a novel family of polyolefins characterized by chain-walking defects of the type that add extra backbone carbons per monomer. These polyolefins display a large decrease in crystallinity relative to polyolefins known in the art. Specifically, the reduction in crystallinity is much greater than for earlier polypropylenes with a matched content of stereo or 1-alkene type defects. The claimed polyolefins can be an alkene-based homopolymer. The defects in the polyolefin backbone are generated by a chain walking mechanism in which three or more carbons per monomer are added to the polymer backbone instead of two, as in conventional polymerization or copolymerization methods of alpha olefins. The novel polyolefins can be used in applications such as plastic wrapping, thin films, co-extrusion layers or molded parts in the absence of polymer blending or copolymerization. The cost of materials production can be reduced.Type: GrantFiled: October 4, 2012Date of Patent: March 12, 2013Assignees: The Florida State University Research Foundation, Inc., Cornell University Cornell Center for Technology, Enterprise & CommercializationInventors: Rufina Alamo, Geoffrey Coates, Carolina Ruiz-Orta
-
Patent number: 8394907Abstract: A polypropylene resin comprising a propylene polymer having the following features: a) melt flow rate (MFR) (ISO 1133) (230° C./2.16 kg) comprised between 120 g/10? and 400 g/10?; b) distribution of molecular weight Mw/Mn lower than 4; c) haze measured according to ASTM D 1003 comprised between 5% and 30%; and d) flexural modulus measured according ISO 178 after 48 h comprised between 1750 N/m2 and 2300 N/m2.Type: GrantFiled: October 12, 2006Date of Patent: March 12, 2013Assignee: Basell Polyolefine GmbHInventors: Alexander Fuchs, Bernd Schuetz
-
Patent number: 8389660Abstract: The invention is a novel family of polyolefins characterized by chain-walking defects of the type that add extra backbone carbons per monomer. These polyolefins display a large decrease in crystallinity relative to polyolefins known in the art. Specifically, the reduction in crystallinity is much greater than for earlier polypropylenes with a matched content of stereo or 1-alkene type defects. The claimed polyolefins can be made by a late metal Ni(II) catalyst. The defects in the polyolefin backbone are generated by a chain waling mechanism in which three or more carbons per monomer are added to the polymer backbone instead of two, as in conventional polymerization or copolymerization methods of alpha olefins. The novel polyolefins can be used in applications such as plastic wrapping, thin films, co-extrusion layers or molded parts in the absence of polymer blending or copolymerization. The cost of materials production can be reduced.Type: GrantFiled: January 24, 2011Date of Patent: March 5, 2013Assignees: The Florida State University Research Foundation, Cornell University Cornell Center for Technology, Enterprise & CommercializationInventors: Rufina Alamo, Geoffrey Coates, Carolina Ruiz-Orta
-
Patent number: 8389655Abstract: A process for preparing polymers, especially multi-block copolymer containing therein two or more segments or blocks differing in chemical or physical properties, by contacting propylene, 4-methyl-1-pentene, or other C4-8 ?-olefins and one or more copolymerizable comonomers, especially ethylene in the presence of a composition comprising the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.Type: GrantFiled: April 19, 2011Date of Patent: March 5, 2013Assignee: Dow Global Technologies, LLCInventors: Daniel J. Arriola, Edmund M. Carnahan, David D. Devore, Phillip D. Hustad, Roger L. Kuhlman, Timothy T. Wenzel
-
Publication number: 20130052149Abstract: The disclosed invention relates to a process, comprising: conducting unit operations in at least two process zones in a process microchannel to treat and/or form a non-Newtonian fluid, a different unit operation being conducted in each process zone; and applying an effective amount of shear stress to the non-Newtonian fluid to reduce the viscosity of the non-Newtonian fluid in each process zone, the average shear rate in one process zone differing from the average shear rate in another process zone by a factor of at least about 1.2.Type: ApplicationFiled: October 4, 2012Publication date: February 28, 2013Applicant: VELOCYS, INC.Inventor: Velocys, Inc.
-
Patent number: 8383540Abstract: Disclosed herein are procatalyst compositions, catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present procatalyst compositions contain a halo-malonate and a 2-fluoro-malonate in particular. The present catalyst compositions improve catalyst selectivity, improve catalyst activity, and also improve hydrogen response during polymerization. Propylene-based polymer produced from the present catalyst composition has a melt flow rate greater than 50 g/10 min.Type: GrantFiled: December 21, 2010Date of Patent: February 26, 2013Assignee: Dow Global Technologies LLCInventors: Linfeng Chen, Tak W. Leung, Tao Tao
-
Publication number: 20130046070Abstract: The present invention relates to a process for the continuous transition between two different and compatible polymerisation catalysts.Type: ApplicationFiled: April 13, 2011Publication date: February 21, 2013Applicant: Ineos Commercial Services Services UK LimitedInventors: Jean-Louis Chamayou, Benoit Sibourd
-
Publication number: 20130046069Abstract: The invention relates to a method and an apparatus for producing a film web made of thermoplastic material in which the thermoplastic material is extruded in at least one layer as plastic melt from a wide-slit nozzle in an extrusion direction and subsequently led away over at least roller, wherein tensile forces are exerted in the extrusion direction and transversely to the extrusion direction in order to stretch the film web longitudinally and transversely, wherein during application of the tensile forces in and transversely to the extrusion direction the film web has a temperature at least corresponding to the melting temperature of the same.Type: ApplicationFiled: August 14, 2012Publication date: February 21, 2013Applicant: Reifenhaeuser GmbH & Co. KG MaschinenfabrikInventors: Helmut MEYER, Jochen HENNES
-
Patent number: 8378047Abstract: The present technology relates to a biaxially oriented polypropylene film. The biaxially oriented polypropylene film comprises a polypropylene material having xylene solubles of at least 0.5 percent by weight. The polypropylene also has a strain hardening index of at least 0.15 measured at a deformation rate d?/dt of 1.00 s?1 at a temperature of 180° C. In certain embodiments, the strain hardening index is defined as the slope of a logarithm to the basis 10 of a tensile stress growth function as a function of a logarithm to the basis 10 of a Hencky strain for the range of Hencky strains between 1 and 3.Type: GrantFiled: January 9, 2009Date of Patent: February 19, 2013Assignee: Borealis Technology OYInventors: Manfred Stadlbauer, Eberhard Ernst, Petri Lehmus, Yvo Daniels, Franck Jacobs
-
Patent number: 8378048Abstract: Provided are amorphous ethylene propylene copolymer, compositions thereof, and methods for making same, whereby the copolymer can include of from about 40 wt. % to about 60 wt. % ethylene derived units; and of from about 60 wt. % to about 40 wt. % propylene derived units. The copolymer can be characterized by having no discernable melting point as measured by DSC, an MFRR (MI (21.6 kg; 230° C.)/MI (2.16 kg; 230° C.)) (MI (2.16 kg; 230° C.)) of about 38 or more, a molecular weight distribution (MWD) of from about 1.5 to about 2.5, and a shear viscosity ?* at 0.01 rad/sec measured at 70° C. that satisfies the relation |?*|(70° C.; 0.01 rad/sec)>1.2*106*|MFR|?0.77, wherein MFR is the melt flow rate.Type: GrantFiled: January 11, 2011Date of Patent: February 19, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Rainer Kolb, Jo Ann Marie Canich, Liehpao Oscar Farng, Sudhin Datta
-
Patent number: 8378042Abstract: Extruded, copolymer pellet compositions and methods for making the same. A copolymer pellet composition can have an ethylene content of about 40 wt % to about 50 wt % and a propylene content of about 50 wt % to about 60 wt %, based on total weight of the copolymer, wherein the copolymer has a MFR (230° C./2.16 kg) of from about 3.0 g/10 min and about 25 g/10 min; a MWD (Mw/Mn) of about 2.3 or less; and no measurable melting peak, as measured by DSC.Type: GrantFiled: September 29, 2009Date of Patent: February 19, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Richard Cheng-Ming Yeh, Rainer Kolb
-
Publication number: 20130041124Abstract: Provided are a polymer article excellent in mechanical strength, toughness, and stretchability and a production method of the polymer article. The polymer article of the present invention is formed of a polymer material and is a polymer blank or a formed polymer body. The polymer article of the present invention has a crystallinity of not less than 50% but less than 90% and a tensile strain at fracture of not less than 60%. A method for producing a polymer article of the present invention includes: a heating step of heating the polymer material to a temperature of not lower than (Tm?70)° C. but lower than Tm(° C.) where Tm is the melting point (° C.) of the polymer material; and a compression step of cooling the polymer material heated in the heating step and compressing the polymer material in the course of the cooling to obtain a polymer article having a crystallinity of not less than 50% but less than 90% and a tensile strain at fracture of not less than 60%.Type: ApplicationFiled: May 24, 2011Publication date: February 14, 2013Inventors: Hironori Tabata, Hiroyuki Hirano, Kazuho Uchida, Akira Nakasuga
-
Patent number: 8372930Abstract: This invention relates to a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(?0.94 (mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)?83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making homo-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.Type: GrantFiled: June 20, 2008Date of Patent: February 12, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Patrick Brant, Donna J. Crowther, Andrew G. Narvaez, Jr.
-
Patent number: 8362183Abstract: A process to make light olefins from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is disclosed. The process includes contacting the feedstock in a primary reactor with a catalyst that includes a metalloaluminophosphate (MeAPO) molecular sieve to form a first reactor effluent that includes a light olefins and a heavy hydrocarbon fraction. The process further includes separating the light olefins from the heavy hydrocarbon fraction and contacting the heavy hydrocarbon fraction in a second reactor to convert the heavy hydrocarbon fraction to light olefins. The MeAPO molecular sieve is expressed by the formula HxMeyAlzPkO2 where y+z+k=1, x is less than or equal to y, y is from 0.0008 to 0.4, z is from 0.25 to 0.67, and k is from 0.2 to 0.67. The MeAPO molecular sieve has a predominantly plate crystal morphology where the width divided by the thickness is greater than or equal to 10.Type: GrantFiled: March 10, 2008Date of Patent: January 29, 2013Assignee: Total Petrochemicals Research FeluyInventors: Walter Vermeiren, Nikolai Nesterenko
-
Publication number: 20130023598Abstract: The present invention provides a process for preparing high melt strength propylene polymer by direct polymerization, comprising that a propylene polymer with wide molecular weight distribution and containing “very high molecular weight fraction” can be prepared by controlling the species and ratios of the external electron donors in the Ziegler-Natta catalyst system at different reaction stages according to the requirment for different molecular weight fractions in the different propylene polymerization stage of the series operation, and said polymer has excellent mechnical properties, especially with very high melt strength. The present invention also provides a propylene homopolymer with high melt strength, comprising the following features: (1) the MFR is 0.2-10 g/10 min at 230° C. with a load of 2.16 kg; (2) the molecular weight distribution Mw/Mn is 6-20; (3) the content of the fraction with a molecular weight higher than 5,000,000 is higher than or equal to 0.Type: ApplicationFiled: January 21, 2011Publication date: January 24, 2013Inventors: Wenbo Song, Meifang Guo, Shijun Zhang, Wenjun Wei, Honghong Huang, Luqiang Yu, Tao Liu, Huijie Hu, Huan Xu, Peiqian Yu, Xiaomeng Zhang
-
Publication number: 20130012676Abstract: Disclosed is a method for producing a devolatilized polyolefin, wherein the method comprises a step that involves providing a twin screw extruder comprising a resin feeding port, a first molten resin kneading zone, a molten resin partially filled zone which is prevented from being fully filled with molten resin, a second molten resin kneading zone, and a devolatilization zone that are disposed in order from the upstream of a cylinder of the extruder, feeding a polyolefin through the resin feeding port, and feeding water to the molten resin partially filled zone in an amount of 0.01 to 50 parts by weight relative to 100 parts by weight of the polyolefin.Type: ApplicationFiled: July 2, 2012Publication date: January 10, 2013Applicant: Sumitomo Chemical Company, LimitedInventors: Hisakatsu HAMA, Tetsuro DOBASHI
-
Publication number: 20130008118Abstract: Wood-based flooring systems with click-type interlocking joint systems include a protective film system covering the contact surfaces of the click system. The protective film system includes one or more sheets of a material with low moisture transmissivity and a low coefficient of friction. In this way, the contact surfaces of the click system are protected against undue humidity absorption and frictional rubbing to thereby avoid squeaking after installation. In some embodiments there are four film sheets covering the entirety of all four click surfaces, in others there is one film sheet covering the entirety of all four click surfaces, in others there is film covering the entirety of only the two longitudinal click surfaces, in others there is film covering the entirety of only the two tongue click surfaces, and in others there is film covering only the contact surfaces of the click surfaces.Type: ApplicationFiled: July 9, 2012Publication date: January 10, 2013Applicant: CHINAFLOORS HOLDING LIMITEDInventors: Thomas L.M. BAERT, Chih-wen TSENG
-
Patent number: 8349975Abstract: Method for transitioning from a first process for producing a first polymer to a second process for producing a second polymer. The first and second processes each include contacting a principal olefin and a comonomer with a catalyst under gas phase polymerization conditions to form the first or second polymer. The first and second processes utilize the same olefin but differ in at least one of the comonomer used and the reaction temperature at which the polymer is produced. The respective first or second polymer is then contacted with a purge gas to remove unreacted monomers. The method includes changing the flow rate of purge gas from a first rate to a second rate defined relative to a flow rate and temperature used for an earlier polymer produced using the same comonomer as the second process.Type: GrantFiled: September 21, 2009Date of Patent: January 8, 2013Assignee: Ineos Europe LimitedInventor: Jean-Louis Chamayou
-
Publication number: 20130005927Abstract: A method of forming a thermoplastic article, comprises steps of a) positioning at least one preheated first component being hollow and having at least one open end in two co-operating first mould halves; b) extruding a blow-mouldable thermoplastic material into the first component and closing the mould halves; and c) blowing the blow-moldable thermoplastic material inside the mould halves to form an article on which the first component is fixedly engaged. The method is simple in implementation, low in cost and easy in modification, and by which a thermoplastic article of varied colors, patterns, materials, and/or functional components being fixedly mounted on its outer surface could be realized.Type: ApplicationFiled: January 8, 2010Publication date: January 3, 2013Applicant: GREAT FORTUNE (HK) LIMITEDInventor: Chi Shing Lam
-
Publication number: 20120325394Abstract: The invention relates to a single-ply protective film that is devoid of a supporting material and consists of a hot-melt adhesive. Said film can be rapidly and easily applied. The invention also relates to a method for applying said film and to a corresponding device.Type: ApplicationFiled: July 5, 2012Publication date: December 27, 2012Applicant: SIKA TECHNOLOGY AGInventor: Martin LINNENBRINK
-
Publication number: 20120329951Abstract: Polypropylene having a melting temperature (Tm) of at least 151.0° C., a melt flow rate MFR2 (230° C.) of more than 2.0 g/10 min, a xylene cold soluble fraction (XCS) of not more than 1.5 wt.-%, <2,1> regiodefects of equal or more than 0.4 mol.-% determined by 13C-spectroscopy, and a number average molecular weight (Mn) of not more than 110 kg/mol.Type: ApplicationFiled: December 21, 2010Publication date: December 27, 2012Applicant: Borealis AGInventors: Dietrich Gloger, Katja Klimke, Joachim Fiebig
-
Publication number: 20120329948Abstract: Disclosed herein are methods of injection molding at low, substantially constant melt pressures. Embodiments of the disclosed method now make possible a method of injection molding that is more energy—and cost—effective than conventional high-velocity injection molding processes. Embodiments of the disclosed method surprisingly allow for the filling of a mold cavity at low melt pressure without undesirable premature hardening of the thermoplastic material in the mold cavity and without the need for maintaining a constant temperature or heated mold cavity. Heretofore, it would not have been expected that a constant pressure method could be performed at low pressure without such premature hardening of the thermoplastic material when using an unheated mold cavity or cooled mold cavity.Type: ApplicationFiled: August 31, 2012Publication date: December 27, 2012Inventors: Gene Michael ALTONEN, Charles John Berg, JR., Ralph Edwin Neufarth, Gary Francis Schiller, John Moncrief Layman, Rainer Scharrenberg
-
Publication number: 20120316312Abstract: In a method of synthesizing a silicoaluminophosphate molecular sieve having 90+% CHA framework-type character, a reaction mixture is prepared comprising sources of water, silicon, aluminum, and phosphorus, as well as an organic template. In one aspect, the reaction mixture is heated at more than 10° C./hour to a crystallization temperature and is retained at the crystallization temperature or within the crystallization temperature range for a crystallization time from 16 hours to 350 hours to produce the silicoaluminophosphate molecular sieve. In another aspect, the reaction mixture is heated at less than 10° C./hour to a crystallization temperature from about 150° C. to about 225° C. and is then retained there for less than 10 hours to produce the silicoaluminophosphate molecular sieve. The molecular sieve can then be recovered from the reaction mixture and, preferably, used in a hydrocarbon conversion process, such as oxygenates to olefins.Type: ApplicationFiled: August 20, 2012Publication date: December 13, 2012Inventors: Machteld M. Mertens, Stephen N. Vaughn
-
Publication number: 20120302716Abstract: A method for producing a propylene-based polymer, including polymerizing propylene or propylene and an ?-olefin except propylene in the presence of a catalyst with a horizontal polymerization reactor equipped with stirring vanes rotating around a horizontal axis therein by a continuous vapor-phase polymerization, which removes heat of polymerization by heat of vaporization of a liquefied propylene, wherein the reactor can set a plurality of area sections different in temperature in a horizontal direction inside the reactor, and satisfies at least one of i) a temperature difference, ?T1=T??T?, between an area section including an upstream end of the reactor (T?) and a downstream end (T?) thereof is 0.1 to 20° C. and ii) a temperature difference, ?T2=Tx?Tz, between an area section including a catalyst feed part (Tx) and dew point (Tz) of a mix gas in the reactor is 0 to 5° C.Type: ApplicationFiled: October 29, 2010Publication date: November 29, 2012Applicant: JAPAN POLYPROPYLENE CORPORATIONInventors: Yoshitaka Kobayashi, Takanori Nakashima, Kiyoshi Yukawa, Yusuke Yamada, Hajime Aoyama, Nobuhiro Iwai
-
Patent number: 8318875Abstract: This invention relates to processes for producing an isotactic propylene homopolymer having more than 15 and less than 100 regio defects (sum of 2,1-erythro and 2,1-threo insertions and 3,1-isomerizations) per 10,000 propylene units; a weight-averaged molecular weight of 35000 g/mol or more; a peak melting temperature of greater than 149° C.; an mmmm pentad fraction of 0.85 or more; a heat of fusion of 80 J/g or more; and a peak melting temperature minus peak crystallization temperature (Tmp?Tcp) of less than or equal to (0.907 times Tmp) minus 99.64 (Tmp?Tcp<(0.907×Tmp)?99.64), as measured in ° C. on the homopolymer having 0 wt % nucleating agent.Type: GrantFiled: November 4, 2008Date of Patent: November 27, 2012Assignee: Exxonmobil Chemical Patents Inc.Inventors: Aspy K. Mehta, Manika Varma-Nair, Gabor Kiss, Robert P. Reynolds, John W. Chu, Steven P. Rucker
-
Patent number: 8318884Abstract: The invention relates to a novel process for producing coloured polypropylene compositions having a high content of ?-modification, wherein polypropylene is melt blended with at least one inorganic pigment and at least one ?-nucleating agent, wherein a1) polypropylene is melt blended with at least one inorganic pigment or with a first concentrate comprising the at least one inorganic pigment to obtain a coloured polypropylene and a2) the coloured polypropylene is melt blended with at least one ?-nucleating agent or with a second concentrate comprising the at least one ?-nucleating agent to obtain the coloured ?-nucleated polypropylene composition or b1) polypropylene is melt blended with at least one ?-nucleating agent or with a second concentrate comprising the at least one ?-nucleating agent to obtain a ?-nucleated polypropylene and b2) the ?-nucleated polypropylene is melt blended with at least one inorganic pigment or with a first concentrate comprising the at least one inorganic pigment to obtain the colType: GrantFiled: November 26, 2008Date of Patent: November 27, 2012Assignee: Borealis Technology OyInventor: Franz Ruemer
-
Patent number: 8318873Abstract: Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. An improved method for preparing cyclopentadienyl complexes used to produce polyolefins is also provided.Type: GrantFiled: February 3, 2011Date of Patent: November 27, 2012Assignee: Chevron Phillips Chemical Company LPInventors: Kumudini C. Jayaratne, Michael D. Jensen, Qing Yang
-
Publication number: 20120270039Abstract: Polypropylene composition comprising a polypropylene having a melt flow rate MFR2 (230° C.) of at least 450 g/10 min and a molecular weight distribution (MWD) of not more than 3.5, a polypropylene having a melt flow rate MFR2 (230° C.) of equal or below 20 g/10 min, wherein the composition has a melt flow rate MFR2 (230° C.) of at least 200 g/10 min.Type: ApplicationFiled: November 11, 2010Publication date: October 25, 2012Inventors: Antti Tynys, Joachim Fiebig, Pascal Perrillat-Collomb
-
Patent number: 8293856Abstract: [Problem] To efficiently obtain an ?-olefin polymer having a high melting point and a high molecular weight. [Solution to Problem] The process for preparing an olefin polymer of the present invention is a process for preparing an olefin polymer, comprising polymerizing at least one monomer selected from ?-olefins of 2 or more carbon atoms, wherein the polymerization is carried out at a temperature of not lower than 40° C.Type: GrantFiled: August 14, 2009Date of Patent: October 23, 2012Assignee: Mitsui Chemicals, Inc.Inventors: Takashi Yukita, Masahiro Yamashita, Nobukazu Yamahira, Wataru Yamada, Hiromu Kaneyoshi
-
Publication number: 20120264873Abstract: A sugar mixture comprising: monosaccharides; oligosaccharides in a ratio ?0.06 to total saccharides; disaccharides in a ratio to total saccharides ?0.05; pentose in a ratio to total saccharides ?0.05; at least one alpha-bonded di-glucose; and at least one beta-bonded di-glucose. Also disclosed are methods to make and/or use such mixtures.Type: ApplicationFiled: June 26, 2011Publication date: October 18, 2012Inventors: Aharon Meir Eyal, Robert P. Jansen, Revital Mali, Asher Vitner
-
Patent number: 8288495Abstract: [Object] To provide a propylene homopolymer suitable for capacitor films having high withstand voltage and a stretched film formed by stretching the propylene homopolymer. [Solution] A propylene homopolymer of the present invention for capacitors satisfies the following requirements (i) to (v) and (ix): (i) the MFR is 1 to 10 g/10 minutes; (ii) the meso pentad fraction (mmmm) measured by 13C-NMR is 0.940 to 0.995; (iii) the integrted amount of elution at 90° C. by CFC using o-dichlorobenzene is 0.5% by weight or less; (iv) the melting point measured using DSC is 152° C. or more; (v) the chlorine content is 2 ppm by weight or less; and (ix) in an elution temperature-elution volume curve measured by cross-fractionation chromatography (CFC) using o-dichlorobenzene, the maximum peak has a peak top temperature in the range of 105° C. to 130° C. and half width of 7.0° C. or less.Type: GrantFiled: January 26, 2010Date of Patent: October 16, 2012Assignees: Mitsui Chemicals, Inc., Prime Polymer Co., Ltd.Inventors: Satoshi Tamura, Keita Itakura, Satoshi Hashizume
-
Patent number: 8288304Abstract: Disclosed are procatalyst compositions having an internal electron donor which includes an adamantane dicarboxylate and optionally an additional electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions to produce propylene-based olefins with broad molecular weight distribution.Type: GrantFiled: April 16, 2010Date of Patent: October 16, 2012Assignee: Dow Global Technologies LLCInventors: Linfeng Chen, Tak W. Leung, Tao Tao, Kuanqiang Gao
-
Patent number: 8283428Abstract: This invention relates to a polymacromonomer comprising at least one macromonomer and from 0 to 20 wt % of a C2 to C12 comonomer, wherein the macromonomer has vinyl termination of at least 70%, and wherein the polymacromonomer has: a) a g value of less than 0.6, b) an Mw of greater than 30,000 g/mol, c) an Mn of greater than 20,000 g/mol, d) a branching index (g?)vis of less than 0.5, e) less than 25% vinyl terminations, f) at least 70 wt % macromonomer, based upon the weight of the polymacromonomer, g) from 0 to 20 wt % aromatic containing monomer, based upon the weight of the polymacromonomer and h) optionally, a melting point of 50° C. or more. This invention also relates to processes to make such polymacromonomers.Type: GrantFiled: June 19, 2009Date of Patent: October 9, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: Patrick Brant, Andrew G. Narvaez, Jr., Donna J. Crowther
-
Patent number: 8283419Abstract: This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(?0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)?83), when 70 to 90 mol % ethylene is present in the co-oligomer.Type: GrantFiled: June 19, 2009Date of Patent: October 9, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: John R. Hagadorn, Matthew W. Holtcamp, Andrew G. Narvaez, Jr., Donna J. Crowther, Patrick Brant
-
Publication number: 20120252999Abstract: Systems and methods of producing chemical compounds are disclosed. An example chemical production system includes a combustion chamber having intake ports for entry of a gas mixture. An igniter ignites the gas mixture in the intake chamber to facilitate a reaction at a high temperature and high pressure. A nozzle restricts exit of the ignited gas mixture from the combustion chamber. An expansion chamber cools the ignited gas. The expansion chamber has an exhaust where the cooled gas exits the expansion chamber. A chemical compound product is formed in the expansion chamber.Type: ApplicationFiled: April 12, 2012Publication date: October 4, 2012Inventor: Bruce H. Peters
-
Publication number: 20120243941Abstract: A synthetic weir board riser system is described that controls the water elevation on the front and rear sides of the structure using synthetic weir boards as the barrier. Weir boards are added and removed from a metallic or composite riser system to control the level of water flowing into a larger body. Synthetic weir boards composed of plastic or composite have an increased life span. Geometrically, the synthetic boards provide a more efficient use of material in terms of weight. A reduced radius per each external corner prevents the increased pressure to the rear of the riser from separating the synthetic boards thereby increasing seepage.Type: ApplicationFiled: March 23, 2011Publication date: September 27, 2012Inventor: Carl Anthony Hazenberg
-
Publication number: 20120242003Abstract: The present invention concerns a propylene polymer comprising at least two propylene polymer fractions of different melt flow index and a minor amount of at least one comonomer, said propylene polymer being further characterized by specific ranges for melt flow index, xylene solubles content and recovery compliance. Said propylene polymer is particularly suited for thermoforming. The present invention further concerns a process for producing said propylene polymer as well as its use in thermoforming.Type: ApplicationFiled: September 30, 2010Publication date: September 27, 2012Applicant: TOTAL PETROCHEMICALS RESEARCH FELUYInventors: Thomas Forgue, Jérôme Gromada, Alain Standaert, Rita De Luca
-
Publication number: 20120245313Abstract: This invention relates to a transition metal catalyst compound represented by the structure: wherein M is hafnium or zirconium; each X is, independently, selected from the group consisting of hydrocarbyl radicals having from 1 to 20 carbon atoms, hydrides, amides, alkoxides, sulfides, phosphides, halogens, dienes, amines, phosphines, ethers, or a combination thereof; each R1 and R3 are, independently, a C1 to C8 alkyl group; and each R2, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, and R14 are, independently, hydrogen, or a substituted or unsubstituted hydrocarbyl group having from 1 to 8 carbon atoms, provided however that at least three of the R10-R14 groups are not hydrogen, compositions thereof and methods of use thereof to prepare polymers.Type: ApplicationFiled: March 25, 2011Publication date: September 27, 2012Inventors: Donna J. Crowther, Renuka N. Ganesh, Andrew G. Narvaez, JR., Patrick Brant
-
Publication number: 20120240802Abstract: A laser-engravable flexographic printing precursor or other patternable material can be laser-engraved to provide a relief image. The relief image is formed in an elastomeric, relief-forming, laser-engravable layer comprising a thermoplastic elastomeric nanocrystalline polyolefin that is melt processable. The laser-engraveable composition can be readily recycled and reformed into another flexographic printing plate precursor.Type: ApplicationFiled: March 22, 2011Publication date: September 27, 2012Inventors: Christine J. Landry-Coltrain, Linda M. Franklin
-
Patent number: 8263692Abstract: Disclosed are propylene-based polymer compositions and processes for producing same. Polymerization with an improved catalyst composition provides a propylene-based polymer with improved stiffness.Type: GrantFiled: December 31, 2009Date of Patent: September 11, 2012Assignee: Dow Global Technologies LLCInventors: William G. Sheard, Linfeng Chen
-
Publication number: 20120214946Abstract: A 10-50 g/d high strength polyethylene fiber and preparation method thereof are provided, which are in the high molecular material field. Said fiber is obtained by cross blend melt spinning method, and its strength is 10-50 g/d, its modulus is 400-2000 g/d. The material used by said cross blend melt spinning method is obtained by mixing low density polyethylene with molecular weight of 2/5-500,000 and super molecule weight polyethylene with molecular weight of 120-7000,000 in the proportion of 2-10:1. Flow modifier or diluent is not additionally added in the present invention, raw material consumption is low, extra high pressure is avoided, energy consumption and cost of production are low, technological process is simple, single line capacity is easily raised, and large scale industrial production can be realized.Type: ApplicationFiled: April 27, 2012Publication date: August 23, 2012Applicant: SHANDONG ICD HIGH PERFORMANCE FIBRES CO., LTD.Inventor: Yi REN
-
Patent number: 8246918Abstract: Polymer compositions and articles formed therefrom are described herein. The compositions include a random copolymer and a radiation additive, wherein the random copolymer includes propylene and less than 2 wt. % ethylene and exhibits a melt flow rate of from about 30 to 100 dg/min., the polymer composition exhibits a flexural modulus of from about 160 kpsi to about 200 kpsi and the polymer composition is adapted to produce a polymer article exhibiting low plate out, a haze at 20 mils of no greater than 15%, radiation stability and autoclavability.Type: GrantFiled: October 19, 2009Date of Patent: August 21, 2012Assignee: Fina Technology, Inc.Inventors: Margarito Lopez, Michael Musgrave