Material Contains A Group Viii Metal Atom Patents (Class 528/15)
  • Publication number: 20140275329
    Abstract: A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a metal-ligand complex that can be prepared by a method including reacting a metal precursor and a ligand.
    Type: Application
    Filed: September 20, 2012
    Publication date: September 18, 2014
    Inventors: Kurt Brandstadt, Simon Cook, Aswini Dash, Matthew Olsen, Avril Surgenor, Richard Taylor, Binh Nguyen, Ming-Shin Tzou
  • Patent number: 8835555
    Abstract: The present invention has an objective to easily obtain an emulsion exhibiting superior storage stability, and in particular, an emulsion of a polyorganosiloxane. The present invention provides a method for producing an emulsion characterized by obtaining an emulsion by emulsifying a mixture of an oil and a surfactant, obtained by synthesizing the surfactant in the oil. In particular, the method is suitably used for the preparation of an emulsion of an organopolysiloxane (A) which is usually difficult to be stably emulsified. A silicone-based surfactant (B), and in particular, a silicone-based surfactant having a small degree of polymerization of a siloxane chain such as a trisiloxane is synthesized in an oil. Thereby, an emulsion exhibiting superior storage stability can be produced.
    Type: Grant
    Filed: December 21, 2009
    Date of Patent: September 16, 2014
    Assignee: Dow Corning Toray Co. Ltd.
    Inventors: Kazuhiko Kojima, Tsutomu Naganawa, Asao Harashima
  • Patent number: 8828551
    Abstract: The general field of the invention is that of airbags. The invention relates to a process for improving the tear strength and the combing strength of coated fabrics intended for uses in the field of inflatable bags, using a silicone composition comprising an additive consisting of a polyorganosiloxane resin (V) and a calcium carbonate. After coating the composition onto the fabric supports and curing, the coated supports not only have optimum adhesion and crease resistance properties, but also have good properties in terms of combing strength and tear strength.
    Type: Grant
    Filed: July 25, 2012
    Date of Patent: September 9, 2014
    Assignee: Bluestar Silicones France SAS
    Inventors: Laurent Dumont, Alain Pouchelon
  • Patent number: 8809469
    Abstract: The present invention is a curable organopolysiloxane composition containing (A) a compound shown by the following average composition formula (1), wherein R1 represents an aliphatic unsaturated group, R2 represents a monovalent hydrocarbon group, R3 represents an aliphatic hydrocarbon group, Ar represents an aryl group, and “n” and “m” represent positive numbers which satisfy n?1, m?1, and n+m?10, (B) a hydrogen atom-containing organic silicon compound having at least two silicon atom-bonded hydrogen atoms per one molecule while not having an aliphatic unsaturated group, and (C) a hydrosilylation catalyst which contains a platinum group metal. Thereby, there can be provided a curable organopolysiloxane composition which can give a cured product having high transparency, high refractive index, and excellent thermal shock resistance; an optical device sealing material; and an optical device.
    Type: Grant
    Filed: January 18, 2013
    Date of Patent: August 19, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Ataru Kobayashi, Toshiyuki Ozai
  • Patent number: 8810046
    Abstract: A silicone resin composition contains a cage octasilsesquioxane having a group represented by the following formula (1), an alkenyl group-containing polysiloxane containing an alkenyl group having a number of moles larger than that of a hydrosilyl group in the cage octasilsesquioxane, a hydrosilylation catalyst, and an organohydrogenpolysiloxane. (where, in formula, R1 represents a monovalent hydrocarbon group selected from a saturated hydrocarbon group and an aromatic hydrocarbon group. R2 represents hydrogen or a monovalent hydrocarbon group selected from a saturated hydrocarbon group and an aromatic hydrocarbon group. The molar ratio of the monovalent hydrocarbon group:hydrogen in R2 in the cage octasilsesquioxane as a whole is, as an average value, in the range of 6.5:1.5 to 5.5:2.5).
    Type: Grant
    Filed: October 17, 2012
    Date of Patent: August 19, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Haruka Ona, Hiroyuki Katayama
  • Patent number: 8796410
    Abstract: One aspect of the present invention provides a polymer having repeating units represented by the formulas (1-1), (1-2) and (1-3) and weight-average molecular weight of from 3,000 to 500,000, as determined by GPC using tetrahydrofuran as a solvent, reduced to polystyrene. Another aspect of the present invention provides an adhesive composition comprising (A) the polymer, (B) a thermosetting resin, and (C) a compound having flux activity. Further, the present invention provides an adhesive sheet having an adhesive layer made of the adhesive composition, a protective material for a semiconductor device, which has the adhesive layer, and a semiconductor device having a cured product obtained from the adhesive composition.
    Type: Grant
    Filed: May 11, 2012
    Date of Patent: August 5, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Michihiro Sugo, Kazunori Kondo
  • Patent number: 8791221
    Abstract: Provided is a metallosiloxane compound (A) prepared by reacting a bifunctional silane compound (S1), a monofunctional silane compound (S2), a boron compound (M), and optionally H2O in a molar ratio of [the silane compound (S1)]:[the silane compound (S2)]:[the boron compound (M)]:[H2O] of n:m:k:a, where n, m, k, and a satisfy all conditions (i), (ii), and (iii), in which the metallosiloxane compound has at least one Si—H bond or C2-10 alkenyl group per molecule, and the conditions (i), (ii), and (iii) are expressed as follows: (i) n>0, m>0, k>0, a?0; (ii) m/n?0.5; and (iii) (n+m)/k?1.8.
    Type: Grant
    Filed: November 29, 2011
    Date of Patent: July 29, 2014
    Assignee: Daicel Corporation
    Inventor: Tomoya Egawa
  • Patent number: 8791213
    Abstract: The invention provides a curable silicone resin composition comprising: (A) an organopolysiloxane containing an aromatic group having two or more alkenyl groups, and having a viscosity at 25° C. of 10 to 1,000,000 mPa·s, (B) an organopolysiloxane having a resin structure, comprising 10 to 80 mol % of a SiO4/2 unit, 1 to 80 mol % of a (R1)2SiO2/2 unit, and 1 to 60 mol % of a (R2)3SiO1/2 unit, and containing a SiOH group in a range of 0.1 to 5.0 mol %, (C) an organohydrogenpolysiloxane having two or more SiH group, and among whole substituents bonded to the silicon atom, 20 to 80 mol % is a phenyl group, and a SiO4/2 unit is less than 5 mol %, and (D) a platinum group metal catalyst, and the component (B) is contained in an amount of 20 to 80% by mass based on a sum of the component (A) and the component (B).
    Type: Grant
    Filed: July 1, 2013
    Date of Patent: July 29, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Tomoyuki Mizunashi, Tsutomu Kashiwagi, Kinya Kodama
  • Patent number: 8785585
    Abstract: A temporary adhesive for which temporary adhesion and subsequent detachment are simple. The temporary adhesive composition includes: (A) an organopolysiloxane having a weight-average molecular weight of at least 15,000, obtained by a hydrosilylation reaction between (A1) and (A2) described below, and (B) an organic solvent having a boiling point of not more than 220° C., wherein (A1) is an alkenyl group-containing organopolysiloxane having a weight-average molecular weight exceeding 2,000, comprising 35 to 99 mol % of T siloxane units and 1 to 25 mol % of M siloxane units, and in which alkenyl groups bonded to silicon atoms represent at least 2 mol % of all the organic groups bonded to silicon atoms, and (A2) is a specific organohydrogenpolysiloxane having at least two silicon atom-bonded hydrogen atoms or a specific hydrosilyl group-containing compound.
    Type: Grant
    Filed: January 5, 2012
    Date of Patent: July 22, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masahiro Furuya, Shohei Tagami, Hideto Kato, Hideyuki Ito, Masahiro Yoshizawa
  • Patent number: 8779043
    Abstract: A silicone resin composition contains a first organopolysiloxane having, in one molecule, both at least two ethylenically unsaturated hydrocarbon groups and at least two silanol groups; a second organopolysiloxane having, in one molecule, at least two hydrosilyl groups without having an ethylenically unsaturated hydrocarbon group; a hydrosilylation catalyst; and a hydrosilylation retarder.
    Type: Grant
    Filed: October 11, 2012
    Date of Patent: July 15, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Hirokazu Matsuda, Ryuichi Kimura, Hiroyuki Katayama
  • Patent number: 8779074
    Abstract: A silicone emulsion composition is provided comprising organopolysiloxane, organohydrogenpolysiloxane, surfactant, and water. Two organopolysiloxanes of different type are blended, whereby a cured silicone coating is improved to be fully adherent to plastic film and lightly peelable from pressure-sensitive adhesive. By limiting the SiH content of organohydrogenpolysiloxane, the composition is improved in shelf stability. A specific surfactant is used to control the size of emulsion particles so as to improve wettability to plastic film.
    Type: Grant
    Filed: June 6, 2013
    Date of Patent: July 15, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Shinji Irifune, Tsutomu Nakajima
  • Publication number: 20140191161
    Abstract: A hydrosilylation curable silicone composition that forms a cured product with a high refractive index, high transparency, excellent heat resistance, and excellent flexibility, the hydrosilylation curable silicone composition comprising, as a main component, an organopolysiloxane represented by the following average unit formula: (R13SiO1/2)a(R12SiO2/2)b(R2SiO3/2)c(SiO4/2)d wherein, R1 are alkyl groups, alkenyl groups, phenyl groups, or hydrogen atoms; R2 is a group recited for R1, a condensed polycyclic aromatic group, or a group containing a condensed polycyclic aromatic group, provided that at least one of R1 or R2 in a molecule is an alkenyl group or hydrogen atom, and at least one R2 in a molecule is a condensed polycyclic aromatic group or a group containing a condensed polycyclic aromatic group; and a, b, c, and d are numbers satisfying: 0.01?a?0.8, 0?b?0.5, 0.2?c?0.9, 0?d<0.2, and a+b+c+d=1.
    Type: Application
    Filed: July 4, 2012
    Publication date: July 10, 2014
    Inventors: Masaaki Amako, Tadashi Okawa, Tomohiro Iimura, Kazuhiro Nishijima, Maki Itoh, Yoshitsugu Morita
  • Patent number: 8765264
    Abstract: Silicone-laminated substrate, including glass cloth, and cured product of silicone resin composition—with which the glass cloth is filled and a surface of the glass cloth is coated. The silicone resin composition includes: (A) an organopolysiloxane having a resin structure of specific siloxane units, (B) an organohydrogenpolysiloxane having a resin structure of specific siloxane units, (C) a platinum group metal-based catalyst, and (D) a filler. The silicone-laminated substrate exhibits excellent mechanical properties, flexibility and workability, has minimal surface tack, and is easy to handle. The silicone-laminated substrate is produced by impregnating a glass cloth with the silicone resin composition dissolved or dispersed in a solvent, subsequently evaporating the solvent from the glass cloth, and subjecting the composition impregnated into the glass cloth to heat-curing under compression-molding conditions.
    Type: Grant
    Filed: September 10, 2009
    Date of Patent: July 1, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Tsutomu Kashiwagi, Toshio Shiobara
  • Patent number: 8759468
    Abstract: The moisture and gas barrier properties of an organopolysiloxane having at least two substituents which are able to undergo crosslinking reactions per molecule shall be improved. This is achieved by providing an organopolysiloxane wherein at least 10 mol % of all substituents are represented by formula (1) wherein q is an integer from 0 to 5 and R1, R2, R3 each independently are methyl or ethyl groups. Furthermore, the invention is directed to a composition based on the aforementioned organopolysiloxane and to the use of the organopolysiloxane and of the composition.
    Type: Grant
    Filed: March 12, 2013
    Date of Patent: June 24, 2014
    Assignee: Henkel (China) Company Limited
    Inventors: Liwei Zhang, Yong Zhang
  • Patent number: 8754174
    Abstract: A solventless addition-curable pressure sensitive silicone adhesive composition is provided. The composition comprises (A) an alkenyl group-containing polydiorganosiloxane; (B) a condensation product of (a) a polydiorganosiloxane having hydroxyl group or an alkoxy group on opposite ends of the molecular chain and (b) a polyorganosiloxane containing R13SiO1/2 unit and SiO2 unit as critical components and also a HOSiO3/2 unit in the molecule; (C1) a polyorganohydrosiloxane having at least three SiH groups per molecule; (C2) a polydiorganohydrosiloxane having SiH group on opposite ends; and (D) a platinum group metal catalyst. Use of the present composition enables production of a pressure sensitive adhesive agent having flexibility, pressure sensitive adhesiveness, and heat resistance, and the present composition is particularly effective for use as a buffer member having pressure sensitive adhesiveness.
    Type: Grant
    Filed: August 4, 2011
    Date of Patent: June 17, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Shunji Aoki
  • Patent number: 8748553
    Abstract: Composite materials contain a silicone addition crosslinkable silicone elastomer composition comprising an organopolysiloxane having aliphatic unsaturation, an Si—H functional cyclic organopolysiloxane, a hydrosilylation catalyst, together with specific adhesion promoters, applied to a substrate material.
    Type: Grant
    Filed: August 8, 2011
    Date of Patent: June 10, 2014
    Assignee: Wacker Chemie AG
    Inventors: Martin Bortenschlager, Thomas Frese, Silvia Jung-Rossetti, Maria Leute
  • Patent number: 8742008
    Abstract: A process for forming a new group of siloxane-based compositions by a one-step co-hydrolysis and the compositions formed thereof. The siloxane-based compositions being functionalized with a carbon-carbon double (C?C) bond and a silicon-hydrogen (Si—H) bond. The C?C bond and hydrogen (H) each being attached directly to a silicon (Si) atom of the silicon-oxygen (Si—O) backbone of the siloxane-based composition. The C?C bond may be from a vinyl or an aromatic radical like a phenyl substituent. The C?C bond substituent provides the functionality needed for forming crosslinkages through standard dehydrocoupling catalysts without the need for siloxane fluids or organic compounds containing alkyl or aryl functional groups. The process provides for varying proportions of silanes as starting monomers to tailor the desired silicon, carbon, hydrogen and oxygen ratios in the siloxane-based compositions or resins.
    Type: Grant
    Filed: September 18, 2007
    Date of Patent: June 3, 2014
    Assignee: Starfire Systems, Inc.
    Inventors: Qionghua Shen, Walter J. Sherwood, Jr., Christopher K. Whitmarsh
  • Patent number: 8735525
    Abstract: The present invention relates to a curable composition. A curable composition may be provided; which shows excellent processability and workability; which shows excellent light extraction efficiency, crack resistance, hardness, thermal shock resistance and adhesive strength after curing; and which has excellent reliability and long-term reliability under high-temperature and/or high-moisture conditions. Also, turbidity and surface stickiness may be prevented in the cured product.
    Type: Grant
    Filed: July 20, 2012
    Date of Patent: May 27, 2014
    Assignee: LG Chem, Ltd
    Inventors: Min Jin Ko, Myung Sun Moon, Jae Ho Jung, Bum Gyu Choi, Dae Ho Kang, Min Kyoung Kim
  • Patent number: 8729170
    Abstract: A curable coating composition that exhibits improved cure and adhesion to various substrates, especially synthetic textiles used in the manufacture of air bags, and good air pressure holding performance.
    Type: Grant
    Filed: December 28, 2009
    Date of Patent: May 20, 2014
    Assignees: Bluestar Silicones France SAS, Bluestar Silicon USA Corp
    Inventors: Remi Thiria, Pascale Jackson
  • Patent number: 8729195
    Abstract: An objective of the present invention is to provide a curable silicone composition of the present invention exhibiting superior adhesive properties with respect to a poor-adhesive resin such as PPS, even if the composition is cured at a relatively low temperature for a short period. The aforementioned objective of the present invention is achieved by a curable silicone composition comprising: (A) an organopolysiloxane having at least two alkenyl groups in a molecule, (B) an organopolysiloxane having at least two silicon-bonded hydrogen atoms in a molecule, (C) a hydrosilylation-reaction catalyst, and (D) an acid anhydride having an alkoxy group bonding to a silicon atom or an alkoxyalkoxy group bonding to a silicon atom.
    Type: Grant
    Filed: December 20, 2010
    Date of Patent: May 20, 2014
    Assignee: Dow Corning Toray Co., Ltd.
    Inventors: Yoshinori Taniguchi, Toyohiko Fujisawa, Yasushi Sugiura
  • Patent number: 8729208
    Abstract: A curable composition is provided. A cured product showing excellent light extraction efficiency, crack resistance, hardness, thermal shock resistance and adhesive strength after a curing, as well as showing excellent processability and workability is provided. Also, surface stickiness may be prevented in the cured product without causing turbidity etc.
    Type: Grant
    Filed: July 25, 2012
    Date of Patent: May 20, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Min Jin Ko, Myung Sun Moon, Jae Ho Jung, Bum Gyu Choi, Dae Ho Kang, Min Kyoun Kim
  • Patent number: 8722153
    Abstract: A release coating composition includes a curable polysiloxane and an aerosol suppressant that has more than one SiO4/2 unit. The aerosol suppressant includes the polymerization product of a siloxane and a cyclic polysiloxane polymerized in the presence of a polymerization catalyst. The siloxane has units of the chemical formula (SiO4/2)(RaRb2SiO1/2)x wherein Ra is a vinyl moiety, Rb is an alkyl moiety, and x is a number from 1.05 to 4. The release coating composition is formed by combining the aerosol suppressant and a curable polysiloxane. The release coating composition is also used to coat a substrate in a release coating process producing a mist of less than 50 mg/cubic meter measured at approximately 457 m/min.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: May 13, 2014
    Assignee: Dow Corning Corporation
    Inventor: Robert Ekeland
  • Patent number: 8716412
    Abstract: A silicone resin composition includes a cage octasilsesquioxane; a polysiloxane containing alkenyl groups at both ends containing an alkenyl group having the number of moles smaller than the number of moles of the hydrosilyl group of the cage octasilsesquioxane; a hydrosilylation catalyst; a hydroxyl group-containing polysiloxane, organohydrogenpolysiloxane, or a polysiloxane containing alkenyl groups at side chain.
    Type: Grant
    Filed: June 15, 2012
    Date of Patent: May 6, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Haruka Fujii, Hiroyuki Katayama
  • Publication number: 20140114041
    Abstract: A curable fluoropolyether gel composition comprising (A) a linear polyfluoro compound having at least two alkenyl groups and a perfluoropolyether structure in its backbone, (B) a polyfluoromonoalkenyl compound having one alkenyl group and a perfluoropolyether structure in its backbone, (C) a fluorinated organohydrogensiloxane having at least two SiH groups, and (D) a platinum-based hydrosilylation catalyst is improved by adding (E) a fluorinated acetylene alcohol as reaction regulator. The resulting composition has advantages including uniform dispersion of the catalyst, storage stability, consistent curability, and cured hardness.
    Type: Application
    Filed: October 18, 2013
    Publication date: April 24, 2014
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Mitsuo MUTO, Kenichi FUKUDA, Mikio SHIONO
  • Publication number: 20140111976
    Abstract: A silicone resin is provided. The silicone resin may be effectively used to encapsulate a semiconductor element, for example, a light-emitting element of a light-emitting diode.
    Type: Application
    Filed: December 30, 2013
    Publication date: April 24, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Min Jin KO, Myung Sun MOON, Jae Ho JUNG, Bum Gyu CHOI, Dae Ho KANG, Min Kyoun KIM
  • Patent number: 8703881
    Abstract: A curable composition of ionic silicones includes a silicone having the formula M1aM2bM3cD1dD2eD3fT1gT2hT3iQj having ionic groups and crosslinking functional groups. The composition can further include polyorganosiloxane having the average compositional formula R26nR27o(OH)pSiO(4-n-o-p)/2, organohydrogenoligosiloxane or organohydrogenpolysiloxane that has the average compositional formula HqR28rSiO(4-q-r)/2 a transition metal catalyst and other components such as UV stabilizer, cure accelerator, pigment, dye, antimicrobial agent, biocide, surfactant, functional or non-functional filler, conductive filler, finely divided surface treated/untreated metal oxides, clay, plasticizers, tackifiers, mold release agents, adhesion promoters, compatibilizers, pharmaceutical excipients, surfactants or antistatic agents.
    Type: Grant
    Filed: December 20, 2012
    Date of Patent: April 22, 2014
    Assignee: Momentive Performance Materials Inc.
    Inventors: Anubhav Saxena, Srividhya Marimuthu, Pranav Ramchandra Joshi, Alok Sarkar
  • Publication number: 20140107309
    Abstract: One object of the present invention is to provide a method for preparing a polyorganosiloxane without using any catalyst having corrosivity and toxicity such as an alkaline earth metal catalyst in a condensation reaction of at least one organic silicon compound having a silanol group and/or an alkoxy silyl group. The present invention is a method for preparing a polyorganosiloxane, wherein the method includes a step of condensation reacting at least one organic silicon compound having at least one —OX group bonding to a silicon atom in the molecule, wherein X is a hydrogen atom, an alkyl group having 1 to 10 carbon atoms or an alkoxyalkyl group having 2 to 10 carbon atoms, in the presence of a catalyst, wherein the catalyst is at least one selected from the group having hydroxides or oxides of elements in Groups 3-15 of the periodic table.
    Type: Application
    Filed: October 3, 2013
    Publication date: April 17, 2014
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takayuki KUSUNOKI, Yuusuke TAKAMIZAWA, Tsutomu KASHIWAGI
  • Publication number: 20140103390
    Abstract: Provided is a curable composition and its use. The curable composition may exhibit excellent processibility and workability. The curable composition has excellent light extraction efficiency, crack resistance, hardness, thermal and shock resistance and an adhesive property after curing. The curable composition may provide a cured product exhibiting stable durability and reliability under severe conditions for a long time and having no whitening and surface stickiness.
    Type: Application
    Filed: December 23, 2013
    Publication date: April 17, 2014
    Applicant: LG Chem, Ltd.
    Inventors: Min Jin KO, Jae Ho JUNG, Myung Sun MOON, Bum Gyu CHOI, Dae Ho KANG, Min Kyoun KIM, Byung Kyu CHO
  • Patent number: 8697798
    Abstract: A silicone rubber composition comprising (A) an organopolysiloxane composition of the organic peroxide cure or addition reaction cure type, (B) a normally solid organic compound having at least two ester bonds per molecule, and (C) particulate aluminum hydroxide having an average particle size of up to 20 ?m is suited for use as high-voltage electric insulator since it maintains insulating properties for a long term in outdoor service and has acid resistance and a long lifetime even in polluted areas.
    Type: Grant
    Filed: March 14, 2013
    Date of Patent: April 15, 2014
    Assignees: Shin-Etsu Chemical Co., Ltd., NGK Insulators, Ltd.
    Inventors: Noriyuki Meguriya, Yoshiaki Koike, Osamu Hayashida, Takanori Kondo, Tatsuya Kuroda
  • Publication number: 20140100347
    Abstract: A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin.
    Type: Application
    Filed: October 4, 2013
    Publication date: April 10, 2014
    Inventors: Simon Cook, Shuangbing Han, Matthew Olsen
  • Patent number: 8668991
    Abstract: The present invention relates to a curable organopolysiloxane composition, which comprises: (A) an organocyclosiloxane having alkenyl groups, represented by the following formula (I) wherein n=3 or 4; (B) a hydrosilicone resin of formula (II) (R1R2R3SiO1/2)M.(R4R5SiO2/2)D.(R6SiO3/2)T.
    Type: Grant
    Filed: March 12, 2013
    Date of Patent: March 11, 2014
    Assignee: Henkel (China) Company Limited
    Inventors: Wenjuan Tan, Zhiming Pasing Li, Wentao Thomas Xing, Liwei Zhang, Yong Zhang
  • Patent number: 8658755
    Abstract: Provided is a silicon-containing curable composition which includes a prepolymer (A) containing two or more Si—H groups in one molecule, which is obtained by subjecting one or more kinds of a cyclic siloxane compound (?) represented the following formula (1) and one or more kinds of a compound (?) represented by the following formula (2), to a hydrosilylation reaction; a cyclic siloxane compound (B) containing, in one molecule, two or more carbon-carbon double bonds that are reactive with Si—H groups; a polysiloxane compound (C) which is different from the prepolymer (A) and the cyclic siloxane compound (B); and a hydrosilylation catalyst (D). In formula (1), R1 to R3 each represent an alkyl group having 1 to 6 carbon atoms, or a phenyl group; a represents a number from 2 to 10; and b represents a number from 0 to 8. In formula (2), n represents the number 1 or 2.
    Type: Grant
    Filed: September 15, 2010
    Date of Patent: February 25, 2014
    Assignee: Adeka Corporation
    Inventor: Masako Saito
  • Patent number: 8637628
    Abstract: One embodiment is related to a silicone composition for sealing a light emitting element, the composition comprising: (A) a vinyl group-containing organopolysiloxane having a three-dimensional network structure; (B) an organohydrogenpolysiloxane which has at least two hydrogen atoms, each hydrogen atom being bonded to a silicon atom per molecule; and (C) a hydrosilylation catalyst.
    Type: Grant
    Filed: June 5, 2012
    Date of Patent: January 28, 2014
    Assignee: Momentive Performance Materials Japan LLC
    Inventors: Kikuo Mochizuki, Nobuo Hirai
  • Patent number: 8637627
    Abstract: A curable phenoxyphenyl polysiloxane composition is disclosed. A cured phenoxyphenyl polysiloxane composition is further disclosed, along with a method of making that cured phenoxyphenyl polysiloxane composition from the curable phenoxyphenyl silicon composition. An encapsulated semiconductor device, and a method of making that encapsulated semiconductor device by coating a semiconductor element of a semiconductor device with cured phenoxyphenyl polysiloxane are further disclosed.
    Type: Grant
    Filed: December 5, 2008
    Date of Patent: January 28, 2014
    Assignee: Rohm and Haas Company
    Inventors: Kathleen A. Auld, David M. Conner, Garo Khanarian, David Wayne Mosley
  • Patent number: 8618245
    Abstract: The present invention relates to an obtainment process of biodegradable polymers from a citric residue resulting from the processing of orange juice. The polymers obtained are polyesters classified as polyhydroxyalkanoates including, among them the poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate). The biodegradable polymer is obtained from the batch culture process or fed batch culture process with or without recirculation of the cells, using as a carbon source the pre-treated pressing liquor and/or the citric molasses. The polyhydroxyalkanoates, herein described, can be used as substitutes of the synthetic polyesters in different areas, including the food, pharmaceutical, medical, agricultural and other areas.
    Type: Grant
    Filed: November 18, 2008
    Date of Patent: December 31, 2013
    Assignees: Citrosuco S/A Agroindustria, Universidade Federal de Santa Catarina
    Inventors: Glaucia Maria Falcão de Aragão, Willibaldo Schimidell Netto, Jaciane Lutz Ienczak, Mônica Lady Fiorese, Francieli Dalcaton, Franciny Schmidt, Ricardo Deucher, Cinthia Vecchi, Rafael Costa Rodrigues
  • Patent number: 8618234
    Abstract: Silicone-based pressure-sensitive adhesive composition comprising 100 parts (A) a branched organopolysiloxane having on molecular terminals at least two alkenyl groups and represented by (R3SiO1/2)4-p(R1R2SiO1/2)p(R2SiO)m(RR1SiO)n(SiO4/2), to 400 parts (B) an organopolysiloxane composed of R3R22SiO1/2 units and SiO4/2 units, (C) an organohydrogenpolysiloxane, and a catalytic quantity of (D) a platinum-type catalyst. Pressure-sensitive adhesive tape or sheet having an adhesive layer in the form of a cured layer of the aforementioned composition.
    Type: Grant
    Filed: August 22, 2008
    Date of Patent: December 31, 2013
    Assignees: Dow Corning Corporation, Dow Corning Toray Company, Ltd.
    Inventors: Haruna Mizuno, Robert Alan Ekeland, Seiji Hori, Takateru Yamada
  • Patent number: 8618233
    Abstract: A polymer cures by either radiation or moisture curing mechanisms, or both. The polymer is prepared by hydrosilylation. The polymer includes units of formula: (R22Si02/2)b, (R2Si03/2)c, (SiO4/2)d, (R1?)f, and (R23Si01/2)g, where each R1 is independently an oxygen atom or a divalent hydrocarbon group; each R1? is independently divalent hydrocarbon group; each R2 is independently a monovalent organic group that is free of terminal aliphatic unsaturation each X is independently a monovalent hydrolyzable group; each J is independently a monovalent epoxy functional organic group; subscript a has a value of 1 or more; subscript b has a value of 0 or more; subscript c has a value of 0 or more; subscript d has a value of 0 or more; subscript e has a value of 1 or more; subscript f has a value of 0 or more; subscript g has a value of 0 or more; subscript s is 1, 2, or 3; and subscript t is 1, 2, or 3.
    Type: Grant
    Filed: November 7, 2007
    Date of Patent: December 31, 2013
    Assignee: Dow Corning Corporation
    Inventors: Khristopher Alvarez, Nick Shephard, James Tonge
  • Publication number: 20130341671
    Abstract: A silicone resin composition contains a polysiloxane containing at least one pair of condensable substituted groups capable of condensation by heating and at least one pair of addable substituted groups capable of addition by an active energy ray.
    Type: Application
    Filed: June 7, 2013
    Publication date: December 26, 2013
    Inventors: Haruka ONA, Hiroyuki Katayama, Sadahiro Nakanishi
  • Patent number: 8614282
    Abstract: A silicone resin composition comprising (A) an organopolysiloxane containing silicon-bonded aryl and alkenyl groups in a molecule, (B) an organohydrogenpolysiloxane, and (C) an addition reaction catalyst is low gas permeable. An optoelectronic device encapsulated therewith is highly reliable.
    Type: Grant
    Filed: September 1, 2011
    Date of Patent: December 24, 2013
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshihira Hamamoto, Tsutomu Kashiwagi
  • Patent number: 8604150
    Abstract: The present invention has an object to provide a curable composition for transfer materials. The curable composition is applicable to a UV nanoimprint process capable of forming micropatterns with high throughput, is applicable to a thermal nanoimprint process in some cases, and is capable of forming a micropattern having high selectivity on etching rates regarding a fluorine-based gas and an oxygen gas. A curable composition for transfer materials of the present invention contains a curable silicon compound produced by subjecting a silicon compound (A) having a Si—H group and a compound (B) having a curable functional group and a carbon-carbon double bond other than the curable functional group to a hydrosilylation reaction.
    Type: Grant
    Filed: November 5, 2008
    Date of Patent: December 10, 2013
    Assignee: Showa Denko K.K.
    Inventors: Katsutoshi Morinaka, Yoshikazu Arai, Hiroshi Uchida, Toshio Fujita
  • Patent number: 8598295
    Abstract: The invention provides a process for preparing branched SiH-functional siloxanes by converting a mixture of one or more low molecular weight SiH-functional siloxanes, one or more low molecular weight SiH-free siloxanes and one or more trialkoxysilanes with addition of water and in the presence of at least one Brønsted-acidic catalyst, which is characterized in that the reaction is performed in one process step.
    Type: Grant
    Filed: September 23, 2008
    Date of Patent: December 3, 2013
    Assignee: Evonik Goldschmidt GmbH
    Inventors: Frauke Henning, Wilfried Knott, Horst Dudzik
  • Patent number: 8592037
    Abstract: Compositions containing a nanostructure, preferably a nanocrystal, are provided. The nanostructures have ligands bound to the surface. Such ligands are preferably siloxane containing ligands having at least one —COON group, although ligands having various ?P?O groups are also contemplated. The nanostructures can be embedded into a polymer such as a silicone polymer.
    Type: Grant
    Filed: October 20, 2011
    Date of Patent: November 26, 2013
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: J. Wallace Parce, Paul Bernatis, Robert Dubrow, William P Freeman, Joel Gamoras, Shihai Kan, Andreas Meisel, Baixin Qian, Jeffery A Whiteford, Jonathan Ziebarth
  • Patent number: 8575290
    Abstract: A silicone resin composition contains a first organopolysiloxane having, in one molecule, both at least two ethylenically unsaturated hydrocarbon groups and at least two hydrosilyl groups; a second organopolysiloxane having, in one molecule, at least two hydrosilyl groups without containing an ethylenically unsaturated hydrocarbon group; a hydrosilylation catalyst; and a hydrosilylation inhibitor.
    Type: Grant
    Filed: May 11, 2012
    Date of Patent: November 5, 2013
    Assignee: Nitto Denko Corporation
    Inventors: Munehisa Mitani, Hiroyuki Katayama, Haruka Fujii
  • Patent number: 8569429
    Abstract: An optical semiconductor device that combines low gas permeability and high reliability. A curable silicone resin composition comprising: (A) an alkenyl group-containing organopolysiloxane comprising an organopolysiloxane represented by an average composition formula (1) and containing at least two alkenyl groups per molecule: (R1SiO3/2)a(R22SiO)b(R3R42SiO1/2)c??(1) wherein R1 represents an alkyl group, R2 represents an aryl group, R3 represents an alkenyl group, and R4 represents an alkyl group or an aryl group, (B) an organohydrogenpolysiloxane represented by an average composition formula (2) and containing at least two silicon atom-bonded hydrogen atoms per molecule: R1dR2eHfSiO(4-d-e-f)/2??(2) wherein R1 and R2 are as defined above, and (C) an addition reaction catalyst.
    Type: Grant
    Filed: November 20, 2012
    Date of Patent: October 29, 2013
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshihira Hamamoto, Tsutomu Kashiwagi
  • Patent number: 8557942
    Abstract: Single-component silicone elastomer compositions (SEA) are crosslinkable by polyaddition into self-adhesive state, contain at least one polyorganosiloxane (POS) including sites of ethylenic and/or acetylenic unsaturation {POS containing units ?Si— [unsaturation]}; at least one polyorganosiloxane (POS) containing units ?Si—H; a catalytic system including at least one metal catalyst and at least one crosslinking inhibitor; a filler; at least one adhesion promoter; optionally, at least one POS resin; optionally, at least one thermal resistance agent; and, optionally, at least one other functional additive, and are useful for gluing, assembling, sealing, e.g., joints, coatings, electrical, electronic and automobile engineering parts.
    Type: Grant
    Filed: December 9, 2005
    Date of Patent: October 15, 2013
    Assignee: Bluestar Silicones France SAS
    Inventors: Alain Pouchelon, Delphine Blanc-Magnard, Catherine George, Fabio Zanandrea
  • Patent number: 8541011
    Abstract: Gel compositions are disclosed comprising a silicone elastomer from the reaction of an SiH containing organopolysiloxane resin and an organic compound having at least two aliphatic unsaturated groups in its molecule.
    Type: Grant
    Filed: June 5, 2012
    Date of Patent: September 24, 2013
    Assignee: Dow Corning Corporation
    Inventors: Shaow Burn Lin, Lori Ann Stark-Kasley
  • Patent number: 8524842
    Abstract: Gels having viscoelastic qualities, physical stability and adhesive properties, well suited for a wide variety of end applications, are prepared by crosslinking, by hydrosilylation, silicone compositions which contain: a polyorganosiloxanes POS (I) of SiH type; a polyorganosiloxanes POS (II) of SiVi type (Vi=vinyl); a polyorganosiloxanes POS (III) of monofunctional SiVi type; a platinum-based catalyst (D); and optionally, a polyorganosiloxanes POS (IV) of polydimethylsiloxane type.
    Type: Grant
    Filed: June 9, 2004
    Date of Patent: September 3, 2013
    Assignee: Bluestar Silicones France SAS
    Inventors: Bernd Jung, Joerg Dienemann, Catherine George
  • Patent number: 8524850
    Abstract: PROBLEM TO BE SOLVED To provide an ophthalmic lens, which can be more safely worn, that is, to provide a material, which is transparent and has high oxygen permeability and a high hydrophilic property, and to provide a novel monomer to be a raw material thereof. SOLUTION A hydrophilic polysiloxane macromonomer contains polyoxyethylene as a hydrophilic side chains in a polysiloxane main chain, wherein transparency, oxygen permeability, and hydrophilic properties of the material are controlled by regulating the length of the polysiloxane main chain, the length of the hydrophilic polyoxyethylene side chains, and the number of the side chains.
    Type: Grant
    Filed: March 5, 2012
    Date of Patent: September 3, 2013
    Assignee: CooperVision International Holding Company, LP
    Inventors: Hiroyuki Ueyama, Seiichiro Ikawa, Junichi Iwata
  • Patent number: 8519078
    Abstract: A polyether-modified polysiloxane containing a perfluoropolyether group and its production method are provided. The polysiloxane has both the properties of a perfluoropolyether and the properties of a polyether-modified silicone, and it also has high affinity for organic solvents as well as coating compositions, cosmetics, and various coating materials. The polysiloxane is represented by the following general formula (1): wherein Rf is a perfluoroalkyl group; X is fluorine atom or trifluoromethyl group; Q is a divalent organic group, R is hydrogen atom, an alkyl group, or acyl group; R1 and R2 are an alkyl group, aryl group, or an aralkyl group; a, b, c, d are 0 to 200; a+b+c+d is at least 1; e is 0 or 1; p and q are 0 to 50 with the proviso that p+q is at least 2; and k is 1 to 3.
    Type: Grant
    Filed: June 27, 2011
    Date of Patent: August 27, 2013
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hiromasa Yamaguchi, Yasunori Sakano
  • Patent number: 8512869
    Abstract: A silicon composition with a silicon compound represented by Formula 1 and a silicon compound represented by Formula 2: wherein, R1, R2, R3, R4, R11, R12, R13, R14, R15, R16, R17, R18, and R19 are each independently a C1-C4 alkyl group, R5, R6, R7, R8, R9, and R10 are each independently hydrogen or deuterium, k, m, and n are positive integers, and the ratio of k to the sum of m and n is from about 1:0.001 to about 1:0.2; and an organic light emitting device including the same.
    Type: Grant
    Filed: April 26, 2011
    Date of Patent: August 20, 2013
    Assignee: Samsung Display Co., Ltd.
    Inventors: Oh-June Kwon, Seung-Yong Song, Young-Seo Choi, Ji-Hun Ryu, Young-Cheol Joo, Jin-Hwan Jeon, Sun-Young Jung