Material Contains A Group Viii Metal Atom Patents (Class 528/15)
-
Patent number: 8222303Abstract: (A) Siloxane-based antifoams and (B) silicone polyethers prepared by reacting organopolysiloxanes (1) containing 0.05% to 1.6% by weight of Si-bonded hydrogen atoms with unsaturated polyethers (3) of the formulae: CH2?CR1—(CH2)aO(C2H4O)bR1??(Ia) CH2?CR1—(CH2)aO(C2H4O)b(C3H6O)cR1??(Ib) CH2?CR1—(CH2)aO(C3H6O)cR1??(Ic), where R1 is a hydrogen or a C1-6 hydrocarbon radical, a is 0 to 16, b is 1 to 50, and c is 1 to 50, wherein the sum b+c is ?10 and at least two different polyethers (Ia), (Ib) and (Ic) are used, and optionally further reacting the reaction product with organopolysiloxanes (2) containing from 0.01% to 0.5% by weight of Si-bonded hydrogen atoms, wherein the first and second step reactions take place with a hydrosilylation catalyst, and the weight ratio of Si-bonded hydrogen in organopolysiloxane (1) to Si-bonded hydrogen in organopolysiloxane (2) is at least 1.5.Type: GrantFiled: June 29, 2010Date of Patent: July 17, 2012Assignee: Wacker Chemie AGInventors: Christian Herzig, Willibald Burger, Martina Joachimbauer, Josef Wimmer
-
Patent number: 8222363Abstract: Gel compositions are disclosed comprising a silicone elastomer from the reaction of an SiH containing organopolysiloxane resin and an organic compound having at least two aliphatic unsaturated groups in its molecule.Type: GrantFiled: September 22, 2008Date of Patent: July 17, 2012Assignee: Dow Corning CorporationInventors: Shaow Burn Lin, Lori Ann Stark-Kasley
-
Patent number: 8217129Abstract: An asymmetric siloxane is made by reacting a silicone having the formula MHDxM?H where MH is R1R2HSiO1/2, M?H is R4R5HSiO1/2 and x is an integer 0?x?10 under selective hydrosilylation conditions in the presence of a precious metal hydrosilylation catalyst, with a first olefinic compound and in a second step, a monohydridosiloxane produced in the first step is reacted under hydrosilylating conditions with another olefinic compound different from the first olefinic compound.Type: GrantFiled: March 23, 2011Date of Patent: July 10, 2012Assignee: Momentive Performance MaterialsInventors: David D Farris, Chauncey J Rinard, Mark D Leatherman
-
Publication number: 20120172472Abstract: A silicone composition is described that includes components having SiH/SiOH group and that can be polymerized/cross-linked by a dehydrocondensation reaction in the presence of a catalyst such as an iron-based complex or salt, requiring a low activation temperature.Type: ApplicationFiled: June 15, 2010Publication date: July 5, 2012Applicant: BLUESTAR SILICONES FRANCEInventor: Christian Maliverney
-
Patent number: 8211544Abstract: A surface modifier comprising an organosilicone compound represented by General Formula (A) and/or General Formula (B): F—(CF2)q—(OC3F6)m—(OC2F4)n—(OCF2)o(CH2)pX(CH2)rSi(X?)3-a(R1)a (A) and F—(CF2)q—(OC3F6)m—(OC2F4)n—(OCF2)o(CH2)pX(CH2)r(X?)2-a(R1)aSiO(F—(CF2)q—(OC3F6)m—(OC2F4)n—(OCF2)o(CH2)pX(CH2)r(X?)1-a(R1)aSiO)zF—(CF2)q—(OC3F6)m—(OC2F4)n—(OCF2)o(CH2)pX(CH2)r(X?)2-a(R1)aSi (B) wherein q is an integer from 1 to 3; m, n, and o are independently integers from 0 to 200; p is 1 or 2; X is O or a bivalent organic group; r is an integer from 2 to 20; R1 is a C1-22 linear or branched hydrocarbon group; a is an integer from 0 to 2; X? is hydrolysable group; and z is an integer from 0 to 10 when a is 0 or 1.Type: GrantFiled: March 30, 2006Date of Patent: July 3, 2012Assignees: Daikin Industries, Ltd., Dow Corning CorporationInventors: Yasuo Itami, Tetsuya Masutani, Peter C. Hupfield, Don Lee Kleyer
-
Patent number: 8207241Abstract: Nanosize titanium dioxide having supported thereon metallic platinum are efficient hydrosilylation catalysts whose hydrosilylation activity may be increased by irradiation. The catalysts are prepared by depositing soluble platinum compounds on a titanium dioxide sol or titanium dioxide pigments followed by drying, calcining, and reduction to platinum metal. The catalysts are particularly useful in preparing addition-curable organopolysiloxane elastomers.Type: GrantFiled: December 1, 2005Date of Patent: June 26, 2012Assignee: Wacker Chemie AGInventors: Marco Hofmann, Hans-Juergen Eberle
-
Patent number: 8202933Abstract: The present invention provides a silicone resin composition for encapsulating light-emitting elements with which encapsulation using a potting method can be easily accomplished, and which can be easily molded into a lens shape such as hemisphere, parabola, or the like. The composition can impart high transparency to the resulting encapsulating lens molded using a potting method. More particularly, the invention provides a silicone resin composition for encapsulating light-emitting elements, including 2 to 25 wt % of silica with a mean particle size of 1 to 30 nm based on the total amount of Components (A) and (B); and having a viscosity (23° C.) of more than 10 Pa·s and less than 70 Pa·s, and a thixotropic index of 2.0 to 5.5; the composition being used for encapsulation using a potting method.Type: GrantFiled: March 10, 2008Date of Patent: June 19, 2012Assignee: Sanyu Rec Co., Ltd.Inventors: Yoshiteru Miyawaki, Osamu Tanaka
-
Patent number: 8198380Abstract: The present invention relates to a composition for a thermosetting silicone resin, the composition including: (A) an organohydrogenpolysiloxane; (B) an alkenyl group-containing epoxy compound; (C) an alkenyl group-containing cyclic siloxane; and (D) a hydrosilylation catalyst, a thermosetting silicone resin composition obtained by reacting the composition and a production method thereof, a photosemiconductor element-encapsulating material including the thermosetting silicone resin composition, and a photosemiconductor device including a photosemiconductor element encapsulated with the resin composition or the photosemiconductor element-encapsulating material.Type: GrantFiled: March 4, 2010Date of Patent: June 12, 2012Assignee: Nitto Denko CorporationInventor: Hiroyuki Katayama
-
Patent number: 8198389Abstract: The present invention is generally related to mold release compounds having improved cure times, environmental friendliness and durability that are formed from cycloaliphatic epoxide functionalized polydimethylsiloxane compounds In still another embodiment, the present invention relates to mold release compounds that are formed from cycloaliphatic epoxide functionalized poly(dimethylsiloxane-co-methylhydrosiloxane) compounds.Type: GrantFiled: May 25, 2007Date of Patent: June 12, 2012Assignee: The University of AkronInventors: Mark D. Soucek, David P. Dworak
-
Publication number: 20120126435Abstract: Provided are a curable composition for semiconductor encapsulation which produces a cured product that is excellent in heat resistance, electrical insulation properties at high temperatures, flexibility and heat cycle resistance, and a semiconductor device encapsulated by curing this curable composition. Specifically, there is provided a curable composition for semiconductor encapsulation containing, as component (A), a particular SiH group-containing siloxane compound; as component (B), a particular vinyl group-containing siloxane compound; as component (C), a compound having at least three SiH groups or at least three vinyl groups; and as component (D), a hydrosilylation catalyst.Type: ApplicationFiled: May 26, 2011Publication date: May 24, 2012Applicant: ADEKA CORPORATIONInventors: Ken-ichiro Hiwatari, Isamu Yumoto
-
Patent number: 8182921Abstract: Crosslinkable compositions containing a crosslinkable organosilicon compound; a silica filler; a silicate or halogen analog thereof, a non-silicate resin-forming monomer; and a solid blowing agent containing intercalated liquid or liquid of crystallization, produce uniform foams of good pore structure, with firm adhesion to substrates, with water repellency and water vapor permeability, and with high elongation and low compression set, and are suitable for use in applications where foamed chloroprene rubber has been used, and in other applications as well.Type: GrantFiled: November 21, 2008Date of Patent: May 22, 2012Assignee: Wacker Chemie AGInventor: Juergen Weidinger
-
Patent number: 8173759Abstract: The present invention provides an organopolysilmethylene represented by the following general formula (1): wherein R1 is, independently of each other, a group selected from the group consisting of an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms, an alkoxy group, a hydroxy group, R3SiCH2— and R3SiO—, wherein R is, independently of each other, a group selected from the group consisting of an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms, an alkoxy group, and a hydroxy group, m is an integer of 1 to 100, and n is an integer of 1 to 100, and wherein at least two out of R1's and R's are an alkenyl group.Type: GrantFiled: August 23, 2010Date of Patent: May 8, 2012Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tsutomu Kashiwagi, Toshio Shiobara
-
Patent number: 8168737Abstract: A polymer cures by both radiation and moisture curing mechanisms. The polymer is prepared by hydrosilylation. The polymer is useful in adhesive compositions. The polymer includes units of formulae (I), (R22Si02/2)b, (R2Si03/2)c, (Si04/2)d, (R1)f, and (R23SiO1/2)g, where each R1 is independently an oxygen atom or a divalent hydrocarbon group; each R1 is independently divalent hydrocarbon group; each R2 is independently a monovalent organic group that is free of terminal aliphatic unsaturation each X is independently a monovalent hydrolyzable group; each J is independently a monovalent epoxy functional organic group; subscript a has a value of 1 or more; subscript b has a value of 0 or more; subscript c has a value of 0 or more; subscript d has a value of 0 or more; subscript e has a value of 1 or more; subscript f has a value of 0 or more; subscript g has a value of 0 or more; subscript s is 1, 2, or 3; and subscript t is 1, 2, or 3.Type: GrantFiled: December 10, 2007Date of Patent: May 1, 2012Assignee: Dow Corning CorporationInventors: Khristopher Edward Alvarez, Nick Evan Shephard, James Tonge
-
Patent number: 8168730Abstract: Provided is a curable silicone rubber composition, comprising (A) an organopolysiloxane containing two or more aliphatic unsaturated bonds within each molecule, having a viscosity at 25° C. within a range from 10 to 100,000 mm2/s, and containing a phenyl group and/or cyclohexyl group, (B) an organopolysiloxane with a resin structure comprising SiO2 units and (R1)3SiO0.5 units (wherein, each R1 represents, independently, a vinyl group, an allyl group, or a monovalent hydrocarbon group that contains no aliphatic unsaturated bonds, provided one or more of all the R1 groups within this component (B) represent, independently, a phenyl group or a cyclohexyl group), (C) an organohydrogenpolysiloxane, and (D) a platinum group metal-based catalyst, wherein the component (B) exists in a quantity that represents from 20 to 80% by mass of the combination of the component (A) and the component (B).Type: GrantFiled: January 16, 2007Date of Patent: May 1, 2012Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Tsutomu Kashiwagi
-
Patent number: 8158265Abstract: Provided is an addition-curable silicone composition including A: a diorganopolysiloxane having a structure represented by a formula (1): (R1)(R2)2SiO((Ar)2SiO)nSi(R2)2(R1) (where R1 represents an aliphatic unsaturated group, R2 represents identical or different, unsubstituted or substituted monovalent hydrocarbon groups, Ar represents identical or different, unsubstituted or substituted aryl groups that may or may not contain a hetero atom, and n represents an integer of 1 or greater), B: an organosilicon compound containing at least two hydrogen atoms bonded to silicon atoms per molecule, and containing no aliphatic unsaturated groups, in an amount that is sufficient to cure the composition in the presence of the hydrosilylation catalyst described below, and C: a platinum group metal-based hydrosilylation catalyst.Type: GrantFiled: November 30, 2009Date of Patent: April 17, 2012Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Shinji Kimura
-
Patent number: 8158738Abstract: An adhesive silicone rubber composition comprising (A) 100 pbw of an organopolysiloxane containing at least two silicon-bonded alkenyl radicals, (B) 0.5-20 pbw of an organohydrogenpolysiloxane containing at least two Si—H radicals, (C) a hydrosilylation catalyst, and (D) 0.1-50 pbw of an organosilicon compound having at least one phenyl structure, at least one alicyclic epoxy radical, and at least one Si—H radical is applicable to an electrolyte membrane and a separator in a polymer electrolyte fuel cell to form a firm integrally molded part.Type: GrantFiled: June 20, 2008Date of Patent: April 17, 2012Assignees: Toyota Jidosha Kabushiki Kaisha, Shin-Etsu Chemical Co., Ltd.Inventors: Chisato Kato, Kazutaka Iizuka, Osamu Hayashida, Takashi Aketa, Shigeki Shudo
-
Patent number: 8142895Abstract: A curable aryl siloxane composition is disclosed. A heat stable cured aryl polysiloxane composition is further disclosed, along with a method of making that heat stable cured aryl polysiloxane composition from the curable aryl siloxane composition. An encapsulated semiconductor device, and a method of making that encapsulated semiconductor device by coating a semiconductor element of a semiconductor device with the heat stable cured aryl polysiloxane are further disclosed.Type: GrantFiled: October 11, 2007Date of Patent: March 27, 2012Assignee: Rohm and Haas CompanyInventors: Garo Khanarian, David Wayne Mosley
-
Patent number: 8143362Abstract: The invention relates to a curable composition comprising addition curable silicone component (A) having a linear siloxane backbone at least one unsaturated, non-activated side group pendant from the Si atom or atoms in the backbone, component (A) having an equivalent weight in the range of about 68 to about 1000, crosslinker component (B) comprising at least 2 SiH groups, catalyst component (C) being able to catalyse the reaction between component (A) and component (B), filler component (D), wherein the equivalent weight is defined as (molecular weight of the molecule)/(number of unsaturations in the molecule).Type: GrantFiled: September 3, 2010Date of Patent: March 27, 2012Assignee: 3M Innovative Properties CompanyInventors: Peter Bissinger, Joachim W. Zech
-
Publication number: 20120061679Abstract: Compositions and methods for controlled polymerization and/or oligomerization of hydrosilanes compounds including those of the general formulae SinH2n and SinH2n+2 as well as alkyl- and arylsilanes, to produce soluble silicon polymers as a precursor to silicon films having low carbon content.Type: ApplicationFiled: November 17, 2011Publication date: March 15, 2012Inventors: Dmitry KARSHTEDT, Joerg ROCKENBERGER, Fabio ZÜRCHER, Brent RIDLEY, Erik SCHER
-
Patent number: 8129480Abstract: Provided is a curable polyorganosiloxane composition which advantageously forms a cured product suitable for LED or optical lens, wherein the cured product has excellent light transmission properties in a short wavelength region, i.e., in the blue to ultraviolet region and is unlikely to suffer yellowing due to exposure to heat.Type: GrantFiled: October 19, 2007Date of Patent: March 6, 2012Assignee: Momentive Performance Materials Japan LLCInventors: Masanori Takanashi, Hideki Kobayashi
-
Patent number: 8124711Abstract: Ruthenium compounds which have, in their ligand sphere, at least one ?6-bonded arene ligand and a silyl ligand; ruthenium complexes which have, in their ligand sphere, at least one ?6-bonded arene ligand to which is bonded a silyl or siloxy radical directly or via a spacer, and ruthenium complexes which have, in their ligand sphere, at least one ?6-bonded arene ligand and at least one further ligand to which is bonded a silyl or siloxy radical directly or via a spacer are useful as hydrosilylation catalysts.Type: GrantFiled: March 28, 2007Date of Patent: February 28, 2012Assignee: Wacker Chemie AGInventors: Marco Hofmann, Hans-Juergen Eberle, Johann Weis
-
Patent number: 8110646Abstract: A triorganosiloxy end-capped organopolysiloxane, i.e., organopolysiloxane having a backbone consisting essentially of repeating (3,3,3-trifluoropropyl)methylsiloxane units and end-capped with triorganosiloxy groups is prepared by copolymerizing tris(3,3,3-trifluoropropyl)trimethylcyclo-trisiloxane with a silanol end-capped organopolysiloxane in the presence of an alkyllithium or lithium silanolate catalyst to form a silanol end-capped copolymer, and adding a trialkylsilyl triflate or strong acid in excess relative to the catalyst and a hexaorganodisilazane for effecting end-capping and neutralization.Type: GrantFiled: August 6, 2010Date of Patent: February 7, 2012Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kazuhiro Oishi, Toshio Yamazaki
-
Publication number: 20120028191Abstract: The invention relates azide functionalized poly(3-hexylthiophene)s. Various azide functionalized poly(3-hexylthiophene)s and intermediates are disclosed and described, as well as method for making novel monomers that are synthesized and transformed into P3HT-Nmp for use as organic conducting polymers in organic photovoltaic devices.Type: ApplicationFiled: July 29, 2011Publication date: February 2, 2012Applicant: Brookhaven Science Associates, LLCInventors: Yang Qin, Robert B. Grubbs, Young Suk Park
-
Patent number: 8101241Abstract: The invention relates to crosslinkable or crosslinked silicone compositions capable of being used to form a water-repellent and release coating for a flexible support made of paper or of polymer, in particular a heat-sensitive flexible support. These compositions are of the type of those comprising crosslinking polyorganosiloxanes carrying SiH units and unsaturated, preferably vinylated, polyorganosiloxanes capable of reacting with the crosslinking agent by polyaddition in the presence of platinum to form the release crosslinked coating on the flexible support. The targeted aim is to make possible the instantaneous crosslinking at low temperature (85-90° C.) of such silicone compositions coated on flexible supports at a very high speed. To achieve this aim, the invention provides for the use of specific crosslinking agents composed of POSs hydrogenated at the chain end and in the chain.Type: GrantFiled: May 20, 2008Date of Patent: January 24, 2012Assignee: Bluestar Silicones FranceInventors: Jean-Paul Benayoun, Didier Dhaler, Jacques Kieffer, John White
-
Patent number: 8093331Abstract: A thermally conductive silicone rubber composition comprising: (A) an organopolysiloxane with the except of below-given components (C) and (E); (B) a thermally conductive filler; (C) a specific organopolysiloxane; (D) a curing agent; and (E) an organopolysiloxane composed of the following units: SiO4/2, R1R22SiO1/2, and R23SiO1/2 (wherein R1 is a univalent hydrocarbon group with an aliphatic, unsaturated bonds, R2 may designate the same or different univalent hydrocarbon groups that do not have aliphatic, unsaturated bonds.), said component (E) being used in an amount of 2 to 10 mass % per sum of components (A) and (E), demonstrates high flowability and good handling characteristics in spite of having a large content of thermally conductive filler and that demonstrates good adhesive properties and elongation and tensile strength in spite of the absence of reinforcing filler.Type: GrantFiled: March 27, 2006Date of Patent: January 10, 2012Assignee: Dow Corning Toray Company, Ltd.Inventor: Hiroshi Fukui
-
Patent number: 8093339Abstract: Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it.Type: GrantFiled: June 27, 2007Date of Patent: January 10, 2012Assignee: Bluestar Silicones France SASInventors: John White, Michel Feder, Alain Pouchelon, Yassine Maadadi, Lucile Gambut-Garel
-
Patent number: 8088878Abstract: ?-cyclopentadienyl-tri(?-hydrocarbyl) platinum compounds in which the cyclopentadienyl ring is linked to a hydrolysable silyl group by an alkylene group are effective light-activated hydrosilylation catalysts which are also non-volatile.Type: GrantFiled: January 22, 2009Date of Patent: January 3, 2012Assignee: Wacker Chemie AGInventor: Andreas Koellnberger
-
Patent number: 8088852Abstract: An oily surface adhesive room temperature curing type organopolysiloxane composition includes: (A) at least one of organopolysiloxanes represented by specific general formulas; (B) heavy calcium carbonate of which the surfaces have been treated with a fatty acid and/or paraffin treating agent; (C) an oil-absorbing carbon powder; (D) a silane represented by a specific general formula or a partial hydrolyzate; (E) a curing catalyst; and (F) an organic compound having one isocyanate group in its molecule.Type: GrantFiled: July 28, 2009Date of Patent: January 3, 2012Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tadashi Araki, Tsuneo Kimura
-
Patent number: 8076427Abstract: Use of release fluids or agents constituting hyperbranched polymers. The three-dimensional structure imparts characteristics that make the hyperbranched polymers useful in xerographic processes. The hyperbranched polymer release fluids or agents may be used with a fuser member having a substrate, an outer layer covering the substrate, and a release coating on the outer layer, wherein the release coating includes a hyperbranched polymer.Type: GrantFiled: January 12, 2009Date of Patent: December 13, 2011Assignee: Xerox CorporationInventors: David J. Gervasi, George Riehle, Samuel Kaplan
-
Publication number: 20110301306Abstract: A compound having the formula below. Each R is methyl or phenyl; R2 comprises one or more of silane, siloxane, and aromatic groups; n is a nonnegative integer; and m is 1 or 2. The dashed bond is a single bond and the double dashed bond is a double bond, or the dashed bond is a double bond and the double dashed bond is a triple bond. A polymer made by a hydrosilation reaction of a polyhedral oligomeric silsesquioxane having pendant siloxane groups with an acetylene- and silicon-containing compound having at least two vinyl or ethynyl groups, and a crosslinked polymer thereof. The reaction occurs between the pendant siloxane groups and the vinyl or ethynyl groups.Type: ApplicationFiled: August 17, 2011Publication date: December 8, 2011Applicant: The Government of the United States of America, as represented by the Secretary of the NavyInventors: Manoj K. Kolel-Veetil, Teddy M. Keller
-
Patent number: 8058351Abstract: A process for producing low molecular weight polymers, the process comprising partially hydrogenating an unsaturated polymer to form a partially hydrogenated polymer, and reacting the partially hydrogenated polymer with an acyclic alkene in the presence of a metathesis catalyst.Type: GrantFiled: May 19, 2006Date of Patent: November 15, 2011Assignee: Bridgestone CorporationInventors: James Pawlow, James Hall, Jason Poulton
-
Patent number: 8048977Abstract: The present invention is directed to compositions and processes that are useful in making organosilicon polymers, including cross-linked organosilicon networks. The invention is also directed to articles that incorporate the cross-linked organosilicon networks.Type: GrantFiled: April 28, 2006Date of Patent: November 1, 2011Assignee: E. I. du Pont de Nemours and CompanyInventors: Kenneth Gene Moloy, Lech Wilczek
-
Patent number: 8044161Abstract: The present invention relates to the use of tocopherol as a co-catalyst in the ring opening polymerisation of cyclic siloxanes. The present invention further relates to a method for manufacturing hydrophilic polysiloxanes, wherein a hydrido-containing cyclic siloxane is reacted with a hydrophilic molecule comprising a carbon-carbon double bond, having the general formula (I) H2C?CH—(CHR)n—O—(CHR1CR2R3)mR4 or (II) H2C?CH—(CHR)n—R5, wherein n is an integer from 0 to 4, m is an integer from 0 to 5, R, R1, R2, R3 and R4 are each independently hydrogen or a C1 to C6 alkyl, R5 is a saturated cyclic hydrocarbon containing carbonyl group, in the presence of a first catalyst to obtain a monomer, and polymerising said monomer in the presence of a second catalyst and tocopherol as a co-catalyst.Type: GrantFiled: March 11, 2008Date of Patent: October 25, 2011Assignee: Bayer Shering Pharma OyInventors: Emilia Tiitinen, Harri Jukarainen
-
Patent number: 8034891Abstract: A novel polyether-modified organopolysiloxane and a novel diorganopolysiloxane-polyether block copolymer are more resistant to oxidation than the heretofore existing polyoxyalkylene-modified organopolysiloxanes and are thus more resistant to producing allergenically antigenic oxidation products during elapsed time in storage. Methods of producing this novel polyether-modified organopolysiloxane and novel diorganopolysiloxane-polyether block copolymer are also provided, as well as cosmetic that the modified organopolysiloxane or diorganopolysiloxane-polyether block copolymer.Type: GrantFiled: May 17, 2007Date of Patent: October 11, 2011Assignee: Dow Corning Toray Company, Ltd.Inventor: Tadashi Okawa
-
Patent number: 8029904Abstract: A curable aryl (thio)ether aryl silicon composition is disclosed. A cured aryl (thio)ether aryl polysiloxane composition is further disclosed, along with a method of making that cured aryl (thio)ether aryl polysiloxane composition from the curable aryl (thio)ether aryl silicon composition. An encapsulated semiconductor device, and a method of making that encapsulated semiconductor device by coating a semiconductor element of a semiconductor device with cured aryl (thio)ether aryl polysiloxane are further disclosed.Type: GrantFiled: November 8, 2007Date of Patent: October 4, 2011Assignee: Rohm and Haas CompanyInventors: David Wayne Mosley, Garo Khanarian
-
Patent number: 8025870Abstract: The present invention is directed to a series of vinyl ether based silicone polymers and their use in personal care applications. They are prepared by the hydrosilylation reaction of a vinyl ether and a silanic hydrogen compound. The compounds find use in personal care applications.Type: GrantFiled: July 2, 2009Date of Patent: September 27, 2011Assignee: Siltech CorporationInventors: Kevin Anthony O'Lenick, Anthony J. O'Lenick, Jr.
-
Patent number: 8013095Abstract: Ru(0) complexes containing sulfoxide ligands and aliphatically unsaturated ligands are effective hydrosilylation catalysts useful in particular for addition curing organosilicon compositions.Type: GrantFiled: May 25, 2009Date of Patent: September 6, 2011Assignee: Wacker Chemie AGInventors: Marco Hofmann, Hans-Juergen Elberle
-
Patent number: 7999053Abstract: A process for preparing aldehyde functional organopolysiloxanes and the products prepared therefrom is disclosed. The process involves a hydrosilylation reaction between an aldehyde having a non -conjugated unsaturated group with a polyorganohydrogensiloxane.Type: GrantFiled: July 5, 2006Date of Patent: August 16, 2011Assignee: Dow Corning CorporationInventors: Lori Jean Sutton, John Joseph Kennan
-
Patent number: 7999127Abstract: A process for preparing a cationically photopolymerizable siloxane oligomer, that includes: combining a platinum group catalyst, a hydrosiloxane compound selected from and a vinyl or allyl compound comprising a cationically photopolymerizable functionality; and then contacting the product with oxygen in the presence of the catalyst to form the cationically photopolymerizable multifunctional siloxane oligomer. R1 and R3 are independently fluoroethyl, methyl or phenyl.Type: GrantFiled: March 4, 2009Date of Patent: August 16, 2011Assignee: Rensselaer Polytechnic InstituteInventor: James V. Crivello
-
Patent number: 7999033Abstract: A thermoconductive silicone elastomer comprising a silicone elastomer being a cured body of a hydrosilation-curable organopolysiloxane composition, a reinforcing fine powder silica, a thermoconductive inorganic powder, and a non-reactive organopolysiloxane that is liquid at room temperature which are dispersed in the aforementioned silicone elastomer; a thermoconductive medium comprising the aforementioned thermoconductive silicone elastomer; a hydrosilation-curable thermoconductive silicone elastomer composition comprising a hydrosilation-curable organopolysiloxane composition, a reinforcing fine powder silica, a thermoconductive inorganic powder, and a non-reactive organopolysiloxane that is liquid at room temperature.Type: GrantFiled: September 29, 2005Date of Patent: August 16, 2011Assignee: Dow Corning Toray Company, Ltd.Inventor: Kazuhiro Sekiba
-
Publication number: 20110178263Abstract: A fluoropolyether adhesive composition comprising (A) a linear polyfluoro compound having at least two alkenyl groups and a perfluoropolyether structure in its main chain, (B) a fluorinated organohydrogensiloxane containing at least two SiH groups, but not alkoxy and epoxy groups, (C) a platinum group metal-based catalyst, (D) an organosilicon compound having at least one silicon-bonded alkoxy group, and (E) a hydrolytic catalyst can be cured to metal and plastic substrates through addition reaction.Type: ApplicationFiled: January 14, 2011Publication date: July 21, 2011Applicant: Shin-Etsu Chemical Co., Ltd.Inventors: Hidenori KOSHIKAWA, Mikio Shiono
-
Patent number: 7968666Abstract: An asymmetric siloxane is made by reacting a silicone having the formula MHDxM?H where MH is R1R2HSiO1/2, M?H is R4R5HSiO1/2 and x is an integer 0?x?10 under selective hydrosilylation conditions in the presence of a precious metal hydrosilylation catalyst, with a first olefinic compound and in a second step, a monohydridosiloxane produced in the first step is reacted under hydrosilylating conditions with another olefinic compound different from the first olefinic compound. The formed asymmetric siloxane is incorporated into a composition in need of hydrolysis resistance.Type: GrantFiled: January 29, 2010Date of Patent: June 28, 2011Assignee: Momentive Performance Materials Inc.Inventors: David D Farris, Chauncey J Rinard, Mark D Leatherman
-
Patent number: 7956121Abstract: A thermoconductive silicone elastomer comprising a silicone elastomer being a cured body of a hydrosilation-curable organopolysiloxane composition, a reinforcement fine silica powder, a thermoconductive inorganic powder, and an alkylphenylpolysiloxane that is liquid at room temperature. A hydrosilation-curable thermoconductive silicone elastomer composition comprising: a hydrosilation-curable organopolysiloxane composition, a reinforcement fine silica powder, a thermoconductive inorganic powder, and an alkylphenylpolysiloxane that is liquid at room temperature. A thermoconductive medium comprising the aforementioned thermoconductive silicone elastomer.Type: GrantFiled: August 29, 2005Date of Patent: June 7, 2011Assignee: Dow Corning Toray Company, Ltd.Inventor: Kazuhiro Sekiba
-
Patent number: 7951891Abstract: A silicone resin composition for die bonding is provided. The composition includes (A) a straight-chain organopolysiloxane having silicon-bonded alkenyl groups, and with a viscosity of no more than 1,000 mPa·s, (B) a three dimensional network-type organopolysiloxane resin that is either wax-like or solid at 23° C., (C) an organohydrogenpolysiloxane having SiH groups, and (D) a platinum-group metal-based catalyst. The composition produces a cured product with a high hardness, and good heat resistance, transparency, and light transmittance in the low wavelength region.Type: GrantFiled: June 6, 2006Date of Patent: May 31, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kei Miyoshi, Tomoyuki Goto, Naoki Yamakawa
-
Patent number: 7947798Abstract: An asymmetric siloxane is made by reacting a silicone having the formula MHDxM?H where MH is R1R2HSiO1/2. M?H is R4R5HSiO1/2 and x is an integer 0?x?10 under selective hydrosilylation conditions in the presence of a precious metal hydrosilylation catalyst, with a first olefinic compound and in a second step, a monohydridosiloxane produced in the first step is reacted under hydrosilylating conditions with another olefinic compound different from the first olefinic compound.Type: GrantFiled: May 28, 2007Date of Patent: May 24, 2011Inventors: David D Farris, Chauncey J Rinard, Mark D Leatherman
-
Patent number: 7943721Abstract: Methods are disclosed of making linear and cross-linked, HMW (high molecular weight) polysilanes and polygermanes, polyperhydrosilanes and polyperhydrogermanes, functional liquids containing the same, and methods of using the liquids in a range of desirable applications. The silane and germane polymers are generally composed of chains of Si and/or Ge substituted with R? substituents, where each instance of R? is, for example, independently hydrogen, halogen, alkenyl, alkynyl, hydrocarbyl, aromatic hydrocarbyl, heterocyclic aromatic hydrocarbyl, SiR?3, GeR?3, PR?2, OR?, NR?2, or SR?; where each instance of R? is independently hydrogen or hydrocarbyl. The cross-linked polymers can be synthesized by dehalogenative coupling or dehydrocoupling. The linear polymers can be synthesized by ring-opening polymerization. The polymers can be further modified by halogenation and/or reaction with the source of hydride to furnish perhydrosilane and perhydrogermane polymers, which are used in liquid ink formulations.Type: GrantFiled: October 5, 2006Date of Patent: May 17, 2011Assignee: Kovio, Inc.Inventor: Vladimir K. Dioumaev
-
Patent number: 7943720Abstract: A method of manufacturing a purified product of a liquid medium-chain alkyl-modified polydimethylsiloxane that is free of a specific (unpleasant) odor and is practically odorless, the method comprising the steps of: [A] synthesizing a liquid medium-chain alkyl-modified polydimethylsiloxane by carrying out a hydrosilylation reaction between a hydrosilyl-containing polydimethylsiloxane and an ?-olefin with 4 to 18 carbon atoms; and [B] subjecting a crude product of the liquid medium-chain alkyl-modified polydimethylsiloxane obtained in preceding step [A] to an odor-removing treatment by conducting a hydrogenation reaction which is carried out in the presence of a hydrogenation catalyst.Type: GrantFiled: February 16, 2005Date of Patent: May 17, 2011Assignee: Dow Corning Toray Company, Ltd.Inventors: Seiki Tamura, Yasuhiro Kaneta
-
Patent number: 7939614Abstract: A curable composition which comprises at least one of the following (A), (B), and (C) and further contains (D) (provided that when (C) is not contained, both (A) and (B) are in the composition. (A): A silicon-containing polymer in which the content of components having a weight-average molecular weight of 1,000 or lower is 20 wt. % or lower and which has a reactive group A? and one or more Si—O—Si bonds. (B): A silicon-containing polymer in which the content of components having a weight-average molecular weight of 1,000 or lower is 20 wt. % or lower and which has an Si—H group and one or more Si—O—Si bonds. (C): A silicon-containing polymer in which the content of components having a weight-average molecular weight of 1,000 or lower is 20 wt. % or lower and which has a reactive group A?, an Si—H group, and one or more Si—O—Si bonds. (D): A catalyst for curing reaction which is a platinum catalyst.Type: GrantFiled: May 10, 2005Date of Patent: May 10, 2011Assignees: Adeka Corporation, Kansai Electric Power Company, Inc.Inventors: Takashi Sueyoshi, Ken-Ichiro Hiwatari, Tadashi Janado, Yoshikazu Shoji, Yoshitaka Sugawara
-
Patent number: 7935386Abstract: An aqueous polyorganosiloxane (POS) emulsion which can easily be deposited on/applied to a fibrous substrate at high speed and at limited deposition rates, for example less than 40 g/m2. The emulsion contains (A) a POS with ?Si-vinyl units, (B) a POS with ?SiH units, (C) an adhesion promoter, (D) a catalyst, (E) at least one surfactant, (F) optionally a POS resin with ?Si-vinyl units, (G) optionally a crosslinking inhibitor, (H) optionally a pH fixing agent, (I) optionally a formulating additive, (J) optionally a filler, and (K) water. Adhesion promoter (C) is selected from protective hydrocolloids, hydroxylated silanes and/or POS carrying at least one hydroxyl group and at least one salified amino group per molecule, and mixtures thereof, and is present in the range from 0.005 to 10% by weight, based on the silicone phase. Also disclosed is the corresponding coating process and the coated substrate.Type: GrantFiled: February 1, 2008Date of Patent: May 3, 2011Assignee: Rhodia ChimieInventors: Laurent Dumont, Michel Feder, Francis Lafaysse, Sylvie Robelin
-
Patent number: 7932097Abstract: A method of manufacturing an analytical sample by a secondary ion mass spectrometry method is provided, which comprises a step of forming a separation layer over a substrate, a step of forming one of a thin film and a thin-film stack body to be analyzed over the separation layer, a step of forming an opening portion in one of the thin film and the thin-film stack body, a step of attaching a supporting body to one of a surface of the thin film and a surface of a top layer of the thin-film stack body, and a step of separating one of the thin film and the thin-film stack body from the substrate.Type: GrantFiled: October 20, 2010Date of Patent: April 26, 2011Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Satoshi Toriumi