Each Of The Carboxylic Acids Or Derivatives Contains An Aryl Group Patents (Class 528/305)
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Publication number: 20120161358Abstract: The invention relates to a process for making polyethylene terephthalate (PET) from ethylene glycol (EG), purified terephthalic acid (PTA) and optionally up to 6 mol % comonomer, using a mixed metal catalyst system and comprising the steps of a) esterifying EG and PTA to form diethyleneglycol terephthalate and oligomers (DGT), and b) melt-phase polycondensing DGT to form PET and EG, wherein the catalyst system substantially consists of 70-160 ppm of Sb-compound, 20-70 ppm of Zn-compound, and 0.5-20 ppm of Ti-glycolate as active components (ppm metal based on PET). With this process that applies reduced amount of metal catalyst components PET can be obtained with high productivity, which polyester shows favourable colour and optical clarity, also if recycling of EG is applied within the process.Type: ApplicationFiled: August 17, 2010Publication date: June 28, 2012Applicant: SAUDI BASIC INDUSTRIES CORPORATIONInventors: Munif Al-Munif, Mummaneni Venkateswara Rao, Zahir Bashir, Suresh Padmanabhan
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Patent number: 8207289Abstract: Polyester compositions, especially polyethylene terephthalate homopolymer and copolymers, are disclosed containing titanium catalysts and catalyst deactivator added late in the manufacturing processing having reduced acetaldehyde generation rates. The polyester compositions are low in free acetaldehyde, making them suitable for fabrication into beverage containers for relatively tasteless beverages such as bottle water. Furthermore, the polyesters are polymerized to a high inherent viscosity in reduced processing time, without the necessity of further polymerization in the solid state, and in the absence of acetaldehyde scavengers leading to polyester polymers having reduced color.Type: GrantFiled: May 23, 2007Date of Patent: June 26, 2012Assignee: Grupo Petrotemex, S.A. de C.V.Inventor: Mary Therese Jernigan
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Patent number: 8193302Abstract: Described as one aspect of the invention are polyester compositions containing: (I) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3 -cyclobutanediol residues; and (ii) 1 to 99 mole % of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %.Type: GrantFiled: October 27, 2006Date of Patent: June 5, 2012Assignee: Eastman Chemical CompanyInventors: Ted Calvin Germroth, Gary Wayne Connell, Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, Benjamin Fredrick Barton, Damon Bryan Shackelford
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Patent number: 8168302Abstract: A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.Type: GrantFiled: November 10, 2008Date of Patent: May 1, 2012Assignee: 3M Innovative Properties CompanyInventors: Timothy J. Hebrink, William W. Merrill, Carl A. Stover
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Patent number: 8163843Abstract: A description is given of the preparation of high molecular mass, crystalline copolyesters with high solubility in non-halogenated and non-aromatic solvents, and of their use in adhesives.Type: GrantFiled: January 8, 2008Date of Patent: April 24, 2012Assignee: Evonik Degussa GmbHInventors: Gabriele Brenner, Rene Koschabek, Georg Becker
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Publication number: 20120095183Abstract: A method of preparing a wholly aromatic liquid crystalline polyester resin and a method of preparing a wholly aromatic liquid crystalline polyester resin compound. The method of preparing the wholly aromatic liquid crystalline polyester resin includes condensation poly-merizing raw 1 monomers including aromatic hydroxy carboxylic acid and a mixture of aromatic diol and aromatic dicarboxylic acid in a predetermined molar ratio.Type: ApplicationFiled: June 16, 2010Publication date: April 19, 2012Applicant: SAMSUNG FINE CHEMICALS CO., LTD.Inventors: Sun Hwa Chang, Mi Jeong Kim, Mahn Jong Kim, Youn Eung Lee, Young Hak Shin, Jin Kyu Lee
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Patent number: 8133967Abstract: Described are restaurant smallware, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.55 to 0.0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 110° C. to 160° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate.Type: GrantFiled: October 7, 2010Date of Patent: March 13, 2012Assignee: Eastman Chemical CompanyInventors: Thomas Joseph Pecorini, Douglas Stephens McWilliams, Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Publication number: 20120043248Abstract: There is provided a thermally shrinkable polyester film where the opening ability along the perforation is very good. A thermally shrinkable polyester film comprising polyester resin in which ethylene terephthalate is a main constituting component and not less than 13 molar % of one or more monomer component (s) which can become non-crystalline component is/are contained in the total polyester resin components, wherein the film has specific thermally shrinking characteristics and specific mechanical characteristics after thermal shrinking treatment.Type: ApplicationFiled: May 6, 2010Publication date: February 23, 2012Applicant: TOYO BOSEKI KABUSHIKI KAISHAInventors: Masayuki Haruta, Yukinobu Mukoyama, Katsuhiko Nose
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Patent number: 8119761Abstract: Described are polyester compositions comprising at least one polyester which comprises terephthalic acid residues in the amount from 80 to 100 mole %, 2,2,4,4-tetramethyl-1,3- cyclobutanediol in the preferable amount from 30 to 40 mole % and 1,4-cyclohexanedimethanol in the preferable amount from 60 to 70 mole % , wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mote %; and the inherent viscosity of polyester is from 0.55 to 0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachtoroethane at a concentration of 0.5 g/100 ml at 25° C., polyester has a Tg from 110 to 160° C. and polyester composition comprises no polycarbonate. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.Type: GrantFiled: March 28, 2006Date of Patent: February 21, 2012Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8119762Abstract: Described are film or sheet, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.55 to 0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 110° C. to 160° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate.Type: GrantFiled: November 10, 2010Date of Patent: February 21, 2012Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8110609Abstract: The invention relates to a composition comprising a modified, random copolyetherester containing a modified, random polytrimethylene terephthalate copolymer block that is derived from a polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and combinations thereof; and contains at least one residue derived from the polyethylene terephthalate component; and a polyalkylene oxide copolymer block that contains polyalkylene oxide and at least one residue derived from the polyethylene terephthalate component.Type: GrantFiled: August 9, 2010Date of Patent: February 7, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Michael Determan, Ganesh Kannan, Kenneth Frederick Miller, Dhaval Shah
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Patent number: 8106148Abstract: A series of resins were synthesized using a range of bio-based materials to control the molecular architecture, and therefore the properties, of the inventive resins. The utility of these resins was demonstrated in the formulation of powder coatings, such as ?-hydroxy amide crosslinked and hybrid types. Generally, the bio-based resins flowed out on heating faster than conventional petrochemically-based resins, allowing the use of lower temperatures in the curing oven than is typically possible and a more active catalyst system, especially in the carboxylic acid-epoxy crosslinked hybrid coatings formulations.Type: GrantFiled: March 20, 2006Date of Patent: January 31, 2012Assignee: Battelle Memorial InstituteInventors: Bhima R. Vijayendran, Jerry L. King, II, Katherine P. Mitchell, Michael C. Clingerman, Jeffrey T. Cafmeyer
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Patent number: 8101705Abstract: Described are articles, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.60 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 100° C. to 130° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate. Composition can be manufactured into articles as fibers, films, bottles or sheets.Type: GrantFiled: May 20, 2010Date of Patent: January 24, 2012Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephen McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8097685Abstract: The present invention is directed to a hyperbranched-polyester comprising at least one kind of a structural unit selected from an aromatic oxycarbonyl unit (P), aromatic and/or aliphatic dioxy units (Q), and an aromatic dicarboxy unit (R), and a trifunctional or higher polyfunctional organic residue (B), wherein the content of B is within a range from 7.5 to 50 mol % based on entire monomers constituting the hyperbranched-polyester. The present invention provides a hyperbranched-polyester which can remarkably improve thin-wall flowability, stiffness and gas barrier property by blending with a thermoplastic resin, and a thermoplastic resin composition blended with the same.Type: GrantFiled: March 30, 2007Date of Patent: January 17, 2012Assignee: TORAY Industries, Inc.Inventors: Koji Tachikawa, Makito Yokoe, Mitsushige Hamaguchi, Makiko Saito, Hideo Matsuoka, Toru Yamanaka
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Patent number: 8084134Abstract: Disclosed herein is a thermoplastic composition comprising a combination of: a polysiloxane-polycarbonate copolymer and a poly(aliphatic ester)-polycarbonate copolymer comprising soft block ester units of the formula (8a): wherein m is 4 to 18, wherein the thermoplastic composition has a melt volume rate of 14 cc/10 min to 22 cc/10 min at 300° C. and under a load of 1.2 Kg and a dwell time of 6 minutes, according to ASTM D1238-04, wherein an article molded from the thermoplastic composition and having a thickness of 3.2 mm has a percent transmittance of greater than 85% according to ASTM D1003-00, and wherein 100% of a set of five test articles each having a thickness of 3.2 mm and molded from the thermoplastic composition exhibit ductile fracture at ?40° C. when measured for notched Izod Impact according to ASTM D256-04. An article comprising the thermoplastic composition is also disclosed.Type: GrantFiled: November 26, 2008Date of Patent: December 27, 2011Assignee: Sabic Innovative Plastics IP B.V.Inventors: Jon M. Malinoski, Sriramakrishna Maruvuda, Anirudha Singh
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Publication number: 20110306730Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and cyclohexanedimethanol residues. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.Type: ApplicationFiled: August 23, 2011Publication date: December 15, 2011Applicant: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8067525Abstract: Described are film(s) and/or sheet(s) comprising polyesters comprising (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: November 29, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8063172Abstract: Described are film(s) and/or sheet(s) made using polyester compositions comprising polyesters comprising (a) a dicarboxylic acid component comprising 70 to 100 mole % of terephthalic acid residues, and up to 30 mole % of aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; and (b) a glycol component comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: November 22, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8063173Abstract: Described as one aspect of the invention are polyesters containing (a) a dicarboxylic acid component having from 70 to 100 mole % of terephthalic acid residues and up to 30 mole % of aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; and (b) a glycol component having from 11 to 25 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, and 75 to 89 mole % of 1,4-cyclohexanedimethanol residues; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %. The polyesters may be manufactured into articles.Type: GrantFiled: March 28, 2006Date of Patent: November 22, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8012571Abstract: The present invention relates to multilayer optical films and birefringent copolyester films. The birefringent copolyester optical layer or birefringent copolyester film comprises a major amount of naphthalate units, ethylene units, and a minor amount of branched or cyclic C4 to C10 alkyl units. Also described are certain copolyester polymeric materials further comprising subunits of a phthalate ionomer such as dimethyl sulfosodium isophthtalate ionomer.Type: GrantFiled: May 2, 2008Date of Patent: September 6, 2011Assignee: 3M Innovative Properties CompanyInventors: Yufeng Liu, David T. Yust, Stephen A. Johnson, Kristopher J. Derks
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Patent number: 7985827Abstract: Described are polyester compositions comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, wherein said 2,2,4,4-tetramethyl-1,3-cyclobutanediol contains certain cis to trans ratios; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: July 26, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Publication number: 20110178239Abstract: Polymer obtainable by polycondensation or polyadduct formation from monomeric compounds, wherein accompanying use is made as monomeric compound of substituted 2-aryl-2-alkyl-1,3-propanediols of the formula I or substituted 2-cyclohexyl-2-alkyl-1,3-propanediols of the formula Ia or the alkoxylated derivatives of the formula I or of the formula Ia.Type: ApplicationFiled: August 24, 2009Publication date: July 21, 2011Applicant: BASF SEInventors: Darijo Mijolovic, Sebastien Garnier, Qiang Miao, Maria Guixa Guardia, Gerd-Dieter Tebben
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Publication number: 20110130480Abstract: The present invention relates to a polyester composition comprising a diacid component and a diol component, wherein the diacid component comprises: i) isophthalic acid present at a concentration in the range of from about 23 mole % to about 30 mole % of the total diacid, and ii) terephthalic acid; and wherein the diol component comprises: i) diethylene glycol present at a concentration in the range of from about 1.1 mole % to about 3.5 mole % of the total diol, and ii) ethylene glycol. Other embodiments of the present invention include a film produced from the polyester composition and processes for producing the film.Type: ApplicationFiled: July 2, 2009Publication date: June 2, 2011Inventor: Uwe Bayer
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Publication number: 20110130515Abstract: A molding produced by a layer-by layer process of selectively melting regions of a respective pulverulent layer via unfocused introduction of electromagnetic energy, using a polymer powder, where the powder has at least one thermoplastic random copolymer with an ISO 1133 MFR value of from 12 to 1 g/10 min.Type: ApplicationFiled: February 10, 2011Publication date: June 2, 2011Applicant: DEGUSSA AGInventors: Sylvia MONSHEIMER, Franz-Erich Baumann, Maik Grebe, Eva Von Der Bey
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Patent number: 7951900Abstract: Described are dialysis filter housings comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: May 31, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Patent number: 7939174Abstract: A film roll of a heat-shrinkable polyester film characterized in that the heat-shrinkable polyester film meets the following requirements (1) and (2). (1) When samples are cut off therefrom at an almost equal interval along the longitudinal direction, and immersed in hot water at 85° C. for 10 seconds, subsequently in water at 25° C. and withdrawn, heat-shrinkage percentages in the maximum shrinkage direction of all the samples are 20% or more. (2) When raw polymers used for production of the film above comprises of a major constitutional unit and one or more sub constitutional units different therefrom; and the content of the primary sub constitutional unit is determined, the content of the primary sub constitutional unit in each sample is more than 7 mole % in 100% of all constitutional units, and when an average of the contents of the primary sub constitutional unit is calculated, the contents thereof of all the samples fall within a range of ±2 mole % relative to the average.Type: GrantFiled: June 23, 2005Date of Patent: May 10, 2011Assignee: Toyo Boseki Kabushiki KaishaInventors: Satoshi Hayakawa, Norimi Tabota, Yoshinori Takegawa, Katsuya Ito, Shigeru Komeda, Katsuhiko Nose
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Publication number: 20110086212Abstract: This invention relates to certain poly(1,4-cyclohexylenedimethylene terephthalate) copolyesters which are useful for the preparation of clear and tough thick wall molded parts, produced at good cycle times. The copolyesters can be molded into desired shapes such as cosmetic jars, fragrance caps, tool handles, and toothbrushes. These molded articles can have thick or thin walls and may be molded in a two shot molding process. The copolyesters also have good flow and reduced cycle times.Type: ApplicationFiled: July 13, 2010Publication date: April 14, 2011Applicant: EASTMAN CHEMICAL COMPANYInventors: Alisa Annette Williams, Mark Allan Treece, Ludovic Claude Robert Gardet, Gary Michael Stack
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Patent number: 7919224Abstract: A coating material including a low-molecular or medium-molecular organic compound represented by general formula (1). (In the formula, R1 is a single bond, methylene, ethylene or oxygen; and R2 is a hydrogen atom, or a hydrocarbon group, a fluorine-containing alkyl group, a cyclic form containing an aromatic group or aliphatic group, which may contain hydroxy group, carboxyl group, amino group, amide group, imide group, glycidyl group, cyano group, fluorocarbinol group, sulfonic group or sulfonylamide group, and a complex thereof, and may contain a fluorine atom, oxygen atom, nitrogen atom, silicon atom or sulfur atom, and R2's of the same type or different type may be connected by an ester bond, amide bond, ether bond, thioether bond, thioester bond or urethane bond.). This compound can be derived from a diol compound and bicyclo[2.2.2]octane-2,3:5,6-tetracarboxylic anhydride.Type: GrantFiled: September 5, 2006Date of Patent: April 5, 2011Assignee: Central Glass Company, LimitedInventors: Satoru Miyazawa, Satoru Kobayashi, Kazuhiko Maeda
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Patent number: 7915376Abstract: Described are bottle(s) comprising polyesters comprising (a) a dicarboxylicacid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: March 29, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, David Scott Porter, Gary Wayne Connell, Michael James Keegan
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Patent number: 7906610Abstract: Described are food storage containers comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: March 15, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Patent number: 7902320Abstract: Described are graphic art films comprising a polyester compositions comprising at least one polyester, comprising dicarboxylic acid component comprising 70 to 100 mole % of terephthalic acid residues and a glycol component comprising: 20 to 30 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and 70 to 80 mole % of 1,4-cyclohexanedimethanol residues, wherein the total mole % of the dicarboxylic acid component is 100 mole %, the total mole % of the glycol component is 100 mole %, and polyester has following properties: the inherent viscosity of the polyester is from 0.60 to 0.75 dL/g; Tg of from 100 to 130° C.; notched Izod impact strength of at least 7.5 ft-b/inch at 23° C. according to ASTM D256; the melt viscosity of the polyester is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C.; and the polyester composition contains no polycarbonate.Type: GrantFiled: March 28, 2006Date of Patent: March 8, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Publication number: 20110054091Abstract: Described are film(s) and/or sheet(s) comprising polyesters comprising (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: ApplicationFiled: November 10, 2010Publication date: March 3, 2011Applicant: EASTMAN CHEMICAL COMPANYInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 7893187Abstract: Described are glass laminates comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: February 22, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Patent number: 7893188Abstract: Described are baby bottle(s) comprising polyesters comprising (a) a dicarboxylic acid component having terephthalic acid or an ester thereof; optionally, an aromatic dicarboxylic acid or aliphatic dicarboxylic acid or esters thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and 1,4-cyclohexanedimethanol.Type: GrantFiled: March 28, 2006Date of Patent: February 22, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, David Scott Porter, Gary Wayne Connell, Michael James Keegan
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Patent number: 7868128Abstract: Described are skylights comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: January 11, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 7855267Abstract: Described are film(s) and/or sheet(s) comprising polyesters comprising (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: December 21, 2010Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Publication number: 20100300918Abstract: Described are bottles comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: ApplicationFiled: August 10, 2010Publication date: December 2, 2010Applicant: EASTMAN CHEMICAL COMPANYInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, David Scott Porter, Gary Wayne Connell, Michael James Keegan
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Patent number: 7842776Abstract: Described are appliance parts comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: November 30, 2010Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Patent number: 7838620Abstract: Described are thermoformed films or sheets comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylicacidcomponent having terephthalic acid or an ester thereof; optionally, an aromatic dicarboxylic acid or aliphatic dicarboxylic acid or esters thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and 1,4-cyclohexanedimethanol.Type: GrantFiled: March 28, 2006Date of Patent: November 23, 2010Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 7834129Abstract: Described are restaurant smallware comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: November 16, 2010Assignee: Eastman Chemical CompanyInventors: Thomas Joseph Pecorini, Douglas Stephens McWilliams, Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Patent number: 7816014Abstract: The present invention provides a liquid crystalline polyester comprising (a) a repeating unit derived from aromatic hydroxycarboxylic acid, (b) a repeating unit derived from aromatic dicarboxylic acid and (c) a repeating unit represented by —X—Ar1-O—Ar1-Y—, wherein Ar1 represents 1,4-phenylene which may be substituted by a halogen atom, an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 20 carbon atoms, and X and Y independently represent O or NH. The polyester in the preset invention has a sufficiently low dielectric constant and/or is a sufficiently high resistance in hydrolysis.Type: GrantFiled: January 13, 2006Date of Patent: October 19, 2010Assignee: Sumitomo Chemical Company, LimitedInventors: Toyonari Ito, Tomoya Hosoda, Satoshi Okamoto
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Patent number: 7812112Abstract: Described are outdoor signs comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: October 12, 2010Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 7812111Abstract: Described are LCD films or sheets comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: October 12, 2010Assignee: Eastman Chemical CompanyInventors: Wesley Raymond Hale, Thomas Joseph Pecorini, Douglas Stephens McWilliams, Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Patent number: 7807775Abstract: Described are point of purchase displays comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: October 5, 2010Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 7807774Abstract: Described are vending machine display panels comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: October 5, 2010Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 7803439Abstract: Described are blood therapy containers comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: September 28, 2010Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Patent number: 7803441Abstract: Described are intravenous components comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: September 28, 2010Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Patent number: 7803440Abstract: Described are bottles comprising polyester compositions comprising polyesters which comprise (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues or ester residues thereof; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: September 28, 2010Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, David Scott Porter, Gary Wayne Connell, Michael James Keegan
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Patent number: 7781562Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.Type: GrantFiled: March 28, 2006Date of Patent: August 24, 2010Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Publication number: 20100168370Abstract: Disclosed herein is a camera lens comprising a thermoplastic composition comprising a poly(aliphatic ester)-polycarbonate copolymer comprising soft block ester units derived from an alpha, omega C6-20 aliphatic dicarboxylic acid or derivative thereof, a dihydroxyaromatic compound, and a carbonate source, wherein the thermoplastic composition has a melt volume rate of 13 to 25 cc/10 min at 250° C. and under a load of 1.2 Kg and a dwell time of 6 minutes, according to ASTM D1238-04, and wherein the camera lens has an effective lens area of 0.5 to 100 mm2. A method of making the camera lens, and a camera lens comprising a thermoplastic composition comprising a redistribution product of a poly(aliphatic ester)-polycarbonate, are also disclosed.Type: ApplicationFiled: December 31, 2008Publication date: July 1, 2010Inventors: Akiro Hatano, Theodorus Lambertus Hoeks, Dennis Karlik, Ken Kuriki, Jon M. Malinoski, Sriramakrishna Maruvuda