Each Of The Carboxylic Acids Or Derivatives Contains An Aryl Group Patents (Class 528/305)
  • Patent number: 6358579
    Abstract: A multiple-pack system composed of a combined pack made from individual packages, where the individual packaging takes place in a biaxially stretch-oriented polypropylene film with modified polyolefinic sealable layers. The characterizing features of the multiple-pack system are that the combined-pack film is composed of a sealable, biaxially stretch-oriented coextruded polyester film having more than one layer, where the sealable outer layer(s) comprise(s) copolyester. In the novel multiple-packed system, the combined-pack film is sealable with itself, but does not seal to the biaxially oriented polypropylene films of the individual packages.
    Type: Grant
    Filed: May 25, 2000
    Date of Patent: March 19, 2002
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Guenther Crass, Ursula Murschall
  • Patent number: 6352783
    Abstract: A copolyester blend resistant to ultraviolet radiation consists essentially of a polyethylene terephthalate based copolyester having 1,4-cyclohexanedimethanol residues; an effective amount of an ultraviolet radiation absorber selected from the group consisting of benzoxazinones, dimeric benzotriazoles, triazines and mixtures thereof; and from about 2 to about 25 mole percent of 4,4′-biphenyldicarboxylic acid residues present in the copolyester wherein the mole percent is based on 100 mole percent of dicarboxylic acid or equivalents. The copolyester blend is useful in making UV radiation resistant thermoformed articles.
    Type: Grant
    Filed: December 13, 1999
    Date of Patent: March 5, 2002
    Assignee: Eastman Kodak Company
    Inventor: David Richard Fagerburg
  • Patent number: 6352761
    Abstract: A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The second set of optical layers comprise copolyesters wherein 0.01 to 2.5 mol % of the combined carboxylate and glycol subunits are carboxylate subunits derived from compounds having three or more carboxylate or ester functionalities, glycol subunits derived from compounds having three or more hydroxyl functionalities, or combinations thereof.
    Type: Grant
    Filed: January 15, 1999
    Date of Patent: March 5, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Timothy J. Hebrink, William W. Merrill, Carl A. Stover
  • Patent number: 6258452
    Abstract: Transparent, articles, in particular sheets, having a thickness greater than 5 mm obtained from polyalkylene terephthalate/isophthalate resin containing 5-20% of isophthalic, acid units,. characterised by an intrinsic viscosity greater than 0.8 dl/g; a melt strength at 280° C. greater than 1 cN and a melt viscosity at 280° C. greater than 2000 Pa·s for shear rates tending to zero and not less than 200 Pa·s for shear rates of 1000 sec−1.
    Type: Grant
    Filed: January 20, 2000
    Date of Patent: July 10, 2001
    Assignee: Sinco Ricerche S.p.A.
    Inventors: Hussain Al Ghatta, Enrico Ballico, Tonino Severini
  • Patent number: 6147016
    Abstract: A laminate sheet comprising (A) a polyester block copolymer which comprises 20 to 70 wt % of a hard segment consisting of an aromatic polyester and 80 to 30 wt % of a soft segment consisting of an aromatic polyester and (B) cloth on at least one side of which the polyester block copolymer is laminated, the melting point (T,.degree. C.) of the polyester block copolymer satisfying the following expressions: T0-5 >T>T0-60 and T>T'+10 (in which T is defined above, T0 is a melting point (0.degree. C.) of the aromatic polyester constituting the hard segment, and T' is a melting point (.degree. C.) of a random polymer obtained by adding 0.1 wt % of titanium tetrabutoxide to the polyester block copolymer and melting and kneading at 250.degree. C. for 3 hours).
    Type: Grant
    Filed: July 31, 1998
    Date of Patent: November 14, 2000
    Assignee: Teijin Limited
    Inventors: Noritugu Saiki, Hodaka Yokomizo
  • Patent number: 6074758
    Abstract: A poly(hydroxy ester ether) is prepared by reacting a) a diacid containing a hetero moiety of the formula:HO.sub.2 CCH.sub.2 X(RX).sub.y CH.sub.2 CO.sub.2 Hwherein X is selected from the group consisting of --O--, --S--, and NH; y is the whole number 0 or 1; and R is selected from the group consisting of an aromatic moiety and a heterocyclic moiety having from 6 to 30 carbon atoms; andb) a diglycidyl ether generally represented by the formula: ##STR1## wherein R.sup.2 is an aromatic moiety or divalent aliphatic hydrocarbon having 2 to 20 carbon atoms. Films, articles and laminations made from the composition exhibit an oxygen permeability of less than about 8 cc-mil/100 in.sup.2 -24 hour-atmosphere. The present invention is further directed to a miscible blend having the poly(hydroxy ester ether) of the present invention and a second component selected from a saturated polyester of an aromatic diacid, such as PET and PEN.
    Type: Grant
    Filed: November 4, 1999
    Date of Patent: June 13, 2000
    Assignee: Eastman Chemical Company
    Inventor: Robert Boyd Barbee
  • Patent number: 6046253
    Abstract: An ink jet ink composition comprising from about 0.5% to about 30% by weight of a pigment, a carrier and a sulfonated polyester dispersant in a ratio of dispersant:pigment from about 0.1:1 to about 5:1.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: April 4, 2000
    Assignee: Eastman Kodak Company
    Inventors: David Erdtmann, Elizabeth G. Burns, John Dicillo
  • Patent number: 6031065
    Abstract: A method is disclosed of producing a copolymer of polyethylene terephthalate and polyethylene naphthalate. The method comprises esterifying a combination of a diester of naphthalene, terephthalic acid, and ethylene glycol to produce an esterification reaction mixture that includes the alcohol byproduct of the naphthalene diester, distilling the reaction mixture to remove at least a portion of the esterification byproducts from the reaction mixture in the form of a vapor stream of which the majority component is water vapor and which includes the alcohol byproduct of the naphthalate ester in the vapor state, and combusting at least a portion of the vapor stream under conditions sufficient to decompose at least a portion of the alcohol byproduct present in the vapor stream.
    Type: Grant
    Filed: February 2, 1998
    Date of Patent: February 29, 2000
    Assignee: Wellman, Inc.
    Inventors: Carl S. Nichols, Robert Adrian Ellis, James Scott Thomas
  • Patent number: 6015551
    Abstract: The disclosure relates to a copolymer obtainable by radically initiated polymerization of the following: A) 70-99.9 wt. % an olefinically unsaturated C.sub.3 -C.sub.5 monocarboxylic acid, an olefinically unsaturated C.sub.4 -C.sub.8 dicarboxylic acid or its anhydride, or a mixture of such carboxylic acids; with B) 0.1-30 wt. % one or more multiply olefinically unsaturated carboxylic acid derivatives of formula (I)Z--Y--(CHR.sup.3 --CH.sub.2 --X).sub.n --R.sup.4 (I)in which Z is a vinyl or allyl group or structure (a), ##STR1## R.sup.1, R.sup.2 are hydrogen or methyl, R.sup.3 is hydrogen, methyl or ethyl, R.sup.4 is a singly or multiply olefinically unsaturated alkenyl or cycloalkenyl group or a singly or doubly olefinically unsaturated arylalkylene group, X is oxygen or NH, Y is oxygen, NH or N-alkyl, n is a number between 0 and 50; and C) 0-29.9 wt. % other copolymerizable monomers. The proposed copolymer can be used as a thickener or dispergent for aqueous systems.
    Type: Grant
    Filed: June 2, 1998
    Date of Patent: January 18, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Christian Schade, Hans-Ulrich Wekel, Axel Sanner, Karin Sperling
  • Patent number: 5919536
    Abstract: Biaxially oriented films containing at least one layer of polyethylene naphthalate bibenzoate (PENBB) copolyester wherein the copolyester contains from about 60 to about 40 mol % of a first recurring unit of the formula (II). ##STR1## and about 40 to about 60 mol % of a second recurring unit of formula (I). The copolyester preferably contains less than 10 mol % of recurring units derived from terephthalate or other dicarboxylic acids. The films have a total thickness of 0.05-500 .mu.m and may contain inert particles.
    Type: Grant
    Filed: April 5, 1996
    Date of Patent: July 6, 1999
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Cynthia Bennett, Bodo Kuhmann, Bennett Clayton Ward, E-Won Choe, John Anthony Flint
  • Patent number: 5866672
    Abstract: There are disclosed a flame retardant polyethylene terephthalate resin composition comprising (A) a polyethylene terephthalate resin containing ethylene terephthalate units as a main constituent, prepared by the use of a germanium compound as a catalyst, (B) a halogen flame retardant, (C) at least one compound selected from the group consisting of epoxy compounds and carbodiimide compounds and (D) an antimony compound, and moreover, resin compositions further containing, besides those (A), (B), (C) and (D), at least one selected from the group consisting of (E) a reinforcing filler, (F) at least one inorganic compound composed of silicates and silicic acid and (G) a crystallization accelerator. The resin compositions are excellent in physical properties and wet heat resistance. By the addition of the specific inorganic compounds and the crystallization accelerators, releasability is also improved and thus high cyclization of molding is possible.
    Type: Grant
    Filed: November 5, 1996
    Date of Patent: February 2, 1999
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Youichi Ohara, Kazuaki Matsumoto, Masahiko Mihoichi, Kazushi Hirobe
  • Patent number: 5773144
    Abstract: A rubber-polyester composite comprising a rubber and a core-and-sheath heterocomponent fiber wherein the fiber core is formed from a linear polyester derived from an alkyl glycol and an aromatic diacid, and wherein the fiber sheath is formed from a compatibilizing acid-terminated or isocyanate-terminated polyester. The fiber sheath may also be composed of a blend of a thermoplastic elastomer and the compatibilizing polyester.
    Type: Grant
    Filed: October 26, 1995
    Date of Patent: June 30, 1998
    Assignee: Hoechst Celanese Corp.
    Inventors: Eui Won Choe, Charles Edward Forbes, Jennifer Ann Filbey, Stephan Fredrick Sherriff
  • Patent number: 5731071
    Abstract: A biaxially oriented polyester film which has excellent resistances to dry heat deterioration and wet heat deterioration, which can withstand the use in an atmosphere of relatively high moisture content, and which is useful, for example, as an electrical insulating film, a film for transparent electrode, a film for absorption of electromagnetic wave (e.g. a film used as an inspection window of microwave oven) and a reflection film. This polyester contains ?ethylene-2,6-naphthalenedicarboxylate as the main recurring unit.! 99.5 to 95 mole % of ethylene-2,6-naphthalenedicarboxylate and 0.5 to 5 mole % of ethylene-2,7-naphthalenedicarboxylate and has a density of 1.355 to 1.370 g/cm.sup.3 and an intrinsic viscosity of 0.62 to 0.90. The polyester film has an amount of terminal carboxyl in the polyester of 40 eg/10.sup.6 g or less and an amount of oligomers of 2.0 mg/m.sup.2 film or less.
    Type: Grant
    Filed: July 17, 1995
    Date of Patent: March 24, 1998
    Assignee: Teijin Limited
    Inventors: Masami Etchu, Masahiro Hosoi, Masanori Nishiyama, Yasuhiro Saeki, Hisashi Hamano
  • Patent number: 5705600
    Abstract: The present invention relates to blends of a polyester, polyamide or polyester/amide containing a copolymerizable fluorescence quenching compound and a second polymer. The blends of the present invention display reduced fluorescence. Specifically the blends comprise(a) a polyester/amide comprising:(1) a dicarboxylic acid component which comprises at least 0.1 mol % of a dicarboxylic acid selected from the group consisting of terephthalic acid and/or terephthalate ester;(2) a diol and/or diamine component;(3) 0.1 to 99.9 mol %, based on 100 mol % dicarboxylic acid and 100 mol % diol, of a copolymerizable fluorescence quenching compound;(b) a second polymer selected from the group poly(alkylene terephthalate) homo and copolyesters, poly(alkylene naphthalate) homo and copolyesters, poly(cycloalkylene terephthalate) homo and copolyesters, poly(alkylene 1,4-cyclohexanedicarboxylate) homo and copolyesters, and polycarbonate homo and copolymers.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: January 6, 1998
    Assignee: Eastman Chemical Company
    Inventors: Allan Scott Jones, Jean Carroll Fleischer, Max Allen Weaver
  • Patent number: 5703134
    Abstract: New copolymers of recycled polyesters having improved properties are disclosed. The copolyesters are produced by a reaction of recycled polyalkylene terephthalate and a dicarboxylate moiety.
    Type: Grant
    Filed: December 10, 1996
    Date of Patent: December 30, 1997
    Assignee: Monsanto Company
    Inventors: Jawed Asrar, A. Hameed Bhombal
  • Patent number: 5644019
    Abstract: In the present invention, a class of catalysts is described, to be used in the polycondensation stage in the synthesis of poly(ethylene terephthalate), constituted by a composition of metal derivatives in quantity so that the content of these in the final polymer is below 130 ppm.
    Type: Grant
    Filed: May 20, 1996
    Date of Patent: July 1, 1997
    Assignee: Enichem S.p.A.
    Inventors: Riccardo Po', Luigi Pelosini, Ernesto Occhiello, Luisa Fiocca
  • Patent number: 5612423
    Abstract: This invention is an improved process for producing polyester copolymers, which employs a combination of an acid-based process and an ester-based process. The ester-based process is used to manufacture a low molecular weight naphthalate-based polymer, and the acid-based process is used to manufacture phthalate-based oligomers. The low molecular weight naphthalate-based polymer is combined with the phthalate-based oligomers, or the raw materials used to form the phthalate-based oligomers, to form a random polyester copolymer. Specifically, the process of the invention may be employed to manufacture, in an ester-based process, a low molecular weight polyethylene naphthalate polymer, which is then combined with polyethylene terephthalate oligomers produced in an acid-based process, and the acid-based process is then used to continue the polymerization reaction. Ester interchange reactions and further polymerization result in the production of a random polyethylene terephthalate/naphthalate copolymer.
    Type: Grant
    Filed: February 1, 1996
    Date of Patent: March 18, 1997
    Assignee: Shell Oil Company
    Inventors: Eugene J. Burkett, Douglas D. Callander, Joseph Galko, Edwin A. Sisson
  • Patent number: 5561213
    Abstract: Hot-melt adhesives are based on a random copolyetherester formed from aromatic dicarboxylic acids, terephthalic acid and isophthalic acid wherein the molar proportion of terephthalic acid is at least 55% based on the acid content, with a butanediol content between 20 and 85 mol % and containing at least 10 mol % triethylene glycol; the remainder of the diol content is preferably diethylene glycol. Copolyetheresters of this type are distinguished by excellent adhesion properties, a low melting point, rapid crystallization, and good resistance to laundering and dry cleaning at a minimum viscosity of 80 Pas.
    Type: Grant
    Filed: August 23, 1995
    Date of Patent: October 1, 1996
    Assignee: FMS-Inventa AG
    Inventor: Gerhard Poessnecker
  • Patent number: 5556712
    Abstract: A base film for a photographic film, which (A) consists essentially of polyethylene-2,6-naphthalenedicarboxylate containing naphthoic acid unit in an amount, in terms of methyl naphthoate, of 2 to 1,000 ppm, (B) has a light transmittance, T.sub.400, of at least 95%/cm at a wavelength of 400 nm when a solution of 10 mg/ml of the polyethylene-2,6-naphthalenedicarboxylate in a hexafluoroisopropanol/chloroform mixed solvent having a hexafluoroisopropanol/chloroform weight ratio of 2/3 is measured, (C) has a yellow index Y.sub.ID of at most S, and (D) has a haze value of 2.0% or less.
    Type: Grant
    Filed: April 18, 1995
    Date of Patent: September 17, 1996
    Assignee: Teijin Limited
    Inventors: Manabu Kimura, Hideshi Kurihara
  • Patent number: 5510417
    Abstract: An aqueous dispersion comprising (A) a polyester comprising an aromatic dicarboxylic acid, an addition product of bisphenol A with ethylene oxide and/or propylene oxide, and a dicarboxylic acid having a metal base of sulfonic acid and/or a polyol having a metal base of sulfonic acid, (B) a water-soluble organic compound having a boiling temperature of about 60.degree. C. to about 250.degree. C., (C) water and (D) a neutralizer; the amounts of the components A, B, C and D satisfying the following ratios of (1) to (3):(1) A/B/C being about 1% to about 70% by weight/about 0% to about 69% by weight/about 9% to about 99% by weight,(2) B/(B+C) being about 0 to about 0.7 (weight ratio), and(3) the equivalent ratio of D to A being about 0.1 to about 20.
    Type: Grant
    Filed: November 4, 1994
    Date of Patent: April 23, 1996
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Hiroshi Tachika, Keiichiro Togawa, Hiroshi Fujimoto
  • Patent number: 5464909
    Abstract: Provided are thermosetting powder coatings based on a resin based on dimethyl 2,6-decalindicarboxylate and neopentyl glycol. The resin may be modified with other diacids or diols but must have a suitable glass transition temperature (Tg) required for powder coatings. We have found that this aliphatic polyester meets the basic Tg requirement of powder coatings and found that it provides powder coating with excellent weatherability. The polyester resin has a number average molecular weight (Mn) of from about 1,500 to about 10,000, a glass transition temperature (Tg) of about 45.degree. C. to 100.degree. C., and a hydroxyl or acid number of from about 20 to about 100.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: November 7, 1995
    Assignee: Eastman Chemical Company
    Inventors: Yeon-Ho Chang, Robert B. Barbee, Brian S. Phillips
  • Patent number: 5458949
    Abstract: A film for heat-sensitive stencil paper comprising a biaxially oriented film having a thickness of 0.5 to 6.0 .mu.m and formed from a polyester composition comprising polybutylene terephthalate and at least one other polyester, the content of the polybutylene terephthalate in the polyester composition being 20 to 80 wt %, the polyester composition has one melting point or a plurality of melting points with a difference of less than 10.degree. C. between the highest melting point and the lowest melting point.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: October 17, 1995
    Assignee: Diafoil Hoechst Company, Limited
    Inventors: Megumi Komiyama, Kazuo Endo, Masashi Tate
  • Patent number: 5418309
    Abstract: The present invention provides a powder coating composition which is suitable for precoated steel plates. The powder coating composition has excellent storage stability (e.g. blocking resistance) and provides a cured film having good weather resistance and a good balance of hardness and processability. The powder coating composition comprises;(I) 95 to 70% by weight of a polyester resin having a glass transition temperature of 40.degree. to 70.degree. C., prepared from (i) and acid component containing at least 80 mole % of an aromatic dicarboxylic acid with (ii) a polyol component which comprises(a) at least 50 mole % of neopentyl glycol, and(b) 1 to 10% by weight of a diol selected from the group consisting of a linear chain C.sub.8 -C.sub.16 alkylene diol, 2-methyl-1,8-octane diol and a mixture thereof, and(II) 5 to 30% by weight of a curing agent.
    Type: Grant
    Filed: December 29, 1993
    Date of Patent: May 23, 1995
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Hisaki Tanabe, Yasuhiko Nakae, Yoshio Eguchi
  • Patent number: 5418318
    Abstract: This invention relates to naphthalenedicarboxylic acid containing polymer compositions having reduced fluorescence. More specifically, the polymers contain at least 0.1 mole percent of a dicarboxylic acid selected from 2,6-naphthalenedicarboxylic acid or 2,6-naphthalenedicarboxylate ester, with 0.1 to 5 mole percent of a copolymerizable halogen containing aromatic compound. These polymers are useful for packaging applications where clarity and/or aesthetic appeal are of concern.
    Type: Grant
    Filed: May 5, 1994
    Date of Patent: May 23, 1995
    Assignee: Eastman Chemical Company
    Inventors: Allan S. Jones, David E. Mills, Mitchell A. Winnik
  • Patent number: 5391330
    Abstract: This invention relates to naphthalenedicarboxylic acid containing polymer compositions having reduced fluorescence. More specifically, the process involves melt blending a naphthalenedicarboxylic acid containing polymer with 0.1 to 5 weight percent of a fluorescence quenching compound selected from a halogen containing aromatic compound, an aromatic ketone or a naphthol compound and thermoforming the blend into an article. The blends are useful for packaging applications where clarity and/or aesthetic appeal are of concern.
    Type: Grant
    Filed: May 5, 1994
    Date of Patent: February 21, 1995
    Assignee: Eastman Chemical Company
    Inventors: Allan S. Jones, David E. Mills
  • Patent number: 5391701
    Abstract: This invention relates to a poly(ethylene 2,6-naphthalene dicarboxylate) composition having reduced fluorescence. More specifically, the composition contains poly(ethylene 2,6-naphthalene dicarboxylate) with 0.1 to 5 mole percent of a copolymerizable halogen containing aromatic compound. The polyesters are useful for packaging applications where clarity and/or aesthetic appeal are of concern.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: February 21, 1995
    Assignee: Eastman Chemical Company
    Inventors: Allan S. Jones, David E. Mills, Mitchell A. Winnik
  • Patent number: 5391702
    Abstract: This invention relates to poly(ethylene 2,6-naphthalene dicarboxylate) blends having reduced fluorescence. More specifically, the process involves melt blending poly(ethylene 2,6-naphthalene dicarboxylate) with 0.1 to 5 weight percent of a fluorescence quenching compound selected from a halogen containing aromatic compound, an aromatic ketone or a naphthol compound and thermoforming the blend into an article. The blends are useful for packaging applications where clarity and/or aesthetic appeal are of concern.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: February 21, 1995
    Assignee: Eastman Chemical Company
    Inventors: Allan S. Jones, David E. Mills
  • Patent number: 5354840
    Abstract: Functional-amine polyesters have at least a first residue of a first monomer, a second residue of a second monomer and from about 0.1 to about 3.0 mole percent of a functional-amine residue of a functional amine prepared by reacting the first and second monomers and the functional amine in an inert atmosphere. The functional amine has a functional group which facilitates polymerizing the amine and the first and second monomers. The amine residue facilitates reaction of the functional-amine polyester in an organic peroxide cross-linking reaction system.
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: October 11, 1994
    Assignee: Xerox Corporation
    Inventor: Peter G. Odell
  • Patent number: 5344872
    Abstract: This invention relates to an aqueous dispersion of a water-dissipatable polyester and a styrenated acrylic copolymer in combination with either an acrylic polymer or a hydantoin-formaldehyde resin.
    Type: Grant
    Filed: February 19, 1993
    Date of Patent: September 6, 1994
    Assignee: Eastman Chemical Company
    Inventors: Theo J. Debord, Nelson Z. Escano, Louis A. Wilkin
  • Patent number: 5336714
    Abstract: Provided are water-dissipatable, sulfo-containing polyesters and polyester-amides having copolymerized therein thermally stable near infrared flourophoric compounds. The polymers are useful in coating or ink compositions, which are in turn useful for marking articles for identification/authentication purposes. Also provided is a method for invisibly marking such articles and a method for detecting and sorting articles by utilizing the near infrared flourophoric ink or coating compositions.
    Type: Grant
    Filed: December 30, 1993
    Date of Patent: August 9, 1994
    Assignee: Eastman Chemical Company
    Inventors: James J. Krutak, Michael R. Cushman, William W. Parham, Clarence A. Coates, Max A. Weaver, Gabor Patonay
  • Patent number: 5302686
    Abstract: A hollow article or sheet of a copolyester which comprises, as main components, terephthalic acid as a dicarboxylic acid component and ethylene glycol as a diol component and which is characterized by:(1) isophthalic acid as a dicarboxylic acid component being from 0.5 to 3.0 mol %,(2) diethylene glycol as a diol component being from 1.0 to 2.5 mol %,(3) the intrinsic viscosity being from 0.60 to 1.50 dl/g,(4) the concentration of terminal carboxyl groups being at most 18 eq/ton, and(5) the content of a cyclic trimer being at most 0.40% by weight.
    Type: Grant
    Filed: July 15, 1993
    Date of Patent: April 12, 1994
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Katsuji Tanaka, Hitoshi Matsumoto, Takuji Hirahara, Osamu Kishiro
  • Patent number: 5288559
    Abstract: Provided is a coating composition for a two-piece can containing a polyester resin (A) consisting essentially of terephthalic acid and propylene glycol and containing tri- or more functional polycarboxylic acid or polyol comonomer(s) and an alkyl-etherified aminoformaldehyde resin (B); and the coating film (C) to be obtained by reacting these (A) and (B) in the composition has larger tensile strength and elongation than the film made of only (A). The coating composition is coated on at least one surface of a metal sheet to give a coated metal sheet for a two-piece can. The coated metal sheet may be formed into a drawn and ironed can or a drawn and re-drawn can. The adhesiveness of the coated film to the metal sheet is high, and the coated film has excellent resistance to blistering and resistance to whitening and has excellent flavor preservability.
    Type: Grant
    Filed: October 15, 1992
    Date of Patent: February 22, 1994
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Masami Oka, Takao Aoki, Hiroshi Fujimoto, Hiroshi Tachika
  • Patent number: 5278278
    Abstract: The present invention relates to polyesters capable to give moldings having excellent flow characteristics, heat resistance and mechanical properties.These polyesters are prepared by copolymerizing specified amounts of specific dioxycompounds such as t-butylhydroquinone, phenylhydroquinone and so on with polyesters comprising specified amounts of p-hydroxybenzoic acid, 4,4'-dihydroxybiphenyl, hydroquinone and terephthalic acid or terephthalic acid and isophthalic acid.
    Type: Grant
    Filed: February 17, 1993
    Date of Patent: January 11, 1994
    Assignee: Toray Industries, Inc.
    Inventors: Masaru Okamoto, Toshihide Inoue, Shiro Kataoka
  • Patent number: 5278280
    Abstract: Hard resinous polyol esters having a high degree of hydroxyl functionality and a ball and ring softening temperature of at least about 50.degree. C.
    Type: Grant
    Filed: June 26, 1990
    Date of Patent: January 11, 1994
    Assignee: Imcera Group Inc.
    Inventor: Paul E. Eckler
  • Patent number: 5274025
    Abstract: This invention relates to a polymer blend comprising water-dissipatable, sulfonate containing, a hydantoin-formaldehyde resin.
    Type: Grant
    Filed: February 19, 1993
    Date of Patent: December 28, 1993
    Assignee: Eastman Kodak Company
    Inventors: Rebecca R. Stockl, Hieu D. Phan, Gary T. Clark
  • Patent number: 5266676
    Abstract: Low-crystallization-speed polyesters obtained by means of the polycondensation of 2,6-naphthalene-dicarboxy acid with at least one (C.sub.2 -C.sub.10)-(cyclo)alkylene glycol in the presence of 0.5-50 mol % of a copolymerizable reactant of general formula:ROOC--Ar--OOC--Ar'--COO--Ar--COOR (I)wherein Ar and Ar' stand for aromatic radicals, and R stands for a hydrogen atom or a (C.sub.1 -C.sub.4)-alkyl radical, or the OR group is replaced by a halogen.
    Type: Grant
    Filed: July 15, 1992
    Date of Patent: November 30, 1993
    Assignee: Istituto Guido Donegani S.p.A.
    Inventors: Riccardo Po', Ernesto Occhiello, Fabio Garbassi, Luigi Pelosini
  • Patent number: 5262513
    Abstract: A copolyester which comprises, as main components, terephthalic acid as a dicarboxylic acid component and ethylene glycol as a diol component and which is characterized by:(1) isophthalic acid as a dicarboxylic acid component being from 0.5 to 3.0 mol %,(2) diethylene glycol as a diol component being from 1.0 to 2.5 mol %,(3) the intrinsic viscosity being from 0.60 to 1.50 dl/g,(4) the concentration of terminal carboxyl groups being at most 18 eq/ton, and(5) the content of a cyclic trimer being at most 0.40% by weight.
    Type: Grant
    Filed: July 13, 1992
    Date of Patent: November 16, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Katsuji Tanaka, Hitoshi Matsumoto, Takuji Hirahara, Osamu Kishiro
  • Patent number: 5250652
    Abstract: The invention is concerned with novel water-dispersible copolymers which contain at least one UVA light-absorbing monomer, one UVB light-absorbing monomer, one hydrophilic monomer, and optionally one hydrophobic monomer component. The UVA light-absorbing monomer absorbs at .lambda.max ultraviolet light in the 320-400 nm range. The UVB light-absorbing monomer absorbs at max ultraviolet light in the 290-320 nm range. Because of the R.sub.3 group used in the invention, the copolymers of the invention permit higher loading of UV monomers than previously obtainable.
    Type: Grant
    Filed: July 30, 1992
    Date of Patent: October 5, 1993
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Matthew E. Langer, Ferial Khorshahi
  • Patent number: 5243021
    Abstract: The invention is concerned with novel water-dispersible or water-soluble copolymers which contain at least one UVA light-absorbing monomer, one UVB light-absorbing monomer, one hydrophilic monomer, and optionally one hydrophobic monomer component. The UVA light-absorbing monomer absorbs at .lambda.max ultraviolet light in the 320-400 nm range. The UVB light-absorbing monomer absorbs at .lambda.max ultraviolet light in the 290-320 nm range.
    Type: Grant
    Filed: April 23, 1992
    Date of Patent: September 7, 1993
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Matthew E. Langer, Ferial Khorshahi, Katherine Lee
  • Patent number: 5213856
    Abstract: Copolyesters having an improved combination of barrier, mechanical, thermal and rheological properties and consisting of acylic and glycolic radicals, wherein the acylic radicals derive from at least isophthalic acid and 2,6-naphthalene dicarboxylic acid and at least 90% by mols of the glycolic radicals derive from ethylene glycol.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: May 25, 1993
    Assignee: Istituto Guido Donegani S.p.A.
    Inventors: Riccardo Po', Paolo Cioni, Ernesto Occhiello, Fabio Garbassi
  • Patent number: 5177296
    Abstract: The present invention describes a method for the synthesis of saturated aliphatic polyesters by reaction of saturated or aromatic diacid chlorides with oligomeric aliphatic polyester diols, a method to thermally crosslink membranes prepared from the above saturated aliphatic polyesters, and the use of the crosslinked membranes to separate aromatics from saturates.
    Type: Grant
    Filed: April 16, 1992
    Date of Patent: January 5, 1993
    Assignee: Exxon Research and Engineering Company
    Inventors: Guido Sartori, W. S. Winston Ho, Bruce H. Ballinger
  • Patent number: 5156937
    Abstract: The present invention relates to a polymer composition comprising a high molecular weight polyester having a glass transition temperature of 50.degree. to 100.degree. C. and a weight average molecular weight of 30,000 to 100,000 and a low molecular weight polyester in linear, amorphous form defined by the formula: ##STR1## said low molecular weight polyester having a glass transition temperature of 55.degree.-65.degree. C., wherein:R is a hydrocarbon radical having 2 to 5 carbons andm is a number which gives the low molecular weight polyester a number average molecular weight of 500 to 2000.
    Type: Grant
    Filed: June 10, 1991
    Date of Patent: October 20, 1992
    Assignee: Eastman Kodak Company
    Inventors: Peter S. Alexandrovich, John E. Derimiggio, Joseph A. Pavlisko
  • Patent number: 5153301
    Abstract: A polyester resin comprised of (a) units derived from a terephthalic acid component and/or a isophthalic acid component, (b) 0 to 80 mole %, based on the total carboxylic acid component, of units derived from a diol component represented by the formula: ##STR1## wherein R represents an alkyl group having 2 or 3 carbon atoms, and x and y are integers satisfying the requirement of 2.ltoreq.x+y.ltoreq.6,and (c) 20 to 200 mole %, based on the total carboxylic acid component, of units derived from an aliphatic diol component. The polyester has a weight average molecular weight M.sub.w of 3,000 to 20,000, a number average molecular weight M.sub.n of 1,000 to 10,000, a glass transition temperature T.sub.g of 40.degree. to 70.degree. C., and a softening temperature of 70.degree. to 130.degree. C. The polyester is valuable for a toner.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: October 6, 1992
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Noriyuki Tajiri, Hirokazu Ito, Masayuki Takyu, Ryo Funato, Shinji Kubo
  • Patent number: 5138022
    Abstract: Aliphatic polyesters of 3,4'-biphenyldicarboxylic acid and optionally 4,4'-biphenyldicarboxylic acid are prepared by contacting at least one aliphatic diol having from 2 to 12 carbon atoms with a lower alkyl diester or phenolic diester of 3,4'-biphenyldicarboxylic acid and, optionally, a lower alkyl diester or phenolic diester of 4,4'-biphenyldicarboxylic acid, in the presence of a catalyst at about 180.degree. to about 300.degree. C. These polyesters are suitable for use in making fibers, films, three dimensional molded articles, barrier containers and coatings.
    Type: Grant
    Filed: August 1, 1991
    Date of Patent: August 11, 1992
    Assignee: The Dow Chemical Company
    Inventors: Michael N. Mang, James L. Brewbaker
  • Patent number: 5134221
    Abstract: Linear saturated copolyesters of terephthalic acid, isophthalic acid, butanediol, and one or more aliphatic diols having at least 13 carbon atoms used as adhesives for the formation of wash-resistant bonds especially for temperature-sensitive materials. Preferably, the melting points of these adhesive compositions are from 50.degree. to 170.degree. C. and their relative viscosities, measured as 1% solutions in meta-cresol at 20.degree. C., are 1.40 to 1.80.
    Type: Grant
    Filed: October 22, 1991
    Date of Patent: July 28, 1992
    Assignee: EMS-Inventa AG
    Inventor: Annette Lavalette
  • Patent number: 5081220
    Abstract: Disclosed are polyesters comprised primarily of residues of 4,4'-biphenyldicarboxylic acid, ethylene glycol and 1,4-butanediol. Articles injection-molded from the polyesters exhibit a unique combination of properties including unusually high tensile strength and excellent heat resistance, flexural modulus and resistance to chemicals and solvents.
    Type: Grant
    Filed: February 27, 1989
    Date of Patent: January 14, 1992
    Assignee: Eastman Kodak Company
    Inventors: John C. Morris, Winston J. Jackson, Jr.
  • Patent number: 5075418
    Abstract: A thermotropic liquid crystal polyester consisting essentially of ethylene glycol residue, terephthalic acid residue and parahydroxybenzoic acid residue wherein the mol ratio of ethylene glycol residue to terephthalic acid residue is substantially about 1:1 and the mol ratio of terephthalic acid residue to parahydroxybenzoic acid residue is in the range of about 5:95 to about 25:75, the polyester having an intrinsic viscosity of at least about 0.5 dl/g measured in a 50:50 by weight solvent mixture of phenol and 1,1,2,2-tetrachlorethane at 20.degree. C., and a transmittance of at least about 80% to 530 nm light at a light path length of said solvent mixture. A method for forming the thermotropic liquid crystal polyester is also disclosed.
    Type: Grant
    Filed: July 13, 1989
    Date of Patent: December 24, 1991
    Assignee: Unitika Ltd.
    Inventors: Jun-ichi Suenaga, Hisayuki Naito, Singo Sasaki
  • Patent number: 5068300
    Abstract: New Z-stilbene compounds and a process for their preparation are disclosed wherein the compounds correspond to the following formulae: ##STR1##
    Type: Grant
    Filed: October 19, 1990
    Date of Patent: November 26, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter Arlt, Axel Bader, Volker Eckhardt
  • Patent number: 5057596
    Abstract: Disclosed is a crosslinked polyester resin comprised of, based on the total acid units, (a) 1 to 30 mole % of units of a trihydric or higher alcohol or units of a trivalent or higher carboxylic acid, (b) 1 to 60 mole % of units of an alicyclic diol in which at least one alcohol component is a secondary alcohol, (c) 40 to 100 mole % of units of an aromatic dicarboxylic acid and (d) 40 to 99 mole % of units of a non-alicyclic diol, wherein the acid value is 0.5 to 25 mg-KOH/g, the glass transition temperature is 50.degree. to 80.degree. C., the softening temperature is not higher than 145.degree. C., the fixing-possible temperature covers a range of at least 30.degree. C., and the difference between the softening temperature and the glass transition temperature is not larger than 75.degree. C. The crosslinked polyester is used for toner for electrostatic recording.
    Type: Grant
    Filed: July 17, 1990
    Date of Patent: October 15, 1991
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Shinji Kubo, Noriyuki Tajiri, Masayuki Takyu, Ryo Funato, Hirokazu Ito
  • Patent number: 5055549
    Abstract: The present invention is connected with a process for preparing a novel photosensitive polyimide precursor having excellent shelf stability and high sensitivity and containing less impurities.The process for preparing a photosensitive heat-resistant polymer containing a repeating unit represented by the formula (III) comprises the step of reacting a photosensitive group-containing isoimide represented by the formula (I) with a diamine represented by the formula (II) at a temperature of 0.degree. to 100.degree. C. in the presence of a solvent: ##STR1## wherein R.sup.1 is independently a tetravalent carbon cyclic aromatic group or heterocyclic group; R.sup.2 is independently an aliphatic group having at least 2 carbon atoms, an alicyclic group, an aromatic aliphatic group, a carbon cyclic aromatic group, a heterocyclic group or a polysiloxane group; R.sup.3 is a monovalent organic group having a photosensitive unsaturated group; and D is an oxygen atom or .dbd.N--R.sup.3.
    Type: Grant
    Filed: January 8, 1990
    Date of Patent: October 8, 1991
    Assignee: Chisso Corporation
    Inventors: Hirotoshi Maeda, Kouichi Kunimune