Each Of The Carboxylic Acids Or Derivatives Contains An Aryl Group Patents (Class 528/305)
  • Publication number: 20100152409
    Abstract: Triptycene derivatives and method for preparing the same are provided. The triptycene derivatives may be triptycene di-ester of the formula (I) or triptycene di-acid of the formula (II): where n=1-5.
    Type: Application
    Filed: December 29, 2008
    Publication date: June 17, 2010
    Applicant: TAIWAN TEXTILE RESEARCH INSTITUTE
    Inventors: Chin-Wen Chen, I-Pin Fu, Yu-Chi Tseng, Jye-Shane Yang, Jyu-Lun Yan
  • Publication number: 20100152411
    Abstract: The present invention relates to a process for making a non-whitening poly(trimethylene terephthalate)-based polymer, wherein the polymer is melt polymerized 1,3-propanediol and a terephthalate component in the presence of a co-monomer, wherein the poly(trimethylene terephthalate)-based polymer comprises a PTT cyclic dimer level below 2 wt. %.
    Type: Application
    Filed: December 16, 2009
    Publication date: June 17, 2010
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Brett Collin Dobrick, Benjamin Weaver Messmore
  • Patent number: 7737246
    Abstract: Described as one aspect of the invention are polyester compositions comprising at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) about 90 to about 100 mole % of terephthalic acid residues; (ii) about 0 to about 10 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and (b) a glycol component comprising: (i) about 20 to about 40 mole % 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and (ii) about 20 to about 40 mole % cyclohexanedimethanol residues; (iii) ethylene glycol residues, and (iv) less than about 2 mole % of a modifying glycol having from 3 to 16 carbon atoms; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.50 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25° C.
    Type: Grant
    Filed: December 7, 2006
    Date of Patent: June 15, 2010
    Assignee: Eastman Chemical Company
    Inventor: Emmett Dudley Crawford
  • Publication number: 20100120979
    Abstract: Described are film(s) and/or sheet(s) comprising polyesters comprising (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.
    Type: Application
    Filed: March 28, 2006
    Publication date: May 13, 2010
    Inventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
  • Publication number: 20100113735
    Abstract: The invention provides improved energy content in and shaft power recovery from off-gas from xylene oxidation reactions while at the same time minimizing wastewater treatment cost. More shaft power is produced using off-gas than is required to drive the main air compressor, even with preferred, relatively low oxidation temperatures. Simultaneously, an amount of wastewater greater than byproduct water from oxidation of xylene is kept in vapor form and treated along with off-gas pollutants in a self-sustaining (self-fueling) gas-phase thermal oxidative destruction unit. Optionally, off-gas is combined from multiple xylene oxidation reactors, comprising primary and/or secondary oxidation reactors and forming TPA and/or IPA. Optionally, air compressor condensate and caustic scrubber blowdown are used in a TPA process or as utility water, effectively eliminating normal flow of liquid wastewater effluent from a TPA plant.
    Type: Application
    Filed: September 9, 2009
    Publication date: May 6, 2010
    Applicant: EASTMAN CHEMICAL COMPANY
    Inventors: Raymond Elbert Fogle, III, Ronald Buford Sheppard, Timothy Alan Upshaw, Alan George Wonders
  • Patent number: 7641950
    Abstract: This invention relates to a polyester/polyamide blend having an excellent gas barrier property. More particularly, the present invention relates to combinations of a polyethylene terephthalate polymer and a polyamide polymer having an excellent gas barrier property and short oxygen scavenging induction periods, where the polyamide polymer has a C:A terminal group concentration ratio of 2:1 or more and a C+A terminal group concentration of at least 0.17 meq/g of polyamide polymer, wherein C represents a cumulative total of a terminal carboxyl group concentration and a terminal hydrocarbyl group concentration expressed in meq/g of polyamide, and A represents a terminal amine group concentration expressed in meq/g of polyamide.
    Type: Grant
    Filed: January 21, 2008
    Date of Patent: January 5, 2010
    Assignee: Eastman Chemical Company
    Inventors: Steven Lee Stafford, Mark Edward Stewart, Benjamin Bradford Gamble
  • Patent number: 7638590
    Abstract: The invention provides a novel polyester adapted for use in a charge control agent for a toner for an electrophotographic process, having a charge stability, a high charge amount, an improved dispersibility and a biodegradability, and a producing method and an application technology therefore.
    Type: Grant
    Filed: June 24, 2005
    Date of Patent: December 29, 2009
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tatsuki Fukui, Tetsuya Yano, Chieko Mihara, Shinya Kozaki, Tsutomu Honma, Takashi Kenmoku, Ako Kusakari
  • Publication number: 20090317575
    Abstract: A process is provided for producing an enriched carboxylic acid compositions produced by contacting composition comprising a carboxylic acid with an enrichment feed in an enrichment zone to form an enriched carboxylic acid composition. This invention also relates to a process and the resulting compositions for removing catalyst from a carboxylic acid composition to produce a post catalyst removal composition.
    Type: Application
    Filed: June 26, 2009
    Publication date: December 24, 2009
    Applicant: Eastman Chemical Company
    Inventors: Philip Edward Gibson, Kenny Randolph Parker, Ronald Buford Sheppard
  • Patent number: 7556861
    Abstract: High frequency-weldable articles, such as sheets or yarns, include at least one high frequency-weldable part that is made from a modified polyethylene terephthalate (PET) material and that has a melting point ranging from 100° C. to 250° C. The modified PET material is prepared from a composition that includes terephthalic acid, ethylene glycol and a diol modifier. The diol modifier is selected from the group consisting of neopentanediol, 1,3-dihydroxy-2-methylpropane, 1,3-dihydroxy-2-methylpropane alkoxylate, 2,5-dimethyl-2,5-hexanediol, polyethylene glycol, and combinations thereof.
    Type: Grant
    Filed: October 22, 2004
    Date of Patent: July 7, 2009
    Assignee: Far Eastern Textile Ltd.
    Inventors: Ru-Yu Wu, Tsung-Hui Chao, Chih-Wei Chu
  • Publication number: 20090137735
    Abstract: This invention relates to thermoplastic article having one or more decorative materials embedded therein which is obtained by applying heat and pressure to one or more laminates wherein at least one of said laminates comprises, in order, (1) an upper sheet material; (2) one or more decorative materials; and (3) a lower sheet material; wherein the upper and lower sheet materials are formed from a polyester/aromatic polycarbonate blend wherein the thermoplastic article comprises at least one polyester composition comprising at least one polyester which comprises terephthalic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol.
    Type: Application
    Filed: February 4, 2009
    Publication date: May 28, 2009
    Applicant: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
  • Publication number: 20090131628
    Abstract: A normal-pressure cation-dyeable polyester is provided which contains an isophthalic acid component having a metal sulfonate group in a predetermined proportion based on the total of acid components present in the polyester, and contains a polyalkylene glycol having an average molecular weight of 150 to 600 in a predetermined proportion based on the polyester, wherein the proportion of diethylene glycol based on the total of glycol components and a terminal carboxyl group concentration are each set within a predetermined range. The polyester is stable in quality and excellent in dark- and pale-color light fastness when used for textile products.
    Type: Application
    Filed: March 2, 2006
    Publication date: May 21, 2009
    Applicant: KB SEIREN, LTD.
    Inventor: Keita Katsuma
  • Publication number: 20090098323
    Abstract: The invention aims at providing an oxygen-absorbing resin which has excellent oxygen absorption performance and which can dispense with the addition of a transition metal catalyst or the irradiation with a radiation. The invention provides an oxygen-absorbing resin which is obtained by polymerizing a raw material containing a monomer (A) having an unsaturated alicyclic structure bearing a carbon-carbon double bond wherein one carbon atom adjacent to the carbon-carbon double bond is bonded to an electron-donating substituent and a hydrogen atom and another carbon atom adjacent to the carbon atom is bonded to a heteroatom-containing functional group or a bonding group derived from the functional group with the electron-donating substituent and the functional or bonding group taking cis-configuration and which contains the unsaturated alicyclic structure in an amount of 0.
    Type: Application
    Filed: October 10, 2008
    Publication date: April 16, 2009
    Applicant: TOYO SEIKAN KAISHA, LTD.
    Inventors: Yoshihiro Ohta, Yoichi Ishizaki
  • Patent number: 7517635
    Abstract: There is provided a novel polyester compound having in its main polymer chain an aliphatic cyclic structure with carboxylic acids or carboxylic acid ester groups as represented by the chemical formula (1), a resist material containing the polyester compound and a patterning method using the resist material.
    Type: Grant
    Filed: August 25, 2006
    Date of Patent: April 14, 2009
    Assignee: Central Glass Company, Limited
    Inventors: Satoru Miyazawa, Satoru Kobayashi, Kazuhiko Maeda
  • Patent number: 7479326
    Abstract: A polymer with a backbone having at least one structural unit represented by formula (I): Wherein R1, R2, R3, R4, and R5 independently denote one of a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, or a substituted or unsubstituted alkenyl group, and n preferably denotes an integer from 1 to 10.
    Type: Grant
    Filed: March 8, 2006
    Date of Patent: January 20, 2009
    Assignee: Valspar Sourcing, Inc.
    Inventors: Paul E. Share, Keith R. Pillage, Charles I. Skillman, Paul E. Fuchs
  • Patent number: 7468204
    Abstract: Modified copolyesters having relatively low refractive indices and relatively high glass transition temperatures are disclosed. These modified copolyesters can be used in forming one or more layers in an optical film, such as a multilayer polymer film.
    Type: Grant
    Filed: February 25, 2008
    Date of Patent: December 23, 2008
    Inventors: Timothy J. Hebrink, Martin E. Denker, Bert T. Chien, Matthew B. Johnson, Richard J. Thompson, Kristopher J. Derks, William W. Merrill, Fuming B. Li
  • Patent number: 7459204
    Abstract: A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
    Type: Grant
    Filed: December 15, 2006
    Date of Patent: December 2, 2008
    Assignee: 3M Innovative Properties Company
    Inventors: Timothy J. Hebrink, William W. Merrill, Carl A. Stover
  • Publication number: 20080135806
    Abstract: Compositions comprising at least one phosphorescent organometallic compound and a polymer comprising structural units of formula II are useful in organic light emitting devices wherein R1, R2, and R4 are independently at each occurrence a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; wherein R3 and R5 are independently selected from the group consisting of hydrogen, triphenylsilyl, t-butyl, mesityl, diphenyl phosphine oxide, and diphenyl phosphine sulfide; and a, b and d are independently 0 or an integer ranging from 1 to 3.
    Type: Application
    Filed: June 19, 2007
    Publication date: June 12, 2008
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Qing Ye, Jie Liu, Kyle Erik Litz
  • Patent number: 7375154
    Abstract: This invention relates to a polyester/polyamide blend having an excellent gas barrier property. More particularly, the present invention relates to combinations of a polyethylene terephthalate polymer and a polyamide polymer having an excellent gas barrier property and short oxygen scavenging induction periods, where the polyamide polymer has a C:A terminal group concentration ratio of 2:1 or more and a C+A terminal group concentration of at least 0.17 meq/g of polyamide polymer, wherein C represents a cumulative total of a terminal carboxyl group concentration and a terminal hydrocarbyl group concentration expressed in meq/g of polyamide, and A represents a terminal amine group concentration expressed in meq/g of polyamide.
    Type: Grant
    Filed: December 6, 2004
    Date of Patent: May 20, 2008
    Assignee: Eastman Chemical Company
    Inventors: Steven Lee Stafford, Mark Edward Stewart, Benjamin Bradford Gamble
  • Patent number: 7306835
    Abstract: The present invention relates to a thermo-shrinkable polyester film with a superior thermal shrinkage, which has an orientation angle of a molecular chain in a range of from 0° to about ±10° relative to a main shrinkage direction, and a molecular orientation ratio (MOR) in a range of from 1.29 to about 2.5, thereby preventing a label made from the film from curling or waving.
    Type: Grant
    Filed: January 29, 2007
    Date of Patent: December 11, 2007
    Assignee: Kolon Industries, Inc.
    Inventors: Ki Il Hong, Gi Sang Song
  • Patent number: 7238417
    Abstract: The invention relates to a polyester film with a thickness of from about 4 to about 23 ?m, which comprises, alongside polyethylene terephthalate as main constituent, from about 2 to about 20% by weight of polyethylene naphthalate (based on the weight of the film), and has fewer than 30 pinholes per 100 m2. The invention further relates to a process for producing these films, and to the use of the films in packaging composites.
    Type: Grant
    Filed: June 16, 2003
    Date of Patent: July 3, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Holger Kliesch, Ursula Murschall, Thorsten Kiehne, Gottfried Hilkert, Bart Janssens
  • Patent number: 7229696
    Abstract: The invention relates to an at least two-layer polyester film with a total thickness of from about 5 to about 200 ?m which comprises polyethylene terephthalate and from about 2 to about 20% by weight—based on the weight of the entire film—of polyethylene naphthalate, and also at least one functional outer layer.
    Type: Grant
    Filed: June 16, 2003
    Date of Patent: June 12, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Holger Kliesch, Ursula Murschall, Franz Hora, Guenther Crass, Herbert Peiffer, Bodo Kuhmann
  • Patent number: 7199211
    Abstract: The present invention relates to novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where AO is for each AO independently at each instance EO, PO or BO where EO is O—CH2-CH2- PO is independently at each instance O—CH2-CH(CH3)- or O—CH(CH3)-CH2- BO is independently at each instance O—CH2-CH(CH2-CH3)- or O—CH(CH2-CH3)-CH2- p1+p2+p3 is 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74 or 75, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.
    Type: Grant
    Filed: June 6, 2003
    Date of Patent: April 3, 2007
    Assignee: BASF Aktiengesellschaft
    Inventors: Andreas Popp, Thomas Daniel, Jürgen Schröder, Thomas Jaworek, Rüdiger Funk, Reinhold Schwalm, Matthias Weismantel, Ulrich Riegel
  • Patent number: 7189452
    Abstract: Biaxially oriented polyester films formed from a crystallizable polyester having increased diethylene glycol content and/or increased polyethylene glycol content, and/or increased isophthalic acid content, preferably polyethylene terephthalate. The films of the invention further include at least one IR-reflective pigment and one UV stabilizer. The inventive films feature adjustable mattness, diffuse scattering power for visible light, high light transmittance and IR reflectance and good thermoformability, and are suitable for thermally protective coatings or thermally protective packaging.
    Type: Grant
    Filed: July 1, 2005
    Date of Patent: March 13, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Thorsten Kiehne, Ursula Murschall, Holger Kliesch
  • Patent number: 7189451
    Abstract: Multilayer, biaxially oriented polyester films which include as a constituent of the base layer B, a crystallizable polyester with increased diethylehe glycol content and/or increased polyethylene glycol content, and/or increased isophthalic acid content, preferably polyethylene terephthalate. The outer layers of the inventive films advantageously include at least one IR-reflective pigment and one UV stabilizer. The inventive films advantageously feature adjustable mattness, diffuse scattering power for visible light, high light transmittance, IR reflectance, and good thermoformability, and are suitable for thermally protective coatings or thermally protective packaging.
    Type: Grant
    Filed: July 1, 2005
    Date of Patent: March 13, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Thorsten Kiehne, Ursula Murschall, Holger Kliesch
  • Patent number: 7150907
    Abstract: A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70–100 mol % of the carboxylate subunits are first carboxylate subunits and 0–30 mo1 % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
    Type: Grant
    Filed: June 30, 2005
    Date of Patent: December 19, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Timothy J. Hebrink, William W. Merrill, Carl A. Stover
  • Patent number: 7147927
    Abstract: Disclosed are biaxially oriented polyester film produced from a polyester comprising: (1) diacid residues comprising at least 90 mole percent of terephthalic acid residues, naphthalenedicarboylic acid residues or combinations thereof; and (2) diol residues comprising at least 90 mole percent of 1,4-cyclohexanedimethanol residues; wherein the polyester comprises a total of 100 mole percent diacid residues and a total of 100 mole percent diol residues; wherein the polyester film is stretched at a ratio of about 2.5× to 3× in the machine direction (MD) and about 2.5× to 3× in the transverse direction (TD) at stretching temperatures between 90 and 1 10OC, wherein the stretched film is subsequently heat-set at an actual film temperature of from 260° C.
    Type: Grant
    Filed: June 25, 2003
    Date of Patent: December 12, 2006
    Assignee: Eastman Chemical Company
    Inventors: Thomas Joseph Pecorini, Gary Darrel Boone
  • Patent number: 7141627
    Abstract: An epoxy resin cured article has a high glass transition temperature and low dissipation factor. An epoxy resin composition from which the cured article can be having excellent solubility in solvents is used to produce the cured articles. A polyester as a curing agent of an epoxy resin composition having an aromatic polyhydroxy coumpound residue including an aryloxycarbonyl group at the molecule of the terminal, an aromatic polyvalent hydrocarbon group residue, and bulky structure, is used. Since the curing agent behaves as a polyfunctional curing agent, a cured article produced therefrom has a high crosslink density. Since highly polar hydroxyl groups are not formed during curing, a cured article has high glass transition temperature and a low dissipation factor. The cured article does not release low molecular weight carboxylic acids though hydrolysis of ester bonds at crosslinked bonds.
    Type: Grant
    Filed: October 27, 2003
    Date of Patent: November 28, 2006
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Satoshi Idemura, Masao Yamada, Koichi Fujimoto, Katsuji Takahashi
  • Patent number: 7115320
    Abstract: In order to provide a polyester film having superior impact resistance and flex pinhole resistance, and further exhibiting superior gas barrier properties after a metal or metal oxide is deposited on the film, with the inherent characteristics of polyester film maintained, such as low hygroscopicity, dimensional stability, flatness, and transparency, the polyester film comprises a mixture of 70% to 97% by weight of polyester A mainly composed of a repeating unit comprising ethylene terephthalate and 3% to 30% by weight of polyester B mainly composed of a repeating unit comprising butylene terephthalate. The polyester film has a melting point in range of 245 to 270° C. The polyester film may comprise a polyester resin containing 90% to 60% by weight of an ethylene terephthalate component, 10% to 40% by weight of a butylene terephthalate component, and 0.1% to 5% by weight of a polyoxyalkylene glycol component. The polyester film is suitably used for packaging and other applications.
    Type: Grant
    Filed: January 14, 2003
    Date of Patent: October 3, 2006
    Assignee: Toray Industries, Inc.
    Inventors: Hiroyuki Tanaka, Ryosuke Matsui, Koukichi Hashimoto
  • Patent number: 6946188
    Abstract: A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
    Type: Grant
    Filed: October 1, 2003
    Date of Patent: September 20, 2005
    Assignee: 3M Innovative Properties Company
    Inventors: Timothy J. Hebrink, William W. Merrill, Carl A. Stover
  • Patent number: 6939616
    Abstract: A film roll of a heat-shrinkable polyester film characterized in that the heat-shrinkable polyester film meets the following requirements (1) and (2). (1) When samples are cut off therefrom at an almost equal interval along the longitudinal direction, and immersed in hot water at 85° C. for 10 seconds, subsequently in water at 25° C. and withdrawn, heat-shrinkage percentages in the maximum shrinkage direction of all the samples are 20% or more. (2) When raw polymers used for production of the film above comprises of a major constitutional unit and one or more sub constitutional units different therefrom; and the content of the primary sub constitutional unit is determined, the content of the primary sub constitutional unit in each sample is more than 7 mole % in 100% of all constitutional units, and when an average of the contents of the primary sub constitutional unit is calculated, the contents thereof of all the samples fall within a range of ±2 mole % relative to the average.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: September 6, 2005
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Satoshi Hayakawa, Norimi Tabota, Yoshinori Takegawa, Katsuya Ito, Shigeru Komeda, Katsuhiko Nose
  • Patent number: 6905774
    Abstract: Biaxially-drawn polyester film for fabrication which is characterized in that it is a film comprising polyester in which ethylene terephthalate units and/or ethylene naphthalate units are the chief structural component, and the melting point of said film is 180-270° C., the angle of contact to water is 70°-120°, and the planar orientation coefficient is 0.08-0.15. This film shows outstanding release properties following repeated use, use after fabrication and use in an aqueous environment and, furthermore, it exhibits stable properties with little variation and, in particular, following lamination to metal sheet such as steel or aluminium, when used as the inner face of a fabricated metal can, it is outstanding in its non-stick properties to the contents, and provides a combination of heat resistance and processability.
    Type: Grant
    Filed: August 27, 2003
    Date of Patent: June 14, 2005
    Assignee: Toray Industries, Inc.
    Inventors: Kohzo Takahashi, Ryosuke Matsui, Masahiro Kimura
  • Patent number: 6893706
    Abstract: The invention relates to a white, biaxially-oriented and coextruded polyester film which is matt on at least one side with at least one base layer B, which contains a cycloolefin copolymer (COC) in amounts of 4 to 60 wt. %, based on the weight of the base layer, in addition to polyester starting material. The glass transition temperature Tg of the COC lies in the range from 70 to 270° C. Said film has at least one matt outer layer (A), made from polyester and is particularly suitable for use in fast running machines such as winding, metallising, printing or laminating machines.
    Type: Grant
    Filed: May 3, 2001
    Date of Patent: May 17, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Holger Kliesch, Gottfried Hilkert, Bart Janssens
  • Patent number: 6872461
    Abstract: The invention relates to a co-extruded, biaxially oriented polyester films containing a flame-retardant agent which can be dissolved in the polyester. The film has a matt outer layer which contains a mixture and/or a blend of two components (I) and (II), whereby component (I) is a polyethylene terephthalate homopolymer, or a polyethylene terephthalate copolymer, or a mixture of polyethylene terephthalate homopolymers or copolymers and component (II) is a polymer containing at least one sulphonate group.
    Type: Grant
    Filed: January 10, 2001
    Date of Patent: March 29, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Gottfried Hilkert
  • Patent number: 6872460
    Abstract: The invention relates to biaxially oriented, co-extruded polyester films. Said films comprise a base layer which consists of at least 70% by weight of a thermoplastic polyester, preferably polyethylene terephthalate (PET) with a diethylene glycol and/or polyethylene glycol content greater than 1.3% by weight and have at least one matt outer layer and optionally additional intermediate layers. The films also contain at least one UV-absorber, preferably hydroxy benzotriazoles and triazines. The films are characterized by high UV-stability, no embrittlement after exposure to temperature, a matt surface devoid of unwanted clouding and excellent thermoforming properties and are, together with the molded bodies produced therefrom, suitable for numerous interior and exterior applications.
    Type: Grant
    Filed: January 10, 2001
    Date of Patent: March 29, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass
  • Patent number: 6838546
    Abstract: The invention relates to an aromatic liquid-crystalline polyester solution composition comprising 100 parts by weight of a solvent (A) and 0.01 to 100 parts by weight of an aromatic liquid-crystalline polyester (B), wherein the solvent (A) is a solvent containing 30% by weight or more of a chlorine-substituted phenol compound represented by the following general formula (I): wherein A represents a hydrogen atom, a halogen atom or a tri-halogenated methyl group, and i represents an integer of 1 or more and 4 or less, a film obtained from the aromatic liquid-crystalline polyester, and a process for producing the film.
    Type: Grant
    Filed: July 27, 2001
    Date of Patent: January 4, 2005
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoshi Okamoto, Manabu Hirakawa
  • Patent number: 6808788
    Abstract: The strength of wood composites, including hybrid composites comprising wood members bonded to reinforced polyester members, is improved by modifying the polyester components with a polyisocyanate. Wood composites adhesively bonded with polyester resins modified according to this invention are particularly desirable for use in applications where exterior exposure is contemplated.
    Type: Grant
    Filed: May 17, 2002
    Date of Patent: October 26, 2004
    Assignee: The University of Maine
    Inventor: Ben R. Bogner
  • Patent number: 6787218
    Abstract: The invention relates to a transparent, biaxially oriented polyester film with a base layer B, at least 80% by weight of which is composed of a thermoplastic polyester, and with at least one outer layer A. The outer layer A is composed of a copolymer or a mixture of polymers/copolymers which contains ethylene 2,6-naphthalate units in a range of from 90 to 98% by weight and up to 10% by weight of ethylene terephthalate units, and/or units derived from cycloaliphatic or aromatic diols and/or dicarboxylic acids. Its thickness is more than 0.7 &mgr;m and makes up less than 25% by weight of the total film and the Tg2 value of the polyester film is above the Tg2 value of the base layer, but below the Tg2 value of the polyester for the outer layer. The transparent film has low permeability to atmospheric oxygen and exhibits very good adhesion between the individual layers. It is particularly suitable for packaging purposes, specifically for packaging foods or other consumable items.
    Type: Grant
    Filed: July 20, 2001
    Date of Patent: September 7, 2004
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Gottfried Hilkert, Richard Lee Davis
  • Publication number: 20040171788
    Abstract: Provided is a main chain type liquid crystal polyester which comprises at least two units selected from an aromatic diol unit, an aromatic dicarboxylic acid unit, and an aromatic hydroxycarboxylic acid unit as essential units and a structural unit having a cationically polymerizable unit in at least one of the terminal ends. The main chain type liquid crystalline polyester, when used as an optical material, is excellent in the capability of retaining a liquid crystal orientation having been aligned and fixed under practical service conditions and exhibits an excellent mechanical strength.
    Type: Application
    Filed: December 5, 2003
    Publication date: September 2, 2004
    Inventors: Yasushi Satoh, Tadahiro Kaminade, Hitoshi Mazaki
  • Publication number: 20040152865
    Abstract: An aromatic liquid-crystalline polyester having a small dielectric loss in a wide frequency region is provided. An aromatic liquid-crystalline polyester is provided that can manufacture a film having a small volume expansion by heating. An aromatic liquid-crystalline polyester substantially comprising a repeating structural unit originating in 2-hydroxy-6-naphthoic acid 30 to 80 mol %, a repeating structural unit originating in aromatic diol 35 to 10 mol %, and a repeating structural unit originating in aromatic dicarboxylic acid 35 to 10 mol %.
    Type: Application
    Filed: December 17, 2003
    Publication date: August 5, 2004
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Satoshi Okamoto, Tomoya Hosoda, Shinji Ohtomo
  • Patent number: 6723444
    Abstract: The present invention provides an image recording material as well as a protective film and an image display material using the same, the image recording material comprising at least: a transparent substrate; an image-receiving layer for forming an image by an electrophotographic system and disposed on one side of the substrate; and a function controlling means disposed on the other side of the substrate; wherein the image-receiving layer include a polyester resin which comprises a structural unit represented by the structural formula (I) and which has a number average molecular weight of 12,000 to 45,000: wherein n and m represent integers such that a molar ratio n/m is from 1 to 9.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: April 20, 2004
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Tomoo Kobayashi, Kunio Sakurai, Kaoru Torikoshi
  • Publication number: 20040044171
    Abstract: The object is to provide liquid crystalline polyester which gives molded articles without generating acetic acid gas, and a method for producing the liquid crystalline polyester. This object is achieved by a method for producing a liquid crystalline polyester comprising melt-polymerizing aromatic hydroxycarboxylic acid represented by the formula (I), aromatic diol represented by the formula (II), and aromatic dicarboxylic acid represented by the formula (III) with using a diaryl carbonate represented by the formula (IV).
    Type: Application
    Filed: August 26, 2003
    Publication date: March 4, 2004
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Satoshi Okamoto, Manabu Hirakawa
  • Patent number: 6660398
    Abstract: The invention concerns powder thermosetting coating compositions comprising (a) an amorphous polyester containing carboxyl groups, rich in isophthalic acid and neopentylglycol, optionally branched with a polycarboxylic acid or a polyol containing at least three functional groups; (b) a semicrystalline polyester containing carboxyl groups prepared from one or several saturated aliphatic dicarboxylic acids with linear chain, and from a saturated aliphatic diol with linear or cyclic chain optionally branched with a polycarboxylic acid or with a polyol containing at least three functional groups, and having a melting point (Tm) of at least 40° C. and an acid value of 5 to 50 mg of KOH/g, and (c) a cross-linking agent. Said compositions are useful for preparing powder paints and varnishes providing excellent quality coatings whereof the brilliance, measured at an angle of 60°, according to the ASTM D 523 standard is always less than 50%, that is half-gloss or matt coatings.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: December 9, 2003
    Assignee: UCB, S.A.
    Inventors: Luc Moens, Kris Buysens, Daniel Maetens
  • Patent number: 6652979
    Abstract: Biaxially-drawn polyester film for fabrication which is characterized in that it is a film comprising polyester in which ethylene terephthalate units and/or ethylene naphthalate units are the chief structural component and containing 0.1-2 wt % of a carnauba wax and 1 to 200 ppm of germanium, and the melting point of said film is 180-270° C., the angle of contact to water is 70°-120°, and the planar orientation coefficient is 0.08-0.15. This film shows outstanding release properties following repeated use, use after fabrication and use in an aqueous environment and, furthermore, it exhibits stable properties with little variation and, in particular, following lamination to metal sheet such as steel or aluminium, when used as the inner face of a fabricated metal can, it is outstanding in its non-stick properties to the contents, and provides a combination of heat resistance and processability.
    Type: Grant
    Filed: August 2, 2001
    Date of Patent: November 25, 2003
    Assignee: Toray Industries, Inc.
    Inventors: Kohzo Takahashi, Ryosuke Matsui, Masahiro Kimura
  • Patent number: 6641900
    Abstract: A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: November 4, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Timothy J. Hebrink, William W. Merrill, Carl A. Stover
  • Patent number: 6617006
    Abstract: A biaxially oriented polyester film to be laminated on a metal plate and molded, which comprises an aromatic polyester composition comprising: (A) an aromatic polyester which comprises ethylene terephthalate as the main recurring unit and a titanium compound and a phosphorus compound both of which satisfy at least one of the following expressions (1) and (2): 0.1≦Ti/P≦3.0  (1) 5≦Ti+P≦60  (2) wherein Ti is the amount (mmol %) of elemental titanium of the titanium compound contained in this aromatic polyester and P is the amount (mmol %) of elemental phosphorus of the phosphorus compound contained in the aromatic polyester, and the following expression (3): 2≦Ti≦20  (3) wherein Ti is as defined hereinabove, and which contains alkali metal compounds, germanium compound and antimony compound in a total amount of not more than 3 ppm in terms of the total of elemental alkali metals, elemental germanium and elemental antimony; and (B) 0.05 to 5.
    Type: Grant
    Filed: September 7, 2001
    Date of Patent: September 9, 2003
    Assignee: Teijin Limited
    Inventors: Koji Kubo, Masahiko Kosuge, Shunsuke Kubota, Kinji Hasegawa, Nobuo Minobe, Kimihiko Sato
  • Patent number: 6461742
    Abstract: The invention concerns a polyester bearing tertiary carboxyl groups, characterised in that it consists of: (a) 8.1 to 35 moles of an aliphatic or cycloaliphatic of a polyol; (b) 9.1 to 36 moles of an aliphatic, cycloaliphatic or aromatic polycarboxylic acid; (c) 1.6 to 2.8 moles of an aliphatic, cycloaliphatic or aromatic compound comprising a tertiary carboxyl group and either a primary or secondary carboxyl group, or a primary or secondary hydroxyl group. Said polyester is prepared in several steps, the first steps consisting in the preparation of a polyester by condensation between (a) an aliphatic or cycloaliphatic polyol, and (b) an aliphatic, cycloaliphatic or aromatic polycarboxylic acid, the final step consisting in condensing said polyester with (c) an aliphatic, cycloaliphatic or aromatic compound comprising a tertiary carboxyl group and either a primary or secondary carboxyl group, or a primary or secondary hydroxyl group.
    Type: Grant
    Filed: July 27, 2000
    Date of Patent: October 8, 2002
    Assignee: UCB, S.A.
    Inventors: Luc Moens, Kris Buysens, Daniel Maetens
  • Patent number: 6461698
    Abstract: The invention relates to a composition comprising from 20 to 70 parts by weight of poly[ethylene terephthalate] (PET), from 20 to 70 parts by weight of poly[ethylene naphthalate] (PEN) and from 10 to 33 parts by weight of poly[butylene terephthalate] (PBT), the total being 100 parts by weight, in the form of a polymer blend and/or copolymer.
    Type: Grant
    Filed: September 22, 2000
    Date of Patent: October 8, 2002
    Assignee: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd)
    Inventors: Farideh Bassam, Michael David Thompson, Barry Woodfine
  • Patent number: 6414063
    Abstract: The application relates to a composition poly[ethylene terephthalate] (PET) and poly[ethylene naphthalate] (PEN), in the form of a polymer blend and/or copolymer, in which the PET:PEN mol ratio is from 20:80 to 80:20, and from 0.1 to 5.0 wt. %, based on the total weight of the composition, of a transition metal salt of a carboxylic acid.
    Type: Grant
    Filed: September 20, 2000
    Date of Patent: July 2, 2002
    Assignee: Kobe Steel, Ltd.
    Inventors: Farideh Bassam, Michael David Thompson, Barry Woodfine
  • Patent number: 6372326
    Abstract: A biaxially oriented polyester film to be molded and laminated with a metal sheet which shows excellent moldability when it is laminated with a metal sheet and subjected to a can making process such as drawing and from which a metal can such as a drink can or food can having excellent heat resistance, retort resistance, taste and odor retention properties, impact resistance and corrosion preventing properties can be produced. This polyester film is produced from a copolyester which contains porous particles having an average particle diameter of 0.1 to 2.5 &mgr;m, a pore volume of 0.05 to 2.5 ml/g, a specific surface area of 50 to 600 m2/g and a compressive resistance of 1 to 100 MPa and has a glass transition temperature of 70° C. or higher and lower than 78° C., a melting point of 210 to 250° C. and an intrinsic viscosity of 0.50 to 0.80 dl/g.
    Type: Grant
    Filed: September 26, 2000
    Date of Patent: April 16, 2002
    Assignee: Teijin Limited
    Inventors: Masahiko Kosuge, Hideshi Kurihara
  • Patent number: 6368724
    Abstract: A copolyester blend resistant to ultraviolet radiation includes a polyethylene terephthalate based copolyester having 1,4-cyclohexanedimethanol; an effective amount of an ultraviolet radiation absorber selected from the group consisting of benzoxazinones, dimeric benzotriazoles, triazines and mixtures thereof; and from 5 mol % to about 40 mol % isophthalic acid residues present in the copolyester wherein the mole percent is based on 100 mole percent of dicarboxylic acid or equivalents. The copolyester blend is useful in making UV radiation resistant thermoformed articles.
    Type: Grant
    Filed: December 13, 1999
    Date of Patent: April 9, 2002
    Assignee: Eastman Chemical Company
    Inventor: David Richard Fagerburg