Carboxylic Acid Contains At Least Four Carboxylic Acid Groups Or Is A Derivative Of A Carboxylic Acid Containing At Least Four Carboxylic Groups Patents (Class 528/353)
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Patent number: 12146057Abstract: Provided is a resin composition that has a low melt viscosity, and is capable of being turned into a cured product having a high heat resistance, a high adhesion and a high glass-transition temperature, though having a low permittivity and a low dielectric tangent. The resin composition is a cyclic imide resin composition containing: (a) a cyclic imide compound represented by the following formula (1), (b) a cyclic imide compound represented by the following formula (2), and (c) a curing catalyst.Type: GrantFiled: December 13, 2021Date of Patent: November 19, 2024Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Hiroyuki Iguchi, Masayuki Iwasaki, Naoyuki Kushihara
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Patent number: 12018128Abstract: A particle-dispersed polyimide precursor solution contains a polyimide precursor having a unit represented by the following formula (I), particles, and a solvent, in which the particle-dispersed polyimide precursor solution satisfies both the following conditions (1) and (2), (in the formula (I), A represents a tetravalent organic group, and B represents a divalent organic group represented by any of the following formulas (B1) to (B4)), (in the formulas (B1) to (B4), Ar1, Ar10, and Ar11 each independently represent a trivalent aromatic group which may have a substituent, Ar2, Ar4, Ar5, Ar7 and Ar8 each independently represent a divalent aromatic group which may have a substituent, Ar3 and Ar6 each independently represent a tetravalent aromatic group which may have a substituent or a group represented by the following formula (II), Ar9 represents a divalent aromatic group which may have a substituent or a group represented by the following formula (III), X1 to X7 each independently represent NType: GrantFiled: July 20, 2021Date of Patent: June 25, 2024Assignee: FUJIFILM Business Innovation Corp.Inventors: Tomoya Sasaki, Hidekazu Hirose, Kosaku Yoshimura, Yasunobu Kashima, Hajime Sugahara, Kosuke Nakada, Tomoyo Okubo
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Patent number: 11820893Abstract: Embodiments relate to a polymer film that is excellent in folding characteristics and transparency and maintains excellent mechanical properties even after repeated elongation and shrinkage in the elastic region, a process for preparing the same, and a front panel and a display device comprising the same. The polymer film comprises a polymer resin selected from the group consisting of a polyamide-based resin and a polyimide-based resin and has an MOR0/9 of Equation A of 2% or less.Type: GrantFiled: June 26, 2020Date of Patent: November 21, 2023Assignee: SK Microworks Co., LTD.Inventors: Jung Hee Ki, Sunhwan Kim, Han Jun Kim, Dae Seong Oh, Jin Woo Lee, Sang Hun Choi, Gun Uk Kim
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Patent number: 11705418Abstract: A semiconductor package includes a semiconductor chip including a contact pad on an active surface, a first insulating layer on the active surface including a first opening that exposes the contact pad, a redistribution layer connected to the contact pad and extending to an upper surface of the first insulating layer, a second insulating layer on the first insulating layer and including a second opening that exposes a contact region of the redistribution layer, a conductive post on the contact region, an encapsulation layer on the second insulating layer and surrounding the conductive post, and a conductive bump on an upper surface of the conductive post. The conductive post includes an intermetallic compound (IMC) layer in contact with the conductive bump. An upper surface of the IMC layer is lower than an upper surface of the encapsulation layer.Type: GrantFiled: September 11, 2020Date of Patent: July 18, 2023Assignee: Samsung Electronics Co., Ltd.Inventors: Hyunsoo Chung, Taewon Yoo, Myungkee Chung
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Patent number: 11508937Abstract: Provided is a light-diffusing barrier film. The film is an integral film comprising a barrier layer, a base layer and a light-diffusing layer, sequentially. The film can prevent moisture penetration into a device such as an organic light emitting device, and also imparts a light-diffusing function to the device. In particular, the film can have excellent moisture blocking properties even after a roll-to-roll process.Type: GrantFiled: April 17, 2019Date of Patent: November 22, 2022Assignee: LG CHEM, LTD.Inventors: Hee Joon Jeong, Jang Yeon Hwang, Bo Ra Park, Sung Jin Shin, Hee Wang Yang
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Patent number: 11487201Abstract: A photosensitive resin composition comprising (A) a polyimide precursor having a polymerizable unsaturated bond; (B) a polymerizable monomer having an aliphatic cyclic skeleton; (C) a photopolymerization initiator; and (D) a solvent.Type: GrantFiled: March 30, 2018Date of Patent: November 1, 2022Assignee: HD MicroSystems, Ltd.Inventors: Etsuharu Tsuchiya, Tetsuya Enomoto, Takashi Kawamori, Nobuyuki Saito, Yukari Koibuchi, Atsutaro Yoshizawa, Akira Asada
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Patent number: 11137644Abstract: The present invention relates to a polymer which is excellent in terms of liquid crystal alignment property, durability, and electrical characteristics, and thus is suitable for use in a liquid crystal aligning agent, a liquid crystal aligning agent composition including the same, a liquid crystal alignment film formed from the liquid crystal aligning agent composition, and a liquid crystal display device including the liquid crystal alignment film.Type: GrantFiled: August 16, 2018Date of Patent: October 5, 2021Assignee: LG CHEM, LTD.Inventors: Seongku Kim, Hee Han, Jung Ho Jo, Sung Joon Min, Soon Ho Kwon, Jun Young Yoon, Hyeongseuk Yun, Hoonseo Park
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Patent number: 11136506Abstract: A polymer having excellent liquid crystal alignment and electrical properties and thus is suitable for use as a liquid crystal alignment agent, a liquid crystal alignment agent including the same, a liquid crystal alignment film formed from the liquid crystal alignment agent, and a liquid crystal display device including the liquid crystal alignment film are provided.Type: GrantFiled: September 20, 2018Date of Patent: October 5, 2021Assignee: LG CHEM, LTD.Inventors: Soon Ho Kwon, Jung Ho Jo, Sung Joon Min, Hang Ah Park, Jun Young Yoon
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Patent number: 11077647Abstract: Provided is an inexpensive thermally conductive silicone rubber composite sheet. The thermally conductive silicone rubber composite sheet of the invention includes a laminated structure body comprised of an intermediate layer and an outer layer laminated on both surfaces of the intermediate layer, in which (A) the intermediate layer is an electrical insulating synthetic resin film layer having a thermal conductivity of not lower than 0.20 W/m·K and a tensile elastic modulus of not lower than 5 GPa, and (B) the outer layer is a silicone rubber layer of a cured product of a composition containing: (a) an organopolysiloxane; (b) a curing agent; (c) a thermally conductive filler; and (d) a silicon compound-based adhesion imparting agent having at least one kind of group selected from the group consisting of an epoxy group, an alkoxy group, a methyl group, a vinyl group and a Si—H group.Type: GrantFiled: July 12, 2017Date of Patent: August 3, 2021Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Akihiro Endo, Yuki Tanaka
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Patent number: 10844173Abstract: A method for manufacturing a poly(imide) prepolymer powder includes combining a bisanhydride powder or organic diamine and a solvent comprising an alcohol, a water-soluble ketone or water to form a mixture, adding an organic diamine or bisanhydride powder to the mixture to form a poly(imide) prepolymer, and removing the solvent to provide the poly(imide) prepolymer powder. A method for manufacturing a poly(imide) prepolymer varnish includes combining a bisanhydride powder or organic diamine and a solvent comprising an alcohol, a water-soluble ketone or water to form a mixture, and adding an organic diamine or bisanhydride powder to the mixture to form a poly(imide) prepolymer. The method of manufacturing the varnish further includes at least one of adding an effective amount of a secondary or tertiary amine to solubilize the poly(imide) prepolymer powder, heating the mixture to a temperature effective to provide the varnish, or agitating the mixture to provide the varnish.Type: GrantFiled: August 1, 2017Date of Patent: November 24, 2020Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Viswanathan Kalyanaraman, Norimitsu Yamaguchi
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Patent number: 10800882Abstract: The present disclosure relates to a polyimide-based block copolymer and a polyimide-based film including the same. The polyimide-based block copolymer according to the present disclosure makes it possible to provide a polyimide-based film exhibiting excellent mechanical properties while having a high molecular weight, and being colorless and transparent.Type: GrantFiled: September 8, 2017Date of Patent: October 13, 2020Assignee: LG CHEM, LTD.Inventors: Sang Gon Kim, Sung Yeol Choi, Duk Hun Jang, Hyung Sam Choi
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Patent number: 10767014Abstract: The instant disclosure relates to a method for manufacturing a transparent polyimide film, including providing a polyamic acid solution having a fluorine content more than 12%; adding a dehydrating agent and a catalyst into the polyamic acid solution, the dehydrating agent having an equivalent number equal to or larger than 3; and baking the polyamic acid solution under a temperature ranging from 250 to 350° C. for performing a chemical imidization process so that the transparent polyimide film is obtained. The transparent polyimide film has an elongation rate of more than 30% and a b* value in a CIELAB coordinate of less than 3.5.Type: GrantFiled: October 18, 2017Date of Patent: September 8, 2020Assignee: TAIMIDE TECH. INC.Inventor: Wen-Hsuan Chung
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Patent number: 10696901Abstract: Provided are a method of manufacturing a liquid crystal alignment layer, a liquid crystal alignment layer manufactured by using the same, and a liquid crystal display device including the liquid crystal alignment layer. More specifically, provided are the method of manufacturing the liquid crystal alignment layer with enhanced alignment property and stability, in which a liquid crystal aligning agent is applied onto a substrate, and after drying, alignment treatment is immediately performed by light irradiation while omitting a high-temperature heat treatment process, and then the alignment-treated coating film is cured by heat treatment, thereby reducing light irradiation energy required in the process and simplifying the process by omitting the high-temperature heat treatment process before light irradiation, the liquid crystal alignment layer, and the liquid crystal display device including the same.Type: GrantFiled: November 2, 2016Date of Patent: June 30, 2020Assignee: LG CHEM, LTD.Inventors: Jung Ho Jo, Hang Ah Park, Soon Ho Kwon, Hee Han, Jun Young Yoon, Hyeong Seuk Yun
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Patent number: 10538665Abstract: This invention relates to a highly heat-resistant polyamic acid solution and a polyimide film having improved thermal dimensional stability, wherein the polyamic acid solution includes a polymer of a diamine compound, containing 1 to 10 mol % of a carboxylic acid functional group-containing diamine compound based on the total amount of diamine, and a dianhydride compound, and the polyimide film includes polyimide, which is an imidized product of the polyamic acid solution and is configured such that main chains thereof are crosslinked through an amide bond (—CONH—).Type: GrantFiled: June 30, 2015Date of Patent: January 21, 2020Assignee: KOLON INDUSTRIES, INC.Inventors: Woong Ki Min, Hyo Jun Park, Hak Gee Jung, Ki Il Hong
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Patent number: 10517171Abstract: The present invention relates to a method for producing a flexible substrate. According to the method of the present invention, a flexible substrate layer can be easily separated from a carrier substrate even without the need for laser or light irradiation so that a device can be prevented from deterioration of reliability and occurrence of defects caused by laser or light irradiation. In addition, according to the method of the present invention, a flexible substrate can be continuously produced in an easier manner based on a roll-to-roll process.Type: GrantFiled: July 25, 2016Date of Patent: December 24, 2019Assignee: LG CHEM, LTD.Inventors: Hye Won Jeong, Yong Goo Son, Kyungjun Kim, Bo Ra Shin, Chang Yoon Lim
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Patent number: 10374247Abstract: The present invention relates to a porous support, a preparation method therefor, and a reinforced membrane containing the same, wherein the porous support comprises a nanoweb in which nanofibers are integrated in the form of a nonwoven fabric comprising a plurality of pores, and the nanoweb has an elongation at break of 1-10%. The porous support has excellent air permeability and water permeability, remarkable durability, heat resistance and chemical resistance, and excellent mechanical strength and processability.Type: GrantFiled: February 24, 2015Date of Patent: August 6, 2019Assignee: KOLON FASHION MATERIAL. INC.Inventors: Heung Ryul Oh, Sung Jin Kim, Yong Hwan Lee, Hwan Kwon Rho, Chul Ki Kim, Jeong Young Choi, Jun Young Park, Ji Suk Baek
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Patent number: 10316144Abstract: The invention provides a selenium-containing polyimide polymer, preparation method and use thereof. The method comprises: (1) polymerizing a selenide diamine monomer with a dianhydride monomer to give a selenium-containing polyamic acid; and (2) performing thermal imidization on the selenium-containing polyamic acid obtained in the step (1) to give a selenium-containing polyimide polymer. In the invention, selenium is introduced into polyimides for increasing refractive index to 1.7-1.82, this greatly improves the defects of low refractive index of the existing polyimide materials, thereby expanding its applications in the optics field.Type: GrantFiled: December 16, 2016Date of Patent: June 11, 2019Assignee: SOOCHOW UNIVERSITYInventors: Jian Zhu, Qilong Li, Chunlai Ding, Huinan Jiang, Xiulin Zhu
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Patent number: 10226743Abstract: Provided are a gas separation composite membrane including a gas separation layer which is formed to include a polyimide compound on the upper side of a gas permeating support, in which the solubility of the polyimide compound in dimethylacetamide at 20° C. is 20 mg/100 g or less, and the thickness of the gas separation layer is 0.1 ?m or greater and less than 5.0 ?m, a method of producing the same, a gas separation module using the gas separation composite membrane, a gas separation device, and a gas separation method.Type: GrantFiled: July 5, 2016Date of Patent: March 12, 2019Assignee: FUJIFILM CorporationInventors: Takayasu Nagai, Daisuke Sawai, Satoshi Sano
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Patent number: 10201682Abstract: Some embodiments of a medical device anchor system include an anchor device that secures a medical instrument (such as a catheter or the like) in place relative to a skin penetration point using subcutaneous anchors. In some implementations, the anchor device can be installed using a technique in which the subcutaneous anchors undergo relatively little or no flexing when being inserted through the skin into the subcutaneous region between the skin and underlying muscle tissue which may be occupied by fatty tissue.Type: GrantFiled: May 5, 2017Date of Patent: February 12, 2019Assignee: INTERRAD Medical, Inc.Inventors: Michael S. Rosenberg, Mark R. Christianson, Kyle P. Taylor, Andrew T. Forsberg
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Patent number: 10177022Abstract: The present invention provides a temporary-bonding adhesive having excellent heat resistance, whereby a semiconductor circuit formation substrate and a support substrate can be bonded by a single type of adhesive layer, the adhesive force thereof does not change over the course of steps for manufacturing a semiconductor device or the like, and the adhesive can subsequently be easily de-bonded at room temperature under mild conditions; and a method for manufacturing a semiconductor device using the temporary-bonding adhesive. The present invention includes a temporary-bonding adhesive wherein a polyimide copolymer having at least an acid dianhydride residue and a diamine residue, the diamine residue including both of (A1) a polysiloxane-based diamine residue represented by a general formula (1) in which n is a natural number from 1 to 15, and (B1) a polysiloxane-based diamine residue represented by a general formula (1) in which n is a natural number from 16 to 100, the polyimide copolymer containing 40-99.Type: GrantFiled: August 5, 2015Date of Patent: January 8, 2019Assignee: Toray Industries, Inc.Inventors: Shinji Arimoto, Takenori Fujiwara, Masao Tomikawa
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Patent number: 9902810Abstract: The present invention addresses the problem of providing: a polyimide film that has a small phase difference in the thickness direction and has a low coefficient of linear thermal expansion; and a polyamic acid and varnish to obtain the same. In order to solve this problem, the present invention provides a polyimide film which comprises polyimide that is produced by reacting a diamine component and a tetracarboxylic dianhydride component, the polyimide film having a coefficient of linear thermal expansion of 35 ppm/K or less over a temperature range of 100 to 200 DEG C, an absolute value of phase difference in the thickness direction of 200 nm or less per 10 ?m thickness, a glass transition temperature of 260 DEG C or more, and a total light transmittance of 85% or more.Type: GrantFiled: April 1, 2014Date of Patent: February 27, 2018Assignee: MITSUI CHEMICALS, INC.Inventors: Tatsuhiro Urakami, Masaki Okazaki, Kenichi Fukukawa, Yoshihiro Sakata, Atsushi Okubo
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Patent number: 9833977Abstract: A substrate structure applied in flexible electrical devices is provided. The substrate structure includes a carrier, a first material layer overlying the carrier with a first area, a second material layer overlying the first material layer and the carrier with a second area, and a flexible substrate overlying the second material layer, the first material layer and the carrier with a third area, wherein the second area is larger than or equal to the first area, the third area is larger than the second area, and the flexible substrate has a greater adhesion force than that of the first material layer to the carrier. The invention also provides a method for fabricating the substrate structure.Type: GrantFiled: December 1, 2009Date of Patent: December 5, 2017Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Chyi-Ming Leu, Yueh-Chuan Huang, Yung Lung Tseng
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Patent number: 9788432Abstract: Polymer materials make useful materials as electrode array bodies for neural stimulation. They are particularly useful for retinal stimulation to create artificial vision. Regardless of which polymer is used, the basic construction method is the same. A layer of polymer is laid down. A layer of metal is applied to the polymer and patterned by wet etch to create electrodes and leads for those electrodes. The base polymer layer is activated. A second layer of polymer is applied over the metal layer and patterned to leave openings for the electrodes, or openings are created later by means such as laser ablation. Hence the array and its supply cable are formed of a single body.Type: GrantFiled: June 2, 2015Date of Patent: October 10, 2017Assignee: Second Sight Medical Products, Inc.Inventors: Robert J Greenberg, Jerry Ok, Jordan Matthew Neysmith, Brian V Mech, Neil Hamilton Talbot
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Patent number: 9631090Abstract: A method for using citraconic anhydride and itaconic anhydride as addition cure end caps in reactions for forming polyamic acid oligomers and polyimide oligomers, is provided. Prepregs and high temperature adhesives made from the resulting oligomers, as well as, high temperature, low void volume composites made from the prepregs, are also provided.Type: GrantFiled: June 20, 2011Date of Patent: April 25, 2017Assignee: I.S.T. (MA) CorporationInventors: Gary L. Deets, Jianming Xiong
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Patent number: 9315620Abstract: The present invention relates to (per)fluoropolymer compositions, in particular to (per)fluoropolyether compositions comprising:—a (per)fluoropolymer having more than two carboxy groups and—a polyamine. The invention further relates to processes for preparing said compositions and to molded articles obtained from said compositions.Type: GrantFiled: July 17, 2012Date of Patent: April 19, 2016Assignee: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.Inventors: Vincenzo Arcella, Claudio Adolfo Pietro Tonelli, Solange Barbieri
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Patent number: 9304356Abstract: A liquid crystal display including a first substrate and a second substrate facing each other, a first alignment layer disposed on the first substrate, the first alignment layer including a vertical photo-alignment material, a second alignment layer disposed on the second substrate, the second alignment layer including a vertical alignment material, and a liquid crystal layer disposed between the first substrate and the second substrate.Type: GrantFiled: November 3, 2011Date of Patent: April 5, 2016Assignee: SAMSUNG DISPLAY CO., LTD.Inventors: Suk Hoon Kang, Jun Woo Lee, Baek Kyun Jeon, Kyoung Tae Kim, Soo-Ryun Cho
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Patent number: 9243119Abstract: Disclosed is a polyimide film, which is colorless and transparent, with superior mechanical properties and high thermal stability.Type: GrantFiled: August 27, 2008Date of Patent: January 26, 2016Assignee: KOLON INDUSTRIES, INC.Inventors: Hak Gee Jung, Hyo Jun Park, Sang Min Song, Chung Seock Kang
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Patent number: 9139707Abstract: A method of producing a composite material, comprising an assembly of natural fibers, impregnated with an amorphous or semi-crystalline thermoplastic polymer, said method including: i) a step of impregnating said assembly with a precursor composition in the molten state and including: a) at least one prepolymer P(X)n of said thermoplastic polymer, having a molecular chain P having, at the ends of same, n reactive functions X, with n ranging from 1 to 3, in particular n being 1 or 2, and preferably 2 b) at least one chain extender Y-A-Y including reactive functions Y with at least one of said functions X ii) a step of polymerization by mass (poly)addition, in the molten state, of said prepolymer with said chain extender with: said thermoplastic polymer being the result of said polymerization by mass polyaddition and said impregnation i) and polymerization ii) taking place at a temperature lower than 250° C.Type: GrantFiled: May 30, 2013Date of Patent: September 22, 2015Assignee: ARKEMA FRANCEInventors: Gilles Hochstetter, Marc Audenaert, Thierry Briffaud
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Patent number: 9127127Abstract: A method for the manufacture of a polyetherimide composition includes catalyzing the reaction of a dianhydride and an organic diamine with a catalyst selected from guanadinium salts, pyridinium salts, imidazolium salts, tetra(C6-24)aryl ammonium salts, tetra(C7-24 arylalkylene) ammonium salts, dialkyl heterocycloaliphatic ammonium salts, bis-alkyl quaternary ammonium salts, (C7-24arylalkylene)(C1-16alkyl) phosphonium salts, (C6-24aryl)(C1-16alkyl)phosphonium salts, phosphazenium salts and combinations thereof, optionally in the presence of a solvent.Type: GrantFiled: October 11, 2012Date of Patent: September 8, 2015Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Thomas Link Guggenheim, Roy Ray Odle, Farid Fouad Khouri
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Patent number: 9127363Abstract: An article having at least one fluorinated porous layer having a basis weight of about 10 to about 300 grams per square meter and a thickness of about 0.20 to about 20 millimeters. The porous layer also exhibits a Q200 of greater than about 1.1.Type: GrantFiled: January 11, 2011Date of Patent: September 8, 2015Assignee: 3M Innovative Properties CompanyInventors: Moses M. David, Gina M. Buccellato, John S. Huberty, Seth M. Kirk
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Patent number: 9101135Abstract: An object of the present invention is to provide insecticides having high effectiveness.Type: GrantFiled: June 24, 2014Date of Patent: August 11, 2015Assignee: MITSUI CHEMICALS, INC.Inventors: Kei Yoshida, Takeo Wakita, Hiroyuki Katsuta, Akiyoshi Kai, Yutaka Chiba, Kiyoshi Takahashi, Hiroko Kato, Nobuyuki Kawahara, Michikazu Nomura, Hidenori Daido, Junji Maki, Shinichi Banba, Atsuko Kawahara
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Patent number: 9096760Abstract: Thermoplastic compositions having miscible and compatible immiscible polymer blends are disclosed. The miscible polymer blends have a single glass transition temperature. The compatible polymer blends have two glass transition temperatures.Type: GrantFiled: March 19, 2013Date of Patent: August 4, 2015Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Robert Russell Gallucci, Tara Mullen, Roy Odle, Kapil Chandrakant Sheth, James M. White
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Patent number: 9096566Abstract: A polyesterimide having a repeating unit expressed by formula (3) is useful for FPC substrates, COF substrates and TAB substrate materials, especially as FPC substrate materials: wherein R represents a phenyl group, R1 represents an alkyl group with 1 to 6 carbon atoms or alkoxy group with 1 to 6 carbon atoms, n each independently takes a value of 0 to 4, a each independently takes a value of 0 to 4, and m represents an integer of 2 to 4, where not all n's are 0 at the same time and 0?n+a?4 is satisfied by each phenylene group, and X is a divalent aromatic group and/or aliphatic group.Type: GrantFiled: February 12, 2010Date of Patent: August 4, 2015Assignee: Honshu Chemical Industry Co., Ltd.Inventors: Masatoshi Hasegawa, Tadashi Hiramine, Yuuki Hashimoto
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Patent number: 9052654Abstract: A polyamic acid composition includes a conductive carbon black and a polyamic acid in which a diamine compound, a tetracarboxylic acid dianhydride, and an acid monoanhydride have been reacted at a quantitative ratio satisfying the following Relational Expression (1) and Relational Expression (2). In Relational Expressions (1) and (2), X represents a content by mol of the diamine compound, Y represents a content by mol of the tetracarboxylic acid dianhydride, and Z represents a content by mol of the acid monoanhydride. 0.962?Y/X?0.997??Relational Expression (1) 0.20?Z/2(X?Y)<0.80.Type: GrantFiled: March 11, 2009Date of Patent: June 9, 2015Assignee: FUJI XEROX CO., LTD.Inventor: Kenya Sonobe
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Publication number: 20150147554Abstract: A composition for preparing a polyimide including a tetracarboxylic dianhydride mixture including a tetracarboxylic dianhydride represented by Chemical Formula 1A, Chemical Formula 1B, or a combination thereof, a tetracarboxylic dianhydride represented by Chemical Formula 2, and a diamine represented by Chemical Formula 3: NH2—R1—NH2 ??Chemical Formula 3 wherein in Chemical Formulae 1A, 1B, 2 and 3, definitions of groups and substituents are described in the specification.Type: ApplicationFiled: November 21, 2014Publication date: May 28, 2015Inventors: Jungha CHAE, Byung Hee SOHN
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Publication number: 20150118472Abstract: A process includes the steps of: casting or coating a polyamic acid organic solvent solution on a support and drying the polyamic acid organic solvent solution thereon, so as to form a partially cured and/or partially dried polyamic acid film; dipping the polyamic acid film in tertiary amine or a solution of tertiary amine, or coating tertiary amine or a solution of tertiary amine on the polyamic acid film; and drying the film while imidizing the polyamic acid. In another process, a chemical converting agent and a catalyst are mixed in an organic solvent solution of polyamic acid. After casting and heating the mixture on a support, a partially cured and/or partially dried polyamic acid film is detached from the support. The film contains, with respect to the remaining volatile component, not less than 50 parts of catalyst, not more than 30 parts of solvent, and not more than 20 parts of chemical converting agent and/or a chemical converting agent derived component.Type: ApplicationFiled: December 24, 2014Publication date: April 30, 2015Applicant: KANEKA CORPORATIONInventors: Hisayasu Kaneshiro, Toshihisa Itoh, Katsunori Yabuta, Kiyokazu Akahori
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Patent number: 9018343Abstract: Disclosed herein is a polyamide-imide copolymer film, comprising a copolymer resin in which a unit structure derived from TFDB (2,2?-bistrifluoromethyl-4,4?-biphenyl diamine), a unit structure derived from 6FDA (4,4?-(hexa-fluoroisopropylidene)diphthalic anhydride), a unit structure derived from BPDA (3,3?,4,4?-biphenyltetracarboxylic dianhydride) and a unit structure derived from TPC (terephthaloyl chloride or 1,4-benzenedicarbonyl chloride) are copolymerized, wherein the copolymer resin has a weight average molecular weight of 10,000˜400,000.Type: GrantFiled: September 27, 2012Date of Patent: April 28, 2015Assignee: Kolon Industries, Inc.Inventors: Hyo Jun Park, Hak Gee Jung
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Patent number: 9012595Abstract: The present invention provides polyimide applied to the buffer coating of semiconductors and a photosensitive resin composition including the same. The polyimide is a polyimide polymer represented by Chemical Formula 1 below. Further, the present invention provides a photosensitive resin composition, including 1) BDA-series soluble polyimide having an i-ray permeability of 70% or more; 2) a polyamic acid having elongation of 40% or more; 3) a novolak resin, and 4) diazonaphthoquinone-series photosensitive substance and having a high resolution, high sensitivity, an excellent film characteristic, and mechanical physical properties which are the requirements of semiconductor buffer coating.Type: GrantFiled: November 5, 2010Date of Patent: April 21, 2015Assignee: LG Chem, Ltd.Inventors: Sang Woo Kim, Chanhyo Park, Kyungjun Kim, Hyeran Seong, Sejin Shin, Hye Won Jeong, Jung Ho Jo
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Publication number: 20150079005Abstract: Nanocarriers are synthesized with polymers that respond to lower pH and/or ROS by being degraded. The compositions may be utilized to selectively deliver payloads within patients by responding to lower pH and/or ROS at localities within the patient. The present invention also features methods of synthesizing nanocarriers that are degraded by lower pH and/or ROS.Type: ApplicationFiled: May 7, 2014Publication date: March 19, 2015Applicant: The Regents of the University of CaliforniaInventors: Adah Almutairi, Jagadis Sankaranarayanan, Enas Mahmoud, Eric Schopf
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Patent number: 8979324Abstract: An optical device structure with a light outcoupling layer is provided. The optical device structure includes a substrate having a first surface and a second surface, and a layer of polyimide (PI) or its copolymer formed on the first surface of the substrate, wherein the layer of polyimide or its copolymer is prepared from at least one aromatic diamine and at least one cycloaliphatic dianhydride, and an optical component formed on the layer of polyimide or its copolymer.Type: GrantFiled: August 9, 2012Date of Patent: March 17, 2015Assignee: Industrial Technology Research InstituteInventors: Yueh-Chuan Huang, Chyi-Ming Leu, Meng-Ting Hsieh
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Patent number: 8975365Abstract: A cage 1,2,3,4-cyclopentanetetracarboxylic acid (1,3:2,4)-dianhydride compound represented by formula [1], and a polyimide obtained by condensing the compound with a diamine. With the compound, it is possible to provide a polyimide which shows no absorption in the ultraviolet region and is highly transparent to light, has high insulating properties, has improved heat resistance and processability, and has excellent solubility in organic solvents. (In formula [1], R1 and R2 each independently represents a hydrogen atom, a halogen atom, or a C1-10 alkyl.Type: GrantFiled: December 31, 2013Date of Patent: March 10, 2015Assignee: Nissan Chemical Industries, Ltd.Inventors: Hideo Suzuki, Takahiro Noda
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Patent number: 8969486Abstract: Disclosed are a liquid crystal alignment agent, a liquid crystal alignment film manufactured using the same, and a liquid crystal display including the liquid crystal alignment film. The liquid crystal alignment agent includes a polymer comprising a polyamic acid including a repeating unit represented by Chemical Formula 1, polyimide including a repeating unit represented by Chemical Formula 2, or a combination thereof: wherein Y1 and Y2 are each independently a divalent organic group derived from diamine, wherein the diamine includes photodiamine represented by Chemical Formula 3 and functional diamine represented by Chemical Formula 5: and wherein the other substituents are the same as defined in the detailed description.Type: GrantFiled: August 22, 2012Date of Patent: March 3, 2015Assignee: Cheil Industries Inc.Inventors: Jae-Deuk Yang, Yong-Sik Yoo, Guk-Pyo Jo
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Patent number: 8962790Abstract: A process includes the steps of: casting or coating a polyamic acid organic solvent solution on a support and drying the polyamic acid organic solvent solution thereon, so as to form a partially cured and/or partially dried polyamic acid film; dipping the polyamic acid film in tertiary amine or a solution of tertiary amine, or coating tertiary amine or a solution of tertiary amine on the polyamic acid film; and drying the film while imidizing the polyamic acid. In another process, a chemical converting agent and a catalyst are mixed in an organic solvent solution of polyamic acid. After casting and heating the mixture on a support, a partially cured and/or partially dried polyamic acid film is detached from the support. The film contains, with respect to the remaining volatile component, not less than 50 parts of catalyst, not more than 30 parts of solvent, and not more than 20 parts of chemical converting agent and/or a chemical converting agent derived component.Type: GrantFiled: February 13, 2007Date of Patent: February 24, 2015Assignee: Kaneka CorporationInventors: Hisayasu Kaneshiro, Toshihisa Itoh, Katsunori Yabuta, Kiyokazu Akahori
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Publication number: 20150051341Abstract: A thermosetting solution composition composed of a biphenyltetracarboxylic acid compound containing a partial lower aliphatic alkyl ester of 2,3,3?,4?-biphenyltetracarboxylic acid and/or a partial lower aliphatic alkyl ester of 2,2?,3,3?-biphenyltetracarboylic acid, an aromatic diamine compound in a molar amount larger than a molar amount of the biphenyltetracarboxylic acid compound, a partial lower aliphatic alkyl ester of 4-(2-phenylethynyl)phthalic acid compound in a molar amount as much as 1.8-2.2 times a molar amount corresponding to a difference between the molar amount of the aromatic diamine compound and the molar amount of the biphenyltetracarboxylic acid compound, and an organic solvent composed of a lower aliphatic alcohol is of value for manufacture of a prepreg.Type: ApplicationFiled: March 14, 2013Publication date: February 19, 2015Inventors: Norio Miura, Hiroaki Yamaguchi, Hideki Ozawa, Mitsushi Taguchi
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Publication number: 20150045501Abstract: The present invention relates to semiaromatic semicrystalline thermoplastic copolyimides obtained by polymerization of at least: (a) an aromatic compound comprising two anhydride functions and/or carboxylic acid and/or ester derivatives thereof; (b) a diamine of formula (I) NH2-R—NH2 in which R is a divalent aliphatic hydrocarbon-based radical optionally comprising heteroatoms, the two amine functions being separated by a number X of carbon atoms, X being between 4 and 12; and (c) a diamine of formula (II) NH2-R?—NH2 in which R? is a divalent aliphatic hydrocarbon-based radical optionally comprising heteroatoms, the two amine functions being separated by a number Y of carbon atoms, Y being between 10 and 20; it being understood that diamine (b) is different from diamine (c).Type: ApplicationFiled: September 18, 2012Publication date: February 12, 2015Inventor: Stéphane Jeol
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Patent number: 8927678Abstract: A thermoplastic polyimide resin containing a repeating structural unit represented by the following formula (1) and a repeating structural unit represented by the following formula (2), a content ratio of the repeating structural unit of formula (2) with respect to the total of the repeating structural unit of formula (1) and the repeating structural unit of formula (2) being from 40 to 70% by mol: wherein R1 represents a divalent group having from 6 to 22 carbon atoms containing at least one alicyclic hydrocarbon structure; R2 represents a divalent chain aliphatic group having from 5 to 12 carbon atoms; and X1 and X2 each independently represent a tetravalent group having from 6 to 22 carbon atoms containing at least one aromatic ring.Type: GrantFiled: February 5, 2013Date of Patent: January 6, 2015Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Yuuki Sato, Jun Mitadera
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Publication number: 20140378645Abstract: A problem of the present invention is to provide a liquid crystal aligning agent which never deteriorates even in a method where UV is irradiated such as a liquid crystal dropping method or the like, and is capable of forming a liquid crystal alignment film having high UV resistance.Type: ApplicationFiled: January 7, 2013Publication date: December 25, 2014Inventors: Atsushi Kozaki, Michihiko Sato
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Patent number: 8901274Abstract: Polyimide oligomers of the general formula: M-(Z—Y—X—Y—Z)n-M wherein n is an integer of 1 to 20; X comprises an aromatic diamine containing 2-4 aryl moieties, each of which contains 0-4 substituents; Z is independently the same as X or is a different aromatic diamine containing 1-4 aryl moieties, each of which contains 0-4 substituents; Y comprises an aromatic dianhydride containing 1-4 aryl moieties, each of which contains 0-4 substituents; and M is independently the same as Y or is a substituted or unsubstituted anhydride, a substituted or unsubstituted dianhydride, a substituted or unsubstituted bisimide, or a substituted or unsubstituted monomeric or oligomeric phthalonitrile.Type: GrantFiled: August 24, 2012Date of Patent: December 2, 2014Assignee: Lonza Group, Ltd.Inventors: Sajal Das, Vilas M. Chopdekar, Megan B. Casey
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Publication number: 20140343223Abstract: This disclosure relates to a process of purifying a polymer. The process includes (a) providing an organic solution containing a polyimide or polyamic ester in at least one polar, aprotic polymerization solvent; (b) adding at least one purification solvent to the organic solution to form a diluted organic solution, the at least one purification solvent is less polar than the at least one polymerization solvent and has a lower water solubility than the at least one polymerization solvent at 25° C.; (c) washing the diluted organic solution with water or an aqueous solution to obtain a washed organic solution; and (d) removing at least a portion of the at least one purification solvent in the washed organic solution to obtain a solution containing a purified polyimide or polyamic ester. This disclosure also relates to a process of preparing a film on a semiconductor substrate, as well as related purified polymer solutions, films, and articles.Type: ApplicationFiled: May 19, 2014Publication date: November 20, 2014Applicant: Fujifilm Electronic Materials U.S.A., Inc.Inventors: William A. Reinerth, Sanjay Malik, Binod B. De
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Publication number: 20140336353Abstract: Disclosed are salt compositions of lysinol and dicarboxylic acids; and lysinol derived polymers including polyamide, polyimide, polyurea, cross-linked polyurea comprising urethane linkages, polyurea foams, cross-linked polyurea foams, and lysinol-epoxy thermoset.Type: ApplicationFiled: July 22, 2014Publication date: November 13, 2014Inventors: KENNETH GENE MOLOY, MARK A. SCIALDONE, MANXUE WANG