From Reactant Having At Least One -n=c=x Group (wherein X Is A Chalcogen Atom) As Well As Precursors Thereof, E.g., Blocked Isocyanate, Etc. Patents (Class 528/44)
  • Patent number: 8153751
    Abstract: Disclosed is a multifunctional urethane monomer prepared by reacting (a) an epoxy compound having two or more epoxy groups, (b) a diol compound having an acidic group and (c) a compound having an ethylenically unsaturated group and an isocyanate group with one another. The photosensitive resin composition comprising the multifunctional urethane monomer has low viscosity, superior sensitivity, excellent chemical resistance and heat-resistance and high development margin.
    Type: Grant
    Filed: June 30, 2009
    Date of Patent: April 10, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Yoon Hee Heo, Min Young Lim, Ho Chan Ji, Sung-Hyun Kim, Han Soo Kim, Sun Hwa Kim
  • Patent number: 8148460
    Abstract: A liquid rheological aid comprising at least one urea derivative preparable which is the reaction product of at least one compound having at least one isocyanate group and at least one co-reactant selected horn primary and secondary monoamines and polyamines and water reacted in the presence of organobismuth catalyst, process for the preparation thereof and its use.
    Type: Grant
    Filed: September 21, 2004
    Date of Patent: April 3, 2012
    Assignee: BASF Coatings GmbH
    Inventors: Christina Alpert, Heinz-Peter Rink
  • Publication number: 20120077932
    Abstract: The invention relates to compositions based on 2,5-diisocyanato-1,4:3,6-dianhydro-2,5-dideoxy-D-manitol (I), 2,5-diisocyanato-1,4:3,6-dianhydro-2,5-dideoxy-D-glucitol (II), and/or 2,5-diisocyanato-1,4:3,6-dianhydro-2,5-dideoxy-L-iditol (III), alone or in any mixtures.
    Type: Application
    Filed: April 23, 2010
    Publication date: March 29, 2012
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Jan Pfeffer, Martina Ortelt, Emmanouil Spyrou, Thomas Haas, Uwe Korek, Harald Schmidt, Uwe Dingerdissen
  • Patent number: 8143325
    Abstract: Absorbable polyurethanes, polyamides and polyester urethanes prepared from at least one compound selected from: or the diamines and diisocyanates thereof, wherein each X represents a member independently selected from —CH2COO— (glycolic acid moiety), —CH(CH3)COO— (lactic acid moiety), —CH2CH2OCH2COO— (dioxanone), —CH2CH2CH2CH2CH2COO— (caprolactone moiety), —(CH2)yCOO— where y is one of the numbers 2, 3, 4 or 6-24 inclusive, and —(CH2CH2O)z?CH2COO— where z? is an integer between 2 and 24, inclusive; each Y represents a member independently selected from —COCH2O— (glycolic ester moiety), —COCH(CH3)O— (lactic ester moiety), —COCH2OCH2CH2O— (dioxanone ester), —COCH2CH2CH2CH2CH2O— (caprolactone ester), —CO(CH2)mO— where m is an integer between 2, 3, 4 or 6-24 inclusive, —COCH2O(CH2CH2O)n— where n is an integer between 2 and 24, inclusive; R? is hydrogen, benzyl or an alkyl group, the alkyl group being either straight-chained or branched; p is an integer between 1 and 4, inclusive; and Rn represents one or more
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: March 27, 2012
    Assignee: Bezwada Biomedical, LLC
    Inventor: Rao S. Bezwada
  • Patent number: 8143345
    Abstract: Fluorinated polyurethanes and methods of making the same are provided. The fluorinated polyurethanes are useful for making polyurethane coating compositions for use in aerospace and other applications. The method includes a “split process” by which a hydroxypolyalkylenoxy derivative of a perfluoropolyoxyalkane is separately reacted with isocyanate to produce an isocyanate-terminated compound. The isocyanate-terminated compound is then reacted with an emulsifier to produce an acid- and hydroxyl-functional compound. The acid- and hydroxyl-functional compound is then reacted with isocyanate to form an acid-functional, isocyanate-terminated compound. The acid-functional, isocyanate-terminated compound is then reacted with at least one polyol to produce a higher molecular weight, acid- and hydroxyl-functional compound. Finally, the acid functional groups of the high molecular weight, acid- and hydroxyl-functional compound are neutralized to form a fluoro-urethane salt which is dispersed in water.
    Type: Grant
    Filed: December 8, 2008
    Date of Patent: March 27, 2012
    Assignee: PRC DeSoto International, Inc.
    Inventor: Razmik Boghossian
  • Patent number: 8138299
    Abstract: Thermoplastic polyurethanes which have a hardness of from 50 Shore A to 80 Shore A and are based on (b) polyester diols, wherein a polyester diol (b1) based on butane-1,4-diol and at least one further diol having at least 5 carbon atoms and a polyester diol (b2) based on butane-1,4-diol and at least one further diol having two or three carbon atoms are present as (b) polyester diols.
    Type: Grant
    Filed: April 25, 2006
    Date of Patent: March 20, 2012
    Assignee: BASF Aktiengesellschaft
    Inventors: Jörn Duwenhorst, Hauke Malz, Karin Scheffer, Thomas Flug, Martin Vallo
  • Patent number: 8137754
    Abstract: Thiocarbonate compounds are reacted with various polyols to introduce hydroxyl end groups thereto which can be subsequently reacted with urethane forming compounds to form various polyurethanes including block copolymers thereof.
    Type: Grant
    Filed: July 19, 2005
    Date of Patent: March 20, 2012
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventors: John Ta-Yuan Lai, Anthony D. Pajerski, Ronald P. Shea
  • Patent number: 8133964
    Abstract: The coating described herein attempts to provide this solution by synthesizing alkoxysilane-terminated N-substituted urea resins, then formulating them into moisture-curable single-component (1K) topside coatings. These coatings will provide greater external stability (to UV and visible radiation), cleanability, flexibility, cure times and lower VOC content than the currently qualified silicone alkyd topside coatings that are found on Navy ships. The single-component coating can include at least an alkoxysilane-terminated N-substituted urea resin, a reactive diluent, a pigment, a filler, and a catalyst. The resin can include an amino-functional silane substituted at the N-position and a non-aromatic isocyanate.
    Type: Grant
    Filed: June 29, 2010
    Date of Patent: March 13, 2012
    Assignee: Science Applications International Corporation
    Inventor: Erick B. Iezzi
  • Patent number: 8129445
    Abstract: The invention relates to a novel poly(ethylene oxide)imine; a novel amine reactive moiety; a novel moisture activated latent curing adhesive or sealant mixture comprising (1) a ketimine or aldimine, and (2) an amine reactive moiety; and a novel moisture activated latent curing adhesive or sealant comprising the reaction product of (1) and (2).
    Type: Grant
    Filed: August 9, 2006
    Date of Patent: March 6, 2012
    Assignee: Ethicon, Inc.
    Inventors: Joseph Zavatsky, Binoy K. Bordoloi
  • Patent number: 8119757
    Abstract: Urethane and siloxane modified water-reducible alkyd resins ABCDE, comprising moieties derived from polyhydric alcohols A, modified fatty acids B made by grafting olefinically unsaturated carboxylic acids B2 onto fatty acids B1, ungrafted fatty acids C, silanol or alkoxysilyl functional siloxane oligomers or polymers D, and polyfunctional isocyanates E, a process for their production, and a method of use thereof in coating binders.
    Type: Grant
    Filed: May 30, 2008
    Date of Patent: February 21, 2012
    Assignee: Cytec Surface Specialties Austria GmbH
    Inventors: Gerhard Reidlinger, Edmund Urbano, Ewald Zrin, Johannes Scherz
  • Patent number: 8114920
    Abstract: The UV-curable aqueous coating composition is characterized by using a UV-curable aqueous emulsion obtained by urethane reaction with a mixture including a poly-carbonate polyol or polyester polyol; an isocyanate compound; a urethane-reactive carboxylic acid; a UV-curable acrylic oligomer having 2 to 9 functional acrylate groups; a UV-curable acrylic monomer; and a urethane-reactive acrylate without an organic solvent. The aqueous composition provides good environmental acceptability and satisfactory film properties comparable to those of the prior oily UV-curable coating composition and, therefore, it is useful for coating various plastics.
    Type: Grant
    Filed: January 15, 2007
    Date of Patent: February 14, 2012
    Assignee: Akzo Nobel Coatings International B.V.
    Inventors: Dong Soo Kim, Tae Yun Jeong, Su Dong Hong, Jung Hyun Oh
  • Patent number: 8114988
    Abstract: The present invention provides a method for preparing a phosphorus-containing bexzoxazine resin having the following structure shown as the formula (I) or (V): wherein, R1˜R4 respectively comprise one selected from the group consisting of hydrogen, C1˜C6 alkyl, C3˜C6 cyclic alkyl, and phenyl.
    Type: Grant
    Filed: February 23, 2010
    Date of Patent: February 14, 2012
    Assignee: Chung-Shan Institute of Science and Technology, Armaments Bureau, Ministry of National Defense
    Inventors: Wen-Chiung Su, Ching-Hsuan Lin, Po-Wen Cheng
  • Patent number: 8110704
    Abstract: Stable NCO prepolymers are produced from polyisocyanates having a melting point greater than 70° C., preferably, naphthalene diisocyanate, having advantageous physical properties. An important feature of the process of the present invention is the rapid cooling of the prepolymer. The process of the present invention may be carried out on a continuous or batch basis. The prepolymers of the present invention are particularly suitable for the production of cast polyurethane elastomers.
    Type: Grant
    Filed: November 2, 2006
    Date of Patent: February 7, 2012
    Assignees: Bayer MaterialScience LLC, Bayer MaterialScince AG
    Inventors: James Michael Barnes, Hartmut Nefzger, Erika Bauer, Stefan Penninger, Thomas Schultz, Heinrich Lutz, Horst Di Mews, Charles S. Gracik
  • Patent number: 8106141
    Abstract: Reaction products prepared from reactants including: (a) at least one compound of structural Formula (I): wherein R1 is selected from aryl and heteroaryl; X is selected from a direct bond, —O—, —S—, —NH—, alkylene, cycloalkylene, heterocyclylene, arylene, alkarylene, and heteroarylene; Y is a substituted alkylene group having at least two contiguous carbon atoms and which can be interrupted by one or more —O—, —S—, or —NH— moieties as defined herein, wherein the alkylene group of Y has substituents independently selected from —OH, —NH2, —SH, cycloalkyl, heterocyclyl, aryl, and heteroaryl, or two hydrogen atoms on the same carbon atom of Y are replaced by carbonyl, and wherein at least two substituents of Y are each independently selected from —OH, —NH2, and —SH, as defined herein; and (b) at least one isocyanate functional material.
    Type: Grant
    Filed: May 7, 2008
    Date of Patent: January 31, 2012
    Assignee: Henkel Corporation
    Inventors: Anthony F. Jacobine, Andrew Messana, David M. Glaser, Steven Thomas Nakos
  • Patent number: 8101702
    Abstract: A silicone-containing composition comprises the reaction product of a first component and an excess of an isocyanate component relative to the first component to form an isocyanated intermediary. The first component is selected from one of a polysiloxane and a silicone resin. The first component includes a carbon-bonded functional group selected from one of a hydroxyl group and an amine group. The isocyanate component is reactive with the carbon-bonded functional group of the first component. The isocyanated intermediary includes a plurality of isocyanate functional groups. The silicone-containing composition comprises the further reaction product of a second component, which is selected from the other of the polysiloxane and the silicone resin. The second component includes a plurality of carbon-bonded functional groups reactive with the isocyanate functional groups of the isocyanated intermediary for preparing the silicone-containing composition.
    Type: Grant
    Filed: January 11, 2008
    Date of Patent: January 24, 2012
    Assignee: Dow Corning Corporation
    Inventor: Mustafa Mohamed
  • Patent number: 8097675
    Abstract: Isocyanate mixtures comprising: (a) NCO prepolymers having an NCO content of 1.5 to 18 wt. %; and (b) 1 to 40 wt. % of monomeric 2,2?-diisocyanatodiphenylmethane, based on the isocyanate mixture; wherein the isocyanate mixture has a total NCO content of from 2 to 22 wt. %; polyisocyanate polyaddition products prepared therefrom; and methods of making the same.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: January 17, 2012
    Assignees: Bayer MaterialScience AG, Polytex Sportbelage Produktions GmbH
    Inventors: Zdenka Finder, Jens Krause, Friedhelm Faehling, Manfred Schmidt, Dirk Wegener
  • Publication number: 20120000251
    Abstract: A method for making items of clothing having shape memory, the method comprising: synthesizing (31) a shape memory polyurethane; subjecting (34) the shape memory polyurethane to wet spinning, dry spinning, melt spinning or multi-component spinning in order to produce shape memory fibers; and knitting or weaving (36) the shape memory fibers to form the item of clothing.
    Type: Application
    Filed: June 30, 2010
    Publication date: January 5, 2012
    Applicant: The Hong Kong Polytechnic University
    Inventors: Jinlian HU, Jianping Han, Jing Lu, Qinghao Meng, Yong Zhu, Yan Liu, Qunmin Ling, Fenglong Ji
  • Patent number: 8082616
    Abstract: There is provided a shoe bottom repair agent consisting of one-component thermosetting composition comprising as main ingredients a terminal isocyanate having urethane prepolymer and/or a polyisocyanate compound and a latent curing agent. This shoe bottom repair agent is free from, experienced in use of solvent base shoe bottom repair agents, safety and sanitation problems such as odor and inflammation by solvent evaporated at the time of curing as well as cured matter thickness reduction of a mended part caused by solvent evaporation. With use of this shoe bottom repair agent, damaged shoe bottom portion can be mended to a desired shape through one-time repair work. Short-time curing can be effected by heating. Further, before heating, there is substantially no viscosity increase and no surface film is formed to avoid adhesion of a film resulting from surface drying to a spatula. Therefore, the repair surface can be finished smoothly and neatly.
    Type: Grant
    Filed: July 26, 2005
    Date of Patent: December 27, 2011
    Assignee: Sunstar Engineering Inc.
    Inventors: Norihiro Tameno, Tetsuya Fujino, Yoshimasu Tanaka, Shinji Ochi, Hidekuni Takano
  • Patent number: 8084566
    Abstract: Mixtures of silicone resin with an organopolysiloxane copolymer prepared by hydrosilylating a substantially linear polymer containing an isocyanate reactive group with an Si—H containing organopolysiloxane, and reacting this intermediate with a diisocyanate, are useful as long lasting defoamers which are compatible with numerous media.
    Type: Grant
    Filed: November 16, 2009
    Date of Patent: December 27, 2011
    Assignee: Wacker Chemie AG
    Inventors: Holger Rautschek, Elisabeth Brehm, Christian Herzig
  • Patent number: 8080626
    Abstract: This invention provides chain extender compositions. These compositions comprise (i) an aromatic primary diamine, and (ii) a component selected from the group consisting of: (a) an aliphatic secondary diamine; (b) an aliphatic primary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) a diimine; and (e) a combination of any two or more of (a) through (d). When (ii) is (a), (a) has amino hydrocarbyl groups which are secondary or tertiary hydrocarbyl groups; when (ii) is (d), and (d) is an aromatic diimine, each imino hydrocarbylidene group has at least two carbon atoms. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.
    Type: Grant
    Filed: February 16, 2011
    Date of Patent: December 20, 2011
    Assignee: Albemarle Corporation
    Inventors: Paul L. Wiggins, John Y. Lee, Judit Orgad
  • Patent number: 8080609
    Abstract: The invention is a composition comprising a) one or more prepolymers having on average three or more aliphatic isocyanate groups and further containing alkoxysilane groups; b) one or more aromatic polyisocyanates; c) one or more compounds having at least one heterocyclic ring which hydrolyzes when exposed to moisture to form at least one isocyanate reactive group; d) one or more solvents; and e) one or more amine and/or organometallic polyurethane catalysts; wherein the ratio of aromatic isocyanate groups to aliphatic isocyanate groups in the composition is from about 0.5:1.0 to about 1.5:1.0, preferably about 0.9:1.0 to about 1.5:1.0, and the equivalent ratio of isocyanate groups to isocyanate reactive groups derivable from the one or more compounds having at least one hydrolyzable heterocylic ring is from about 0.8:1.0 to about 5.3:1.0, and most preferably about 1.5:1.0 to about 1.7:1.0.
    Type: Grant
    Filed: October 29, 2009
    Date of Patent: December 20, 2011
    Assignee: Dow Global Technologies LLC
    Inventor: Stefan Schmatloch
  • Patent number: 8076381
    Abstract: The object is to provide a molded product of foamed particles obtained by charging biodegradable resin foamed particles which are of vegetable origin and excellent in environmental compatibility into a mold, followed by heat molding, which molded product is not accompanied by post shrinkage after the molding with a wide range of variation of processing in the molding. Further, P3HA resin foamed particles being composed of a resin composition that comprises an isocyanate compound, and a polymer, poly(3-hydroxyalkanoate), having a recurring unit represented by the general formula (1): [—O—CHR—CH2—CO—]??(1) (wherein R represents an alkyl group represented by CnH2n+1, wherein n is an integer of from 1 to 15) produced by a microorganism are provided.
    Type: Grant
    Filed: April 10, 2006
    Date of Patent: December 13, 2011
    Assignees: Kaneka Corporation, Meredian, Inc.
    Inventors: Toshio Miyagawa, Fuminobu Hirose, Kenichi Senda
  • Patent number: 8076518
    Abstract: This invention provides chain extender compositions. These compositions comprise (i) an aliphatic secondary diamine, and (ii) a component selected from the group consisting of: (a) a cycloaliphatic primary diamine; (b) an aliphatic secondary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) an aliphatic diimine; and (e) a combination of any two or more of (a) through (d), with the proviso that when (ii) is (a), (i) is a noncyclic aliphatic secondary diamine. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.
    Type: Grant
    Filed: September 25, 2006
    Date of Patent: December 13, 2011
    Assignee: Albemarle Corporation
    Inventors: Paul L. Wiggins, John Y. Lee, Judit Orgad, David W. Owens
  • Patent number: 8076445
    Abstract: A composition comprising a carbodiimide and a polymer, wherein the carbodiimide comprises a reaction product of a) at least one of an aliphatic C4 to C20 polyisocyanate and an araliphatic C4 to C20 polyisocyanate, b) at least one of a hydroxy carboxylic acid and a hydroxy carboxylic salt, c) optionally, a further compound carrying groups able to react with isocyanate groups in an addition reaction, d) optionally, at least one other isocyanate, and the carbodiimide units being derived essentially exclusively from the isocyanate groups of component a), and the polymer comprises a reaction product of an ethylenically unsaturated carboxylic acid and at least one of a (meth)acrylate, a vinyl ester of a carboxylic acid, a vinyl aromatic compound, an ethylenically unsaturated nitrile, a vinyl halide, an aliphatic hydrocarbon, and a free-radically polymerizable monomer. Also, a method of applying the composition on and/or in a substrate.
    Type: Grant
    Filed: February 21, 2003
    Date of Patent: December 13, 2011
    Inventors: Robert Shane Porzio, Karl Häberle, Jacob Wildeson, Martin Jung, Norbert Willenbacher, Lars Börger
  • Patent number: 8071663
    Abstract: The present invention is directed to a medically acceptable formulation comprising a diisocyanate terminated macromer or mixture thereof, and bio-absorbable desiccant comprising a hygroscopic and/or hydrophilic or combination thereof. The present invention is also directed to methods of use for such formulations for medical procedures.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: December 6, 2011
    Assignee: Ethicon, Inc.
    Inventors: Benjamin D. Fitz, Elizabeth Vailhe, Joseph Zavatsky, Christopher M. Westergom
  • Patent number: 8067522
    Abstract: The present invention relates to a process for preparing alkoxysilane-functional prepolymers by reacting A) 1.0 equivalent of a polyol component have a number average molecular weight of 3000 g/mol to 20,000 g/mol and containing one or more polyoxyalkylene polyols or polyoxyalkylene polyol prepolymers with B) 1.05 to 1.50 equivalent of an isocyanate- and alkoxysilane-functional compound of formula I) wherein X, Y, and Z independently of one another are linear or branched C1-C8 alkyl or C1-C8 alkoxy radicals, wherein at least one of the radicals is a C1-C8 alkoxy group and R is an organic radical having a functionality of at least two, and subsequently further reacting the remaining free NCO groups by allophanatization or by reaction with C) an isocyanate-reactive component. The present invention also relates to the alkoxysilane-functional prepolymers obtained by the process of the invention.
    Type: Grant
    Filed: August 30, 2006
    Date of Patent: November 29, 2011
    Assignee: Bayer MaterialScience AG
    Inventors: Michael Ludewig, Mathias Matner, Frank Kobelka
  • Patent number: 8062709
    Abstract: A process for preparing polyurethane carpet backings uses a filled polyurethane-forming composition that contains a mixture of certain metal acetylacetonate and sulfur-containing organotin catalysts. The mixture of catalysts is particularly beneficial in instances where the composition is processed at temperatures of above 30 to about 500 C, as long pot life is provided together with a rapid thermally-induced cure.
    Type: Grant
    Filed: March 19, 2007
    Date of Patent: November 22, 2011
    Assignee: Dow Global Technologies LLC
    Inventor: Randall C. Jenkines
  • Patent number: 8058343
    Abstract: Novel aqueous polyurethane dispersions and adhesive films formed therefrom are provided. The aqueous polyurethane dispersions are provided in solvent-free systems of a prepolymer comprising at least one polyether or polyester polyol, a mixture of MDI isomers, and a diol. The adhesive films from such dispersions can be heat-activated for bonding, lamination, and adhesion of textile fabrics, including stretch fabrics.
    Type: Grant
    Filed: May 14, 2007
    Date of Patent: November 15, 2011
    Assignee: Invista North America S.àr.l.
    Inventors: Hong Liu, Carmen A Covelli, Douglas K Farmer
  • Publication number: 20110274903
    Abstract: Embodiments of the invention may include one or more high-density textile fibers with a density from about 1 to about 11 g/mL. Some embodiments may include fabrics and/or garments made from such fibers. Embodiments comprising garments can include, for instance, exercise aids for providing extra mass to the wearer. Other embodiments can comprise, without limitation, building materials, safety equipment, armor, body armor, protective apparel, marine repair materials, marine protective devices, boat hulls, vehicle chassis, or blast-resistant materials.
    Type: Application
    Filed: May 7, 2011
    Publication date: November 10, 2011
    Inventors: Charlene Stuart, Patricia Dorton
  • Patent number: 8053488
    Abstract: An ambient temperature curable hydrophilic PU oligomer includes a PU pre-polymer having a hydrophilic center group and a curable terminated group. The ambient temperature curable hydrophilic PU oligomer includes the moisture-curable hydrophilic PU oligomer such as isocyanate-terminated PU pre-polymer and free-radical curable hydrophlic PU oligomer. The isocyanate-terminated PU pre-polymer is synthesized by mixing at least one multi-isocyanate, at least one polyol and one or more diol monomer with hydrophilic group. The acrylate-terminated PU oligomer is synthesized by adding 2-hydroxyethyl methacrylate (HEMA) into the isocyanate-terminated hydrophilic PU pre-polymer. Either acrylate- or isocyanate-terminated PU oligomer can be applied on a textile or a glass surface with a thin-layer coating technology. The curing reactions of these hydrophilic thin-layer coatings are carried out with moisture or UV-radiation, respectively, at ambient temperature.
    Type: Grant
    Filed: January 4, 2008
    Date of Patent: November 8, 2011
    Assignee: Tamkang University
    Inventors: Jing-Zhong Hwang, Shih-Chieh Wang, Po-Cheng Chen, Kan-Nan Chen
  • Patent number: 8053484
    Abstract: A polyurethane foam composition includes a polyol, a polyisocyanate, a catalyst, a foam stabilizer, a blowing agent and a fluorinated carbonate wherein the fluorinated carbonate is a compound represented by Formula 1: a compound represented by Formula 2: or a mixture thereof. Also disclosed is a polyurethane foam derived from the composition.
    Type: Grant
    Filed: August 24, 2009
    Date of Patent: November 8, 2011
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Sung Woo Hwang, Myung Dong Cho, Sang Ho Park, Kwang Hee Kim
  • Publication number: 20110265797
    Abstract: The present disclosure describes systems and methods that utilize an extendable tracheal tube system. The extendable tracheal tube system includes an extendable tracheal tube having a distal end portion and a proximal end portion. The proximal end portion and the distal end portion of the extendable tracheal tube are capable of moving axially relative to each other. An obturator is also provided that is capable of aiding in the intubation and/or extubation of the extendable tracheal tube. The use of the extendable tracheal tube system and methods enables the secure attachment of the extendable tracheal tube to a patient airway while allowing for certain movements of the patient, such as neck and head movements.
    Type: Application
    Filed: April 30, 2010
    Publication date: November 3, 2011
    Applicant: Nellcor Puritan Bennett LLC
    Inventor: Paul Waldron
  • Patent number: 8048979
    Abstract: The present invention involves the design of a radiation curable organic pre polymer resin material based on urethane acrylic linkage synthesized from the natural renewable resource cardanol or a derivative thereof, for coating application. These new molecules have a faster and better curing rate compared to the starting renewable resource—cardanol. This is brought about by the hydrogen bonding of the urethane linkage which leads to a pre organization of the molecules in such a way as to bring the cross linkable double bonds closer to each other. The present invention also involves a UV curable formulation of the above mentioned resins along with 2-10 parts by weight of a photopolymerization initiator. The resin, either in a formulation or alone turns into a cross linked film upon photopolymerization in presence of photoinitiator under a UV curable radiation source like a mercury vapor pressure lamp.
    Type: Grant
    Filed: December 30, 2005
    Date of Patent: November 1, 2011
    Assignee: Council of Scientific and Industrial Research
    Inventors: Asha Syamakumari, Chennakkattu Krishna Sadasivan Pillai
  • Patent number: 8048954
    Abstract: The present invention relates to aqueous non-ionically hydrophilised binding-agent dispersions based on polyurethane ureas with terminal polyethylene-oxide groups, to the preparation thereof, and to the use thereof for producing coatings.
    Type: Grant
    Filed: November 12, 2008
    Date of Patent: November 1, 2011
    Assignee: Bayer MaterialScience AG
    Inventors: Hans Georg Grablowitz, Thorsten Rische, Thomas Feller, Juergen Meixner, Karin Naujoks, Holger Casselmann
  • Patent number: 8048953
    Abstract: A polymer having at least one urea linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, having isocyanate groups, and (b) at least one fluorinated compound selected from the formula (I): Rf(CH2CF2)p(CH2CH2)q(R1)r—XH??Formula (I) wherein p and q are each independently an integer of 1 to 3; r is 0 or 1; X is —O—, —NH— or —S—; R1 is a divalent radical selected from the group consisting of —S(CH2)n—, n is an integer of 2 to 4; s is an integer of 1 to 50; R2, R3, and R4 are each independently hydrogen or an alkyl group containing 1 to 6 carbon atoms; and Rf is a linear or branched chain perfluoroalkyl group having 1 to 6 carbon atoms; and (ii) reacting with (c) water, a linking agent, or a mixture thereof and methods for treating substrates to obtain surface effects is disclosed.
    Type: Grant
    Filed: November 13, 2006
    Date of Patent: November 1, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Sheng Peng, Stephen James Getty, Timothy Edward Hopkins, Ying Wang
  • Patent number: 8044163
    Abstract: An aqueous polyurethane resin is obtained by allowing at least a polyol compound, an active hydrogen group-containing compound having anionic group, an active hydrogen group-containing acrylate compound and an alkoxysilyl group-containing polyamine compound to react with a polyisocyanate compound.
    Type: Grant
    Filed: June 21, 2007
    Date of Patent: October 25, 2011
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Takashi Uchida, Mitsuhiro Nishimura
  • Patent number: 8022200
    Abstract: The invention relates to a process for the preparation of liquid, storage-stable isocyanate mixtures which are characterized by a low color number and which contain carbodiimide (CD) and/or uretonimine (UI) groups. This invention also relates to the isocyanate mixtures obtained by this process, to their use for the preparation of blends with further isocyanates, and to the preparation of prepolymers containing isocyanate groups and of polyurethane plastics, preferably polyurethane foams from these isocyanate mixtures.
    Type: Grant
    Filed: July 1, 2005
    Date of Patent: September 20, 2011
    Assignee: Bayer MaterialScience AG
    Inventors: Stefan Wershofen, Manfred Schmidt, Hans-Georg Pirkl, Nobuhiro Kamiyama, Shinichi Murakami, Tetsuo Harada
  • Patent number: 8022138
    Abstract: Aqueous polyurethane dispersion are disclosed where the dispersions contain from 5 to 70 weight percent polyurethane solids wherein the solids are obtained from at least one isocyanate terminated prepolymer prepared by reacting (a) a polyol or polyol blend having a mean average equivalent weight of 200 to 2,000; and (b) at least one polyisocyanate where the prepolymer is dispersed in water; optionally in the presence of (c) one or more stabilizers; or (d) one or more amine chain extenders or both; wherein the prepolymers have an isocyanate (NCO) content of from 2 to 40 weight percent and the polyol or polyol blend (a) contains at least 15 weight percent of a polyester based on a polycarboxylic acid or lactone component and a glycol component, wherein the glycol component contains isomers of 1,3- and 1,4-cyclohexanedimethanol (1,3-/1,4-CHDM) where the ratio of the 1,3-/1,4-isomers is from 35:65 to 65:35.
    Type: Grant
    Filed: May 17, 2007
    Date of Patent: September 20, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: John N. Argyropoulos, Debkumar Bhattacharjee
  • Publication number: 20110224395
    Abstract: The present invention relates to a process for manufacturing isocyanates from an amine compound. The process comprises the steps of a) Providing chlorine; b) Providing carbon monoxide; c) Reacting said chlorine and said carbon monoxide for providing phosgene, the carbon monoxide being provided in an adjustable molar excess; d) Providing an amine compound and phosgenating said amine compound using said phosgene thereby providing said isocyanate; the process further comprises adjusting said adjustable molar excess, i.e. the molar excess of carbon monoxide, for adjusting the colour of the isocyanate.
    Type: Application
    Filed: November 5, 2009
    Publication date: September 15, 2011
    Applicant: Huntsman International LLC
    Inventors: Robert Henry Carr, Johannes Lodewijk Koole, Udo Brian Dave Mike Rodger Bruinsma
  • Patent number: 8017686
    Abstract: The invention relates to a polyurethane dispersant resin having a polyurethane backbone having pendant hydrophilic polyalkylene oxide based side groups, the pendant side groups being linked to the polyurethane backbone via covalent bonds, and wherein the content of polyalkylene oxide in the polyurethane dispersant resin is at least 45% by weight, characterized in that the polyurethane additionally has pendant hydrophobic side groups which are linked to the polyurethane backbone via covalent bonds.
    Type: Grant
    Filed: August 21, 2006
    Date of Patent: September 13, 2011
    Assignee: Akzo Nobel Coating International B.V.
    Inventors: Roelof Buter, Josephina Johanna Hendrika Maria Raben-Schlief, Hendrik Meijer, Geertje Marte Kuiken, Rienk Hettema, Jamie MacLiver Roy, Bart Bouma
  • Patent number: 8012588
    Abstract: A laminated product has a multilayer structure comprising an optical base and a cured polyurethane resin layer formed thereon from a moisture-curable polyurethane resin and/or a precursor therefor. The polyurethane resin layer is formed by applying a coating fluid comprising a moisture-curable polyurethane resin and/or precursor therefor and a solvent having a boiling point of 70° C. or higher and a solubility parameter of 8 or larger. Also provided is a coating material comprising a radical-polymerizable monomer ingredient, a silicone or fluorochemical surfactant, and a photochromic compound. In producing a photochromic optical article, excellent adhesion between a base and a photochromic layer is attained.
    Type: Grant
    Filed: February 13, 2004
    Date of Patent: September 6, 2011
    Assignee: Tokuyama Corporation
    Inventors: Shinobu Izumi, Junji Momoda
  • Patent number: 8008422
    Abstract: In general, the invention provides curable resin compositions that may be used to rebuild insulation and/or to provide environmental protection for cable splices, potted articles, and the like. The curable resin compositions can be curable at room temperature. The components used to form and cure the resin compositions may be provided in two or more parts. In specific embodiments, the invention provides curable resin compositions having anhydride, polyol, epoxy, and urethane components.
    Type: Grant
    Filed: July 11, 2008
    Date of Patent: August 30, 2011
    Assignee: 3M Innovative Properties Company
    Inventor: Jeanine I. Zeller-Pendrey
  • Patent number: 8003744
    Abstract: The present invention provides a curable composition including: an organic polymer (A) which has on average 1.1 to 50 groups per one molecule thereof each represented by the general formula (1) and has one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds: —NR1—C(?O)—??(1) wherein R1 is a hydrogen atom, or a substituted or unsubstituted monovalent organic group; and a metal carboxylate and/or a carboxylic acid (B), the curable composition giving a cured article excellent in curability and also excellent in heat resistance although a non-organotin catalyst is used.
    Type: Grant
    Filed: August 12, 2004
    Date of Patent: August 23, 2011
    Assignee: Kaneka Corporation
    Inventors: Toshihiko Okamoto, Katsuyu Wakabayashi
  • Publication number: 20110190466
    Abstract: A polymerizable composition for polythiourethane optical materials comprising a compound represented by the general formula (1), M(L)n??(1) wherein, in the formula, M is Al, Fe, Cu, Zn, Zr or Bi; L is a dithiocarbamic acid group, a sulfonic acid group, a mono- or di-alkyl phosphoric acid ester group, a substituted acetylacetonato group or a halogen; and n is an integer of 1 to 5, one or two or more isocyanates selected from the group consisting of isocyanate compounds and isothiocyanate compounds, and one or two or more active hydrogen compounds each having a mercapto group. The compounds represented by the general formula (1) exhibit catalytic activity equal to or superior to that of organotin catalysts having been employed as catalysts for the production of polythiourethane optical materials from the past, and have high safety. Further, the thus obtained polythiourethane resins satisfactorily meet the property requirements for optical materials, in particular, excelling in weather resistance.
    Type: Application
    Filed: February 15, 2007
    Publication date: August 4, 2011
    Inventors: Hidetoshi Hayashi, Nobuo Kawato, Masanori Iwazumi, Mamoru Tanaka, Seiichi Kobayshi
  • Patent number: 7989074
    Abstract: A polymeric material may be prepared by reacting a mixture comprising an amino functional polyorganosiloxane, polyisocyanate, and polyol. The polyol may comprise a hydroxy-functional poly(meth)acrylate. The polymeric material may be used as a coating for a substrate and may inhibit fouling on a surface exposed to aquatic conditions.
    Type: Grant
    Filed: June 6, 2007
    Date of Patent: August 2, 2011
    Assignee: NDSU Research Foundation
    Inventors: Dean C. Webster, Robert J. Pieper, Abdullah Ekin
  • Patent number: 7976816
    Abstract: A method for functionalizing the wall of single-wall or multi-wall carbon nanotubes involves the use of acyl peroxides to generate carbon-centered free radicals. The method allows for the chemical attachment of a variety of functional groups to the wall or end cap of carbon nanotubes through covalent carbon bonds without destroying the wall or endcap structure of the nanotube. Carbon-centered radicals generated from acyl peroxides can have terminal functional groups that provide sites for further reaction with other compounds. Organic groups with terminal carboxylic acid functionality can be converted to an acyl chloride and further reacted with an amine to form an amide or with a diamine to form an amide with terminal amine. The reactive functional groups attached to the nanotubes provide improved solvent dispersibility and provide reaction sites for monomers for incorporation in polymer structures. The nanotubes can also be functionalized by generating free radicals from organic sulfoxides.
    Type: Grant
    Filed: May 12, 2010
    Date of Patent: July 12, 2011
    Assignee: William Marsh Rice University
    Inventors: Valery N. Khabashesku, Haiqing Peng, John L. Margrave, Mary Lou Margrave, legal representative, Wilbur Edward Billups, Yunming Ying
  • Patent number: 7968668
    Abstract: A novel macromer or mixture thereof is described herein, comprising benzoyl isocyanate terminal moieties and at least two residues of a water-soluble polymer having a molecular weight ranging from 80 to 10,000 adjacent to the carbonyl group of the benzoyl isocyanate moieties, thereby forming at least two ester linkages in the macromer or mixture thereof. A method for making a polyisocyanate macromer is also described herein.
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: June 28, 2011
    Assignee: Ethicon Inc.
    Inventors: Benjamin D. Fitz, Christopher M. Westergom
  • Patent number: 7964696
    Abstract: The present invention relates to chain extenders, processes for their preparation and their use in the preparation of biocompatible biodegradable polyurethanes and polyurethane ureas for biomedical applications such as stents, scaffolds for tissue engineering.
    Type: Grant
    Filed: September 20, 2006
    Date of Patent: June 21, 2011
    Assignee: Polynovo Biomaterials Pty Limited
    Inventors: Pathiraja Arachchillage Gunatillake, Timothy Graeme Moore, Raju Adhikari
  • Patent number: 7964279
    Abstract: Disclosed herein are a nanocrystal-polydimethylsiloxane composite and a method for preparing the same. More specifically, provided are a nanocrystal-polydimethylsiloxane composite in which one or more polydimethylsiloxane derivatives having urea cross-links are bound to the surface of a nanocrystal, and a method for preparing the same. The nanocrystal-polydimethylsiloxane composite comprises optically transparent polydimethylsiloxane with remarkably high durability, thus imparting improved luminescence efficiency and product reliability to various electronic devices, when applied as a luminescent material to the electronic devices.
    Type: Grant
    Filed: October 29, 2008
    Date of Patent: June 21, 2011
    Assignees: Samsung Electronics Co., Ltd., Pohang University of Science and Technology Academy-Industry Foundation
    Inventors: Sungjee Kim, JinSik Lee, Songjoo Oh
  • Patent number: 7964695
    Abstract: This invention provides chain extender compositions. These compositions comprise (i) an aromatic primary diamine, and (ii) a component selected from the group consisting of: (a) an aliphatic secondary diamine; (b) an aliphatic primary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) a diimine; and (e) a combination of any two or more of (a) through (d). When (ii) is (a), (a) has amino hydrocarbyl groups which are secondary or tertiary hydrocarbyl groups; when (ii) is (d), and (d) is an aromatic diimine, each imino hydrocarbylidene group has at least two carbon atoms. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.
    Type: Grant
    Filed: September 25, 2006
    Date of Patent: June 21, 2011
    Assignee: Albemarle Corporation
    Inventors: John Y. Lee, Paul L. Wiggins, Judit Orgad, Mahmood Sabahi, Vernon O. Brandt