With Pretreatment Process Patents (Class 536/37)
  • Patent number: 11718688
    Abstract: The hydroxyethyl cellulose derived from biomass is made by preparing a biomass by extracting resins and waxes, acid leaching, and alkali treatment to obtain a cellulose-rich residue, and then bleaching the cellulose-rich residue, followed by hydroxyethylation of the cellulose to obtain hydroxyethyl cellulose. The use of hydroxyethyl cellulose in brine treatment include reacting concentrated brine and hydroxyethyl cellulose with an effluent gas stream to capture CO2 and reduce salinity of the concentrated brine. The reduced salinity brine may then be useful for enhanced oil recovery methods.
    Type: Grant
    Filed: August 19, 2020
    Date of Patent: August 8, 2023
    Assignee: UNITED ARAB EMIRATES UNIVERSITY
    Inventors: Ameera Fares Mohammad, Ali H. Al-Marzouqi, Emmanuel Galiwango, Essa Georges Lwisa, Jawad Mustafa
  • Publication number: 20110230655
    Abstract: A process is disclosed for regenerating or derivatizing cellulose. The process comprises the steps of providing a source of unrefined cellulose, and dissolving the unrefined cellulose in a molten inorganic salt. The source of unrefined cellulose may be a biomass, such as wood. The process permits the regeneration or derivatization of cellulose having a high degree of polymerization.
    Type: Application
    Filed: February 18, 2011
    Publication date: September 22, 2011
    Inventors: Jacob A. MOULIJN, Sjoerd Daamen, Paul O'Connor, Rob Van Der Meij
  • Publication number: 20070203335
    Abstract: The present invention relates to a new process for preparing 6-carboxy-cellulose nitrates and also to their use.
    Type: Application
    Filed: January 26, 2007
    Publication date: August 30, 2007
    Applicant: Wolff Cellulosics GmbH & Co. KG
    Inventors: Carsten Huttermann, Thomas Wagner, Jorn-Bernd Pannek
  • Publication number: 20040072201
    Abstract: The invention provides screening methods for the identification of compounds that inhibit nonstop degradation of mRNA, including compounds that inhibit the exosome. The invention further provides methods of treatment for genetic disorders caused by premature termination codons.
    Type: Application
    Filed: April 16, 2003
    Publication date: April 15, 2004
    Inventors: Harry C. Dietz, Pamela A. Frischmeyer, Roy Robert Parker, Ambrosius Theodorus Cornelis Van Hoof
  • Patent number: 6646119
    Abstract: The starting pyroxylin is subjected to an acetylation reaction while it is dispersed in a dispersion medium such as toluene and kept in a solid phase state, and acetylated pyroxylin is then separated from a reaction solution by means of filtration, so that an extra portion of anhydrous acetic acid taking no part in the reaction can be immediately recovered. This dispenses with the precipitation process required for a prior art solution reaction, and so eliminates an unstable quality factor due to product particle size variations. In addition, the process of washing the post-reaction crude acetylated pyroxylin is designed to include a washing step at a high temperature of 60° C. to 105° C. and a washing step using a stabilizer-containing washing agent, so that acetylated pyroxylin having improved heat resistance and stability can be provided.
    Type: Grant
    Filed: October 4, 2000
    Date of Patent: November 11, 2003
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tokuji Tanaka, Kazuhiro Nishioka
  • Patent number: 6417345
    Abstract: The invention provides a method for producing acetylated pyroxylin with safety yet at low cost, using inexpensive water-wetted pyroxylin rather than expensive alcohol-wetted pyroxylin. The acetylated pyroxylin is produced by dehydrating the water-wetted pyroxylin in the presence of a nonalcoholic non-solvent for pyroxylin, and then permitting an acetylating agent to act on the dehydrated pyroxylin. According to the first dehydration process, the water-wetted pyroxylin is dispersed in a dispersing medium comprising a nonalcoholic non-solvent for pyroxylin, and then dehydrated by distillation. According to the second dehydration process, a replacing agent comprising a nonalcoholic non-solvent for pyroxylin is added to the water-wetted pyroxylin, and the wetted pyroxylin is then dehydrated by filtration. With either one of these processes, the water-wetted pyroxylin can be dehydrated with safety.
    Type: Grant
    Filed: October 8, 1999
    Date of Patent: July 9, 2002
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tokuji Tanaka, Noboru Kamei, Hideo Yabune
  • Patent number: 6417344
    Abstract: The starting pyroxylin is subjected to an acetylation reaction while it is dispersed in a dispersion medium such as toluene and kept in a solid phase state, and acetylated pyroxylin is then separated from a reaction solution by means of filtration, so that an extra portion of anhydrous acetic acid taking no part in the reaction can be immediately recovered. This dispenses with the precipitation process required for a prior art solution reaction, and so eliminates an unstable quality factor due to product particle size variations. In addition, the process of washing the post-reaction crude acetylated pyroxylin is designed to include a washing step at a high temperature of 60 to 105° C. and a washing step using a stabilizer-containing washing agent, so that acetylated pyroxylin having improved heat resistance and stability can be provided.
    Type: Grant
    Filed: July 9, 1999
    Date of Patent: July 9, 2002
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tokuji Tanaka, Kazuhiro Nishioka
  • Patent number: 6365732
    Abstract: The present invention includes a process for extracting a stereoisomer fro biomass. The method comprises providing biomass and subjecting the biomass to substantially instantaneous pressurization and depressurization to separate cellulose, hemicellulose, and lignin from the biomass. The hemicellulose is hydrolyzed to form hemicellulose hydrolysates. The hydrolysates are separated using chromatography.
    Type: Grant
    Filed: July 10, 2000
    Date of Patent: April 2, 2002
    Assignee: Sweet Beet Incorporated
    Inventor: Doug Van Thorre
  • Patent number: 6362330
    Abstract: The present invention relates to novel thermoplastic materials based on polysaccharide ethers which are simultaneously substituted by carboxylic acid ester groups and carbamate groups, together with mixtures of such derivatives with low molecular weight aliphatic urea derivatives.
    Type: Grant
    Filed: November 1, 1999
    Date of Patent: March 26, 2002
    Assignee: Wolff Wolsrode AG
    Inventors: Joachim Simon, Hanns-Peter Müller, Dirk Jacques Dijkstra, Gunter Weber
  • Patent number: 5792856
    Abstract: This invention provides certain carboxymethyl cellulose (CMC) esters of higher acids (e.g., CMC acetate propionate, CMC propionate, CMC acetate butyrate, and CMC butyrate). These new ether derivatives of cellulose esters exhibit solubility in a wide range of organic solvents, compatibility with a variety of resins, and ease of dispersion in a water-borne formulation and are useful in coating compositions as binder resins and rheology modifiers.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: August 11, 1998
    Inventors: John Michael Allen, Alan Kent Wilson, Paul Lee Lucas, Larry Gerald Curtis
  • Patent number: 4849514
    Abstract: This invention is an improved process of making azidodeoxycellulose a hig energetic ingredient for use in a propellant. The process is accomplished by nitrating cellulose to nitrocellulose, converting the nitrocellulose in sequence to the iodine derivative, and finally reacting the iodine derivative of cellulose with sodium azide to produce azidodeoxycellulose having up to about 1.5% residual nitrogen as nitrate groups.
    Type: Grant
    Filed: March 7, 1988
    Date of Patent: July 18, 1989
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventor: Everett E. Gilbert
  • Patent number: 4814439
    Abstract: An improved chemical process is provided for the disposal of scrap nitroculose. The process involves the use of organic sulfhydryl-containing compounds to effect the nitrogen release from the nitrocellulose polymer. The nitrogen released by the application of this procedure is in the form of inorganic nitrite ions. The process is in effect a nucleophilic attack on the nitrocellulose, and is accompanied by cleavage or breakage of the cellulose chain.
    Type: Grant
    Filed: August 17, 1987
    Date of Patent: March 21, 1989
    Assignee: The United States of America as repesented by the Secretary of the Army
    Inventors: Kenneth Gold, Bruce W. Brodman
  • Patent number: H430
    Abstract: A process of making azidodeoxycellulose nitrate in yields as high as 90 pent. The process initially involves the conversion of cellulose to the mesylate or tosylate derivative. This is followed by reacting the above cellulose derivative with a metallic azide to produce azidodeoxycellulose. Thereafter, the azidodeoxycellulose is nitrated thereby producing azidodeoxycellulose nitrate which is a propellant.
    Type: Grant
    Filed: March 2, 1987
    Date of Patent: February 2, 1988
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Yvon P. Carignan, Everett E. Gilbert