Phthalocyanines Patents (Class 540/122)
  • Patent number: 7291448
    Abstract: A photothermographic material having, on at least one side of a support, an image forming layer including at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, and at least one non-photosensitive layer, wherein the photothermographic material contains a water-insoluble azomethine dye and a metal phthalocyanine dye represented by formula (PC-1): wherein M represents a metal atom; R1, R2, R3, R4, R5, R6, R7, and R8 each independently represent a hydrogen atom or a substituent; and at least one of them is an electron-attracting group. The invention provides a photothermographic material which exhibits preferable image tone and excellent image storability.
    Type: Grant
    Filed: February 21, 2006
    Date of Patent: November 6, 2007
    Assignee: Fujifilm Corporation
    Inventors: Minoru Sakai, Yasuhiro Yoshioka
  • Patent number: 7255733
    Abstract: A process for the production of a ? type copper phthalocyanine pigment, comprising dry-milling a crude copper phthalocyanine having a purity of 97 to 100% and a primary crystal diameter of 0.5 to 100 ?m at a temperature of 180 to 50° C., to prepare an ?/? mixed crystal type copper phthalocyanine having an ? ratio of 5 to 35%, and treating the dry-milled product with a water-miscible organic solvent, wherein 0.1 to 20% by weight of at least one compound selected from the group consisting of a compound of the formula (1), a compound of the formula (2) and a compound of the formula (3) is added to the dry-milled product before, during or after the step (B) MePc—{X—(CH2)kNR1R2}n??(1) MePc—(SO3?N+R5R6R7R8)p.
    Type: Grant
    Filed: June 18, 2004
    Date of Patent: August 14, 2007
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventors: Osamu Shiromaru, Yusaku Ide, Toshio Oshiba, Takuya Kotani
  • Patent number: 7241319
    Abstract: Disclosed herein is a dye composition for dyeing human keratin fibers, such as the hair, comprising a direct polycationic dye of formula (I) below: Col-Z-Col??(I) in which Col, which may be identical or different, is a noncationic dye chosen from azo dyes, methine dyes, azomethine dyes, phenothiazine dyes, triarylmethene dyes, xanthene dyes, phenanthridine dyes, and phthalocyanin dyes; and Z is chosen from linear and branched, saturated and unsaturated C1-C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing at least two cationic charges, and also to processes for dyeing human keratin fiber using said composition, to the use of the dyes of formula (I) as direct dyes, and to multi-compartment devices.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: July 10, 2007
    Assignee: L'Oreal S.A.
    Inventor: Alain Lagrange
  • Patent number: 7199237
    Abstract: A flexible organic single crystal has a plurality of columns. The plurality of columns includes a plurality of planar organic compounds arranged so that molecular planes of molecules are respectively parallel to each other. As the organic compound, an organic compound is used that has a large molecular plane and a large area overlapping on an adjacent organic compound due to an intermolecular interaction. Further, energy changes in proportion to a strain. In this structure, when force along the direction of a stack axis is exerted, an angle formed by the stack axis and the normal of the molecular plane of the organic compound changes. Thus, the single crystal obtains flexibility.
    Type: Grant
    Filed: August 31, 2004
    Date of Patent: April 3, 2007
    Assignee: Sony Corporation
    Inventors: Hideo Yamakado, Toshiyuki Kunikiyo, Akito Ugawa
  • Patent number: 7186276
    Abstract: Disclosed herein is a dye composition for dyeing human keratin fibers, such as the hair, comprising a direct polycationic dye of formula (I) below: Col-Z-Col??(I) in which Col, which may be identical or different, is a monocationic dye chosen from azo dyes, methine dyes, azomethine dyes, and phenothiazine dyes; and Z is chosen from linear and branched, saturated and unsaturated C1–C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing at least two cationic charges, and also to processes for dyeing human keratin fibers using said composition, to the use of the dyes of formula (I) as direct dyes, and to multi-compartment devices.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: March 6, 2007
    Assignee: L'Oreal
    Inventor: Alain Lagrange
  • Patent number: 7179512
    Abstract: A liquid crystal display which has spacers reliably joined with a pair of substrates of the liquid crystal display by using spacers adapted to the purpose with respect to material, structure, method of joining with the substrates, etc. A pair of substrates can be reliably joined with spacers, and the strength of the liquid crystal display against an external pressure as well as display characteristics can be thereby improved. A manufacturing methods for such a liquid crystal display is also disclosed.
    Type: Grant
    Filed: May 13, 2003
    Date of Patent: February 20, 2007
    Assignee: Fujitsu Limited
    Inventors: Katsuji Ebisu, Takahiro Kashikawa
  • Patent number: 7169194
    Abstract: A dye composition for dyeing human keratin fibers, such as hair, comprising at least one direct tricationic dye of formula (I) below: Col—Z—Col ??(I) wherein: Col, which may be identical or different, is a monocationic dye chosen from azo dyes, cyanomethine dyes and phenothiazine dyes and Z is chosen from linear and branched, saturated and unsaturated C1–C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing a cationic charge. Also processes for dyeing human keratin fibers using the dye composition, to the use of the at least one direct tricationic dye of formula (I) as direct dyes, and to multi-compartment devices.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: January 30, 2007
    Assignee: L'Oreal S.A.
    Inventor: Alain Lagrange
  • Patent number: 7094262
    Abstract: A dye composition for dyeing human keratin fibres, such as hair, comprising at least one dissymmetrical polycationic direct dye of formula (I) below: Col1-Z-Col2??(I) wherein: Col1 and Col2, which differ in structure, are chosen from tazo dyes, methine dyes, azomethine dyes, phenothiazine dyes, triarylmethane dyes, xanthene dyes, phenanthridine dyes and phthalocyanin dyes and Z is chosen from linear and branched, saturated, unsaturated and cyclic C1–C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing at least one cationic charge; and also to processes for dyeing human keratin fibres using the composition, to the use of the at least one dissymmetrical polycationic direct dye of formula (I) as direct dyes, and to multi-compartment devices.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: August 22, 2006
    Assignee: L'Oreal S.A.
    Inventor: Alain Lagrange
  • Patent number: 7083984
    Abstract: Water soluble hybrid phthalocyanine derivatives useful in competitive and noncompetitive assays immunoassays, nucleic acid and assays are disclosed and claimed having (1) at least one donor subunit with a desired excitation peak; and (2) at least one acceptor subunit with a desired emission peak, wherein said derivative(s) is/are capable of intramolecular energy transfer from said donor subunit to said acceptor subunit. Such derivatives also may contain an electron transfer subunit. Axial ligands may be covalently bound to the metals contained in the water soluble hybrid phthalocyanine derivatives. Ligands, ligand analogues, polypeptides, proteins and nucleic acids can be linked to the axial ligands of the dyes to form dye conjugates useful in immunoassays and nucleic acid assays.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: August 1, 2006
    Assignee: Biosite, Inc.
    Inventors: Kenneth F. Buechler, Joseph B. Noar, Lema Tadesse
  • Patent number: 7077896
    Abstract: A pigment composition composed of 50 to 95% by weight of a phthalocyanine, 1 to 45% by weight of a halogenated phthalocyanine of which the number of substituents of a halogen atom is 1 to 9 and the average number of the substituents is 2.0 to 4.0 and 0.1 to 10% by weight of a phthalocyanine derivative of the formula (1) or a phthalimide methylated phthalocyanine derivative, a colorant containing the above pigment composition and a molded article obtained from a plastic containing the above colorant, P—(X)m??(1) wherein P represents a phthalocyanine structure, X represents an alkyl group having 12 to 18 carbon atoms, an alkoxy group having 12 to 18 carbon atoms, —SO2NHR, —SO2NR2, —NR2, —CONR2, —CONHR or —SR (wherein R represents an alkyl group or an alkenyl group which has 12 to 18 carbon atoms), and m is an integer of 1 to 4.
    Type: Grant
    Filed: June 10, 2004
    Date of Patent: July 18, 2006
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventors: Naoki Hamada, Mikiya Kato, Akiyoshi Iguchi
  • Patent number: 7005517
    Abstract: The present invention provides a novel paramagnetic metal-phthalocyanine complexes and pharmaceutically acceptable salts thereof, which are useful as contrast agents for MRI(Magnetic Resonance Imaging), diagnostic X-ray imaging and computed tomography(CT). The present invention also provides contrast agents for imaging, comprising the new paramagnetic metal-phthalocyanine complexes. The new contrast agents of the present invention show high imaging enhancement effects at lower concentration and are safer than the previously reported contrast agents.
    Type: Grant
    Filed: January 4, 2002
    Date of Patent: February 28, 2006
    Inventors: Sung-Young Lee, Kyo-Im Koo
  • Patent number: 6949139
    Abstract: In a process for forming an amorphous pigment mixture consisting essentially of TiOPc and TiOFPc and containing more than about 75 weight percent of TiOPc, a mixture of crude crystalline TiOPc and TiOFPc pigments in a weight ratio of at least 75:25 TiOPc:TiOFPc is combined with at least about 5 wt. %, based on the total weight of TiOPc and TiOFPc, of an organic milling aid. The mixture is treated under conditions effective to form a substantially amorphous pigment mixture of TiOPc and TiOFPc. The organic milling aid can be separated from the substantially amorphous pigment mixture, which can be converted to a nanoparticulate cocrystalline TiOPc/TiOFPc composition.
    Type: Grant
    Filed: September 4, 2003
    Date of Patent: September 27, 2005
    Assignee: Eastman Kodak Company
    Inventors: Michel F. Molaire, Louis J. Sorriero
  • Patent number: 6860934
    Abstract: A process for the production of a ? type copper phthalocyanine pigment having an average primary crystal diameter of 80±40 nm and a primary crystal aspect ratio of 2.0±1.0 and having a crystallite diameter of 22±5 nm in the direction perpendicular to a monoclinic ? (200) plane, a crystallite diameter of 27±5 nm in the direction perpendicular to a ? (001) plane and a crystallite diameter of 15±5 nm in the direction perpendicular to a ? (010) plane, which process comprises, dry-milling a crude copper phthalocyanine having a purity of 97 to 100% and a primary crystal diameter of 0.5 to 100 ?m at 180 to 50° C., to prepare an ?/? mixed crystal type copper phthalocyanine having an a ratio of 5 to 35%, and treating the dry-milled product in a water-miscible organic solvent.
    Type: Grant
    Filed: June 10, 2004
    Date of Patent: March 1, 2005
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventors: Osamu Shiromaru, Yuusaku Ide, Toshio Oshiba, Takuya Kotani
  • Publication number: 20040250734
    Abstract: A process for the production of a &bgr; type copper phthalocyanine pigment having an average primary crystal diameter of 80±40 nm and a primary crystal aspect ratio of 2.0±1.
    Type: Application
    Filed: June 10, 2004
    Publication date: December 16, 2004
    Inventors: Osamu Shiromaru, Yuusaku Ide, Toshio Oshiba, Takuya Kotani
  • Patent number: 6652636
    Abstract: The novel phthalocyanine cyan dye of the formula (I) in which M represents an ion of a metal selected from the group consisting of Cu, Fe, Co, Mg, Mn, Sn and Ni, X represents a linear compound having 6-10 atoms in length containing C, O, and/or N, R1 represents pyridine, imidazole, sulfide, thiol, phenol, benzene, benzaldehyde, pyrimidine, pyrizine, triazine, thiazole, oxazole, pyridone, pyrone, pyrole, thiophene, furan, pyran, dioxane, and morpholine, and derivatives thereof, R2 represents an atom or chemical group that imparts water solubility to the phthalocyanine cyan dye, and y and z each independently represent an integer of 1 to 3 satisfying the relation of 2≦y+z≦4. Ink formulations containing at least one dye of the formula (I) and methods for ink jet printing with inks containing the phthalocyanine cyan dyes of formula (I).
    Type: Grant
    Filed: June 29, 2001
    Date of Patent: November 25, 2003
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Larrie A Deardurff, Hiang P Lauw
  • Patent number: 6645928
    Abstract: Nonionic, hydrophobic photobleach compounds, especially those based on Si(IV) phthalocyanines, which are liquid at ambient temperatures and their use in a variety of consumer product compositions.
    Type: Grant
    Filed: February 11, 2002
    Date of Patent: November 11, 2003
    Assignee: Case Western Reserve University
    Inventors: Malcolm Edward Kenney, Ying-Syi Li, Gongzhen Cheng, Rafael Ortiz, David Johnathan Kitko, Michael Eugene Burns
  • Publication number: 20030194646
    Abstract: An optical recording medium having a recording layer which contains at least one compound selected from the group consisting of mono-, di-, and triazaporphyrin compounds optionally in the form of a metal complex; or an optical recording medium comprising a substrate and formed thereon at least a recording layer containing an organic dye as a main component, characterized in that the organic dye has a first maximum value of absorption at a wavelength &lgr;1 of 400 nm or less in the absorption spectrum and has a second maximum value of absorption at a longer-wavelength side than the &lgr;1, and a wavelength band wherein the refractive index (n) and the absorption coefficient (k) of the above organic dye satisfy n≧1.90 and 0.03≦k≦0.30.
    Type: Application
    Filed: June 28, 2002
    Publication date: October 16, 2003
    Inventors: Akira Ogiso, Shinobu Inoue, Taizo Nishimoto, Hisashi Tsukahara, Tsutami Misawa, Tadashi Koike, Norihiko Mihara, Shunsuke Murayama, Ryousuke Nara
  • Patent number: 6632808
    Abstract: Methods, compounds and compositions are disclosed for treating amyloidogenic diseases, like Alzheimer's disease and type 2 diabetes, and particularly prion diseases associated with conversion of protease sensitive PrP (PrP-sen) to protease resistant PrP (PrP-res), by administering therapeutically effective amounts of a tetrapyrrole. Particular disclosed tetrapyrroles having this activity include phthalocyanines, deuteroporphyrins, and meso-substituted porphines. Complexes of certain of the pyrroles with metals or metal ions produce compounds that are particularly effective in converting the conversion of PrP-sen to PrP-sen. The treatment of the present invention is particularly suited for preventing or inhibiting the progression of prion related diseases, such as transmissible spongiform encephalopathies.
    Type: Grant
    Filed: March 7, 2001
    Date of Patent: October 14, 2003
    Assignee: The United States of America as represented by the Department of Health and Human Services
    Inventors: Winslow S. Caughey, Byron Caughey
  • Publication number: 20030164118
    Abstract: Organic pigments are conditioned by introducing a liquid prepigment suspension into a miniaturized continuous reactor and thermally treating therein.
    Type: Application
    Filed: March 31, 2003
    Publication date: September 4, 2003
    Applicant: Clariant Finance (BVI) Limited
    Inventors: Uwe Nickel, Klaus Kund, Erwin Dietz, Joachim Webber, Olaf Schupp
  • Patent number: 6613488
    Abstract: A phthalimide salt compound is contained in a photosensitive material having a charge generating function. Such a photosensitive material exhibits high retention rates of the surface charge. An electrophotographic photoconductor comprising such a photosensitive material is useful in, for example, printers, photocopiers, and facsmilie machines.
    Type: Grant
    Filed: October 6, 2000
    Date of Patent: September 2, 2003
    Assignee: Fuji Electric Imaging Devices Co., Ltd.
    Inventors: Yoichi Nakamura, Shinjirou Suzuki, Hideki Kina, Kenichi Hara, Teruo Sasaki
  • Patent number: 6593286
    Abstract: Consumer product compositions such as laundry detergents comprising selected photosensitive compounds for photobleaching, photodisinfection, antibacterial activity, hueing or other benefits. The compositions are preferably formulated with detersive surfactants and/or water-soluble polymers.
    Type: Grant
    Filed: January 23, 2002
    Date of Patent: July 15, 2003
    Assignee: Case Western Reserve University
    Inventors: Malcolm Edward Kenney, Ying-Syi Li, Rafael Ortiz, David Johnathan Kitko, Michael Eugene Burns
  • Patent number: 6562121
    Abstract: Organic pigments are conditioned by introducing a liquid prepigment suspension into a miniaturized continuous reactor and thermally treating therein.
    Type: Grant
    Filed: June 27, 2001
    Date of Patent: May 13, 2003
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Uwe Nickel, Klaus Kund, Erwin Dietz, Joachim Weber, Olaf Schupp
  • Publication number: 20030054273
    Abstract: An electrophotographic photosensitive member exhibiting a high sensitivity and a potential stability on repetitive use and capable of suppressing image defects, such as black spots in a reversal development scheme, is provided. The photosensitive member includes a support, and a phthalocyanine layer formed on the support and a novel phthalocyanine crystal, which comprises a phthalocyanine compound and a substituted or unsubstituted condensed polycyclic hydrocarbon compound.
    Type: Application
    Filed: August 23, 2002
    Publication date: March 20, 2003
    Inventors: Masato Tanaka, Hidetoshi Hirano, Kan Tanabe, Kazue Asakura, Atsushi Fujii
  • Publication number: 20030041775
    Abstract: The novel phthalocyanine cyan dye of the formula (I) 1
    Type: Application
    Filed: June 29, 2001
    Publication date: March 6, 2003
    Inventors: Larrie A. Deardurff, Hiang P. Lauw
  • Publication number: 20030036538
    Abstract: The present invention discloses dye-sulfenate derivatives and their bioconjugates for dual phototherapy of tumors and other lesions. The compounds of the present invention may contain either a mixture of Type 1 and Type 2 agents or a single entity that integrates both units in the same molecules. The compounds are designed to produce both Type 1 and Type 2 phototherapeutic effect at once using dual wavelength light source that will produce singlet oxygen and free radicals at the lesion of interest.
    Type: Application
    Filed: July 3, 2001
    Publication date: February 20, 2003
    Applicant: MALLINCKRODT INC.
    Inventors: Raghavan Rajagopalan, Samuel I. Achilefu, Joseph E. Bugaj, Richard B. Dorshow
  • Patent number: 6511971
    Abstract: Phthalocyanine compounds of the formulas I and II: wherein X1-8 are each halogen and R1-8 are each independently halogen or an anti-stacking moiety; and [MxLySz]Cw  (II) wherein M is a metal, L is an anion of a phthalocyanine compound of formula I as defined above, S is an organic or inorganic ligand, C is a counterion, x and y are numbers greater than zero, and z and w are numbers zero or greater, are disclosed. Pharmaceutical compositions comprising the compounds and methods of using the compounds, for example for treatment of cancer, are also disclosed.
    Type: Grant
    Filed: October 12, 1999
    Date of Patent: January 28, 2003
    Assignee: Brown University Research Foundation
    Inventor: Sergiu M. Gorun
  • Publication number: 20030017164
    Abstract: The present invention discloses dye-azide derivatives and their bioconjugates for dual phototherapy of tumors and other lesions. The compounds of the present invention may contain either a mixture of Type 1 and Type 2 agents or a single entity that integrates both units in the same molecules. The compounds are designed to produce both Type 1 and Type 2 phototherapeutic effect at once using dual wavelength light source that will produce singlet oxygen and nitrene at the lesion of interest.
    Type: Application
    Filed: July 3, 2001
    Publication date: January 23, 2003
    Applicant: MALLINCKRODT INC.
    Inventors: Raghavan Rajagopalan, Samuel I. Achilefu, Joseph E. Bugaj, Richard B. Dorshow
  • Publication number: 20030013028
    Abstract: [Problem] To provide a novel reaction product useful as an organic photoconductive material for electrophotographic photoconductors.
    Type: Application
    Filed: February 5, 2002
    Publication date: January 16, 2003
    Applicant: Ricoh Company, Ltd.
    Inventors: Kaoru Tadokoro, Masayuki Shoshi, Michihiko Namba, Tomoyuki Shimada, Chiaki Tanaka
  • Patent number: 6468713
    Abstract: The invention relates to a novel phthalocyanine compound which absorbs in a near-infrared region of 700˜1000 nm with little absorption in the visible region of the spectrum and can be applied with advantage to a near-infrared light-absorbing filter for plasma display, a secret ink and other applications and to a process for producing the phthalocyanine compound. The above phthalocyanine compound has the following general formula (I). A near-infrared light-absorbing material containing the same is also provided.
    Type: Grant
    Filed: October 10, 2000
    Date of Patent: October 22, 2002
    Assignee: Yamamoto Chemicals, Inc.
    Inventors: Hiroshi Terao, Shigeo Fujita, Yojiro Kumagae
  • Patent number: 6444807
    Abstract: The invention relates to phthalocyanine compounds and are represented by the formula: The compounds are used as a colorant and a pigment precursor, especially in light-sensitive compositions for color filters.
    Type: Grant
    Filed: March 12, 2001
    Date of Patent: September 3, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Annemarie Wolleb, Heinz Wolleb, Gerardus De Keyzer, Barbara Wagner
  • Patent number: 6391505
    Abstract: Disclosed are a phthalocyanine crystal in which an organic acceptor compound is associated with a phthalocyanine molecule, wherein said organic acceptor compound has a reduction potential to a reference electrode (Ag+/Ag) is not less than −1.5 V and not more than −0.5 V, and an electrophotosensitive material containing said phthalocyanine crystal as an electric charge generating material, which exhibits sufficient photosensitivity even in high-speed image forming apparatuses.
    Type: Grant
    Filed: July 27, 2000
    Date of Patent: May 21, 2002
    Assignee: Kyocera Mita Corporation
    Inventors: Kazunari Hamasaki, Yukimasa Watanabe
  • Patent number: 6384027
    Abstract: Disclosed are compounds of formula V wherein M is selected from: a metal atom; a metal compound; 2H whereby one H is bonded to each of the two nitrogen atoms depicted as being bonded to M (positions 29 and 31 shown) R3 is H or methyl; R1 and R4 are independently selected from: H, C1 to C4 alkyl, C2 to C4 alkenyl, methoxy, butoxy, propoxy, NH2, NH—(C1 to C4 alkyl), N—(C1 to C4 alkyl)2, S—(C1 to C4 alkyl); R8 to R25 are the same or different and are independently selected from: C1 to C32 alkyl; C2 to C32 alkenyl; X—O—Y; X—phenyl, X2COOX1, X2CONR1R11, H; halide; wherein: X and X2 are independently selected from: a chemical bond, —(CH2)n— wherein n is an integer from 1 to 32, —(CH2)a—CH═CH(CH2)b where a and b are independently selected from integers 0-32 and a+b totals 32; X1 and Y are independently selected from: C1 to C32 alkyl, C2 to C32 alkenyl, and H; R1 and R11 are independently selected from: H; C1 to C32 alkyl, C2 to C
    Type: Grant
    Filed: April 18, 2000
    Date of Patent: May 7, 2002
    Assignee: QinetiQ Limited
    Inventor: Michael J Cook
  • Patent number: 6348453
    Abstract: The present invention provides a method for treating a viral infection in a subject in need of such treatment comprising administering to the subject a photosensitizer formulated in a liposome carrier, and exposing the subject to light at a wavelength 20-40 nm greater than the maximum absorption of the photosensitizer at a sufficient dose and duration to treat the viral infection in the subject. The present invention also provides a method for treating a viral infection in a subject in need of such treatment comprising administering to the subject (i) a photosensitizer formulated in a liposome carrier and (ii) at least one quencher, and exposing the subject to light at a sufficient wavelength, dose and duration to treat the viral infection in the subject.
    Type: Grant
    Filed: April 5, 2000
    Date of Patent: February 19, 2002
    Assignee: New York Blood Center, Inc.
    Inventor: Ehud Ben-Hur
  • Patent number: 6335442
    Abstract: Phthalocyanine compounds substituted by from 1 to 8 substituents of formula (—O—R—O—) wherein R is a 1,2-arylene group are provided. Preferably, the phthalocyanine compounds are substituted by catechol. Additional substituents which may be present include hydrocarlyloxy, hydrocarbylthio, halogen and sulphonic acid or a salt thereof.
    Type: Grant
    Filed: February 3, 1997
    Date of Patent: January 1, 2002
    Assignee: Avecta Limited
    Inventors: Peter Gregory, Stephen James Reynolds
  • Patent number: 6274728
    Abstract: Compounds of formula A(B)x  (I), wherein x is an integer from 1 to 8, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, indanthrone, isoindolinone, isoindoline, dioxazine, azo, phthalocyanine or diketopyrrolopyrrole series that is bonded to x groups B via one or more hetero atoms, those hetero atoms being selected from the group consisting of N, O and S and forming part of the radical A, each group B independently of any other(s) is hydrogen or a group of the formula  at least one group B being a group of the formula The compounds according to the invention are used in high-molecular-weight organic materials, thermo-, photo- or chemo-sensitive recording materials, light-sensitive negative or positive resist compositions, ink compositions for ink-jet printing and color tapes for thermal transfer printing.
    Type: Grant
    Filed: December 16, 1999
    Date of Patent: August 14, 2001
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Véronique Hall-Goulle, Aline Bize
  • Patent number: 6268097
    Abstract: An electrophotographic photoreceptor is disclosed. The photoreceptor comprises pigment particles obtained by incorporating one or more metal atom into polycyclic anhydride-aromatic diamine condensation compound particles.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: July 31, 2001
    Assignee: Konica Corporation
    Inventors: Hirofumi Hayata, Kazumasa Watanabe, Kenichi Yasuda
  • Patent number: 6251177
    Abstract: Solid preparations of metal-containing or metal-free phthalocyanine dyes, a) which have an average particle size of greater than 100 &mgr;m, and b) which have a pH of greater than or equal to 10 when dissolved in 10 times the amount of water, are particularly suitable for the dyeing and printing of paper, after dissolution in water.
    Type: Grant
    Filed: December 8, 1999
    Date of Patent: June 26, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventor: Josef-Walter Stawitz
  • Patent number: 6245758
    Abstract: The present invention provides a method for the treatment of diseases by the decomposition of peroxynitrite, preferably decomposition to benign products, comprising the use of a complex which is a selected ligand structure providing a complexed metal such as Mn, Fe, Ni and V transition metals. The method of use, as well as novel pharmaceutical compositions therefor, are for the treatment of diseases advantageously affected by decomposition of peroxynitrite ed at a rate over the natural background rate of decay of peroxynitrite in humans suffering from the disease which comprises administration of an amount of a complex, in dosage unit form, which is effective for such acceleration of the decomposition of peroxynitrite .
    Type: Grant
    Filed: September 9, 1996
    Date of Patent: June 12, 2001
    Inventors: Michael K. Stern, Daniela Salvemini
  • Patent number: 6232281
    Abstract: The present invention relates to photochemical singlet oxygen generators useful as bleaching agents for laundry detergent compositions or in hard surface cleaning compositions and as anti-microbials. The photochemical singlet oxygen generators comprise a heavy atom unit-containing axial unit wherein the heavy atoms overlap with the &pgr; electron cloud of the photosensitizer unit and enhance the quantum efficiency of the transition of an electron from exited singlet state to triplet state.
    Type: Grant
    Filed: July 23, 1999
    Date of Patent: May 15, 2001
    Assignee: Procter & Gamble Co.
    Inventors: Alan David Willey, Brian Jeffreys, David William Ingram
  • Patent number: 6218533
    Abstract: A method of manufacturing an organic pigment including the steps of providing an organic pigment wet cake which includes at least an organic pigment and a solvent and drying the organic pigment wet cake while the wet cake is heated at a temperature higher than room temperature to prepare a powder of the organic pigment, wherein the organic pigment is present in the organic pigment wet cake in an amount of not greater than about 70% by weight.
    Type: Grant
    Filed: July 7, 2000
    Date of Patent: April 17, 2001
    Assignee: Ricoh Company, Ltd.
    Inventor: Tatsuya Niimi
  • Patent number: 6156116
    Abstract: A method for converting crude phthalocyanine blue from red to green by milling a dispersion of the crude phthalocyanine and an aqueous medium containing a particulate grinding aid and a surfactant grinding aid composition characterized by employing a surfactant grinding aid composition comprising an acetylenic diol surfactant of the general formulas I and II: ##STR1## where R.sup.1 and R.sup.2, which may be the same or different, are C1-C8 alkyl, R.sup.3 is hydrogen or methyl, R.sup.4 is hydrogen, methyl, ethyl, or any combination thereof, and m+n=an average value from 1 to 100.
    Type: Grant
    Filed: March 19, 1999
    Date of Patent: December 5, 2000
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Frank Jin Lee, Kevin Richard Stank
  • Patent number: 6150518
    Abstract: A process for preparing .chi.-form metal free phthalocyanine comprising: dry milling amorphous-like .alpha.-form metal free phthalocyanine to form .chi.-form metal free phthalocyanine partially; and wet milling or dispersing with stirring the resulting polymorph mixture in the presence of a cyclic organic solvent comprising an amide moiety. A simple process for preparing high-pure .chi.-form H2-Pc suitable as a charge generating meterial of an organic photoreceptor is provided, by improving the conventional technique for preparing .chi.-form H2-Pc.
    Type: Grant
    Filed: October 16, 1998
    Date of Patent: November 21, 2000
    Assignee: Orient Chemical Industries, Ltd.
    Inventors: Yasuhiro Yamasaki, Kazuyoshi Kuroda
  • Patent number: 6136966
    Abstract: A phthalocyanine radical anion stable in ambient atmosphere, which is formed by subjecting a salt containing dihalogeno(phthalocyaninato)antimony (V) cation to a one-electron reduction. According to the present invention, a phthalocyaninc radical stable in ambient atmosphere, which is expected to be developed as an n-type organic semiconductor, is provided.
    Type: Grant
    Filed: September 23, 1999
    Date of Patent: October 24, 2000
    Assignee: National Research Institute for Metals
    Inventors: Hiroaki Isago, Yutaka Kagaya, Md. Hasan Zahir
  • Patent number: 6103896
    Abstract: A process for the production of a metal phthalocyanine excellent in color-related properties such as tinting strength, clearness and hue, in which no reactions of raw materials with a solvent take place and a substance harmful to human bodies such as polychlorinated biphenyl (PCB) is not formed, the process comprising heating phthalic anhydride or phthalimide, urea, metal salt and a catalyst in mixed solvents of chlorinated benzene and a linear hydrocarbon.
    Type: Grant
    Filed: April 2, 1999
    Date of Patent: August 15, 2000
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Atsushi Endo, Yasumasa Suda
  • Patent number: 6066729
    Abstract: A photothermal conversion material showing high sensitivity to the light of a semiconductor laser having an emission frequency band of 750 nm.about.900 nm with a high photothermal conversion efficiency and a planographic original plate fabricated by using the transducer are provided. This photothermal conversion material comprises a phthalocyanine compound of the following general formula (I) ##STR1## wherein R.sub.1 .about.R.sub.8 each represents alkyl or alkoxyalkyl; X.sub.1 .about.X.sub.8 each represents sulfur or NR.sub.9, where R.sub.9 is hydrogen or alkyl.
    Type: Grant
    Filed: November 17, 1998
    Date of Patent: May 23, 2000
    Assignee: Yamamoto Chemicals, Inc
    Inventors: Shigeo Fujita, Jun-ichi Taniguchi, Hiroshi Terao, Yojiro Kumagae
  • Patent number: 6063924
    Abstract: Compounds of formulaA(B).sub.x (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine, diketopyrrolopyrrole or azo series, which radical A contains x N-atoms linked with B, preferably with at least one immediately adjacent or conjugated carbonyl group.B is a group of formula ##STR1## and, if x=2, 3 or 4, can also be one, two or three hydrogen atom(s), and wherein Q is a group of formula ##STR2## These soluble chromophores can be readily converted to the corresponding pigments by heating, even in the substrate into which they can be incorporated without any difficulty in dissolved form.R.sub.1 -R.sub.9 are as defined herein.
    Type: Grant
    Filed: July 22, 1996
    Date of Patent: May 16, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Veronique Hall-Goulle
  • Patent number: 6060598
    Abstract: Fluorescence immunoassays methods are provided which use fluorescent dyes which are free of aggregation and serum binding. Such immunoassay methods are thus, particularly useful for the assay of biological fluids, such as serum, plasma, whole blood and urine.
    Type: Grant
    Filed: June 13, 1997
    Date of Patent: May 9, 2000
    Assignee: Hyperion, Inc.
    Inventors: Robert Francis Devlin, Walter Beach Dandliker, Peter Olaf Gustaf Arrhenius
  • Patent number: 6054449
    Abstract: A broad class of photosensitive compounds having enhanced in vivo target tissue selectivity and versatility in photodynamic therapy. Many furocoumarin compounds, such as psoralens, exhibit cytostatic activity when photoactivated but exhibit little in vivo specificity for selectively accumulating in any particular target tissue such as atheromatous plaques. Reactive Oxygen Producing Photosensitizers ("ROPPs") are photoactivatable compounds having an affinity for hyperproliferating cells (such as atheromatous plaque cells), which when photoactivated, produce cytotoxic reaction products. The photoactivity of a ROPP, such as a porphyrin, may be reduced by metalating the porphyrin while the selective affinity of the metalized ROPP for hyperproliferating tissue remains substantially unchanged.
    Type: Grant
    Filed: February 14, 1997
    Date of Patent: April 25, 2000
    Assignee: Miravant Pharmaceuticals, Inc.
    Inventors: Byron Robinson, Alan R. Morgan, Hugh L. Narciso, Jr.
  • Patent number: 6051360
    Abstract: Dyestuffs represented by the below-described formula (1), that is, dyestuffs formed of a chromophoric nucleus and a bisphenol introduced therein have excellent solubility in solvents and binder resins, and can provide color filters having excellent transmittance characteristics and durability. ##STR1## wherein Dye represents a chromophoric nucleus, X represents a direct bond or a divalent connecting group, R.sup.1 to R.sup.10 and n are defined with the provision that one of R.sup.9 and R.sup.10 has 3 or more carbon atoms.
    Type: Grant
    Filed: December 31, 1997
    Date of Patent: April 18, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Akio Karasawa, Hisato Itoh
  • Patent number: 6051702
    Abstract: Phthalocyanine compounds are disclosed having a structure according to formula I as shown below: ##STR1##
    Type: Grant
    Filed: December 3, 1997
    Date of Patent: April 18, 2000
    Assignee: Rutgers, The University of New Jersey
    Inventors: George R. Bird, Ronald Raymond Sauers, Paul Panayotatos