Phthalocyanines Patents (Class 540/122)
  • Patent number: 4970021
    Abstract: Phthalocyanine compounds are described, which are represented by the following general formula (I): ##STR1## wherein R.sub.1 -R.sub.8 are individually a hydrogen atom or an alkyl or aryl group, a-h stand individually for an integer of 1-20, and M denotes two hydrogen atoms or a metal atom, metal halide, metal oxide, metal hydroxide, dialkylmetal, diarylmetal, bis(alkyloxy)metal or bis(trialkylsilyloxy)metal. Optical recording media and liquid crystal display panels, which contain at least one of the phthalocyanine compounds, are also described.
    Type: Grant
    Filed: August 29, 1988
    Date of Patent: November 13, 1990
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Masakatsu Nakatsuka, Tsutomu Nishizawa, Takahisa Oguchi, Hisato Itoh, Katashi Enomoto
  • Patent number: 4946762
    Abstract: Metal-containing or metalfree, monosubstituted or disubstituted phthalocyanines I which have one or two of the following radicals R as substituents on their benzene rings: R=bromine, cyano, C.sub.1 -C.sub.3 -alkyl, n-butyl, i-butyl, C.sub.5 -C.sub.20 -alkyl, C.sub.5 -C.sub.10 -cycloalkyl, fluorinated C.sub.1 -C.sub.6 -alkyl, C.sub.6 -C.sub.20 -aryl, XR.sup.1, where X is oxygen, sulfur, selenium, tellurium or imino (NH) and R.sup.1 is C.sub.1 -C.sub.6 -alkyl, fluorinated C.sub.1 -C.sub.6 -alkyl or C.sub.6 -C.sub.20 -aryl, or Si(R.sup.2).sub.3, where R.sup.2 is C.sub.1 -C.sub.6 -alkyl, each and every substituted benzene ring being substituted by only one R radical, are useful in Laser-optical recording materials.
    Type: Grant
    Filed: February 24, 1989
    Date of Patent: August 7, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernhard Albert, Harald Kuppelmaier, Gerhard Wagenblast
  • Patent number: 4935501
    Abstract: Reactive dyes of the formula ##STR1## in which D is the radical of a dye of the monoazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide series, R.sub.1 is hydrogen or an unsubstituted or substituted C.sub.1-4 -alkyl radical, and X is the vinyl, .beta.-sulfatoethyl, .beta.-thiosulfatoethyl, .beta.-chloroethyl or .beta.-acetoxyethyl group, are suitable in particular for dyeing and printing cellulose-containing fibre materials by the cold pad-batch method and produce, in high dyeing yields, dyeings and prints having good fastness properties.
    Type: Grant
    Filed: March 7, 1988
    Date of Patent: June 19, 1990
    Assignee: Ciba-Geigy Corporation
    Inventor: Athanassios Tzikas
  • Patent number: 4842970
    Abstract: There is disclosed an electrophotographic plate comprising an electroconductive supporting substrate and a photoconductive layer formed thereon, wherein the photoconductive layer contains an organic photoconductive material as a charge generation material, said organic photoconductive material being a naphthalocyanine compound represented by the formula ##STR1## or the general formula ##STR2## wherein M denotes one member selected from the group consisting of Cu, Zn, Mg, OTi, OV, ClAl ClGa, ClIn, Cl.sub.2 Si, Cl.sub.2 Ge, and Cl.sub.2 Sn.
    Type: Grant
    Filed: April 20, 1988
    Date of Patent: June 27, 1989
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Seiji Tai, Shigeru Hayashida, Nobuyuki Hayashi
  • Patent number: 4814441
    Abstract: Finely divided, transparent, metal-free X-phthalocyanine has a specific surface area of from 75 to 120 m.sup.2 g and not less than 80% by weight of the phthalocyanine particles have a Stokes-equivalent diameter of .ltoreq.0.12 .mu.m.The phthalocyanine is very useful as a pigment for printing inks and finishes.
    Type: Grant
    Filed: November 20, 1987
    Date of Patent: March 21, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Hauser, Volker Radtke
  • Patent number: 4814256
    Abstract: An optical recording material possesses a light-absorbing layer on a base, the said layer containing one or more colorants of the formula (I) ##STR1## where M is two hydrogen atoms or Fe, Cu, Co, Ni, Pb, Cr, Mn, VO, TiO, ZrO, Nb, Ta, Pd, SiCl.sub.2, Sn or SnX.sub.2, X is Cl, Br or I, and A is a divalent radical of an unsaturated, unsubstituted or substituted carbocyclic ring system.The colorants (I) present on the novel recording materials have a high absorption in the range from 650 to 850 nm and accordingly can be written on and read by means of a laser. The colorants can be applied as 20-1000 nm layers on a suitable base by vapor deposition or as a solution or dispersion, with or without the addition of a polymeric binder, by a conventional method.The layers are very stable to atmospheric influences and daylight.
    Type: Grant
    Filed: July 2, 1987
    Date of Patent: March 21, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Reinhard Aldag, Peter Neumann
  • Patent number: 4800145
    Abstract: An organic photoconductor suitable for use in electro-reprography comprising an electrically conducting support, a charge generating phase comprising a charge generator and a charge transport phase characterized in that the charge generator is a phthalocyanine compound in which each of at least four of the peripheral carbon atoms numbered from 1 to 16 in the phthalocyanine nucleus shown below is linked, by an atom from Group VA or Group VIA of the Periodic Table, to a carbon atom of an organic radical.
    Type: Grant
    Filed: July 14, 1987
    Date of Patent: January 24, 1989
    Assignee: Imperial Chemical Industries, PLC
    Inventors: Anthony J. Nelson, Peter J. Duggan
  • Patent number: 4788128
    Abstract: A transfer printing medium comprising a substrate supporting a thermal transfer dye and a radiation absorber positioned to provide thermal energy to the transfer dye when subjected to radiation within a predetermined absorption waveband, has a radiation absorber which is an infra-red absorbing poly(substituted)phthalocyanine compound in which each of at least five of the peripheral carbon atoms in the 1, 4, 5, 8, 9, 12, 13 or 16 positions (the "3,6-positions") of the phthalocyanine nucleus, as shown in Formula I, is linked by an atom from Group VB or Group VIB of the Periodic Table, other than oxygen, to a carbon atom of an organic radical. In preferred compounds each of the eight 3,6-positions is linked by an atom from Group VB or Group VIB, especially sulphur, selenium or nitrogen, to an organic radical.
    Type: Grant
    Filed: October 20, 1986
    Date of Patent: November 29, 1988
    Assignee: Imperial Chemical Industries PLC
    Inventor: William A. Barlow
  • Patent number: 4784736
    Abstract: The preparation of a novel class of thin film membranes by interfacial polymerization is disclosed, said membanes incorporating as part of their polymeric structure the functionality of monomeric or oligomeric precursors. Specific embodiments include porphyrin and phthalocyanime derivatives that are photochemically or electrochemically active, as well as chemically asymmetric membranes.
    Type: Grant
    Filed: July 7, 1986
    Date of Patent: November 15, 1988
    Assignee: Bend Research, Inc.
    Inventors: Harold K. Lonsdale, Carl C. Wamser
  • Patent number: 4783386
    Abstract: Provided is an optical information recording medium and a method of recording information thereon. The information layer of the recording medium comprises an anthracyanine or phenanthracyanine chromophore compound. In a preferred embodiment, the chromophore is substituted with at least one substituent conferring film forming properties to the chromophore, e.g., a monomer or oligomeric substituent comprised of acid, amide or ester units. The resulting information layer exhibits strong absorption in the range of from about 780-850 nm. Employing an anthracyanine or phenanthracyanine chromophore substituted with a film forming substituent further offers the advantages of a single component material exhibiting good thermomechanical properties.
    Type: Grant
    Filed: January 12, 1987
    Date of Patent: November 8, 1988
    Assignee: Hoechst Celanese Corporation
    Inventors: David E. Nikles, R. Sidney Jones, Jr., James E. Kuder
  • Patent number: 4657554
    Abstract: Novel azaphthalocyanines are described which are of the formula ##STR1## in which Me is Al(III), Zn(II), Ge(IV) or Sn(IV), E is an anionic group, Z is a cation, Y is a halogen, n is any desired number from 1 to 3 and p is any desired number from 0 to 2, the sum n+p being at most 8 and A, B, C and D independently of one another completing a benzene ring or a ring of the formula ##STR2## at least one of the rings completed by A, B, C or D being one of the said heterocyclic rings.The novel compounds can be used as photoactivators, in particular for bleaching textiles and for controlling microorganisms in or on organic or inorganic substrates.Bleaching, washing and steeping agents and antimicrobially active agents are also described which contain the novel azaphthalocyanine compounds.
    Type: Grant
    Filed: May 22, 1985
    Date of Patent: April 14, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Reinert, Gerd Holzle, Gregor Graf
  • Patent number: 4606859
    Abstract: An infra-red absorbing phthalocyanine compound in which each of at least five of the peripheral carbon atoms in the 1, 4, 5, 8, 9, 12, 13 or 16 positions (the "3,6-positions") of the phthalocyanine nucleus, as shown in Formula I, is linked by an atom from Group VB or Group VIB of the Periodic Table, other than oxygen, to a carbon atom of an organic radical. In preferred compounds each of the eight 3,6-positions is linked by an atoms from Group VB or Group VIB, especially sulphur, selenium or nitrogen, to an organic radical.
    Type: Grant
    Filed: March 21, 1985
    Date of Patent: August 19, 1986
    Assignee: Imperial Chemical Industries PLC
    Inventors: Peter J. Duggan, Paul F. Gordon
  • Patent number: 4180578
    Abstract: A compound selected from a 2,4-diamino-5-thiobenzylpyrimidine of the formula: ##STR1## in which R is selected from hydrogen, alkyl, lower alkoxy, and halogen and R' is alkyl; and pharmacologically acceptable acid addition salts thereof. These compounds have an anti-bacterial action and are sulphonamide potentiators.
    Type: Grant
    Filed: March 29, 1978
    Date of Patent: December 25, 1979
    Assignee: Ludwig Heumann, & Co. GmbH
    Inventors: Edgar Fritschi, Walter Liebenow, Jaroslav Prikryl
  • Patent number: H477
    Abstract: The invention relates to phthalocyanine compounds, and more particularly to the preparation of aryloxy, arylthio, alkyloxy, and alkylthio phthalocyanine compounds and their subsequent incorporation into semiconducting thin films by the Langmuir-Blodgett technique.
    Type: Grant
    Filed: August 21, 1985
    Date of Patent: June 7, 1988
    Assignee: United States of America
    Inventors: William R. Barger, Neldon L. Jarvis, Arthur W. Snow, Henry Wohltjen