Heavy Metal Or Aluminum Containing Patents (Class 546/2)
  • Patent number: 7790912
    Abstract: A polycarbodiimide polymer that is reversibly switchable between two distinct optical orientations is described. The polymer is useful in forming devices such as filters, storage media, actuators, and displays. Methods of making and using such polymers are also described.
    Type: Grant
    Filed: December 30, 2008
    Date of Patent: September 7, 2010
    Assignee: North Carolina State University
    Inventors: Bruce M. Novak, Hong-Zhi Tang
  • Patent number: 7790889
    Abstract: Disclosed herein are a di-(4-vinylpyridine) metal phthalocyanine compound in which 4-vinylpyridines as ligands are included in a phthalocyanine having a metal, a composition comprising the same and a preparation method thereof. The di-(4-vinylpyridine) metal phthalocyanine compound has an excellent UV blocking effect together with low surface resistance and is prepared but by charging a powder phase with nitrogen, not by dissolving raw materials in an organic solvent as in the prior art.
    Type: Grant
    Filed: December 24, 2008
    Date of Patent: September 7, 2010
    Assignee: Hoseo University Academic Cooperation Foundation
    Inventors: Young Goo Kang, Dae Woo Ihm, Shi Surk Kim
  • Publication number: 20100216993
    Abstract: The invention is reported a type of chair ruthenium complexes and their used as anticancer agent. The general formulae of these chair ruthenium complexes is: A-[Ru(bpy)2L](PF6)2, where in A is ? or ?, L is tFPIP, IPBP, IPBH or PYNI. These chair ruthenium complexes is characterized with that the centre atom is ruthenium ion, the main ligand is 2-phenyl imidazole[4,5f][1,10]phenanthroline and its derivate, the co-ligand is two bipyridine, and the space structure is rigid octahedral. The complexes indicated by the invention are the chair isomer of all of these ruthenium complexes. This type of ruthenium complexes exhibit excellent inhibitory activity against liver cancer cell line BEL-7402, and can be used in preparing anticancer agent.
    Type: Application
    Filed: July 21, 2008
    Publication date: August 26, 2010
    Applicant: GUANGDONG PHARMACEUTICAL UNIVERSITY
    Inventor: Wenjie Mei
  • Publication number: 20100204473
    Abstract: The invention relates to di-aryl, di-heteroaryl or aryl-heteroaryl azaallyl compounds that are useful as chelates for metals.
    Type: Application
    Filed: February 11, 2010
    Publication date: August 12, 2010
    Applicant: CORNELL UNIVERSITY
    Inventors: Peter T. Wolczanski, Brenda A. Frazier
  • Patent number: 7767213
    Abstract: A compound and methods of making thereof having the structure shown below is disclosed. Each Ar is an aromatic group. Each M is palladium, platinum, or rhenium. At least one X in the compound has an aliphatic having at least 1 carbon atom. Each x, each y, and each z is an integer greater than or equal to zero. Each m is an integer greater than or equal to one. n is an integer greater than or equal to three.
    Type: Grant
    Filed: January 22, 2009
    Date of Patent: August 3, 2010
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Devanand K Shenoy, Enrico Dalcanale, Sander Willems, Marco Busi
  • Publication number: 20100184978
    Abstract: A bipyridine compound represented by the formula (1): wherein R1, R2 and R3 each independently represent a C1-C10 alkyl group which may be substituted etc., and R4, R5, R6, R7 and R8 each independently represent a hydrogen atom etc., a transition metal complex obtained by contacting a bipyridine compound represented by the formula (1) with a compound of a transition metal belonging to Group 9, 10 or 11, and a method for production of a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of the transition metal complex.
    Type: Application
    Filed: June 18, 2008
    Publication date: July 22, 2010
    Inventors: Taku Asaumi, Takashi Kamikawa
  • Patent number: 7759488
    Abstract: Disclosed herein are novel platinum-based analogs with a single substituted azole ligand: RN?NR7, wherein the RN?NR7 functional group is covalently bonded to the platinum through nitrogen of NR7. The analogs also have nitrogen donor ligands capable of forming hydrogen bonds with the bases in DNA or RNA, and one or more leaving groups which can be displaced by water, hydroxide ions or other nucleophiles, which is thought to form active species in vivo, and then, form cross-linked complexes between nucleic acid strands, principally between purines in DNA (or RNA), i.e., at the Guanine or Adenine bases, thereof.
    Type: Grant
    Filed: January 26, 2006
    Date of Patent: July 20, 2010
    Assignee: BioNumerik Pharmaceuticals, Inc.
    Inventors: Zejun Xiao, Harry Kochat, Frederick H. Hausheer
  • Patent number: 7759489
    Abstract: Provided are an organic electroluminescence device having high luminous efficiency and a long emission lifetime, and a transition metal complex compound realizing the organic electroluminescence device. In the transition metal complex compound, three ligands are crosslinked with a crosslinking group having a saturated cyclic structure or a saturated polycyclic structure in a tripod manner. The organic electroluminescence device includes an organic thin film layer composed of one or multiple layers including at least a light emitting layer, the organic thin film layer being interposed between a pair of electrodes. In the organic electroluminescence device, at least one layer of the organic thin film layer contains the transition metal complex compound.
    Type: Grant
    Filed: September 7, 2006
    Date of Patent: July 20, 2010
    Assignees: Idemitsu Kosan Co., Ltd., Osaka University
    Inventors: Masami Watanabe, Toshikazu Hirao, Toshiyuki Moriuchi, Lisheng Mao, Hsyueh-Liang Wu
  • Patent number: 7759490
    Abstract: There is disclosed herein phosphorescent compounds, uses thereof, and devices including organic light emitting diode (OLEDs) including such compounds. Compounds of interest include: wherein A is Os or Ru The anionic chelating chromophores N^N, which are formed by connecting one pentagonal ring structure containing at least two nitrogen atoms to a hexagonal pyridine type of fragment via a direct carbon-carbon linkage. L is a neutral donor ligand; the typical example includes carbonyl, pyridine, phosphine, arsine and isocyanide; two neutral L's can also combine to produce the so-called chelating ligand such as 2,2?-bipyridine, 1,10-phenanthroline and N-heterocyclic carbene (NHC) ligand, or bidentate phosphorous ligands such as 1,2-bis(diphenylphosphino)ethane, 1,2-bis(diphenylphosphino)benzene. L can occupy either cis or trans orientation.
    Type: Grant
    Filed: July 11, 2008
    Date of Patent: July 20, 2010
    Assignees: National Research Council of Canada, National Tsing Hua University
    Inventors: Ye Tao, Yun Chi, Yung-Liang Tung, Arthur Carty, Pi-Tai Chou
  • Publication number: 20100176031
    Abstract: Crystals of [VOBDC](H2BDC)0.71 were synthesized hydrothemally. The guest acid molecules were removed by heating in air to give high quality single crystals of VOBDC. VOBDC was observed to show crystal-to-crystal transformations on absorption of the guest molecules aniline, thiophene and acetone from the liquid phase. Accurate structural data of the guest molecules and framework deformations were obtained from single crystal X-ray data. VOBDC was also shown to absorb selectively thiophene and dimethyl sulphide from methane.
    Type: Application
    Filed: August 9, 2007
    Publication date: July 15, 2010
    Inventors: Allan J. Jacobson, Xiqu Wang, Lumei Liu
  • Publication number: 20100176386
    Abstract: The present invention relates to auxiliary ligands for luminescent metal complexes, particularly emitter complexes having such auxiliary ligands, and particularly light-emitting devices, and particularly organic light-emitting devices (OLED) having metal complexes, which have the auxiliary ligands according to the invention.
    Type: Application
    Filed: July 3, 2008
    Publication date: July 15, 2010
    Applicant: MERCK PATENT GMBH
    Inventors: Hartmut Yersin, Gafal Czewieniec, Uwe Monkowius
  • Patent number: 7754347
    Abstract: An organic electroluminescent device comprising a pair of electrodes and at least one organic layer between the pair of electrodes, wherein the organic layer contains at least one compound represented by the formula (I), preferably by the formula (II) and more preferably by the formula (III) as defined herein.
    Type: Grant
    Filed: September 28, 2006
    Date of Patent: July 13, 2010
    Assignee: FUJIFILM Corporation
    Inventors: Toshihiro Ise, Seiji Ichijima
  • Publication number: 20100170395
    Abstract: Disclosed are tetratopic carboxylic acid phenyl for use in metal-organic framework compounds. These compounds are useful in catalysis, gas storage, sensing, biological imaging, drug delivery and gas adsorption separation.
    Type: Application
    Filed: October 13, 2009
    Publication date: July 8, 2010
    Inventors: Omar K. Farha, Joseph T. Hupp
  • Patent number: 7750157
    Abstract: The present invention relates to luminescent compounds having a functionalised linker arm, their synthesis and use in bioconjugation and labelling of biomolecules, such as for example nucleosides, nucleotides, nucleic acids (DNA, RNA or PNA) and proteins, as well as their use in the execution of in vitro and in vivo analytic and diagnostic assays.
    Type: Grant
    Filed: June 1, 2005
    Date of Patent: July 6, 2010
    Assignee: Universita' Degli Studi di Torino
    Inventors: Giuseppe Caputo, Roberto Gobetto, Guido Viscardi
  • Patent number: 7745627
    Abstract: The invention relates to a method for the production of high-purity, heteroleptic, orth-etallated, organometallic compounds of application as a functional material for colouring components in a wide range of applications within the widest sense of the electronics industry. A method is thus used for the cleavage of a bridged metal dimer with organometallic substances. Dihalo complexes, which may be used as monomers for polymerisations, in particular, may be produced thus.
    Type: Grant
    Filed: October 21, 2004
    Date of Patent: June 29, 2010
    Assignee: Merck Patent GmbH
    Inventors: Philipp Stössel, Arne Büsing, Ingrid Bach
  • Publication number: 20100137596
    Abstract: Diarylethene-containing ligands and their coordination compounds are described. The ligands display photochromism with UV excitation, while the coordination compounds display photochromism with both excitation in the UV region and excitation into lower energy absorption bands characteristic of the coordination compounds, through which the excitation wavelengths for the photocyclization can be extended from ??340 nm to wavelengths beyond 470 nm. Switching of the luminescence properties of the compounds has also been achieved through photochromic reactions.
    Type: Application
    Filed: January 26, 2010
    Publication date: June 3, 2010
    Inventors: Vivian Wing-Wah Yam, Chi-Chiu Ko
  • Patent number: 7728149
    Abstract: A process produces a corresponding dicarboxylic acid by subjecting a cycloalkane to an oxidative cleavage reaction with oxygen in the presence of a catalyst in a liquid phase using a continuous reactor, in which a residence time ? (hr) satisfies the following condition: 0.1???50/c, wherein c is the proportion (% by weight) of the cycloalkane to the total weight of a charged liquid. The catalyst includes, for example, cobalt compounds, manganese compounds, and mixtures of these compounds, as well as imide compounds having at least one cyclic imide skeleton.
    Type: Grant
    Filed: January 14, 2003
    Date of Patent: June 1, 2010
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Kiyokazu Murata, Hiroyuki Miura
  • Publication number: 20100126880
    Abstract: The invention provides a compound of structure (I): wherein X is S, O or NRN, where RN is H or alkyl; L is a linker group; Q is a group capable of binding with dsDNA; G and G? are, independently, absent or have between 1 and 20 main chain atoms; FG is a functional moiety comprising at least one O or N atom or a transition metal complex; and R is selected from the group consisting of H, alkyl, alkoxy or OCRaRb coupled to an atom in L so as to form a six-membered ring. Ra and Rb are independently H or optionally substituted alkyl.
    Type: Application
    Filed: November 9, 2007
    Publication date: May 27, 2010
    Inventors: Hsiao-Hua Yu, Jackie Y. Ying, Natalia C. Tansil, Eric Assen B. Kantchev
  • Patent number: 7723520
    Abstract: The present invention relates to novel red phosphorescent compounds exhibiting high luminous efficiency, and organic electroluminescent devices comprising the same.
    Type: Grant
    Filed: July 24, 2008
    Date of Patent: May 25, 2010
    Assignee: SKC Haas Display Films Co., Ltd.
    Inventors: Hyun Kim, Young Jun Cho, Hyuck Joo Kwon, Bong Ok Kim, Sung Min Kim, Seung Soo Yoon
  • Publication number: 20100113779
    Abstract: The present invention describes novel organometallic compounds which are phosphorescence emitters. Such compounds can, as active constituents (=functional materials), be used in a number of different applications, which in the broadest sense can be classed as belonging to the electronics industry. The compounds according to the invention are described by the formulas (I), (Ia), (II), (IIa), (III), (IIIa), (IV) and (IVa).
    Type: Application
    Filed: November 5, 2009
    Publication date: May 6, 2010
    Applicant: Merck Patent GmbH
    Inventors: Philipp Stössel, Ingrid Bach, Hubert Spreitzer, Heinrich Becker
  • Publication number: 20100112545
    Abstract: Novel trans-1,2-diphenylethylene derivatives are synthesized which can be used to form nanoparticles-monomer-nanomolecule-receptor nanosensors. These trans-1,2-diphenyl-ethylene derivatives are soluble in both water and organic solvents, highly fluorescent and can be synthesized in high yields. The trans-1,2-diphenylethylene derivatives are bonded to a nanoparticle, a nanomolecule bonded to the derivative and a receptor bonded to the nanomolecule to form a nanosensor that can be used to detect chemical and biological agents.
    Type: Application
    Filed: July 13, 2007
    Publication date: May 6, 2010
    Inventors: Subra Muralidharan, Chun Wang
  • Publication number: 20100105853
    Abstract: A metal complex represented by the following formula (1): wherein R1 to R6 each independently represent a hydrogen atom or a substituent; Y1 and Y2 each independently represent any one of the following groups: wherein R? represents a hydrogen atom or a hydrocarbon group having 1 to 4 carbon atoms; P1 and P2 each represent a group of atoms necessary for forming a heterocyclic ring together with Y1 or Y2 and the two carbon atoms at a position adjacent to Y1 or Y2; P1 and P2 may be linked to each other to form a ring; M represents a transition metal element or typical metal element; m represents 1 or 2; X represents a counter ion or a neutral molecule; n represents the number of X's in the complex, and an integer of 0 or more; and Q1 and Q2 each independently represent an aromatic heterocyclic group.
    Type: Application
    Filed: March 10, 2008
    Publication date: April 29, 2010
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Tadafumi Matsunaga, Nobuyoshi Koshino, Hideyuki Higashimura
  • Patent number: 7692012
    Abstract: Novel Vanadium compounds are described as well as their use as inhibitors of phosphatases, particularly inositol phosphatases, The use of the compound in the treatment of nerodegenerative diseases is also described.
    Type: Grant
    Filed: December 6, 2004
    Date of Patent: April 6, 2010
    Assignee: Imperial College Innovations Limited
    Inventors: Rudiger Woscholski, Erika Rosivatz, Ramon Vilar
  • Publication number: 20100072425
    Abstract: 7-ethynyl-2,4,9-trithiaadamantane and related methods are presented. Manufacturing 7-ethynyl-2,4,9-trithiaadamantane includes the steps of: (1) reducing alkyl 2,4,9-trithiaadamantane-7-carboxylate to produce 7-hydroxymethyl-2,4,9-trithiaadamantane; (2) oxidizing 7-hydroxymethyl-2,4,9-trithiaadamantane to produces 7-carbonyl-2,4,9-trithiaadamantane; and (3) reacting 7-carbonyl-2,4,9-trithiaadamantane with Ohira-Bestmann reagent to produces 7-ethynyl-2,4,9-trithiaadamantane. Molecular wires having 2,4,9-trithiaadamantane surface anchors are also disclosed.
    Type: Application
    Filed: October 31, 2008
    Publication date: March 25, 2010
    Applicant: THE UNIVERSITY OF AKRON
    Inventor: Jun Hu
  • Publication number: 20100066243
    Abstract: An organic electroluminescent device is provided and includes: a pair of electrodes; and at least one organic layer between the pair of electrodes, the at least one organic layer including a light-emitting layer containing a light-emitting material. The at least one organic layer includes at least one layer containing an indole derivative represented by formula (1). R102, R103, R104, R105 and R106 each independently represents a hydrogen atom or a substituent; R101 represents a substituent linking via a carbon atom; R101 and R106 may be bonded to each other to form a ring; R107 represents a substituent; n101 represents 1 or 2; and n102 represents an integer of from 0 to 5, provided that n101+n102?6.
    Type: Application
    Filed: November 27, 2007
    Publication date: March 18, 2010
    Applicant: FUJIFILM CORPORATION
    Inventors: Tatsuya Igarashi, Kazunari Yagi
  • Patent number: 7675228
    Abstract: The present invention is directed to electroluminescent complexes of iridium(III) with silylated, germanylated and stannylated ligands. The invention is further directed to electronic devices in which the active layer includes an electroluminescent Ir(III) complex with silylated, germanylated and stannylated ligands.
    Type: Grant
    Filed: June 14, 2006
    Date of Patent: March 9, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Alex Sergey Ionkin, Ying Wang
  • Publication number: 20100051879
    Abstract: A plasma treatment has been used to modify the surface of BNNTs. In one example, the surface of the BNNT has been modified using ammonia plasma to include amine functional groups. Amine functionalization allows BNNTs to be soluble in chloroform, which had not been possible previously. Further functionalization of amine-functionalized BNNTs with thiol-terminated organic molecules has also been demonstrated. Gold nanoparticles have been self-assembled at the surface of both amine- and thiol-functionalized boron nitride Nanotubes (BNNTs) in solution. This approach constitutes a basis for the preparation of highly functionalized BNNTs and for their utilization as nanoscale templates for assembly and integration with other nanoscale materials.
    Type: Application
    Filed: November 21, 2007
    Publication date: March 4, 2010
    Applicant: The Regents od the Univesity of California
    Inventors: Toby Sainsbury, Takashi Ikuno, Alexander K. Zettl
  • Publication number: 20100044688
    Abstract: Metal complexes of the formula I or I? [LDH]nM[L]m (I) [LTH](M[L]p)2 (I1) wherein n is an integer 1 or 2, m and p each is an integer 1 or 2, the sum (n+m) being 2 or 3, M is a metal with an atomic weight of greater than 40 such as Iridium, L is a ligand as described in claim 1, and LDH is a bidentate ligand of the formula I1 and LTH is a dimer of LDH, binding to 2 metal atoms M, of the formula II? wherein W is selected from O, S, NR4, CR5R6, X is N or CR7, Y is selected from O, S, NR8; and further residues are as defined in claim 1, show good light emitting efficiency in electroluminescent applications.
    Type: Application
    Filed: February 4, 2008
    Publication date: February 25, 2010
    Applicant: CIBA CORPORATION
    Inventors: Annemarie Wolleb, Heinz Wolleb
  • Patent number: 7662962
    Abstract: An organometallic complex. The organometallic complex has formula (I) , wherein M is a transition metal with an atomic number greater than 40 comprising Ir, Os, Pt, Pd, Re, or Ru, is a substituted or non-substituted heterocyclic ring containing at least one nitrogen atom, and is any bidentate ligand comprising bipyridyl groups. The invention also provides an organic light-emitting diode and a display including the organometallic complex.
    Type: Grant
    Filed: May 6, 2005
    Date of Patent: February 16, 2010
    Assignee: AU Optronics Corp.
    Inventor: Pei-Chi Wu
  • Publication number: 20100034733
    Abstract: The present invention provides a catalyst for the decomposition of formic acid including a dinuclear metal complex represented by a formula (1) below, a tautomer or stereoisomer thereof, or any of their salts, where M1 and M2 are transition metals and may be the same or different; Ar is a ligand having aromaticity and may be unsubstituted or substituted by one or more substituents; R1 to R27 are each independently a hydrogen atom, an alkyl group, or the like, or R15 and R16 may together form a —CH?CH—, where Hs in the —CH?CH— may be each independently replaced by an alkyl group or the like, and R23 and R24 may together form a —CH?CH—, where Hs in the —CH?CH— may be each independently replaced by an alkyl group or the like; L is an arbitrary ligand or is absent; and m is a positive integer, 0, or a negative integer.
    Type: Application
    Filed: May 17, 2007
    Publication date: February 11, 2010
    Applicant: OSAKA UNIVERSITY
    Inventors: Shunichi Fukuzumi, Tomoyoshi Suenobu, Seiji Ogo
  • Patent number: 7659397
    Abstract: Zinc pyrithione and copper pyrithione are highly evaluated in the market as an antidandruff agent for shampoo, or an antifouling agent for ship bottom paint and fish-farming net, or an antibacterial/antifungal agent or preservative/mildewcide for industrial products and household articles. For enhancing the market value thereof, there has been a demand for a product that not only attains an increase in conventional antibacterial/antifungal effects but also exhibits novel bioactive effects and that achieves improvement with respect to problems and drawbacks relating to properties, such as solubility in seawater, and stability, such as thermal stability and weather resistance, of polymer materials. There is provided a novel pyrithione complex compound obtained by converting the conventional pyrithione metal salt to a complex compound with an oxide or hydroxide of metal such as zinc, copper or aluminum.
    Type: Grant
    Filed: October 22, 2004
    Date of Patent: February 9, 2010
    Assignee: YHS Ltd.
    Inventor: Yasuhiro Hidaka
  • Publication number: 20100029540
    Abstract: Biheteroaryl metal complexes and the use thereof as bleach catalysts are described.
    Type: Application
    Filed: October 12, 2009
    Publication date: February 4, 2010
    Applicant: Henkel AG & Co. KGaA
    Inventors: Andre Hätzelt, Anette Nordskog, Stefan Leopold, Peter Schmiedel, Wolfgang von Rybinski, Jörg Sundermeyer, Jan Döring
  • Publication number: 20100024133
    Abstract: Tris(heterocyclyl)-metal complexes and the use thereof as bleach catalysts are described.
    Type: Application
    Filed: October 12, 2009
    Publication date: February 4, 2010
    Applicant: Henkel AG & Co. KGaA
    Inventors: Andre Hätzelt, Anette Nordskog, Stefan Leopold, Peter Schmiedel, Wolfgang von Rybinski, Jörg Sundermeyer, Jan Döring
  • Publication number: 20100029469
    Abstract: Transition metal complexes of selected monoanionic phosphine ligands, which also contain a selected Group 15 or 16 (IUPAC) element and which are coordinated to a Group 3 to 11 (IUPAC) transition metal or a lanthanide metal, are polymerization catalysts for the (co)polymerization of olefins such as ethylene and ?-olefins, and the copolymerization of such olefins with polar group-containing olefins. These and other nickel complexes of neutral and monoanionic bidentate ligands copolymerize ethylene and polar comonomers, especially acrylates, at relatively high ethylene pressures and surprisingly high temperatures, and give good incorporation of the polar comonomers and good polymer productivity. These copolymers are often unique structures, which are described.
    Type: Application
    Filed: August 1, 2008
    Publication date: February 4, 2010
    Applicant: E. I. du Pont de Nemours and Company
    Inventors: LIN WANG, Elisabeth M. Hauptman, Lynda Kaye Johnson, Elizabeth Forrester McCord, Stephan J. McLain, Ying Wang
  • Patent number: 7652136
    Abstract: The present invention provides a diarylaminofluorene chromophore compound having the following structure: wherein: M is a metal atom of Ir, Pt; R is H, CH3, OCH3, or F; A is none or six-member carbocyclic aromatic ring system; 0?m?3 0?n?1. The invention also provides high-efficiency organic light-emitting devices fabricated using these compounds.
    Type: Grant
    Filed: September 12, 2006
    Date of Patent: January 26, 2010
    Assignees: The Hong Kong University of Science and Technology, Hong Kong Baptist University
    Inventors: Hoi-Sing Kwok, Wai-Yeung Wong, Xiao-Ming Yu, Gui-Jiang Zhou
  • Patent number: 7645879
    Abstract: A photosensitizer dye is provided.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: January 12, 2010
    Assignee: National Central University
    Inventors: Chun-Guey Wu, Chia-Yuan Chen, Shi-Jhang Wu, Jheng-Ying Li
  • Patent number: 7638628
    Abstract: The invention relates to a new class of ruthenium (II) complexes containing as ligands 2-(aminomethyl)pyridines and phosphines, proven to be extremely active catalysts in the reduction of ketones to alcohols via hydrogen transfer. By using 2-propanol as the hydrogen source with the ruthenium complexes, high yields of the corresponding alcohol can be rapidly obtained starting from linear and cyclic alkyl aryl, dialkyl and diaryl ketones. The conversion of ketones to alcohols can reach 100% if operating in a gaseous hydrogen atmosphere (2-3 atm). Where the phosphines used are optically active, starting from prochiral ketone compounds various types of optically active alcohols can be produced, being important intermediates in the pharmaceutical industry, in the agrochemical industry and for fine chemicals generally.
    Type: Grant
    Filed: May 2, 2005
    Date of Patent: December 29, 2009
    Assignee: Universita' Degli Studi Di Udine
    Inventors: Walter Baratta, Katia Siega, Micaela Toniutti, Pierluigi Rigo
  • Patent number: 7635776
    Abstract: A ligand represented by the formula (1): R1R2N-Q1-X-Q2-NR3R4??(1) wherein R1, R2, R3 and R4 are each the same or different and represent a group represented by the formula (2): wherein Q3 is an optionally substituted alkylene group, an optionally substituted cycloalkylene group, an optionally substituted arylene group, or an optionally substituted divalent heterocyclic group, R5 is an optionally substituted alkyl group, an optionally substituted aryl group or an optionally substituted heterocyclic group and R6 is a substituent which may coordinate or bind to a metal atom, or R5 and R6, taken together, may form a ring, Q1 and Q2 are each the same or different and represent an optionally substituted alkylene group or a single bond, and X is a divalent spacer.
    Type: Grant
    Filed: February 4, 2004
    Date of Patent: December 22, 2009
    Assignee: Takasago International Corporation
    Inventors: Kazushi Mashima, Koji Ohno, Kazuhiko Matsumura
  • Patent number: 7632576
    Abstract: Light emitting devices are incorporate, as the light emitting element, a dendrimer of which the constituent dendrons include a conjugated dendritic structure comprising aryl and/or heteroaryl groups connected to each other via bonds between sp2 hybridized ring atoms of said aryl or heteroaryl groups.
    Type: Grant
    Filed: February 20, 2002
    Date of Patent: December 15, 2009
    Assignees: Isis Innovation Limited, The University Court of the University of St. Andrews
    Inventors: Paul Leslie Burn, Ifor David Samuel, Shih-Chun Lo
  • Patent number: 7632827
    Abstract: Gold(III) phosphine complexes [Aum(CNC)mL]n+ (where HCNCH=2,6-diphenylpyridine) and their use as anti-tumor agents are disclosed. Notable results for the appearance of new potential anti-tumor application of these gold(III) complexes are reported. The described complexes show promising cytotoxic properties toward cancer cells in both in vitro and in vivo studies.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: December 15, 2009
    Assignee: The University of Hong Kong
    Inventors: Chi Ming Che, Raymond Wai Yin Sun, Zhen Fan Yang, Carrie Ka Lei Li
  • Patent number: 7632772
    Abstract: The invention relates to novel carbene ligands and their incorporated monomeric and resin/polymer linked ruthenium catalysts, which are recyclable and highly active for olefin metathesis reactions. It is disclosed that significant electronic effect of different substituted 2-alkoxybenzylidene ligands on the catalytic activity and stability of corresponding carbene ruthenium complexes, some of novel ruthenium complexes in the invention can be broadly used as catalysts highly efficient for olefin metathesis reactions, particularly in ring-closing (RCM), ring-opening (ROM), ring-opening metathesis polymerization (ROMP) and cross metathesis (CM) in high yield. The invention also relates to preparation of new ruthenium complexes and the use in metathesis.
    Type: Grant
    Filed: July 3, 2006
    Date of Patent: December 15, 2009
    Inventor: Zheng-Yun James Zhan
  • Patent number: 7626115
    Abstract: Disclosed are a novel dye, having a dispersant functional group to simultaneously exhibit a dye function and a dispersant function, and a dye-sensitized solar cell including the same. According to this invention, the dye may simultaneously manifest a dye function for absorbing light, made possible by being adsorbed on the entire surface of metal oxide particles, to thus produce excited electrons which are then transferred into a conduction band of metal oxide, and a dispersant function for preventing the agglomeration of the particles to thus improve the uniformity of the metal oxide particles in a paste and film density.
    Type: Grant
    Filed: November 16, 2006
    Date of Patent: December 1, 2009
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Eun Sung Lee, Won Cheol Jung, Sang Cheol Park, Young Jun Park, Jung Gyu Nam, Jin Young Bae
  • Publication number: 20090292123
    Abstract: A ligand contains: a benzimidazole skeleton; and functional groups at the 5-position and the 6-position of the benzimidazole skeleton. The functional group is capable of forming a coordinate bond with a metal, and contains a nitrogen atom.
    Type: Application
    Filed: May 21, 2009
    Publication date: November 26, 2009
    Applicant: FUJITSU LIMITED
    Inventors: Toshio Manabe, Fumio Takei
  • Patent number: 7615633
    Abstract: An organic electroluminescent device, which has a pair of electrodes, and at least one organic layer including a luminescent layer between the electrodes, wherein the organic layer contains at least one compound of formula (I): wherein Q11 are atoms for forming a nitrogen-containing hetero ring; Z11 to Z13 each independently represents CR, wherein R represents a substituent, CH or N; n11 is 0 or 1; M11 is a metal or boron ion that may further have a ligand(s); and a compound of formula (6): wherein R63 to R66 each is a hydrogen atom or a substituent; X61 to X64 and Z61 to Z66 each is CR, wherein R represents a substituent, CH or N.
    Type: Grant
    Filed: May 7, 2004
    Date of Patent: November 10, 2009
    Assignee: FUJIFILM Corporation
    Inventors: Tatsuya Igarashi, Kousuke Watanabe, Seiji Ichijima, Toshihiro Ise
  • Patent number: 7615636
    Abstract: A ruthenium complex is provided. The ruthenium complex is represented by the following Formula (I): in which, X is a monodentate anion ligand, R1, R2, R4 and R5 are the same or different substituents and represent alkyl, alkoxy, aminoalkyl, haloalkanes or substituted phenyl group, carboxylic acid group or acid radical salt thereof, sulfonic acid group or acid radical salt thereof, phosphoric acid group or acid radical salt thereof or hydrogen atom. R3 represents perhalogenated alkyl group, alkoxy, alkyl, amino, halogens, or hydrogen atom. The ruthenium complexes are suitable for being used as dye-sensitizers for fabricating dye-sensitized solar cells.
    Type: Grant
    Filed: November 14, 2007
    Date of Patent: November 10, 2009
    Assignee: Industrial Technology Research Institute
    Inventors: Ching-Yen Wei, Chao-Ining Yu, Fu-Ching Tung, Yun Chi, Hsing-Yi Chen, I-Hui Lin
  • Patent number: 7615637
    Abstract: Novel transition metal complexes of iron, cobalt, ruthenium, osmium, and vanadium are described. The transition metal complexes can be used as redox mediators in enzyme-based electrochemical sensors. The transition metal complexes include substituted or unsubstituted (pyridyl)imidazole ligands. Transition metal complexes attached to polymeric backbones are also described.
    Type: Grant
    Filed: November 12, 2008
    Date of Patent: November 10, 2009
    Assignee: Abbott Diabetes Care Inc.
    Inventors: Fei Mao, Adam Heller
  • Publication number: 20090275714
    Abstract: The invention relates to novel metathesis catalysts of the formula a process for making the same and their use in metathesis reactions such as ring closing or cross metathesis. The invention further relates to a process for the manufacture of a macrocyclic compound of formula VII which have the potential to be useful as HCV protease inhibitors.
    Type: Application
    Filed: April 10, 2009
    Publication date: November 5, 2009
    Inventors: Kurt Puentener, Michelangelo Scalone
  • Publication number: 20090269541
    Abstract: An optical recording material comprising at least one kind of chalcone type compound represented by the following general formula (I) or a metal complex using the chalcone type compound as a ligand: wherein ring A represents a 5- or 6-membered heterocyclic ring or an aromatic ring; ring B represents a 5- or 6-membered heterocyclic ring, an aromatic ring, or a metallocene structure; the above-mentioned heterocyclic and aromatic ring may be condensed with other rings or may be substituted; n is 0 or 1.
    Type: Application
    Filed: April 24, 2007
    Publication date: October 29, 2009
    Applicant: ADEKA CORPORATION
    Inventors: Toru Yano, Yohei Aoyama
  • Publication number: 20090264609
    Abstract: The present invention discloses single site catalyst systems having scorpion-like three dimensional structure that are suitable for oligomerising or polymerising ethylene and alpha-olefins.
    Type: Application
    Filed: July 6, 2006
    Publication date: October 22, 2009
    Inventors: Caroline Hillairet, Guillaume Michaud, Sirol Sabine
  • Patent number: RE41209
    Abstract: Platinum complexes of formula Ia or Ib where each A, is a leaving group and may be the same or different, which is suitably halo, especially chloro, hydroxy, carboxylate or together form a bi-dentate carboxylate or sulphate, each B, which may be the same or different, is halo, hydroxy, carboxylate, carbamate or carbonate ester, Z is a substituted amine wherein the substituent sterically hinders access of the Pt atom to a DNA strand of a tumour cell, and X is NH3 or mono- or di-alkyl substituted NH3, are active against cancer cells, and appear to show a unique form of chemical and biological action.
    Type: Grant
    Filed: May 8, 2009
    Date of Patent: April 6, 2010
    Assignees: Genzyme Corporation, The Institute of Cancer Research
    Inventor: Barry Murrer