Three Or More Chalcogens Containing Patents (Class 546/57)
  • Publication number: 20140326164
    Abstract: A method for preparing a surface modified organic pigment includes the steps of a) reacting the organic pigment in an aromatic hydrocarbon solvent with a surface modifying reagent to form a surface modified organic pigment; and b) washing and drying the surface modified organic pigment; wherein the surface modifying reagent is represented by Formula (I): wherein, X is selected from the group consisting of O, S and N—R3; Y is selected from the group consisting of —O and NR4; R1 to R4 are each independently selected from the group consisting of hydrogen, an alkyl group, an alkenyl group, an alkynyl group, a -aralkyl group, an alkaryl group, and an aryl group and s heteroaryl group; with the proviso that when Y—R1 is different from OH that at least one of R2 to R4 is substituted by at least one functional group having a pKa between 2.5 and 9.
    Type: Application
    Filed: November 21, 2012
    Publication date: November 6, 2014
    Applicant: AGFA GRAPHICS NV
    Inventors: Johan Loccufier, Nicolas Vriamont, Paul Callant
  • Patent number: 8614317
    Abstract: The invention concerns the production of quinoline compounds containing sulfonic acid groups, the said quinoline compounds and their conversion into dyes containing sulfonic acid groups. The dyes according to the invention are used especially to label analytes, for example to label biomolecules.
    Type: Grant
    Filed: March 25, 2011
    Date of Patent: December 24, 2013
    Assignee: Atto-Tec GmbH
    Inventors: Alexander Zilles, Jutta Arden-Jacob, Karl-Heinz Drexhage, Norbert Uwe Kemnitzer, Monika Hamers-Schneider
  • Patent number: 8334387
    Abstract: The present invention relates to compounds useful for measuring aromatase activity. The invention further provides methods for measuring aromatase activity and for screening test agents which modulate aromatase activity. A kit is also provided for use in such screening methods.
    Type: Grant
    Filed: September 28, 2010
    Date of Patent: December 18, 2012
    Assignee: GE Healthcare UK Limited
    Inventors: John Gerard Whateley, Rahman Aziz Ismail, Peter Gordon Laughton
  • Publication number: 20110190486
    Abstract: The invention concerns the production of quinoline compounds containing sulfonic acid groups, the said quinoline compounds and their conversion into dyes containing sulfonic acid groups. The dyes according to the invention are used especially to label analytes, for example to label biomolecules.
    Type: Application
    Filed: March 25, 2011
    Publication date: August 4, 2011
    Applicant: ATTO-TEC GMBH
    Inventors: Alexander Zilles, Jutta Arden-Jacob, Karl-Heinz Drexhage, Norbert Uwe Kemnitzer, Monika Hamers-Schneider
  • Publication number: 20110172420
    Abstract: The invention concerns the production of quinoline compounds containing sulfonic acid groups, the said quinoline compounds and their conversion into dyes containing sulfonic acid groups. The dyes according to the invention are used especially to label analytes, for example to label biomolecules.
    Type: Application
    Filed: March 25, 2011
    Publication date: July 14, 2011
    Applicant: ATTO-TEC GMBH
    Inventors: Alexander Zilles, Jutta Arden-Jacob, Karl-Heinz Drexhage, Norbert Uwe Kemnitzer, Monika Hamers-Schneider
  • Publication number: 20100092887
    Abstract: Use of quinacridones of the formula (I) in which A is an organic radical substituted by one or more fluorine atoms, B is H, F, Cl, Br or an optionally substituted organic radical which may optionally together with A form a ring in colour filters for LCDs.
    Type: Application
    Filed: May 19, 2009
    Publication date: April 15, 2010
    Applicant: LANXESS DEUTSCHLAND GMBH
    Inventors: ULRICH FELDHUES, FRANK LINKE, STEPHAN MICHAELIS, DIRK PFUETZENREUTER, HORST BERNETH, MEINHARD ROLF
  • Publication number: 20090101890
    Abstract: A novel semiconductor device comprises an azaperylene organic semiconductor of the formula I (I) wherein each of R1, R2, R3 and R4 independently is selected from H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl, halogen, Si(RH)3, XR6; or one or more of R1 and R2, R2 and R3, R3 and R4, together with the carbon atoms they are bonding to, form a saturated or unsaturated, unsubstituted or substituted carbocyclic or heterocyclic ring; R5 is OR7, SR7, NR7R8, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, or unsubstituted or substituted aryl; R6 is Si(R11)3, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl; R7 is H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl
    Type: Application
    Filed: May 3, 2006
    Publication date: April 23, 2009
    Inventors: Frank Bienewald, Beat Schmidhalter, Ulrich Berens, Hans Jurg Kirner
  • Publication number: 20090074825
    Abstract: The present invention includes methods, articles, compositions and colorant dyes and pigments that include biocidal N-halamine dye composition having two or more heterocyclic ring structures attached to one or more N-halamine groups, wherein one or more halogens associate with the one or more one or more N-halamine groups to affect biocidal activity.
    Type: Application
    Filed: September 19, 2008
    Publication date: March 19, 2009
    Applicant: Board of Regents, The University of Texas System
    Inventors: Yuyu Sun, Jie Luo
  • Publication number: 20080185577
    Abstract: Diimide-based semiconductor materials are provided with processes for preparing the same. Composites and electronic devices including the diimide-based semiconductor materials also are provided.
    Type: Application
    Filed: November 19, 2007
    Publication date: August 7, 2008
    Inventors: Antonio Facchetti, Tobin J. Marks, He Yan
  • Patent number: 7294287
    Abstract: Tetrahydro- and dihydroquinophenanthrine dione fluorescent whitening agents and a process for their preparation are provided.
    Type: Grant
    Filed: September 1, 2006
    Date of Patent: November 13, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Damien Thurber Cole, Kevin Rodney Gerzevske
  • Patent number: 6972333
    Abstract: A process for by oxidizing a quinacridone in a liquid medium with a non-metal oxidant producing a quinacridonequinone.
    Type: Grant
    Filed: January 14, 2004
    Date of Patent: December 6, 2005
    Assignee: Sun Chemical Corporation
    Inventors: Edward H. Sung, James Z. Dong, George H. Robertson
  • Patent number: 6864371
    Abstract: A novel method for the preparation of a beta quinacridone pigment is described by the oxidation of 6,13-dihydroquinacridone in the presence of polyvinyl pyrrolidone, a catalyst and optionally a particulate quinacridone or particle growth inhibitor using hydrogen peroxide as the oxidant.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: March 8, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fridolin Bäbler
  • Patent number: 6664396
    Abstract: Disclosed is a process for forming a N,N′-diarylquinacridone compound comprising the step of reacting a N,N′-unsubstituted quinacridone compound with a haloaryl compound in the presence of a metal or metal compound to arylate the N and N′ positions and form the corresponding N,N′-diarylquinacridone compound. The process is versatile and provides high yields and purity for the synthesis of N,N′-diarylquinacridone compounds.
    Type: Grant
    Filed: February 24, 2003
    Date of Patent: December 16, 2003
    Assignee: Eastman Kodak Company
    Inventor: Lelia Cosimbescu
  • Patent number: 6626990
    Abstract: The present invention relates to a process for producing alpha, gamma-I, gamma-II and gamma-III crystal modifications of quinacridone and transparent quinacridone pigments including the solid solutions of various quinacridones, using a variety of tris-aryl-s-triazines, particularly resorcinol triazine derivatives, or aromatic- or heteraromatic-compounds having at least one hydroxyl or keto group bonded to the ring, as an additive, prior to or concurrently with the oxidation of corresponding dihydroquinacridone salts.
    Type: Grant
    Filed: March 18, 2002
    Date of Patent: September 30, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Shivakumar Basalingappa Hendi, Suruliappa Gowder Jeganathan, James Barry Ganci
  • Patent number: 6406533
    Abstract: A 6,13-dihydroquinacridone derivative of formula I: (MO3S)m—Q—[CH2—(X)—(Y)n]o  (I) wherein: Q represents a 6,13-dihydroquinacridone moiety of formula II; A and B each independently represent a substituent selected from H, F, Cl, C1-C3alkyl and C1-C3alkoxy M represents a metal cation, quaternary N cation or H; X is an aromatic group, a cyclo-hetero aliphatic group with at least one 5 or 6 atom ring or a hetero aromatic group with at least one 5 or 6 atom ring and which is not a phthalimido group; Y is a sulfonic or carboxylic acid or salt thereof; m and n independently from each other are numbers from zero to 2.5; and o is a number from zero to 4, wherein m and o are not zero simultaneously.
    Type: Grant
    Filed: March 7, 2001
    Date of Patent: June 18, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fridolin Bäbler
  • Patent number: 6365594
    Abstract: Heterocycle-condensed morphinoid derivatives of formula (I), or solvates or salts thereof, are potent and selective delta opioid agonists and antagonists and are useful as i.a. analgesics. Pharmaceutical compositions containing such compounds, the use of such compounds as therapeutic agents, a method of treatment comprising the administration of such compounds, and a process for the preparation of such compounds are also described.
    Type: Grant
    Filed: February 22, 1999
    Date of Patent: April 2, 2002
    Assignee: SmithKline Beecham S.p.A.
    Inventors: Giulio Dondio, Silvano Ronzoni, Pier Andrea Gatti, Davide Graziani
  • Patent number: 6323342
    Abstract: A new gamma-I type quinacridone pigment characterized by C.I.E color space values in masstone, and a process for its preparation is disclosed. The new gamma quinacridone pigment is especially useful for coloring coating compositions, such as automotive paints, and plastics.
    Type: Grant
    Filed: July 26, 2000
    Date of Patent: November 27, 2001
    Assignee: Ciba Specialty Chemicals Corp.
    Inventor: Fridolin Bäbler
  • Patent number: 6313300
    Abstract: A process for preparing an unsubstituted or substituted quinacridone of the formula or a solid solution of quinacridones of the formula (I), wherein X and Y are independently 1 or 2 substituents selected from hydrogen, fluorine, chlorine, C1-C3alkyl, C1-C3alkoxy and COOR wherein R is hydrogen or C1-C10alkyl in which a salt of a corresponding 6,13-dihydroquinacridone of formula II  having the same substitutions as the desired quinacridone of formula I, or a mixture of corresponding 6,13-dihydroquinacridones of formula II, is oxidized with an oxygen containing gas in the presence of an aqueous base and a catalytically effective amount of an oxidation catalyst, characterized in that the oxidation is performed in the presence of an polyglycolic reaction medium of formula R1—O—[(CH2)m—(CHR1′)n—O]x—O—R1″  (III).
    Type: Grant
    Filed: August 14, 2000
    Date of Patent: November 6, 2001
    Assignee: Ciba Specialty Chemicals Corp.
    Inventor: Shivakumar Basalingappa Hendi
  • Patent number: 6274728
    Abstract: Compounds of formula A(B)x  (I), wherein x is an integer from 1 to 8, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, indanthrone, isoindolinone, isoindoline, dioxazine, azo, phthalocyanine or diketopyrrolopyrrole series that is bonded to x groups B via one or more hetero atoms, those hetero atoms being selected from the group consisting of N, O and S and forming part of the radical A, each group B independently of any other(s) is hydrogen or a group of the formula  at least one group B being a group of the formula The compounds according to the invention are used in high-molecular-weight organic materials, thermo-, photo- or chemo-sensitive recording materials, light-sensitive negative or positive resist compositions, ink compositions for ink-jet printing and color tapes for thermal transfer printing.
    Type: Grant
    Filed: December 16, 1999
    Date of Patent: August 14, 2001
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Véronique Hall-Goulle, Aline Bize
  • Patent number: 6264733
    Abstract: Pigment particle growth and/or crystal phase directors of the following formula: (MO3S)m—Q—(CH2—(X)—(Y)n)o wherein: Q represents a pigment moiety; M represents a metal cation, quaternary N cation or H; X is an aromatic group, a cyclo-hetero aliphatic group with at least one 5 atom or 6 atom ring or a hetero aromatic group with at least one 6 atom ring and which is not a phthalimido group; Y is a sulfonic or carboxylic acid or salt thereof; m and n independently from each other represent an integer from 0 to 2.5; and o is an integer from 0.05 to 4.
    Type: Grant
    Filed: February 2, 2000
    Date of Patent: July 24, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fridolin Bäbler
  • Patent number: 6090196
    Abstract: A new beta quinacridone pigment characterized by masstone and tint reflection spectra, and a process for its preparation is disclosed. The new beta quinacridone pigment is especially useful for coloring coating compositions, such as automotive paints, and plastics. Also disclosed is a new pigment composition consisting of the inventive beta quinacridone pigment and a carbazole dioxazine pigment.
    Type: Grant
    Filed: April 24, 1998
    Date of Patent: July 18, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fridolin Babler
  • Patent number: 6063924
    Abstract: Compounds of formulaA(B).sub.x (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine, diketopyrrolopyrrole or azo series, which radical A contains x N-atoms linked with B, preferably with at least one immediately adjacent or conjugated carbonyl group.B is a group of formula ##STR1## and, if x=2, 3 or 4, can also be one, two or three hydrogen atom(s), and wherein Q is a group of formula ##STR2## These soluble chromophores can be readily converted to the corresponding pigments by heating, even in the substrate into which they can be incorporated without any difficulty in dissolved form.R.sub.1 -R.sub.9 are as defined herein.
    Type: Grant
    Filed: July 22, 1996
    Date of Patent: May 16, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Veronique Hall-Goulle
  • Patent number: 6031100
    Abstract: This invention relates to a process for the preparation of quinacridone pigments by(a) exposing a reaction mixture containing(i) 2,5-dianilinoterephthalic acid, 2,5-dianilino-3,6-dihydroterephthalic acid, 2,5-dianilino-3,6-dioxo-1,4-cyclohexadiene-1,4-dicarboxylic acid, and/or derivatives thereof,(ii) about 3 to about 20 parts by weight, per part of component (a)(i), of a dehydrating agent, and(iii) 0 to about 20 parts by weight, per part of component (a)(i), of a pigment additive,to microwave radiation under conditions that raise the bulk temperature of the reaction mixture to no more than about 250.degree. C.
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: February 29, 2000
    Assignee: Bayer Corporation
    Inventor: Ibraheem T. Badejo
  • Patent number: 5840901
    Abstract: The present invention relates to a process of preparing quinacridone by oxidizing a 6,13-dihydroquinacridone salt corresponding to the quinacridone pigment with hydrogen peroxide as the oxidizing agent. The inventive process is economical and environmentally friendly and yields high performance quinacridone pigments in a high yield.
    Type: Grant
    Filed: August 13, 1997
    Date of Patent: November 24, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fridolin Babler
  • Patent number: 5725651
    Abstract: Mono-N-alkyl-quinacridone pigments are disclosed. They exhibit high light fastness, high temperature stability and high migration fastness. Moreover, they show hypsochromic shifts, fluorescence and high photoconductivity. These pigments are suited for coloring high molecular weight organic materials, for use as light emitting materials of organic electroluminescent elements as well as photoreceptors of electrophotography.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: March 10, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: John Zambounis, Jin Mizuguchi
  • Patent number: 5561232
    Abstract: Compounds of formulaA(B).sub.x, (I),whereinx is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m and n, are as defined in claim 1. These carbamate group-containing soluble chromophores am distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: October 1, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Zhimin Hao, John S. Zambounis, Abul Iqbal
  • Patent number: 5496405
    Abstract: This invention relates to a process for the preparation of quinacridone pigments comprising(a) heating, at a temperature of about 80.degree. C. to about 145.degree. C., a reaction mixture comprising(i) 2,5-dianilinoterephthalic acid or a 2,5-dianilinoterephthalic acid derivative having one or more substituents in at least one aniline ring,(ii) about 2 to about 10 parts by weight, relative to component (a)(i), of a dehydrating agent, and(iii) about 0.01 to about 10 percent by weight, relative to component (a)(i), of a salt other than an iron salt;(b) drowning the reaction mixture from step (a) by adding said reaction mixture to about 3 to about 15 parts by weight, relative to component (a)(i), of a liquid in which the pigment is substantially insoluble;(c) isolating the quinacridone pigment; and(d) optionally, conditioning the quinacridone pigment.
    Type: Grant
    Filed: December 6, 1994
    Date of Patent: March 5, 1996
    Assignee: Bayer Corporation
    Inventors: Margot Campos, Guenter Franke, Michael J. Greene
  • Patent number: 5491235
    Abstract: This invention relates to a process for the preparation of quinacridone pigments comprising(a) heating, at a temperature of about 80.degree. C. to about 145.degree. C., a reaction mixture comprising(i) 2,5-dianilinoterephthalic acid or a 2,5-dianilinoterephthalic acid derivative having one or more substituents in at least one aniline ring,(ii) about 2 to about 10 parts by weight, relative to component (i), of a strong acid, and(iii) at least about 0.4 mole percent, relative to component (i), of iron in the form of an iron salt;(b) drowning the reaction mixture from step (a) by adding said reaction mixture to about 3 to about 15 pads by weight, relative to component (i), of a liquid in which the pigment is substantially insoluble;(c) isolating the quinacridone pigment; and(d) optionally, conditioning the quinacridone pigment.
    Type: Grant
    Filed: May 6, 1994
    Date of Patent: February 13, 1996
    Assignee: Bayer Corporation
    Inventors: Margot Campos, Dirk Pfuetzenreuter, Guenter Franke, Michael J. Greene
  • Patent number: 5441956
    Type: Grant
    Filed: January 5, 1994
    Date of Patent: August 15, 1995
    Assignee: Smithkline Beecham Farmaceutici S.p.A.
    Inventors: Vittorio Vecchietti, Giulio Dondio, Silvano Ronzoni, Roberto Colle
  • Patent number: 5368641
    Abstract: A process for the preparation of 2,9-dimethylquinacridone pigments or mixed crystal pigments or mixtures of 2,9-dimethylquinacridone and quinacridones which in the two outer fused benzene rings can be substituted, characterized by the form of their crystalline particles having an average ratio of length to width of <2:1 and an average particle size of <0.4 .mu.m, by adding to the solution of 2,9-dimethylquinacridone before or during the finishing of the corresponding crude quinacridones of the quinacridones mentioned in water or solvent mixtures at temperatures from about 60.degree. to about 200.degree. C., in each case a compound of the general formula (I) ##STR1## in an amount of about 1 to 20% by weight, in which Q is a quinacridone radical which is unsubstituted or substituted, Y is an --NR.sup.4 R.sup.5 group or the radical of a five-, six- or seven-membered heterocycle which contains one to three hetero atoms and can be substituted, R and R' are hydrogen or alkyl, and R.sup.1 to R.sup.
    Type: Grant
    Filed: December 22, 1992
    Date of Patent: November 29, 1994
    Assignee: Hoechst AG
    Inventors: Erwin Dietz, Adolf Kroh
  • Patent number: 5281269
    Abstract: Aqueous processes for the preparation of a new beta quinacridone modification possessing a magenta color having C.I.E. color space values in masstone of L=33-36, A=34-40 and B=8-15 starting with the crude pigment and comprising several milling and alternative deaggregation and recrystallization steps, the latter being facilitated at elevated temperatures aided by the presence of base and minor amounts of crystal growth auxiliaries, and the beta quinacridone modification having the indicated C.I.E. color space values.
    Type: Grant
    Filed: September 14, 1992
    Date of Patent: January 25, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: James B. Ganci, Shivakumar B. Hendi, Walter C. Zukowski
  • Patent number: 5137576
    Abstract: Quinacridones having selectively adjusted triboelectric effects, which quinacridones contain about 0.05% to 100 percent by weight of triboelectrically active compounds of the general formula IQ--A--Y].sub.n (I),in which Q is a quinacridone radical which is unsubstituted or substituted by halogen atoms, alkyl, alkoxy H.sub.2 N--CO--, alkyl--NH--CO-- or (alkyl).sub.2 N--CO groups, A is a direct bond or --O--, --S--, --NR.sup.1 --, --CO--, --SO.sub.2 --, --CR.sup.2 R.sup.3 -- or arylene and Y is an --NR.sup.4 R.sup.5 group or a five-, six- or seven-membered heterocycle which contains one to three heteroatoms from the series comprising nitrogen and/or oxygen and/or sulfur and which can be substituted by alkyl, alkoxy, hydroxyphenyl, halogen, --CN, --COOH, --CO-- NRR', --SO.sub.2 --NRR', hydroxyalkyl or alkylaminoalkyl, in which R and R' together with the nitrogen atom can be a heterocycle, R and R' are hydrogen atoms or alkyl and R.sup.1 to R.sup.
    Type: Grant
    Filed: September 28, 1989
    Date of Patent: August 11, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans-Tobias Macholdt, Adolf Kroh, Alexander Sieber, Erwin Dietz
  • Patent number: 4956464
    Abstract: Dihydroquinacridones, quinacridones and quinacridonequinones are prepared by cyclizing 2,5-dianilino-3,6-dihydroterephthalic acid derivatives or 2,5-dianilinoterephthalic acid derivatives in the liquid or solid state or in solution, in each case in finely divided form, or in the gas phase, in the presence or absence of an oxidizing agent.
    Type: Grant
    Filed: October 27, 1988
    Date of Patent: September 11, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Bender, Horst Colberg, Friedhelm Teich, Reinhard Kemper
  • Patent number: 4881980
    Abstract: Pigments of the quinacridonequinone series consisting of 98-20 mol percent of a quinacridonequinone of the general formula (1) ##STR1## in which R denotes a hydrogen or chlorine atom or a methyl or carbonamide group and m and n are 1 or 2, and 1-65 mol percent of a quinacridone of the general formula (2) ##STR2## in which R, m and n have the abovementioned meaning, and 1-15 mol percent of one or two acridone derivatives of the general formulae (3) and/or (4) ##STR3## in which X denotes O or NH and R can be identical or different and, like m and n, has the abovementioned meaning, the added compounds of the general formulae (2), (3) and/or (4) being predominantly incorporated into the crystal lattice if the quinacridonequinone of the general formula (1), processes for their preparation and their use for coloring synthetic and naturally occurring materials.
    Type: Grant
    Filed: July 9, 1987
    Date of Patent: November 21, 1989
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Erwin Dietz, Frank Prokschy
  • Patent number: 4812568
    Abstract: Process for the preparation of a 6,13-dihydroquinacridone of the general formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 designate hydrogen or substituents customary for quinacridone, characterized in that an optionally substituted dialkyl 2,5-di-(phenylamino)-3,6-dihydroterephthalate is heated to temperatures of 240.degree.-320.degree. C. in an essentially oxygen-free atmosphere in the presence of a dimethyl-diphenyl ether isomer mixture of the formula ##STR2## as the solvent and/or diluent, and a process for the preparation of optionally substituted quinacridone, characterized in that the resulting 6,13-dihydroquinacridone is oxidized in the customary manner.
    Type: Grant
    Filed: February 10, 1987
    Date of Patent: March 14, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Herzog, Detlef-Ingo Schutze, Jurgen Schneider, Reinold Schmitz
  • Patent number: 4801702
    Abstract: A process for the preparation and conditioning of organic pigments, which comprises the use of at least one tricyclodecane alcohol or tricyclodecene alcohol.
    Type: Grant
    Filed: October 30, 1986
    Date of Patent: January 31, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Fridolin Babler
  • Patent number: 4760004
    Abstract: Compounds of the formulae I, II and III ##STR1## in which R is --F, --Cl, --Br, C.sub.1 -C.sub.18 alkoxy, and n is the number 0, 1, 2 or 3, are suitable in particular for use as photoconductive substances.
    Type: Grant
    Filed: November 12, 1987
    Date of Patent: July 26, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Alain C. Rochat, Edward E. Jaffe, Jin Mizuguchi
  • Patent number: 4758664
    Abstract: Process for the preparation of linear quinacridones of the formula (1) ##STR1## in which R denotes a hydrogen, fluorine, chlorine or bromine atom or a C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.3 -alkoxy or phenyl group or a fused benzene ring or a phenylamino or phenoxy group which can be substituted on the aromatic nucleus by fluorine, chlorine or bromine atoms or C.sub.1 -C.sub.4 -alkyl groups, and n denotes a number from 0 to 2, it being possible, in the event that n.noteq.0, for the substituents R present on the same benzene ring or on the two benzene rings to be identical or different, by the oxidation of linear 6,13-dihydroquinacridones of the formula (2) ##STR2## in which R and n have the meanings mentioned above, which comprises heating, at temperatures from about 180.degree. C. to about 280.degree. C., 1 mole of the last-mentioned compounds with 1 to 2 moles of iodine in a high-boiling organic solvent which is inert towards the reactants.
    Type: Grant
    Filed: May 1, 1986
    Date of Patent: July 19, 1988
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ernst Spietschka, Frank Prokschy
  • Patent number: 4634708
    Abstract: 4,6,6a,7,8,12b-hexahydro-indolo[4,3-ab]phenanthridines are useful as dopaminergic and analgesic agents.
    Type: Grant
    Filed: January 25, 1985
    Date of Patent: January 6, 1987
    Assignee: Sandoz Ltd.
    Inventors: Alexander Hagenbach, Max P. Seiler, Hans J. Wuthrich
  • Patent number: 4541872
    Abstract: Finished grade pigments are prepared from crude pigment precursors by conversion to aggregated low crystallinity pigment followed by milling the aggregated low crystallinity pigment in water having a pH of from 7 to 14 and from 5 to 25% based on pigment of a separate phase comprising an organic liquid which is effective in growing and improving the crystallinity of the pigment particles. The resulting material is extracted in dilute acid, washed free of acid and dried to produce the final finished grade pigment.
    Type: Grant
    Filed: March 26, 1984
    Date of Patent: September 17, 1985
    Assignee: Ciba-Ceigy Corporation
    Inventor: Edward E. Jaffe
  • Patent number: 4455173
    Abstract: Pigmentary grade quinacridone pigments are prepared from crude quinacridone by conversion to aggregated low crystallinity quinacridones followed by milling the aggregated low crystallinity quinacridone in the presence of a liquid which wets the pigment and can improve the crystallinity of quinacridone at 10.degree. to 60.degree. C. Suitable quinacridones include ##STR1## and mixtures thereof with up to 15 wt. % of ##STR2## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 R.sup.6 are hydrogen, fluorine, chlorine, bromine, methyl or methoxy; R.sup.7, R.sup.9 and R.sup.10 are hydrogen or chlorine; and R.sup.8 is hydrogen, chlorine, bromine, nitro, alkyl groups of 1 to 5 carbon atoms, alkoxy groups of 1 or 2 carbon atoms or benzoylamino, and m is an integer of from 1 to 4.
    Type: Grant
    Filed: April 16, 1982
    Date of Patent: June 19, 1984
    Assignee: E. I. Du Pont De Nemours and Company
    Inventor: Edward E. Jaffe
  • Patent number: 4400515
    Abstract: Compositions of linear trans-quinacridones containing at least one component (I) selected from unsubstituted, chloro- and methyl-substituted quinacridone and at least one component (II) selected from bis-(carbamoyl)-quinacridones, the carbamoyl groups of which are unsubstituted, N-mono-alkyl substituted or N,N-dialkyl-substituted, are pigments useful for coloring plastics and especially lacquers. These compositions are preferably prepared by joint ring closure of the corresponding 2,5-dianilino-terephthalic acids or esters.
    Type: Grant
    Filed: February 23, 1981
    Date of Patent: August 23, 1983
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Otto Fuchs, Adolf Kroh
  • Patent number: 4289892
    Abstract: Active hydrogen-containing fluorochemical is used as a foam stabilizer for polyurethane foams. For example, rigid or flexible polyurethane foams with high or low density and uniform cellular structure are prepared using fluoroaliphatic radical-substituted poly(oxyalkylene) polyols as foam stabilizers.
    Type: Grant
    Filed: April 30, 1979
    Date of Patent: September 15, 1981
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Fredrich A. Soch
  • Patent number: 4247695
    Abstract: A process for preparing beta or gamma crystals of linear quinacridone, substituted quinacridone or solid solutions thereof by contacting premilled quinacridone with 45-60% by weight sulfuric acid and 0-10% by weight of a surfactant based on the quinacridone at a weight ratio of acid to quinacridone of 3:1-6:1 to form a slurry, agitating said slurry for a period of time at 45.degree.-75.degree. C., adding water to form a dilute slurry, agitating said dilute slurry for a period of time at 75.degree.-95.degree. C. and separating quinacridone from the liquid of the dilute slurry.
    Type: Grant
    Filed: February 26, 1979
    Date of Patent: January 27, 1981
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Patrick H. Fitzgerald
  • Patent number: 4233206
    Abstract: A process for the production of a colored polyolefin molded articles comprising adding to a polyolefin either a compound of the formula D--CH.sub.2 O.OC--R]).sub.n as a colorant wherein D is the residue of a common organic pigment, R is an alkyl, alkenyl or aryl group having up to 20 carbon atoms and n is an integer of 1-4, or a mixture of the compound of the above formula with at least one usual pigment, to form a mixture, and then molding the mixture thereby producing the desired colored articles. This invention also relates to the compound of said formula and to a mixture thereof with at least one common pigment.
    Type: Grant
    Filed: November 6, 1975
    Date of Patent: November 11, 1980
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Hiromitsu Katsura, Morihiko Endo, Takashi Kanno