Chalcogen Attached Indirectly To The Thiazole Ring By Nonionic Bonding Patents (Class 548/169)
  • Patent number: 4340740
    Abstract: An alpha-thio-alpha-aryl-substituted alkanonitrile of the general formula ##STR1## wherein Ar represents an aromatic group, R represents a hydrogen atom or an alkyl group, R.sup.1 represents an alkyl group or an aromatic group, and Y represents an oxygen atom or a carbonyl group. The above compound can be prepared by reacting an alpha-aryl-substituted-alpha-thio-acetonitrile of the general formula ##STR2## wherein Ar, Y and R.sup.1 are as defined above, with an alkylating agent in the presence of a strong base. This compound is useful as an intermediate for producing an alpha-aryl-substituted alkane-carboxylic acid of the general formula ##STR3## wherein Ar, Y and R.sup.1 are as defined above.
    Type: Grant
    Filed: July 15, 1980
    Date of Patent: July 20, 1982
    Assignee: Sagami Chemical Research Center
    Inventors: Genichi Tsuchihashi, Shuichi Mitamura, Katsuyuki Ogura
  • Patent number: 4308390
    Abstract: Sulphoalkyl and sulphoalkenyl quaternary salts of heterocyclic nitrogen compounds are prepared by reacting heterocyclic compounds containing a tertiary ring nitrogen atom at an elevated temperature with an O-sulphoalkyl or O-sulphoalkenylisourea compound.
    Type: Grant
    Filed: March 6, 1980
    Date of Patent: December 29, 1981
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Helmut Kampfer, Max Glass
  • Patent number: 4289886
    Abstract: Imides derived from 2-thioxo-3-benzothiazoline acetic and propionic have been found to be effective as herbicides and plant growth regulants. Imides derived from 2-thioxo-3-benzoxazoline acetic and propionic acid have been found to be effective plant growth regulants.
    Type: Grant
    Filed: July 5, 1979
    Date of Patent: September 15, 1981
    Assignee: Monsanto Company
    Inventor: John J. D'Amico
  • Patent number: 4287348
    Abstract: Sulphoalkyl quaternary salts of the formula ##STR1## wherein X is --O--, --Se--, --S--, --NR-- or --CR(R)--, R is hydrogen or alkyl, R.sub.1 is hydrogen, methyl or ethyl, R.sub.2 and R.sub.3 are each hydrogen or substituents or together represent the atoms necessary to complete an optionally substituted benzene ring, R.sub.4 is optionally substituted alkylene of 3 or 4 carbon atoms and n is 1 or 0, except that when n is 1, R.sub.1 cannot be hydrogen, are prepared by heating at a temperature above 80.degree. C. a heterocyclic base of the formula ##STR2## wherein X, R.sub.1, R.sub.2, R.sub.3 and n have the indicated meanings with a hydroxysulphonic acid of the formula HOR.sub.4 SO.sub.3 H.
    Type: Grant
    Filed: June 5, 1978
    Date of Patent: September 1, 1981
    Assignee: Ciba-Geigy AG
    Inventors: Rainer Kitzing, Geoffrey E. Ficken, Victor W. Dolden
  • Patent number: 4275065
    Abstract: Novel 2-substituted-3-hydroxythiazolo[2,3-b]benzo-(and azabenzo)thiazolium salts, the mesoionic didehydro derivatives thereof and related compounds are disclosed, as well as the use thereof as modulators of the immune response.
    Type: Grant
    Filed: March 31, 1980
    Date of Patent: June 23, 1981
    Assignee: American Home Products Corporation
    Inventors: Peter H. L. Wei, Francis J. Gregory
  • Patent number: 4263440
    Abstract: Heterocyclic phenyl ethers of the formula ##STR1## in which (R).sub.n is hydrogen or up to three identical or different substituents selected from halogen, CF.sub.3, NO.sub.2, CN, alkyl, alkoxy and alkylthio, and A is oxygen, sulfur or N(C.sub.1 -C.sub.4)alkyl, provided that the --OH group is not in para-position if (R).sub.n is hydrogen and A is sulfur, are useful as starting materials for the manufacture of selective herbicides.
    Type: Grant
    Filed: August 28, 1978
    Date of Patent: April 21, 1981
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Reinhard Handte
  • Patent number: 4254266
    Abstract: Fluorinated-alkyl sulfides represented by [R.sub.f (CH.sub.2).sub.n S].sub.z Q where R.sub.f is fluoroalkyl, n is 2 or 3, z is 1 or 2, and Q is an aryl, alkylaryl, alkyl heterocyclic or heterocyclic radical, are useful as surfactants or as intermediates for the preparation of salt-type, quaternary-salt, or amphoteric surfactants.
    Type: Grant
    Filed: July 30, 1979
    Date of Patent: March 3, 1981
    Assignee: Pennwalt Corporation
    Inventors: Sameeh S. Toukan, Murray Hauptschein
  • Patent number: 4180663
    Abstract: A process for the preparation of a disperse methine dye containing at least one dicyanomethylidene group comprising the steps of(A) preparing an anhydrous solution of an aldehyde formed by contacting an aromatic amine, 1,2,3,4-tetrahydroquinoline or benzomorpholine compound capable of undergoing the Vilsmeier-Haack reaction with POCl.sub.3 and a N,N-di-alkylformamide wherein the alkyl moiety is 1-4 carbon atoms;(B) subsequently adding to said solution at least one equivalent of cyanoacetamide based on the equivalents of aldehyde formed in (A), thereby forming a reaction mixture of aldehyde and in situ generated malononitrile; and(C) adjusting the pH of the solution to a point sufficient for the condensation of the aldehyde and in situ generated malononitrile to occur thereby producing a disperse methine dye.
    Type: Grant
    Filed: March 12, 1979
    Date of Patent: December 25, 1979
    Assignee: Eastman Kodak Company
    Inventor: Mark D. Frishberg
  • Patent number: 4178253
    Abstract: A lubricating oil composition comprising 0.001% to 10%, based on the total lubricating composition, of a compound of formula I: ##STR1## wherein x is an integer from 1 to 25; R, R.sup.1 and R" are the same or different and each is hydrogen, an optionally substituted straight- or branched-chain alkyl residue having from 1 to 20 carbon atoms, an alkenyl or alkynyl residue having from 2 to 12 carbon atoms, an optionally substituted cycloalkyl residue having from 3 to 12 carbon atoms, an optionally substituted aryl residue having from 6 to 10 carbon atoms, an optionally substituted aralkenyl or aralkynyl residue each having from 8 to 12 carbon atoms, an optionally substituted aralkyl residue having from 7 to 20 carbon atoms or an optionally substituted heterocyclic residue having from 3 to 10 ring members, an alkylene residue having from 2 to 12 carbon atoms, a cycloalkylene residue having from 5 to 12 carbon atoms or an arylene residue having from 6 to 10 carbon atoms; or R is the group -(S).sub.
    Type: Grant
    Filed: April 3, 1978
    Date of Patent: December 11, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter I. Lee, Brian Holt