Divalent Chalcogen Double Bonded Directly To The Phosphorus Patents (Class 558/207)
  • Patent number: 11794179
    Abstract: This invention relates generally to olefin metathesis catalysts, to the preparation of such compounds, compositions comprising such compounds, methods of using such compounds, and the use of such compounds in the metathesis of olefins and in the synthesis of related olefin metathesis catalysts. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and in industrial applications such as oil and gas, fine chemicals and pharmaceuticals.
    Type: Grant
    Filed: June 25, 2021
    Date of Patent: October 24, 2023
    Inventor: Adam M. Johns
  • Patent number: 8889760
    Abstract: Described herein is a degradable linking agent of formula Photo1-LG-Photo2, wherein Photo1 and Photo2 independently represent at least one photoreactive group and LG represents a linking group comprising one or more silicon atoms or one or more phosphorous atoms. The degradable linking agent includes a covalent linkage between at least one photoreactive group and the linking group, wherein the covalent linkage between at least one photoreactive group and the linking group is interrupted by at least one heteroatom. A method for coating a support surface with the degradable linking agent, coated support surfaces and medical devices are also described.
    Type: Grant
    Filed: March 29, 2011
    Date of Patent: November 18, 2014
    Assignee: SurModics, Inc.
    Inventors: Aleksey V. Kurdyumov, Dale G. Swan
  • Patent number: 8207367
    Abstract: The present invention relates to a method of producing a polymerizable phosphate containing at least one selected from polymerizable phosphates represented by formula (II), (III) or (IV) by a batch reaction, including a step of adding a compound represented by formula (I) into a mixture of a polymerizable phosphate reaction product containing at least one selected from polymerizable phosphates represented by formula (II), (III) or (IV), obtained by a pre-batch reaction, and phosphoric acid anhydride to react them: wherein R1 represents H or a C1-4 alkyl group, R2 represents a C2-6 alkylene group and n denotes an integer from 1 to 3.
    Type: Grant
    Filed: December 26, 2006
    Date of Patent: June 26, 2012
    Assignee: Kao Corporation
    Inventors: Minoru Kurata, Keishi Shimokawa
  • Publication number: 20110245386
    Abstract: The invention relates to a method for producing mixed-substituted dialkyiphosphinic acids, esters, and salts, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester (II) thereof, b) the obtained alkylphosphonous acid, the salt or ester (II) thereof is reacted with an olefin (IV) in the presence of a catalyst B to obtain the mixed-substituted dialkylphosphinic acid derivative (III), wherein R1, R2, R3, R4, R11, R12, R13, R14 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl, X represents H, C1-C18-alkyl, C8-C18-aryl, C6-C18-aralkyl, C8-C18-alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonated nitrogenous base, catalyst A represents transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transit
    Type: Application
    Filed: October 6, 2009
    Publication date: October 6, 2011
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Michael Hill, Werner Krause, Martin Sicken
  • Publication number: 20110237720
    Abstract: The invention relates to a method for producing mono-carboxyfunctionalized dialkylphosphinic acids and esters and salts thereof by means of vinyl compounds, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (II) thereof in the presence of a catalyst A, b) the thus obtained alkylphosphonic acid, salt or ester (II) thereof is reacted with acetylenic compounds of formula (V) to yield a mono-functionalized dialkylphosphinic acid derivative (VI) in the presence of a catalyst B, and c) the thus obtained mono-functionalized dialkylphosphinic acid derivative (VI) is reacted with carbon monoxide to yield a mono-carboxyfunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst C, wherein R1, R2, R3, R4, R5, R6 are the same or different and stand independently of each other, among other things, for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, and X and Y are the same or different and stand indepe
    Type: Application
    Filed: October 6, 2009
    Publication date: September 29, 2011
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Michael Hill, Werner Krause, Martin Sicken
  • Publication number: 20110224340
    Abstract: The invention relates to a method for producing mono-vinylfunctionalized dialkylphosphinic acids, esters, and salts, characterized in that a) a phosphinic acid source (I) is converted with olefins (IV) to an alkylphosphonic acid, salt, or ester (II) in the presence of a catalyst A, b) the alkylphosphonic acid, salt, or ester (II) thus created is converted with acetylenic compounds of formula (V) into a mono-vinylfunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst B, where R1, R2, R3, R4, R5, R6 are the same or different and are independent of each other, among other things, H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, and X stands for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonized nitrogen base, and the catalysts A and B are transition metals and/or transition metal compounds and/or catalyst systems comprised of a transition metal and/or a transitio
    Type: Application
    Filed: October 6, 2009
    Publication date: September 15, 2011
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Michael Hill, Werner Krause, Martin Sicken
  • Publication number: 20110039467
    Abstract: The present invention relates to the use of ionic liquids as flame retardants. The compounds of the invention may be used as flame retardants in various materials without causing damage to the environment and or health of humans or animals. Ionic liquid flame retardants maybe applied alone or in combination with traditional flame retardants. Ionic liquid flame retardants can be applied to finish textile, plastic, leather, paper, rubber, or as wild fire flame retardants.
    Type: Application
    Filed: August 9, 2010
    Publication date: February 17, 2011
    Applicant: H&C Chemical
    Inventor: Yanjie Xu
  • Publication number: 20100027192
    Abstract: Disclosed are coated metal oxide nanoparticles comprising a metal oxide nanoparticle having a surface; and ligands attached to the metal oxide nanoparticle surface. Also disclosed are phosphonic acid compounds comprising the structure Gn-R-Xn, wherein G is a terminal group; wherein R is a bridging group; wherein X is a phosphonic acid group; and wherein each n is, independently, 1, 2, or 3. Also disclosed are methods for preparing and using coated metal oxide nanoparticles. Also disclosed are nanocomposite compositions comprising a polymer; and a coated metal oxide nanoparticle dispersed within the polymer. Also disclosed are articles, films, and capacitors comprising a coated metal oxide nanoparticle or a nanocomposite composition. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
    Type: Application
    Filed: May 12, 2006
    Publication date: February 4, 2010
    Inventors: Joseph Perry, Simon Jones, Joshua N. Haddock, Peter Hotchkiss
  • Patent number: 7517869
    Abstract: Process for the specific fluorination of the phosphorus atom of a phosphonocinnamic compound of the general formula (II) or (II?): X being selected from: an oxygen atom, a sulfur atom, R1, R2, R3, R4, R5 and R6 being selected from: H, an alkyl group, an aryl group, OH, O-alkyl, S-alkyl, NH2, NH-alkyl, N-(alkyl)2; R7 being selected from: H, an alkyl group, an aryl group, a silyl group; R8 being selected from: H, an alkyl group, an aryl group, TBDPS representing a tert-butyldiphenylsilyl group; in the process the compound is reacted with a fluorinating agent comprising a complex formed between a tertiary amine and hydrogen fluoride.
    Type: Grant
    Filed: September 26, 2005
    Date of Patent: April 14, 2009
    Assignee: Centre National de la Recherche Scientique (C.N.R.S.)
    Inventors: Michel Baltas, Florence Bedos-Belval, Hubert Duran, Caroline Lapeyre, Anne-Elisabeth Negre-Salvayre
  • Patent number: 7491294
    Abstract: The present invention relates to a new paper making composition useful for reducing linting and dusting in paper, a method for reducing paper linting and dusting wherein certain phosphate esters are added to a fiber pulp during the paper making process and the novel additive composition for reducing linting and dusting in paper comprising the phosphate ester.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: February 17, 2009
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: François Brouillette, Daniel Morneau, François Fournier
  • Publication number: 20080194843
    Abstract: Crosslinkers having a covalently bonded phosphorous atom, the phosphorous atom having at least one covalently bonded oxygen atom. Crosslinkers can be used with resins such as epoxy, acrylic, polyurethane, polycarbonate, polysiloxane, polyvinyl, polyether, aminoplast, and polyester resins. A process to produce a crosslinker includes incorporating a pendent group comprising a covalently bonded phosphorous atom.
    Type: Application
    Filed: February 8, 2007
    Publication date: August 14, 2008
    Applicant: BASF CORPORATION
    Inventors: Sergio GONZALEZ, Timothy S. December
  • Patent number: 7279515
    Abstract: Resorcinol carbonate-based phosphate esters are prepared by reacting resorcinol carbonates with phosphorous oxychloride or a chlorophosphate. The resorcinol carbonates can be synthesized by the reaction of resorcinol with phosgene or diphenyl carbonate. The resorcinol carbonate-based phosphate esters can be used as flame retardants and perhaps flowing agents.
    Type: Grant
    Filed: September 21, 2005
    Date of Patent: October 9, 2007
    Inventors: Raj B. Durairaj, Gary A. Jesionowski
  • Patent number: 6790975
    Abstract: This invention is an aminostyrylanthracene compound represented by, for example, the following general formula [I]. This compound is produced by condensation from a corresponding aminobenzaldehyde and a phosphonic ester or phosphonium salt. [where, in the general formula [I] above, R2 represents an unsubstituted aryl group, R1 represents an aryl group which may have a variety of substituents, and R3 to R5 each represent a hydrogen atom, a cyano group, or a hydrocarbon group.
    Type: Grant
    Filed: March 19, 2002
    Date of Patent: September 14, 2004
    Assignee: Sony Corporation
    Inventors: Mari Ichimura, Tadashi Ishibashi, Shinichiro Tamura
  • Publication number: 20040121985
    Abstract: Farnesyl diphosphate analogs, specifically the 3-substituted alcohol precursors of the diphosphate analogs, 3-allylfarnesol and 3-vinylfarnesol, are potent inhibitors of mammalian protein fanesyltransferase (FTase). 3-allylgeranylgeraniol is a highly specific cellular inhibitor of protein geranylgeranylation (GGTase I). Furthermore, these compounds are able to efficiently block the anchorage-dependent growth of ras transformed cells. While 3-allylfarnesol inhibits protein farnesylation in situ, 3-vinylfarnesol instead leads to the abnormal prenylation of proteins with the 3-vinylfarnesyl group. In a similar manner, treatment with 3-allylgeranylgeraniol inhibits protein geranylgeranylation while 3-vinylgeranylgeraniol restores protein geranylgeranylation in cells.
    Type: Application
    Filed: June 10, 2003
    Publication date: June 24, 2004
    Inventor: Richard A. Gibbs
  • Publication number: 20040097745
    Abstract: The invention pertains to the use of Group 8 transition metal carbene complexes as catalysts for olefin cross-metathesis reactions. In particular, ruthenium and osmium alkylidene complexes substituted with an N-heterocyclic carbene ligand are used to catalyze cross-metathesis reactions to provide a variety of substituted and functionalized olefins, including phosphonate-substituted olefins, directly halogenated olefins, 1,1,2-trisubstituted olefins, and quaternary allylic olefins. The invention further provides a method for creating functional diversity using the aforementioned complexes to catalyze cross-metathesis reactions of a first olefinic reactant, which may or may not be substituted with a functional group, with each of a plurality of different olefinic reactants, which may or may not be substituted with functional groups, to give a plurality of structurally distinct olefinic products.
    Type: Application
    Filed: April 1, 2002
    Publication date: May 20, 2004
    Inventors: Robert H. Grubbs, Arnab K. Chatterjee, Tae-Lim Choi, Steven D. Goldberg, Jennifer A. Love, John P. Morgan, Daniel P. Sanders, Matthias Scholl, F. Dean Toste, Tina M. Trnka
  • Publication number: 20040092752
    Abstract: A novel, optically active alkenylphosphinic acid ester having chirality on a phosphorus atom; and a simple process for producing the ester. An optically active, hydrogen phosphinic acid ester is reacted with an acetylene compound in the presence of a catalyst containing a metal of group 9 or 10 of the periodic table to thereby obtain a novel, optically active alkenylphosphinic acid ester which has chirality on a phosphorus atom and is represented by the following general formula [1] and/or [2].
    Type: Application
    Filed: September 8, 2003
    Publication date: May 13, 2004
    Inventors: Li-Biao Han, Chang-Qiu Zhao, Masato Tanaka
  • Patent number: 6696589
    Abstract: The present invention provides a novel process for the removal and recovery of radionuclides from waste waters and process streams. The process of the present invention utilizes a combination of a supported liquid membrane (SLM) and a strip dispersion to improve extraction of the target species while increasing membrane stability and reducing processing costs. Additionally, the invention provides a family of new extractants, alkyl phenylphosphonic acids, for the removal and recovery of radionuclides and/or metals, including the use of the new extractants in the process. The new extractant selectively removes radionuclides and metals from the feed stream to provide a concentrated strip solution of the target species.
    Type: Grant
    Filed: February 20, 2001
    Date of Patent: February 24, 2004
    Assignee: Commodore Separation Technologies, Inc.
    Inventor: W. S. Winston Ho
  • Publication number: 20040015003
    Abstract: A high viscosity liquid is fed into a rotation pack bed at a position with a distance far enough from a rotation axis, creating a centrifugal force exerted on the high viscosity liquid overwhelming a drag thereof, so that it can flow radially through the rotation pack bed. A high pressure gas is introduced into the rotation pack bed peripherally and/or a suction force source is connected to a position near the rotation axis, so that a volatile component contained in the high viscosity fluid is entrained in the gas counter currently flowing through the rotation pack bed and withdrawn from the position near the rotation axis, or the volatile component exits from the position near the rotation axis in gas phase, and thus the volatile component is removed from the high viscosity liquid. A second fluid can also be fed into the rotation pack bed to react with the high viscosity liquid, so that a reaction product is formed, and a volatile side product is removed at the same time.
    Type: Application
    Filed: July 17, 2002
    Publication date: January 22, 2004
    Applicant: Industrial Technology Research Institute
    Inventors: Sheng Yang, Chia-Chang Lin, I-Min Tseng, Wen-Tzong Liu, Hua-Tang Yu
  • Publication number: 20030171339
    Abstract: The present invention relates to a novel retinoid derivative compound represented by the formula I: 1
    Type: Application
    Filed: September 17, 2002
    Publication date: September 11, 2003
    Inventors: Hong-Sig Sin, Soo-Jong Um, Young-Soy Rho, Si-Ho Park, Youn-Ja Kwon, Myoung-Soon Park, Hye-Sook Han, So-Mi Kim, Dong-Myong Kim, Deon-Kun Oh, Jong-Sup Park, Tae-Sung Bae
  • Publication number: 20030139622
    Abstract: The invention relates to a process for the preparation of alk(en)ylphosphoric ester salts which comprises reacting the alk(en)ylphosphoric esters in the form of their melts with a base. Advantageously, the alk(en)ylphosphoric esters do not need to be dissolved in a solvent prior to neutralization.
    Type: Application
    Filed: December 18, 2002
    Publication date: July 24, 2003
    Applicant: Clariant GmbH
    Inventors: Torsten Henning, Roman Morschhauser, Matthias Loffler
  • Publication number: 20030100776
    Abstract: The invention pertains to the use of Group 8 transition metal carbene complexes as catalysts for olefin cross-metathesis reactions. In particular, ruthenium and osmium alkylidene complexes substituted with an N-heterocyclic carbene ligand are used to catalyze cross-metathesis reactions to provide a variety of substituted and functionalized olefins, including phosphonate-substituted olefins, directly halogenated olefins, 1,1,2-trisubstituted olefins, and quaternary allylic olefins. The invention further provides a method for creating functional diversity using the aforementioned complexes to catalyze cross-metathesis reactions of a first olefinic reactant, which may or may not be substituted with a functional group, with each of a plurality of different olefinic reactants, which may or may not be substituted with functional groups, to give a plurality of structurally distinct olefinic products.
    Type: Application
    Filed: April 1, 2002
    Publication date: May 29, 2003
    Inventors: Robert H. Grubbs, Arnab K. Chatterjee, Tae-Lim Choi, Steven D. Goldberg, Jennifer A. Love, John P. Morgan, Daniel P. Sanders, Matthias Scholl, F. Dean Toste, Tina M. Trnka
  • Publication number: 20030045738
    Abstract: Bisphenol-phosphorus compound complexes represented by the following general formula (1) are disclosed (R1 to R4 represent hydrogen atom or a group that can be a substituent on a benzene ring; L represents —S— group or a —CHR5— group where R5 represents hydrogen atom or an alkyl group; and R6 to R8 represent an alkyl group, an aryl group, a heterocyclic group etc.). The present invention provides reducing agents that can realize thermally processed image recording materials that can provide sufficient image density at a practical reaction temperature (specifically 100-140° C.) and within a practical reaction time (specifically 1-30 seconds), and can sufficiently suppress the coloration of white portions when the materials are stored in a dark place after the development.
    Type: Application
    Filed: August 22, 2002
    Publication date: March 6, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Makoto Suzuki, Yasuhiro Yoshioka
  • Publication number: 20030022869
    Abstract: The invention provides compounds of formula I: 1
    Type: Application
    Filed: April 3, 2002
    Publication date: January 30, 2003
    Inventors: David Wiemer, Raymond J. Hohl
  • Patent number: 6468992
    Abstract: The present invention provides novel phosphonic acid diester derivatives useful as medicines. The phosphonic acid diester derivatives are represented by the general formula: wherein R1 represents amino group, N-lower alkylamino group, N-lower alkenylamino group, or the like; R2 and R3 represent hydrogen atom, lower alkyl group, halogen atom, lower alkoxy group, or the like; R4 represents hydrogen atom, lower alkyl group or phenyl(lower)alkyl group; R5 and R6 represent lower alkyl group; X, Y and Z represent that all of them are carbon atoms or one of them is nitrogen atom and the other two are carbon atoms; Q represents a single bond or alkylene group; or the pharmacologically acceptable salts thereof.
    Type: Grant
    Filed: December 13, 2000
    Date of Patent: October 22, 2002
    Assignee: Otsuka Pharmaceutical Factory, Inc.
    Inventors: Yasuhiro Sakai, Kazuyoshi Miyata, Kenichi Kawamura, Yoshihiko Tsuda, Yasuhide Inoue
  • Patent number: 6465687
    Abstract: Novel thyroid receptor ligands are provided which have the general formula (I) where R1 is alkyl of 1 to 4 carbons or cycloalkyl of 3 to 7 carbons; R2 and R3 are the same or different and are hydrogen, halogen, alkyl of 1 to 3 carbons or cycloalkyl of 3 to 5 carbons, at least one of R2 and R3 being other than hydrogen; n is an integer from 0 to 4; R4 is an aliphatic hydrocarbon, an aromatic hydrocarbon, carboxylic acid ester thereof, alkenyl carboxylic acid or ester thereof, hydroxy, halogen, cyano, or a phosphonic acid or an ester thereof, or a pharmaceutically acceptible salt thereof. A method for treating diseases associated with metabolism dysfunction or which are dependent on the expression of a T3 regulated gene, such as obesity, hypercholesterolemia, osteoporosis, hypothyroidism, and goiter, is also provided.
    Type: Grant
    Filed: March 20, 2000
    Date of Patent: October 15, 2002
    Assignee: Karo Bio AB
    Inventors: Yi-Lin Li, Ye Liu, Asa Hedfors, Johan Malm, Charlotta Mellin, Minsheng Zhang
  • Patent number: 6448422
    Abstract: This application relates to a novel compound of formula I, as defined herein, processes and intermediates for its preparation and the use of the compound of formula I as a substrate for a pharmaceutical screen.
    Type: Grant
    Filed: July 3, 2000
    Date of Patent: September 10, 2002
    Assignee: Eli Lilly and Company
    Inventors: Patrick Irving Eacho, Patricia Sue Foxworthy-Mason, Richard Waltz Harper, Ho-Shen Lin, Jose Eduardo Lopez, Michael Enrico Richett
  • Publication number: 20020068778
    Abstract: Disclosed herein are a novel phosphate compound by which a copper ion can be dispersed in a high proportion in a synthetic resin, thereby providing a resin composition which has excellent visible ray-transmitting property and performance that near infrared rays are absorbed with high efficiency, and is little in the deterioration of its near infrared ray-absorbing ability by ultraviolet rays, and a preparation process thereof, a phosphate copper compound obtained from the phosphate compound and a preparation process thereof, and a near infrared ray-absorbing acrylic resin composition which has excellent visible ray-transmitting property and performance that near infrared rays are absorbed with high efficiency and is little in the deterioration of its near infrared ray-absorbing ability by ultraviolet rays.
    Type: Application
    Filed: February 17, 2000
    Publication date: June 6, 2002
    Inventors: YASUHIRO OHNISHI, HIROKI KATONO
  • Patent number: 6372730
    Abstract: The invention provides novel Prostaglandin F analogs. In particular, the present invention is directed to compounds having a structure according to the following formula: wherein R1, R2, X, Y, V, a, b, W, and Z are defined below. This invention also includes optical isomers, diastereomers and enantiomers of the formula above, and pharmaceutically—acceptable salts, biohydrolyzable amides, esters, and imides thereof. The compounds of the present invention are useful for the treatment of a variety of diseases and conditions, such as bone disorders and glaucoma. Accordingly, the invention further provides pharmaceutical compositions comprising these compounds. The invention still further provides methods of treatment for bone disorders and glaucoma using these compounds or the compositions containing them.
    Type: Grant
    Filed: August 3, 2000
    Date of Patent: April 16, 2002
    Assignee: The Procter & Gamble Company
    Inventors: Mitchell Anthony deLong, John August Wos, Biswanath De, Frank Hallock Ebetino
  • Patent number: 6184187
    Abstract: Novel phosphorus compounds are effective corrosion inhibitors for perfluoropolyether lubricating oils and greases, and hydraulic fluids.
    Type: Grant
    Filed: April 7, 1998
    Date of Patent: February 6, 2001
    Assignee: E. I. duPont de Nemours and Company
    Inventors: Jon L. Howell, Michael A. Hofman
  • Patent number: 6147244
    Abstract: Improved methods for converting phosphite or phosphonate esters into corresponding thiophosphites or thiophosphonates and for synthesizing specific thiophosphite and thiophosphonate compounds so produced are disclosed and claimed. The methods start from phosphite diesters using P.sub.4 S.sub.10 as the thionation reagent. The reaction mixture is refluxed until the reaction is complete and may be followed by separation and chloroformate ester phosphonation steps to produce pure thiophosphonocarboxylate triesters. Alternatively, these esters may be prepared directly by action of P.sub.4 S.sub.10 on the corresponding phosphonocarboxylate esters. The former method was used to prepare dimethyl thiophosphite and thence trimethyl thiophosphonoformate, a key intermediate in synthesis of salts of thiophosphonoformic acid, which have anti-viral properties.
    Type: Grant
    Filed: May 3, 1999
    Date of Patent: November 14, 2000
    Assignee: University of Southern California
    Inventors: Charles E. McKenna, Zengmin Li
  • Patent number: 5679863
    Abstract: The preparation of .alpha.-carbonylphosphine oxides by oxidizing an .alpha.-hydroxyalkyl phosphine oxide with an organic hydroperoxide or of an organic peroxy acid in the presence of a compound of a Group IV to Group VIII metal in the periodic table, and novel .alpha.-hydroxybenzyl phosphine oxides. .alpha.-Carbonylphosphine oxides are used as photoinitiators for polymerizable compositions.
    Type: Grant
    Filed: October 16, 1995
    Date of Patent: October 21, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Fischer, Eckhard Hickmann, Rudolf Kropp, Jochen Schroeder, Beate Trentmann
  • Patent number: 5569800
    Abstract: An electrophotographic photoconductor which is composed of an electroconductive support and a photoconductive layer formed thereon comprising a novel pyrene-ring-containing olefin compound having formula [I]: ##STR1## wherein R.sup.1 and R.sup.2 each represent hydrogen or an alkyl group which may have a substituent; Y is an aliphatic hydrocarbon group which may have a substituent, a cyclic hydrocarbon group which may have a substituent, or an aromatic group which may have a substituent; n is an integer of 0 or 1, and m is an integer of 1 to 3, provided that when n is 0, m is 1, R.sup.1 is hydrogen, and Y is an aromatic group with a substituent ##STR2## R.sup.2 and R.sup.3 each represent hydrogen, and Y and R.sup.1 may be bonded to form a ring, a method of synthesizing the pyrene-ring-containing olefin compound and an intermediate therefor are disclosed.
    Type: Grant
    Filed: May 2, 1995
    Date of Patent: October 29, 1996
    Assignee: Ricoh Company, Ltd.
    Inventors: Tamotsu Aruga, Masaomi Sasaki, Tomoyuki Shimada, Hiroshi Adachi
  • Patent number: 5550277
    Abstract: Perfluoroalkyl and perfluoroalkylether substituted aromatic phosphates, phosphonates and related compositions prepared by reaction of pefluoroalkyl or pefluoroakylether substituted phenols with mono- and dihalophosphite and primary and secondary phosphonyl halides are disclosed. These materials are useful as antioxidant, anticorrosion, antirust, and lubricity enhancing agents for perfluoropolyalkylether fluids.
    Type: Grant
    Filed: January 19, 1995
    Date of Patent: August 27, 1996
    Inventors: Kazimiera J. L. Paciorek, Wen-Huey Lin, Steven R. Masuda, James H. Nakahara
  • Patent number: 5550276
    Abstract: Compounds of the general formula I ##STR1## in which n is 1, 2 or 3 and in which X is oxygen or sulfur, T has the meaning of --S--, --S--S--, --S--S--, --S--S--S--S--, --S--S--S--S--S--, ##STR2## and Y has the meaning of ##STR3## in which Z has the meaning of --H, --COR.sup.13, --COOR.sup.13 or --CONHR.sup.13, and Q has the meaning of oxygen or --NR.sup.0 --, and R.sup.1, R.sup.2, R.sup.0, R.sup.4 and R.sup.13 are as defined in claim 1, with the proviso that the compound of the formula C.sub.2 H.sub.5 --S--CH.sub.2 CH(OH)--P(OC.sub.2 H.sub.5).sub.2 is excepted.The invention also relates to compositions containing the compounds of the formula I and organic materials, for example functional liquids and, in particular, lubricants.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 27, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Hermann O. Wirth, Hans-Helmut Friedrich, Kay S. Groninger
  • Patent number: 5424474
    Abstract: The present invention relates to fluorinated carboxylic acid esters of phosphono- and phosphinocarboxylic acids containing hydroxyl and/or mercapto groups, their use as waterproofing and/or oil-repellency agents, and a method for their preparation.
    Type: Grant
    Filed: December 23, 1993
    Date of Patent: June 13, 1995
    Assignee: Bayer AG
    Inventors: Klaus Pohmer, Rainer Weber, Hans-Dieter Block, Hans-Heinrich Moretto
  • Patent number: 5414102
    Abstract: The present invention relates to fluorinated carboxylic acid esters of phosphonocarboxylic acids containing acrylate and/or methacrylate groups, their use as waterproofing or oil-repellency agents, and a method for their preparation.
    Type: Grant
    Filed: December 27, 1993
    Date of Patent: May 9, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus Pohmer, Rainer Weber, Hans-Dieter Block, Hans-Heinrich Moretto
  • Patent number: 5362906
    Abstract: The present invention is directed to farnesyl pyrophosphate analogs which inhibit farnesyl-protein transferase (FTase) and the farnesylation of the oncogene protein Ras. The invention is further directed to chemotherapeutic compositions containing the compounds of this invention, and methods for inhibiting farnesyl-protein transferase and the farnesylation of the oncogene protein Ras.
    Type: Grant
    Filed: June 18, 1993
    Date of Patent: November 8, 1994
    Assignee: Merck & Co., Inc.
    Inventors: Neville J. Anthony, Ta-Jyh Lee, Robert L. Smith, Gerald E. Stokker
  • Patent number: 5308517
    Abstract: A composition of matter having utility in lubricant formulations, said composition being the reaction product of adenine, alkoxylated amine and dihydrocarbyldithiophosphoric acid and having the general formula (I): ##STR1## where R is hydrogen or a hydrocarbyl group of from 1 to 20 carbon atoms, R.sup.1 is a hydrocarbyl group of 2 to 22 carbon atoms, R.sup.2 and R.sup.3 are each independently hydrocarbyl groups having from 3 to 30 carbon atoms, x and y are each independently integers of from 1 to 15 with the proviso that the sum of x+y is from 2 to 20, and a, b and c are independent numbers from 1.0 to 3.0 wherein the ratios between a:b, a:c and b:c range from 1.0:3.0 to 3.0:1.0.
    Type: Grant
    Filed: February 22, 1993
    Date of Patent: May 3, 1994
    Assignee: Exxon Research & Engineering Co.
    Inventors: Jacob J. Habeeb, Morton Beltzer
  • Patent number: 5260051
    Abstract: The invention relates to novel compositions, in particular personal product compositions containing phosphate ester surfactants in which a portion of the surfactant molecule has a so-called "benefit reagent" function. It is believed that this benefit reagent portion comes to play when the surfactant is metabolized or hydrolyzed.
    Type: Grant
    Filed: December 17, 1990
    Date of Patent: November 9, 1993
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventor: Suk H. Cho
  • Patent number: 5107011
    Abstract: Compounds which are inhibitors of cholesterol biosynthesis (by inhibiting de novo squalene biosynthesis), and thus are useful as hypocholesterolemic agents and antiatherosclerotic agents, are provided which have the structure ##STR1## wherein R.sup.2 is a metal ion, lower alkyl or H; R.sup.3 is a metal ion or lower alkyl;R is R.sup.1 --(CH.sub.2).sub.n --, R.sup.1 --(CH.sub.2).sub.m --O-- or R.sup.1 --(CH.sub.2).sub.m --OCH.sub.2 --, wherein n is 1 to 4 and m is 0 to 3, andR.sup.1 is R.sup.5 --Q.sup.1 --Q.sup.2 --Q.sup.3 -- wherein R.sup.5, Q.sup.1, Q.sup.2 and Q.sup.3 are as defined herein.New intermediates, new methods of preparation and a method for using such compounds to inhibit cholesterol biosynthesis are also provided.
    Type: Grant
    Filed: February 5, 1991
    Date of Patent: April 21, 1992
    Assignee: E. R. Squibb & Sons, Inc.
    Inventor: Scott A. Biller
  • Patent number: 5080813
    Abstract: Amine salts having utility in metalworking operations is disclosed. The amine salts are prepared by the reaction of(A) a dihydrocarbyldithiophosphoric acid of the formula ##STR1## wherein R.sup.1 and R.sup.2 are hydrocarbyl-based groups independently containing from about 5 to about 30 carbon atoms, X is oxygen or sulfur, and(B) an alkoxylated amine prepared by reacting a non-tertiary amine comprising(a) a monoamine,(b) a diamine, or(c) a polyamine,with from about 2 up to about 15 moles of an alkylene oxide comprising ethylene oxide or propylene oxide.
    Type: Grant
    Filed: March 26, 1990
    Date of Patent: January 14, 1992
    Assignee: Ferro Corporation
    Inventors: Karl P. Kammann, Jr., William R. Garrett
  • Patent number: 5068425
    Abstract: Phosphinamides are prepared by the action of an organic halide on an oxazaphospholidine. Depending upon the configuration desired for the stereoisomer to be obtained, an oxazaphospholidine is utilized which has been derived from a (+) or (-) optically-active amino-alcohol. These phosphinamides are useful for the preparation of phosphinates, in particular optically-active phosphinates of known absolute configuration; for this, the phosphinamide is subjected to alcoholysis.
    Type: Grant
    Filed: October 17, 1990
    Date of Patent: November 26, 1991
    Assignee: Societe Nationale Elf Aquitaine
    Inventor: Sylvain Juge
  • Patent number: 4997912
    Abstract: Fatty acid esters of oxalkylated alkylalkylenediamines, which may be quaternized:Esters of oxalkylated alkylalkylenediamines, which may be quaternized, of the formula ##STR1## where the individual symbols have the meaning given in the description, process for their production and their use as corrosion inhibitors, particularly in crude oil recovery plants and crude oil treatment plants.
    Type: Grant
    Filed: December 15, 1988
    Date of Patent: March 5, 1991
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Herbert Wirtz, Hermann Hoffmann, Werner Ritschel, Manfred Hofinger, Michael Mitzlaff, Dietrich Wolter
  • Patent number: 4960919
    Abstract: A process for the preparation of alkyl esters of alkenylphosphinic acid, having the general formula I ##STR1## wherein R.sup.1 represents H or CH.sub.3, R.sup.2 alkyl having from 1 to 4 carbon atoms or phenyl and R.sup.3 alkyl having from 1 to 8 carbon atoms, which comprises cleaving an alkyl ester of 2-acetoxyethyl phosphinic acid, having the general formula II ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning indicated above, in contact with a liquid catalytically acting medium and at a partial pressure of the total of the components of the reaction system in the range of from 1 to 500 mbar, and drawing off the resulting alkyl esters of alkenyl phosphinic acid and other volatile reaction products.The invention also relates to compounds of the formula I ##STR3## wherein (a) R.sup.1 represents H, R.sup.2 represents alkyl having from 1 to 4 carbon atoms or phenyl and R.sup.3 represents isobutyl or alkyl having from 5 to 8 carbon atoms, or(b) R.sup.1 represents CH.sub.3, R.sup.
    Type: Grant
    Filed: February 16, 1989
    Date of Patent: October 2, 1990
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans-Jerg Kleiner, Gunter Roscher
  • Patent number: 4924024
    Abstract: Compounds which are useful as inhibitors of cholesterol biosynthesis and thus as hypocholesterolemic agents are provided which have the structure ##STR1## wherein Q is ##STR2## or a bond; Z is --(CH.sub.2).sub.n -- or --(CH.sub.2).sub.p --CH.dbd.CH--(CH.sub.2).sub.m --, wherein n is 1 to 5; p is 0, 1 or 2; m is 0, 1 or 2;R, R.sup.1 and R.sup.1a are the same or different and are H, lower alkyl or a metal ion; andR.sup.2 and R.sup.3 may be the same or different and are H or halogen.New intermediates used in preparing the above compounds and method for preparing same, pharmaceutical compositions containing such compounds and a method for using such compounds to inhibit cholesterol biosynthesis are also provided.
    Type: Grant
    Filed: June 1, 1989
    Date of Patent: May 8, 1990
    Assignee: E. R. Squibb & Sons, Inc.
    Inventor: Scott A. Biller
  • Patent number: 4883615
    Abstract: A process for flameproofing a substrate comprising applying to the substrate a compound of formula I ##STR1## in which R.sub.1.sup..sym. is a N.sup..sym. cation defined in the Specification and R.sub.2 and R.sub.3 are organic radicals.Substrates to which the compound of formula I can be applied include cellulosic substrates.
    Type: Grant
    Filed: July 14, 1986
    Date of Patent: November 28, 1989
    Assignee: Sandoz Ltd.
    Inventors: Tibor Robinson, Rainer Wolf
  • Patent number: 4774351
    Abstract: Phosphorus, sulfur and nitrogen containing salts prepared from dithiophosphorus compounds and amines are disclosed, which salts find utility in aqueous functional fluids. Compositions comprising a continuous aqueous phase, at least one of said salts prepared from dithiophosphorus compounds and amines and optionally a surface active agent are also disclosed.
    Type: Grant
    Filed: November 6, 1987
    Date of Patent: September 27, 1988
    Assignee: The Lubrizol Corporation
    Inventor: John W. Forsberg
  • Patent number: 4753749
    Abstract: The present invention relates to microbiocidal cleansing agent and to a microbiocidal amine alkyl phosphate additive which is incorporated therein.The microbiocidal amine alkyl phosphate has the following general structure: ##STR1## wherein R=an alkyl group containing from 1 to 24 carbon atoms;R.sub.1 =an alkyl group containing from 1 to 3 carbon atoms; andR.sub.2 =an alkyl group containing from 1 to 5 carbon atoms.The microbiocidal cleansing agent of the present invention may be prepared by dissolving the amine alkyl phosphate additive in water or a conventional detergent.
    Type: Grant
    Filed: September 23, 1987
    Date of Patent: June 28, 1988
    Assignee: Interface Research Corporation
    Inventor: Robert H. McIntosh
  • Patent number: 4721802
    Abstract: Phosphorus, sulphur and nitrogen containing salts prepared from dithiophosphorus compounds and amines are disclosed, which salts find utility in aqueous functional fluids. Compositions comprising a continuous aqueous phase, at least one of said salts prepared from dithiophosphorus compounds and amines and optionally a surface active agent are also disclosed.
    Type: Grant
    Filed: January 7, 1983
    Date of Patent: January 26, 1988
    Assignee: The Lubrizol Corporation
    Inventor: John W. Forsberg
  • Patent number: 4661601
    Abstract: New compounds having the formula 1 ##STR1## wherein W is hydrogen, halogen, n-alkyl, --NHCOR.sup.1, --COR.sup.1, or phenoxyacetylamino optionally substituted by one or two C.sub.1-12 straight- or branched chain alkyl, X is a substituent in the coupling position and is selected from hydrogen, chlorine, bromine, --SR.sup.11 or a nitrogen-containing heterocyclic residue attached at a ring nitrogen atom, and Y is a group having the formula 2 ##STR2## wherein Q is selected from the residues: --COOR.sup.4 or --CONR.sup.4 R.sup.5, --OM, --NR.sup.7 R.sup.8, --PO(OR.sup.9)[O].sub.x R.sup.10 with X=0 or 1, --SO.sub.2 OH, --SO.sub.2 NR.sup.4 R.sup.5 or CN. The groups R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, M, k and n are defined hereinafter.These compounds are used as black color couplers in photographic materials.
    Type: Grant
    Filed: April 3, 1985
    Date of Patent: April 28, 1987
    Assignee: Ciba-Geigy AG
    Inventor: Frederick H. Howell