And Divalent Chalogen Double Bonded Directly To The Ring Phosphorus (e.g., Cyclic Phosphates, Etc.) Patents (Class 558/79)
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Publication number: 20150038036Abstract: A flameproofing agent for fibers which has high flameproofness and excellent physical properties (light resistance, heat resistance, texture), a process for manufacturing a flameproof fiber product and a flameproof fiber product. The flameproofing agent comprises an organic phosphorus compound (component A) represented by the following formula (1). (In the above formula, X1 and X2 are the same or different and each an aromatic substituted alkyl group represented by the following formula (2).) ?AL??Ar)n??(2) (In the above formula, AL is a branched or linear aliphatic hydrocarbon group having 1 to 5 carbon atoms, Ar is a phenyl group, naphthyl group or anthryl group all of which may have a substituent, ānā is an integer of 1 to 3, and Ar may be bonded to any carbon atom contained in AL.Type: ApplicationFiled: March 26, 2013Publication date: February 5, 2015Applicants: TEIJIN LIMITED, MARUBISHI OIL CHEMICAL CO., LTD.Inventors: Katsuhiro Yamanaka, Tsuyoshi Takeda, Kuniaki Kondo, Masaki Haruyoshi
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Patent number: 8877956Abstract: The present disclosure relates to a non-acidic, sulfur-containing, phosphorus-containing compound of the formula I where R1, R2, R3, R4, R5, R6, and R7 are as defined herein. Such a compound may exhibit improved antiwear performance and thermal stability in lubricating compositions.Type: GrantFiled: November 8, 2013Date of Patent: November 4, 2014Assignee: Afton Chemical CorporationInventors: John Marshall Baker, Naresh Mathur, Roger M. Sheets, David J. Degonia
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Patent number: 8796389Abstract: The present invention relates to a method for thermal crosslinking of adhesives and also to products produced with these adhesives. An object of the invention is to provide a method for thermal crosslinking of adhesives where the crosslinking is covalent and (initiated by a chemical or physical stimulus) reversible. As and when required, the crosslinking method can also be configured to result in a covalent, irreversible network.Type: GrantFiled: June 15, 2012Date of Patent: August 5, 2014Assignee: TESA SEInventors: Alexander Prenzel, Sarah Bamberg
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Publication number: 20140171394Abstract: The present invention is directed to polyphosphorylated and pyrophosphate derivatives of cyclitols. More particularly, the invention relates to polyphosphorylated and pyrophosphate derivatives of inositols. The invention also relates to compositions of the polyphosphorylated and pyrophosphate derivatives of inositol and other similar, more lipophilic derivatives, and their use as allosteric effectors, cell-signaling molecule analogs, and therapeutic agents.Type: ApplicationFiled: December 9, 2013Publication date: June 19, 2014Applicants: Universite de Strasbourg, NormOxys, Inc.Inventors: Jean-Marie Lehn, Srinivasu Pothukanuri, Alexandros Koumbis, Carolina Duarte, Claude Nicolau
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Patent number: 8674130Abstract: A process for producing a cyclic alkylene phosphorohalidite, which comprises reacting a specific phosphorus trihalide with a specific alkylene glycol compound under conditions where the phosphorus trihalide is present in an excess amount relative to the amount of the alkylene glycol compound in the reaction system to order to obtain the cyclic alkylene phosphorohalidite by reacting the alkylene glycol compound with the phosphorus trihalide; and a process for producing a cyclic phosphoric acid ester by using the obtained cyclic alkylene phosphorohalidite as a raw material.Type: GrantFiled: September 21, 2010Date of Patent: March 18, 2014Assignee: Daihachi Chemical Industry Co., Ltd.Inventors: Toshiya Hamada, Sakiko Hamada
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Publication number: 20140066646Abstract: The present disclosure relates to a non-acidic, sulfur-containing, phosphorus-containing compound of the formula I where R1, R2, R3, R4, R5, R6, and R7 are as defined herein. Such a compound may exhibit improved antiwear performance and thermal stability in lubricating compositions.Type: ApplicationFiled: November 8, 2013Publication date: March 6, 2014Applicant: Afton Chemical CorporationInventors: John Marshall Baker, Naresh Mathur, Roger M. Sheets, David J. Degonia
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Patent number: 8420847Abstract: A novel bis-phosphate compound is provided which can be applied to a wide range of reactive substrates and reactions as an asymmetric reaction catalyst and can realize an asymmetric reaction affording a high yield and a high enantiomeric excess. The bis-phosphate compound has a tetraaryl skeleton represented by General Formula (1). In an asymmetric reaction, an amidodiene and an unsaturated aldehyde compound are reacted with each other in the presence of the optically active bis-phosphate compound to give an optically active amidoaldehyde. The invention allows a reaction such as an asymmetric Diels-Alder reaction to proceed efficiently, which has been difficult with conventional mono-phosphate compounds.Type: GrantFiled: March 8, 2011Date of Patent: April 16, 2013Assignees: National University Corporation Tohoku University, API CorporationInventors: Masahiro Terada, Norie Momiyama, Tohru Konno
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Publication number: 20120330038Abstract: A novel bis-phosphate compound is provided which can be applied to a wide range of reactive substrates and reactions as an asymmetric reaction catalyst and can realize an asymmetric reaction affording a high yield and a high enantiomeric excess. The bis-phosphate compound has a tetraaryl skeleton represented by General Formula (1). In an asymmetric reaction, an amidodiene and an unsaturated aldehyde compound are reacted with each other in the presence of the optically active bis-phosphate compound to give an optically active amidoaldehyde. The invention allows a reaction such as an asymmetric Diels-Alder reaction to proceed efficiently, which has been difficult with conventional mono-phosphate compounds.Type: ApplicationFiled: March 8, 2011Publication date: December 27, 2012Applicants: API Corporation, National University Corporation TOHOKU UNIVERSITYInventors: Masahiro Terada, Norie Momiyama, Tohru Konno
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Patent number: 8324418Abstract: Organic dithiopyrophosphates of formula wherein R1, R2, R3, R4 and R5 independently are hydrogen, C1-4 alkyl, chloromethyl or bromomethyl, are prepared in a two-step process from the corresponding 1,3-diols and thiophosphoryl chloride, using 3-methylpyridine both as solvent and as base.Type: GrantFiled: October 21, 2009Date of Patent: December 4, 2012Assignee: Lonza Ltd.Inventors: Gesa Paradies, Thomas Riedel, Christian Schnider
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Publication number: 20120264965Abstract: A process for producing a cyclic alkylene phosphorohalidite, which comprises reacting a specific phosphorus trihalide with a specific alkylene glycol compound under conditions where the phosphorus trihalide is present in an excess amount relative to the amount of the alkylene glycol compound in the reaction system to order to obtain the cyclic alkylene phosphorohalidite by reacting the alkylene glycol compound with the phosphorus trihalide; and a process for producing a cyclic phosphoric acid ester by using the obtained cyclic alkylene phosphorohalidite as a raw material.Type: ApplicationFiled: September 21, 2010Publication date: October 18, 2012Applicant: DAIHACHI CHEMICAL INDUSTRY CO., LTD.Inventors: Toshiya Hamada, Sakiko Hamada
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Publication number: 20110207955Abstract: Organic dithiopyrophosphates of formula wherein R1, R2, R3, R4 and R5 independently are hydrogen, C1-4 alkyl, chloromethyl or bromomethyl, are prepared in a two-step process from the corresponding 1,3-diols and thiophosphoryl chloride, using 3-methylpyridine both as solvent and as base.Type: ApplicationFiled: October 21, 2009Publication date: August 25, 2011Applicant: LONZA LTD.Inventors: Gesa Paradies, Thomas Riedel, Christian Schnider
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Publication number: 20100267674Abstract: The present invention relates to mixed calcium/sodium salt of inositol tripyrophosphate, methods of preparing and methods of use. The mixed calcium/sodium salt may be a monocalcium tetrasodium salt of inositol tripyrophosphate. Methods of use include administering the above salts in an effective amount to treat diseases caused by hypoxia or other conditions associated with inadequate function of the lungs or circulatory system, such as various types of cancer and Alzheimer's disease.Type: ApplicationFiled: June 28, 2010Publication date: October 21, 2010Applicants: NORMOXYS, INC., UNIVERSITE DE STRASBOURGInventors: Yves Claude Nicolau, Jean-Marie Lehn, Konstantina C. Fylaktakidou, Ruth Greferath
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Patent number: 7728162Abstract: A novel process for preparing in a high purity and in a high yield phosphorus compounds having a phosphate-phosphonate bond within one molecule, along with only a small amount of a by-product, without being restricted by the kind of a phosphonate having an alcoholic hydroxyl group which is a raw material, without using a catalyst such as magnesium chloride, but only using a nitrogen-containing basic compound.Type: GrantFiled: October 18, 2005Date of Patent: June 1, 2010Assignee: Daihachi Chemical Industry Co., Ltd.Inventors: Kazuo Fujimoto, Sakiko Tanaka
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Publication number: 20100029594Abstract: The present invention relates to mixed calcium/sodium salt of inositol tripyrophosphate, methods of preparing and methods of use. The mixed calcium/sodium salt may be a monocalcium tetrasodium salt of inositol tripyrophosphate. Methods of use include administering the above salts in an effective amount to treat diseases caused by hypoxia or other conditions associated with inadequate function of the lungs or circulatory system, such as various types of cancer and Alzheimer's disease.Type: ApplicationFiled: July 21, 2009Publication date: February 4, 2010Inventors: Yves Claude Nicolau, Jean-Marie Lehn, Konstantina C. Fylaktakidou, Ruth Greferath
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Patent number: 6608046Abstract: The invention provides novel &bgr;-lactamase inhibitors, which are structurally unrelated to the natural product and semi-synthetic &bgr;-lactamase inhibitors presently available, and which do not possess &bgr;-lactam pharmacophore. These new inhibitors are fully synthetic, allowing ready access to a wide variety of structurally related analogs. Certain embodiments of these new inhibitors also bind bacterial DD-peptidases, thus potentially acting both as &bgr;-lactamase inhibitors and as antibiotics.Type: GrantFiled: September 1, 2000Date of Patent: August 19, 2003Assignee: MethylGene, Inc.Inventors: Jeffrey M. Besterman, Jubrail Rahil, Rex Pratt
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Patent number: 6599889Abstract: The invention provides novel &bgr;-lactamase inhibitors, which are structurally unrelated to the natural product and semi-synthetic &bgr;-lactamase inhibitors presently available, and which do not possess a &bgr;-lactam pharmacophore. These new inhibitors are fully synthetic, allowing ready access to a wide variety of structurally related analogs. Certain embodiments of these new inhibitors also bind bacterial DD-peptidases, thus potentially acting both as &bgr;-lactamase inhibitors and as antibiotics.Type: GrantFiled: March 1, 2001Date of Patent: July 29, 2003Assignee: MethylGere, Inc.Inventors: Jeffrey M. Besterman, Jubrail Rahil, Rex Pratt
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Publication number: 20030109736Abstract: The phosphorus-containing compound of the present invention is represented by the following formula (I), (II) or (III): 1Type: ApplicationFiled: December 26, 2001Publication date: June 12, 2003Inventors: Yoko Onchi, Ikuo Takahashi
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Publication number: 20020111487Abstract: A bisphosphite of the formula I 1Type: ApplicationFiled: October 29, 2001Publication date: August 15, 2002Inventors: Dirk Roettger, Dieter Hess, Klaus-Diether Wiese, Cornelia Borgmann, Armin Borner, Detlef Selent, Reinhard Schmutzler, Christine Kunze
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Patent number: 5852197Abstract: The invention relates to cyclic diphosphoric esters of the formula ##STR1## with R=methylethylene, 1,3-cyclohexylene, 1,4-cyclo-hexylene or 1,3-phenylene, a process for their preparation and their use as flame retardants.Type: GrantFiled: July 15, 1996Date of Patent: December 22, 1998Assignee: Hoechst AktiengellschaftInventor: Horst Staendeke
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Patent number: 5401788Abstract: Organic phosphorus compounds of the formula (I): ##STR1## wherein R.sub.1 and R.sub.2 are, the same or different, a C.sub.1-8 straight chain or branched chain alkyl group, an optionally substituted C.sub.6-12 aryl group; and A represents a bond, a lower alkylene group or --(OCH.sub.2 CH.sub.2).sub.n -- group, (n is an integer of 1 to 5), which are useful as flame-retardants.Type: GrantFiled: March 10, 1994Date of Patent: March 28, 1995Assignee: Daihachi Chemical Industry Co., Ltd.Inventors: Noriaki Tokuyasu, Tatsushi Ono, Katsumi Kameda
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Patent number: 5362898Abstract: A bis(pentaerythritol phosphate alcohol) alkylphosphonate compound, such as one comprising an alkyl group of from about one to four carbon atoms, preferably bis(pentaerythritol phosphate alcohol) methylphosphonate, is a flame retardant compound. Such a compound can be prepared by the transesterification of a diphenyl alkyl phosphonate carrying the desired alkyl group with pentaerythritol phosphate alcohol. An alternative process of preparation comprises the reaction of pentaerythritol phosphate alcohol, a trialkylamine, and an alkylphosphonic dihalide.Type: GrantFiled: November 22, 1993Date of Patent: November 8, 1994Assignee: Akzo Nobel nvInventor: Jeffrey E. Telschow
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Patent number: 5300617Abstract: A method for producing a potassium para-diphenyl phosphino sulfonate ligand which comprises reacting potassium diphenyl phosphide with a lithium salt of para-chloro benzenesulfonic acid in the presence of tetrahydrofuran at elevated temperatures.Type: GrantFiled: January 21, 1993Date of Patent: April 5, 1994Assignee: Exxon Chemical Patents Inc.Inventors: Elena N. Suciu, Joel R. Livingston, Jr., Edmund J. Mozeleski
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Patent number: 5239103Abstract: 3,7,9-Trioxa-1-aza-2,8-diphosphaspiro[4.5]decanes of formula I ##STR1## wherein R.sub.1 and R.sub.2 are independently hydrogen, alkyl, cycloalkyl, bicycloalkyl, tricycloalkyl or aryl; or can be halogen when n or m is zero,R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are independently hydrogen, alkyl, aralkyl or aryl;X and Y are independently --O--, --S-- or --NR.sub.16 -- where R.sub.16 is alkyl, cycloalkyl, alkenyl, aryl or aralkyl;W and Z are independently O or S; andn, m, o and p are independently zero or 1, are effective in stabilizing organic materials against the deleterious effects of oxygen, heat and/or actinic radiation.Type: GrantFiled: November 12, 1992Date of Patent: August 24, 1993Assignee: Ciba-Geigy CorporationInventors: Raymond Seltzer, Paul A. Odorisio, Sai P. Shum, Stephen D. Pastor
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Patent number: 5075482Abstract: 3,7,9-Trioxa-1-aza-2,8-diphosphaspiro[4.5]decanes of formula I ##STR1## wherein R.sub.1 and R.sub.2 are independently hydrogen, alkyl, cycloalkyl, bicycloalkyl, tricycloalkyl or aryl; or can be halogen when n or m is zero,R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are independently hydrogen, alkyl, aralkyl or aryl;X and Y are independently --O-- --S--, or --NR.sub.16 -- where R.sub.16 is alkyl, cycloalkyl, alkenyl, aryl or aralkyl;W and Z are independently O or S; andn, m, o and p are independently zero or 1, are effective in stabilizing organic materials against the deleterious effects of oxygen, heat and/or actinic radiation.Type: GrantFiled: August 23, 1990Date of Patent: December 24, 1991Assignee: Ciba-Geigy CorporationInventors: Raymond Seltzer, Paul A. Odorisio, Sai P. Shum, Stephen D. Pastor
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Patent number: 4673701Abstract: Alkylidene bisphenol phosphites and phosphates having 2,2,6,6-tetramethyl piperidinyl groups are provided having the formula: ##STR1## wherein: R.sub.1 is alkyl having from one to about twelve carbon atoms;R.sub.2, R.sub.3 and R.sub.4 are each selected from the group consisting of hydrogen and alkyl having from one to about twelve carbon atoms;m is 0 or 1;n is 0 or 1;X is selected from the group consisting of ##STR2## wherein: R.sub.5 is selected from the group consisting of hydrogen, oxyl O.sup.2, alkyl having from one to about twelve carbon atoms; arylalkyl having from seven to about eighteen carbon atoms; 2,3-epoxypropyl, acyl having from one to about eight carbon atoms and ##STR3## in which R.sub.6 is selected from the group consisting of hydrogen, alkyl having from one to about twelve carbon atoms and phenyl, and Y.sub.1 is selected from the group consisting of hydrogen; acyl having from one to about twelve carbon atoms; and ##STR4## Z.sub.1 is selected from the group consisting of ##STR5## wherein R.Type: GrantFiled: December 28, 1984Date of Patent: June 16, 1987Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Motonobu Minagawa, Yutaka Nakahara, Toshihiro Shibata, Ryozo Arata