And Divalent Chalogen Double Bonded Directly To The Ring Phosphorus (e.g., Cyclic Phosphates, Etc.) Patents (Class 558/79)
  • Publication number: 20150038036
    Abstract: A flameproofing agent for fibers which has high flameproofness and excellent physical properties (light resistance, heat resistance, texture), a process for manufacturing a flameproof fiber product and a flameproof fiber product. The flameproofing agent comprises an organic phosphorus compound (component A) represented by the following formula (1). (In the above formula, X1 and X2 are the same or different and each an aromatic substituted alkyl group represented by the following formula (2).) ?AL??Ar)n??(2) (In the above formula, AL is a branched or linear aliphatic hydrocarbon group having 1 to 5 carbon atoms, Ar is a phenyl group, naphthyl group or anthryl group all of which may have a substituent, ā€œnā€ is an integer of 1 to 3, and Ar may be bonded to any carbon atom contained in AL.
    Type: Application
    Filed: March 26, 2013
    Publication date: February 5, 2015
    Applicants: TEIJIN LIMITED, MARUBISHI OIL CHEMICAL CO., LTD.
    Inventors: Katsuhiro Yamanaka, Tsuyoshi Takeda, Kuniaki Kondo, Masaki Haruyoshi
  • Patent number: 8877956
    Abstract: The present disclosure relates to a non-acidic, sulfur-containing, phosphorus-containing compound of the formula I where R1, R2, R3, R4, R5, R6, and R7 are as defined herein. Such a compound may exhibit improved antiwear performance and thermal stability in lubricating compositions.
    Type: Grant
    Filed: November 8, 2013
    Date of Patent: November 4, 2014
    Assignee: Afton Chemical Corporation
    Inventors: John Marshall Baker, Naresh Mathur, Roger M. Sheets, David J. Degonia
  • Patent number: 8796389
    Abstract: The present invention relates to a method for thermal crosslinking of adhesives and also to products produced with these adhesives. An object of the invention is to provide a method for thermal crosslinking of adhesives where the crosslinking is covalent and (initiated by a chemical or physical stimulus) reversible. As and when required, the crosslinking method can also be configured to result in a covalent, irreversible network.
    Type: Grant
    Filed: June 15, 2012
    Date of Patent: August 5, 2014
    Assignee: TESA SE
    Inventors: Alexander Prenzel, Sarah Bamberg
  • Publication number: 20140171394
    Abstract: The present invention is directed to polyphosphorylated and pyrophosphate derivatives of cyclitols. More particularly, the invention relates to polyphosphorylated and pyrophosphate derivatives of inositols. The invention also relates to compositions of the polyphosphorylated and pyrophosphate derivatives of inositol and other similar, more lipophilic derivatives, and their use as allosteric effectors, cell-signaling molecule analogs, and therapeutic agents.
    Type: Application
    Filed: December 9, 2013
    Publication date: June 19, 2014
    Applicants: Universite de Strasbourg, NormOxys, Inc.
    Inventors: Jean-Marie Lehn, Srinivasu Pothukanuri, Alexandros Koumbis, Carolina Duarte, Claude Nicolau
  • Patent number: 8674130
    Abstract: A process for producing a cyclic alkylene phosphorohalidite, which comprises reacting a specific phosphorus trihalide with a specific alkylene glycol compound under conditions where the phosphorus trihalide is present in an excess amount relative to the amount of the alkylene glycol compound in the reaction system to order to obtain the cyclic alkylene phosphorohalidite by reacting the alkylene glycol compound with the phosphorus trihalide; and a process for producing a cyclic phosphoric acid ester by using the obtained cyclic alkylene phosphorohalidite as a raw material.
    Type: Grant
    Filed: September 21, 2010
    Date of Patent: March 18, 2014
    Assignee: Daihachi Chemical Industry Co., Ltd.
    Inventors: Toshiya Hamada, Sakiko Hamada
  • Publication number: 20140066646
    Abstract: The present disclosure relates to a non-acidic, sulfur-containing, phosphorus-containing compound of the formula I where R1, R2, R3, R4, R5, R6, and R7 are as defined herein. Such a compound may exhibit improved antiwear performance and thermal stability in lubricating compositions.
    Type: Application
    Filed: November 8, 2013
    Publication date: March 6, 2014
    Applicant: Afton Chemical Corporation
    Inventors: John Marshall Baker, Naresh Mathur, Roger M. Sheets, David J. Degonia
  • Patent number: 8420847
    Abstract: A novel bis-phosphate compound is provided which can be applied to a wide range of reactive substrates and reactions as an asymmetric reaction catalyst and can realize an asymmetric reaction affording a high yield and a high enantiomeric excess. The bis-phosphate compound has a tetraaryl skeleton represented by General Formula (1). In an asymmetric reaction, an amidodiene and an unsaturated aldehyde compound are reacted with each other in the presence of the optically active bis-phosphate compound to give an optically active amidoaldehyde. The invention allows a reaction such as an asymmetric Diels-Alder reaction to proceed efficiently, which has been difficult with conventional mono-phosphate compounds.
    Type: Grant
    Filed: March 8, 2011
    Date of Patent: April 16, 2013
    Assignees: National University Corporation Tohoku University, API Corporation
    Inventors: Masahiro Terada, Norie Momiyama, Tohru Konno
  • Publication number: 20120330038
    Abstract: A novel bis-phosphate compound is provided which can be applied to a wide range of reactive substrates and reactions as an asymmetric reaction catalyst and can realize an asymmetric reaction affording a high yield and a high enantiomeric excess. The bis-phosphate compound has a tetraaryl skeleton represented by General Formula (1). In an asymmetric reaction, an amidodiene and an unsaturated aldehyde compound are reacted with each other in the presence of the optically active bis-phosphate compound to give an optically active amidoaldehyde. The invention allows a reaction such as an asymmetric Diels-Alder reaction to proceed efficiently, which has been difficult with conventional mono-phosphate compounds.
    Type: Application
    Filed: March 8, 2011
    Publication date: December 27, 2012
    Applicants: API Corporation, National University Corporation TOHOKU UNIVERSITY
    Inventors: Masahiro Terada, Norie Momiyama, Tohru Konno
  • Patent number: 8324418
    Abstract: Organic dithiopyrophosphates of formula wherein R1, R2, R3, R4 and R5 independently are hydrogen, C1-4 alkyl, chloromethyl or bromomethyl, are prepared in a two-step process from the corresponding 1,3-diols and thiophosphoryl chloride, using 3-methylpyridine both as solvent and as base.
    Type: Grant
    Filed: October 21, 2009
    Date of Patent: December 4, 2012
    Assignee: Lonza Ltd.
    Inventors: Gesa Paradies, Thomas Riedel, Christian Schnider
  • Publication number: 20120264965
    Abstract: A process for producing a cyclic alkylene phosphorohalidite, which comprises reacting a specific phosphorus trihalide with a specific alkylene glycol compound under conditions where the phosphorus trihalide is present in an excess amount relative to the amount of the alkylene glycol compound in the reaction system to order to obtain the cyclic alkylene phosphorohalidite by reacting the alkylene glycol compound with the phosphorus trihalide; and a process for producing a cyclic phosphoric acid ester by using the obtained cyclic alkylene phosphorohalidite as a raw material.
    Type: Application
    Filed: September 21, 2010
    Publication date: October 18, 2012
    Applicant: DAIHACHI CHEMICAL INDUSTRY CO., LTD.
    Inventors: Toshiya Hamada, Sakiko Hamada
  • Publication number: 20110207955
    Abstract: Organic dithiopyrophosphates of formula wherein R1, R2, R3, R4 and R5 independently are hydrogen, C1-4 alkyl, chloromethyl or bromomethyl, are prepared in a two-step process from the corresponding 1,3-diols and thiophosphoryl chloride, using 3-methylpyridine both as solvent and as base.
    Type: Application
    Filed: October 21, 2009
    Publication date: August 25, 2011
    Applicant: LONZA LTD.
    Inventors: Gesa Paradies, Thomas Riedel, Christian Schnider
  • Publication number: 20100267674
    Abstract: The present invention relates to mixed calcium/sodium salt of inositol tripyrophosphate, methods of preparing and methods of use. The mixed calcium/sodium salt may be a monocalcium tetrasodium salt of inositol tripyrophosphate. Methods of use include administering the above salts in an effective amount to treat diseases caused by hypoxia or other conditions associated with inadequate function of the lungs or circulatory system, such as various types of cancer and Alzheimer's disease.
    Type: Application
    Filed: June 28, 2010
    Publication date: October 21, 2010
    Applicants: NORMOXYS, INC., UNIVERSITE DE STRASBOURG
    Inventors: Yves Claude Nicolau, Jean-Marie Lehn, Konstantina C. Fylaktakidou, Ruth Greferath
  • Patent number: 7728162
    Abstract: A novel process for preparing in a high purity and in a high yield phosphorus compounds having a phosphate-phosphonate bond within one molecule, along with only a small amount of a by-product, without being restricted by the kind of a phosphonate having an alcoholic hydroxyl group which is a raw material, without using a catalyst such as magnesium chloride, but only using a nitrogen-containing basic compound.
    Type: Grant
    Filed: October 18, 2005
    Date of Patent: June 1, 2010
    Assignee: Daihachi Chemical Industry Co., Ltd.
    Inventors: Kazuo Fujimoto, Sakiko Tanaka
  • Publication number: 20100029594
    Abstract: The present invention relates to mixed calcium/sodium salt of inositol tripyrophosphate, methods of preparing and methods of use. The mixed calcium/sodium salt may be a monocalcium tetrasodium salt of inositol tripyrophosphate. Methods of use include administering the above salts in an effective amount to treat diseases caused by hypoxia or other conditions associated with inadequate function of the lungs or circulatory system, such as various types of cancer and Alzheimer's disease.
    Type: Application
    Filed: July 21, 2009
    Publication date: February 4, 2010
    Inventors: Yves Claude Nicolau, Jean-Marie Lehn, Konstantina C. Fylaktakidou, Ruth Greferath
  • Patent number: 6608046
    Abstract: The invention provides novel &bgr;-lactamase inhibitors, which are structurally unrelated to the natural product and semi-synthetic &bgr;-lactamase inhibitors presently available, and which do not possess &bgr;-lactam pharmacophore. These new inhibitors are fully synthetic, allowing ready access to a wide variety of structurally related analogs. Certain embodiments of these new inhibitors also bind bacterial DD-peptidases, thus potentially acting both as &bgr;-lactamase inhibitors and as antibiotics.
    Type: Grant
    Filed: September 1, 2000
    Date of Patent: August 19, 2003
    Assignee: MethylGene, Inc.
    Inventors: Jeffrey M. Besterman, Jubrail Rahil, Rex Pratt
  • Patent number: 6599889
    Abstract: The invention provides novel &bgr;-lactamase inhibitors, which are structurally unrelated to the natural product and semi-synthetic &bgr;-lactamase inhibitors presently available, and which do not possess a &bgr;-lactam pharmacophore. These new inhibitors are fully synthetic, allowing ready access to a wide variety of structurally related analogs. Certain embodiments of these new inhibitors also bind bacterial DD-peptidases, thus potentially acting both as &bgr;-lactamase inhibitors and as antibiotics.
    Type: Grant
    Filed: March 1, 2001
    Date of Patent: July 29, 2003
    Assignee: MethylGere, Inc.
    Inventors: Jeffrey M. Besterman, Jubrail Rahil, Rex Pratt
  • Publication number: 20030109736
    Abstract: The phosphorus-containing compound of the present invention is represented by the following formula (I), (II) or (III): 1
    Type: Application
    Filed: December 26, 2001
    Publication date: June 12, 2003
    Inventors: Yoko Onchi, Ikuo Takahashi
  • Publication number: 20020111487
    Abstract: A bisphosphite of the formula I 1
    Type: Application
    Filed: October 29, 2001
    Publication date: August 15, 2002
    Inventors: Dirk Roettger, Dieter Hess, Klaus-Diether Wiese, Cornelia Borgmann, Armin Borner, Detlef Selent, Reinhard Schmutzler, Christine Kunze
  • Patent number: 5852197
    Abstract: The invention relates to cyclic diphosphoric esters of the formula ##STR1## with R=methylethylene, 1,3-cyclohexylene, 1,4-cyclo-hexylene or 1,3-phenylene, a process for their preparation and their use as flame retardants.
    Type: Grant
    Filed: July 15, 1996
    Date of Patent: December 22, 1998
    Assignee: Hoechst Aktiengellschaft
    Inventor: Horst Staendeke
  • Patent number: 5401788
    Abstract: Organic phosphorus compounds of the formula (I): ##STR1## wherein R.sub.1 and R.sub.2 are, the same or different, a C.sub.1-8 straight chain or branched chain alkyl group, an optionally substituted C.sub.6-12 aryl group; and A represents a bond, a lower alkylene group or --(OCH.sub.2 CH.sub.2).sub.n -- group, (n is an integer of 1 to 5), which are useful as flame-retardants.
    Type: Grant
    Filed: March 10, 1994
    Date of Patent: March 28, 1995
    Assignee: Daihachi Chemical Industry Co., Ltd.
    Inventors: Noriaki Tokuyasu, Tatsushi Ono, Katsumi Kameda
  • Patent number: 5362898
    Abstract: A bis(pentaerythritol phosphate alcohol) alkylphosphonate compound, such as one comprising an alkyl group of from about one to four carbon atoms, preferably bis(pentaerythritol phosphate alcohol) methylphosphonate, is a flame retardant compound. Such a compound can be prepared by the transesterification of a diphenyl alkyl phosphonate carrying the desired alkyl group with pentaerythritol phosphate alcohol. An alternative process of preparation comprises the reaction of pentaerythritol phosphate alcohol, a trialkylamine, and an alkylphosphonic dihalide.
    Type: Grant
    Filed: November 22, 1993
    Date of Patent: November 8, 1994
    Assignee: Akzo Nobel nv
    Inventor: Jeffrey E. Telschow
  • Patent number: 5300617
    Abstract: A method for producing a potassium para-diphenyl phosphino sulfonate ligand which comprises reacting potassium diphenyl phosphide with a lithium salt of para-chloro benzenesulfonic acid in the presence of tetrahydrofuran at elevated temperatures.
    Type: Grant
    Filed: January 21, 1993
    Date of Patent: April 5, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Elena N. Suciu, Joel R. Livingston, Jr., Edmund J. Mozeleski
  • Patent number: 5239103
    Abstract: 3,7,9-Trioxa-1-aza-2,8-diphosphaspiro[4.5]decanes of formula I ##STR1## wherein R.sub.1 and R.sub.2 are independently hydrogen, alkyl, cycloalkyl, bicycloalkyl, tricycloalkyl or aryl; or can be halogen when n or m is zero,R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are independently hydrogen, alkyl, aralkyl or aryl;X and Y are independently --O--, --S-- or --NR.sub.16 -- where R.sub.16 is alkyl, cycloalkyl, alkenyl, aryl or aralkyl;W and Z are independently O or S; andn, m, o and p are independently zero or 1, are effective in stabilizing organic materials against the deleterious effects of oxygen, heat and/or actinic radiation.
    Type: Grant
    Filed: November 12, 1992
    Date of Patent: August 24, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Raymond Seltzer, Paul A. Odorisio, Sai P. Shum, Stephen D. Pastor
  • Patent number: 5075482
    Abstract: 3,7,9-Trioxa-1-aza-2,8-diphosphaspiro[4.5]decanes of formula I ##STR1## wherein R.sub.1 and R.sub.2 are independently hydrogen, alkyl, cycloalkyl, bicycloalkyl, tricycloalkyl or aryl; or can be halogen when n or m is zero,R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are independently hydrogen, alkyl, aralkyl or aryl;X and Y are independently --O-- --S--, or --NR.sub.16 -- where R.sub.16 is alkyl, cycloalkyl, alkenyl, aryl or aralkyl;W and Z are independently O or S; andn, m, o and p are independently zero or 1, are effective in stabilizing organic materials against the deleterious effects of oxygen, heat and/or actinic radiation.
    Type: Grant
    Filed: August 23, 1990
    Date of Patent: December 24, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Raymond Seltzer, Paul A. Odorisio, Sai P. Shum, Stephen D. Pastor
  • Patent number: 4673701
    Abstract: Alkylidene bisphenol phosphites and phosphates having 2,2,6,6-tetramethyl piperidinyl groups are provided having the formula: ##STR1## wherein: R.sub.1 is alkyl having from one to about twelve carbon atoms;R.sub.2, R.sub.3 and R.sub.4 are each selected from the group consisting of hydrogen and alkyl having from one to about twelve carbon atoms;m is 0 or 1;n is 0 or 1;X is selected from the group consisting of ##STR2## wherein: R.sub.5 is selected from the group consisting of hydrogen, oxyl O.sup.2, alkyl having from one to about twelve carbon atoms; arylalkyl having from seven to about eighteen carbon atoms; 2,3-epoxypropyl, acyl having from one to about eight carbon atoms and ##STR3## in which R.sub.6 is selected from the group consisting of hydrogen, alkyl having from one to about twelve carbon atoms and phenyl, and Y.sub.1 is selected from the group consisting of hydrogen; acyl having from one to about twelve carbon atoms; and ##STR4## Z.sub.1 is selected from the group consisting of ##STR5## wherein R.
    Type: Grant
    Filed: December 28, 1984
    Date of Patent: June 16, 1987
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Motonobu Minagawa, Yutaka Nakahara, Toshihiro Shibata, Ryozo Arata