Sulfur, Oxygen, Halogen Or Group Ia Or Iia Light Metal Containing Patents (Class 568/6)
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Publication number: 20090005344Abstract: Imidazole and benzimidazole boronic acid compounds, analogs thereof, and pharmaceutical formulations are described, along with methods of use thereof for inhibiting inflammatory cytokines such as tumor necrosis factor alpha (TNF-?) in a subject in need thereof.Type: ApplicationFiled: October 27, 2005Publication date: January 1, 2009Applicant: NKUADA, LLCInventors: James F. Burns, Leonardo A. Cabana, Glenn C. Collupy, John R. Didsbury, Tatyana A. Dyakonov, Simon N. Haydar, Michael L. Jones, Francine F. Li, Christopher J. Markworth, Jessymol Mathew, Frank J. Schoenen, David S. Van Vliet, David Middlemiss
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Publication number: 20080306302Abstract: A process for the preparation of organic cation tetrakis(Faryl) borate salts. The process includes preparation of intermediate, mono-hydrazine substituted (Faryl) compound, from (Faryl) compound using hydrazine at temperatures below 78° C. A stoichiometric excess of hydrazine to the (Faryl) compound to the (Faryl) compound is used. The process further includes the preparation of the organic cation tetrakis(Faryl) borate in ethereal medium.Type: ApplicationFiled: December 8, 2006Publication date: December 11, 2008Inventor: Bruce C. Berris
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Publication number: 20080297034Abstract: The invention provides a novel compound used as a material for organic light-emitting elements, and an organic light-emitting element which has highly efficient and highly luminescent optical power and is superior in durability. The organic light-emitting element includes an anode and a cathode, and a layer which contains an organic compound and is held between the anode and the cathode.Type: ApplicationFiled: April 1, 2008Publication date: December 4, 2008Applicant: CANON KABUSHIKI KAISHAInventors: Shigemoto Abe, Akihiro Senoo, Jun Kamatani, Satoshi Igawa, Naoki Yamada
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Publication number: 20080300426Abstract: Provided is a new and improved process for preparing a borated alkaline earth metal toluene sulfonate salt.Type: ApplicationFiled: May 30, 2007Publication date: December 4, 2008Inventors: Perla Duchesne, John McDonald, Gilles Sinquin, Pierre Tequi
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Publication number: 20080262139Abstract: Disclosed is a flame retardant crosslink agent free of halogen and phosphorous. The crosslink agent can be applied in epoxy resin composition, such that the composition achieves V0 under UL-94 standard after curing. The crosslink agent, a novolac structure modified by nitrogen-containing and/or silicon containing compound, may collocate with inorganic powder, such that the thermal cured epoxy resin composition contains thermal retardancy, low expansion, low water uptake, and high glass transfer temperature properties. The epoxy resin composition including the crosslink agent of the invention can be applied in a prepreg used in copper clad laminates or printed circuit plates.Type: ApplicationFiled: September 12, 2007Publication date: October 23, 2008Inventors: Hsin-Ho Wu, Weita Yang, Ching Cheng Hsueh
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Publication number: 20080248636Abstract: Methods of implanting boron-containing ions using fluorinated boron-containing dopant species that are more readily cleaved than boron trifluoride. A method of manufacturing a semiconductor device including implanting boron-containing ions using fluorinated boron-containing dopant species that are more readily cleaved than boron trifluoride. Also disclosed are a system for supplying a boron hydride precursor, and methods of forming a boron hydride precursor and methods for supplying a boron hydride precursor. In one implementation of the invention, the boron hydride precursors are generated for cluster boron implantation, for manufacturing semiconductor products such as integrated circuitry.Type: ApplicationFiled: August 30, 2006Publication date: October 9, 2008Applicant: ADVANCED TECHNOLOGY MATERIALS, INC.Inventors: W. Karl Olander, Jose I. Arno, Robert Kaim
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Publication number: 20080241754Abstract: A radiation-sensitive composition includes a free-radically polymerizable component, an initiator composition capable of generating free radicals sufficient to initiate polymerization upon exposure to imaging radiation, an infrared radiation absorbing compound, and a polymeric binder. The initiator composition includes a unique polyonium borate comprising a polyvalent onium cation with multiple onium moieties and sufficient organic borate counterions to provide a net neutral charge. The radiation-sensitive composition can be used to prepare a negative-working imageable element that is sensitive to suitable imaging infrared radiation, can be imaged at relatively low energy, and can be developed either on-press or off-press.Type: ApplicationFiled: March 28, 2007Publication date: October 2, 2008Inventors: Koji Hayashi, Jianbing Huang
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Publication number: 20080242859Abstract: The present invention provides compounds which are useful as safe substitutes for the organotin reagent used in coupling reaction for the oxymethylation of aromatic rings, such as alkoxymethylation or hydroxymethylation, with a palladium catalyst and which can dispense with chromatographic purification with silica gel in the production and are suitable for mass production; and compounds applicable even to the oxymethylation of aromatic ring substrates which do not permit coupling reaction by conventional technique or have low reactivity.Type: ApplicationFiled: March 13, 2006Publication date: October 2, 2008Applicant: Eisai R&D Management Co., LtdInventors: Keigo Tanaka, Satoshi Inoue, Daisuke Ito, Norio Murai, Yosuke Kaburagi, Shuji Shirotori, Shuichi Suzuki, Yoshiaki Ohashi
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Patent number: 7429671Abstract: A process for fluorination of borohydride salts including providing a reaction medium comprising HF and a superacid. A borohydride salt compound is added to the reaction medium. The borohydride salt is reacted with the reaction medium under conditions to form a fluorinated borohydride salt. In addition, reactor vessels may be provided for reacting the HF, superacid additive and borohydride that are fabricated from materials resistant to superacid compositions.Type: GrantFiled: December 6, 2006Date of Patent: September 30, 2008Assignee: Air Products and Chemicals, Inc.Inventors: Wade H. Bailey, III, William Jack Casteel, Jr., Sergei Vladimirovich Ivanov, Xukun Luo
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Publication number: 20080234229Abstract: The present invention is directed to compounds having the structure Formula (I) wherein R1, R2, R3, R4, R5 and m are as defined herein. The compounds of this invention are novel therapeutic agents for the treatment of cancer, metabolic diseases and skin disorders in mammalian subjects. These compounds are also useful modulators of gene expression. They exert their activity by interfering with certain cellular signal transduction cascades. The compounds of the invention are thus also useful for regulating cell differentiation and cell cycle processes that are controlled or regulated by various hormones or cytokines. In particular, the invention relates to compounds that induce apoptosis of cancer cells and therefore may be used for the treatment or prevention of cancer, including advanced cancers and pre-cancerous cells. The invention also discloses pharmaceutical compositions and methods of treatment of disease in mammals.Type: ApplicationFiled: August 17, 2006Publication date: September 25, 2008Applicant: AUSPEX PHARMACEUTICALS, INC.Inventor: Sepehr Sarshar
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Publication number: 20080221069Abstract: The present invention is directed to novel compounds according to formula (I) wherein R1, R2, and X are as defined herein. The invention also discloses methods of preparation, pharmaceutical compositions, and methods of disease treatment utilizing pharmaceutical compositions comprising these compounds. The compounds of this invention are novel therapeutic agents for the treatment of cancer, diabetes, metabolic diseases and skin disorders in mammalian subjects. These compounds are also useful modulators of gene expression. They exert their activity by interfering with certain cellular signal transduction cascades. The compounds of the invention are thus also useful for regulating cell differentiation and cell cycle processes that are controlled or regulated by various hormones or cytokines. The invention also discloses pharmaceutical compositions and methods of treatment of disease in mammals.Type: ApplicationFiled: August 31, 2006Publication date: September 11, 2008Applicant: AUSPEX PHARMACEUTICALS, INC.Inventor: Sepehr Sarshar
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Publication number: 20080214829Abstract: The invention relates to salts having alkoxytris(fluoroalkyl)borate anions which on the one hand are used for the synthesis of ionic liquids, but on the other hand can be employed per se as ionic liquid, and to processes for the preparation thereof.Type: ApplicationFiled: July 9, 2005Publication date: September 4, 2008Inventors: Nikola (Mykola) Ignatyev, Urs Welz-Biermann, Maik Finze, Eduard Bernhardt, Helge Willner
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Publication number: 20080200728Abstract: The invention relates to a process for the synthesis of dialkoxyorganoboranes, in particular to a process for the synthesis of dialkoxyorganoboranes by an ester exchange reaction. Moreover, the invention relates to a process for the synthesis of organo-oxazaborolidine catalysts (organo-CBS) and of trialkylboroxins. Furthermore, the invention relates to methods of using dialkoxyorganoboranes for the preparation of organo-CBS catalysts and in Suzuki-type coupling reactions.Type: ApplicationFiled: June 9, 2006Publication date: August 21, 2008Applicant: BASF AktiengesellschaftInventors: Elizabeth Burkhardt, William Atkins
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Publication number: 20080175781Abstract: Metal hydride materials react with BZ3 compounds in the presence of ligand to form BH3-L compounds. A compound of the formula HBZ2 is prepared from a compound of the formula BZ3 by reacting a first amount of a compound of the formula HBZ2 with a metal hydride material “MH” and a compound “L” to form a material of the formula BH3-L, and then reacting the BH3-L thus formed with a compound of the formula BZ3 to form HBZ2 in a second amount greater than the first amount of HBZ2. Z is selected from alkoxy, aryloxy, amido, arylamido, doubly substituted alkoxy, doubly substituted aryloxy, doubly substituted amido, doubly substituted arylamido, alkoxy-amido, and aryloxy-arylamido. When Z is bidentate, then HBZ2 has a ring structure. “L” is selected from ethers, aromatic ethers, amines, aromatic amines, heterocyclic nitrogen compounds, sulfides, aromatic sulfides, and heterocyclic sulfur compounds. “L” becomes a ligand in the BH3-L material.Type: ApplicationFiled: September 13, 2007Publication date: July 24, 2008Inventors: David L. Thorn, William Tumas
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Publication number: 20080171723Abstract: The present invention relates to novel boronic acid aryl derivatives which are useful as antitumor/anticancer agents. The present compounds, which are inexpensive to synthesize, exhibit unexpectedly good inhibitors of the growth of human breast cancer cells. The present invention also relates to the use of the novel boronic acid aryl derivatives to treat cancer. The invention also provides pharmaceutical compositions comprising the inhibitors of the invention and methods of utilizing the inhibitors and pharmaceutical compositions in the treatment and prevention of cancer.Type: ApplicationFiled: December 21, 2004Publication date: July 17, 2008Applicant: John Hopkins University, Johns Hopkins Technology TransferInventor: Saeed R. Khan
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Publication number: 20080154065Abstract: A method for stabilizing an aryl boron compound of formula (1): wherein Ar1, Ar2, and Ar3 are aryl groups, including mixing a compound which has higher affinity for the aryl boron compound than water, as a stabilizer, in a solution or slurry containing the aryl boron compound in a hydrocarbon solvent; and a stabilized composition obtained thereby. The stabilizing method and the stabilized composition of the present invention make it possible to store aryl boron compounds stably over a long term, while keeping their high purity, in the form of forming a substantially homogeneous system in the case of a solution or in the form of forming a substantially homogeneous system by heating in the case of slurry.Type: ApplicationFiled: January 25, 2006Publication date: June 26, 2008Inventor: Ikuyo Katsumi
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Publication number: 20080139851Abstract: A process is used for the preparation of 1,3,2-oxazaborolidine compounds. This process prepares compounds of formula (I) or (IA): in which: R1 is an alkyl or an aryl; and R2, R3, R4 and R5 are especially a hydrogen atom or an alkyl, wherein the following are reacted in two steps: a) a boric precursor compound with an acetal compound to give a boronate compound; and b) the boronate compound with an amino alcohol compound. This process avoids by-products and exhibits a very good stereospecificity.Type: ApplicationFiled: January 25, 2007Publication date: June 12, 2008Applicant: PPG-SIPSYInventors: Alain Burgos, Stephane Frein
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Publication number: 20080125602Abstract: In order to synthesize an ionic metal complex having a chemical structural formula represented by the formula (1), at least one of a compound represented by the formula (2) and a compound represented by the formula (3) is reacted with a halogen-containing compound represented by the formula (4) or formula (5), in an organic solvent, in the presence of a compound containing an element of group 1, group 2, group 13 or group 14 of the periodic table as a reaction aid.Type: ApplicationFiled: January 24, 2006Publication date: May 29, 2008Applicant: Central Glass Company, LimitedInventors: Yoshimi Isono, Syoichi Tsujioka
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Publication number: 20080124569Abstract: An electroluminescent material is a complex of boron and a beta diketone.Type: ApplicationFiled: November 4, 2005Publication date: May 29, 2008Applicant: OLED-T LIMITEDInventors: Poopathy Kathirgamanathan, Sivagnanasundram Surendrakumar
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Publication number: 20080102279Abstract: A borate for a near-infrared ray absorption material, having an anion represented by the formula (1): [BR1mR24?m]? (wherein R1 represents an aryl group having an electron withdrawing group; R2 represents an organic group, a halogen group or a hydroxyl group; and m is an integer in the range of 1 to 4) is provided. The borate of the present invention enables to improve durability, in particular, heat resistance and moisture resistance of a near-infrared ray absorbing dye.Type: ApplicationFiled: January 30, 2006Publication date: May 1, 2008Applicant: NIPPON SHOKUBAI CO., LTD.Inventors: Akio Ito, Satoshi Ishida, Toshiya Iida, Takako Ishii, Nobuhiro Nobayashi
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Patent number: 7339081Abstract: A process for preparing bromo-1-oxypentafluorosulfanylbenzene is provided, the process including the step of brominating pentafluorosulfanyloxybenzene with a bromination agent to provide the bromo-1-oxypentafluorosulfanylbenzene. The process is more effective than prior art processes for preparing such compounds.Type: GrantFiled: July 10, 2006Date of Patent: March 4, 2008Assignee: Air Products and Chemicals, Inc.Inventors: Robert George Syvret, Gauri Sankar Lal
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Patent number: 7332551Abstract: Non-coordinating anions or anion precursors are disclosed. These non-coordinating anions serve as the activator for olefin polymerization catalyst systems. As such, they abstract an alkyl leaving group from a metallocene catalyst precursor leaving an activated catalyst charge balanced by a non-coordinating anion. These anions are formed by 3 or 4 partially fluorinated naphthyl ligands coordinated around boron (or other Group-13 element) creating corresponding tris-borane or tetrakis-borate complexes.Type: GrantFiled: November 12, 2002Date of Patent: February 19, 2008Assignee: ExxonMobil Chemical Patents Inc.Inventors: George Rodriguez, Francis C. Rix, Periagaram S. Ravishankar, Matthew C. Kuchta
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Patent number: 7329781Abstract: The present invention relates to a method of preparing main group boryl compounds by reacting main group hydrides with hydroborating reagents in the presence of a transition metal catalyst.Type: GrantFiled: February 21, 2006Date of Patent: February 12, 2008Inventors: Stephen A. Westcott, Jonathan D. Webb, Daniel I. McIsaac, Christopher M. Vogels
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Patent number: 7297653Abstract: A fluorophenylborate useful as an activator for an olefin polymerization catalyst is represented by the formula: Ct+[B—(ArfRn)4]? where Ct+ is a cation capable of extracting an alkyl group from, or breaking a carbon-metal bond of, an organo metallic compound; Arf is a fluorophenyl group; n is 1 or 2; and each R is independently selected from a fluorophenyl group and a fluoronaphthyl group, provided that when n=1, each R group is connected at the 3-position relative the connection between the associated Arf group and the boron atom and, when n=2; the R groups are connected at the 3-position and the 5-position respectively relative the connection between the associated Arf group and the boron atom.Type: GrantFiled: July 21, 2005Date of Patent: November 20, 2007Assignee: ExxonMobil Chemical Patents Inc.Inventor: George Rodriguez
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Patent number: 7211636Abstract: An ionic compound comprising a cationic portion having a hydroxyl group and/or a carboxylic acid group and an anionic portion of the formula (1): [BR4]???(1) wherein R may be the same or different and represents a phenyl group substituted with F or CF3. Preferably, the anionic portion is [B(C6F5)4]?, [B(C6H4CF3)4]? or [B(C6H3F2)4]?. In other aspects, a radiation polymerization initiator and a resin composition comprising the ionic compound are provided. A resin composition prepared by using the radiation polymerization initiator generates a small amount of outgas during reaction and has excellent reactivity and transparency.Type: GrantFiled: June 22, 2005Date of Patent: May 1, 2007Assignee: Mitsui Chemicals, Inc.Inventors: Yugo Yamamoto, Yasushi Mizuta
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Patent number: 7196219Abstract: A process for preparing anilineboronic acid derivative of the formula I, by converting an aniline to a diprotected aniline by introducing two protecting groups, metalating the diprotected aniline with a metalating agent and simultaneously or subsequently reacting with a boronic ester B(OR1,2,3)3 to form a protected anilineboronic ester, which is converted, by detaching the protecting groups, to the anilineboronic esters of the formula (I).Type: GrantFiled: May 14, 2004Date of Patent: March 27, 2007Assignee: Archimica GmbHInventors: Stefan Scherer, Andreas Meudt, Bernd Lehnemann, Alexei Kalinin, Victor Snieckus
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Patent number: 7153975Abstract: A method of making a metal complex comprises combining a 1-monoacyldipyrromethane with a compound of the formula R1R2MX, wherein M is boron, R1 and R2 are each independently organic substituents; and X is an anion leaving group; to produce a metal complex of the formula DMR1R2 wherein DH is a 1-monoacyldipyrromethane. The methods and complexes are useful for the purification and synthesis of dipyrromethanes and porphyrins.Type: GrantFiled: June 18, 2004Date of Patent: December 26, 2006Assignee: North Carolina State UniversityInventors: Jonathan S. Lindsey, Kannan Muthukumaran, Marcin Ptaszek, H. Z. Syeda Huma
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Patent number: 7145040Abstract: The present invention provides process useful for the preparation of intermediates which are useful in the preparation of amino acids useful in preparing peptide receptor modulators, for example agonists or partial agonists of such peptide receptors. Such peptide receptor modulators include, for example glucagon like peptide-1 receptor modulators which are useful for the amelioration of the diabetic condition.Type: GrantFiled: June 30, 2005Date of Patent: December 5, 2006Assignee: Bristol-Myers Squibb Co.Inventors: Arvind Mathur, K. Selva Kumar
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Patent number: 7115539Abstract: A metal compound obtained by a process comprising the step of contacting, in a specific ratio, a compound represented by the formula M1L1r, a compound represented by the formula R1s?1TH, and a compound represented by the formula R24?nJ(OH)n; a catalyst component for addition polymerization comprising the metal compound; a catalyst for addition polymerization using the catalyst component; and a process for producing an addition polymer using the catalyst.Type: GrantFiled: January 9, 2004Date of Patent: October 3, 2006Assignee: Sumitomo Chemical Company LimitedInventors: Kazuo Takaoki, Hideki Oshima, Makoto Satoh
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Patent number: 7087780Abstract: The liquid ethereal medium or liquid hydrocarbyl medium of a solution or slurry of an alkali metal tetrakis(Faryl)borate is substituted with at least one halogenated hydrocarbon, without isolating the alkali metal tetrakis(Faryl)borate, to form a new slurry or solution. At least a portion of the new solution is mixed together with a salt selected from a) a protic ammonium salt, b) an onium salt, and c) a triarylmethyl salt, to produce a protic ammonium tetrakis(Faryl)borate, an onium tetrakis(Faryl)borate, or a triarylmethyl tetrakis(Faryl)borate.Type: GrantFiled: June 24, 2004Date of Patent: August 8, 2006Assignee: Albemarle CorporationInventors: John Y. Lee, Rajeev S. Mathur
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Patent number: 7077977Abstract: A discrete polyolefin catalyst activator is disclosed. A salient feature of invention borate-based activators is that at least one of the ligands on the borate non-coordinating anion (NCA) comprises a fluorinated aryl group linked to the boron atom through an acetylenic group appropriate pairing of invention activators with olefin polymerization. Catalyst precursors yield increased catalytic activity. Polymerization results are disclosed.Type: GrantFiled: December 3, 2002Date of Patent: July 18, 2006Assignee: ExxonMobil Chemical Patents Inc.Inventors: George Rodriguez, Francis C. Rix, Matthew C. Kuchta, John F. Walzer, Jr.
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Patent number: 7067653Abstract: The invention describes the synthesis of a panel of novel carbon-carbon linked carboranyl-containing 5,10,15,20-tetraphenylporphyrins bearing 25–44% boron by weight. In certain embodiments, a phenyl porphyrin compound has a carboranyl group attached to the phenyl group by a carbon-carbon linkage, wherein the phenyl group corresponds to the following formula where R7 through R11 are hydrogen, a carboranyl group, or are selected from the group consisting of hydroxyl, NMe3+, PMePh2+, PO(OH)2, SO3H, COOH, and NH2. In this embodiment, the carboranyl group is attached to the phenyl group by a carbon-carbon linkage, either one or two of R7 through R11 are other than hydrogen; and the phenyl porphyrin compound contains at least one phenyl group having at least one of said carboranyl groups.Type: GrantFiled: May 9, 2001Date of Patent: June 27, 2006Assignee: The Regents of the University of CaliforniaInventors: Maria Da Graca H. Vicente, Shankar Jayaram Shetty, Laurent Jaquinod, Kevin M. Smith
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Patent number: 6958420Abstract: A process is described for synthesizing aminoarylboronic esters of the general formula wherein R, R2, and R3 are each an alkyl, aryl, vinyl, alkoxy, carboxylic esters, amides, or halogen; Ar is any variety of phenyl, naphthyl, anthracyl, heteroaryl; and R1 is alkyl, hydrogen, or aryl. The aminoarylboronic esters are produced via the metal-catalyzed coupling of arylboronic esters of the general formula wherein R and R1 are any non-interfering group and X is chloro, bromo, iodo, triflates, or nonaflates to amines (primary and secondary). In particular, a process is described for the synthesis of the aminoarylboronic esters via a step-wise or tandem process in which one catalytic event is a metal-catalyzed borylation and the other catalytic event is a metal-catalyzed amination.Type: GrantFiled: July 18, 2003Date of Patent: October 25, 2005Assignee: Board of Trustees of Michigan State UniversityInventors: Robert E. Maleczka, Jr., Milton R. Smith, III, Daniel Holmes
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Patent number: 6849767Abstract: A method of hydroborating an alkene or alkyne, or reducing an organic functionality, oxidizing primary and secondary alcohols using a fluorous borane-sulfide is disclosed. The method includes regeneration and recycling the fluorous borane-sulfide.Type: GrantFiled: July 24, 2003Date of Patent: February 1, 2005Assignee: The Board of Trustees of the University of IllinoisInventors: David C. Crich, Santhosh Neelamkavil
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Patent number: 6849752Abstract: The invention relates to a process for synthesizing an ionic metal complex represented by the general formula (1) or (5). This process includes reacting in an organic solvent a compound (corresponding to ligand of the complex) represented by the general formula (2) or (6) with a halogen-containing compound represented by the general formula (3) or (4), in the presence of a reaction aid containing an element selected from the group consisting of elements of groups 1-4 and 11-14 of the periodic table. It is possible by this process to easily and efficiently synthesize the ionic metal complex, which can be used as a supporting electrolyte for electrochemical devices, a polymerization catalyst of polyolefins and so forth, or a catalyst for organic synthesis.Type: GrantFiled: November 1, 2002Date of Patent: February 1, 2005Assignee: Central Glass Company, Ltd.Inventors: Shoichi Tsujioka, Hironari Takase, Mikihiro Takahashi, Yoshimi Isono
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Patent number: 6841635Abstract: Disclosed are internally blocked borates useful for polymerizable compositions, and polymerizable adhesives made therewith. The internally blocked borates have general structures: wherein X represents —CHR6—, oxygen or sulfur; n is an integer; R1, R2, R3, R4, R5, and R6 are independently selected, for example, from unsubstituted and substituted C1-C10 alkyl, alkylene groups, or aryl groups, including other embodiments further defined, and M is a counter ion with positive charge m.Type: GrantFiled: September 9, 2003Date of Patent: January 11, 2005Assignee: Lord CorporationInventors: Jonathan L. Kendall, Robin F. Righettini, Kirk J. Abbey
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Patent number: 6831200Abstract: The liquid ethereal medium or liquid hydrocarbyl medium of a solution or slurry of an alkali metal tetrakis(Faryl)borate is substituted with at least one halogenated hydrocarbon, without isolating the alkali metal tetrakis(Faryl)borate, to form a new slurry or solution. At least a portion of the new solution is mixed together with a salt selected from a) a protic ammonium salt, b) an onium salt, and c) a triarylmethyl salt, to produce a protic ammonium tetrakis(Faryl)borate, an onium tetrakis(Faryl)borate, or a triarylmethyl tetrakis(Faryl)borate.Type: GrantFiled: October 3, 2002Date of Patent: December 14, 2004Assignee: Albemarle CorporationInventors: John Y. Lee, Rajeev S. Mathur
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Patent number: 6812360Abstract: Bis(fluoroaryl)borane derivative is produced by reacting tris(fluoroaryl)borane with a compound, such as water, ethanol, ammonia and the like, in a hydrocarbon solvent at a molar ratio raging from 1:0.9 to 1:1.1. It is more preferable that the reaction is carried out while the hydrocarbon solvent is distilled off. It is more preferable that hydrocarbon solvent is substantially an aliphatic hydrocarbon solvent. With this arrangement, it is possible to provide a method for producing and isolating the bis(fluoroaryl)borane derivative of a high purity, with ease and at a low cost.Type: GrantFiled: September 9, 2002Date of Patent: November 2, 2004Assignee: Nippon Shokubai Co., Ltd.Inventors: Ikuyo Ikeno, Hitoshi Mitsui, Toshiya Iida, Toshimitsu Moriguchi
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Patent number: 6809209Abstract: The invention addresses an composition of matter comprising a cation [Ct]+ and an anion [A]−, the anion comprises a core Group-13 element bound to partially or completely fluorinated fluoroaryl ligands, at least one of the fluoroaryl ligands is substituted with a Group-15 element that has been rendered essentially inert for subsequent chemical reaction through its unbonded electron pair by substituting an electron-withdrawing group on it. [Ct]+ may be selected from anilinium and ammonium cations, trityl carbenium cations, Group-11 metal cations, silylium cations, the cations of the hydrated salts of Group-1 or -2 metals, and derivatives of the foregoing anilinium, ammonium, trityl carbenium, and silylium cations containing C1-C20 hydrocarbyl, hydrocarbylsilyl, or hydrocarbylamine substituents for one or more hydrogen atoms of said cations.Type: GrantFiled: September 17, 2002Date of Patent: October 26, 2004Assignee: ExxonMobil Chemical Patents Inc.Inventor: George Rodriguez
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Patent number: 6781005Abstract: This invention relates to an improvement in a liquid phase process for the direct fluorination of borohydride salts including the B10H10−2 and B12H12−2 salts wherein said borohydride salt is contacted with fluorine, under conditions for forming said fluorinated borohydride salt. The improvement in the liquid phase process resides in effecting the fluorination of said borohydride salt in the presence of a reaction medium having an acidity between that of water and anhydrous HF. More specifically, the reaction medium should have a Hammett acidity, Ho, between 0>Ho>−11.Type: GrantFiled: May 1, 2003Date of Patent: August 24, 2004Assignee: Air Products and Chemicals, Inc.Inventors: William Jack Casteel, Jr., Sergei Vladimirovich Ivanov
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Patent number: 6767654Abstract: This invention relates to a borane derivative represented by the formula (1) and an organic electroluminescent device: wherein R1 to R8 and Z2 are each independently a hydrogen atom, a saturated or unsaturated hydrocarbon group, an aromatic group, a heterocyclic group, a substituted amino group, a substituted boryl group, an alkoxy group or an aryloxy group; X, Y and Z1 are each independently a saturated or unsaturated hydrocarbon group, an aromatic group, a heterocyclic group, a substituted amino group, an alkoxy group or an aryloxy group; substituents of Z1 and Z2 may be united to form a condensed ring; and n is an integer of 1-3; with the provisos that when n is two or more, Z1s may be different from each other; and that cases where n is 1, X, Y and R2 are each methyl, and R8 is hydrogen or substituted boryl and those where n is 3 and Z1 is methyl are excluded.Type: GrantFiled: August 24, 2001Date of Patent: July 27, 2004Assignee: Chisso CorporationInventors: Kouhei Tamao, Shigehiro Yamaguchi, Manabu Uchida, Takaharu Nakano, Toshihiro Koike, Takenori Izumizawa, Kenji Furukawa
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Publication number: 20040116747Abstract: A method of hydroborating an alkene or alkyne, or reducing an organic functionality, oxidizing primary and secondary alcohols using a fluorous borane-sulfide is disclosed. The method includes regeneration and recycling the fluorous borane-sulfide.Type: ApplicationFiled: July 24, 2003Publication date: June 17, 2004Inventors: David C. Crich, Santhosh Neelamkavil
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Patent number: 6713566Abstract: This invention relates to a process for covalently coupling organic compounds which comprises: reacting an olefinic compound having at least one carbon to carbon double bond or an acetylenic compound having at least one carbon to carbon triple bond with a diboron derivative in the presence of a Group 8-11 metal catalyst to form an organoboron intermediate having an organoboronate residue on at least one carbon atom of the respective double or triple bond; and reacting the organoboron intermediate with an organic compound having a halogen or halogen-like substituent at a coupling position in the presence of a Group 8-11 metal catalyst and a suitable base, whereby the olefinic or acetylenic compound is coupled to the organic compound via a direct bond between the carbon atom having the organoboronate residue and the coupling posiitijno.Type: GrantFiled: August 6, 2001Date of Patent: March 30, 2004Assignee: Commonwealth Scientific and Industrial Research OrganisationInventors: Sebastian Mario Marcuccio, Mary Rodopoulos, Helmut Weigold, Peter Osvath
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Publication number: 20040053139Abstract: The object of the present invention is to supply organic borates highly soluble even in a solvent of a low dielectric constant; nonaqueous electrolytes made from these organic borates and excellent in characteristics; lithium secondary batteries with improved high-temperature storage characteristics; electric appliances that can be free of protection circuits, and; various applications of the electric appliances.Type: ApplicationFiled: August 15, 2003Publication date: March 18, 2004Applicants: Hitachi, Ltd., Kanto Kagaku Kabushiki KaishaInventors: Juichi Arai, Hideaki Katayama, Mitsuru Kobayashi, Hiroyuki Yamaguchi, Hideki Takahashi, Masaru Kato
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Publication number: 20040034253Abstract: Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.Type: ApplicationFiled: September 3, 2003Publication date: February 19, 2004Inventors: Charles A. Angell, Wu Xu
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Patent number: 6686428Abstract: Compositions and processes of forming chemical bonds, such as carbon-carbon and carbon-heteroatom bonds are provided. The compositions include at least one &agr;-halo carbonyl compound, and one or more transmetallation reagents. The transmetallation reagents are formed by the addition of a metal or metal catalyst to a target compound. The target compound is the compound undergoing chemical bond formation. Bond formation can be carried out in both intermolecular reactions (i.e. between two or more target compounds), or intramolecular (within the same target compound) reactions.Type: GrantFiled: March 29, 2002Date of Patent: February 3, 2004Assignee: The Penn State Research FoundationInventors: Xumu Zhang, Aiwen Lei
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Patent number: 6683218Abstract: A fluoroaryl magnesium derivative expressed by General Formula (1): where each of R1-R5 represents a hydrogen atom, a fluorine atom, a hydrocarbon group, or an alkoxy group while at least one of R1-R5 representing a fluorine atom, and Xa represents a chlorine atom, a bromine atom, or an iodine atom; and boron halide expressed by General Formula (2): BXb3 (2) where Xb represents a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom, are reacted with each other in a solvent (a) containing diethyl ether and/or tetrahydrofuran, after which the resulting reaction solution is added to a solvent (b) having a higher boiling point than diethyl ether and/or tetrahydrofuran while diethyl ether and/or tetrahydrofuran are distilled out.Type: GrantFiled: October 21, 1997Date of Patent: January 27, 2004Assignee: Nippon Shokubai Co., Ltd.Inventors: Hitoshi Mitsui, Ikuyo Katsumi, Naoko Yamamoto
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Patent number: 6635683Abstract: A memberane sensitive to anions is obtained by forming into a membrane either a composition comprising an onium salt compound such as trioctylmethylammonium chloride or tetraoctylammonium bromide, and an aromatic boric diester compound such as (p-alkyloxy)phenyl borate, or a composition which comprises these two ingredients and a membrane-forming polymer such as polyvinyl chloride or polystyrene, and may further contain a fat-soluble anion salt such as tetraphenyl borate. This membrane can yield an ion-selective electrode which permits hydrogencarbonate ions contained in body fluids to be rapidly determined with high sensitivity and high selectivity and which has a long life.Type: GrantFiled: January 26, 2001Date of Patent: October 21, 2003Assignee: Tokuyama CorporationInventors: Hiroaki Taira, Kazuya Ibaragi, Hiromasa Yamamoto, Hiroyuki Yanagi
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Patent number: 6635597Abstract: A catalyst activator particularly adapted for use in the activation of metal complexes of metals of Group 3-10 for polymerization of ethylenically unsaturated polymerizable monomers, especially olefins, comprising a neutral (Lewis acid) or charge separated (cation/anion pair) comprising a boron ligand containing a fluorinated organic group containing from 10 to 1000 non-hydrogen atoms.Type: GrantFiled: May 12, 2000Date of Patent: October 21, 2003Assignee: Northwestern UniversityInventors: Tobin J. Marks, Liting Li, You-Xian Chen, Mark H. McAdon, Peter N. Nickias
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Patent number: RE38325Abstract: A process for preparing tetrakis (pentafluorophenyl) borate is described that involves reaction of a pentafluorophenyl magnesium halide with an alkali metal tetrafluoroborate.Type: GrantFiled: January 18, 2002Date of Patent: November 18, 2003Assignee: Boulder Scientific CompanyInventor: Terry E. Krafft