Product Compound Has More C Atoms Than Feed Compound, E.g., Cyclic Polymerization, Etc. Patents (Class 585/415)
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Patent number: 5212127Abstract: This invention relates to a process for reactivating a dehydrocyclodimerization catalyst. Dehydrocyclodimerization catalysts which contain an aluminum phosphate binder can be deactivated when they are exposed to hydrogen at temperatures above 500.degree. C. The instant process restores substantially all of the catalyst's lost activity. The process involves treating the catalyst with an aqueous solution of a weakly acidic ammonium salt or a dilute acid solution at a temperature of about 50.degree. to about 100.degree. C. for a time of about 1 to about 48 hours. An ammonium nitrate solution is preferred. Next the catalyst is calcined at a temperature of about 500.degree. to about 700.degree. C. for a time of about 1 to about 15 hours to provide a reactivated catalyst. The catalyst can be reactivated several times using this process.Type: GrantFiled: November 8, 1991Date of Patent: May 18, 1993Assignee: UOPInventors: Joseph A. Kocal, Christopher D. Gosling, Paul J. Kuchar, Tamotsu Imai
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Patent number: 5202513Abstract: A process for producing modified crystalline galloalumino silicate having the ZSM-5 crystal structure, and a process for producing aromatic hydrocarbons by the use of a catalyst containing the above modified crystalline galloalumino silicate are disclosed. The modified crystalline galloalumino silicate having the ZSM-5 type crystal structure is produced contacting with a 0.1-2N aqueous alkali hydroxide, followed by calcining galloalumino silicate having the ZSM-5 type crystal structure as obtained by the hydrothermic reaction, at a temperature of 700.degree. to 1,000.degree. C. The aromatic hydrocarbons are produced by contacting hydrocarbons having 2 to 12 carbon atoms with a catalyst containing the above modified crystalline galloalumino silicate.Type: GrantFiled: February 21, 1992Date of Patent: April 13, 1993Assignee: Research Association for Utilization of Light OilInventor: Junichi Kanai
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Patent number: 5191137Abstract: There is provided a molecular sieve coated with a non-oxide ceramic. The molecular sieve may be a zeolite, such as ZSM-5, and the ceramic coating may be, e.g., boron nitride. The coated molecular sieve may be prepared by contacting the molecular sieve with a ceramic precursor material comprising a thermally decomposable material, such as polyborazylene, and thermally decomposing this thermally decomposable material. The coated molecular sieves may be used as organic conversion catalysts. The non-oxide ceramic coating may alter or enhance the shape-selective properties of the molecular sieve by providing a diffusion barrier to molecules.Type: GrantFiled: April 27, 1992Date of Patent: March 2, 1993Assignee: Mobil Oil Corp.Inventor: Jeffrey S. Beck
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Patent number: 5191138Abstract: There is provided a process for converting methane to hydrocarbons having at least two carbon atoms (i.e. higher hydrocarbons). The process involves oxidizing methane with a metal sulfide oxidizing agent. After this conversion of methane, the reduced metal sulfide may be regenerated by oxidation of the reduced metal sulfide.Type: GrantFiled: November 19, 1991Date of Patent: March 2, 1993Assignee: Mobil Oil Corp.Inventors: Scott Han, James N. Michaels, Robert E. Palermo, David L. Stern, Dennis E. Walsh
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Patent number: 5177279Abstract: An integrated process for the conversion of methanol feed to gasoline and distillate range liquid hydrocarbons comprising the steps of splitting the methanol feed into two portions, contacting the first portion of the methanol feed with a medium-pore shape selective zeolite catalyst in a first reaction zone at elevated temperature and moderate pressure to convert the first portion of the methanol feed to hydrocarbons comprising C.sub.2 + olefins; cooling and separating effluent from the first reaction zone to recover a C.sub.3 + olefin hydrocarbon stream and a C.sub.2 - light gas stream; pressurizing the C.sub.3 + olefin hydrocarbon stream and the second portion of the methanol feed and contacting the C.sub.3 + hydrocarbon stream and the methanol feed in a second reaction zone with a medium-pore shape selective oligomerization zeolite catalyst at substantially increased pressure and moderate temperature to convert at least a portion of the C.sub.Type: GrantFiled: October 1, 1991Date of Patent: January 5, 1993Assignee: Mobil Oil CorporationInventor: Mohsen N. Harandi
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Patent number: 5176817Abstract: This invention relates to molecular sieve compositions and processes for using the molecular sieves. The molecular sieves have a three-dimensional microporous crystalline framework structure of tetrahedral oxide units of AlO.sub.2, SiO.sub.2, TiO.sub.2 and/or FeO.sub.2. These molecular sieves can be prepared by contacting a starting zeolite with a solution or slurry of a fluoro salt of titanium and/or iron under effective process conditions to extract aluminum from the zeolite framework and substitute titanium and/or iron. The molecular sieves can be used as catalysts in hydrocarbon conversion processes and other processes.Type: GrantFiled: December 16, 1991Date of Patent: January 5, 1993Assignee: UOPInventors: Gary W. Skeels, Richard Ramos
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Patent number: 5157188Abstract: A method for the oxidative conversion of methane, to higher hydrocarbons, particularly ethylene and ethane, in which a methane-containing gas, such as natural gas, and a free oxygen containing gas are contacted with a contact material selected from the group consisting of:(a) a component comprising: (1) at least one oxide of a metal selected from the group consisting of calcium, strontium and barium and, optionally, a component comprising: (2) at least one material selected from the group consisting of chloride ions, compounds containing chloride ions, tin and compounds containing tin;(b) a component comprising: (1) at least one metal selected from the group consisting of sodium, potassium and compounds containing said metals, a component comprising: (2) at least one metal selected from the group consisting of Group IIA metals and compounds containing said metals, and, optionally, a component comprising: (3) at least one material selected from the group consisting of chloride ions, compounds containing chloriType: GrantFiled: March 19, 1985Date of Patent: October 20, 1992Assignees: Phillips Petroleum Company, Atlantic Richfield CompanyInventors: John H. Kolts, James B. Kimble
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Patent number: 5157189Abstract: A process is disclosed for catalytically converting light hydrocarbons, such as natural gas, to saturated or unsaturated higher molecular weight hydrocarbons, such as ethylene, propylene, ethyl benzene, and styrene. The process employs gaseous catalyst or a mixture of catalysts selected from hydrogen sulfide, hydrogen halides other then hydrogen fluoride, halogen other than fluorine, sulfur vapor, and/or sulfur containing hydrocarbons.Type: GrantFiled: November 21, 1990Date of Patent: October 20, 1992Inventor: Sankaram B. Karra
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Patent number: 5146027Abstract: A method for converting methane to higher hydrocarbon products and coproduct water wherein a gas comprising methane and a gaseous oxidant are contacted with a nonacidic catalyst at temperatures within the range of about 700.degree. to 1200.degree. C. in the presence of a halogen promoter, the contacting being conducted in the substantial absence of alkali metals or compounds thereof.Type: GrantFiled: May 24, 1985Date of Patent: September 8, 1992Assignees: Atlantic Richfield Co., Phillips Petroleum Co.Inventor: Anne M. Gaffney
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Patent number: 5132482Abstract: An improvement in the process for the oxidative coupling of methane is provided. Typically, the reaction takes place in a reactor that includes a catalyst zone. A primary CH.sub.4 /O.sub.2 stream is fed into the entrance of the reactor and reacted at a temperature of 600.degree. C.-1000.degree. C. and a pressure of between 101 kPa and 800 kPa. The improvement comprises introducing an auxiliary oxygen stream directly into the catalyst zone and one or more points to thereby selectively increase the yield of C.sub.2+ products.Type: GrantFiled: June 14, 1990Date of Patent: July 21, 1992Assignee: Alberta Research CouncilInventors: Kevin J. Smith, Jan Z. Galuszka
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Patent number: 5114563Abstract: The catalytic conversion of hydrocarbon feedstocks is affected under effective conversion process conditions in the presence of silicoaluminophosphate-based catalyst compositions.Type: GrantFiled: November 27, 1990Date of Patent: May 19, 1992Assignee: UOPInventors: Brent M. Lok, Celeste A. Messina, Robert L. Patton, Richard T. Gajek, Thomas R. Cannan, Edith M. Flanigen
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Patent number: 5105045Abstract: A method for the oxidative conversion of feed organic compounds, such as methane and ethane, to product organic compounds, such as ethylene, in the presence of a free oxygen containing gas and a contact material comprising: (1) Group IA and/or Group IIA metals/O.sub.2 /halogen; (2) Group IA metals/La Series metals/O.sub.2 /halogen and, optionally, Group IIA metals; (3) Group IA metals/Zn/O.sub.2 /halogen and, optionally, Group IIA metals; (4) Group IA metals/Ti or Zr/O.sub.2 /halogen and, optionally, Group IIA metals; (5) Group IA and/or IIA metals/phosphate/halogen or (6) Co/Zr, Zn, Nb, In, Pb and/or Bi/P/O.sub.2 halogen, and, optionally, Group IA metals and/or S, in which a contact material containing no halogen or an ineffective amount are activated and/or regenerated by contacting them with a halogen and, when the contact material is contact material (6), with a reducing agent or both a reducing agent and a halogen.Type: GrantFiled: October 15, 1990Date of Patent: April 14, 1992Assignee: Phillips Petroleum CompanyInventors: James B. Kimble, John H. Kolts
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Patent number: 5095161Abstract: Methane is upgraded to higher molecular weight hydrocarbons in a process using a novel catalyst comprising oxides of boron, tin and zinc. The feed admixture also comprises oxygen. The novel catalyst may comprise one or more Group I-A or II-A elements, preferably potassium and is characterized by its method of manufacture.Type: GrantFiled: August 6, 1990Date of Patent: March 10, 1992Assignee: UOPInventors: Hayim Abrevaya, Tamotsu Imai, Lisa M. Lane
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Patent number: 5093542Abstract: A method for converting methane to higher hydrocarbon products and coproduct water wherein a gas comprising methane and a gaseous oxidant are contacted with a nonacidic catalyst at temperatures within the range of about 700.degree. to 1200.degree. C. in the presence of a halogen promoter, the contacting being conducted in the substantial absence of alkali metals or compounds thereof.Type: GrantFiled: October 25, 1990Date of Patent: March 3, 1992Assignee: Atlantic Richfield CompanyInventor: Anne M. Gaffney
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Patent number: 5087787Abstract: A method for the oxidative conversion of feed organic compounds to product organic compounds, particularly, the conversion of methane to higher hydrocarbons and the conversion of saturated C.sub.2 to C.sub.7 hydrocarbons to less saturated hydrocarbons, in which the feed compounds are contacted with a free oxygen-containing gas, water and a contact material, comprising at least one Group IIA metal or lanthanum and oxygen; at least two Group IIA metals, Lanthanum Series metals, zinc, or titanium and oxygen; at least one Group IA metal, at least one Group IIA metal, Lanthanum Series metals, zinc or titanium and oxygen; at least one Group IA metal or Group IIA metal, phosphorous and oxygen; cobalt, at least one of zirconium, zinc, nickel, indium, lead or bismuth, phosphorous, at least one Group IA metal and oxygen; or cobalt, at least one Group IA metal, silicon and oxygen.Type: GrantFiled: May 6, 1991Date of Patent: February 11, 1992Assignee: Phillips Petroleum CompanyInventors: James B. Kimble, John H. Kolts
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Patent number: 5077446Abstract: A method for the oxidative conversion of methane, at a high conversion and high selectivity to ethylene and ethane, in which a methane-containing gas, such as a natural gas, and an oxygen-containing gas are contacted with a contact material comprising lithium, in an effective amount, preferably 0.1 to 50 wt. % (expressed as the metal), and magnesium oxide, as by passing a mixture of the methane-containing gas and the oxygen-containing gas through a body of the contact material.Type: GrantFiled: March 19, 1985Date of Patent: December 31, 1991Assignee: Phillips Petroleum CompanyInventors: John H. Kolts, Jack H. Lunsford
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Patent number: 5073673Abstract: A high-octane gasoline is produced by the conversion of a light hydrocarbon containing C.sub.2 -C.sub.7 paraffins and/or C.sub.2 -C.sub.7 olefins using a crystalline aluminogallosilicate containing about 0.1-2.5% by weight of aluminum and about 0.1-5% by weight of gallium in the skeleton thereof and having a particle size in the range of about 0.05-20 .mu.m, with at least 80% by weight of the crystalline aluminogallosilicate having a particle size of 0.1-10 .mu.m.Type: GrantFiled: May 30, 1990Date of Patent: December 17, 1991Assignee: Research Association for the Utilization of Light OilInventors: Kazuo Hirabayashi, Tadami Kondoh, Hiroaki Nishijima, Shinichi Inoue, Kouji Adachi, Fumiho Igarashi, Toshio Wakai
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Patent number: 5073672Abstract: A MFI-based gallosilicate type catalyst is described.The catalyst is characterized by the following composition expressed by weight:a) 0.1 to 99.49% of a matrix,b) 0.5 to 99.99% of a zeolite having the following approximate chemical formula:M.sub.2/n O, Ga.sub.2 O.sub.3, xSiO.sub.2whereinM represents a proton and/or a metallic cation,n is the valence of said cation,x is a number ranging from 12 to 1,00,the zeolite of MFI structure synthesized in a fluoride medium having a fluorine content ranging from 0.02 to 1.5% by weight incorporated during synthesis.The catalyst is notably used in aromatization reactions of light C.sub.2 -C.sub.4 gases in the presence or not of olefins.Type: GrantFiled: March 14, 1991Date of Patent: December 17, 1991Assignee: Institut Francais Du PetroleInventors: Laurent Petit, Jean-Paul Bournonville, Jean-Louis Guth, Francis Raatz, Alain Seive
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Patent number: 5059735Abstract: The C.sub.2 -C.sub.4 olefin yield is unexpectedly increased while coke and heavy aromatics production are decreased by the addition of a propane-rich supplemental feedstream in a process for catalytically upgrading C.sub.5 -C.sub.7 paraffinic feedstreams. Further benefits include increased conversion of the C.sub.5 -C.sub.7 paraffinic feedstream, decreased coke production and prolonged catalyst useful life. Udex raffinate is a particularly preferred feedstream.Type: GrantFiled: January 22, 1991Date of Patent: October 22, 1991Assignee: Mobil Oil Corp.Inventor: Margaret Nemet-Mavrodin
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Patent number: 5059744Abstract: An improved olefin upgrading technique and fixed-bed reactor system has been developed for increasing production of premium heavy hydrocarbons, such as distillate fuel, from lower olefinic feedstock. During recovery and recycle of intermediate range hydrocarbons products, a technique has been found for withdrawing a fraction rich in C.sub.5 -C.sub.9 gasoline range olefinic hydrocarbons from the oligomerization reactor effluent stream. By separating the reaction effluent in a multi-stage distillation system, fractionation feed can be separated into a heavier bottoms stream rich in C.sub.10 + hydrocarbons and a light hydrocarbon overhead, while withdrawing a liquid stream as an overflash fractionation stream rich in intermediate hydrocarbons. The overflash stream is combined to form a portion of the recycle stream to the reactor, thereby providing a more efficient and lower cost recovery process.Type: GrantFiled: September 29, 1989Date of Patent: October 22, 1991Assignee: Mobil Oil CorporationInventors: Moshen N. Harandi, Hartley Owen
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Patent number: 5053575Abstract: A method of converting natural gas or light alkane(s) into unsaturated hydrocarbons, consisting in providing inside of a reaction space a fluidized bed of particles of a refractory and advantageously catalytic material and feeding a plasma of a hydrogen-containing gas and the natural gas or the light alkane(s) into the bed so that the latter effects the quenching of the reaction medium and catalyses the conversion reaction.Type: GrantFiled: November 22, 1989Date of Patent: October 1, 1991Assignee: Gaz de FranceInventors: Mehrdad Nikravech, Isabelle Vedrenne, Jacques Amouroux, Jacques Saint-Just
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Patent number: 5043505Abstract: A catalytic process for gas phase oxidative coupling of aliphatic and alicyclic hydrocarbon compounds to produce higher molecular weight hydrocarbon compounds, the catalyst being a mixed basic metal oxide or sulfide catalyst. One preferred mixed basic metal oxide catalyst is boron/alkali metal promoted metal oxide.Type: GrantFiled: May 7, 1990Date of Patent: August 27, 1991Assignee: Institute of Gas TechnologyInventors: Erek J. Erekson, Anthony L. Lee, S. Peter Barone, Irvine J. Solomon
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Patent number: 5034565Abstract: A improved process is provided for upgrading light olefins from hydrocarbon cracking, such as light crackate gas containing ethene, propene and other C.sub.1 -C.sub.4 lower aliphatics. The process comprises the steps of: maintaining an oligomerization reactor containing a fluidized bed of zeolite catalyst particles in a low severity reactor bed at oligomerization temperature conditions by passing hot olefinic gas upwardly through the fluidized catalyst bed under throughput rate conditions sufficient to convert at least 50 wt % of lower olefins to hydrocarbons in the C.sub.5 -C.sub.10 range; maintaining turbulent fluidized bed conditions through the fluidized bed by passing fresh ethene-rich feedstream gas upwardly through the fluidized catalyst bed and adding thereto sufficient recycled light byproduct gas to maintain a minimum gas velocity; cooling reaction effluent from the conversion zone to provide light gas byproduct and liquid hydrocarbon reaction product rich in C.sub.5 -C.sub.Type: GrantFiled: September 26, 1988Date of Patent: July 23, 1991Assignee: Mobil Oil CorporationInventors: Mohsen N. Harandi, Hartley Owen, Samuel A. Tabak
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Patent number: 5030782Abstract: Aliphatics are aromatized in a two-stage catalytic upgrading process. In the first stage, aliphatic hydrocarbons are at least partially cracked and dehydrogenated to form an intermediate product stream. The extent and selectivity of the cracking and dehydrogenation reactions are preferably controlled to maintain heat balance in a second stage catalytic aromatization step.In a preferred embodiment, a first aliphatic feedstream is cracked and dehydrogenated to form an intermediate product stream. The intermediate product stream is then mixed with a second aliphatic feedstream and contacted with a zeolite aromatization catalyst. Cracking and dehydrogenation of the first aliphatic feedstream is controlled to provide heat balanced aromatization of the combined streams.Type: GrantFiled: May 4, 1989Date of Patent: July 9, 1991Assignee: Mobil Oil CorporationInventors: Mohsen N. Harandi, Hartley Owen
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Patent number: 5026921Abstract: Therein is provided a process for the aromatization of non-aromatic hydrocarbons having at least two carbon atoms. The non-aromatic feed is contacted with a catalyst which includes gallium or zinc which is incorporated into or onto a pillared layered silicate. A preferred pillared layered silicate is kenyaite containing interspathic silica.Type: GrantFiled: December 21, 1989Date of Patent: June 25, 1991Assignee: Mobil Oil CorporationInventors: Thomas F. Degnan, Jr., Ivy D. Johnson
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Patent number: 5026937Abstract: Methane is upgraded to aromatic hydrocarbons and other valuable C.sub.3 -plus hydrocarbons by contact with a catalyst comprising gallium and a ZSM-type zeolite incorporated in a phosphorous-containing alumina at relatively low temperature conditions.Type: GrantFiled: December 29, 1989Date of Patent: June 25, 1991Assignee: UOPInventor: Jeffery C. Bricker
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Patent number: 5019663Abstract: The endothermic heat of reaction for zeolite-catalyzed paraffin aromatization is provided by a co-fed oxygenate stream. Advantageously, the addition of a dehydrogenation metal to the zeolite reduces the reaction temperature for paraffin aromatization to a range suitable for the exothermic conversion of an oxygenate to C.sub.5 + gasoline. Preferred paraffinic feedstreams include C.sub.3 -C.sub.4 LGP and the preferred oxygenate is methanol.Type: GrantFiled: April 3, 1989Date of Patent: May 28, 1991Assignee: Mobil Oil Corp.Inventors: Tai-Sheng Chou, Melcon G. Melconian
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Patent number: 5015799Abstract: A method for converting methane to higher molecular weight hydrocarbons wherein hot oxidative coupling reactor effluent is briefly contacted with a C.sub.2 to C.sub.20 alkane quench material to remove part of the heat contained in the raw reactor effluent, and is then further quenched by thermal quenching means to achieve a temperature which discourages retrograde reactions.Type: GrantFiled: July 6, 1989Date of Patent: May 14, 1991Assignee: Amoco CorporationInventors: Robert H. Walker, Paul A. Willems, George A. Huff, Lewis E. Grimes, David F. Tatterson, Robert L. Mehlberg
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Patent number: 5013423Abstract: Improved, dehydrocyclization and low-pressure reforming processes based on a non-acidic metal containing crystalline microporous indium catalyst, in which the feed is rich in C.sub.6 -C.sub.7 low octane hydrocarbons, such as paraffins, and in which the reformate has increased aromatic content and increased octane value over that of the feed are disclosed.Type: GrantFiled: January 11, 1989Date of Patent: May 7, 1991Assignee: Mobil Oil CorporationInventors: Nai Y. Chen, Ralph M. Dessau, Randall D. Partride, Ernest W. Valyocsik
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Patent number: 5012025Abstract: A catalyst for promoting the molecular restructuring of the components of hydrocarbons to form desired products. The catalyst comprises copper salts, copper acetate being particularly preferred, in combination with anhydrous aluminum chloride. The catalyst can be used with either gaseous hydrocarbon raw materials such as natural gas, refinery gas, biomass decomposition gases, and similar materials, or with solids, meltable solids, or liquid hydrocarbon-containing raw materials including tar sands, oil shale, waxes, asphaltic compositions and the like. In the case of gaseous raw materials, the gases are preferably brought into contact with the copper salt coated on a catalyst support such as refractory alumina, in the presence of anhydrous aluminum chloride, which can be in vaporous form, in a continuous process.Type: GrantFiled: August 23, 1989Date of Patent: April 30, 1991Inventor: Viswanatha Sankaran
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Patent number: 5004856Abstract: There is provided a process for the direct partial oxidation of methane with oxygen, whereby hydrocarbons having at least two carbon atoms are produced. The catalyst used in this reaction is a cadmium-manganese oxide catalyst.Type: GrantFiled: December 29, 1989Date of Patent: April 2, 1991Assignee: Mobil Oil CorporationInventors: Lorenzo C. DeCaul, Scott Han, Robert E. Palermo, Dennis E. Walsh
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Patent number: 5004852Abstract: Light aliphatic streams containing C.sub.4 - olefins are upgraded to C.sub.5 + gasoline in a two-stage process. In the first stage, olefins are oligomerized to C.sub.5 + olefinic gasoline. Unreacted light aliphatics including ethylene as well as light oligomerization byproducts are then charged to a second stage aromatization zone. Catalysts useful for both stages include medium pore zeolites.Type: GrantFiled: August 24, 1989Date of Patent: April 2, 1991Assignee: Mobil Oil Corp.Inventor: Mohsen N. Harandi
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Patent number: 5003125Abstract: The present invention relates to a process for the oligomerization of light olefins or mixtures thereof, wherein a reaction is brought about between olefins with a carbon number of between 2 and 20 and synthetic zeolites containing silicon, titanium and gallium oxides which in the calcined, anyhdrous state have the following empirical formula:pHGaO.sub.2 .multidot.qZTiO.sub.2 .multidot.SiO.sub.2,where p is of a value greater than zero and less than or equal to 0.050 and q is of value greater than zero and less than or equal to 0.025, with the H.sup.+ of HGaO.sub.2 being at least partly exchangeable or exchanged with cations.Type: GrantFiled: June 28, 1989Date of Patent: March 26, 1991Assignees: Eniricerche S.p.A., AGIP S.p.A.Inventors: Aldo Giusti, Stefano Gusi, Giuseppe Bellussi, Vittorio Fattore
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Patent number: 4996381Abstract: An improved aromatization process is disclosed in which conversion is increased by recycling a highly purified C.sub.2 -C.sub.4 aliphatic stream. Loss of valuable ethane to fuel gas is substantially eliminated. In a preferred embodiment, a dephlegmator purifies the C.sub.2 -C.sub.4 recycle stream.Type: GrantFiled: October 7, 1988Date of Patent: February 26, 1991Assignee: Mobil Oil Corp.Inventors: John L. Pickering, Jr., Margaret Nemet-Mavrodin
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Patent number: 4990714Abstract: A process and reactor apparatus are disclosed for upgrading paraffinic feedstocks to olefinic and/or aromatic products. Hydrogen diffuses through a selectively permeable membrane from the reaction zone into a combustion zone where it reacts exothermically with an oxygen-containing fluid to supply at least a portion of the endothermic heat of reaction for the paraffin upgrading process. Additionally, in-situ separation of by-product hydrogen from the reactant mixture in the reaction zone increases yield of valuable olefinic and aromatic products.Type: GrantFiled: May 4, 1989Date of Patent: February 5, 1991Assignee: Mobil Oil CorporationInventor: Margaret Nemet-Mavrodin
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Patent number: 4985203Abstract: Aliphatic oxygenates are converted to high octane gasoline by an integrated reactor system wherein three reaction zones are utilized. In a first reaction zone the oxygenates are directly converted to gasoline and an isobutane by-product. In a second reaction zone oxygenates are dehydrated to an intermediate product comprising C.sub.3 -C.sub.4 olefins, which are then further reacted with the isobutane by-product in a third reaction zone to yield a gasoline alkylate. Ethylene-containing vapors may be separated from the second reaction zone and recycled to the first reaction zone for further processing.Type: GrantFiled: February 5, 1987Date of Patent: January 15, 1991Assignee: Mobil Oil CorporationInventor: Samuel A. Tabak
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Patent number: 4973781Abstract: This invention relates to a synthetic porous zeolite, identified as ZSM-57, a method for its preparation and use thereof in catalytic conversion of organic compounds. This crystalline material may have a ratio of XO.sub.2 : Y.sub.2 O.sub.3 of at least 4, wherein X represents silicon and/or germanium and Y represents aluminum, boron, chromium, iron and/or gallium. The silica/alumina form of this crystalline material has a silica to alumina ratio of at least 4 and may be prepared with directing agents which are N,N,N,N',N',N'-hexaethylpentane-diammonium compounds. The crystalline material exhibits a characteristic X-ray diffraction pattern.Type: GrantFiled: July 11, 1989Date of Patent: November 27, 1990Assignee: Mobil Oil CorporationInventors: Ernest W. Valyocsik, Nancy M. Page, Cynthia T. Chu
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Patent number: 4973785Abstract: Crystalline molecular sieves having three-dimensional microporous framework structures of ELO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 framework oxide units are disclosed. The molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; "EL" represents at least one element capable of forming a framework oxide unit; and "w", "x", "y" and "z" represent the mole fractions of element(s) "EL", aluminum, phosphorus and silicon, respectively, present as framework oxides. Their use as adsorbents, catalysts, etc. is also disclosed.Type: GrantFiled: April 18, 1988Date of Patent: November 27, 1990Assignee: UOPInventors: Brent M. T. Lok, Bonita K. Marcus, Lawrence D. Vail, Edith M. Flanigen, Robert L. Patton, Stephen T. Wilson
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Patent number: 4973778Abstract: A reactor system contained in a fired heater and a hydrocarbon upgrading process are discosed for the concurrent conversion of a hydrocarbon feedstock and the regeneration of a deactivated catalyst. An effluent product slipstream from a set of operating reactors is used to hydrogen-regenerate deactivated catalyst in another set of reactors. Flue gas withdrawn from the fired heater stack is used as a purge and/or carrier gas during oxygen-regeneration of the catalyst.Type: GrantFiled: December 29, 1987Date of Patent: November 27, 1990Assignee: Mobil Oil Corp.Inventors: Mohsen N. Harandi, Hartley Owen
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Patent number: 4973776Abstract: A process is described for the gas-phase condensation of natural gas or methane into gasoline-range hydrocarbons comprising the steps of: (a) reacting a mixture of methane and acetylene in the presence of a solid superacid catalyst to form isobutene, and (b) converting the isobutene product into gasoline-range hydrocarbons in the presence of a crystalline silicate zeolite catalyst.Type: GrantFiled: December 12, 1989Date of Patent: November 27, 1990Assignee: Energy, Mines & Resources - CanadaInventors: Vincenza M. Allenger, Raj N. Pandey
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Patent number: 4973777Abstract: A process for thermally converting methane e.g., at 1,000.degree.-1,300.degree. C. into hydrocarbons with higher molecular weights, especially ethylene comprises circulating a gas containing methane in ceramic channels (11) grouped in rows which cover at least a part of the reactor (1) length, parallel to its axis. At the reaction temperature, the temperature variation is kept at less than 20.degree. C. The rows of channels form multiple plates (4) which are not adjacent to one another and which define tight spaces (17) in which are housed the electric heating (5, 22) means that heat the channel plates in a first zone (9) through successive, independent cross sections substantially perpendicular to the axis of the reactor and substantially parallel to the plane of the plates. Means for heating, servocontrol and modulation (7, 8) regulate the heating system. At the exit of the heating zone (9), the effluent is cooled in a second zone (10) equipped with cooling means and finally collected.Type: GrantFiled: April 27, 1988Date of Patent: November 27, 1990Assignee: Institut Francais du PetroleInventors: Jacques Alagy, Christian Busson, Michel Fouquet
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Patent number: 4956510Abstract: Valuable product yield and catalyst useful life are improved by regenerating spent catalyst at temperatures below those maintained in the reaction zone. Relatively cold regenerated catalyst is then preheated and reactor effluent product is quenched by directly contacting the regenerated catalyst with hot reactor effluent product. The quenching step minimizes undesirable thermal cracking of valuable product to C.sub.2 -light gas. The process and apparatus are useful both in aromatization and dehydrogenation of aliphatic hydrocarbons.Type: GrantFiled: March 14, 1989Date of Patent: September 11, 1990Assignee: Mobil Oil Corp.Inventor: Mohsen N. Harandi
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Patent number: 4950829Abstract: The invention is directed to aromatization of hydrocarbons of low octane value to produce aromatics over a catalyst composition comprising a zeolite type material which has been treated with the chloride of an oxophilic element such as Si on Ti.Type: GrantFiled: August 8, 1988Date of Patent: August 21, 1990Assignee: Mobil Oil CorporationInventors: Scott Han, Sharon B. McCullen
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Patent number: 4950827Abstract: A catalyst and a process for oxidative coupling of aliphatic and alicyclic hydrocarbon compounds with aliphatic and alicyclic substituted aromatic hydrocarbon compounds to form a longer substituent hydrocarbon on the aromatic ring. The catalyst is mixed basic metal oxide catalyst, one preferred catalyst is boron/alkali metal promoted metal oxide. Reaction of methane with toluene and oxygen according to this invention results in conversion to styrene.Type: GrantFiled: November 21, 1988Date of Patent: August 21, 1990Assignee: Institute of Gas TechnologyInventors: Erek J. Erekson, Anthony L. Lee
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Patent number: 4946579Abstract: A crystalline, galliosilicate molecular sieve having the erionite-type structure and the following composition expressed in terms of oxide mole ratios in the anhydrous state:Ga.sub.2 O.sub.3 :xSiO.sub.2 :yM.sub.2 O:zN.sub.2 O:tQ.sub.2 Owhere M is an alkali metal, preferably sodium, N is an alkali metal other than M, preferably potassium, Q is a cation derived from the templating agent used in synthesizing the galliosilicate molecular sieve, preferably a choline cation, x equals 5.5 to 30, y equals 0.1 to 0.9, z equals 0.1 to 0.9, t equals 0.1 to 0.6 and y+z+t equals about 1.0. The crystalline, galliosilicate molecular sieve of the invention may be employed, after reducing its alkali metal content, as a component of a catalyst which can be used in a variety of chemical conversion processes, preferably hydrocarbon conversion processes, and most preferably hydrodewaxing, hydrocracking and isomerization processes.Type: GrantFiled: May 1, 1989Date of Patent: August 7, 1990Assignee: Union Oil Company of CaliforniaInventor: Mario L. Occelli
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Patent number: 4945175Abstract: A dehydrocyclodimerization process employing a catalyst comprising a crystalline aluminosilicate and a metal oxide component is started-up by contacting the catalyst with a start-up gas that contains less than 50 mole percent hydrogen. The catalyst is exposed to the gaseous atmosphere containing less than 50 mole percent hydrogen until a C.sub.2 -C.sub.5 aliphatic hydrocarbon feedstock is contacted with the catalyst at dehydrocyclodimerization reaction conditions at which point hydrogen is generated as a dehydrocyclodimerization reaction product and displaces the non-hydrogen start-up gas from the process.Type: GrantFiled: May 26, 1989Date of Patent: July 31, 1990Assignee: UOPInventors: Simon H. Hobbs, Christopher D. Gosling
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Patent number: 4935572Abstract: A catalyst and process for oxidative coupling of methane, the catalyst being a mixed basic metal oxide catalyst. One preferred catalyst is boron/alkali metal promoted metal oxide.Type: GrantFiled: November 21, 1988Date of Patent: June 19, 1990Assignee: Institute of Gas TechnologyInventors: Erek J. Erekson, Anthony L. Lee
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Patent number: 4925455Abstract: A process is disclosed for converting a light hydrocarbon feedstock that contains a mixture of linear and branched olefins to ether-rich high octane gasoline streams that include tertiary alkyl and isoalkyl ethers such as MTBE, TAME, methyl isopropyl ether (MIPE), and methyl sec-butylether (MSBE). Further, it has been discovered that, following etherification unreacted paraffins in the process can be dehydrogenated to produce C.sub.3 -C.sub.4 olefins which can be recycled to the etherification process. The conversion is achieved by utilizing the differing reactivity of tertiary olefins under selected conditions compared to linear olefins in the catalyzed etherification processes. The process integrates a first stage tertiary olefin etherification, separation of ether-rich gasoline and a second stage linear olefin etherification to produce a second ether rich gasoline stream.Type: GrantFiled: March 17, 1989Date of Patent: May 15, 1990Assignee: Mobil Oil CorporationInventors: Mohsen N. Harandi, Hartley Owen
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Patent number: 4925996Abstract: A process is disclosed for converting a feedstock containing ethylene to produce heavier hydrocarbons in the gasoline or distillate boiling range including the steps of contacting the olefins feedstock with a first siliceous crystalline molecular sieve at an elevated temperature and relatively low pressure under conditions which maximize the conversion of ethylene to C.sub.3 -C.sub.4 olefins and C.sub.5 + hydrocarbons, separating C.sub.3 -C.sub.4 olefins from the C.sub.5 + hydrocarbons, and contacting the separated C.sub.3 -C.sub.4 olefins with a second siliceous crystalline molecular sieve at moderate temperatures under conditions favorable for conversion of the C.sub.3 -C.sub.4 olefins to heavier hydrocarbons in the gasoline or distillate boiling range.Type: GrantFiled: December 16, 1985Date of Patent: May 15, 1990Assignee: Atlantic Richfield CompanyInventor: Harry Mazurek
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Patent number: 4918256Abstract: There is provided a process for converting a C.sub.5 -C.sub.10 paraffinic feedstock such as a Udex reffinate into other hydrocarbons including C.sub.6 -C.sub.8 aromatics, C.sub.2 -C.sub.4 olefins, C.sub.9.sup.+ aromatics and C.sub.1 -C.sub.3 paraffins. By using a catalyst comprising (1) a binder and (2) ZSM-5 or ZSM-11, said catalyst having low acid catalytic activity as measured by an alpha value of 25 or less, the selectivity to the more desired C.sub.6 -C.sub.8 aromatics and C.sub.2 -C.sub.4 olefins is increased. The low alpha value of the catalyst may be achieved by deactivating the catalyst under conditions comprising steaming, high temperature calcining and/or coking.Type: GrantFiled: January 4, 1988Date of Patent: April 17, 1990Assignee: Mobil Oil CorporationInventor: Margaret Nemet-Mavrodin