Abstract: In one embodiment, a method for cooling a reaction effluent gas includes feeding a sufficient amount of a suitable silicon source cooling gas into a stream of the reaction effluent gas, wherein the reaction effluent gas is produced by a thermal decomposition of at least one silicon source gas in a reactor, and wherein sufficient amount of the suitable silicon source cooling gas is defined based a concentration of the at least one chemical species in the reaction effluent gas; cooling the reaction effluent gas to a sufficient temperature so that: the cooled reaction effluent gas is capable of being handled by a material that is not suitable for handling the reaction effluent gas.

Abstract: A method for recovering C2 and higher weight hydrocarbons, or alternatively C3 and higher weight hydrocarbons, from low pressure gas, wherein the method avoids the need to significantly compress contaminated low pressure gas in most cases, and is robust in response to pressure and temperature variations in the low pressure gas feed.

Abstract: Methods of reducing the concentration of low boiling point components in liquefied natural gas are disclosed. The methods involve dynamic decompression of the liquefied natural gas and one or more pre-fractionation vessels. Particular embodiments are suited for recovering helium and/or nitrogen enriched streams from a liquefied natural gas stream.

Abstract: Provided are azeotropic or azeotrope-like mixtures of 1,1,3,3-tetrachloro-1-fluoropropane (HCFC-241fa) and hydrogen fluoride. Such compositions are useful as an intermediate in the production of HFC-245fa and HCFO-1233zd.

Abstract: Provided are azeotropic or azeotrope-like mixtures of 1,1,1,3,3-pentachloro-propane (240fa) and hydrogen fluoride. Such compositions are useful as an intermediate in the production of HFC-245fa and HCFO-1233zd.

Abstract: A method of producing a liquid product stream, for example, a liquid nitrogen product stream, at a production rate that is selectively varied. This variation is produced in either a waste expansion or air expansion process by increasing the pressure and flow rate of the feed stream during periods in which a high rate of liquid production is desired without substantially increasing the pressure of the exhaust stream produced by a variable speed turboexpander. This increases the expansion ratio across the turboexpander and therefore the refrigeration supplied to increase liquid production. At the same time, the increase in flow rate prevents a decrease in the performance of the variable speed turboexpander.

Abstract: A process and a device for treating a carbon dioxide-containing flue gas stream are described. At least a part of the carbon dioxide present is removed from the flue gas stream by means of a scrubber, forming a low carbon dioxide gas stream and a high carbon dioxide gas stream. The high carbon dioxide and water-saturated gas stream formed from the flue gas stream after removal of the carbon dioxide is cooled by means of a refrigeration system 4 in a heat exchanger 3 below the dew point temperature of the water contained in the gas stream and dried by condensing and separating out the water in a condensate separator 5. The dried gas stream meets the requirements of carbon dioxide products intended for further use.

Abstract: A method for capturing ammonia present in combustion flue gas subjected to carbon dioxide removal, using a water wash unit (102) included in a chilled ammonia process, comprises: providing CO2 loaded liquid (122) comprising CO2 dissolved in the liquid; providing wash water liquid (108, 138); combining the CO2 loaded liquid with the wash water liquid to form CO2 enriched wash water liquid (105, 106) before the liquid is added said water wash unit (102); and bringing said combustion flue gas into contact with said CO2 enriched wash water liquid by adding the CO2 enriched wash water liquid to said water wash unit (102).

Abstract: A method and a plant for producing liquid CO2 from flue gas as described with reduced energy consumption and a stable behaviour.

Abstract: The present invention relates to a method for recovery of carbon dioxide from a gas stream. The method is a two-step method in which carbon dioxide is compressed in the first step, while the residual carbon dioxide is recovered by an absorption process in a subsequent step. The present invention also relates to the use of the method for the recovery of carbon dioxide and a plant for recovery of carbon dioxide.

Abstract: A process for compressing a CO2-rich fluid containing water. The CO2-rich fluid is compressed in a compressor; upstream of the compression step, an antifreeze is mixed with the CO2-rich fluid containing water. The CO2-rich fluid containing antifreeze is cooled, water is separated from the cooled fluid and the water-depleted cooled fluid is compressed in the compressor, wherein the CO2-rich fluid containing water is sent to a scrubbing column fed, preferably at the top, with a water/antifreeze mixture, where it cools and is separated from the water, the water-depleted cooled fluid is extracted from the top of the column; a water/antifreeze mixture in the column is extracted at a level below the top; the mixture is cooled using the refrigeration from an apparatus for cooling and/or purifying the cooled fluid compressed in the compressor and the fluid is returned to the top of the column.

Abstract: The present invention relates to an improved method for removing contaminants from a gaseous stream substantially comprising carbon dioxide. More specifically, the method comprises the step of subjecting the gaseous stream to an absorption step in which the absorbent is liquid carbon dioxide wherein the waste of carbon dioxide is minimized by utilizing a compressing means for generating a pressure difference between two streams in a reboiler.

Abstract: Multiple designs and methods for aerodynamic separation nozzles and systems for integrating multiple aerodynamic separation nozzles into a single system are disclosed herein. These aerodynamic separation nozzles utilize a combination of aerodynamic forces and separation nozzle structure to induce large centrifugal forces on the gases that in combination with the structure of the nozzle are used to separate heavier constituents of the process gas from lighter constituents. In some embodiments a number of separation nozzles are combined into a single system suitable for dynamic processing of a process gas. In other embodiments the separation nozzles are temperature controlled to condition the incoming gas to a temperature in order to encourage a phase change in certain constituents of the gas to occur within the nozzle to further enhance separation.

Abstract: The present invention relates to a method for recovering carbon dioxide from a gaseous stream originating from a fermentation process by compression, absorption, condensation and distillation, wherein at least the absorption and condensation is performed under a high pressure of at least 30 bar.

Abstract: A method is described for use in the separation of carbon dioxide from a gas mixture comprising carbon dioxide. The method includes the steps of: (i) compressing and cooling the gas mixture using a compressor to form a two-phase mixture including liquid carbon dioxide (ii) separating a liquid carbon dioxide stream from the two-phase mixture; and (iii) recirculating at least a part of the liquid carbon dioxide stream and introducing the recirculated liquid stream into a process stream by recirculating separated liquid CO2 into an upstream process stream, cooling of the process stream can be obtained. By using the liquid stream, additional cooling is possible as cooling is affected by the evaporation of the liquid CO2. Thus the recirculated liquid can be used to reduce the temperature of the process stream.

Abstract: Refrigeration duty in a carbon dioxide purification unit (CPU) operating at elevated pressure and sub-ambient temperature can be provided in at least a first part by indirect heat exchange against at least latent heat of at least one liquid first refrigerant, preferably carbon dioxide liquid(s) produced in the CPU, thereby typically evaporating the liquid(s), and a second part by indirect heat exchange with sensible heat energy alone of a second refrigerant. The second refrigerant may be nitrogen gas imported from an integrated cryogenic air separation unit (ASU) or carbon dioxide liquid exported from the CPU, cooled and returned to the CPU. One advantage is that total power consumption of the CPU and an integrated ASU is reduced.

Abstract: A process for the recovery of carbon dioxide from a gas mixture that includes pretreating a gas mixture comprising carbon dioxide, water vapor, and one or more light gases in a pretreating system to form a cooled gas mixture, fractionating the cooled gas mixture to recover a bottoms fraction comprising carbon dioxide and an overheads fraction comprising carbon dioxide and the light gases, passing the overheads fraction over a membrane selective to carbon dioxide to separate a carbon dioxide permeate from a residue gas comprising the light gases, recycling the carbon dioxide permeate to the pretreating system, and recovering at least a portion of the bottoms fraction as a purified carbon dioxide product stream is described.

Abstract: A system for removing acid gases from a raw gas stream is provided. The system includes a cryogenic distillation column. The cryogenic distillation column receives a dehydrated and chilled sour gas stream, and separates the sour gas stream into an overhead gas stream comprised primarily of methane, and a bottom acid gas stream comprised primarily of carbon dioxide. The system also includes a series of co-current contactors. The co-current contactors may be placed in series to receive the bottom acid gas stream and recapture any entrained methane gas. Alternatively or in addition, the co-current contactors may be placed in series to receive the overhead gas stream, and sweeten it using a reflux liquid such as methane. In this instance, the sweetened gas is optionally liquefied and delivered for commercial sale, or is used as fuel gas on-site.

Abstract: A gas cleaning system is operative for removing water vapour from a carbon dioxide rich flue gas generated in a boiler combusting a fuel in the presence of a gas containing oxygen gas. The gas cleaning system comprises a flue gas condenser (12) being operative for condensing water from at least a portion of the carbon dioxide rich flue gas generated in the boiler by bringing the carbon dioxide rich flue gas into contact with a circulating cooling liquid, thereby generating a cleaned carbon dioxide rich flue gas having a lower concentration of water vapour than the carbon dioxide rich flue gas leaving the boiler. The gas cleaning system comprises a heat pump (100) being operative for absorbing heat at a first temperature from the cooling liquid, and for desorbing heat at a second temperature, being higher than the first temperature, to a heat sink (124).

Abstract: A device for capturing carbon dioxide includes a supply source for supplying a compressed flue gas; a multi-stream heat exchanger for pre-cooling the compressed flue gas and a gas expansion device located downstream of the multi-stream heat exchanger. The multi-stream heat exchanger is configured to separate the compressed flue gas into a first compressed stream and a second compressed stream. The gas expansion device is configured to expand the compressed flue gas into a first sub-stream of carbon dioxide depleted gas and a second sub-stream of carbon dioxide. The device includes a first recirculation channel that recirculates a portion of the first sub-stream into the multi-stream heat exchanger and a second recirculation channel that recirculates at least a portion of the second sub-stream into the multi-stream heat exchanger, wherein the multi-stream heat exchanger is configured to pre-cool the compressed flue gas using the first sub-stream and the second sub-stream.

Abstract: In accordance with one aspect of the present invention, methods of condensing carbon dioxide (CO2) from a CO2 stream are provided. The method includes (i) compressing and cooling the CO2 stream to form a partially cooled CO2 stream, wherein the partially cooled CO2 stream is cooled to a first temperature. The method includes (ii) cooling the partially cooled CO2 stream to a second temperature by magneto-caloric cooling to form a cooled CO2 stream. The method further includes (iii) condensing at least a portion of CO2 in the cooled CO2 stream to form a condensed CO2 stream.

Abstract: The present invention relates to a process for purifying a gas mixture comprising dinitrogen monoxide, at least comprising the at least partial condensation of a gas mixture G-I comprising dinitrogen monoxide to obtain a liquid composition C-1 comprising dinitrogen monoxide, and the contacting of the composition C-1 with a gas mixture M-1 to obtain a composition C-2 and a gas mixture M-2.

Abstract: A carbon dioxide gas recovery device is provided which includes an absorption tower causing an absorbent to absorb carbon dioxide gas to generate a rich absorbent and a regeneration tower regenerating a lean absorbent by heating the rich absorbent to separate carbon dioxide gas therefrom. The regeneration tower includes a reboiler system heating the absorbent led out from the regeneration tower and reintroducing the heated absorbent into the regeneration tower and a mixed gas cooling system cooling a mixed gas led out from the regeneration tower, condensing a vapor fraction of a solute and a solvent, reintroducing the condensed vapor fraction into the regeneration tower, and discharging carbon dioxide gas. The carbon dioxide gas recovery device further includes a heat pump as a heat source of an endothermic reaction in which carbon dioxide gas is separated from the rich absorbent in the regeneration tower.

Abstract: Apparatus and process for producing a hydrogen-containing product stream and a carbon monoxide-containing product stream from a crude synthesis gas produced in a syngas production unit. Carbon dioxide is removed from the process gas by a non-cryogenic means and the hydrogen-containing product stream is separated from the process gas in a pressure swing adsorber. Residual gas from the pressure swing adsorber is passed to a cryogenic separation unit where the cryogenic separation unit separates the residual gas stream into the carbon monoxide-containing product stream, a hydrogen-enriched stream, a methane-enriched stream, and a carbon monoxide-containing intermediate stream by cryogenic fractionation. At least a portion of the hydrogen-enriched stream is recycled to the pressure swing adsorber.

Abstract: A process for separating carbon dioxide from a fluid containing carbon dioxide, NO2, and at least one of oxygen, argon, and nitrogen comprises the steps of separating at least part of the fluid into a carbon dioxide enriched stream, a carbon dioxide depleted stream comprising CO2 and at least one of oxygen, argon, and nitrogen and a NO2 enriched stream and recycling said NO2 enriched stream upstream of the separation step.

Abstract: The disclosure provides an apparatus and method for gas separation through the supersonic expansion and subsequent deceleration of a gaseous stream. The gaseous constituent changes phase from the gaseous state by desublimation or condensation during the acceleration producing a collectible constituent, and an oblique shock diffuser decelerates the gaseous stream to a subsonic velocity while maintain the collectible constituent in the non-gaseous state. Following deceleration, the carrier gas and the collectible constituent at the subsonic velocity are separated by a separation means, such as a centrifugal, electrostatic, or impingement separator. In an embodiment, the gaseous stream issues from a combustion process and is comprised of N2 and CO2.

Abstract: The present disclosure is directed to the introduction of an additive to a contaminated gas stream. An additive introduction system uses a compressor and carbon dioxide separator to provide a treated carrier gas for introduction of an alkaline additive to a contaminated gas stream.

Abstract: A trap apparatus provided between a chamber and an evacuating unit includes an inlet port and an exhausting port to be respectively connected to the chamber and the evacuating unit; a cooling trap portion provided with a first space for cooling gas in the first space; and a bypass portion provided with a first channel capable of communicating between the inlet port and the first space, a second channel capable of communicating between the first space and the exhausting port, and a second space capable of communicating between the inlet port and the exhausting port, the bypass portion being relatively movable with respect to the cooling trap portion to selectively form a first path from the inlet port to the exhausting port via the first channel, the first space and the second channel, and a second path from the inlet port to the exhausting port via the second space.

Abstract: A system for recovering products from a gas stream comprises a cooled chamber having an inlet that feeds the gas stream to a plurality of sequential conduit loops within the chamber. A critical orifice follows each loop, and each loop includes an output port. Based upon the physical characteristics of each loop, the sizing of the critical orifice following the loop, and the temperature within the chamber, different products are condensed from the gas stream through the output ports. The system may be configured to condense hydrocarbonaceous products such as ethane, propane, butane or methane, as well as fundamental products such as carbon dioxide, nitrogen or hydrogen. Gaseous products may be stored in gas or liquid form or vented to atmosphere depending upon amount, purity, and so forth.

Abstract: The invention relates to an apparatus for the distillation separation of a mixture containing, as the main components thereof, carbon dioxide and at least one other fluid selected from the group containing nitrogen, oxygen, argon, hydrogen, methane, carbon monoxide, said apparatus comprising a distillation column (8), a condenser (9), a reboiler (7, 11), means for conveying the mixture to be separated to the column or the condenser, means for conveying a head gas from the column to the condenser, and means for conveying a liquid condensed in the condenser into the head of the column. The condenser is formed by an exchanger with plates and blades made from brazed aluminum and having an exchange surface area per m3 of exchanger greater than 400 m2/m3, with ammonia being used as refrigerant.

Abstract: A self-regulating system for reducing concentration of hydrocarbon vapor in a container may be performed by introducing air into the container and extracting a mixture of air and vapor from the container. The extracted mixture may be compressed with a compressor to produce a flow of compressed mixture of air and vapor. The compressed mixture may be passed through an oxidation reactor that may be either catalytic or thermal to produce a flow air and CO2. A turbine may be driven with the flow of air and CO2. The compressor may be driven with the turbine. Extraction from the container may continue until vapor concentration is low enough so that flow of CO2 and air from the reactor is insufficient to drive the turbine.

Abstract: A process and system for recovering valuable by-products (e.g., hydrogen) from refinery gas streams. For hydrogen-only recovery, the invention comprises a partial condensation step to upgrade the refinery fuel gas to a minimum of 60% hydrogen, which is further purified in a pressure swing adsorption process. When configured to recover hydrogen, methane-rich gas and raw LPG (methane depleted gas containing C2 hydrocarbons and heavier), the invention comprises two partial condensation steps where the feed is cooled in the first step to allow separation of ethane and heavier hydrocarbons, and the resulting vapor is cooled to a lower temperature in a second step for hydrogen recovery.

Abstract: A method is provided for separating a cleaned useful gas from a gas mixture substantially containing carbon dioxide, at least one useful gas, and at least one hazardous substance. The carbon dioxide is condensed, and the liquid carbon dioxide that is enriched with the hazardous substance is separated from the useful gas. The hazardous material is then separated from the liquid carbon dioxide by adsorption, and one part of the cleaned liquid carbon dioxide is fed into the useful gas to absorb hazardous substances still contained in the useful gas.

Abstract: Methods and systems of the current invention separate condensable vapors such as carbon dioxide from light gases or liquids in a mixed process stream. The separation is carried out in a cryogenic process using one or more external cooling loops (ECLs) that first cool down a mixed process stream containing condensable vapors and light gases or liquids, causing the condensable vapors to desublimate and form solids. Next, the solids are separated from the light gases or liquids, forming a solid stream and a light gas or liquid stream. Then the refrigerants of the ECL are cooled by warming the separated solid stream and light gas or liquid stream, efficiently recovering energy used in cooling and desublimating the condensable vapors.

Abstract: A process for separating sour shifted synthesis gas feedstock into liquid carbon dioxide, a gaseous hydrogen-containing gas and separated sulphur-containing components includes the steps of a. scrubbing the sour shifted gas elevated pressure with an alcohol solvent in a first scrubber and separately recovering an alcohol stream containing the sulphur-containing components and a sweet shifted gas; b. thereafter cooling the sweet shifted gas to a temperature and elevated pressure at which the carbon dioxide contained therein condenses and a two-phase gas- liquid mixture is formed; c. separating the two-phase mixture of stage (b) into separate liquid carbon dioxide and gaseous hydrogen-containing fractions in a fractionation unit; d. extracting residual carbon dioxide from the separated gaseous hydrogen-containing fraction by scrubbing the gaseous hydrogen-containing fraction at elevated pressure with an alcohol solvent in a second scrubber and recovering an alcohol stream containing carbon dioxide; e.

Abstract: A liquid carbon dioxide refrigeration system is provided. The refrigeration system may include a storage tank arranged for storing liquid carbon dioxide, and a vessel arranged to separate carbon dioxide into a vapor carbon dioxide portion and a liquid carbon dioxide portion. A first conduit is coupled to the storage tank and the first vessel such that liquid carbon dioxide can pass from the storage tank to the first vessel. A second conduit is coupled to the first vessel such that the liquid carbon dioxide portion can pass into a refrigeration device, and a third conduit is coupled to the first vessel and the first conduit to recycle the vapor carbon dioxide portion back to the first conduit.

Abstract: Dry dust removal method in organic chlorosilane production is provided, in which the detailed steps are as follows: delivering high-temperature flue gas (a) from fluidized bed reactor (I) into inorganic film cross-flow filter (E) to remove dust for the first time; delivering the concentrated dust gas (c) trapped by inorganic film cross-flow filter (II) into bag filter (III) to remove dust for the second time; returning the gas mixture (f) of passing through bag filter (EI) to the air intake of inorganic film cross-flow filter (II); condensing the residual clean gas (b) from the osmotic side of inorganic film in condenser (A), and then rectifying in rectifying column (B) to separate the products of chloromethane (g) and methyl chlorosilane (h) to obtain the product of methyl chlorosilane (h); returning chloromethane to fluidized bed reactor to take part in reaction; retreating the dust (e) trapped by inorganic film cross-flow filter and bag filter, and then returning it to fluidized bed reactor (I) to take par

Abstract: A method of separating a carbon-dioxide-rich liquid stream from a synthesis gas including carbon dioxide and hydrogen, includes carrying out a first cooling step to cool a synthesis gas feed stream using at least one heat exchanger such that a first two-phase mixture is formed. The first two-phase mixture is passed at a first pressure and a first temperature to a first separator and a first separation is carried out to separate the first mixture into a first CCVrich liquid stream and a H2-Hcli gas stream. The H2-rich gas stream is pressurised and a second cooling step is carried out to cool the H2-rich gas stream using at least one heat exchanger such that a second two-phase mixture is formed. The second mixture is passed at a second pressure and a second temperature to a second separator, the second pressure being higher than the first pressure and a second separation is carried out to separate the second mixture into a second CO2-rich liquid stream and a further H2-rich gas stream.

Abstract: A method for separating a feed gas, containing nitrogen and carbon monoxide as main components, in a distillation column: the feed gas is cooled in a heat exchanger; at least a portion of the feed gas, or at least a portion of a gas derived from the feed gas, is sent to a reboiler of the distillation column so as to condense the gas while producing a liquid, and optionally a gas; at least a portion of the liquid is sent to the distillation column; a nitrogen gas-rich flow is extracted from the distillation column; a carbon monoxide-rich flow is extracted from the distillation column, heated in the heat exchanger, and compressed so as to provide a carbon monoxide-rich material at production pressure.

Abstract: In a method for compressing a water-containing CO2-rich fluid wherein the CO2-rich fluid is compressed in a compressor located upstream from the compression step, an antifreeze agent is injected into the water-containing CO2-rich fluid in order to lower the water solidification temperature. The antifreeze agent-containing CO2-rich fluid is frozen, water is extracted from the frozen fluid, and the frozen fluid is compressed in the compressor.

Abstract: The invention relates to a method and a device for treating a carbon-dioxide-containing gas stream, in particular from a large-scale fired plant, e.g. from a power plant. The precompressed gas stream is separated in a carbon dioxide purification stage into a gas substream having an elevated carbon dioxide content (carbon dioxide product stream) and a gas substream having a decreased carbon dioxide content (vent gas stream). The carbon dioxide product stream is fed to further utilization and/or storage. In particular, by injecting the carbon dioxide underground, the emission of gases harmful to the climate can be reduced. For improving the energy efficiency, it is proposed that the vent gas stream is expanded in at least one expansion turbine and both the resultant kinetic energy and the resultant refrigeration are utilized for energy recovery.

Abstract: The invention relates to a method and an apparatus for treating a carbon dioxide-containing gas stream. Precompressed raw gas stream (1) is partially liquefied in a cryogenic carbon dioxide purification stage (2, 3, 4). Part of the resultant liquid is used to obtain a gas stream having an elevated carbon dioxide content (7). From the non-liquefied raw gas, a gas stream having a reduced carbon dioxide content is obtained. This vent gas stream is expanded and the refrigeration generated is recovered for cooling the raw gas stream. The carbon dioxide gas stream is compressed (8) to a final pressure and fed to further utilization and/or storage. Another part of the liquid from the cryogenic carbon dioxide purification stage is fed in a liquid phase (9) to further utilization and/or storage (10).

Abstract: A separation method and apparatus that separates a component from a feed stream by use of a membrane in which separation is driven, at least in part, by a sweep stream. The sweep stream may be pumped to a supercritical pressure and then heated to at least near supercritical temperature, at least in part, through heat exchange with a component laden sweep stream being discharged from the membrane. A multi-component mixture can also be used that will produce the sweep stream as a vapor as a result of the heat exchange. The component laden sweep stream, due to cooling through the indirect heat exchange, will form a two-phase fluid that can be phase separated into a vapor phase enriched in the component that can be taken as a product and a residual liquid that can be recirculated in the formation of the sweep stream in the liquid state.

Abstract: An improved process for the separation of carbon dioxide from the flue gas of an oxy-combustion power plant is provided. The flue gas is compressed, cleaned, cooled and dried. This clean, compressed dry flue gas is then further cooled, partially condensed and separated into liquid and vapor streams. The liquid streams, which contain a high concentration of carbon dioxide, are vaporized, compressed and exported to an end user. The vapor streams are heated and expanded, in order to extract useable energy. At least two expanders are used to extract this energy, with an intermediate warming step.

Abstract: Disclosed herein is a system comprising a first heat exchanger; the first heat exchanger being operative to reduce a temperature of a carbon dioxide rich flue gas stream to about ?100 to about ?60 C; an absorber; the absorber being located downstream of the first heat exchanger; wherein the absorber facilitates contact between the flue gas stream and a solvent to form a carbon dioxide rich solvent stream; the solvent being operative to selectively absorb carbon dioxide over other gases present in the flue gas stream; and a valve; the valve being located downstream of the absorber; the valve being operative to reduce a pressure on the carbon dioxide rich solvent stream to produce carbon dioxide and a lean carbon dioxide solvent stream.

Abstract: CO2 is removed from high-pressure feed gas in configurations and methods according to the inventive subject matter by contacting feed gas with cooled semi-rich solvent to form a two-phase mixture that is flashed into the bottom section of an absorber. Rich solvent from the absorber is then reduced in pressure to generate refrigeration for the semi-rich solvent and lean solvent countercurrently contacts the partially treated feed gas in the absorber to produce the semi-rich solvent. Among other advantages, cooling of the feed gas and semi-rich solvent by the pressure reduced rich solvent heats the rich solvent to allow enhanced regeneration of the solvent, and external refrigeration and heating of the solvent can be entirely avoided.

Abstract: The present invention provides methods and systems for extracting ethanol from an ethanol-water solution comprising (1) extracting ethanol from an ethanol-water solution with a first solvent comprising an esterified fatty acid, wherein the esterified fatty acid comprises a hydroxylated fatty acid component and an alcohol component such that the alcohol component is a C3-6 alcohol, such that the distribution coefficient for ethanol in the mixture of the ethanol-water solution and the first solvent is at least 0.02 favoring the transfer of ethanol from the ethanol-water solution to the first solvent, thereby extracting the ethanol from the ethanol-water solution into the first solvent, and (2) extracting the ethanol-enriched first solvent with carbon dioxide, such that the carbon dioxide is at a liquid or near supercritical phase, wherein the distribution coefficient for ethanol in a mixture of the first solvent and the carbon dioxide is at least 0.

Abstract: A process and system for recovering valuable by-products (e.g., hydrogen) from refinery gas streams. For hydrogen-only recovery, the invention comprises a partial condensation step to upgrade the refinery fuel gas to a minimum of 60% hydrogen, which is further purified in a pressure swing adsorption process. When configured to recover hydrogen, methane-rich gas and raw LPG (methane depleted gas containing C2 hydrocarbons and heavier), the invention comprises two partial condensation steps where the feed is cooled in the first step to allow separation of ethane and heavier hydrocarbons, and the resulting vapor is cooled to a lower temperature in a second step for hydrogen recovery.

Abstract: The present invention provides a method for purifying HFO-1234yf, comprising the steps of (1) cooling a liquid mixture containing HFO-1234yf and HF to separate the mixture into a upper liquid phase having a high concentration of HF and a lower liquid phase having a high concentration of 2,3,3,3-tetrafluoropropene; and (2) subjecting the lower liquid phase obtained in step (1) to a distillation operation to withdraw a mixture containing HFO-1234yf and HF from a top of a distillation column, thereby obtaining substantially HF-free HFO-1234yf from a bottom of the distillation column. According to the present invention, HF and HFO-1234yf contained in a mixture containing HF and HFO-1234yf can be separated under simple and economically advantageous conditions.

Abstract: Improvements in tubes, which increase the heat exchange capacity of tubular heat exchangers using the tubes, are described. These improvements involve the use of one or more external surface enhancements, optionally combined with an internal enhancement and/or differing tube geometries. These improvements apply, for example, to internal condensers, including those in which the tube bundles are oriented vertically, in vapor-liquid contacting apparatuses such as distillation columns.