Separation Of Gas Mixture Patents (Class 62/617)
  • Patent number: 7467527
    Abstract: The invention provides an installation for the production of hydrogen and/or carbon monoxide and/or a mixture of hydrogen and carbon monoxide, by separating a mixture to be processed (1) which contains at least carbon monoxide and hydrogen. Said installation comprises a production apparatus (9), for producing a feed mixture (3), a separating unit (BF), means for supplying the feed mixture to the separating unit, means for collecting hydrogen and/or carbon monoxide and/or a mixture of both products (7, 8), derived from the separating unit, means for drawing off at least one recycling gas (6) from the separating unit, means for returning said recycling gas upstream of the separating unit, for separating said gas simultaneously with the feed mixture from the production apparatus and means for modifying the rate and composition of said feed mixture, by modifying the operation of the production apparatus, according to the rate and composition of said at least one recycling gas.
    Type: Grant
    Filed: October 14, 2004
    Date of Patent: December 23, 2008
    Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventor: Alain Briglia
  • Publication number: 20080302132
    Abstract: The present invention relates to a method and an apparatus for continuously separating aromatic dialdehyde from a reaction mixture obtained by gas-phase oxidation of dimethylbenzene. The method for continuously separating aromatic dialdehyde includes the steps of congealing aromatic dialdehyde by cooling the gas-phase reaction mixture including the aromatic dialdehyde, which is obtained by gas-phase oxidation of dimethylbenzene, to 5-70° C. and separating the congealed aromatic dialdehyde from the remaining reaction mixture. Using the method and apparatus in accordance with the present invention, aromatic dialdehyde can be effectively and selectively separated from a reaction mixture obtained by gas-phase oxidation of dimethylbenzene in high yield.
    Type: Application
    Filed: June 2, 2008
    Publication date: December 11, 2008
    Inventors: Jong-Hyun Chae, Won-Ho Lee, Dong-Il Lee, Hyun-Kyung Yoon
  • Publication number: 20080302133
    Abstract: The method and the system for capturing the carbon dioxide present in flue-gas implement a) a first cooler device (110, 120) for cooling flue-gas and comprising at least one heat exchanger (122) for eliminating a fraction of the water present in the flue-gas by condensation; b) a flue-gas dehydration device (130); c) a second cooler device (140) for cooling the flue-gas and comprising at least one heat exchanger (141, 142) for bringing the flue-gas to a temperature that causes anti-sublimation of the carbon dioxide present in the flue-gas; d) a heater device (141, 142) in a closed enclosure for heating the solidified carbon dioxide to cause it to melt; and e) a device (144) for drawing off or pumping liquid and/or gaseous carbon dioxide to a thermally insulated tank (150).
    Type: Application
    Filed: December 20, 2006
    Publication date: December 11, 2008
    Applicant: GAZ DE FRANCE
    Inventors: Samuel Saysset, Joelle Gitton
  • Patent number: 7461521
    Abstract: The invention relates to a system unit for desorbing carbon dioxide and other impurities from highly pressurized methanol. Said system unit comprises at least one or more expansion vessels arranged in succession, at least one heat exchanger, and at least one liquid/gas separator. The inventive system unit contains: a) a line (1) through which the intensely cooled methanol leaving expansion vessel (C) is introduced into the heat exchanger (E) from underneath, and; b) a line (2), though which the heated methanol is drawn out of the heat exchanger (E) from the top, and which serves to connect said heat exchanger to a liquid/gas separator inside of which the remaining carbon dioxide still contained in the methanol is desorbed and separated out to the greatest possible extent. This system unit enables the cold due to evaporation, said cold resulting during the desorption of carbon dioxide, to be obtained inside a heat exchanger and constitutes an important cold energy source for carrying out absorption.
    Type: Grant
    Filed: April 19, 2003
    Date of Patent: December 9, 2008
    Assignee: Lurgi AG
    Inventors: William Davey, Manfred Meyer
  • Patent number: 7461522
    Abstract: A method of separating one or more first light components from a carbon dioxide containing gaseous mixture that contains at least 30 mole percent carbon dioxide. In accordance with the method, a feed stream composed of the carbon dioxide is cooled to effect at least in part, liquefaction of the carbon dioxide containing gaseous mixture. The feed stream and a stripping gas stream are introduced into a liquid-vapor contact column to initiate counter-current vapor liquid mass transfer and the formation of a gaseous column overhead stream and a liquid column bottoms stream. The stripping gas stream contains one or more second light components having boiling point lower than that of carbon dioxide and higher than that of the first light component(s) to enrich the gaseous column overhead stream with the first light component(s).
    Type: Grant
    Filed: November 26, 2007
    Date of Patent: December 9, 2008
    Assignee: Praxair Technology, Inc.
    Inventor: Henry Edward Howard
  • Patent number: 7454923
    Abstract: A method of separating one or more first light components from a carbon dioxide containing gaseous mixture that contains at least 30 mole percent carbon dioxide. In accordance with the method, a feed stream composed of the carbon dioxide is cooled to effect at least in part, liquefaction of the carbon dioxide containing gaseous mixture. The feed stream and a stripping gas stream are introduced into a liquid-vapor contact column to initiate counter-current vapor liquid mass transfer and the formation of a gaseous column overhead stream and a liquid column bottoms stream. The stripping gas stream contains one or more second light components having boiling point lower than that of carbon dioxide and higher than that of the first light component(s) to enrich the gaseous column overhead stream with the first light component(s).
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: November 25, 2008
    Assignee: Praxair Technology, Inc.
    Inventor: Henry Edward Howard
  • Publication number: 20080202160
    Abstract: The invention relates to a method and device for the fractionated cryocondensation of a process gas in at least one cooler and a freezer, wherein a specific process temperature is set inside the cooler.
    Type: Application
    Filed: January 4, 2008
    Publication date: August 28, 2008
    Inventors: Stefan Wolf, Hans-Rudolf Himmen, Hans-Jurgen Reinhardt
  • Patent number: 7407532
    Abstract: The invention relates to a process for separating NH3 from a mixture containing NH3, CO2 and H2O which comprises an NH3 rectification step carried out in a NH3 separation device to which one or more streams containing NH3, CO2 and H2O including the mixture, are supplied, with a stream consisting substantially of gaseous NH3 being formed in the NH3 separation device, separated from the mixture and discharged. In the process according to the invention a condensation step is carried out on at least one of the stream consisting substantially of gaseous NH3 or the one or more streams containing NH3, CO2 and H2O supplied to the NH3 separation device, in which at least a part of the existing CO2 is converted to a liquid phase.
    Type: Grant
    Filed: January 9, 2004
    Date of Patent: August 5, 2008
    Assignee: DSM IP Assets B.V.
    Inventors: Andreas Johannes Biermans, Kees Jonckers, Johannes Henricus Mennen, Nora Anna De Wit, Herbert Willem Gerrit Hooijkaas, Bastiaan Renè Agnes Marie Van De Kerkhove
  • Publication number: 20080168797
    Abstract: A gas condensate production plant comprises a plurality of separation units in which C2 and/or C3 lighter components are stripped from the separator feeds using compressed heated stripping vapor produced from the feed in respective downstream separation units. Contemplated plants substantially reduce heating and cooling duties by using the waste heat from the compressor discharges in the separation process. Furthermore, the multi-stage fractionation according to the inventive subject matter provides improved gas condensate recovery at reduced energy costs.
    Type: Application
    Filed: June 22, 2005
    Publication date: July 17, 2008
    Applicant: FLUOR TECHNOLOGIES CORPORATION
    Inventor: John Mak
  • Publication number: 20080134716
    Abstract: A method for separating hydrogen, helium and/or neon from a nitrogen-rich liquid fraction present at a pressure of at least 10 bar is disclosed. The nitrogen-rich liquid fraction is expanded and undergoes phase separation where expansion takes place at a pressure which allows separation of hydrogen, helium and/or neon except for residues of less than 20 ppmV.
    Type: Application
    Filed: February 3, 2006
    Publication date: June 12, 2008
    Inventors: Nikos Larass, Hans Schmidt
  • Patent number: 7380413
    Abstract: A method for simultaneously producing hydrogen and carbon monoxide by subjecting synthesis gas to a decarbonation in a decarbonation unit, and to desiccation in a desiccation unit. After the decarbonation and the desiccation, the remaining synthesis gas components are cryogenically separated and a hydrogen-enriched gas is recycled upstream from the decarbonation unit and downstream from synthesis gas producing unit.
    Type: Grant
    Filed: April 14, 2003
    Date of Patent: June 3, 2008
    Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Eric Dumont, Antoine Hernandez
  • Publication number: 20080115531
    Abstract: A cryogenic process for the production of oxygen by cryogenic distillation using an air separation unit comprising a double column, said double column comprising a high pressure column and a low pressure column comprising the steps of: sending compressed, cooled and purified air to the high pressure column in gaseous form, sending oxygen enriched fluid from the bottom of the high pressure column to the low pressure column, removing nitrogen enriched gas from the top of the high pressure column, sending a first portion of nitrogen enriched gas to a lower reboiler in the low pressure column following compression in a cold compressor having a cryogenic inlet temperature, sending a second portion of nitrogen enriched gas to an upper reboiler in the low pressure column, sending nitrogen enriched liquid from at least one of the first and second reboilers to at least one of the high pressure column and the low pressure column, expanding a stream of nitrogen enriched gas from the high pressure column in an expander f
    Type: Application
    Filed: November 16, 2006
    Publication date: May 22, 2008
    Inventors: Bao Ha, Jean-Renaud Brugerolle
  • Patent number: 7351310
    Abstract: A process for rectificatively separating fluids including (meth)acrylic monomers in a rectification column by directly cooling the vapor including (meth)acrylic monomers rising to the top of the rectification column to form top condensate including (meth)acrylic monomers, the condensation space at the top of the column being separated from the region of the rectification column containing the separating internals only by at least one chimney tray from which the top condensate formed is removed from the rectification column, which includes effecting the direct cooling of the vapor in the condensation space in at least two spray zones which are spatially successive and are flowed through by vapor by spraying supercooled top condensate including added polymerization inhibitor, and the temperature of the sprayed supercooled top condensate becoming lower from spray zone to spray zone in the flown direction of the vapor.
    Type: Grant
    Filed: September 10, 2003
    Date of Patent: April 1, 2008
    Assignee: BASF Aktiengesellschaft
    Inventors: Joachim Thiel, Albrecht Dams, Juergen Schroeder
  • Patent number: 7343759
    Abstract: Volatile vapors are removed from a storage vessel by establishing a flow of a stream of volatile vapors from the storage vessel and directing the stream through a first low temperature condenser for condensing a portion of the stream flowing through the first low temperature condenser. Since a portion of the condensed condensate freezes and causes a pressure drop in the first low temperature condenser, further steps may include directing the stream from the first low temperature condenser through a second low temperature condenser after the pressure drop exceeds a setpoint, stopping the flow of the refrigerant through the first low temperature condenser and using the heat of the volatile vapor stream to melt the frozen condensate in the first low temperature condenser. The stream is switched between the condensers as necessary to prevent excessive plugging due to frozen condensate formation. The system includes the means for implementing the method.
    Type: Grant
    Filed: March 29, 2005
    Date of Patent: March 18, 2008
    Assignee: Hilliard Emission Controls, Inc.
    Inventor: Henry T. Hilliard, Jr.
  • Patent number: 7337616
    Abstract: A system for sampling cryogenic liquids, and an air separation unit provided with at least one such system. The cryogenic liquid is introduced into a vaporizer, through heat exchange with the compressed air. The liquid passes through the vaporizer generally downwards. The walls of the vaporizer that are intended to come into contact with the cryogenic liquid are maintained at a temperature above the sublimation temperature or the boiling point of the least volatile impurity contained in this liquid. Downstream of the vaporizer, a gaseous phase coming from the vaporization of the cryogenic liquid is withdrawn and at least some of the gaseous phase is sent to an analyzer.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: March 4, 2008
    Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: David Meneses, Jean-Yves Thonnelier, Jean-Yves Lehman
  • Publication number: 20080034790
    Abstract: The invention relates to a method of enriching a pressurised gas stream (1) with one of the components (A) thereof. The inventive method comprises the following steps: the stream is separated into at least first and second fractions (2, 3); at least one part of the first fraction (2) is sent to a separation unit (ASU); the separation unit supplies at least two discharges, including a first discharge (10) having a greater A content than that of the fraction (2) supplied to the separation unit; at least one part of the first discharge (10) is mixed with at least one part of the second fraction (3) such as to form a pressurised gas mixture (15); the second fraction (3) is expanded and, subsequently, at least one part of the first discharge (10) is mixed therein.
    Type: Application
    Filed: November 5, 2004
    Publication date: February 14, 2008
    Inventors: Patrick Le Bot, Xavier Pontone
  • Patent number: 7305850
    Abstract: The disclosed invention relates to a process for distilling a fluid mixture in a microchannel distillation unit, the microchannel distillation unit comprising a plurality of microchannel distillation sections, the fluid mixture comprising a more volatile component and a less volatile component, the process comprising: flowing a vapor phase of the fluid mixture in a first microchannel distillation section in contact with a liquid phase of the fluid mixture, part of the more volatile component transferring from the liquid phase to the vapor phase to form a more volatile component rich vapor phase, part of the less volatile component transferring from the vapor phase to the liquid phase to form a less volatile component rich liquid phase; separating the more volatile component rich vapor phase from the less volatile component rich liquid phase; flowing the less volatile component rich liquid phase to another microchannel distillation section upstream from the first microchannel distillation section; and flowing
    Type: Grant
    Filed: July 23, 2004
    Date of Patent: December 11, 2007
    Assignee: Velocys, Inc.
    Inventors: Anna Lee Tonkovich, Wayne W. Simmons, Laura J. Silva, Dongming Qiu, Steven T. Perry, Thomas Yuschak
  • Publication number: 20070277551
    Abstract: Processes are disclosed which include: (a) providing a gas comprising chlorine, oxygen, and carbon dioxide; (b) feeding the gas to a distillation column having a head, a bottom, a rectifying section and a stripping section, wherein the gas is fed to the distillation column at an introduction point between the rectifying section and the stripping section; (c) distilling the gas in the column at a pressure of 8 to 30 bar and at a column head temperature of ?10° C. to ?60° C., to form liquid chlorine and a head mixture comprising carbon dioxide and oxygen; (d) removing the liquid chlorine from the distillation column at the bottom of the column; and (e) removing a first portion of the head mixture from the head of the distillation column, and refluxing a second portion of the head mixture in the column.
    Type: Application
    Filed: May 17, 2007
    Publication date: December 6, 2007
    Applicant: Bayer Material Science AG
    Inventor: Friedhelm Kamper
  • Patent number: 7302812
    Abstract: A process for producing an isotopically enriched compound of a desired isotope includes (a) providing a cryogenic reaction zone containing a catalyst adapted to catalyze an isotope exchange reaction at a cryogenic reaction temperature, (b) feeding to the cryogenic reaction zone an enriched mixture comprising at least a compound containing the desired isotope, wherein the enriched mixture is enriched in the desired isotope above a natural abundance of the desired isotope, (c) reacting the enriched mixture in the cryogenic reaction zone thereby forming a resulting mixture containing the isotopically enriched compound, and (d) separating the resulting mixture into an enriched product which is enriched in the isotopically enriched compound and a depleted product which is depleted in the isotopically enriched compound.
    Type: Grant
    Filed: September 2, 2003
    Date of Patent: December 4, 2007
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Matthew Joseph Okasinski, David Ross Graham, Adam Adrian Brostow, Madhukar Bhaskara Rao
  • Patent number: 7294327
    Abstract: A relatively simple and energy efficient multiple stage cryogenic process for the purification of a hydrogen-rich stream by the removal of acid gases, mainly CO2 and H2S, by method of autorefrigeration and delivering or producing those acid gases, mainly CO2, at pressure sufficiently high for disposal by containment, commonly known as sequestration. Autorefrigeration is comprised of (a) condensing acid gases from the syngas stream by cooling the syngas, (b) separating the liquefied acid gases from the syngas, and (c) evaporating the liquefied acid gases at a pressure lower than that of the syngas to provide cooling. The process is composed of multiple autorefrigeration stages to generate multiple acid gas product streams with a pressure as high as practical in each stream so as to lessen the power needed to pressurize the acid gas streams for sequestration.
    Type: Grant
    Filed: March 21, 2006
    Date of Patent: November 13, 2007
    Assignee: Tennessee Valley Authority
    Inventors: Timmons S. McClanahan, Michael C. Crim
  • Patent number: 7269972
    Abstract: An plant unit for fractionating and purifying synthesis gas is described, which is comprised of a device for partially condensing synthesis gas and a device for nitrogen washing, whereat the device for nitrogen washing is adjacent to the device for partial condensation.
    Type: Grant
    Filed: March 22, 2003
    Date of Patent: September 18, 2007
    Assignee: Lurgi AG
    Inventor: William Davey
  • Patent number: 7266948
    Abstract: Method and device for separating gases and/or liquids in a vertical column (1). The top product (4) of the column (1) is cooled and partly recycled. The bottom product (3) of the column (1) is heated and partly recycled. Cooling and heating take place with the aid of a thermoacoustic heat pump (10), which can be driven by external heating (2). A relatively large temperature difference between top product and bottom product can be overcome by this means.
    Type: Grant
    Filed: September 10, 2004
    Date of Patent: September 11, 2007
    Assignee: Stitchting Energieonderzoek Centrum Nederland
    Inventor: Symen Spoelstra
  • Patent number: 7263858
    Abstract: The present invention provides generally a method and apparatus for purifying a liquid. More particularly, purification of a bulk liquid is performed by introducing a liquid stream to a purification vessel, which comprises both a distillation chamber for forming a purified vapor and an annular chamber for collecting a purified liquid that is condensed from the purified vapor. A refrigerant system provides thermodynamic efficiency in the purification method by directing waste heat generated in one part of the refrigerant system for heating duty in another part of the refrigerant system. The method and apparatus can be applied to producing purified carbon dioxide, nitrous oxide, ammonia and fluorocarbons.
    Type: Grant
    Filed: May 20, 2005
    Date of Patent: September 4, 2007
    Assignee: The BOC Group, Inc.
    Inventor: Walter Whitlock
  • Patent number: 7237407
    Abstract: This process includes the following steps: (a) the feed natural gas (101) is introduced into a first distillation column (31) which produces, as top product, a pretreated natural gas (111), which pretreated natural gas (111) no longer contains practically any C6+ hydrocarbons; (b) the pretreated natural gas (111) is introduced into an NGL recovery unit (19) comprising at least a second distillation column (49), so as to produce, on the one hand, as column top product, a purified natural gas (151) and, on the other hand, an NGL cut (15); and (c) the said liquefiable natural gas (161) is formed from the purified natural gas (151) resulting from step (b).
    Type: Grant
    Filed: June 2, 2004
    Date of Patent: July 3, 2007
    Assignee: Technip France
    Inventor: Henri Paradowski
  • Patent number: 7231785
    Abstract: Temperature related changes in dimension in a column system, having at least one separating column, a column vessel and a coldbox with coldbox casing, can be compensated for by providing for axial and/or radial movement. The column vessel is connected to the coldbox casing slidably in the axial and/or radial direction by means of radial, rigid connecting members (3, 3a, 3b, 3c, 3d).
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: June 19, 2007
    Assignee: Linde Aktiengesellschaft
    Inventor: Stefan Wilhelm
  • Patent number: 7219512
    Abstract: An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO2) clean-up cycle.
    Type: Grant
    Filed: May 5, 2005
    Date of Patent: May 22, 2007
    Assignee: Battelle Energy Alliance, LLC
    Inventors: Bruce M. Wilding, Dennis N. Bingham, Michael G. McKellar, Terry D. Turner, Kevin T. Raterman, Gary L. Palmer, Kerry M. Klingler, John J. Vranicar
  • Patent number: 7201019
    Abstract: A method of separating one or more light components, such as helium, from a carbon dioxide containing stream. A two-phase stream is obtained, at least in part, by cooling a pressurized feed stream to at least partially condense such stream. The stream that is subsequently degassed to produce a first vapor stream enriched in the light component(s) and a first liquid stream containing an entrained fraction of the light component(s). The first liquid stream is expanded to create another two-phase stream that is degasified to produce a second vapor stream that is also enriched in the light component(s) and a second liquid stream having an enriched carbon dioxide content. The second liquid stream is repressurized and vaporized. In case of a supercritical feed, the pressurized feed stream is expanded after having been cooled. Thereafter, the feed is degassed to produce the light component enriched vapor stream and a liquid stream enriched in the carbon dioxide.
    Type: Grant
    Filed: November 19, 2004
    Date of Patent: April 10, 2007
    Assignee: Praxair Technology, Inc.
    Inventor: Henry Edward Howard
  • Patent number: 7089762
    Abstract: Multi-stage vacuum distilling, cooling, and freezing processes for solution separation and seawater desalination are implemented through multi-stage vacuum distilling, cooling, and freezing systems. The systems are set to their initial state for implementing constant temperature distilling process, drain-to-vacuum and freezing process, transferring of a specific solution, and recycling of a hot circulating solution, so as to separate the specific solution. In the multi-stage cooling process, vacuum evaporation cooling is utilized to cool the solution in order to supply the low-temperature solution needed in the multi-stage vacuum freezing process. Vapors produced in the multi-stage vacuum distilling and cooling systems provide condensation heat needed to melt ice crystals produced in the multi-stage vacuum freezing system.
    Type: Grant
    Filed: June 27, 2003
    Date of Patent: August 15, 2006
    Inventor: Cheng-Ming Chou
  • Patent number: 7076969
    Abstract: A system for the supply and delivery of a high or a ultrahigh purity (UHP) carbon dioxide product stream to at least one process tool within a manufacturing facility and method comprising same is disclosed herein. In one embodiment, the system is comprised of the following sub-systems: a carbon dioxide source, a carbon dioxide delivery system, and the point of use (POU) containing at least one process tool.
    Type: Grant
    Filed: January 19, 2004
    Date of Patent: July 18, 2006
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Vladimir Yliy Gershtein, Paul Anthony Mattiola, John Frederick Cirucci, John Christopher Ivankovits
  • Patent number: 7076970
    Abstract: A system for the bulk supply and delivery of a carbon dioxide product stream to at least one process tool in a plurality of applications at varying pressure, purity or other process parameter within a manufacturing facility and method comprising same is disclosed herein. In one embodiment, the system is comprised of: a carbon dioxide source, a carbon dioxide delivery system containing a low pressure delivery and distribution system, and a plurality of applications containing at least one process tool.
    Type: Grant
    Filed: January 19, 2004
    Date of Patent: July 18, 2006
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Vladimir Yliy Gershtein, Paul Anthony Mattiola
  • Patent number: 7069742
    Abstract: This invention relates to an improvement in a process and apparatus for delivering ultra high purity liquid carbon dioxide to a point of use at pressures above ambient without pumping. In the process a high purity carbon dioxide feed is charged to a vessel and at least partially solidified. Once filled, the slush or solid is isochorically heated, i.e., heated at constant vessel volume whereby the solid phase carbon dioxide is converted to a liquid. Liquid, then, is withdrawn from the vessel at a desired pressure at a rate at which the solid phase carbon dioxide is converted to a liquid. The improvement resides in effecting partial solidification and recycle of carbon dioxide.
    Type: Grant
    Filed: January 19, 2004
    Date of Patent: July 4, 2006
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Vladimir Yliy Gershtein
  • Patent number: 7048777
    Abstract: The invention uses both heating and cooling zones to prevent the precipitation of solids onto equipment surfaces until they are efficiently removed from the gas phase via one or more heat exchangers. Each heat exchanger may be regenerated to melt off the solids when the amount collected becomes excessive. A storage plenum is available under each heat exchanger to store the melted solids until final removal to avoid the need to open the equipment for the removal of the unwanted solids.
    Type: Grant
    Filed: December 31, 2003
    Date of Patent: May 23, 2006
    Assignee: Air Liquide America, L.P.
    Inventor: Richard A. Sauer
  • Patent number: 7013673
    Abstract: Processes and apparatus are disclosed for separating and purifying aqueous solutions such as seawater by causing a substantially impermeable mat of gas hydrate to form on a porous restraint. Once the mat of gas hydrate has formed on the porous restraint, the portion of the mat of gas hydrate adjacent to the restraint is caused to dissociate and flow through the restraint, e.g., by lowering the pressure in a collection region on the opposite side of the restraint. The purified or desalinated water may then be recovered from the collection region. The process may be used for marine desalination as well as for drying wet gas and hydrocarbon solutions. If conditions in the solution are not conductive to forming hydrate, a heated or refrigerated porous restraint may be used to create hydrate-forming conditions near the restraint, thereby causing gas hydrates to form directly on the surface of the restraint.
    Type: Grant
    Filed: March 25, 2005
    Date of Patent: March 21, 2006
    Assignee: Marine Desalination Systems, L.L.C.
    Inventor: Michael D. Max
  • Patent number: 6955714
    Abstract: A collecting facility for collecting a component of a high melting point in a gas that includes a collecting tower through which a gas flows, a treating liquid projecting apparatus projecting treating liquid having temperature not higher than the melting point of a high melting point component in the gas in the collecting tower, and an extracting device for extracting from the inside of the collecting tower a slurry composed of the treating liquid and the high melting point component solidified by contact with the treating liquid.
    Type: Grant
    Filed: August 8, 2003
    Date of Patent: October 18, 2005
    Assignees: Tsukishima Kikai Co., Ltd., Idemitsu Kosan Co., Ltd.
    Inventors: Kenji Oouchi, Kiwamu Ishii, Jyunji Wakayama, Tomio Ohno
  • Patent number: 6915660
    Abstract: A method and system for liquefaction monitoring of a gas in a gas piping system in which pressure and temperature information about the gas is gathered and the liquefaction status of the gas is determined and reported.
    Type: Grant
    Filed: April 6, 2001
    Date of Patent: July 12, 2005
    Assignee: The BOC Group, Inc.
    Inventors: Gavin D. Hartigan, David L. Ruppert, Henry S. Hui
  • Patent number: 6912872
    Abstract: The present invention provides generally a method and apparatus for purifying a liquid. More particularly, purification of a bulk liquid is performed by introducing a liquid stream to a purification vessel, which comprises both a distillation chamber for forming a purified vapor and an annular chamber for collecting a purified liquid that is condensed from the purified vapor. A refrigerant system provides thermodynamic efficiency in the purification method by directing waste heat generated in one part of the refrigerant system for heating duty in another part of the refrigerant system. The method and apparatus can be applied to producing purified carbon dioxide, nitrous oxide, ammonia and fluorocarbons.
    Type: Grant
    Filed: August 23, 2002
    Date of Patent: July 5, 2005
    Assignee: The BOC Group, Inc.
    Inventor: Walter H. Whitlock
  • Patent number: 6907751
    Abstract: Liquid is distributed substantially uniformly in a liquid-vapour separation column 22 located on an off-shore floating platform using a liquid distributor 24 characterised in that (i) the distance between the two apertures that are furthest apart in the or each secondary distributor is such that the liquid distributor provides, at each angle of tilt, a standard deviation of liquid flow rates through the apertures of the or each secondary distributor that is less than a first predetermined maximum for all angles of tilt; and (ii) the difference in flow rate between the aperture having maximum liquid flow and the aperture having minimum liquid flow in the or each secondary distributor at each angle of tilt is less than a second predetermined maximum for all angles of tilt.
    Type: Grant
    Filed: July 14, 2003
    Date of Patent: June 21, 2005
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Mohammad A. Kalbassi, Ian R. Zone
  • Publication number: 20040261451
    Abstract: The invention relates to a method and system for purifying exhaust gas, especially a solvent-containing exhaust gas from refrigerator recycling, wherein the dried, pressurized exhaust gas is cryogenically condensed, the condensed components are seperated from the remaining exhaust gas, the cold and purified pressurized exhaust gas is passed through an adsorber to adsorbe the remaining condensed components, the adsorber is purged with a warmed gas stream, namely either a warmed inert gas stream or the purified exhaust gas respectively at reduced pressure, and the desorbed gas is recycled.
    Type: Application
    Filed: April 28, 2004
    Publication date: December 30, 2004
    Inventors: Hans Erler, Peter Zollner, Klaus Hermanns, Norbert Hagenbruck
  • Publication number: 20040231358
    Abstract: Gases are vented from a waste site such as a landfill, and the gases are separated into at least three streams comprising a hydrocarbon stream, a carbon dioxide stream, and residue stream. At least a portion of the carbon dioxide stream and hydrocarbon stream are liquefied or converted to a supercritical liquid. At least some of the carbon dioxide gas stream (as a liquid or supercritical fluid) is used in a cleaning step, preferably a polymer cleaning step, and more preferably a polymer cleaning step in a polymer recycling process, and most preferably in a polymer cleaning step in a polymer recycling system where the cleaning is performed on-site at the waste site.
    Type: Application
    Filed: May 22, 2003
    Publication date: November 25, 2004
    Applicant: Cool Clean Technologies
    Inventors: Jon P. Wikstrom, Dan Schiller, Jon R. Turner
  • Publication number: 20040206112
    Abstract: An NGL recovery plant includes a demethanizer (7) in which internally generated and subcooled lean oil absorbs CO2 and C2 from a gas stream (11), thereby preventing build-up and freezing problems associated with CO2, especially where the feed gas has a CO2 treatment at ethane recoveries above 90% and propane recoveries of at least 99%.
    Type: Application
    Filed: June 14, 2004
    Publication date: October 21, 2004
    Inventor: John Mak
  • Publication number: 20040163411
    Abstract: High boiling contaminants such as chloro-aromatic compounds are removed from a gas by compressing the gas containing the contaminant, cooling the compressed gas to reduce the temperature of the gas to at least 20° C. above the outlet temperature of a second cooling stage but above the freezing point of the highest melting compound in the first cooling stage, further cooling the gas in a second cooling stage to at least −20° C., returning cooled gas from the second cooling stage to the first cooling stage, and recovering condensate streams which contain the contaminant compound from the first and second cooling stages. An apparatus suitable for carrying out this process is also disclosed. The process of the present invention is particularly useful for removing chloro-aromatic compounds from anhydrous hydrogen chloride gas.
    Type: Application
    Filed: February 26, 2004
    Publication date: August 26, 2004
    Inventors: Bill L. Brady, Guenther Weymans, Berthold Keggenhoff, Friedhelm Steffens
  • Publication number: 20040148961
    Abstract: The present invention pertains to a method and system for extracting and storing carbon dioxide from fumes derived from the combustion of hydrocarbons in an apparatus designed in particular for the production of mechanical energy. The system comprises: extracting means, in particular exchangers (11, 25) and a dehydrator (56), for extracting water from the said fumes in liquid form at a pressure more or less equal to atmospheric pressure; cooling means, in particular an integrated cascaded refrigerating apparatus (18, 22, 25, 26, 28, 32, 33, 34, 39, 40), for cooling the said fumes at a pressure more or less equal to atmospheric pressure and at a temperature such that the carbon dioxide passes directly from the vapor state to the solid state, via an anti-sublimation process; storage means, in particular a fixed (49) and/or removable (51) reservoir and suction means, in particular a pneumatic pump (48), for storing the carbon dioxide in liquid form after defrosting.
    Type: Application
    Filed: April 7, 2004
    Publication date: August 5, 2004
    Inventors: Denis Clodic, Mourad Younes
  • Publication number: 20040129021
    Abstract: A process for rectificatively separating fluids comprising (meth)acrylic monomers in a rectification column by directly cooling the vapor comprising (meth)acrylic monomers rising to the top of the rectification column to form top condensate comprising (meth)acrylic monomers, the condensation space at the top of the column being separated from the region of the rectification column containing the separating internals only by at least one chimney tray from which the top condensate formed is removed from the rectification column, which comprises effecting the direct cooling of the vapor in the condensation space in at least two spray zones which are spatially successive and are flowed through by vapor by spraying supercooled top condensate comprising added polymerization inhibitor, and the temperature of the sprayed supercooled top condensate becoming lower from spray zone to spray zone in the flow direction of the vapor.
    Type: Application
    Filed: September 10, 2003
    Publication date: July 8, 2004
    Applicant: BASF Akiengesellschaft
    Inventors: Joachim Thiel, Albrecht Dams, Jurgen Schroder
  • Patent number: 6746516
    Abstract: An air treatment system including an exhaust including an exhaust annulus defined by an inner exhaust wall, an outer exhaust wall circumscribing the inner wall, and a pressurized annulus between the inner and outer walls, and at least one condenser suspended within the exhaust annulus, where the at least one condenser includes a cooling fluid therein.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: June 8, 2004
    Inventor: James A. Titmas
  • Patent number: 6740226
    Abstract: In a hydrocracking unit, the flash gases from the high-pressure separator are fed to the bottom of an absorption zone where the entering gases are counter-currently contacted with a lean solvent. The lean solvent absorbs away the contained methane, ethane, propane, butanes and pentanes (C1+) from the contained hydrogen. The overhead gas stream from the absorption zone typically contains hydrogen at a purity of 90 to 98 mol %, or even higher, which is fed to the recycle gas stream to provide hydrogen purity in the range of 96 to 99 mol %, thereby providing an increase in the overall efficiency of the hydroprocessor unit. The process can also be employed with hydrotreating, hydrodesulfurization, hydrodenitrogenation and hydrodealkylation reactors.
    Type: Grant
    Filed: January 16, 2002
    Date of Patent: May 25, 2004
    Assignee: Saudi Arabian Oil Company
    Inventors: Yuv Raj Mehra, Ali Hassan Al-Abdulal
  • Patent number: 6735978
    Abstract: A system and process for utilization and disposition of a supercritical fluid composition, in which a supercritical fluid (SCF) composition is used in an SCF-using process facility such as a semiconductor manufacturing plant. The supercritical fluid composition is withdrawn from the process facility containing at least one component that is extraneous with respect to the further disposition of the supercritical fluid composition. The withdrawn supercritical fluid composition is converted to a pressurized liquid, which is treated to at least partially remove the extraneous component(s) therefrom. The extraneous component(s)-depleted pressurized liquid in its further disposition can be reconverted to a supercritical state for recycle to the SCF-using process facility, or it can be gasified and discharged to the atmosphere in the case of supercritical fluids such as CO2.
    Type: Grant
    Filed: February 11, 2003
    Date of Patent: May 18, 2004
    Assignee: Advanced Technology Materials, Inc.
    Inventors: Glenn M. Tom, Michael B. Korzenski, Eliodor G. Ghenciu, Chongying Xu, Thomas H. Baum
  • Patent number: 6712881
    Abstract: An apparatus and method for producing a diffusive, continuous laminar flow for particle growth via condensation of vapors with a mass diffusivity near or higher than the thermal diffusivity of the surrounding gas. In an exemplary embodiment, the method uses the condensation of water vapor onto particles suspended in air.
    Type: Grant
    Filed: January 30, 2003
    Date of Patent: March 30, 2004
    Assignee: Aerosol Dynamics Inc.
    Inventors: Susanne Vera Hering, Mark Richard Stolzenburg
  • Patent number: 6713158
    Abstract: A structured packing with improved packing elements and method of using the structured packing. Each structured packing element comprises corrugated sheets and planar members alternating with and located between the corrugated sheets The planar members are positioned so that at least the lowermost horizontal edges of the planar members and the corrugated sheets are situated proximal to one another. Perforations provided in the planar members and the corrugated sheets are designed to avoid turbulent flows and bulk fluid flow across the packing element while allowing transverse pressure equalization. Different configurations of corrugated sheets may be used with the planar members to form the structured packing.
    Type: Grant
    Filed: December 22, 2000
    Date of Patent: March 30, 2004
    Assignee: The BOC Group, Inc.
    Inventors: Kevin McKeigue, Ramachandran Krishnamurthy, Nancy Irwin, Hendrik Jekeli Kooijman
  • Publication number: 20040050094
    Abstract: The invention concerns a method and an installation for purifying impure helium. Said method consists in subjecting the helium to at least two successive steps: (a) cryogenic refrigeration of impure helium so as to eliminate by condensation at least part of the main impurities it contains and recuperating helium with intermediate purity containing residual impurities; and (b) permeation of at least part of the helium with intermediate purity derived form step (a) so as to eliminate at least part of said residual impurities and recuperating helium with final purity higher than said intermediate purity. Said method and said installation are useful for purifying impure helium recuperated at the output of an optical fibre cooling chamber, prior to the reintroduction of the resulting purified helium into said chamber so as to recycle the helium.
    Type: Application
    Filed: September 22, 2003
    Publication date: March 18, 2004
    Inventors: Jean-Yves Thonnelier, Catherine Candela
  • Publication number: 20040045440
    Abstract: A method and apparatus for continuously removing siloxanes and H2O from a waste gas stream containing H2O and siloxanes comprises cooling the waste gas stream in a primary heat exchanger to a temperature of greater than 32° F. to condense a portion of the H2O from the waste gas stream, chilling the waste gas stream in a first gas-refrigerant heat exchanger to a temperature of about −20° F. to condense the siloxanes and freeze the H2O, and then directing the cooled waste gas stream from the primary heat exchanger to a second gas-refrigerant heat exchanger while the first gas-refrigerant heat exchanger is defrosted to remove frozen H2O and siloxanes.
    Type: Application
    Filed: September 5, 2002
    Publication date: March 11, 2004
    Applicant: Pioneer Air Systems, Inc.
    Inventors: Sanjiv K. Baseen, Rame Sulaiman