Separation Of Gas Mixture Patents (Class 62/617)
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Publication number: 20100261942Abstract: A method for producing isoprene comprising an aqueous medium including genetically modified host cells capable of producing isoprene, where the resulting isoprene composition is processed through at least one separation and/or purification process to provide an isoprene enriched composition and a system for doing the same.Type: ApplicationFiled: March 1, 2010Publication date: October 14, 2010Applicant: Amyris Biotechnologies, Inc.Inventor: Derek McPhee
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Patent number: 7806965Abstract: Produced natural gas containing carbon dioxide is dehydrated and chilled to liquefy the carbon dioxide and then fractionated to produce a waste stream of liquid carbon dioxide and hydrogen sulfide. Natural gas liquids may be first separated and removed before fractionation. After fractionation, the waste stream is pressurized and transmitted to a remote injection well for injection either for disposal of the waste stream and preferably to urge hydrocarbons toward the producing well. A hydrocarbon stream proceeds from fractionation to a methanol absorber system which removes carbon dioxide gas. The hydrocarbon stream is thereafter separated into at least hydrocarbon gas, nitrogen and helium. Some of the nitrogen is reintroduced into a fractionation tower to enhance the recovery of hydrocarbons. A methanol recovery system is provided to recover and reuse the methanol. The hydrocarbons are sold as natural gas and the helium is recovered and sold. Excess nitrogen is vented.Type: GrantFiled: August 22, 2008Date of Patent: October 5, 2010Inventor: Donald Leo Stinson
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Patent number: 7793517Abstract: An ethane recovery process utilizing multiple reflux streams is provided. Feed gas is cooled, partially condensed, and separated into a first liquid stream and a first vapor stream. First liquid stream is expanded and sent to a demethanizer. First vapor stream is split into a first and a second separator vapor streams. First separator vapor stream is expanded and sent to demethanizer. Second separator vapor stream is partially condensed and is separated into a reflux separator liquid stream, which is sent to demethanizer, and a reflux separator vapor stream, which is condensed and sent to demethanizer. Demethanizer produces a tower bottom stream containing a substantial amount of ethane and heavier components, and a tower overhead stream containing a substantial amount of remaining lighter components and forms a residue gas stream. A portion of residue gas stream is cooled, condensed, and sent to the demethanizer tower as top reflux stream.Type: GrantFiled: December 30, 2008Date of Patent: September 14, 2010Assignee: Lummus Technology Inc.Inventors: Sanjiv N. Patel, Jorge H. Foglietta
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Patent number: 7771509Abstract: A process for separating O2 from air, that includes the steps effecting an increase in pressure of an air stream, magnetically concentrating O2 in one portion of the pressurized air stream, the one portion then being an oxygen rich stream, and there being another portion of the air stream being an oxygen lean stream, compressing the oxygen rich stream and removing water and carbon dioxide therefrom, to provide a resultant stream, and cryogenically separating said resultant stream into a concentrated oxygen stream and a waste stream.Type: GrantFiled: September 7, 2007Date of Patent: August 10, 2010Assignee: Cryogenic Group, Inc.Inventor: Ross M. Brown
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Patent number: 7749307Abstract: Process for providing a purified gas stream, comprising: providing a crude gas stream comprising an organic impurity; condensing at least a portion of the impurity from the gas stream to form a prepurified gas stream; and subjecting the prepurified stream to adsorption on a first adsorption medium; wherein the first medium is subjected to a regeneration comprising: providing a circulating inert gas stream having a temperature of at least 100° C.; passing the circulating inert gas stream over the first medium to form an organic impurity-loaded inert gas stream; cooling the loaded stream; condensing at least a portion of the organic impurity from the cooled stream to provide a prepurified circulating inert gas stream; subjecting the prepurified gas stream to adsorption on a second adsorption medium to provide a purified circulating inert gas stream; and recycling the purified gas stream to the circulating inert gas stream.Type: GrantFiled: April 10, 2008Date of Patent: July 6, 2010Assignee: Bayer MaterialScience AGInventors: Ole Brettschneider, Knud Werner, Torsten Erwe
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Publication number: 20100162754Abstract: A method and to a device for separating a mixture of hydrogen, methane and carbon monoxide by cryogenic distillation is provided. In particular, the present invention relates to a method for producing a mixture of H2/CO with a low CH4 content, possibly combined with the production of CH4 in liquid form.Type: ApplicationFiled: April 23, 2008Publication date: July 1, 2010Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation des Procedes Georges ClaudeInventors: Jean Billy, Antoine Hernandez, Marie-Khuny Khy
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Patent number: 7740812Abstract: The present invention relates to a method and an apparatus for continuously separating aromatic dialdehyde from a reaction mixture obtained by gas-phase oxidation of dimethylbenzene. The method for continuously separating aromatic dialdehyde includes the steps of congealing aromatic dialdehyde by cooling the gas-phase reaction mixture including the aromatic dialdehyde, which is obtained by gas-phase oxidation of dimethylbenzene, to 5-70° C. and separating the congealed aromatic dialdehyde from the remaining reaction mixture. Using the method and apparatus in accordance with the present invention, aromatic dialdehyde can be effectively and selectively separated from a reaction mixture obtained by gas-phase oxidation of dimethylbenzene in high yield.Type: GrantFiled: June 2, 2008Date of Patent: June 22, 2010Assignee: LG Chem, Ltd.Inventors: Jong-Hyun Chae, Won-Ho Lee, Dong-Il Lee, Hyun-Kyung Yoon
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Publication number: 20100150813Abstract: A method and apparatus for producing carbon monoxide by cryogenic distillation is presented.Type: ApplicationFiled: January 30, 2008Publication date: June 17, 2010Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Alain Briglia, Arthur Darde, Natacha Haik-Beraud, Marie-Khuny Khy
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Publication number: 20100147023Abstract: The invention relates to cryogenic engineering. The inventive device for liquefying and separating gas and for releasing one or more gases from a mixture thereof, comprises, in series axially positioned, a prechamber (1) with gas flow whirling means (2) arranged therein, a subsonic or supersonic nozzle (3) with a working segment (4), which is abutted thereto and to which liquid phase extracting means (5) is connected, and a subsonic diffuser (7) or the combination of a supersonic (6) and the subsonic diffuser (7). The nozzle (3) is designed in such a way that it makes it possible to achieve the ratios, between the inlet and outlet cross-sectional areas and the minimum cross-section thereof, which provides, at the output of the nozzle, a statical pressure and a statical temperature corresponding to the conditions of condensation of gas or target gas mixture components. The length of the working segment (4) is selected according to a condition of forming condensate drops with a size greater than 0.Type: ApplicationFiled: July 31, 2008Publication date: June 17, 2010Applicant: TransLang Technology LTdInventors: Vadim Ivanovich Alferov, Lev Arkadievich Bagirov, Leonard Makarovich Dmitriev, Salavat Zainetdinovich Imaev, Vladimir Isaakovich Feygin
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Publication number: 20100126215Abstract: The invention relates to a method for the cryogenic separation, the cooling or the liquefaction of a fluid using an exchange line, that comprises extracting from said exchange line at least one dual phase fluid (11), separating said dual phase fluid into at least one vapour fraction (4) and one liquid fraction (5) in a phase separator (40), expanding at least one portion of the liquid fraction (5) using a first expansion means (60, 90), reinjecting, reheating and at least partially vaporising said expanded liquid fraction in the exchange line, the first expansion means being a valve, wherein during the cooling of said exchange line, at least a fraction of the fluid extracted from the exchange line (2, 4 or 5) and/or from the phase separator (40) is expanded in second expansion means (61, 71, 81, 91) parallel to the first expansion means (6), while during a normal operation, the second expansion means is essentially closed.Type: ApplicationFiled: April 2, 2008Publication date: May 27, 2010Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Philippe Court, Antoine Hernandez, Christian Monereau
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Publication number: 20100126180Abstract: This invention relates to the recovery of carbon dioxide (26) and hydrogen (3,24) concentrated form from shifted a synthesis gas stream comprising hydrogen and carbon dioxide thereby generating a carbon dioxide stream that is sequestered or used for enhanced oil recovery and a hydrogen stream that is used as fuel for a power plant thereby generation electricity. In the process of the present invention a shifted synthesis gas stream is fed to a hydrogen selective membrane separation unit (M101) at a pressure of at least 50 bar gauge and the hydrogen rich permeate stream (3) is fed directly to the combustor of a gas turbine without any requirement to re-compress the hydrogen. The residual gas stream (carbon dioxide enriched stream) from the membrane separation unit is cooled using at least one, preferably, at least two external refrigeration stages (E-101, E-102, E-103, E-104) such that the hydrogen containing offgas (24) is also obtained at above the operating pressure of the combustor of the gas turbine.Type: ApplicationFiled: July 8, 2008Publication date: May 27, 2010Inventors: Jonathan Alec Forsyth, Roger Neil Harper, Antonie Pieter Hinderink, Badrul Huda, Evert Van Der Pol
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Publication number: 20100122552Abstract: A separation method and apparatus that separates a component from a feed stream by use of a membrane in which separation is driven, at least in part, by a sweep stream. The sweep stream may be pumped to a supercritical pressure and then heated to at least near supercritical temperature, at least in part, through heat exchange with a component laden sweep stream being discharged from the membrane. A multi-component mixture can also be used that will produce the sweep stream as a vapor as a result of the heat exchange. The component laden sweep stream, due to cooling through the indirect heat exchange, will form a two-phase fluid that can be phase separated into a vapor phase enriched in the component that can be taken as a product and a residual liquid that can be recirculated in the formation of the sweep stream in the liquid state.Type: ApplicationFiled: November 10, 2009Publication date: May 20, 2010Inventors: Joseph Michael Schwartz, Raymond Francis Drnevich, Jerome Thomas Jankowiak, Dante Patrick Bonaquist
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Patent number: 7716947Abstract: Apparatus for condensing hydrocarbons, such as but not limited to butane and propane, from a stream of natural gas includes as its primary components a pre-cooler assembly, a chiller assembly, a refrigerant compressor/condenser assembly, and separator assembly. In the pre-cooler assembly warm gas entering the apparatus is cooled by counter-current flow heat exchange with cooled natural gas exiting the apparatus. The chiller assembly of the apparatus the hydrocarbon stream is cooled in co-current flow heat exchange with a first refrigerant tube, carrying a first refrigerant which is itself cooled in co-current heat exchange with a second refrigerant tube disposed in coaxial relationship with the first refrigerant tube. Both first and second refrigerant tubes are disposed in coaxial relationship with an outer jacket conveying the gas stream through the chiller assembly. Condensed hydrocarbons are separated from the gas stream in the separator assembly.Type: GrantFiled: October 6, 2006Date of Patent: May 18, 2010Assignee: Gas-Chill, Inc.Inventors: Mark A. Brandon, Calvin Cain, Bruce Primrose
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Publication number: 20100115991Abstract: A modified purifier process, includes supplying a first stream of a feed gas containing hydrogen and nitrogen in a mol ratio of about 2:1, and also containing methane and argon, then cryogenically separating the feed gas into the following: f) a second stream of synthesis gas containing hydrogen and nitrogen in a mol ratio of about 3:1, g) waste gas containing principally nitrogen, and also containing some hydrogen and all of the methane supplied in the first stream, and splitting the waste gas into: h) a third stream of hydrogen/nitrogen gas i) a fourth stream of high concentrated nitrogen j) a fifth stream of methane rich gas, to be used as fuel. The combined second and third streams typically are passed to an ammonia synthesis process.Type: ApplicationFiled: January 11, 2010Publication date: May 13, 2010Inventor: Robert R. J. Jungerhans
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Patent number: 7713497Abstract: A natural gas liquid plant includes a separator (103) that receives a cooled low pressure feed gas (4), wherein the separator (103) is coupled to an absorber (108) and a demethanizer (110). Refrigeration duty of the absorber (108) and demethanizer (110) are provided at least in part by expansion of a liquid portion of the cooled low pressure feed gas (4) and an expansion of a liquid absorber bottom product (19), wherein ethane recovery is at least 85 mol % and propane recovery is at least 99 mol %. Contemplated configurations are especially advantageous as upgrades to existing plants with low pressure feed gas where high ethane recovery is desirable.Type: GrantFiled: August 15, 2002Date of Patent: May 11, 2010Assignee: Fluor Technologies CorporationInventor: John Mak
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Publication number: 20100107685Abstract: A process and system for recovering valuable by-products (e.g., hydrogen) from refinery gas streams. For hydrogen-only recovery, the invention comprises a partial condensation step to upgrade the refinery fuel gas to a minimum of 60% hydrogen, which is further purified in a pressure swing adsorption process. When configured to recover hydrogen, methane-rich gas and raw LPG (methane depleted gas containing C2 hydrocarbons and heavier), the invention comprises two partial condensation steps where the feed is cooled in the first step to allow separation of ethane and heavier hydrocarbons, and the resulting vapor is cooled to a lower temperature in a second step for hydrogen recovery.Type: ApplicationFiled: December 5, 2007Publication date: May 6, 2010Applicant: PRAXAIR TECHNOLOGY, INC.Inventors: Ramona Manuela Dragomir, Raymond Francis Drnevich
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Patent number: 7708804Abstract: A process for separating carbon dioxide from a fluid containing carbon dioxide, NO2, and at least one of oxygen, argon, and nitrogen comprises the steps of separating at least part of the fluid into a carbon dioxide enriched stream, a carbon dioxide depleted stream comprising CO2 and at least one of oxygen, argon, and nitrogen and a NO2 enriched stream and recycling said NO2 enriched stream upstream of the separation step.Type: GrantFiled: July 11, 2007Date of Patent: May 4, 2010Assignee: L'Air Liquide, Societe Anonyme pour l'Etude Et l'Exploitation des Procedes Georges ClaudeInventors: Arthur Darde, Bao Ha, Jean-Pierre Tranier
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Patent number: 7707852Abstract: The present invention concerns a process for recovering lower carbon olefins from MTO or DTO product gas. Said process primarily comprises the product gas compressing, pre-deethanizing, demethanizing and ethylene recovering apparatus, depropanizing column, ethylene rectification column, propylene rectification column and the like. In addition, the process of the present invention needs no independent ethylene cooling system, and the ethylene recovery rate may achieve 99.5%.Type: GrantFiled: September 29, 2006Date of Patent: May 4, 2010Assignees: China Petroleum & Chemical Corporation, Sinopec Engineering IncorporationInventors: Zhenwei Wang, Zaihang Sheng, Xueliang Zhao
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Publication number: 20100071410Abstract: The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.Type: ApplicationFiled: November 3, 2009Publication date: March 25, 2010Inventors: Anna Lee Tonkovich, Wayne W. Simmons, Laura J. Silva, Dongming Qiu, Steven J. Perry, Thomas Yuschak, Thomas P. Hickey, Ravi Arora, Amanda Smith, Robert Dwayne Litt, Paul Neagle
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Publication number: 20100069686Abstract: The present invention provides methods and systems for extracting ethanol from an ethanol-water solution comprising (1) extracting ethanol from an ethanol-water solution with a first solvent comprising an esterified fatty acid, wherein the esterified fatty acid comprises a hydroxylated fatty acid component and an alcohol component such that the alcohol component is a C3-6 alcohol, such that the distribution coefficient for ethanol in the mixture of the ethanol-water solution and the first solvent is at least 0.02 favoring the transfer of ethanol from the ethanol-water solution to the first solvent, thereby extracting the ethanol from the ethanol-water solution into the first solvent, and (2) extracting the ethanol-enriched first solvent with carbon dioxide, such that the carbon dioxide is at a liquid or near supercritical phase, wherein the distribution coefficient for ethanol in a mixture of the first solvent and the carbon dioxide is at least 0.Type: ApplicationFiled: May 15, 2008Publication date: March 18, 2010Applicant: DYNASEP LLCInventors: Brian J. Waibel, Val J. Krukonis
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Publication number: 20100051876Abstract: A process and related equipment for producing ammonia synthesis gas are disclosed, wherein a raw syngas (13) is purified in a cryogenic section (CS) and a nitrogen-rich liquid stream (30) is separated from the raw syngas flow during purification and HN ratio adjustment, and wherein the pressure of said liquid stream (30) is reduced in a turbine (80) to enhance net refrigerative effect for the cryogenic section. Embodiments wherein chilling is also provided by a low-pressure or high-pressure syngas expander are also disclosed.Type: ApplicationFiled: July 29, 2009Publication date: March 4, 2010Applicant: Ammonia Casale S.A.Inventors: Ermanno Filippi, Geoffrey Frederick Skinner
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Publication number: 20100055021Abstract: The invention relates to a method for producing carbon monoxide consisting, during an adsorption step, in using N adsorbers (4A, 4B), wherein N is equal to greater than two, each of which follows, at an offset; the same period T cycle during which adsorption and regeneration phases succeed each other, in exposing, at the beginning of the adsorption phase, each adsorber to an eluting phase during which only a part of a nominal flowrate of the mixture is transferred to the adsorber until said adsorber is substantially carbon monoxide saturated while at least the second adsorber is maintained in the adsorption phase and a purified gaseous mixture is partially liquefied for producing a liquefied gaseous mixture, in storing said mixture in a capacity (7) and in transferring the liquefied gaseous mixture from the capacity to at least one column (11) for the separation thereof into a carbon monoxide rich product and, during at least one part of the adsorber eluting phases, the liquid level in the container is decreaType: ApplicationFiled: January 23, 2006Publication date: March 4, 2010Inventors: Guillaume Teixeira, Jean-Marc Peyron, Jean-François Rauch, Natacha Haik-Beraud, Jean Billy
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Patent number: 7669438Abstract: A method and apparatus are disclosed for recovering and separating anesthetic gas components from waste anesthetic gases to be purged from a healthcare facility. Prior to a condensation step, a compressor is used to increase the waste anesthetic gas pressure in order to facilitate condensation of anesthetic gas components at higher temperatures and in greater amounts than through condensation at lower pressures. Condensing the anesthetic gas components from the compressed waste anesthetic gas stream is then achieved using conventional condensation systems, which remove anesthetic gases as either liquid condensates or solid frosts. A preferred embodiment of the invention may be used with existing high-flow scavenging or reclamation systems but is more preferably used with low-flow scavenging or reclamation systems, which employ intelligent waste anesthetic gas collection units to minimize the ingress of atmospheric gas when no waste anesthetic gas is to be purged from the healthcare facility.Type: GrantFiled: May 11, 2006Date of Patent: March 2, 2010Assignee: Anesthetic Gas Reclamation, LLCInventors: James M. Berry, Steve Morris
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Publication number: 20100047150Abstract: A method and an apparatus for producing carbon dioxide by cryogenic distillation is provided.Type: ApplicationFiled: January 30, 2008Publication date: February 25, 2010Applicant: LiAir Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Alain Briglia, Arthur Darde, Natacha Haik-Beraud, Marie-Khuny Khy
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Patent number: 7666251Abstract: Method of purifying a feed stream containing carbon dioxide wherein the feed stream after having been compressed and dried is partly cooled and then used to reboil a stripping column. Thereafter, the feed stream is further cooled and expanded to a lower operational temperature of the stripping column. A carbon dioxide product stream composed of the liquid column bottoms of the stripping column is expanded at one or more pressures to generate refrigeration, then fully vaporized within the main heat exchanger and compressed by a compressor to produce a compressed carbon dioxide product. Refrigeration is recovered in the main heat exchanger from a column overhead stream extracted from the stripping column within the main heat exchanger either directly or indirectly by auxiliary processing in which carbon dioxide is further separated and optionally recycled back to the main compressor used in compressing the feed stream.Type: GrantFiled: April 3, 2006Date of Patent: February 23, 2010Assignee: Praxair Technology, Inc.Inventors: Minish Mahendra Shah, Henry Edward Howard
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Publication number: 20100024476Abstract: Carbon dioxide-containing gas such as flue gas and a carbon dioxide-rich stream are compressed and the combined streams are then treated to desorb moisture onto adsorbent beds and then subjected to subambient-temperature processing to produce a carbon dioxide product stream and a vent stream. The vent stream is treated to produce a carbon dioxide-depleted stream which can be used to desorb moisture from the beds, and a carbon dioxide-rich stream which is combined with the carbon dioxide-containing gas.Type: ApplicationFiled: July 23, 2009Publication date: February 4, 2010Inventor: Minish Mahendra Shah
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Publication number: 20100024471Abstract: A method for removal of CO2 from a gas stream by anti-sublimation, comprising the steps of: a) introducing a gas stream containing CO2 into a frosting vessel; b) reducing the temperature of at least a portion of the gas stream in said frosting vessel to a temperature at which solid CO2 is deposited by anti-sublimation; c) discharging the gas stream depleted of CO2 from the frosting vessel; and d) recovering the deposited solid CO2; wherein the pressure of the gas stream in step b) is higher than atmospheric pressure. An anti-sublimation system for removal of CO2 from a gas stream, comprising: a frosting vessel configured to receive the gas stream, said frosting vessel comprising a low temperature refrigeration device configured for reducing the temperature of at least a portion of a gas stream in said frosting vessel to a temperature at which solid CO2 is deposited by anti-sublimation; and a compressor configured to increase the gas pressure of the gas stream which is fed to the frosting vessel.Type: ApplicationFiled: July 15, 2009Publication date: February 4, 2010Applicant: ALSTOM Technology LtdInventors: Wolfgang Georg Hees, Charles Malcom Monroe
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Publication number: 20100024472Abstract: A process is described for removing contaminants from a natural gas feed stream including water. The process includes the steps of cooling the natural gas feed stream in a first vessel to a first operating temperature at which hydrates are formed, heating the hydrates to a temperature that is above the first operating temperature by introducing a warm liquid to the first vessel so as to melt the hydrates and liberate a dehydrated gas and a water-containing liquid, and removing from the first vessel a stream of dehydrated gas.Type: ApplicationFiled: October 8, 2009Publication date: February 4, 2010Applicant: WOODSIDE ENERGY LIMITEDInventors: Robert Amin, Casper Krijno Groothuis
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Publication number: 20100018248Abstract: A cryogenic distillation tower is provided for the separation of a fluid stream containing at least methane and carbon dioxide. The cryogenic distillation tower has a lower stripping section, an upper rectification section, and an intermediate spray section. The intermediate spray section includes a plurality of spray nozzles that inject a liquid freeze zone stream. The nozzles are configured such that substantial liquid coverage is provided across the inner diameter of the intermediate spray section. The liquid freeze zone stream generally includes methane at a temperature and pressure whereby both solid carbon dioxide particles and a methane-enriched vapor stream are formed. The tower may further include one or more baffles below the nozzles to create frictional resistance to the gravitational flow of the liquid freeze zone stream. This aids in the breakout and recovery of methane gas. Additional internal components are provided to improve heat transfer and to facilitate the breakout of methane gas.Type: ApplicationFiled: October 20, 2007Publication date: January 28, 2010Inventors: Eleanor R Fieler, Edward J. Grave, Paul Scott Northrop, Norman K. Yeh
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Patent number: 7644594Abstract: A method and apparatus are disclosed for recovering and separating anesthetic gas components from waste anesthetic gases to be purged from a healthcare facility. With minimal reliance on the utility infrastructure and supplies of a healthcare facility, the method and apparatus needs only electrical or mechanical power, a source of waste anesthetic gases, and an atmospheric vent in order to operate. A heat exchanger/condenser, which uses a dedicated heat transfer fluid as a refrigerant, is employed to condense anesthetic gas components from the waste anesthetic gases as either liquid condensates or solid frosts. The warmed heat transfer fluid is cooled in a separate refrigeration unit and recycled back to the heat exchanger/condenser. A preferred embodiment of the invention is a self-contained, packaged unit which can be easily accommodated in a physician's office, small animal clinic, dental office or other healthcare facility requiring effective waste anesthetic gas management.Type: GrantFiled: May 11, 2006Date of Patent: January 12, 2010Assignee: Anesthetic Gas Reclamation, L.L.C.Inventors: James M. Berry, Steve Morris
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Patent number: 7644595Abstract: A pressure differential of a feed gas (110) between a compressor (120) and expander (160) is employed to cool the feed gas to condense and remove at least a portion of one component to produce a partially depleted feed gas from which another component may then be removed. In especially preferred aspects, the feed gas comprises C2-C5 hydrocarbons and hydrogen, wherein the hydrocarbons are condensed in the cooler and hydrogen is removed using a pressure swing adsorption unit (180).Type: GrantFiled: December 17, 2002Date of Patent: January 12, 2010Assignee: Fluor Technologies CorporationInventor: Satish Reddy
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Publication number: 20090320519Abstract: A mixture of air and one or more halogenated alkanes is directed to a gas separation membrane where it is separated into an oxygen, nitrogen, and moisture-enriched and halogenated alkane-depleted permeate and a halogenated alkane-enriched and oxygen, nitrogen, and moisture-depleted retentate. The retentate is directed to a cryogenic condenser where an amount of halogenated alkane is condensed therein.Type: ApplicationFiled: June 30, 2008Publication date: December 31, 2009Applicant: American Air Liquide, Inc.Inventors: Sarang Gadre, Shawn Bratt, Edgar S. Sanders, JR.
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Publication number: 20090308100Abstract: An apparatus for stripping and strengthening and subsequent condensing and final strengthening of an easily vaporizable component of a preferably aqueous mixture permits the heat necessary for stripping and strengthening to be transferred through a common heat transmission body (3), where the heat is derived from condensing the vapour generated by stripping and strengthening, which vapour via compression using a heat pump (26) has obtained the increase in boiling point necessary for condensation. The apparatus is comprised of two sections, namely a stripping and strengthening section or first section (1) and a condensing and final strengthening section or second section (2), said sections being joined around a common heat transmission body (3) forming a dividing wall, each section being further defined by a horizontal partially cylindrical housing (13) and an end wall at each end.Type: ApplicationFiled: April 28, 2006Publication date: December 17, 2009Inventor: Erik Jensen
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Patent number: 7628034Abstract: A method and system for removal of nitrous oxide and volatile halocarbon gas components from waste anesthetic gases using a low-flow scavenging or reclamation system preferably including an intelligent waste anesthetic gas collection unit fluidly coupled between each individual anesthetic machine and the waste gas evacuation manifold. Through a system including a collection chamber, a pressure detector, and a exhaust valve which is actuated based on the detected pressure in the collection chamber, the waste anesthetic gas collection unit allows flow to the waste suction manifold only in the presence of waste gas and interrupts all flow into the suction manifold when no waste gas is present.Type: GrantFiled: November 4, 2005Date of Patent: December 8, 2009Assignee: Anesthetic Gas Reclamation, LLCInventors: James M. Berry, Steve Morris
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Patent number: 7617701Abstract: In a process for producing a mixture containing at least 10% carbon monoxide (73) by cryogenic separation of a feed gas containing at least carbon monoxide, hydrogen and methane, the feed gas (1) is separated to produce a first gas enriched in hydrogen (71), the feed gas is scrubbed in a methane wash column (7), a carbon monoxide enriched stream (13) from the bottom of the methane wash column is separated (19) to produce a stream further enriched in carbon monoxide (23), the stream further enriched in carbon monoxide is separated to form a carbon monoxide rich stream (31,49) and a liquid methane stream (27), at least part (72) of the carbon monoxide rich stream is mixed with the first gas enriched in hydrogen to form the mixture containing at least 10% carbon monoxide as a product stream.Type: GrantFiled: April 7, 2004Date of Patent: November 17, 2009Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean Billy, Natacha Haik-Beraud, Jean Gallarda, Franck Wegrzyn
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Patent number: 7610775Abstract: The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.Type: GrantFiled: July 8, 2005Date of Patent: November 3, 2009Assignee: Velocys, Inc.Inventors: Anna Lee Tonkovich, Wayne W. Simmons, Laura J. Silva, Dongming Qiu, Steven T. Perry, Thomas Yuschak, Thomas P. Hickey, Ravi Arora, Amanda Smith, Robert Dwayne Litt, Paul Neagle
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Publication number: 20090266107Abstract: The present invention relates to methods and apparatuses for the operation of a distillation tower containing a controlled freezing zone and at least one distillation section. The process and tower design are utilized for the additional recovery of hydrocarbons from an acid gas. In this process, a separation process is utilized in which a multi-component feedstream is introduced into an apparatus that operates under solids forming conditions for at least one of the feedstream components. The freezable component, although typically CO2, H2S, or another acid gas, can be any component that has the potential for forming solids in the separation system. A dividing wall is added to at least a portion of the lower distillation section of the apparatus to effect the separation of at least some fraction of the hydrocarbons in that portion of the tower.Type: ApplicationFiled: November 20, 2007Publication date: October 29, 2009Inventors: Vikram Singh, Edward J. Grave, Paul Scott Northrop, Narasimhan Sundaram
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Publication number: 20090255273Abstract: The invention relates to a method and to a device for condensing CO2 or CO2 separation. According to the invention the thermoacoustic effect is used, with the aid of waste heat from a power station, to produce power for a compressor for compressing a working medium, in particular for compressing a CO2-containing flue gas, and/or for cooling the working medium.Type: ApplicationFiled: April 2, 2009Publication date: October 15, 2009Inventors: Vladimir Danov, Bernd Gromoll
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Patent number: 7596965Abstract: A method and system for the fractionation and removal of nitrous oxide and other volatile halocarbon gas components from waste anesthetic gases using liquid oxygen are disclosed. Liquid oxygen is warmed for use in a healthcare facility by cooling and condensing waste anesthetic gases. A cold trap/fractionator is provided wherein selective components of the waste anesthetic gas are collected as a frost on the coils of the cold trap/fractionator by desublimation/deposition and/or condensation/solidification. In a periodic batch process, the collected frost is first thawed and the melted liquids or gases are then collected at various increasing temperatures, thereby separating the nitrous oxide and other halocarbon gas components by their varying melting points. The thawed anesthetic components are collected in separate tanks based on their melting points. Warmed by the waste anesthetic gases in the cold trap/fractionator, the oxygen is supplied to the healthcare facility for its normal uses.Type: GrantFiled: May 11, 2006Date of Patent: October 6, 2009Assignee: Anesthetic Gas Reclamation, LLCInventors: James M. Berry, Steve Morris
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Patent number: 7584629Abstract: The invention relates to a process for the partial or complete separation of a mixture comprising hydrogen chloride and phosgene, possibly solvents and possibly low boilers and inerts as are typically obtained in the preparation of isocyanates by reaction of amines with phosgene, which comprises firstly carrying out a partial or complete condensation of phosgene, then a distillation or stripping step in a column to remove the hydrogen chloride from the bottom product phosgene and subsequently a scrub of the top product hydrogen chloride by means of the process solvent to absorb the phosgene in the process solvent. An after-purification by means of adsorption on activated carbon or by another suitable method can subsequently be carried out to remove solvent residues.Type: GrantFiled: December 13, 2003Date of Patent: September 8, 2009Assignee: BASF AktiengesellschaftInventors: Martin Sohn, Eckhard Stroefer, Filip Nevejans, Ulrich Penzel, Hans-Juergen Pallasch, Peter Van Den Abeel, Filip Deberdt, Jan D. Jacobs, Wolfgang Mackenroth
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Publication number: 20090211295Abstract: Heat exchange assembly comprising at least one first and one second heat exchange body (5, 7), each body being of the plate heat exchanger type, comprising a plurality of metal plates of substantially similar contour extending along a first dimension or length and a second dimension or width, spaced from and arranged in parallel rows to one another along a third dimension or thickness and sealing means bounding flattened passages with the said plates, forming at least one passage of a first type and at least one passage of a second type, the sealing means allocated to each passage releasing one fluid inlet and one fluid outlet, characterized in that one side bounded by a width and a thickness of at least one first heat exchange body is located at least partially opposite a side bounded by a width and a thickness of at least one second heat exchange body, the two sides being separated by insulating material (I).Type: ApplicationFiled: December 23, 2005Publication date: August 27, 2009Inventors: Patrice Cavagne, Alain Guillard, Patrick Le Bot, Daniel Gourdain, Marc Wagner, Frederic Judas, Jean-Marc Peyron, Bernard Saulnier, David Averous, Isabelle Naude, Ivan Lewon
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Publication number: 20090188278Abstract: The invention relates to cryogenic engineering, in particular to purifying krypton-xenon mixture and is usable in the chemical and oil-and-gas industries. The inventive method comprises purifying and separating the mixture in rectification columns, wherein coolant is removed and returned to a cooling cycle, additionally removing radionuclides from krypton and xenon fractions and from krypton and xenon production flows by means of filtration and/or adsorption and/or rectification and/or absorption and/or chemical and/or physicochemical methods in apparatuses for additional removing radionuclides. Balloons for reception of the separated products are certified with respect to radionuclides content and/or activity prior to and after the filling thereof.Type: ApplicationFiled: December 26, 2006Publication date: July 30, 2009Inventor: Mikhail Jurievich Savinov
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Patent number: 7555917Abstract: High boiling contaminants such as chloro-aromatic compounds are removed from a gas by compressing the gas containing the contaminant, cooling the compressed gas to reduce the temperature of the gas to at least 20° C. above the outlet temperature of a second cooling stage but above the freezing point of the highest melting compound in the first cooling stage, further cooling the gas in a second cooling stage to at least ?20° C., returning cooled gas from the second cooling stage to the first cooling stage, and recovering condensate streams which contain the contaminant compound from the first and second cooling stages. An apparatus suitable for carrying out this process is also disclosed. The process of the present invention is particularly useful for removing chloro-aromatic compounds from anhydrous hydrogen chloride gas.Type: GrantFiled: February 26, 2004Date of Patent: July 7, 2009Assignees: Bayer MaterialScience LLC, Bayer MaterialScience AGInventors: Bill L. Brady, Jr., Guenther Weymans, Berthold Keggenhoff, Friedhelm Steffens
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Publication number: 20090145167Abstract: Methods, apparatuses and systems for processing fluid streams having multiple constituents are provided including embodiments utilizing ascending temperature separation processes as well as combined ascending and descending temperature separation processes. For example, in one embodiment, a mixed gas stream may be processed by flowing the stream through multiple heat exchangers, expanding the stream, and then separating the stream into a liquid portion and a vapor portion. The vapor portion, having an increased or decreased concentration of an identified constituent may then pass through the heat exchangers again in reverse order and collected. The liquid portion may then be subjected to further, sequential separation acts which each take place at increasing temperatures. In another embodiment, numerous, sequential separation acts take place in, for example, at decreasing temperatures and, subsequently, at increasing temperatures.Type: ApplicationFiled: December 6, 2007Publication date: June 11, 2009Applicant: Battelle Energy Alliance, LLCInventors: Terry D. Turner, Bruce M. Wilding, Dennis N. Bingham, Michael G. McKellar, Kerry M. Klingler
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Publication number: 20090133437Abstract: A novel process is disclosed which produces a CO-rich stream from a stream containing hydrogen, carbon monoxide, methane, and components heavier than methane. The process utilizes a combined CO purification and demethanizer column (5) which reduces the overall capital cost of the process, and efficient heat integration which reduces the energy required by the process. This process is useful in recovering a CO-rich stream (10) from the effluent (1) of an autothermal cracking reactor. It is particularly useful when one or more of the heavy components (6) has a higher value as pure product than when admixed with methane (11), and when product of a purified hydrogen stream (8) is also desirable.Type: ApplicationFiled: July 28, 2005Publication date: May 28, 2009Inventors: Rian Reyneke, Michael J. Foral
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Patent number: 7510596Abstract: A thermal processor includes an oven for thermally developing an imaging media which produces gaseous contaminants during development. The gaseous contaminants includes odorous portions and condensable portions which have a condensation temperature. A contaminant removal cartridge has a housing configured to couple to the oven, a heat exchanger, and a filter module. The heat exchanger receives from the oven at least a first air flow at a first temperature, wherein the first temperature is above the condensation temperature, and including gaseous contaminants. The heat exchanger cools the first air flow to a desired filtering temperature, which is below the condensation temperature, to condense and collect the condensable portion of the gaseous contaminants and form a filtering air flow. The filter module receives the filtering air flow, to collect the remaining condensed contaminants, and to absorb the odorous portion of the gaseous contaminants to form an exhaust air flow.Type: GrantFiled: December 22, 2005Date of Patent: March 31, 2009Assignee: Carestream Health, Inc.Inventors: Kent R. Struble, David J. McDaniel, John M. Nutter
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Patent number: 7493779Abstract: The invention provides a method of removing solid carbon dioxide from cryogenic equipment, including the steps of: (a) introducing a stream including ethane to the cryogenic equipment to convert solid carbon dioxide to liquid form whereby a mixture of liquid ethane and liquid carbon dioxide is formed; and (b) removing the mixture of liquid ethane and liquid carbon dioxide from the cryogenic equipment. In particular, the method can be used in a liquefied natural gas (LNG) plant wherein cryogenic equipment contains LNG, and the method includes the steps of: (a?) removing the LNG from the cryogenic equipment; (a) introducing a stream including ethane to convert solid carbon dioxide to liquid form whereby a mixture of liquid ethane and liquid carbon dioxide is formed; and (b) removing the mixture of liquid ethane and liquid carbon dioxide from the cryogenic equipment. The result is an effective cleaning method for fouled LNG equipment.Type: GrantFiled: August 27, 2003Date of Patent: February 24, 2009Assignee: Shell Oil CompanyInventor: Robert Amin
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Publication number: 20090041654Abstract: A system and method are provided for recovering a re-usable grade of sulphur hexafluoride (SF6) from a potentially contaminated gas source. The system includes extraction vessels connected to the potentially contaminated gas source. A first cryogenic means reduces the temperature of the extraction vessel to a temperature below the phase transition of SF6 causing a pressure differential which causes the potentially contaminated gas to enter the extraction vessels. The SF6 turns to liquid and/or solid form in the extraction vessel. Non-condensed contaminant gas is evacuated from the extraction vessels. Recovery vessels are connected to the extraction vessel. A second cryogenic means is used to reduce the temperature of the recovery vessels. Raising the temperature of the extraction vessels creates a pressure differential which causes a re-usable grade of SF6 to enter the recovery vessels.Type: ApplicationFiled: May 16, 2005Publication date: February 12, 2009Applicant: GOLDEN TRIANGLE ENTERPRISES PTY LTDInventor: Anthony Stokes
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Patent number: 7481074Abstract: A process and apparatus for the on-site delivery of a gas having improved purity to from a container filled with liquid under pressure and integrated with a purifier. In the process a portion of the liquid is converted to vapor by reducing the pressure in the container and expanding the thus formed vapor through a pressure reducer generating refrigeration. The cooled vapor is warmed against incoming vapor prior to exit from the purifier.Type: GrantFiled: March 1, 2006Date of Patent: January 27, 2009Assignee: Air Products and Chemicals, Inc.Inventors: John Frederick Cirucci, Derek Miller, Paul David Kottler
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Publication number: 20090013717Abstract: A process for separating carbon dioxide from a carbon dioxide containing fluid comprises the steps of: compressing the fluid in a compressor to form a compressed fluid, drying at least part of the compressed fluid to form a compressed and dried fluid, cooling at least part of the compressed and dried fluid to form a compressed, dried and cooled fluid, separating the compressed, dried and cooled fluid at a temperature lower than 0° C. into a carbon dioxide rich stream, a carbon dioxide lean stream and at least one intermediate purity liquid stream having a carbon dioxide purity lower than that of the carbon dioxide rich stream and higher than that of the carbon dioxide lean stream, expanding at least one intermediate purity liquid stream to produce at least one expanded stream using at least one expanded stream to cool the compressed and dried fluid and recycling at least part of the expanded stream.Type: ApplicationFiled: July 11, 2007Publication date: January 15, 2009Applicants: L'Air Liquide, Societe Anonyme our l'Etude et l'Exploitation des Procedes George Claude, Air Liquide Process & Construction, Inc.Inventors: Arthur DARDE, Bao Ha, Jean-Pierre Trainer