Nonmetal Is Boron(b) Or Nitrogen(n) Patents (Class 75/238)
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Patent number: 12172227Abstract: A method of manufacturing an article is described. At S102, the method comprises obtaining a first layer having a first face and a reverse second face, wherein the first layer comprises and/or is a first metal and wherein the first metal is a heat treatable first aluminium alloy. At S104, the method comprises providing a second layer on the first face of the first layer by cold spraying particles comprising a second metal thereupon, wherein the second metal is a second aluminium alloy. At S106, the method comprises depositing a third layer on the second layer by additive friction stir deposition using a third metal, wherein the third metal is a third aluminium alloy.Type: GrantFiled: November 25, 2022Date of Patent: December 24, 2024Assignee: BAE Systems plcInventor: Howard James Price
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Patent number: 12109625Abstract: A surface-coated TiN-based cermet cutting tool is a surface-coated TiN-based cermet cutting tool, in which a TiN-based cermet containing a TiN phase as a hard phase component is used as a body, and a hard coating layer including a titanium carbonitride layer and an aluminum oxide layer is formed on a surface, in which a linear expansion coefficient of the TiN-based cermet is set to 9.0×10?6 (/K) or more, a thermal conductivity is set to 30 (W/m·K) or more, and a residual compressive stress of the hard coating layer is set to 600 to 2,000 MPa, and particularly 600 to 2,000 MPa even in an as-deposited state by adjusting component composition and the like of the TiN-based cermet.Type: GrantFiled: September 25, 2019Date of Patent: October 8, 2024Assignee: MITSUBISHI MATERIALS CORPORATIONInventors: Makoto Igarashi, Kazutaka Fujiwara
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Patent number: 12098447Abstract: A rock drill insert made of cemented carbide includes hard constituents of tungsten carbide (WC) in a binder phase of Ni—Cr, or Ni—Co—Cr, and a balance of WC and unavoidable impurities. The cemented carbide has a 3.5-18 wt % binder phase. The binder phase has >0 wt % Ni. The mass ratio Cr/(Ni+Co) is 0.02-0.19. A difference between the hardness at 0.3 mm depth at some point of the surface of the rock drill insert and the minimum hardness of the bulk of the rock drill insert is at least 30 HV3.Type: GrantFiled: March 22, 2019Date of Patent: September 24, 2024Assignee: Sandvik Mining and Construction Tools ABInventors: Mirjam Lilja, Jose Maria Tarrago Cifre, Ida Borgh, Malin Martensson, Ioannis Arvanitidis, Krystof Turba
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Patent number: 12000027Abstract: Methods and compositions are provided for improving metal dusting corrosion, abrasion resistance and/or erosion resistance for various materials, preferably for applications relating to high-temperature reactors, including dense fluidized bed reactor components. In particular, cermets comprising (a) at least one ceramic phase selected from the group consisting of metal carbides, metal nitrides, metal borides, metal oxides, metal carbonitrides, and mixtures of thereof and (b) at least one metal alloy binder phase are provided. Ceramic phase materials include chromium carbide (Cr23C6). Metal alloy binder phase materials include ?-NiAl intermetallic alloys and Ni3Sn2 intermetallic alloys, as well as alloys that contain ?-Cr and/or ??-Ni3Al hard phases. Preferably, bimetallic materials are provided when the cermet compositions are applied using a laser, e.g.Type: GrantFiled: October 29, 2020Date of Patent: June 4, 2024Assignee: ExxonMobil Chemical Patents Inc.Inventors: Changmin Chun, Ning Ma, Jorge J. Perdomo, John S. Coleman, Larry L. Iaccino
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Patent number: 11965227Abstract: The invention belongs to the technical field of metal ceramics, in particular to a metal ceramic and a preparation method thereof. The hard phase is formed by at least four kinds of crystal grains with different compositions and shapes; and in the scanning electron microscope photograph of the metal ceramic, it can be observed the first hard phase comprising black titanium nitrocarbide, a thin ring and a thick ring wherein the core phase is pure black; the second hard phase in the form of a dark gray core-ring structure particles; the third hard phase in the form of a high-brightness white core-gray ring; and the fourth hard phase in the form of a homogenous gray phase and off-white core-gray ring structure particles. In addition, a white binder phase can also be observed, and the binder phase is at least one of cobalt and nickel.Type: GrantFiled: October 17, 2023Date of Patent: April 23, 2024Assignee: CHONGYI ZHANGYUAN TUNGSTEN CO., LTD.Inventors: Zhiqiang Zhong, Lei Yin, Yan Xue, Zhuopeng Tan, Bangming Chen, Yanyuan Tang, Guozuan Xu
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Patent number: 11939646Abstract: Disclosed herein are embodiments of nickel-based alloys. The nickel-based alloys can be used as feedstock for PTA and laser cladding hardfacing processes, and can be manufactured into cored wires used to form hardfacing layers. The nickel-based alloys can have high corrosion resistance and large numbers of hard phases such as isolated hypereutectic hard phases.Type: GrantFiled: October 25, 2019Date of Patent: March 26, 2024Assignee: OERLIKON METCO (US) INC.Inventors: James Vecchio, Justin Lee Cheney, Jonathon Bracci, Petr Fiala
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Patent number: 11865809Abstract: Disclosed herein is a method of forming a multi-layered metallic part. The method comprises stacking at least two metallic layers, each made of a metallic material having a ductility, to form a multi-layered metallic assembly. The method also comprises interposing a diffusion-bond preventing element directly between adjacent ones of the at least two metallic layers of the multi-layered metallic assembly. The method further comprises diffusion bonding the at least two metallic layers to each other at locations other than a location contiguous with the diffusion-bond preventing element to produce a multi-layered metallic part having a non-bonded region between the at least two metallic layers at the location of the diffusion-bond preventing element.Type: GrantFiled: August 22, 2019Date of Patent: January 9, 2024Assignee: The Boeing CompanyInventors: Marc R. Matsen, Mark A. Negley, Landon K. Henson, John R. Hull
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Patent number: 11530467Abstract: Cemented carbide contains a first hard phase and a binder phase. The first hard phase is composed of tungsten carbide particles. The binder phase is composed of cobalt, nickel, iron, and copper as constituent elements. An average content of each of the constituent elements is not lower than 10 atomic % and not higher than 30 atomic %. Cemented carbide contains no second hard phase, or a content of the second hard phase is equal to or lower than 2 mass % of a total amount of cemented carbide. The second hard phase is composed of a compound containing at least one type of a metal element selected from the group consisting of a group-IV element, a group-V element, and a group-VI element in a periodic table except for tungsten and at least one type of an element selected from the group consisting of carbon, nitrogen, and oxygen.Type: GrantFiled: December 23, 2020Date of Patent: December 20, 2022Assignee: SUMITOMO ELECTRIC HARDMETAL CORP.Inventors: Takato Yamanishi, Shinya Imamura
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Patent number: 11311946Abstract: A coated tool of the present disclosure may include a base and a coating layer covering at least a part of the base. The base may include a hard phase of a carbonitride including Ti and a binder phase including at least one of Co and Ni and has a thermal expansion coefficient at 25 to 1000° C. of 9.0×10?6/° C. or more. The coating layer may include a TiCN layer and an Al2O3 layer positioned on the TiCN layer. The TiCN layer may have a compressive stress of 250 to 500 MPa. The Al2O3 layer may have a thickness of 2 ?m or more and a compressive stress of 450 MPa or more, and the value of the compressive stress is greater than the compressive stress of the TiCN layer.Type: GrantFiled: March 15, 2019Date of Patent: April 26, 2022Assignee: KYOCERA CorporationInventors: Ayano Tanaka, Ryoma Nomiyama
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Patent number: 11117206Abstract: A heterogeneous composite consisting of near-nano ceramic clusters dispersed within a ductile matrix. The composite is formed through the high temperature compaction of a starting powder consisting of a core of ceramic nanoparticles held together with metallic binder. This core is clad with a ductile metal such that when the final powder is consolidated, the ductile metal forms a tough, near-zero contiguity matrix. The material is consolidated using any means that will maintain its heterogeneous structure.Type: GrantFiled: November 16, 2017Date of Patent: September 14, 2021Assignee: Powdermet, Inc.Inventors: Mark Grogan, Brian Doud, Andrew Sherman
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Patent number: 11072841Abstract: A high-strength dual-scale structure titanium alloy, a preparation method therefor, and an application thereof, belonging to the technical field of alloy processing. The composition system of the titanium alloy is Ti—Nb—Cu—Co—Al, the atomic percentage of the various elements being 58˜70% Ti, 9˜16% Nb, 4˜9% Cu, 4˜9% Co, and 2˜8% Al. The microstructure comprises a dual-scale coexistence of micro-crystal isometric bcc ?-Ti and ultra-fine crystal isometric bcc ?-Ti, and a dual-scale coexistence of micro-crystal strip fcc CoTi2 and ultra-fine crystal isometric fcc CoTi2, or an ultra-fine crystal strip fcc CoTi2 twin crystal is distributed along a boundary of a dual-scale substrate, the dual-scale substrate being a nano needle-shaped martensite a? phase dispersed within micro-crystal bcc ?-Ti. The mechanical properties of the titanium alloy are significantly improved, and the titanium alloy may be used in fields such as aerospace and aviation, weaponry and sports equipment.Type: GrantFiled: December 20, 2016Date of Patent: July 27, 2021Assignee: SOUTH CHINA UNIVERSITY OF TECHNOLOGYInventors: Chao Yang, Yaguang Yao, Shengguan Qu, Xiaoqiang Li, Weiwen Zhang, Yuanyuan Li
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Patent number: 11066937Abstract: An integrally bladed rotor, including: a plurality of blades integrally formed with a hub as a single component, each of the plurality of blades having a blade body extending from the hub to an opposed blade tip surface along a longitudinal axis, wherein the blade body defines a pressure side and a suction side, and wherein the blade body includes a cutting edge defined between the blade tip surface of the blade body and the pressure side of the blade body, wherein the cutting edge is configured to abrade a seal section of an engine case.Type: GrantFiled: March 20, 2020Date of Patent: July 20, 2021Assignee: RAYTHEON TECHNOLOGIES CORPORATIONInventors: Changsheng Guo, Christopher W. Strock
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Patent number: 10773307Abstract: A composite sintered body cutting tool, in which tungsten is reduced, is made of a TiCN-based cermet and WC-based cemented carbide. The cutting tool has an angle of less than 90 degrees formed by a rake face and a flank face. The rake face including a cutting edge contains WC-based cemented carbide including 4% to 17% by mass of iron group metal components with a remainder being WC. The thickness of the carbide is 0.05 to 0.3 times the thickness of the composite sintered body. The TiCN-based cermet which is a base body of the cutting tool includes 4% to 25% of the iron group metal components, less than 15% of W, 2% to 15% of Mo, 2% to 10% of Nb, and 0.2% to 2% of Cr. The cermet may contain iron group metal Co and Ni, where, Co/Co+Ni is 0.5 to 0.8.Type: GrantFiled: September 18, 2015Date of Patent: September 15, 2020Assignee: MITSUBISHI MATERIALS CORPORATIONInventors: Makoto Igarashi, Akihiro Murakami
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Patent number: 10570486Abstract: A cermet (1) includes a bonding phase (2) and a hard phase (4). The hard phase (4) includes: a first hard phase (5) composed of TiCN; and a second hard phase (6) composed of a composite carbonitride of Ti, which is greater than the average particle diameter of the first hard phase (5). The cermet (1) further includes an aggregate part (10) formed by interlinking parts of the second hard phase (6). The second hard phase (6) forming the aggregate part (10) includes a 2a-th hard phase (7) having a maximum W content of an inner part thereof that is more than 1.1 times as great as an average W content of an outer circumferential part thereof, in terms of mass ratio. The aggregate part (10) composes a proportion of from 20% to 60% of the cermet (1) in terms of surface area.Type: GrantFiled: June 19, 2014Date of Patent: February 25, 2020Assignee: KYOCERA CORPORATIONInventor: Hideyoshi Kinoshita
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Patent number: 10472704Abstract: The invention relates cold work tool steel. The steel includes the following main components (in wt. %): C 2.2-2.4, Si 0.1-0.55, Mn 0.2-0.8, Cr 4.1-5.1, Mo 3.1-4.5, V 7.2-8.5, balance optional elements, iron and impurities.Type: GrantFiled: April 10, 2015Date of Patent: November 12, 2019Assignee: UDDEHOLMS ABInventors: Thomas Hillskog, Kjell Bengtsson, Petter Damm, Annika Engström Svensson, Rikard Robertsson, Kristoffer Steiner, Amanda Forsberg, Magnus Tidesten, Pär Emanuelsson
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Patent number: 10094005Abstract: A cermet and a cutting tool are provided which have high wear resistance and high fracture resistance at a cutting edge even in a mode of cutting where the cutting edge comes to have a high temperature. A cermet 1 includes a hard phase 2 including a carbonitride of one or more kinds of metals selected from Group 4, Group 5, and Group 6 metals of the periodic table including at least Ti and a binder phase 3 containing W and at least one kind of a metal selected from Co and Ni, wherein the binder phase 3 includes a first binder phase 4 in which a mass ratio of W to a total amount of Co and Ni (W/(Co+Ni)) is 0.8 or less and a second binder phase 5 in which a mass ratio of W to a total amount of Co and Ni (W/(Co+Ni)) is 1.2 or more.Type: GrantFiled: August 28, 2015Date of Patent: October 9, 2018Assignee: KYOCERA CORPORATIONInventors: Ryoma Nomiyama, Hideyoshi Kinoshita
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Patent number: 9970082Abstract: A heat-resistant alloy that satisfies physical properties such as proof stress and hardness adapted to an increase in the melting point of a welding object compared to conventional alloys is provided. The heat resistant alloy includes a first phase, as a main component, containing a Mo or W metal phase, a second phase containing a Mo—Si—B—based alloy, and a third phase containing titanium carbonitride, wherein the balance is inevitable compounds and inevitable impurities.Type: GrantFiled: December 13, 2012Date of Patent: May 15, 2018Assignee: A.L.M.T.CORP.Inventors: Shigekazu Yamazaki, Ayuri Tsuji, Masahiro Katoh, Akihiko Ikegaya
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Patent number: 9758708Abstract: An abrasive particle having an irregular surface, wherein the surface roughness of the particle is less than about 0.95. A method for producing modified abrasive particles, including providing a plurality of abrasive particles, providing a reactive coating on said particles, heating said coated particles; and recovering modified abrasive particles.Type: GrantFiled: June 1, 2016Date of Patent: September 12, 2017Assignee: DIAMOND INNOVATIONS, INCInventors: Timothy Francis Dumm, Kan-Yin Ng
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Patent number: 9399600Abstract: The present invention relates to a method of producing a sintered composite body comprising cubic boron nitride particles dispersed in a cemented carbide matrix by sintering a mixture comprising cubic boron nitride particles and a cemented carbide powder at a sintering temperature below 1350° C. without applying a pressure.Type: GrantFiled: September 23, 2011Date of Patent: July 26, 2016Assignee: SANDVIK INTELLECTUAL PROPERTY ABInventors: Jane Smith, Peter Chan, Michael Carpenter
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Patent number: 9381617Abstract: A cutting tool having a sintered compact including 30 to 80 vol. % cubic boron nitride and a binder phase, wherein the binder phase includes about 2 to about 6 vol. % ZrN, is disclosed. In more specific examples, the cutting tool has a sintered compact including 30 to 80 vol. % cubic boron nitride, between about 4 vol. % and about 15 vol. % aluminum and/or aluminum compound and/or aluminum alloy and/or combinations thereof, and a binder phase, wherein the binder phase includes TiN and about 3 to about 5 vol. % ZrN, and wherein the cubic boron nitride has a grain size of less than 20 microns. Cutting tools of the disclosed composition display improved performance, particularly at higher operating speeds, e.g., about 200 m/min or greater.Type: GrantFiled: July 1, 2011Date of Patent: July 5, 2016Assignee: Diamond Innovations, Inc.Inventor: Abds-Sami Malik
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Patent number: 9346716Abstract: A tool made of a cubic boron nitride sintered body which has a long life in a stable manner in any application of cutting and plastic working is provided. The tool made of the cubic boron nitride sintered body according to the present invention includes a cubic boron nitride sintered body at least at a tool working point and it is characterized by satisfying an Equation (I) and any one of an Equation (II) and an Equation (III) 20?X?98??(I) Y?0.6×X+3 (where 20?X<88)??(II) Y?5.8×X?455 (where 88?X?98)??(III) where a ratio of cubic boron nitride contained in the cubic boron nitride sintered body is denoted as X volume % and thermal conductivity of the cubic boron nitride sintered body is denoted as Y (W/m·K).Type: GrantFiled: October 29, 2010Date of Patent: May 24, 2016Assignee: Sumitomo Electric Hardmetal Corp.Inventors: Katsumi Okamura, Makoto Setoyama, Satoru Kukino
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Patent number: 9284230Abstract: The present invention relates to a novel process for producing ceramic materials, in particular refractory materials having a reduced relative density. In particular, the invention relates to a process for producing light, refractory materials having non-contiguous pores based on shaped and unshaped materials. These materials can be used as working lining in high-temperature applications. The process is based on the production of spherical, closed and isolated pores in the microstructure of the material. The pores having a pore diameter which can be set in a targeted manner are generated by use of polymer particles, in particular polymethacrylates, in particular polymers or copolymers prepared by means of suspension polymerization, as pore formers which can be burnt out. The polymers or copolymers are present in the form of small spheres having a defined diameter.Type: GrantFiled: August 23, 2012Date of Patent: March 15, 2016Assignee: Evonik Röhm GmbHInventors: Tadeusz Von Rymon Lipinski, Bruno Keller, Frank Beissmann, Peter Neugebauer, Ruth Kernke, Dirk Poppe
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Patent number: 9238854Abstract: Disclosed is a method of producing carbide and carbon nitride powders containing a binder, and cermet obtained from the same. The method includes preparing Ti—Ni alloy powders for Ti alloy powders and graphite, planetary-pulverizing the Ti—Ni alloy powders and the graphite, mortar-pulverizing the alloy powders and the graphite which are subject to the planetary-pulverizing, and performing heat treatment for the Ti—Ni alloy powders and the graphite that are pulverized. Cermet, which is made of the composite powders of carbide and carbon nitride/metal including both TiC which is ceramic material and Ni which is metal is provided.Type: GrantFiled: March 14, 2013Date of Patent: January 19, 2016Assignee: KOREA INSTITUTE OF GEOSCIENCE AND MINERAL RESOURCESInventors: Han-Jung Kwon, Sun-A Jung, Sung-Wook Cho, Dae-Sup Kil, Ji-Woong Kim, Ki-Min Roh, Jae-Won Lim
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Patent number: 9222153Abstract: Provided are Ti(C,N)-based cermets with Ni3Al and Ni as binder and a preparation method thereof. The Ti(C,N)-based cermets are prepared by raw materials subjected to ball-mill mixing, die forming, vacuum degreasing and vacuum sintering, wherein weight percentage of each chemical component of the raw materials is as follows: TiC 34.2˜43%, TiN 8˜15%, Mo 10˜15%, WC 5˜10%, graphite 0.8˜1.0%, Ni 20˜24%, and Ni3Al powder containing B 6˜10%. Ni powder and Ni3Al powder containing B are used as binder. The Ti(C,N)-based cermets feature in excellent corrosion resistance, oxidation resistance and mechanical properties at high temperature, has a hardness of 89.0˜91.9 HRA, a room temperature bending strength of 1600 MPa or more, and a fracture toughness of 14 MPa·m1/2 or more, and is applicable for manufacturing high-speed cutting tools, dies and heat-resisting and corrosion-resisting components.Type: GrantFiled: December 31, 2014Date of Patent: December 29, 2015Assignee: HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGYInventors: Weihao Xiong, Bin Huang, Qingqing Yang, Mingkun Chen, Zhenhua Yao, Guopeng Zhang, Xiao Chen, Shan Chen
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Publication number: 20150107411Abstract: An Fe-based magnetic material sintered compact containing BN, wherein the Fe-based magnetic material sintered compact has an oxygen content of 4000 wtppm or less. The present invention provides a sintered compact which enables the formation of a magnetic thin film in a thermally assisted magnetic recording media, and in which the generation of cracks and chipping is suppressed when the sintered compact is processed into a sputtering target or the like.Type: ApplicationFiled: August 6, 2013Publication date: April 23, 2015Inventor: Shini-ichi Ogino
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Patent number: 8992657Abstract: A lightweight material for decorative parts having a silver metallic color tone is provided. The material includes a sintered body including a main hard phase composed of a solid solution formed of titanium carbonitride and titanium carbide; a main binder phase composed of nickel; a first additive material composed of at least one selected from the group consisting of molybdenum carbide, niobium carbide, tungsten carbide, and tantalum carbide; a second additive material composed of at least one of chromium and chromium carbide; and the balance being incidental impurities. The N content in the sintered body is 2.0% to 6.0% by mass. The color tone of the sintered body satisfies L*=9 to 14, a*=?2 to 3, and b*=?6 to 0, which are values of the L*a*b* color system measured with a spectrophotometric colorimeter.Type: GrantFiled: February 23, 2012Date of Patent: March 31, 2015Assignees: Sumitomo Electric Hardmetal Corp., Sumitomo Electric Industries, Ltd.Inventors: Yoshimitsu Sawazono, Katsuya Uchino, Yoshihiro Minato
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Publication number: 20140356215Abstract: Provided is a heat-resistant alloy that satisfies physical properties such as proof stress and hardness adapted to an increase in the melting point of a welding object compared to conventional alloys. A heat-resistant alloy of this invention includes a first phase, as a main component, containing a Mo or W metal phase, a second phase containing a Mo—Si—B-based alloy, and a third phase containing titanium carbonitride, wherein the balance is inevitable compounds and inevitable impurities.Type: ApplicationFiled: December 13, 2012Publication date: December 4, 2014Applicant: A.L.M.T.CORP.Inventors: Shigekazu Yamazaki, Ayuri Tsuji, Masahiro Kato, Akihiko Ikegaya
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Patent number: 8764876Abstract: PCBN material consisting essentially of cubic boron nitride (cBN) grains and binder material, the content of the cBN grains being at least 80 weight percent of the PCBN material; the binder material comprising greater than 50 weight percent Al and a combined content of at least 5 weight percent of an iron group element and a refractory element, the iron group element selected from the group consisting of Co, Fe, Ni and Mn, and the refractory element selected from the group consisting of W, Cr, V, Mo, Ta, Ti, Hf and Zr.Type: GrantFiled: July 6, 2011Date of Patent: July 1, 2014Assignee: Element Six LimitedInventor: Stefan Magnus Olof Persson
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Publication number: 20140174255Abstract: A hard-faced article includes a wear-resistance element that has a precipitated hard phase and a non-precipitated hard phase that is different from the precipitated hard phase in composition. The precipitated hard phase and the non-precipitated hard phase are dispersed through a boron-containing metallic matrix. The precipitated hard phase includes a boride material. The wear-resistance element can include, by weight, less than 50% of the non-precipitated hard phase. The wear-resistance element can also include boron, carbon, chromium and silicon such that, by weight exclusive of the non-precipitated hard phase, a product of the amounts of boron, carbon, chromium and silicon is greater than 28 and less than 350 and the amount of chromium by weight is less than 15%. A method includes forming the wear-resistance element with the precipitated hard phase and the non-precipitated hard phase dispersed through the boron-containing metallic matrix.Type: ApplicationFiled: December 26, 2012Publication date: June 26, 2014Applicant: DEERE & COMPANYInventor: Brent A. Augustine
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Patent number: 8679220Abstract: This invention relates to a ceramic and a cermet each having a second phase for improving toughness via phase separation from a complete solid-solution phase and to a method of preparing them. The ceramic and the cermet may have the second phase phase-separated from the complete solid-solution phase, thereby easily achieving a great improvement in toughness and exhibiting other good properties including high strength, consequently enabling the manufacture of high-strength and high-toughness cutting tools, instead of conventional WC—Co hard materials.Type: GrantFiled: June 20, 2007Date of Patent: March 25, 2014Assignee: SNU R&DB FoundationInventor: Shin Hoo Kang
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Publication number: 20130303356Abstract: The present invention relates to a method of producing a sintered composite body comprising cubic boron nitride particles dispersed in a cemented carbide matrix by sintering a mixture comprising cubic boron nitride particles and a cemented carbide powder at a sintering temperature below 1350° C. without applying a pressure.Type: ApplicationFiled: September 23, 2011Publication date: November 14, 2013Applicant: SANDVIK INTELLECTUAL PROPERTY ABInventors: Jane Smith, Peter Chan, Michael Carpenter
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Patent number: 8535407Abstract: The invention relates to a hard-metal comprising at least 13 volume % of a metal carbide selected from the group consisting of TiC, VC, ZrC, NbC, MoC, HfC, TaCl WC or a combination thereof, a binder phase comprising one or more of iron-group metals or alloy thereof and 0.1 to 10 weight % Si and 0.1 to 10 weight % Cr and having a liquidus temperature at 1280 degrees C. or lower and 3 to 39 volume % of diamond or cBN grains coated with a protective coating or a mixture thereof and a process for making the hard-metal.Type: GrantFiled: September 15, 2009Date of Patent: September 17, 2013Assignee: Element Six GmbHInventors: Igor Yuri Konyashin, Bernd Heinrich Ries, Frank Friedrich Lachmann
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Publication number: 20130087019Abstract: A lightweight material for decorative parts having a silver metallic color tone is provided. The material includes a sintered body including a main hard phase composed of a solid solution formed of titanium carbonitride and titanium carbide; a main binder phase composed of nickel; a first additive material composed of at least one selected from the group consisting of molybdenum carbide, niobium carbide, tungsten carbide, and tantalum carbide; a second additive material composed of at least one of chromium and chromium carbide; and the balance being incidental impurities. The N content in the sintered body is 2.0% to 6.0% by mass. The color tone of the sintered body satisfies L*=9 to 14, a*=?2 to 3, and b*=?6 to 0, which are values of the L*a*b* color system measured with a spectrophotometric colorimeter.Type: ApplicationFiled: February 23, 2012Publication date: April 11, 2013Applicant: SUMITOMO ELECTRIC INDUSTRIES, LTD.Inventors: Yoshimitsu Sawazono, Katsuya Uchino, Yoshihiro Minato
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Publication number: 20130052075Abstract: A wear pad of a band saw guide exposed to wear from a moving band saw blade is produced in a powder metallurgical manner from a steel material having the following composition, in percent by weight: 0.01-2 C, 0.01-3.0 Si, 0.01-10.0 Mn, 16-33 Cr, max. 5 Ni, 0.01-5.0 (W+Mo/2), max. 9 Co, max. 0.5 S, 1.6-9.8 N, 7.5 to 14 of (V+Nb/2), wherein the contents of N and of (V+Nb/2) are balanced in relation to each other so that the contents of the elements are within a range I?, F?, G, H, I? in a coordinate system, where the content of N is the abscissa and the content of (V+Nb/2) is the ordinate, and where the coordinates for the points (in the format [x: (N, (V+Nb/2)]) are [I?: (1.6, 7.5)], [F?: (5.8, 7.5)], [G: (9.8, 14.0)], and [H: (2.6, 14.0)], max 7 of any of Ti, Zr, and Al; and a balance essentially only iron and unavoidable impurities.Type: ApplicationFiled: March 9, 2011Publication date: February 28, 2013Inventor: Jan Boström
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Patent number: 8318045Abstract: Disclosed is a radiation shielding member having improved radiation absorption performance, including 80.0˜99.0 wt % of a polymer matrix or metal matrix and 1.0˜20.0 wt % of a radiation shielding material in the form of nano-particles having a size of 10˜900 nm as a result of pulverization, wherein the radiation shielding material is homogeneously dispersed in the matrix through powder mixing or melt mixing after treatment with a surfactant which is the same material as the matrix or which has high affinity for the matrix. A preparation method thereof is also provided. This radiation shielding member including the nano-particles as the shielding material further increases the collision probability of the shielding material with radiation, compared to conventional shielding members including micro-particles, thus reducing the mean free path of radiation in the shielding member, thereby exhibiting superior radiation shielding effects.Type: GrantFiled: May 12, 2009Date of Patent: November 27, 2012Assignee: Korea Atomic Energy Research InstituteInventors: Jaewoo Kim, Young Rang Uhm, Byungchul Lee, Jinwoo Jung, Chang Kyu Rhee, Min-Ku Lee, Hee Min Lee, Sang Hoon Lee
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Patent number: 8303681Abstract: A mixed powder and a sintered body obtained by sintering the mixed powder. The mixed powder includes a solid-solution powder with complete solid-solution phase. The solid-solution powder includes a carbide or a carbonitride of at least two metals selected, including Ti, from metals of Groups IVa, Va and VIa of the periodic table, or a mixture thereof. A mixed cermet powder and a cermet obtained by sintering the mixed cermet powder are also disclosed. The mixed cermet powder includes at least a cermet powder with complete solid-solution phase. The cermet powder includes a carbide or a carbonitride of at least two metals selected, including Ti, from metals of Groups IVa, Va and VIa of the periodic table, or a mixture thereof, and at least one metal selected from the group consisting of Ni, Co and Fe. Also disclosed are a sintered body and a fabrication method of a cermet.Type: GrantFiled: August 8, 2007Date of Patent: November 6, 2012Assignee: Seoul National University Industry FoundationInventors: Shin-Hoo Kang, Jin-Kwan Jung, Han-Jung Kwon
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Publication number: 20120063943Abstract: Provided are a composite powder of a metal and carbide (carbonitride) for a structural material, a sintered body, and methods of preparing the composite powder and sintered body. The composite powder for a structural member has a composition of M1-x % M2C, M1-x % (M2,M1)C, M1-x % M2(CN), or M1-x % (M2,M1)(CN). A matrix-phase metal M1 is one selected from tungsten (W) and molybdenum (Mo) of the periodic table of the elements, an accessory-phase metal M2 is one selected from the group consisting of Group-IV to Group-VI metals of the periodic table of the elements and forms a carbide or carbonitride having an average particle size of about 1 ?m or less, and the matrix-phase metal M1 and the accessory-phase metal M2 coexist due to a reaction.Type: ApplicationFiled: September 28, 2009Publication date: March 15, 2012Applicant: SNU R&DB FOUNDATIONInventor: Shinhoo Kang
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Publication number: 20120003466Abstract: A cermet has a hard phase which contains W and nitrogen, and includes at least one selected from a carbide, nitride and carbonitride of a metal having Ti as a main component, and a binder phase having an iron group metal as a main component. A W amount contained in the whole cermet is 5 to 40% by weight, an interfacial phase including a complex carbonitride with a larger W amount than a W amount of the hard phase being present between grains of the hard phase, and when a W amount contained in the interfacial phase based on the whole metal element is represented by Wb (atomic %), and a W amount contained in the hard phase based on the whole metal element is represented by Wh (atomic %), then, an atomic ratio of Wb to Wh (Wb/Wh) is 1.7 or more. The cermet is excellent in fracture resistance and wear resistance.Type: ApplicationFiled: March 10, 2010Publication date: January 5, 2012Applicant: TUNGALOY CORPORATIONInventors: Keitaro Tamura, Daisuke Takesawa, Hiroki Hara, Kozo Kitamura, Yasuro Taniguchi, Koji Hayashi, Akihiro Matsumoto, Sung-Pyo Cho
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Patent number: 8007561Abstract: A cermet insert having a structure composed of a hard phase and a binding phase and, as a sintered body composition, containing Ti, Nb and/or Ta, and W in a total amount of Ti in terms of carbonitride, Nb and/or Ta in terms of carbide and W in terms of carbide of 70 to 95 wt. % of an entirety of the microstructure, and containing W in terms of carbide in an amount of 15 to 35 wt. % of the entirety of the microstructure, the sintered body composition further containing Co and/or Ni. The hard phase has one or two or more of the phases: (1) a first hard phase of a core-having structure whose core portion contains a titanium carbonitride phase and a peripheral portion containing a (Ti, W, Ta/Nb)CN phase, (2) a second hard phase of a core-having structure whose core portion and peripheral portion both contain a (Ti, W, Ta/Nb)CN phase, and (3) a third hard phase of single-phase structure including a titanium cabonitride phase.Type: GrantFiled: June 13, 2006Date of Patent: August 30, 2011Assignees: NGK Spark Plug Co., Ltd., Mitsubishi Materials CorporationInventors: Tomoaki Shindo, Atsushi Komura, Hiroaki Takashima, Toshiyuki Taniuchi, Masafumi Fukumura, Kei Takahashi
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Publication number: 20110150692Abstract: A cemented carbide body is 1-30% by mass of binder consisting of Co, Co/Ni, Co/Fe, Co/Ni/Fe or Ni/Fe and a hard material having a hexagonal WC phase and having a face-centered cubic phase of the form (M1, M2, M3)C or (M1, M2, M3)(C, N) or (M1, M2, M3)(O, C, N) where M1=Ti and/or Zr and M2=W and M3 optionally means none or one or a plurality of the elements Ta, Nb, Hf, Cr, Mo or V, wherein the proportion of the face-centered cubic phase based on the total mass is 2% to 97%, preferably 5 to 12% by mass, and the microstructure of the hexagonal phase and of the face-centered cubic phase has a mean grain size of between 0.2 ?m and 1 ?m, preferably ?0.9 ?m, and the mean grain sizes of the hexagonal phase and of the face-centered cubic phase differ at most by 30%.Type: ApplicationFiled: July 14, 2009Publication date: June 23, 2011Inventors: Klaus Rödiger, Hendrikus Van Den Berg, Walter Lengauer, Klaus Dreyer, Dominic Janisch
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Patent number: 7909905Abstract: A cermet comprises a binding phase made of a binding metal including Co and/or Ni. The binding phase is 5 to 30 mass %. The cermet further comprises a plurality of hard particles bound each other with the binding phase. The hard particles comprise core-containing structure particles having cores and shells both including TiCN. The core-containing structure particles comprise first core-containing structure particles of which shells contain the binding metal and second core-containing structure particles of which cores and shells both contain the binding metal.Type: GrantFiled: September 13, 2007Date of Patent: March 22, 2011Assignee: Kyocera CorporationInventor: Takashi Tokunaga
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Patent number: 7892315Abstract: Disclosed are a solid-solution powder, a method for preparing the solid-solution powder, a cermet powder including the solid-solution powder, a method for preparing the cermet powder, a cermet using the cermet powder and a method to prepare the cermet. According to the present invention, the problem of low toughness due to high hardness that conventional cermets (especially TiC or Ti(CN) based cermet) have is resolved because a complete solid-solution phase without core/rim structure is provided to the cermets as a microstructure thereof, and in which further increased the hardness as well as the toughness, thereby substantially and considerably increasing general mechanical properties of materials using the cermet, and thus substituting WC—Co hard material and allowing manufacturing of cutting tools with high hardness and toughness.Type: GrantFiled: January 23, 2009Date of Patent: February 22, 2011Assignee: Seoul National University Industry FoundationInventor: Shinhoo Kang
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Publication number: 20110020163Abstract: The present invention relates to a super-hard enhanced hard-metal comprising particulate hard material and a binder and at least one formation, the formation comprising a core cluster and a plurality of satellite clusters, spaced from, surrounding and smaller than the core cluster, and the core cluster and satellite clusters each comprising a plurality of contiguous super-hard particles.Type: ApplicationFiled: April 15, 2009Publication date: January 27, 2011Inventor: Roger William Nigel Nilen
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Patent number: 7799111Abstract: The invention relates to a thermal spray feedstock composition that employs free flowing agglomerates formed from (a) a ceramic component that sublimes,(b) a metallic or semi-conductor material that does not sublime and (c) a binder. The invention also relates to a method for preparing the agglomerates and a method for preparing ceramic containing composite structures from the agglomerates.Type: GrantFiled: March 28, 2005Date of Patent: September 21, 2010Assignee: Sulzer Metco Venture LLCInventors: David S. Gollob, Thomas H. Piquette, James Derby, Omar Basil Al-Sabouni, Richard Karl Schmid, Jacobus Cornelis Doesburg
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Publication number: 20100089203Abstract: A Ti-based cermet 1 includes at least one of Co and Ni, at least one of titanium carbide, titanium nitride and titanium carbonitride including at least one selected from the metal elements of groups 4, 5 and 6 of the periodic table, and Ru.Type: ApplicationFiled: February 25, 2008Publication date: April 15, 2010Applicant: KYOCERA CORPORATIONInventors: Hideyoshi Kinoshita, Takashi Tokunaga
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Patent number: 7691173Abstract: The present invention includes consolidated hard materials, methods for producing them, and industrial drilling and cutting applications for them. A consolidated hard material may be produced using hard particles such as B4C or carbides or borides of W, Ti, Mo, Nb, V, Hf, Ta, Zr, and Cr in combination with an iron-based, nickel-based, nickel and iron-based, iron and cobalt-based, aluminum-based, copper-based, magnesium-based, or titanium-based alloy for the binder material. Commercially pure elements such as aluminum, copper, magnesium, titanium, iron, or nickel may also be used for the binder material. The mixture of the hard particles and the binder material may be consolidated at a temperature below the liquidus temperature of the binder material using a technique such as rapid omnidirectional compaction (ROC), the CERACON® process, or hot isostatic pressing (HIP). After sintering, the consolidated hard material may be treated to alter its material properties.Type: GrantFiled: September 18, 2007Date of Patent: April 6, 2010Assignee: Baker Hughes IncorporatedInventors: Jimmy W. Eason, James C. Westhoff, Roy Carl Lueth
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Patent number: 7658781Abstract: Composite bodies made by a silicon metal infiltration process that feature a metal phase in addition to any residual silicon phase. Not only does this give the composite material engineer greater flexibility in designing or tailoring the physical properties of the resulting composite material, but the infiltrant also can be engineered compositionally to have much diminished amounts of expansion upon solidification, thereby enhancing net-shape-making capabilities. These and other consequences of engineering the metal component of composite bodies made by silicon infiltration permit the fabrication of large structures of complex shape. Certain liquid-based preforming techniques are particularly well suited to the task, particularly where a high volumetric loading of the reinforcement component is desired.Type: GrantFiled: July 19, 2005Date of Patent: February 9, 2010Inventors: W. Michael Waggoner, Barry R Rossing, Marlene Rossing, legal representative, Michael A Richmond, Michael K Aghajanian, Allyn L McCormick
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Patent number: 7645316Abstract: A titanium based carbonitride alloy contains Ti, Nb, W, C, N and Co. The alloy also contains, in addition to Ti, Co with only impurity levels of Ni and Fe, 4-7 at % Nb, 3-8 at % W and has a C/(C+N) ratio of 0.50-0.75. The Co content is 9-<12 at % for general finishing applications and 12-16% for semifinishing applications. The amount of undissolved Ti(C,N) cores must be kept between 26 and 37 vol % of the hard constituents, the balance being one or more complex carbonitrides containing Ti, Nb and W. The invented alloy is particularly useful for semifinishing of steel and cast iron.Type: GrantFiled: October 30, 2006Date of Patent: January 12, 2010Assignee: Sandvik Intellectual Property AktiebolagInventors: Ulf Rolander, Marco Zwinkels, Gerold Weinl
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Patent number: 7635448Abstract: A compact is obtained from a mixed powder of a multi-component system ceramics composed of constitutive elements of at least two metal elements selected from the group consisting of Ti, Al, V, Nb, Zr, Hf, Mo, Ta, Cr, and W, N, and optionally C; and Fe, Ni, Co, or an alloy composed of a constitutive element of at least one metal element of Fe, Ni, and Co. A composite material is prepared by sintering the compact.Type: GrantFiled: September 10, 2004Date of Patent: December 22, 2009Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Mitsuo Kuwabara, Masanori Ohtsuka
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Patent number: 7588621Abstract: A titanium based carbonitride alloy containing Ti, Nb, W, C, N and Co. The alloy also contains, in addition to Ti, 9-14 at % Co with only impurity levels of Ni and Fe, 1-<3 at % Nb, 3-8 at % W and has a C/(C+N) ratio of 0.50-0.75. The amount of undissolved Ti(C,N) cores should be kept between 26 and 37 vol % of the hard constituents, the balance being one or more complex carbonitrides containing Ti, Nb and W. The alloy is particularly useful for milling of steel.Type: GrantFiled: August 23, 2007Date of Patent: September 15, 2009Assignee: Sandvik Intellectual Property AktiebolagInventors: Gerold Weinl, Ulf Rolander, Marco Zwinkels