Nonmetal Is Boron(b) Or Nitrogen(n) Patents (Class 75/238)
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Patent number: 5889219Abstract: A sintered body having diamond grains dispersed and held in a matrix of cemented carbide or cermet is obtained by direct resistance heating and pressurized sintering. The sintering is performed at a liquid phase generating temperature in a short time, so that the diamond grains are not directly bonded to each other. Thus, a superhard composite member that has excellent hardness and wear resistance can be obtained without employing an ultra high-pressure vessel.Type: GrantFiled: November 12, 1996Date of Patent: March 30, 1999Assignee: Sumitomo Electric Industries, Ltd.Inventors: Hideki Moriguchi, Yoshifumi Arisawa, Michio Otsuka
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Patent number: 5882777Abstract: Super hard composite material for tools, comprising a substrate of CBN sintered body containing more than 20% by volume of cubic boron nitride (CBN), improved in strength of base material, wear-resistance, hardness at high temperatures and acid-resistance usable in cutting work of steels which are difficult to be machined. The substrate (2) has a laminated film (1) consisting of super thin films (a) and (b) each deposited alternatively on the substrate (2), the super thin film (a) being made of nitride and/or carbide of at least one element selected from a group comprising IVa group elements, Va group elements, VIa group elements, Al and B and possessing a crystal structure of cubic system and metallic bond property, the super thin film (b) being made of at least one compound possessing a crystal structure other than cubic system and covalent bond property under equilibrium condition at ambient temperature and pressure, each unit layer of the super thin films (a) and (b) having a thickness of 0.Type: GrantFiled: August 1, 1995Date of Patent: March 16, 1999Assignee: Sumitomo Electric Industries, Ltd.Inventors: Satoru Kukino, Mitsuhiro Goto, Tetsuo Nakai, Makoto Setoyama, Takashi Yoshioka
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Patent number: 5856032Abstract: A cermet including a cermet core zone in which the content of a binder amounts to at most 90% by mass in relationship to a cermet hard phase is formed with a 0.01 to 3 um deep surface layer having an increased resistance to wear compare to the cermet core zone.Type: GrantFiled: September 30, 1996Date of Patent: January 5, 1999Assignee: Widia GmbHInventors: Hans Werner Daub, Klaus Dreyer
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Patent number: 5789686Abstract: Methods for making, methods for using and articles comprising cermets, preferably cemented carbides and more preferably tungsten carbide, having at least two regions exhibiting at least one property that differs are discussed. Preferably, the cermets further exhibit a portion that is binder rich and which gradually or smoothly transitions to at least a second region. The multiple-region cermets are particularly useful in compressively loaded application wherein a tensile stress or fatigue limit might otherwise be excessive for monolithic articles. The cermets are manufactured by juxtaposing and densifying at least two powder blends having different properties (e.g., differential carbide grain size, differential carbide chemistry, differential binder content, differential binder chemistry, or any combination of the preceding).Type: GrantFiled: June 6, 1995Date of Patent: August 4, 1998Assignee: Kennametal Inc.Inventors: Ted R. Massa, John S. Van Kirk, Robert R. McNaughton, Jr.
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Patent number: 5756909Abstract: The invention relates to the filed of powder metallurgy. A steel is disclosed, which is compacted from a powder mixture by means of pressure and heat, its microstructure arising mainly from two components, the first of which being austenitic (e.g., Hadfield manganese steel) and the second being an essentially martensitic component rich in hard precipitates. The austenitic microstructure is more ductile than the martensitic, and it effectively prevents the propagation of microscopic cracking. Thus, the material is suitable for use in wear parts subjected to strong forces, as in, e.g., stone crushers.Type: GrantFiled: January 14, 1997Date of Patent: May 26, 1998Assignee: Rauma Materials Technologies, OYInventors: Jari Ilmari Liimatainen, Mikko Aimo Antero Kumpula
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Patent number: 5754935Abstract: The present invention provides a vane material having an excellent scuffing resistance in a compressor employing an alternative Freon gas as a cooling medium and a process for the preparation thereof. In accordance with the present invention, a vane material is provided having a structure comprising a base material consisting essentially of 1.0 to 4.5% by weight of carbon, not more than 1.5% by weight of silicon, not more than 1.0% by weight of manganese, 3 to 6% by weight of chromium, not more than 30% of tungsten and/or not more than 20% by weight of molybdenum provided that (W+2Mo) is not more than 45% by weight, 2 to 10% by weight of vanadium and/or niobium, not more than 20% by weight of cobalt, and a balance of iron and inavoidable impurities with additive particles of a carbide and additive particles of a nitride and/or a carbonitride, sintered thereto in an amount of more than 0% to not more than 25% by weight and 2 to 25% by weight based on the total weight of the vane material, respectively.Type: GrantFiled: June 10, 1994Date of Patent: May 19, 1998Assignee: Hitachi Metals, Ltd.Inventors: Yutaka Kubo, Hideki Nakamura, Norimasa Uchida, Keiji Yamasaki
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Patent number: 5733664Abstract: A matrix powder for formation along with an infiltrant into a matrix for use as a wear element or for use in retaining at least one discrete hard element. The matrix powder includes crushed sintered cemented tungsten carbide particles. The composition of the crushed sintered cemented tungsten carbide comprises between about 6 weight percent and about 13 weight percent binder metal and between about 87 weight percent and about 94 weight percent tungsten carbide.Type: GrantFiled: December 18, 1995Date of Patent: March 31, 1998Assignee: Kennametal Inc.Inventors: Harold E. Kelley, William E. Silvis, Charles J. Terry, Gary R. Peterson
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Patent number: 5729823Abstract: The present invention relates to a cemented carbide insert, comprising a cemented carbide substrate and a coating. The substrate contains WC and cubic carbonitride phase in a binder phase based of Co and/or Ni and has a binder phase enriched surface zone essentially free of cubic phase. The binder phase enriched surface zone prevails over the edge. As a result, an insert according to the invention has improved edge toughness and resistance against plastic deformation and is particularly useful for machining of sticky work piece materials such as stainless steel.Type: GrantFiled: March 14, 1996Date of Patent: March 17, 1998Assignee: Sandvik ABInventors: Per Gustafson, Leif kesson
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Patent number: 5723800Abstract: According to the present invention there is provided a wear resistant vane for alternate flow that is appropriate for a rotary compressor that employs HFC flow as an alternate refrigerant, and which vane possesses: a reciprocal or opposed characteristic in that it does not cause to wear a piston to which it contacts and nevertheless causes little wear to itself; a preferable corrosion resistance; and an ensured reliability, in that when employed for an operation that continues for an extended period of time there is no possibility of a surface layer suddenly peeling off.Type: GrantFiled: July 3, 1996Date of Patent: March 3, 1998Assignee: Nachi-Fujikoshi Corp.Inventors: Takashi Yoshimoto, Yasushi Hara, Hirokuni Amano, Masao Koshi
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Patent number: 5710383Abstract: A cutting tool composed of a carbonitride-type cermet having excellent wear resistance, characterized by having a microstructure comprising a homogeneous (Ti,W,Nb/Ta)CN phase, the grains of which have grown in shape of a cashew nut; and a Co--Ni alloy binder phase which is present as a dispersed phase between the grains of said homogeneous (Ti,W,Nb/Ta)CN phase. The cermet tools to be manufactured can exhibit more excellent wear resistance for a long time even in high-speed cuttings as well as ordinary cuttings as compared with the conventional cermet tools, and therefore, they can sufficiently satisfy demands for labor saving and energy saving, and further, factory automation systemizing, in relation to cutting work.Type: GrantFiled: November 26, 1996Date of Patent: January 20, 1998Inventor: Hidemitsu Takaoka
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Patent number: 5682595Abstract: The ceramic/metal composite material is comprised of a ceramic phase with particles of alumina or of a solid solution based on alumina and a refractory phase including titanium nitride and/or carbonitride and a metallic matrix based on Ni, Co, Fe. The interface between the particles of alumina or the solid solution of alumina and the metallic matrix is rich in nitrogen and in titanium or in compounds thereof.Type: GrantFiled: November 1, 1994Date of Patent: October 28, 1997Assignee: UFEC- Universal Fusion Energie Company SAInventors: Denis Gonseth, Daniele Mari, Paul Bowen, Claude Paul Carry, Pascal Streit, Roberto Mulone
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Patent number: 5682590Abstract: A titanium-based carbonitride grade for finishing and semi-finishing turning operations with excellent properties is obtained starting from a titanium-based carbonitride grade used for milling operations. The carbon content of a conventional titanium-based carbonitride grade used for milling operations is optimized in such a way that it is close to the point where .eta.-phase or other substoichiometric phases are formed. The improved titanium-based carbonitride is also provided with a thin wear resistant Ti-containing coating deposited preferably by PVD technique.Type: GrantFiled: January 23, 1996Date of Patent: October 28, 1997Assignee: Sandvik ABInventor: Gerold Weinl
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Patent number: 5679908Abstract: A high vanadium, powder metallurgy cold work tool steel article and method for production. The chromium, vanadium, and carbon plus nitrogen contents of the steel are controlled during production to achieve a desired combination of corrosion resistance and metal to metal wear resistance.Type: GrantFiled: November 8, 1995Date of Patent: October 21, 1997Assignee: Crucible Materials CorporationInventors: Kenneth Pinnow, William Stasko, John Hauser
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Patent number: 5670726Abstract: In order to improve the toughness characteristics of a cermet alloy, while retaining high resistance to wear, a composition is disclosed which contains 30 to 60% by weight of Ti, 5 to 20% by weight of W, 5 to 15% by weight of Ta, in which up to 70% of the Ta can be replaced by Nb, and 5 to 25% by weight of Ni and/or Co binder with more than 80 mole %, relative to the above transition elements of carbon and nitrogen. The composition is prepared by grinding, compressing and sintering a solid, powder-form mixture containing (Ti,W,Ta,Nb)C powder, Ti(C,N) powder, and WC powder, each powder having a particle size <1.5 .mu.m, plus Ni powder and/or Co powder. The mixture includes the following ingredients: (a) (Ti,W,Ta,Nb)C with a mean particle size <1.5 .mu.m, this mixed carbide containing 20 to 50% by weight of TiC, 20 to 40% by weight of WC, and 20 to 40% by weight of (Ta, Nb)C; (b) Ti(C,N), with a mean particle size <1.5 .mu.m and an N/(C+N) ratio <0.7; WC with a mean particle size <1.5 .mu.Type: GrantFiled: September 1, 1995Date of Patent: September 23, 1997Assignee: Widia GmbHInventors: Hans Kolaska, Klaus Dreyer
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Patent number: 5656787Abstract: A process of forming a sintered article for powder metal comprising blending carbon and ferro alloys and lubricant with compressible elemental iron powder, pressing said blended mixture to form sintering said article, and then high temperature sintering said article in a reducing atmosphere to produce a sintered article having a high density from a single compression.Type: GrantFiled: November 21, 1995Date of Patent: August 12, 1997Assignee: Stackpole LimitedInventors: Rohith Shivanath, Peter Jones, Danny Thien Duc Thieu
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Patent number: 5624475Abstract: A composite material comprising a pure copper or dispersion strengthened copper matrix and a boron rich species, such as, but not limited to, elemental boron or boron carbide, for use in the fabrication of baskets that support spent nuclear fuel in nuclear waste containers. A method for manufacturing the composite material using powder metallurgy and hot extrusion.Type: GrantFiled: December 2, 1994Date of Patent: April 29, 1997Assignee: SCM Metal Products, Inc.Inventors: Anil V. Nadkarni, Jack D. Troxell
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Patent number: 5596156Abstract: The invention provides a sintered body for high-hardness tools which, when used for cutting work of cast irons where the cutting edge undergoes high temperature and abrupt impact, holds high chip-off and abrasion resistances and exhibits good cutting performance. The sintered body for high-hardness tools is obtained by sintering 60 to 75% by volume of cubic boron nitride powder and remaining part of a binder powder under a superhigh pressure, the binder comprising 5 to 15% by weight of Al, and the remaining part comprising a compound represented by (Hf.sub.X Ti.sub.y M.sub.1-x-y)(C.sub.Z N.sub.1-z).sub..alpha. (where M denotes an element belonging to IVa, Va or VIa group in the periodic table except Ti and Hf, and where 0.1.ltoreq.x.ltoreq.0.5, 0.5.ltoreq.y.ltoreq.0.9, 0.7.ltoreq.z.ltoreq.0.9, and 0.6.ltoreq..alpha..ltoreq.0.8) or a mixture of a plurality of compounds that totally results in the aforementioned composition.Type: GrantFiled: September 18, 1995Date of Patent: January 21, 1997Assignee: Sumitomo Electric Industries, Ltd.Inventors: Tomohiro Fukaya, Tetsuo Nakai
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Patent number: 5577424Abstract: A nitrogen-containing sintered hard alloy in which the content of the binder phase is at the highest level in an area to a depth of between 3 .mu.m and 500 .mu.m from its surface and its content in this area is between 1.1 and 4 times the average content of the binder phase in the entire alloy. Below this area, the content of the binder phase decreases gradually so that its content becomes equal to the average content of the binder phase at a depth of 800 .mu.m or less. The content of the binder phase in the surface layer is 90% or less of its maximum value. The depth of 800 .mu.m is a value at which the thermal conductivity is kept sufficiently high and at the same time a tool can keep high resistance to plastic deformation during cutting.Type: GrantFiled: March 28, 1995Date of Patent: November 26, 1996Assignee: Sumitomo Electric Industries, Ltd.Inventors: Kazutaka Isobe, Keiichi Tsuda, Nobuyuki Kitagawa, Toshio Nomura
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Patent number: 5569862Abstract: A high-pressure phase boron nitride sintered body for cutting tools consists of a high-pressure phase boron nitride and an intermetallic compound containing a titanium carbonitride Ti(C,N) and at least one metal of Al, W, Co and Zr, and is produced by mixing the above components, and then sintering at a temperature of not lower than 1000.degree. C. under a pressure of not less than 2.4 GPa but less than 4 GPa.Type: GrantFiled: March 13, 1995Date of Patent: October 29, 1996Assignee: NOF CorporationInventors: Yutaka Kuroyama, Mitsuhiro Furuta
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Patent number: 5545248Abstract: A titanium-base sintered alloy which comprises a TiC and/or TiN or Ti(C,N) solid solution accounting for 5 to 70 vol %, with the remainder being composed of two components. The first component is at least one species selected from the group consisting of Groups Va and VIa metallic elements, except Cr, or at least one species selected from the group consisting of carbides, nitrides, and carbonitrides of Groups Va and VIa metallic elements, except Cr. The second component is titanium. The first component accounts for 1 to 30 vol % and the second component accounts for 70 to 99 vol % of the total amount of the first and second components. The alloy produces a preferred result when the content of TiC or TiN is 35 to 70 vol % and the first component accounts for 1 to 15 vol % of the remainder. It is desirable that the TiC, TiN, and the first component of the remainder be in the form of a solid solution.Type: GrantFiled: February 14, 1995Date of Patent: August 13, 1996Assignee: Nippon Tungsten Co., Ltd.Inventors: Kei Tokumoto, Tetsunori Kitada, Hironobu Shinoaki, Shigeya Sakaguchi
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Patent number: 5503653Abstract: The present invention relates to a sintered titanium-based carbonitride alloy for milling and turning where the hard constituents are based on Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and/or W 3-25% binder phase based on Co and/or Ni. the alloy is characterized in that the bottom of the crater caused by the crater wear on an insert used in milling and turning contain grooves with a mutual distance between their peaks of 40-100 .mu.m, preferably 50-80 .mu.m, and where the main part, preferably >75% of the grooves have a depth of >12 .mu.m, preferably >15 .mu.m.Type: GrantFiled: July 26, 1994Date of Patent: April 2, 1996Assignee: Sandvik ABInventors: Rolf G. Oskarsson, Gerold Weinl, Ake Ostlund
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Patent number: 5500289Abstract: A sinterable powder mix for the production of a tungsten-based cemented carbide material, said powder mix comprising at least 70% by weight of WC, from about 2 to about 15% by weight of an iron group metal binder, and optionally up to about 15% by weight of one or more carbides, nitrides and carbonitrides of metals of the groups IVb, Vb and VIb of the periodic table; characterized in thatsaid powder mix comprises from about 1 to about 8% by weight of Ta(Nb) oxide and powdered elemental carbon in about the stoichiometric amount required for the reaction:Ta(Nb).sub.2 O.sub.5 +7C.fwdarw.Type: GrantFiled: June 20, 1995Date of Patent: March 19, 1996Assignee: ISCAR Ltd.Inventor: Ilan Gavish
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Patent number: 5476530Abstract: This invention relates to submicron carbonitride powders of titanium and, optionally, other transition metals of the fifth (Me.sup.(5)) and sixth (Me.sup.(6)) secondary group of the periodic system of elements which have the following general molar composition: (Ti.sub.L Me.sub.M.sup.(5) Me.sup.(6).sub.1-L-M) (C.sub.1-y N.sub.y).sub.z with 0.50.ltoreq.L.ltoreq.1; 0.ltoreq.m.ltoreq.0.15; 0.ltoreq.(1-L-M).ltoreq.0.50; 0.10.ltoreq.y.ltoreq.0.95 and z.gtoreq.0.90, to a process for the production of these powders and to their use.Type: GrantFiled: April 30, 1993Date of Patent: December 19, 1995Assignee: Hermann C. Starck GmbH & Co. KGInventors: Benno Gries, Gerhard Gille, Mario Salvadori
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Patent number: 5470372Abstract: There is now provided a sintered titanium-based carbonitride alloy for metal cutting containing hard constituents based on Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and/or W and 3-30% binder phase based on Co and/or Ni. The structure contains well-dispersed and/or as agglomerates, 10-50% by volume hard constituent grains essentially without core-rim structure with a mean grain size of 0.8-5 .mu.m in a more fine-grained matrix with a mean grain size of the hard constituents of <1 .mu.m. The matrix is made from a powder being prepared from an intermetallic pre-alloy disintegrated to <50 .mu.m particle size and then carbonitrided in situ to extremely fine-grained hard constituents having a diameter .ltoreq.0.1 .mu.m within the binder phase metals.Type: GrantFiled: June 22, 1993Date of Patent: November 28, 1995Assignee: Sandvik ABInventor: Gerold Weinl
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Patent number: 5468278Abstract: This invention provides a cermet alloy having a structure comprising a hard phase and a bonding phase, wherein the hard phase comprising carbide particles rich An TiC, those rich in WC and (Ti, W, MO)C or (Ti, W, Mo)(C, N) and the bonding phase comprising at least one of Co and Ni. Mo contents in the bonding phase satisfies the conditions: 1.0.ltoreq.Mo (wt %)/Ti (wt %) and 6 (wt %).ltoreq.Ti+Mo. The cermet alloy has superior hardness and toughness as well as improved heat resistance and is applicable as a material for a wet machining tool.Type: GrantFiled: November 10, 1993Date of Patent: November 21, 1995Assignee: Hitachi Metals, Ltd.Inventors: Yuichi Nakahara, Katsuhiko Kojo
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Patent number: 5466276Abstract: A secondary hardening type high temperature wear-resistant sintered alloy body comprising 0.4 to 15 wt. % of at least one species of metal carbide forming element which is selected from the group consisting of W, Mo, V, Ti, Nb, Ta and B; 5 to 35 wt. % of at least one species of austenite forming element which is selected from the group consisting of Ni, Co, Cu, and Cr; 0.2 to 1.2 wt. % of C; and 0.04 to 0.2 wt. % of Al consisting essentially the remainder of Fe, wherein the alloy body contains an austenite phase which is capable of martensitic transformation.Type: GrantFiled: July 7, 1993Date of Patent: November 14, 1995Assignees: Honda Giken Kogyo Kabushiki Kaisha, Nippon Piston Ring Co., Ltd.Inventors: Katsuaki Sato, Katsuhiko Tominaga, Tsutomu Saka, Osamu Kawamura, Teruo Takahashi, Arata Kakiuchi
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Patent number: 5462574Abstract: There is provided a sintered titanium-based carbonitride alloy for metal cutting containing hard constituents based on Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and/or W and 3-30% binder phase based on Co and/or Ni. The structure contains 10-50% by weight well-dispersed Ti-rich hard constituent grains essentially without core-rim structure with a mean grain size of 0.8-5 .mu.m in a conventional carbonitride alloy matrix with a mean grain size of the hard constituents of 1-2 .mu.m. The Ti-rich hard constituent grains are essentially rounded, non-angular grains with an approximately logarithmic normal grain size distribution with a standard deviation of <0.23 logarithmic .mu.m.Type: GrantFiled: June 16, 1993Date of Patent: October 31, 1995Assignee: Sandvik ABInventors: Niclas During, Gerold Weinl
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Patent number: 5460640Abstract: A fully dense ceramic-metal body including 40-88 v/o of an oxide hard phase of, in v/o of the body, 4-88 v/o M-aluminum binary oxides, where the binary oxide has a C-type rare earth, garnet, .beta.-MAl.sub.11 O.sub.18, or perovskite crystal structure, and M is a lanthanide or indium, and 0-79 v/o .alpha.-alumina; about 10-50 v/o of a hard refractory carbide, nitride, or boride as a reinforcing phase; and about 2-10 v/o of a dispersed metal phase combining Ni and Al mostly segregated at triple points of the microstructure. The preferred metal phase contains a substantial amount of the Ni.sub.3 Al ordered crystal structure. In the preferred body, the reinforcing phase is silicon carbide partially incorporated into the oxide grains, and bridges the grain boundaries. The body including a segregated metal phase is produced by densifying a mixture of the hard phase components and the metal component, with the metal component being present in the starting formulation as Ni powder and Al powder.Type: GrantFiled: August 17, 1992Date of Patent: October 24, 1995Assignee: Valenite Inc.Inventor: Sergej-Tomislav Buljan
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Patent number: 5457075Abstract: A sintered ceramic composite comprising 35 to 80 wt. % of aluminum nitride, 2 to 60 wt. % of boron nitride, 0.1 to 25 wt. % of an oxide of magnesium, 0.5 to 20 wt. % of at least one of rare earth oxides including yttrium oxide as an optional component and 25 wt. % or less of aluminum oxide as an optional component is disclosed.Type: GrantFiled: May 11, 1994Date of Patent: October 10, 1995Assignee: Hitachi Metals, Ltd.Inventors: Hideko Fukushima, Yasuo Sawano, Katsuhiko Kojo
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Patent number: 5447549Abstract: A hard alloy suitable for use in cutting tools, which exhibits excellent wear and fracture resistance, is disclosed. The hard alloy includes a hard dispersed phase and a binder metal phase, and the binder metal phase is constructed so that compressive stress, preferably of no less than 98 MPa (10 kgf/mm.sup.2), is retained therein. The hard alloy may be a cermet which includes a hard dispersed phase of at least one compound of titanium carbonitride and composite carbonitrides of titanium with at least one element of tantalum, tungsten, molybdenum, niobium, vanadium, chromium, zirconium or hafnium, and a binder metal phase of one or more of cobalt, nickel, iron and aluminum.Type: GrantFiled: February 17, 1993Date of Patent: September 5, 1995Assignee: Mitsubishi Materials CorporationInventor: Hironori Yoshimura
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Patent number: 5439744Abstract: This invention relates generally to a novel directed metal oxidation process which is utilized to produce self-supporting bodies. In some of the more specific aspects of the invention, a parent metal (e.g., a parent metal vapor) is induced to react with at least one solid oxidant-containing material to result in the directed growth of a reaction product which is formed from a reaction between the parent metal and the solid oxidant-containing material. The inventive process can be utilized to form bodies having substantially homogeneous compositions, graded compositions, and macrocomposite bodies.Type: GrantFiled: February 25, 1993Date of Patent: August 8, 1995Assignee: Lanxide Technology Company, LPInventors: Terry D. Claar, Vilupanur A. Ravi, Philip J. Roach
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Patent number: 5421851Abstract: The present invention relates to a sintered titanium-based carbonitride alloy for milling and turning where the hard constituents are based on Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and/or W and the binder phase based on Co and/or Ni. The structure comprises 10-50% by volume hard constituent grains with core-rim-structure with a mean grain size for the cores of 2-8 .mu.m in a more fine-grained matrix with a mean grain size of the hard constituents of <1 .mu.m and where said mean grain size of the coarse hard constituents grains is >1.5 .mu.m, preferably >2 .mu.m, larger than the mean grain size for the grains in the matrix. The coarse grains can be Ti(C,N), (Ti,Ta)C, (Ti,Ta)(C,N) and/or (Ti,Ta,V)(C,N).Type: GrantFiled: May 6, 1992Date of Patent: June 6, 1995Assignee: Sandvik ABInventors: Rolf G. Oskarsson, Gerold Weinl, Ake Ostlund
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Patent number: 5403373Abstract: A hard sintered component of a cemented carbide or a stellite alloy having a complex three-dimensional shape and a small hole or the like and the high strength originally provided by the used material for making the component without any secondary working, is formed by injection molding a compact molding die having an inner mold surface roughness R.sub.max of not more than 3 .mu.m. Where a core pin is used the outer surface of the pin has a surface roughness R.sub.max of not more than 3 .mu.m. The compact is then sintered. The hard sintered component is composed of a cemented carbide or a stellite alloy. In such a hard sintered component, the surface of a complex three-dimensional shape such as a disc portion or a thin portion, or the inner surface of a small hole, is defined by a sintered surface which has a surface roughness R.sub.max of not more than 4 .mu.m.Type: GrantFiled: May 28, 1992Date of Patent: April 4, 1995Assignee: Sumitomo Electric Industries, Ltd.Inventors: Nobuyuki Kitagawa, Toshio Nomura
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Patent number: 5403541Abstract: Method of making sintered insert for milling and turning formed of a titanium-based carbonitride containing hard constituents and binder phase metal comprising milling at least one hard constituent with binder phase metal, adding a second hard constituent at a later time during milling, pressing and sintering the pressed constituents to form the insert.Type: GrantFiled: May 6, 1992Date of Patent: April 4, 1995Assignee: Sandvik ABInventors: Rolf G. Oskarsson, Gerold Weinl, Ake stlund
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Patent number: 5403374Abstract: A watch exterior part is formed of cemented carbide or stellite alloy, and has a three-dimensionally curved as-sintered surface or a small hole with an as-sintered interior peripheral surface, or has a three-dimensionally curved polished surface obtained by polishing an as-sintered surface. The watch exterior part is manufactured by a method in which organic binder is milled into a material powder, and a molded body obtained by injection molding is subjected to a binder removing process and then sintered. By the manufacturing method, a watch exterior part formed of cemented carbide or stellite alloy has a high strength and a complicated configuration such as a three-dimensional curved surface and a small hole, without applying secondary machining operations such as discharge operations.Type: GrantFiled: May 28, 1992Date of Patent: April 4, 1995Assignees: Sumitomo Electric Industries, Ltd., Namiki Precision Jewel Co., Ltd.Inventors: Nobuyuki Kitagawa, Toshio Nomura, Yoichi Yaguchi, Hidehiro Uchiumi, Naoko Iwashimizu
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Patent number: 5401292Abstract: A carbonyl iron powder (CIP) premix composition suitable for metal injection molding is provided herein. The composition comprises (a) CIP having a particle size in the range of about 0.2-7 microns, preferably about 0.2-5 microns, and a narrow particle size distribution; and (b) an alloying material, having a particle size in the range of about 0.02 to 5 microns, preferably about 0.03 to 3.0 microns, and a narrow particle size distribution, comparable to the CIP, and present in an amount of about 0.1-60% by weight of the composition, preferably 0.5-50%. The alloy material substantially covers the surface of the iron particles and is adhered thereto by attractive forces. Preferably the alloy material includes elemental metal powders which are smaller in particle size than the CIP.The premix composition is prepared by intensive mixing of its powder components, e.g.Type: GrantFiled: August 3, 1992Date of Patent: March 28, 1995Assignee: ISP Investments Inc.Inventor: Joseph E. Japka
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Patent number: 5395421Abstract: There now exists a sintered titanium-based carbonitride alloy containing hard constituents with core-rim structure based on, besides Ti, W, one or more of the metals Zr, Hf, V, Mo, Nb, Ta or Cr in 5-30 weight % binder phase based on Co and/or Ni with simultaneously increased wear resistance and toughness. The alloy is characterized in that at least 70%, preferably at least 80%, of said hard constituents have four different types of cores with the following contents of Ti and W in weight % of the total metal content: 1-5 W and 90-95 Ti (1A), 15-25 W and 65-85 Ti (1B), 50-75 W and 20-40 Ti (1C), as well as 20-30 W and 30-60 Ti (2A), whereby the amount of each type is at least 5%.Type: GrantFiled: September 30, 1993Date of Patent: March 7, 1995Assignee: Sandvik ABInventors: Gerold Weinl, Rolf Oskarsson, Lars Hultman
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Patent number: 5395700Abstract: In this invention, a cutting tool comprises two layers of hard sintered compact of cBN. The first sintered compact layer comprises about 75-98% by volume of cBN and a first binder material. The first binder material comprises from about 1 to out 40% by weight of Al. The second sintered compact layer comprises from about 40 to about 65% by volume of cBN and a second binder material. The second binder material comprises about 2 to about 30% by weight of Al. The first sintered compact layer is bonded to the second sintered compact layer. This composite material is bonded directly or indirectly to a tool holder to form a cutting tool. The first sintered compact layer constitutes a rake face of the cutting tool.Type: GrantFiled: June 25, 1992Date of Patent: March 7, 1995Assignee: Sumitomo Electric Industries, Ltd.Inventors: Tetsuo Nakai, Mitsuhiro Goto
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Patent number: 5387294Abstract: A hard surfacing alloy which has a Rockwell C hardness of greater than about 50 and which includes tungsten carbide, chromium carbide and bi-metallic chromium and tungsten carbide crystals which are precipitated in the alloy. Alloys of the present invention in their nominal composition comprise from about 12% to about 20% tungsten; from about 13% to about 30% chromium; an effective amount of carbon for forming carbides with the tungsten and chromium and include effective amounts of fluxes and melting point depressants and the like. The balance of the composition is nickel. The alloys include precipitated carbide crystals of chromium, tungsten and bi-metallic mixtures thereof which are interspersed through the hard surfacing alloy and are metallurgically bonded in the metal matrix of the alloy. The alloys have extremely low porosities and therefore are suitable for glass plunger and other applications where low porosity is essential.Type: GrantFiled: May 19, 1992Date of Patent: February 7, 1995Assignee: Wall Comonoy CorporationInventor: Samuel C. DuBois
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Patent number: 5348808Abstract: In a hard sintered cutting tool, the tool life can be further increased. In this hard sintered body cutting tool, a rake face of an edge portion is formed by a major surface of a first sintered body layer containing at least 80 percent by volume and less than 98 percent by volume of diamond, while a flank of the edge portion is formed by a second sintered body layer containing at least 30 percent by volume and less than 75 percent by volume of cubic boron nitride (CBN). The first sintered body layer is formed to have a thickness of at least 0.02 mm and less than 0.1 mm, and to be in a thickness ratio of at least 1:5 to the second sintered body layer. Thus, chipping resistance of the rake face is improved by the first sintered body layer, while wear resistance of the flank is improved by the second sintered body layer. As a result, it is possible to suppress progress of local wear and chipping, whereby the life of the cutting tool is increased as compared with the prior art.Type: GrantFiled: May 25, 1993Date of Patent: September 20, 1994Assignee: Sumitomo Electric Industries, Ltd.Inventors: Mitsuhiro Goto, Tetsuo Nakai
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Patent number: 5348806Abstract: A cermet alloy having a structure comprising a hard phase and a bonding phase, said hard phase comprising (1) at least one of MC, MN, and MCN, wherein M is at least one element selected from Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, and W (2) at least one compound selected from (M,Mo)(B,C), M,Mo)(B,N) and (M,Mo)(B,CN) and (3) at least one Mo--Co--B compound; said bonding phase comprising Co. The cermet alloy has superior toughness and hardness, and can be worked by conventional sintering methods. The invention also includes a method for producing the cermet alloy.Type: GrantFiled: September 18, 1992Date of Patent: September 20, 1994Assignee: Hitachi Metals, Ltd.Inventors: Katsuhiko Kojo, Akibumi Negishi, Masayuki Gonda
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Patent number: 5330553Abstract: A sintered titanium-based carbonitride alloy contains hard constituents based on, in addition to Ti, W and/or Mo, one or more of the metals Zr, Hf, V, Nb, Ta or Cr in 5-30% binder phase based on Cobalt and/or nickel. The content of tungsten and/or molybdenum, preferably molybdenum in the binder phase is >1.5 times higher than in the rim and >3.5 times higher than in the core of adjacent hard constituent grains. The alloy is produced by a particular method.Type: GrantFiled: May 22, 1992Date of Patent: July 19, 1994Assignee: Sandvik ABInventors: Gerold Weinl, Rolf G. Oskarsson, Per Gustafsson
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Patent number: 5314657Abstract: There is now provided a method of manufacturing a sintered body of titanium-based carbonitride alloy comprising hard constituents in 5-25% binder phase where the hard constituents contain, in addition to Ti, one or more of the metals V, Nb, Ta, Cr, Mo or W and the binder phase is based on cobalt and/or nickel by powder metallurgical methods, i.e., milling, pressing and sintering. The composition of the hard constituents is:0.88<a<0.96;0.04<b<0.08;0.ltoreq.c<0.04;0.ltoreq.d<0.04;0.60<f<0.73;0.80<x<0.90; and0.31<h<0.40.and the overall composition of the hard constituents phase is expressed by the formula:(Ti.sub.a,Ta.sub.b,Nb.sub.c,V.sub.d).sub.x (Mo.sub.e,W.sub.f).sub.y (C.sub.g,N.sub.h).sub.z.Type: GrantFiled: July 6, 1993Date of Patent: May 24, 1994Assignee: Sandvik ABInventor: Ake Ostlund
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Patent number: 5308376Abstract: A cermet in which the hard constituents are based on Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and/or W and the binder phase is based on Co and/or Ni and possibly small amounts of Al being present. At least 80% by volume of the hard constituents consist of duplex structures made up of a core and at least one surrounding rim. The duplex hard constituents consist of several, preferably at least two, different hard constituent types concerning the composition of core and/or rim(s). These individual hard constituent types consist each of 10-80%, preferably 20-70% by volume of the total content of hard constituents. In addition, non-duplex hard constituents may be present in amounts of up to 20% by volume of the total hard constituent amount.Type: GrantFiled: June 26, 1990Date of Patent: May 3, 1994Assignee: Sandvik ABInventor: Rolf Oskarsson
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Patent number: 5306326Abstract: A sintered body of titanium based carbonitride alloy containing hard constituents based on, in addition to titanium, one or more of the metals Zr, Hf, V, Nb, Ta, Cr, No or W in 5-30% binder phase based on Co and/or Ni is disclosed. The body has a binder phase enriched surface zone with a higher binder phase content than in the inner portion of the body in combination with an enrichment of simple hard constituents, i.e., the share of grains with core-rim structure is lower in the surface zone than in the inner of the body.Type: GrantFiled: May 22, 1992Date of Patent: April 26, 1994Assignee: Sandvik ABInventors: Rolf G. Oskarsson, Gerold Weinl
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Patent number: 5303617Abstract: A Cu--Sn based sintered material, which has an improved corrosion-resistance, is provided by setting the Pb content at 1 to less than 10% and adding from 0.1 to 30% of a hard matter(s) selected from the groups (a), (b), (c) and (d). The hard matter is(a) Fe.sub.2 P, Fe.sub.3 P, FeB, Fe.sub.2 B and Mo.(b) Fe--Cr, Fe--Mn, Fe--Ni, Fe--Si, Fe--W, Fe--Mo, Fe--V, Fe--Ti, Fe--Nb, CuP, Cr, and W;(c) SiC, TiC, WC, B.sub.4 C, TiN, cubic BN, Si.sub.3 N.sub.4, SiO.sub.2, ZrO.sub.2, and Al.sub.2 O.sub.3 ;(d) Si--Mn, Cu--Si, and FeS.Most of said hard matter being dispersed in Cu particles, grain boundaries between Cu particles, and between the Cu and Pb particles.Type: GrantFiled: November 3, 1992Date of Patent: April 19, 1994Assignee: Taiho Kogyo Co., Ltd.Inventors: Eiji Asada, Hiromi Ogino
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Patent number: 5298051Abstract: This invention relates generally to a novel method of manufacturing a composite body, such as a ZrB.sub.2 -ZrC-Zr (optional) composite body, by utilizing a post-treatment process and to the novel products made thereby. More particularly, the invention relates to a method of modifying a composite body comprising one or more boron-containing compounds (e.g., a boride or a boride and a carbide) which has been made by the reactive infiltration of a molten parent metal into a bed or mass containing boron carbide, and optionally one or more inert fillers, to form the body.Type: GrantFiled: November 9, 1992Date of Patent: March 29, 1994Assignee: Lanxide Technology Company, LPInventors: Terry D. Claar, Gerhard H. Schiroky, William B. Johnson
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Patent number: 5296016Abstract: There is disclosed a surface coated cermet blade member which includes a cermet substrate and a hard coating of an average thickness of 0.5 to 20 .mu.m formed thereon. The substrate contains, apart from unavoidable impurities, a binder phase of 5 to 30% by weight of at least one of cobalt, nickel, iron and aluminum, and a hard dispersed phase of a balance carbo-nitride of metals. The metals are titanium, tungsten and at least one of tantalum, niobium, vanadium, zirconium, molybdenum and chromium. The substrate includes a surface portion having a hardness greater than an interior portion. The hard coating may be composed of one or more coating layers. Each coating layer is formed of TiX or Al.sub.2 O.sub.3, where X denotes at least one element of carbon, nitrogen, oxygen and boron.Type: GrantFiled: September 17, 1991Date of Patent: March 22, 1994Assignee: Mitsubishi Materials CorporationInventors: Hironori Yoshimura, Seiichirou Nakamura, Niro Odani
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Patent number: 5288670Abstract: This invention relates generally to a novel method of preparing self-supporting bodies, and to novel products made thereby. In its more specific aspects, this invention relates to a method of producing self-supporting bodies comprising one or more boron-containing compounds, e.g., a boride or a boride and a carbide, by reactive infiltration of a molten parent metal actinide into (1) a bed or mass containing boron carbide and, optionally, (2) at least one of a boron donor material (i.e., a boron-containing material) and a carbon donor material (i.e., a carbon-containing material), (3) a bed or mass comprising a mixture of a boron donor material and a carbon donor material and, optionally, (4) one or more inert fillers in any of the above masses, to form the body.Type: GrantFiled: November 23, 1992Date of Patent: February 22, 1994Assignee: Lanxide Technology Company, LPInventor: Paul V. Kelsey
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Patent number: 5246480Abstract: In a contact material, there is present in addition to silver, at least one higher melting point metal, metal alloy or metal compound. According to the invention, the material contains in addition to silver (Ag), at least iron (Fe) and/or titanium (Ti) in percent by weight of from 2 to 50%. Optionally, nitrides, carbides and/or borides of the metals titanium, zirconium and/or tantalum may also e present. It has been found that in their contact property spectrum such materials are largely equivalent to the material AgNi10. Thus the latter contact material can be replaced completely.Type: GrantFiled: October 17, 1990Date of Patent: September 21, 1993Assignee: Siemens AktiengesellschaftInventors: Wolfgang Haufe, Joachim Grosse, Bernhard Rothkegel, deceased