Abstract: The present invention provides a manufacturing method of crude copper from low-grade copper sludge, one embodiment of the present invention comprises the steps of: (1) calcining a low-grade copper sludge (step 1); (2) producing a mixture by adding at least one selected from a group consisting of binder, flux and combinations thereof to the calcined low-grade copper sludge (step 2); (3) producing a briquette by compression molding the mixture (step 3); (4) melting and reducing by charging the briquette into a submerged arc furnace with adding flux (step 4); and (5) separating crude copper and slag produced by melting and reducing (step 5).

Abstract: A method of producing a fluxing agent that can be used in production of steel, preferably stainless steel, employs as a raw material a hydroxide sludge that results from neutralization of metal-contaminated pickling liquid from a pickling step for a steel and contains at least one fluoride-containing compound. The hydroxide sludge is calcined. Steel, preferably stainless steel, is produced by decarburizing a steel heat, whereby a slag is formed on top of the steel heat, and adding a fluxing agent to the slag.

Abstract: A mold powder for continuous steel casting, contains CaO, SiO.sub.2 and fluoride as the main components. The ratio by weight of CaO', represented by the following equation, to SiO.sub.2 is 0.9-2.8 and the CaF.sub.2 content is about 5-60 wt. %. The powder contains Na.sub.2 O in an amount of 0-25 wt. % and C in an amount of 0-10 wt. %.CaO'=T.CaO-F.times.(56/38)wherein T.CaO represents the total Ca content in the mold powder as converted to CaO(wt. %) and F represents the total F content in the mold powder(wt. %). The powder is used in a method for continuous steel casting.

Abstract: A clean refractory metal sponge fines product is made from refractory metal sponge fines free of refractory metal oxides, carbides, nitrides and binary iron alloys; silicon carbide, oils, greases and organic compounds; salt; dust; dirt; pieces of iron, iron alloy and tungsten carbide; and light contaminants. The sponge fines are vigorously washed and rinsed with a displacement wash to remove the bulk of the wash fluid and subject to a counter-current wash to yield clean refractory metal sponge fines. The clean sponge fines can be pressed into briquettes and sintered at elevated pressures, or mixed with an alkali metal refractory metal halide slat, pressed at elevated pressures into sponge fines/salt briquettes and dried or pressed into briquettes, dried and packaged, or pressed into briquettes and stored wet. The briquettes are non-pyrophoric.

Abstract: A clean refractory metal SWARF particle product is made from refractory metal SWARF. The SWARF particles are produced with coolant at a temperature less than 650.degree. C. to prevent formation of refractory metal oxides and nitrides. The SWARF particles are comminuted to reduce the particle size of the SWARF slivers and to liberate residual coolant The comminuted SWARF slivers are washed with a displacement wash to remove the bulk of the coolant and subject to a counter current wash to remove substantially all of the coolant components to produce to clean SWARF particles. The clean SWARF particles can be pressed into briquettes and sintered at elevated pressures or mixed with an alkali metal refractory metal halide salt, pressed at elevated pressures into SWARF/soft briquettes and dried. The briquettes are non-pyrophoric.

Abstract: A method for reducing particulate iron oxide and/or other iron units to molten iron utilizing gaseous hydrogen as reductant in a reducing furnace, in which the ore freely falls during the melting and reduction process. Reacted top gas is purified and recirculated through the reduction furnace, establishing a counter-flow relationship to the particulate iron oxide, thereby heating and reducing the oxide. The heat for reduction is generated by combusting a fraction of the hydrogen reductant with oxygen. Heat may also be supplied via the use of electric arc heating. Oxygen may be partially or wholly replaced with water in order to maintain reaction oxidizer ratios while reducing heat supplied to the reaction.

Abstract: Dealuminizing cast iron by contacting it with free-flowing flux particles having a solid silica core and a molten silica shell wherein said flux comprises silica and about 1% to about 5% calcium fluoride.

Abstract: The desulfurization agent for molten iron is made up of 70 to 95% commercial calcium carbide, 5 to 25% silicon dioxide, 0 to 10% of a metal oxide; and 0 to 5% calcium fluoride. The metal oxides are iron oxides and manganese oxides. The desulfurizing agent has been found to reduce the amount of calcium carbide in the resulting slag.

Abstract: Hexafluorophosphates may be used as structure refiner during solidification of molten aluminium-silicon alloys. The structure refining effect is obtained almost immediately after addition of the hexafluorophosphate to the molten alloy. The hexafluorophosphates are preferably used in the form of a master composition wherein as diluents metals are used, especially copper.

Abstract: A granular additive alloy designed for addition of calcium to molten steel to obtain maximum calcium effects with minimal additions, especially in steels which cannot tolerate the other elements commonly accompanying calcium additions. An alloy is described which contains a ratio of not more than 2.85:1 nor less than 0.35:1 calcium to aluminum, and can contain other reactive metals such as, but not limited to, rare earths, boron, titanium, and zirconium in amounts up to 40% by weight of the alloy. The preferred embodiment is an alloy with 60% by weight calcium and 40% by weight aluminum. The particles are intended to dissolve in the molten steel and form a boundary layer adjacent their surfaces. The particles are sized such that substantially all of the particle is consumed in the formation of this boundary layer, according to a given relationship based on the concentration of calcium and aluminum in the alloy.

Abstract: The desulfurization agent for molten iron is made up of 95 to 70% commercial calcium carbide, 30 to 5% calcium aluminate slag, and 10 to 0% of a metal oxide. The calcium aluminate slag is made up of 65 to 50% calcium oxide, 35 to 25% aluminum oxide, and 12 to 3% calcium fluoride. The metal oxides are ferric oxide, manganomanganic oxide and ferrosoferric oxide. The desulfurizing agent has been found to reduce the amount of calcium carbide in the resulting slag.