Solid Treating Composition For Liquid Metal (e.g., Flux, Slagging Agent, Casting Agent, Etc.) Or Charge Patents (Class 75/303)
  • Patent number: 11407069
    Abstract: A flux containing terpene phenolic resin and having an acid value of 120 mgKOH/g or more is provided. The acid value can be 250 mgKOH/g or less. The terpene phenolic resin can be contained by 0.05 mass % or more and 30 mass % or less. The flux can contain the terpene phenolic resin and another resin component as a rosin component, and an amount of the terpene phenolic resin contained in the rosin component can be 0.1 mass % or more and 80 mass % or less.
    Type: Grant
    Filed: January 15, 2018
    Date of Patent: August 9, 2022
    Assignee: KOKI COMPANY LIMITED
    Inventors: Yuri Misumi, Takeshi Yahagi, Motohide Sasaki, Tatsuya Baba, Kazuma Karube
  • Patent number: 10435760
    Abstract: The invention relates to fluxing agents for the agglomeration process based on slag from the secondary metallurgy, the use of these fluxing agents in the process of agglomeration in the manufacture of the agglomerate designed for the use as a metallic charge in blast furnaces and a process of production of fluxing agents based on slag from the secondary metallurgy or based on a mixture of slag from the secondary metallurgy with other materials.
    Type: Grant
    Filed: July 2, 2014
    Date of Patent: October 8, 2019
    Assignee: ECOFER, S.R.O.
    Inventor: Milan Raclavský
  • Patent number: 10185792
    Abstract: The present disclosure relates to a method for predicting a slagging production position and a slagging production possibility in a furnace, the method including: the analyzing step of analyzing physical compositions of two or more kinds of coal; the phase diagram producing step of producing a phase diagram on the basis of the physical components of the two or more kinds of coal analyzed in the analyzing step; the deriving step of simulating the situation generated when the two or more kinds of coal are co-fired on the basis of the produced phase diagram; and the characteristic analyzing step of analyzing the characteristics in the furnace in the co-firing process of the two or more kinds of coal.
    Type: Grant
    Filed: September 16, 2016
    Date of Patent: January 22, 2019
    Assignee: Doosan Heavy Industries Construction Co., Ltd
    Inventors: Eunseong Cho, Dongkil Kim, Hyukje Kim, Byounghwa Lee
  • Patent number: 9525176
    Abstract: A carbothermic reduction method is provided for reducing a La-, Ce-, MM-, and/or Y-containing oxide in the presence of carbon and a source of a reactant element comprising Si, Ge, Sn, Pb, As, Sb, Bi, and/or P to form an intermediate alloy material including a majority of La, Ce, MM, and/or Y and a minor amount of the reactant element. The intermediate material is useful as a master alloy for in making negative electrode materials for a metal hydride battery, as hydrogen storage alloys, as master alloy additive for addition to a melt of commercial Mg and Al alloys, steels, cast irons, and superalloys; or in reducing Sm2O3 to Sm metal for use in Sm—Co permanent magnets.
    Type: Grant
    Filed: January 10, 2013
    Date of Patent: December 20, 2016
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Karl A. Gschneidner, Jr., Frederick A. Schmidt
  • Patent number: 9200348
    Abstract: Provided are an aluminum alloy and a manufacturing method thereof. In the method, aluminum and a master alloy containing a calcium (Ca)-based compound are provided. A melt is prepared, in which the master alloy and the Al are melted. The aluminum alloy may be manufactured by casting the melt.
    Type: Grant
    Filed: November 18, 2010
    Date of Patent: December 1, 2015
    Assignee: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY
    Inventors: Shae-Kwang Kim, Jin-Kyu Lee, Min-Ho Choi, Jeong-Ho Seo
  • Patent number: 9200349
    Abstract: A molten metal refining wire (11) comprises a metal sheath (12) encapsulating a core (14) of refining material, such as pure calcium powder, wherein the core (14) is sealed within the sheath (12) in a fluid-tight manner. A corresponding method of manufacturing the molten metal refining wire (11) is disclosed, as well as a method of refining molten metal by injecting the refining wire (11) into the molten metal.
    Type: Grant
    Filed: January 30, 2006
    Date of Patent: December 1, 2015
    Assignee: Injection Alloys Limited
    Inventor: Victor Colin Stekly
  • Patent number: 9169531
    Abstract: The present invention is a recycling method for aluminum dust collection and aluminum metallic smelting slag, where aluminum dross is processed into dross pellets having a particle diameter of larger than 200 meshes and smaller than 400 meshed, with which an aqueous solution of a binder is mixed to form a raw material. The raw material is then pressure molded to form a raw refractory material and sintered under a work temperature of 1050° C.˜1450° C., and reduced in temperature to finally form a refractory material.
    Type: Grant
    Filed: January 6, 2014
    Date of Patent: October 27, 2015
    Assignee: JIA XIE METAL CO., LTD.
    Inventors: Shih-Chien Chiang, Ya-Ping Liu
  • Patent number: 8696790
    Abstract: A process for converting organic wastes into a reducing agent-coke substitute (“RACS”). More specifically, a process for producing a reducing agent-coke substitute from a mixed waste material containing economically recoverable metals and organic based materials is described. In accordance with one aspect, the process comprises blending mixed waste material with a metal-containing smelter by-product, processing the blend of mixed waste material and smelter by-product through a heated mixing device to convert the blend into reducing agent-coke substitute.
    Type: Grant
    Filed: July 27, 2011
    Date of Patent: April 15, 2014
    Assignee: CONECSUS LLC
    Inventor: Jack Alan Scott
  • Publication number: 20130228044
    Abstract: A composite product and a method of manufacturing the composite product are disclosed. The composite product includes (a) a polymeric material binder and a metal-bearing material or (b) the polymeric material binder and a carbon-bearing material. The 5 method includes heating and mixing the components of the composite product and thereafter forming the heated mixture into a final product shape, with the heating step being sufficient to melt at least a part of the polymeric material binder to facilitate forming the product.
    Type: Application
    Filed: August 1, 2011
    Publication date: September 5, 2013
    Inventors: Paul James O'Kane, Catherine Louise Skidmore
  • Publication number: 20130047787
    Abstract: Disclosed is a carbon-material-containing iron oxide briquette composition that, when obtaining direct reduced iron by heating in a moving hearth reduction furnace, does not turn into powder in the furnace leading to an accumulation of powder, and reliably prevents the obtained direct reduced iron from turning into powder during conveyance, decreasing yield. Further disclosed are a method for producing same, and a method for producing direct reduced iron using same. The carbon-material-containing iron oxide briquette composition is characterized by: the solidus temperature that is of an Al2O3-CaO—SiO2 ternary system slag in said briquette composition and that is determined by the amount of contained Al2O3, CaO, and SiO2 being no greater than 1300 DEG C.
    Type: Application
    Filed: March 24, 2011
    Publication date: February 28, 2013
    Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
    Inventors: Motohiro Horiguchi, Kazutaka Kunii
  • Publication number: 20130025411
    Abstract: A process for converting organic wastes into a reducing agent-coke substitute (“RACS”). More specifically, a process for producing a reducing agent-coke substitute from a mixed waste material containing economically recoverable metals and organic based materials is described. In accordance with one aspect, the process comprises blending mixed waste material with a metal-containing smelter by-product, processing the blend of mixed waste material and smelter by-product through a heated mixing device to convert the blend into reducing agent-coke substitute.
    Type: Application
    Filed: July 27, 2011
    Publication date: January 31, 2013
    Applicant: ECS REFINING TEXAS, LLC
    Inventor: Jack Alan Scott
  • Publication number: 20120180598
    Abstract: A process of preparing for reuse small particles of one or more waste products produced from iron or steel mill activities, comprising the steps of creating a blend of one or more waste products with a blending system, the blend including a predetermined proportion of each of the one or more waste products, combining fly ash and the blend with a liquid in a mixing container to create a mixture, adding a predetermined amount of moisture reduction additive to the mixture, adjusting the amount of the liquid in the mixture to achieve a predetermined moisture and time before set up occurs, mixing the mixture continuously until set up occurs and an agglomeration forms, casting the agglomeration onto a surface, dividing the agglomeration into predetermined size chunks, removing particles of less than the predetermined size from the agglomeration. The chunks produced according to this process.
    Type: Application
    Filed: January 13, 2012
    Publication date: July 19, 2012
    Inventor: Tom Anderson
  • Patent number: 8221519
    Abstract: Powder which is for a flux-cored wire intended to become alloyed with a molten metal bath and which is formed by particles composed with at least 95% of sulphur, characterised in that its granulometric population is defined by: ?1 ?m?d10?340 ?m; ?200 ?m d50?2000 ?m; ?500 ?m d90?2900 ?m. Sulphur-based flux-cored wire, characterised in that it contains the preceding powder, and in that the compaction rate of the powder within the wire is greater than or equal to 85%. Method for producing a sulphur-based flux-cored wire for alloying with molten metal baths.
    Type: Grant
    Filed: April 15, 2010
    Date of Patent: July 17, 2012
    Assignee: Affival
    Inventors: Andre Poulalion, Sebastien Gerardin, Vincent Moreschi
  • Publication number: 20120144955
    Abstract: A metallurgical process involves providing an ingredient enclosure and placing a plurality of granules of a first material in the ingredient enclosure. The first material contains a first ingredient in a metallurgical process. A metallurgical process furnace having a chamber in which ingredients for the metallurgical process are added is provided and the ingredient enclosure and the first material are added to the chamber. The chamber is heated after the addition of the ingredient enclosure and the first material to the chamber, although it may also be heated prior to such addition. In one form, the granules comprise mill scale and the metallurgical process furnace is a blast furnace.
    Type: Application
    Filed: August 16, 2011
    Publication date: June 14, 2012
    Applicant: IRON MOUNT CORPORATION
    Inventor: Leonard Reiffel
  • Publication number: 20120017725
    Abstract: The invention relates to a method for the agglomeration of iron-oxide-containing residual materials, in particular scale and mill scale, wherein the residual materials and paper sludge are dried and ground and agglomerates are produced, by hot briquetting, from a mixture of the residual materials and paper sludge so processed. In this manner, it is possible to produce mill scale briquettes of high strength and density. These briquettes can then be charged into an electric arc steelmaking furnace for the purpose of recycling the iron contained in the residual materials.
    Type: Application
    Filed: July 22, 2010
    Publication date: January 26, 2012
    Inventors: Udo Meynerts, Michael Maurer, Saulo Henrique Freitas Seabra Da Rocha, Christian Wirtgen
  • Patent number: 7963402
    Abstract: The present invention relates to a ceramic filter device for molten metal filtration comprising a major ceramic phase and a minor carbon phase bonded by phosphate bond, a method for producing such filter devices, and the use of such filter devices for the filtration of molten steel.
    Type: Grant
    Filed: September 4, 2006
    Date of Patent: June 21, 2011
    Assignee: Sud-Chemie Hi-Tech Ceramics Inc.
    Inventor: Kassim Juma
  • Patent number: 7914599
    Abstract: A slag conditioner containing MgO, carbon or a filler and a binder is mixed and formed under pressure to produce aggregates which can have the form of a briquette. The slag conditioner is used to improve the operating performance and refractory life in steel melting furnaces. A slag conditioner comprising by weight a mixture and 2% to 25% binder for bonded agglomerates or larger particles of said mixture, the mixture comprising: 20% to 90% burned aggregates comprised of particles less than 8 mm of which at least 30% is 0.2 mm or greater and containing between 35% and 94% MgO; up to 50% slag-making carbonaceous or other additive; and up to 50% light burned magnesite.
    Type: Grant
    Filed: November 17, 2004
    Date of Patent: March 29, 2011
    Assignee: ISM, Inc.
    Inventors: Joseph L. Stein, Brian J Stein, John Beatty
  • Patent number: 7879130
    Abstract: The present invention relates to a calcium-silicate based slag having a phosphorous content of less than 3 ppmw. The invention further relates to a method for producing a low phosphorous calcium-silicate based slag, where molten calcium-silicate based slag is treated with a molten ferrosilicon alloy in a vessel, whereby phosphorous in the calcium-silicate based slag is transferred to the ferrosilicon alloy, and a low phosphorous calcium-silicate to based slag is removed from the vessel.
    Type: Grant
    Filed: March 3, 2008
    Date of Patent: February 1, 2011
    Assignee: Elkem ASA
    Inventors: Erik Enebakk, Gabriella Maria Tranell, Ragnar Tronstrad
  • Patent number: 7854784
    Abstract: A method for making solar grade silicon from metallurgical grade silicon is accomplished by treating a calcium silicate based slag with ferrosilicon in the first vessel so as to obtain a purification of the calcium silicate based slag. In a second vessel, the purified calcium based silicate slag is used to treat metallurgical grade silicon in order to obtain a solar grade silicon. The purification of calcium silicate based slag in the first vessel is accomplished to reduce phosphorous to a level of less than 3 ppmw.
    Type: Grant
    Filed: July 13, 2009
    Date of Patent: December 21, 2010
    Assignee: Elkem ASA
    Inventors: Erik Enebakk, Gabriella Maria Tranell, Ragnar Tronstad
  • Publication number: 20100275728
    Abstract: A method of producing a fluxing agent that can be used in production of steel, preferably stainless steel, employs as a raw material a hydroxide sludge that results from neutralization of metal-contaminated pickling liquid from a pickling step for a steel and contains at least one fluoride-containing compound. The hydroxide sludge is calcined. Steel, preferably stainless steel, is produced by decarburizing a steel heat, whereby a slag is formed on top of the steel heat, and adding a fluxing agent to the slag.
    Type: Application
    Filed: June 10, 2010
    Publication date: November 4, 2010
    Applicant: OUTOKUMPU OYJ
    Inventors: Sven-Eric Lunner, Ye Guozhu
  • Publication number: 20100263485
    Abstract: Powder which is for a flux-cored wire intended to become alloyed with a molten metal bath and which is formed by particles composed with at least 95% of sulphur, characterised in that its granulometric population is defined by: —1 ?m?d10?340 ?m; —200 ?m d50?2000 ?m; —500 ?m d90?2900 ?m. Sulphur-based flux-cored wire, characterised in that it contains the preceding powder, and in that the compaction rate of the powder within the wire is greater than or equal to 85%. Method for producing a sulphur-based flux-cored wire for alloying with molten metal baths.
    Type: Application
    Filed: April 15, 2010
    Publication date: October 21, 2010
    Applicant: AFFIVAL
    Inventors: André POULALION, Sébastien GERARDIN, Vincent MORESCHI
  • Publication number: 20100242678
    Abstract: There are provided a method of manufacturing an Fe/Ni-containing material having a low content of sulfur (S) from an Fe/Ni/SO4-containing liquid waste, a ferronickel mass using the Fe/Ni-containing material, and a method of manufacturing the ferronickel mass. The method of manufacturing an Fe/Ni-containing material from an Fe/Ni-containing liquid waste includes: removing SO4 from an Fe/Ni/SO4-containing liquid waste by adding an SO4 neutralizing agent to the liquid waste so that pH of the liquid waste can be maintained to a pH level of 0.5 to 2.5; precipitating Fe and Ni in the form of hydroxide [(Ni,Fe)(OH)] by adding NaOH to the SO4-free solution; washing the precipitate with water; and manufacturing an Ni/Fe-containing material by filtering and drying the washed Ni/Fe-containing sludge.
    Type: Application
    Filed: May 15, 2008
    Publication date: September 30, 2010
    Inventor: Jae Young Lee
  • Publication number: 20100206131
    Abstract: Provided are self-fluxing pellets for a blast furnace, characterized in that a CaO/SiO2 mass ratio C/S is 0.8 or more and a MgO/SiO2 mass ratio M/S is 0.4 or more; when an iron content (mass %) in the entire pellet is represented by % TFe, % TFe is 65 or less; and a temperature Ts (unit: ° C.) at which the pressure loss starts to increase sharply in a loaded high-temperature reduction test and which is calculated by the equation below is 1290° C.
    Type: Application
    Filed: December 15, 2008
    Publication date: August 19, 2010
    Applicant: Kabushiki Kaisha Kobe Seiko Sho(Kobe Steel, Ltd.)
    Inventors: Eisaku Yasuda, Nobuhiro Hasegawa, Yoshiyuki Matsui, Shuji Kitayama
  • Publication number: 20100116870
    Abstract: A tin or tin alloy plating film surface treatment aqueous solution that can reduce whiskers on the surface of a tin or tin alloy plating film, and can provide a favorable tin or tin alloy plating film using a simple method for tin or tin alloy plating films that are used on electronic components.
    Type: Application
    Filed: September 22, 2009
    Publication date: May 13, 2010
    Applicant: Rohm and Haas Electronic Materials LLC
    Inventor: Yutaka Morii
  • Publication number: 20100037729
    Abstract: A carbonaceous material substitute product for blast furnace metallurgical coal and method of making the carbonaceous material is disclosed. A metallurgical coal substitute material is made from non-metallurgical grade coal or other carbon sources.
    Type: Application
    Filed: April 29, 2009
    Publication date: February 18, 2010
    Inventors: Siddhartha Gaur, Vibha Bansal
  • Publication number: 20080257108
    Abstract: The invention relates to coated slag, which is coated with a layer of a hydrophobic polyurethane.
    Type: Application
    Filed: October 5, 2006
    Publication date: October 23, 2008
    Applicant: BASF SE
    Inventors: Marcus Leberfinger, Hans Ulrich Schmidt, Hans-Jurgen Reese, Johann Leitner, Andrea Eisenhardt
  • Publication number: 20080196548
    Abstract: A method and composition for removing sulfur from molten ferrous material, particularly molten iron. The desulfurization agent includes one or more pucks or briquettes of deoxidizing and/or desulfurization agent. The pucks or briquettes of deoxidizing and/or desulfurization agent include at least one deoxidizing metal and at least one ferrous metal.
    Type: Application
    Filed: February 16, 2007
    Publication date: August 21, 2008
    Inventor: Thomas H. Bieniosek
  • Publication number: 20080156145
    Abstract: The present invention relates to a calcium-silicate based slag having a phosphorous content of less than 3 ppmw. The invention further relates to a method for producing a low phosphorous calcium-silicate based slag, where molten calcium-silicate based slag is treated with a molten ferrosilicon alloy in a vessel, whereby phosphorous in the calcium-silicate based slag is transferred to the ferrosilicon alloy, and a low phosphorous calcium-silicate to based slag is removed from the vessel.
    Type: Application
    Filed: March 3, 2008
    Publication date: July 3, 2008
    Applicant: ELKEM ASA
    Inventors: Erik ENEBAKK, Gabriella Maria TRANELL, Ragnar TRONSTAD
  • Patent number: 7226493
    Abstract: The present invention relates to a method for grain refining of steel. A grain refining alloy having a composition FeXY where X is one or more elements selected from the group consisting of Cr, Mn, Si, Ni, and Mo and where Y is one or more oxide and/or sulphide and or nitride and/or carbide forming elements selected from the group consisting of Ce, La, Nd, Pr, Ti, Al, Zr, Ca, Ba, Sr, Mg, C and N where X is between 0.001 and 99% by weight based on the weight of the alloy and where Y is between 0.001 and 50% by weight of the alloy, said alloy additionally containing between 0.001 and 2% by weight of oxygen and/or between 0.001 and 2% by weight of sulphur, said alloy containing at least 103 inclusion particles per mm3 consisting of oxides and/or sulphides and/or carbides and/or nitrides of one or more of the Y elements and/or one or more of the X elements Cr, Mn and Si in addition to Fe, said inclusion particles having a mean diameter of less than 10 ?m, is added to molten steel in an amount of between 0.
    Type: Grant
    Filed: January 29, 2001
    Date of Patent: June 5, 2007
    Assignee: Elkem ASA
    Inventors: Oystein Grong, Ole Svein Klevan
  • Patent number: 6972059
    Abstract: An exothermal feeder mass is described, containing aluminum and magnesium, at least one oxidizing agent, a SiO2-containing filler, and an alkali silicate as the binder; it is characterized in that it contains roughly 2.5 to 20% by weight of a reactive aluminum oxide with a specific surface of at least roughly 0.5 m2/g and an average particle diameter (d50) from roughly 0.5 to 8 microns and is essentially free of fluoride-containing fluxes.
    Type: Grant
    Filed: May 20, 2000
    Date of Patent: December 6, 2005
    Assignee: AS Lungen GmbH & Co. KG
    Inventor: Udo Skerdi
  • Publication number: 20040177722
    Abstract: Cermet material obtained from unused inert anodes, used inert anodes and cermet used in the production of inert anodes is beneficiated into a nonferrous metal concentrate composition from which metal values contained in the composition may be readily recovered by using a conventional smelting process. The invention also relates to the use of the composition in a smelting process for the recovery of metal values from the cermet composition of the invention.
    Type: Application
    Filed: February 27, 2004
    Publication date: September 16, 2004
    Applicant: WORLD RESOURCES COMPANY
    Inventors: Peter T. Halpin, Ulrich R. Schlegel, Kenneth E. Riegel
  • Patent number: 6770366
    Abstract: The invention relates to a cored wire for introducing additives into a molten metal bath comprising a metallic sheath (5) containing an additive (6), which metallic sheath is covered by a wrapping (7) which, being combustible without leaving harmful residues, momentarily retards the propagation of heat to the core of the cored wire, this cored wire being characterized in that on top of this combustible wrapping, a protective metallic casing encloses the assembly thus constituted by the additive, the metallic sheath and the combustible wrapping.
    Type: Grant
    Filed: March 16, 2001
    Date of Patent: August 3, 2004
    Assignee: Affival S.A.
    Inventors: Dominique Bernard Riche, Jean-Claude Becart
  • Patent number: 6613119
    Abstract: A pellet, intended for the late inoculation of cast irons, obtained by agglomeration of a powdered inoculant, characterised in that the mass proportion of the granulometric fraction 50-250 microns of the powdered inoculant of which the pellet is constituted is comprised between 35 and 60%, and the mass proportion of the granulometric fraction below 50 microns is lower than 25%.
    Type: Grant
    Filed: January 10, 2002
    Date of Patent: September 2, 2003
    Assignee: Pechiney Electrometallurgie
    Inventor: Thomas J. Margaria
  • Patent number: 6342088
    Abstract: A granular thermal insulating material comprising rice hull ash, ceramic clay binder, rice bran and an exfoliating agent, and methods to produce the insulating material.
    Type: Grant
    Filed: September 24, 1999
    Date of Patent: January 29, 2002
    Assignee: Ricegrower's Cooperative Limited
    Inventors: Peter Waldemar Klatt, Mark William Townsend
  • Patent number: 6328781
    Abstract: A method of making a powder for covering an ingot mold for the continuous casting of steel, in particular steels with ultra-low carbon content. The powder comprises a base powder and particles of at least one metal nitride, its free carbon content being between 0 and 1% by weight, the method comprising forming a slip of raw materials for the basis powder, at least one metal nitride and water and atomizing the slip to form a mist and drying the mist to form granules having diameters lying between 20 &mgr;m and 800 &mgr;m.
    Type: Grant
    Filed: October 13, 1998
    Date of Patent: December 11, 2001
    Assignees: Sollac, Denain Anzin Metallurgie (D.A. Met)
    Inventors: Bernard Debiesme, Jean-Paul Radot, Denis Coulombet, Claude Lefebvre, Jean-Noël Pontoire, Yves Roux, Corinne Damerval
  • Patent number: 6238633
    Abstract: A non-metallic product (NMP) substantially free of metallic aluminum and aluminum nitride which is utilized for making calcium aluminate.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: May 29, 2001
    Assignee: Aluminum Waste Technology, Inc.
    Inventors: John W. Pickens, Edward L. Morris
  • Patent number: 6179895
    Abstract: The tundish flux composition of the invention employs solid recycled ladle metallurgy furnace (LMF) slag as a fluidizing and refining base ingredient in a mixture of raw materials. The preferred recycled LMF slag material comprises about 35% to about 65% CaO, about 10% to about 35% Al2O3, about 1% to about 10% SiO2, about 3% to about 15% MgO, about 0.3% to about 10% FeO, about 0.1% to about 5% MnO, about 0.1% to about 0.15% P2O5, and about 0.1% to about 0.5% S. The tundish flux composition comprises from about 10% to about 80% of recycled LMF slag with the balance being raw materials selected from a calcium oxide source, a fluorine source, a magnesium oxide source, a carbon source, a silica source, a sodium source, a potassium source, and mixtures of these raw materials.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: January 30, 2001
    Assignee: Performix Technologies, Ltd.
    Inventor: Bruce J. Barker
  • Patent number: 6171361
    Abstract: A glass composition which is lithium-free and which is suitable as a metallurgical mold powder includes, based on total weight of the glass composition: Oxide wt % Na2O  0.2-14.4 K2O 0.0-2.5 CaO 31.0-41.9 Al2O3 4.9-8.5 B2O3 0.00-1.9  SiO2 15.6-30.0 F 18.1-30.8 wherein the glass composition has a total content of Na2O+K2O+CaO which ranges from about 38.4 to about 52.6% so that the glass composition is lithium-free and suitable as a metallurgical mold powder.
    Type: Grant
    Filed: May 7, 1996
    Date of Patent: January 9, 2001
    Assignee: PEMCO Corporation
    Inventors: Dechun Fu, Manfred Beck
  • Patent number: 6106589
    Abstract: An agent for treating metal ions in an aqueous solution, which comprises an anthrahydroquinone compound and a metal supported on a carbonaceous carrier.
    Type: Grant
    Filed: August 12, 1997
    Date of Patent: August 22, 2000
    Assignees: Kawasaki Kasei Chemicals Ltd., N.E. Chemcat Corporation
    Inventors: Suehide Hirata, Koji Kusabe, Hiroshi Nakamura, Kikuo Fujiwara
  • Patent number: 5993508
    Abstract: Silicon-containing residues, as they accumulate especially during the synthesis of organosilanes out of metallic silicon, and especially methyl chloride, are processed according to the invention to briquettes, being additives for the quality adjustment of cast iron being produced in a cupola furnace in order to avoid either costly regeneration for the recovering of the valuable components or the total dumping of said silicon-containing residues. Besides the silicon-containing residue the briquettes contain 1-10 percent by weight of cardboard fiber, 5-40 percent by weight of hydraulic cement and 0-20 percent by weight of additional additives having influence on the quality of the cast iron. The cement- and cardboard fiber-containing briquettes are mechanically and thermally sufficiently stable with respect to the operation of the melting furnace. The yielding rate of the inserted small-sized silicon in the cast iron is about 85% and reaches thereby the same range of lumpy ferrosilicon.
    Type: Grant
    Filed: January 23, 1997
    Date of Patent: November 30, 1999
    Assignee: Elkem ASA
    Inventor: Lutz Stephan
  • Patent number: 5954857
    Abstract: Briquettes of either technical or chemical grade molybdenum oxide and a binding material selected from the group consisting of (a) sodium hydroxide, and (b) a binding composition comprising (i) at least one of ammonium and an alkali metal hydroxide, and (ii) an inert filler that has a d.sub.80 particle size at least about the same d.sub.80 particle size of the molybdenum oxide exhibit excellent resistance to breakage and dusting.
    Type: Grant
    Filed: June 11, 1997
    Date of Patent: September 21, 1999
    Assignee: Kennecott Holdings Corporation
    Inventor: Frederick A. Rudloff
  • Patent number: 5944914
    Abstract: The invention relates to an aluminothermic mixture consisting of a finely particulate base portion of iron oxides and aluminum as well as metallic additives, wherein a master alloy, namely a ferrochromium alloy consisting of (in % by weight)C: 0.1 to 20Si: 2 to 40Cr: 5 to 80and iron with impurities resulting from manufacture and, if appropriate, other alloying elements, is added in a quantity of from 5 to 50% by weight, relative to the base portion, as metallic additive.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: August 31, 1999
    Assignee: Elektro-Thermit GmbH
    Inventors: Georg Frommeyer, Michael Kulse, Gerhardus Mulder, Michael Steinhorst
  • Patent number: 5876482
    Abstract: A powder for covering an ingot mold for the continuous casting of steel, in particular steels with ultra-low carbon content. The powder comprises a base powder and particles of at least one metal nitride, its free carbon content (%C.sub.free) being between 0 and 1% by weight, it being produced by atomization, and having the form of granules of between 20 and 800 .mu.m in diameter. In one application of the invention, the nitride is silicon nitride, and its weight content (%Si.sub.3 N.sub.4) is equal to: %Si.sub.3 N.sub.4 =0.5-0.28.times.%C.sub.free .+-.0.10.
    Type: Grant
    Filed: September 20, 1996
    Date of Patent: March 2, 1999
    Assignee: Sollac and Denain-Anzin Mineraux
    Inventors: Bernard Debiesme, Jean-Paul Radot, Denis Coulombet, Claude Lefebvre, Jean-Noel Pontoire, Yves Roux, Corinne Damerval
  • Patent number: 5873924
    Abstract: A desulfurization composition contains from about 3% to about 20% particulate metallic aluminum, about 5% to about 30% particulate alumina, about 0.5% to about 12% particulate hydrocarbon material or other gas generating composition and the balance lime plus impurities. Preferably aluminum dross is the source of aluminum and alumina. The desulfurization composition is injected into molten iron from a blast furnace preferably in an amount of 4 to 20 pounds desulfurizer per ton of hot metal. The desulfurizing composition can be injected as a blend or co-injected into the hot metal through a lance using a carrier gas or dumped into the hot metal as it is being poured into the ladle. At least for torpedo ladles, the desulfurization composition can be placed in the ladle before the hot metal is poured into it.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: February 23, 1999
    Assignees: Reactive Metals & Alloys Corporation, USX Corporation
    Inventors: Brian Mark Kinsman, Leon A. Luyckx, James H. Young, Jr., Robert V. Branion, Jr.
  • Patent number: 5853622
    Abstract: An inventive method for electrical and thermal electronic component attachment is disclosed. The combination of transient liquid phase sintering (TLPS) and a permanent adhesive flux binder provides the advantages of both conventional soldering technology and conductive adhesives. This hybrid approach delivers electrical and thermal conduction through sintered metal joints and mechanical properties based on a tailorable polymer matrix. These transient liquid phase sintering conductive adhesives can utilize conventional dispensing, placement, and processing equipment. During the reflow process, metal powders in the composition undergo interparticle sintering as well as alloying to the contact pads. This process produces a strong mechanical, thermal, and electrical interconnect which ensures good conductivity that is also resistant to humidity and temperature cycling.
    Type: Grant
    Filed: August 28, 1996
    Date of Patent: December 29, 1998
    Assignee: Ormet Corporation
    Inventors: Catherine Gallagher, Goran Matijasevic, M. Albert Capote
  • Patent number: 5851262
    Abstract: A molten metal is subjected to a refining under a reduced pressure of vacuum or a low oxygen partial pressure atmosphere, and subsequently heated by means of inert gas plasma to re-refine. The metals to be processed are stainless steels, Ni-base alloys, Fe--Ni system alloys, electromagnetic steels, medium carbon structural steels having low nitrogen and low sulfur, and high carbon alloy tool-steels whose carbon, oxygen and/or sulfur content is strictly limited. In re-refining, any one of CaO and CaF.sub.2, CaO and Al.sub.2 O.sub.3, and CaO, CaF.sub.2 and Al.sub.2 O.sub.3 is used. For example, an Fe--Ni system alloy having 0.01% carbon and sulfur 0.005% can be produced.
    Type: Grant
    Filed: July 24, 1996
    Date of Patent: December 22, 1998
    Assignee: Hitachi Metals, Ltd.
    Inventor: Takashi Mukai
  • Patent number: 5762722
    Abstract: The present invention relates to a highly efficient aluminum covering flux and a process for its preparation. The said covering flux comprises potassium chloride, sodium chloride, lithium chloride, potassium fluoride and sodium hydrosulfate, wherein the composition of the mentioned covering flux is: potassium chloride, 20-65 parts by weight; sodium chloride, 20-65 parts by weight; lithium chloride, 1-20 parts by weight; potassium fluoride, 0.3-5 parts by weight, sodium hydrosulfate, 0.2-3 parts by weight. The said covering flux can effectively prevent the oxidization of aluminum in the process of smelting aluminum and can increase the yield of aluminum.
    Type: Grant
    Filed: October 28, 1996
    Date of Patent: June 9, 1998
    Inventor: Zongiiang Zhang
  • Patent number: 5582791
    Abstract: The present invention relates to a method for grain refining of aluminium and aluminium alloys wherein a siliconboron alloy containing between 0.01 to 4.0 % by weight of boron is added to molten aluminium or aluminium alloy in such an amount that the resulting melt of aluminium or aluminium alloy contains at least 50 ppm boron. The invention further relates to a grain refining alloy for aluminium and aluminium alloys which grain refining alloy is a siliconboron alloy containing between 0.01 and 4.0 % by weight of boron.
    Type: Grant
    Filed: January 9, 1995
    Date of Patent: December 10, 1996
    Assignee: Elkem Aluminum ANS
    Inventors: Lars Arnberg, Gunnar Halvorsen, Per Arne T.o slashed.ndel
  • Patent number: 5407459
    Abstract: The present invention is concerned with a process for the preparation of sintered calcium aluminates that can generally be used as a protective cover for liquid metals, and particularly steel, and the process comprising the steps of mixing calcium oxide, or its precursor, particles and aluminum dross residue, such as NOVAL.TM.; calcining the resulting mixture; maintaining a calcining temperature of 1200.degree. C. or higher for approximately 5 minutes or more which is sufficient to form a friable sintered product rich in calcium aluminates; and recovering the sintered product after cooling. Optionally, calcium fluoride, or other fluoride can be added to the starting mixture, if it is not already contained in the dross residue.
    Type: Grant
    Filed: September 23, 1993
    Date of Patent: April 18, 1995
    Assignees: Alcan International Limited, Les Sables Olimag Inc.
    Inventors: Raymond Breault, Sylvain P. Tremblay, Yvan Huard, Gilles Mathieu
  • Patent number: 5397379
    Abstract: A process of refining steel in a ladle using solid granules or briquettes made from recycled LMF slag and raw materials to make a desulfurizing addition, a slag conditioner or synthetic refining slag is described. The preferred recycled LMF slag material generally comprises of 35% to about 65% CaO; 10% to about 35% Al.sub.2 O.sub.3 ; 1% to about 10% SiO.sub.2 ; 3% to about 15% MgO; 0.3% to about 10% FeO; 0.1% to about 5% MnO; 0% to about 0.5% P.sub.2 O.sub.5 ; and 0.1% to about 0.5% S. The ladle refining additive comprises from about 10% to about 90% of a recycled ladle metallurgy furnace slag and the balance of raw materials selected from the group consisting of: a calcium oxide source; soda ash; fluorspar; borax; calcium carbonate; aluminum source; calcium aluminate; alumina source; metallic calcium, magnesium, sodium and their oxides, fluorides and carbides; and mixtures of all of the foregoing.
    Type: Grant
    Filed: September 22, 1993
    Date of Patent: March 14, 1995
    Assignee: Oglebay Norton Company
    Inventors: Bruce J. Barker, William C. Weber, William J. West