Containing Iron(fe) Compound Patents (Class 75/319)
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Patent number: 11932914Abstract: A process for manufacturing a slag conditioning agent for steel desulfurization is shown in which a dried slag material Obtained from a secondary steelmaking process is mixed with quicklime particles. The quicklime particles react with moisture in the slag material to dry the slag material and produce a blend of slag material, hydrated lime and any unreacted quicklime. The blend is then sieved to separate out the hydrated lime. The retained dried fraction after sieving is then mixed with an Al2O3 mass fraction from which the slag conditioning agent can be collected. The slag conditioning agent has an equivalent mass ratio which is between 0.55 and 1.5.Type: GrantFiled: December 17, 2019Date of Patent: March 19, 2024Assignee: S.A. LHOIST RECHERCHE ET DEVELOPPEMENTInventors: Eric Perrin, Souliyann Chunlamani
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Patent number: 11549160Abstract: A method for controlling pellet quality in iron ore production includes the steps of mixing water, binder and iron ore particles in at least one mixer to form a mixture (step (i)) and pelletizing the mixture into green pellets (step (ii)). Between step (i) and step (ii), a part of the mixture is taken in a sampling operation, formed into a test specimen and subjected to a test.Type: GrantFiled: November 6, 2018Date of Patent: January 10, 2023Assignee: METSO OUTOTEC FINLAND OYInventors: Sebastian Lang, Karl Semiller, Suvi Rannantie
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Patent number: 11530464Abstract: Disclosed herein are methods and compositions for producing composite pellets comprising a core comprising: iron ore and a carbonaceous reducing agent; and a shell comprising: iron ore; and having a core and shell transition in a manner such that no visible boundary exists between the core and the shell in a cross-section of the pellet. The methods can be used to produce composite pellets with improved productivity and quality, and the resulting composite pellets can be used to produce direct reduced iron (DRI).Type: GrantFiled: April 18, 2016Date of Patent: December 20, 2022Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Mohamed Bahgat Saddik, Hesham Ahmed Hanafy
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Patent number: 10626053Abstract: A method for recovering valuable metals and simultaneously preparing ceramsite by roasting cyanide tailing belongs to the area of comprehensive recovery and high value utilization of metallurgical waste residue. In this method, cyanide tailings, bentonite, calcium chloride, coal powder and albite are mixed by ball milling according to certain weight ratio to get a mixture. After drying and roasting twice, dust is collected from the roasted ash, the obtained polymetallic ash is collected and treated. The secondary calcined material is cooled to obtain ceramsite. The invention volatilizes and recovers the valuable metal in the roasting and sintering process of cyanide tailings and directly prepares the ceramsite through reasonable batching, which achieves the effect of recycling cyanide tailings and high-value utilization, can create good economic and environmental benefits, and has significant effect of energy saving and consumption reduction.Type: GrantFiled: May 28, 2018Date of Patent: April 21, 2020Assignee: BEIJING UNIVERSITY OF TECHNOLOGYInventors: Yufeng Wu, Dean Pan, Xudong Sun, Tieyong Zuo
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Patent number: 9027399Abstract: A quartz glass liquid level sensor includes a support frame, a light masking plate, a quartz glass tube, and a sensor module. The light masking plate is movably mounted on the support frame. The quartz glass tube is movably mounted to the support frame. One end of the quartz glass tube is securely fixed to the light masking plate. The sensor module is mounted on the support frame, for sensing a position of the light masking plate relative to the support frame.Type: GrantFiled: January 30, 2013Date of Patent: May 12, 2015Assignees: Hong Fu Jin Precision Industry (ShenZhen) Co., Ltd., Hon Hai Precision Industry Co., Ltd.Inventors: Tian-Feng Huang, Wen-Li Wang, Hao-Chung Lee
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Patent number: 8871002Abstract: The invention provides a technological method for preparing sponge titanium from sodium fluotitanate raw material, comprising the following steps: step A: placing aluminum in an airtight resistance furnace, evacuating, introducing inert gas into the resistance furnace, and heating the aluminum to obtain molten aluminum; step B: opening a reactor cover, adding a proper amount of sodium fluotitanate into the reactor, closing the reactor cover, detecting leakage, slowly heating the reactor to 150° C., evacuating and continuously heating the reactor to 250° C.; step C: introducing inert gas into the reactor, continuously heating the reactor to 900° C., and stirring uniformly; step D: opening a valve, adjusting the stirring speed, dripping the molten aluminum, and controlling the temperature of reaction in a range from 900 to 1000° C.; and step E: opening the reactor cover, removing a stirring device out of the reactor, and eliminating NaAlF4 at upper layer to obtain sponge titanium.Type: GrantFiled: August 14, 2012Date of Patent: October 28, 2014Assignee: Shenzhen Sunxing Light Alloys Materials Co., Ltd.Inventors: Xuemin Chen, Jun Yang, Zhi Zhou
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Publication number: 20140190310Abstract: The instant invention relates to a binder composition for pelletization of fine mineral particles comprising a) at least one colloid agent which exerts a cohesive force on the mineral particles forming the pellets, and b) at least one synthetic polymer which disperses mineral particles evenly in the pellets.Type: ApplicationFiled: July 3, 2012Publication date: July 10, 2014Applicants: CLARIANT S.A., CLARIANT FINANCE (BVI) LIMITEDInventors: Carlos Augusto Blasques Tooge, Nilson Mar Bartalini, Almir T. Santos, Wagner Claudio Da Silva, Monica Speck Cassola, Jorge Antonio Arias Medina
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Publication number: 20140165784Abstract: The invention relates to a process for producing an iron- and/or tungsten containing powder or powder agglomerate including the steps of: a) mixing at least a first powder fraction comprising a tungsten carbide containing powder, and at least a second powder fraction comprising an iron oxide powder and/or a tungsten oxide containing powder and optionally an iron powder, the weight of the first fraction being in the range of 50-90% by weight of the mix and the weight of the second fraction being in the range of 10-50% by weight of the mix, b) heating the mix of step a) to a temperature in the range of 400-1300° C., preferably 1000-1200° C. The invention also relates to an iron- and/or tungsten containing powder or powder agglomerate.Type: ApplicationFiled: February 10, 2014Publication date: June 19, 2014Applicant: MINPRO AKTIEBOLAGInventor: Johan Arvidsson
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Patent number: 8603215Abstract: A desulfurizer containing at least a composition of a highly concentrated amorphous iron oxide hydroxide as the active ingredient. A method for preparing a composition containing at least a highly concentrated amorphous iron oxide hydroxide. A method for regenerating the desulfurizer. The desulfurizer contains at least the composition of a highly concentrated amorphous iron oxide hydroxide as the active ingredient and a binder. The composition and the desulfurizer have a high sulfur capacity and can be regenerated. This saves resources and reduces environmental pollution. The method for regenerating the desulfurizer includes at least the following steps: a) mixing a solid soluble ferrous salt with a solid hydroxide, b) kneading the mixture and allowing it to react at temperatures not exceeding 90° C., c) drying in air, d) washing with water and filtering to yield a solid, and e) drying naturally or roasting the solid.Type: GrantFiled: April 29, 2010Date of Patent: December 10, 2013Assignee: Beijing Sanju Environmental Protection and New Material Co., Ltd.Inventors: Zhenyi Liu, Xiangsheng Wang
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Publication number: 20130192421Abstract: The invention relates to a method of agglomerating iron oxide-containing residual substances, in particular scale and mill scale, wherein the residual materials and the paper sludge are dried and comminuted and agglomerates are produced by means of hot briquetting from the mixture comprising the residual substances and the paper sludge. In this way, mill scale briquettes of high strength and density can be produced which in steelmaking processes can then be charged into an electric arc furnace for the purpose of recycling the iron contained in the residual substances.Type: ApplicationFiled: July 2, 2011Publication date: August 1, 2013Applicant: RHM Rohstoff-Handelsgesellschaft mbHInventors: Udo Meynerts, Seulo Henrique Seabra Da Rocha, Michael Maurer
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Publication number: 20130032005Abstract: A method for producing compacts containing iron oxide from undersized oxidic iron carriers may include producing a mixture which comprises undersized oxidic iron carriers, bentonite as a binder and water, pressing the mixture and hardening the green compacts obtained by the pressing, as well as to the compacts produced by the method and to the use of the compacts as lump iron carriers. The mixture may be subjected to a kneading process lasting at least 3 minutes and up to 30 minutes, prior to the pressing. The compacts may thus be produced without a maturing process.Type: ApplicationFiled: March 21, 2011Publication date: February 7, 2013Inventors: Christian Boehm, Hado Heckmann
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Publication number: 20100300246Abstract: A method for producing a substantially metallic iron-containing product from iron oxide. The metallic iron produced according to the invention is non-pyrophoric and may be safely shipped and handled without additional process steps. The method of the invention is simple, economical, and produces high quality metallic product which may be used as a feed for Electric Arc Furnace (EAF), Blast Furnaces and Cupolas among other applications.Type: ApplicationFiled: May 24, 2010Publication date: December 2, 2010Inventors: James L. Coburn, John L. Sullivan
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Publication number: 20080047395Abstract: The present invention discloses a composition for a desulfurizer with a high sulfur capacity and a process for making the same. The composition comprises the active components of three kinds of iron oxides and is used in the desulfurizer to remove hydrogen sulfide from the gaseous and liquid state feed stocks. The above-mentioned composition comprises cubic ferroferric oxide in the form of crystalline phase (Fe3O4), amorphous ferric oxide (Fe2O3) and amorphous ferric oxide monohydrate (Fe2O3.H2O). The composition has a sulfur capacity of at least 40%.Type: ApplicationFiled: May 24, 2007Publication date: February 28, 2008Inventors: Zhenyi Liu, Ke Lin, Jie Zhang, Fengren Liu, Yongsheng Yu
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Patent number: 6918944Abstract: A nonfired agglomerated ore which is satisfactory in reduction property in the shaft of a blast furnace and excellent in rapid heating bursting property and a production method thereof are provided. A carbon containing nonfired agglomerated ore for blast furnace which is prepared in such a way that iron oxide and a carbonaceous material are blended with each other to prepare a mixture, a binder is added to the mixture, and the mixture is kneaded, formed, and cured, wherein the agglomerated ore contains carbon in the content of 80 to 120% of the theoretical carbon quantity required to reduce the reducible oxygen in the iron ores to form metallic iron, and the binder is selected so that the crushing strength may be 7,850 kN/m2 or more at room temperature.Type: GrantFiled: May 28, 2003Date of Patent: July 19, 2005Assignees: Tetsugen Corporation, Nippon Steel CorporationInventors: Hideo Kanoshima, Seita Uekawa, Koji Morimoto, Shinichi Matsunaga, Masaaki Naito
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Publication number: 20040201140Abstract: The present invention provides a reducing furnace of the rotary hearth-type and a method for reducing a metal oxide simplified in the process from dehydration to molding, according to which a moisture-rich powdery raw material is reduced at low cost. The present invention also provides an operation method whereby dusts or sludge generated in the refining or processing of metal are economically recycled.Type: ApplicationFiled: April 30, 2004Publication date: October 14, 2004Inventors: Tetsuharu Ibaraki, Takashi Hiromatsu, Satoshi Kondo, Shoji Imura, Yoichi Abe
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Patent number: 6786949Abstract: Self-reducing agglomerates are provided for use in the production of metal. The agglomerates comprise a mixture of iron oxide containing particles and particles of a reducing agent bonded by use of a pre-gel. The agglomerates are produced by a method and apparatus that provides for mixing and curing thereof. The agglomerates may then be used for reduction thereof for the production of iron.Type: GrantFiled: March 20, 2001Date of Patent: September 7, 2004Assignee: Startec Iron, LLCInventor: Edmar Saul Marcheze
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Patent number: 6682583Abstract: Provided is a process for producing sintered ore in which a small amount of a water-soluble compound (a sintering aid) is added to iron ore powder and, thereby, which product shows improved strength and no adverse influence as an ironmaking raw material either without any increase in content of an auxiliary material (CaO) serving as a binder. In production of sintered ore, an aqueous solution is added to iron ore powder and an auxiliary material, the iron ore powder and the auxiliary material are kneaded to form a mixture, and the mixture is granulated to form granules, wherein the aqueous solution contains a water-soluble compound reacting with the iron ore powder to form a reaction product having a melting point of 1200° C. or lower.Type: GrantFiled: May 17, 2000Date of Patent: January 27, 2004Assignee: Kabushiki Kaisha Kobe Seiko ShoInventors: Kouichi Morioka, Toshihide Matsumura, Jyunpei Kiguchi
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Patent number: 6605130Abstract: Pellets incorporated with a carbonaceous material of the present invention contain a carbonaceous material and iron ore mainly composed of iron oxide. The maximum fluidity of the carbonaceous material in softening and melting, and the ratio of iron oxide particles of 10 &mgr;m or smaller in the iron ore are within the range above a line which connects in turn points A, B and C shown in FIG. 1, including the line. This permits the production of pellets incorporated with a carbonaceous material having excellent thermal conductivity and high strength. Reduction of the pellets incorporated with a carbonaceous material produces reduced iron having high strength after reduction and a low fines ratio with improved productivity.Type: GrantFiled: November 15, 2001Date of Patent: August 12, 2003Assignee: Kobe Steel, Ltd.Inventors: Yoshimichi Takenaka, Shoji Shirouchi, Masakata Shimizu, Kazuya Miyagawa
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Publication number: 20020170388Abstract: Self-reducing agglomerates are provided for use in the production of metal. The agglomerates comprise a mixture of iron oxide containing particles and particles of a reducing agent bonded by use of a pre-gel. The agglomerates are produced by a method and apparatus that provides for mixing and curing thereof. The agglomerates may then be used for reduction thereof for the production of iron.Type: ApplicationFiled: March 20, 2001Publication date: November 21, 2002Inventor: Edmar Saul Marcheze
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Patent number: 6451083Abstract: Metal baghouse dust can be solidified and thereby used for a variety of different purposes including a binder material by blending the electric arc furnace dust with a reducing agent such as ferrous chloride or ferrous sulphate. This forms a solidified mass which has excellent hardness and high temperature strength enabling it to be directly added to molten metal. Particles coated with hardened metal baghouse dust can be used in the Midrix process or can be used to add carbon to molten metal. This is an excellent way to dispose of waste metal baghouse dust.Type: GrantFiled: June 9, 2000Date of Patent: September 17, 2002Inventor: Robert Kevin Twilley
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Patent number: 6428599Abstract: Electric arc furnace production of recycled steel is plagued by the formation of an iron-depleted, metal-rich electric arc flue dust (EAFD). In the present invention, we recover at least about 85 wt. % of the base metals in the EAFD (i.e., lead, cadmium, copper, and zinc) as high quality metals products without producing any solid, liquid, of gaseous wastes. We use a recyclable calcium chloride/hydrochloric acid leach mill solution to extract the base metals from the EAFD in a reactor under a controlled pH of about 2.6 at an elevated temperature and pressure in an oxygen environment wherein the solids content in the reaction slurry is about 15-30 wt. %. In this way, we place the base metals in solution while leaving the iron as a solid hematite iron complex. When separated from the metal-rich solution, the solid hematite iron complex is recycled to the electric arc furnace. The base metals are precipitated and recovered.Type: GrantFiled: May 8, 1997Date of Patent: August 6, 2002Inventor: Joseph B. Cashman
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Patent number: 6391086Abstract: The present invention refers to a method for using electric steel plant slag, ground and/or in particles of less than 6 mm, in self-reducing agglomerates, in the form of pellets or briquettes, as a fluxing material and as a secondary source of iron, in sufficient amounts to adjust the binary basicity of the final slag (ratio of CaO/SiO2) of the reduction/melting process to values equal or greater than 1.1. This application enables a reject that is difficult to discard to be transformed into a secondary source of iron and a final slag having adequate characteristics to be used in the concrete and asphalt paving industries.Type: GrantFiled: March 20, 2001Date of Patent: May 21, 2002Assignee: Northstar Steel Co.Inventors: Marcos de Albuquerque Contrucci, Edmar Saul Marcheze
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Patent number: 6342089Abstract: A method for producing the direct reduced iron pellets. The method includes pelletizing, iron oxide-containing material, internal reductant and binder to form green pellets. The binder includes a non-combustible fibrous material. The method also includes firing the green pellets to convert the green pellets into direct reduced iron pellets.Type: GrantFiled: December 6, 1999Date of Patent: January 29, 2002Inventor: John R. McGaa
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Patent number: 6334883Abstract: Pellets incorporated with a carbonaceous material of the present invention contain a carbonaceous material and iron ore mainly composed of iron oxide. The maximum fluidity of the carbonaceous material in softening and melting, and the ratio of iron oxide particles of 10 &mgr;m or smaller in the iron ore are within the range above a line which connects in turn points A, B and C shown in FIG. 1, including the line. This permits the production of pellets incorporated with a carbonaceous material having excellent thermal conductivity and high strength. Reduction of the pellets incorporated with a carbonaceous material produces reduced iron having high strength after reduction and a low fines ratio with improved productivity.Type: GrantFiled: November 22, 1999Date of Patent: January 1, 2002Assignee: Kobe Steel, Ltd.Inventors: Yoshimichi Takenaka, Shoji Shirouchi, Masakata Shimizu, Kazuya Miyagawa
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Patent number: 6258150Abstract: An iron based product having at least a sufficient total ferrous content by weight to render the product commercially feasible wherein the product is derived by a process comprising the beneficiation of kish slag waste material having a relatively low ferrous material content before beneficiation. The resulting iron based product has a total ferrous content of substantially 90% by weight thereby making it both practical and economical for the reintroduction into iron and/or steel making processes utilizing an injection method or by briquetting at at least a portion of the resulting product. The beneficiation process involves the heating of the waste material to an extent at least sufficient for drying, separating the high sulphur slag from a remainder of the waste material and subsequently classifying the remainder of the waste material, once separated from the high sulphur slag by particle size.Type: GrantFiled: March 24, 1998Date of Patent: July 10, 2001Inventor: William James MacKellar
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Patent number: 6179895Abstract: The tundish flux composition of the invention employs solid recycled ladle metallurgy furnace (LMF) slag as a fluidizing and refining base ingredient in a mixture of raw materials. The preferred recycled LMF slag material comprises about 35% to about 65% CaO, about 10% to about 35% Al2O3, about 1% to about 10% SiO2, about 3% to about 15% MgO, about 0.3% to about 10% FeO, about 0.1% to about 5% MnO, about 0.1% to about 0.15% P2O5, and about 0.1% to about 0.5% S. The tundish flux composition comprises from about 10% to about 80% of recycled LMF slag with the balance being raw materials selected from a calcium oxide source, a fluorine source, a magnesium oxide source, a carbon source, a silica source, a sodium source, a potassium source, and mixtures of these raw materials.Type: GrantFiled: December 11, 1996Date of Patent: January 30, 2001Assignee: Performix Technologies, Ltd.Inventor: Bruce J. Barker
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Patent number: 5851262Abstract: A molten metal is subjected to a refining under a reduced pressure of vacuum or a low oxygen partial pressure atmosphere, and subsequently heated by means of inert gas plasma to re-refine. The metals to be processed are stainless steels, Ni-base alloys, Fe--Ni system alloys, electromagnetic steels, medium carbon structural steels having low nitrogen and low sulfur, and high carbon alloy tool-steels whose carbon, oxygen and/or sulfur content is strictly limited. In re-refining, any one of CaO and CaF.sub.2, CaO and Al.sub.2 O.sub.3, and CaO, CaF.sub.2 and Al.sub.2 O.sub.3 is used. For example, an Fe--Ni system alloy having 0.01% carbon and sulfur 0.005% can be produced.Type: GrantFiled: July 24, 1996Date of Patent: December 22, 1998Assignee: Hitachi Metals, Ltd.Inventor: Takashi Mukai
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Patent number: 5681367Abstract: A method for preparing iron bearing green pellets that can be processed in a rotary hearth furnace without degradation and become self-fluxing sponge iron pellets when charged to a submerged arc furnace operating at a lower temperature than the rotary hearth furnace, to produce hot metal having a carbon content from 1% to about 5%.Type: GrantFiled: June 20, 1996Date of Patent: October 28, 1997Assignee: USX Engineers & Consultants, Inc.Inventor: Phillip B. Hunter
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Patent number: 5607780Abstract: Disclosed are a target material for magneto-optical recording medium having a structure formed by sintering of an RE-TM phase (A) having a composition with an RE content higher than that of the composition of an intermetallic compound represented by the chemical formula TM.sub.2 RE, and a TM-RE phase (B) having a composition with an RE content equal to or lower than that of the composition of an intermetallic compound represented by the chemical formula TM.sub.2 E, wherein RE denotes at least one rare earth element selected from the group of elements consisting of Nd, Gd, Tb, Dy, Ho and Er, and TM denotes at least one element selected from the group of metals of the iron group which consists of Fe, Co and Ni; and a process for producing the same.Type: GrantFiled: May 20, 1994Date of Patent: March 4, 1997Assignee: Hitachi Metals, Ltd.Inventors: Kaoru Masuda, Takashi Meguro
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Patent number: 5573576Abstract: A method of treating steel mill waste containing iron oxides and silica includes reacting the steel mill waste with an alkali aqueous solution in an amount sufficient to raise the pH to at least about 7 to solubilize silica to form soluble silicate compounds and silica gels and thereby produce a chemically reactive mixture. The mixture is reacted with an alkaline silicic compound to produce a solid, stable, non-polluting material.Type: GrantFiled: June 26, 1995Date of Patent: November 12, 1996Assignee: International Solidification, Inc.Inventor: David Krofchak
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Patent number: 5439505Abstract: Steel mill waste containing iron, iron oxides and polluting compounds are treated with a strong alkali to raise the Ph to 14 to allow more alkali to solubilize silica. The mixture of materials and silica gels is then reacted with alkaline silicic compounds and allowed to cure and form hard sedimentary rock-like materials, solidified into a non-polluting solid which can be recycled in a steel-making furnace to produce iron and non-polluting slag.Type: GrantFiled: October 24, 1994Date of Patent: August 8, 1995Inventor: David Krofchak
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Patent number: 5397379Abstract: A process of refining steel in a ladle using solid granules or briquettes made from recycled LMF slag and raw materials to make a desulfurizing addition, a slag conditioner or synthetic refining slag is described. The preferred recycled LMF slag material generally comprises of 35% to about 65% CaO; 10% to about 35% Al.sub.2 O.sub.3 ; 1% to about 10% SiO.sub.2 ; 3% to about 15% MgO; 0.3% to about 10% FeO; 0.1% to about 5% MnO; 0% to about 0.5% P.sub.2 O.sub.5 ; and 0.1% to about 0.5% S. The ladle refining additive comprises from about 10% to about 90% of a recycled ladle metallurgy furnace slag and the balance of raw materials selected from the group consisting of: a calcium oxide source; soda ash; fluorspar; borax; calcium carbonate; aluminum source; calcium aluminate; alumina source; metallic calcium, magnesium, sodium and their oxides, fluorides and carbides; and mixtures of all of the foregoing.Type: GrantFiled: September 22, 1993Date of Patent: March 14, 1995Assignee: Oglebay Norton CompanyInventors: Bruce J. Barker, William C. Weber, William J. West