Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers. MOFs having ambient condition stability may comprise a plurality of metal clusters comprising one or more M4O clusters (M is a metal), and a plurality of 4-pyrazolecarboxylate ligands coordinated to the plurality of metal clusters to define an at least partially crystalline network structure having a plurality of internal pores. The MOFs may have a Pa3 symmetry, which upon activation may convert into Fm3m symmetry.

Abstract: A method and associated apparatus for disinfecting at least one banknote, each banknote including a substrate, visual data, and a security feature, including disposing the at least one banknote in an oxygen-free environment, and exposing the at least one banknote to a temperature and for a duration sufficient to disinfect the at least one banknote and not compromise the security feature and the visual data, where to disinfect the at least one banknote includes to significantly deactivate, kill, or eliminate one or more pathogens from the at least one banknote.

Abstract: An apparatus and method for nitrogen production from compressed air. The apparatus is a portable compact unit including a compressed air input, a nitrogen generator configured to receive compressed air from a compressor through the compressed air input, a nitrogen storage vessel configured to store pressurized nitrogen, and a compressor failure monitor disposed between the compressed air input and the nitrogen generator. The compressor failure monitor can be in combination with an air dryer device, wherein the compressor failure monitor is configured to monitor a change in air pressure and/or air temperature at or from the air dryer, which can indicate compressor issues.

Abstract: A unit for purifying a gas mixture by adsorption, including at least one adsorber having at least one cluster of N identical adsorbent modules operating in parallel, where N?2, each cluster of N adsorbent modules includes a common inlet manifold having a straight inlet duct of axis Xe supplying N inlet nozzles Tei, where i ranges from 1 to N, respectively connected to the inlets Ei, where i ranges from 1 to N, of the N modules of the cluster, a common outlet manifold having a straight outlet duct of axis Xs collecting the flow leaving the N outlet nozzles Tsi, where i ranges from 1 to N, respectively connected to the outlets Si, where i ranges from 1, of the N modules of the cluster.

Abstract: A portable oxygen concentrator includes at least one separation mechanism and an oxygen storage tank, where the separation mechanism is connected to the oxygen storage tank and includes an air bag and a molecular sieve tank that is filled with a molecular sieve for adsorption. The air bag has an air inlet and an air outlet. The air bag is connected to the molecular sieve tank through a valve group, which includes a first single valve and a second single valve. The air bag is connected to the molecular sieve tank through the first single valve. Each of the two ends of the molecular sieve tank has at least one gas outlet. When an inner space of the air bag is compressed and expanded once, the molecular sieve in the molecular sieve tank adsorbs and desorbs once.

Abstract: Disclosed in the present invention are a pressure equalizing system for air separation purification, and a control method. The system comprises: a first air main pipe; a pressurizing gas pipeline, which is connected to the first air main pipe and used for receiving a pressurizing gas and delivering same to the first air main pipe; and a control valve, located on the pressurizing gas pipeline, and having a degree of opening regulated by the flow regulator, thereby regulating an air intake amount of the pressurizing gas pipeline.

Abstract: An oxygen concentrator includes one or more adsorbent sieve beds operable to remove nitrogen from air to produce concentrated oxygen gas at respective outlets thereof, a product tank fluidly coupled to the respective outlets of the sieve bed(s), a compressor operable to pressurize ambient air, one or more sieve bed flow paths from the compressor to respective inlets of the sieve bed(s), a bypass flow path from the compressor to the product tank that bypasses the sieve bed(s), and a valve unit operable to selectively allow flow of pressurized ambient air from the compressor along the one or more sieve bed flow paths and along the bypass flow path in response to a control signal. The valve unit may be controlled in response to a command issued by a ventilator based on a calculated or estimated total flow of gas and entrained air or % FiO2 of a patient.

Abstract: The present disclosure describes a system and method for maintaining oxygen purity in portable oxygen concentrators, even with asymmetric generation of oxygen enriched gas volumes from different sieve beds of the concentration system. The present system and method compensate for asymmetric oxygen enriched gas generation using asymmetric delivery of purge volumes. Purge valves are used to deliver the asymmetric purge gas volumes, enables the system to maintain oxygen purity without additional power consumption, even when a portable oxygen concentrator does not include a product tank. The present system and method are configured such that asymmetry in enriched oxygen generation can be monitored and the asymmetric purge gas compensation can be applied independently from other control mechanisms of a portable oxygen concentrator.

Abstract: The invention relates to regenerative, solid sorbent for adsorbing carbon dioxide from a gas mixture, with the sorbent including a modified polyamine and a nano-structured solid support. The modified polyamine is the reaction product of an amine and an aldehyde. The sorbent provides structural integrity, as well as high selectivity and increased capacity for efficiently capturing carbon dioxide from gas mixtures, including the air. The sorbent is regenerative, and can be used through multiple operations of absorption-desorption cycles.

Abstract: Disclosed are a carbon dioxide separating material comprising a polyamine carrier in which a polyamine having at least two isopropyl groups on one or more of the nitrogen atoms is loaded on a support, and a method for separating or recovering carbon dioxide using the carbon dioxide separating material.

Abstract: An air separation unit includes an air inlet with a reversible blower downstream therefrom and an adsorption bed filled with adsorption media downstream of the reversible blower. The adsorption bed contains an adsorption media which preferentially adsorbs nitrogen over oxygen. An oxygen and argon output is located downstream of the absorption bed. At least a portion of the mixed gas of oxygen and argon is routed to a modular argon separator which separates out at least a portion of the argon to provide high purity oxygen to a high purity oxygen outlet. The argon separator can be configured as a molecular sieve filter to separate the argon from the oxygen or the argon separator can be in the form of a gas cooler and condenser which condenses liquid oxygen for storage and discharge as substantially pure oxygen.

Abstract: The present invention generally relates to a method to enhance heat transfer in the temperature swing adsorption process (TSA) and to an intensified TSA process for gas/liquid purification or bulk separation. Helium is designed as the heat carrier media to directly bring heat/cool to the adsorbent bed during the TSA cycling process. With helium's superior heat conductivity, the time consuming regeneration steps (warming, regeneration and precooling) of TSA process can be significantly reduced and allowing for the TSA process to be intensified.

Abstract: Adsorption systems providing a capacity of at least 200 g/L for oxygen-containing mixtures, or an oxygen-nitrogen selectivity of at least 1.4:1 or at least 1:2 with an adsorbed capacity of at least 0.6 mmol/g at 4 bar and 22° C.

Abstract: The present invention relates to a furnace (12) for melting heated glass using burners (13), wherein the combustion energy is at least partially produced by oxy-fuel combustion, and wherein at least a portion of the oxygen used in the burners (13) is produced by separation, on a ceramic separation membrane (18), from a gaseous mixture including oxygen, the oxygen from the separation being directly channeled into at least one burner (13).

Abstract: A method for producing ozone for use in ozonolysis reactions. Oxygen is separated from the mixture of ozone and oxygen from an ozone generation unit and is fed back to the oxygen feed to the generation unit. Nitrogen is fed to the ozone separation unit and the mixture of nitrogen and ozone is fed to the ozonation reactor where the ozone will react with organic compounds to produce desired end products.

Abstract: The invention relates to an increased efficiency high-capacity pressure and/or temperature swing adsorption process comprising: contacting a feedstream at a rate of more than 75 MSCFD with an adsorbent material under conditions sufficient for the adsorbent material to selectively adsorb at least one of the component gases in the feedstream, so as to form a first effluent; and selectively desorbing the adsorbed gas from the adsorption material, so as to form a second effluent The adsorption module can contain rotary valves both on the feed end and on the product end and a rotational member defining a central rotational axis, with the adsorption bed(s) oriented circumferentially thereto. The adsorption bed walls can be angled, the feed end cross-sectional area of the adsorption bed(s) can be larger than the product end, and/or the feed end rotary valve diameter of the module(s) can be larger than the product end.

Abstract: Systems and methods for producing an ozone destructor are disclosed herein. Generally, these systems and methods include an ozone destructor that has a housing defining an air passage duct. In some cases, this air passage duct includes a first chamber and a second chamber that are arranged so that air is able to flow into the first chamber, through the second chamber, and out of the destructor. In some cases, an air drying mechanism is disposed in the first and/or the second chamber. Additionally, in some cases, the ozone destructor further includes multiple mechanisms that reduce ozone to oxygen. In light of these features, the ozone destructor is capable of incrementally drying and reducing air and ozone, respectively, as they pass through the first chamber and the second chamber.

Abstract: The present invention is directed to the prevention of an exothermic reaction in the gas purifier of an ultra-high purity gas system.

Abstract: A method is provided for forming a zeolitic imidazolate framework composition using at least one reactant that is relatively insoluble in the reaction medium. Also provided herein is a material made according to the method, designated either as EMM-19 or as EMM-19*, and a method of using same to adsorb and/or separate gases, such as carbon dioxide.

Abstract: One ozone concentrating chamber is provided therein with a part of a cooling temperature range where ozone can be selectively condensed or an oxygen gas can be selectively removed by transmission from an ozonized oxygen gas, and a part of a temperature range where condensed ozone can be vaporized, and condensed ozone is vaporized by moving condensed ozone with flow of a fluid or by gravitation to the part where condensed ozone can be vaporized, whereby the ozonized oxygen gas can be increased in concentration. Such a constitution is provided that a particle material 13 for condensation and vaporization filled in the ozone concentrating chambers 11 and 12 has a spherical shape of a special shape with multifaceted planes on side surfaces, or an oxygen transmission membrane 130 capable of selectively transmitting an oxygen gas in an ozone gas is provided.

Abstract: The present invention relates to a process for removing at least one component selected from the group consisting of oxygen, nitrogen oxides, acetylenes and dienes from a gas mixture comprising the at least one component and also hydrogen, one or more olefins which are not dienes and possibly further gas constituents, in which the gas mixture is brought into contact with a catalyst in a reaction zone, wherein the catalyst comprises copper(I) sulfide.

Abstract: A method is provided for forming a zeolitic imidazolate framework composition using at least one reactant that is relatively insoluble in the reaction medium. Also provided herein is a material made according to the method, designated either as EMM-19 or as EMM-19*, and a method of using same to adsorb and/or separate gases, such as carbon dioxide.

Abstract: Methods of absorbing oxygen are disclosed with the use of compositions useful as oxygen absorbers. The compositions are generally salts of unsaturated fatty acids that have one or more carbon to carbon double and or triple bonds. The compositions may be prepared by reacting an unsaturated fatty acid with a hydroxide resulting in a salt of the unsaturated fatty acid. Water soluble compositions are dissolved in aqueous solutions for the purpose of absorbing oxygen from the aqueous solutions and or their containers. Water insoluble compositions are protected from moisture due to their water repellent character and this characteristic is used advantageously in order to absorb oxygen from containers that may contain moisture where it is desired that the compositions remain relatively unaffected by moisture, intact and remain where they are placed.

Abstract: The disclosure provides methods and systems for sequestering and/or reducing sulfur oxides, nitrogen oxides and/or carbon dioxide present in industrial effluent fluid streams. A solid particulate material comprising a slag component, a binder component (distinct from the slag component), and optionally water is formed and then contacted with the effluent fluid stream to reduce at least one of the sulfur oxides, nitrogen oxides, and/or carbon dioxide. The contacting of the effluent stream may occur in a packed bed reactor with the solid dry particulate material. Methods of reducing pollutants from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided.

Abstract: One ozone concentrating chamber is provided therein with a part of a cooling temperature range where ozone can be selectively condensed or an oxygen gas can be selectively removed by transmission from an ozonized oxygen gas, and a part of a temperature range where condensed ozone can be vaporized, and condensed ozone is vaporized by moving condensed ozone with flow of a fluid or by gravitation to the part where condensed ozone can be vaporized, whereby the ozonized oxygen gas can be increased in concentration. Such a constitution is provided that a particle material 13 for condensation and vaporization filled in the ozone concentrating chambers 11 and 12 has a spherical shape of a special shape with multifaceted planes on side surfaces, or an oxygen transmission membrane 130 capable of selectively transmitting an oxygen gas in an ozone gas is provided.

Abstract: An apparatus for producing high-concentration ozone gas has a plurality of adsorption/desorption columns and a plurality of valves capable of switching opening/closing of the passage of gas flowing into or out of the adsorption/desorption columns, such that each of the adsorption/desorption columns can performs ozone adsorption processing, evacuation processing or desorption processing. At least two of the adsorption/desorption columns are placed in a serial cycle arrangement to constitute a main adsorption/desorption column group, and one or more of the other adsorption/desorption columns is placed in parallel with the main adsorption/desorption column group to constitute an auxiliary adsorption/desorption column. The auxiliary adsorption/desorption column performs desorption processing during a period in which none of the adsorption/desorption columns of the main adsorption/desorption column group is performing desorption processing.

Abstract: A system and method for systematically generating potential metal-organic framework (MOFs) structures given an input library of building blocks is provided herein. One or more material properties of the potential MOFs are evaluated using computational simulations. A range of material properties (surface area, pore volume, pore size distribution, powder x-ray diffraction pattern, methane adsorption capability, and the like) can be estimated, and in doing so, illuminate unidentified structure-property relationships that may only have been recognized by taking a global view of MOF structures. In addition to identifying structure-property relationships, this systematic approach to identify the MOFs of interest is used to identify one or more MOFs that may be useful for high pressure methane storage.

Abstract: The present invention is directed toward a method for purifying a natural gas stream comprising: 1) removing the bulk of CO2 by at least one non-membrane gas separation means; and 2) removing oxygen and other impurities by at least one additional gas separation means, wherein the final natural gas product has low level of CO2 and oxygen.

Abstract: Provided is an ozone concentrator including an ozone generator (3), adsorption/desorption columns (4) in which silica gel (6) cooled with a certain-temperature refrigerant (25) for concentrating ozone generated by the ozone generator (3) is packed, a refrigerating machine (23) for cooling the refrigerant (25), a vacuum pump (20) for enhancing a concentration of the ozone in one of the adsorption/desorption columns (4) by discharging mainly oxygen from the silica gel (6) adsorbing the ozone, a plurality of valves (8) to (13) for air pressure operations, for switching passages of gas that is allowed to flow in or flow out with respect to the adsorption/desorption columns (4), and ozone concentration meters (28, 29) for measuring the concentration of the ozone enhanced by the vacuum pump (20), in which a discharge line of the vacuum pump (20) is connected to another one of the adsorption/desorption columns (4), whereby the ozone is allowed to pass through another one of the adsorption/desorption columns again.

Abstract: A method of concentrating ozone gas in which, although the apparatus configuration is simple, ozone gas of a predetermined concentration can be efficiently taken out, and an apparatus therefor are provided. In a method of concentrating ozone gas in which an ozone-oxygen mixture gas is acted in an adsorbing column that is filled with an adsorbent, to cause the adsorbent to selectively adsorb the ozone gas, and the selectively adsorbed ozone gas is desorbed, thereby concentrating and purifying the ozone gas, the ozone-oxygen mixture gas is acted on the adsorbent in a non-cooled state to cause the ozone gas to be selectively adsorbed to the adsorbent, the adsorbing column is vacuumed when performing an operation desorbing of the ozone gas, thereby desorbing the ozone gas from the adsorbent, and an initial amount of the leading out of the desorbed ozone gas is not recovered, thereby obtaining high-concentration ozone gas.

Abstract: An adsorbent media composition has a finished media lithium-exchanged zeolite X (LiX) with a finished Li content in a range from 96% to 83%, based on the total cation equivalents in the LiX. The adsorbent media composition is obtained from a slurry comprising water, a LiX precursor having a pre-media production Li content that is greater than the finished media LiX Li content, and another media component material, such as fibers. The water used to produced the media has a specific conductance in a range from 2.2 ?Siemens/cm to 150 ?Siemens/cm. The finished media LiX has a monovalent cation (Na, K, Rb, Cs and combinations thereof) in a range from 0.05% to 3%, based on the total equivalents of exchangeable cations in the finished media LiX.

Abstract: Fe2(dobdc) has a metal-organic framework with a high density of coordinatively-unsaturated FeII centers lining the pore surface. It can be effectively used to separate O2 from N2 and in a number of additional separation applications based on selective, reversible electron transfer reactions. In addition to being an effective O2 separation material, it can be used for many other processes, including paraffin/olefin separation, nitric oxide/nitrous oxide separation, acetylene storage, and as an oxidation catalyst.

Abstract: Method for recovering a desired component from a waste gas comprising (a) at an operating facility, introducing a waste gas comprising the desired component and one or more undesired components into an adsorber containing adsorbent material selective for the desired component, adsorbing at least a portion of the desired component therein, (b) terminating flow of waste gas into the adsorber; and (c) recovering and concentrating the desired component by either (1) isolating the adsorber, transporting the adsorber to a central processing facility, or (2) withdrawing from the adsorber an intermediate gas enriched in the desired component, compressing the intermediate gas and storing it in a vessel, isolating the vessel, transporting the vessel to a central processing facility to provide a concentrated product further enriched in the desired component.

Abstract: The present invention relates to a process for separating oxygen at high temperature by means of a material comprising at least one compound according to the formula AxBO2-?.yH2O with a lamellar structure composed of sheets generated by the sequence of octahedra connected to one another by the edges, whereby A is at least one of the elements IA or IIA of the periodic classification of elements, B is at least one of the elements IIIB to IIB of the periodic classification of the elements, 0<x?2, 0?y?2, and ?0.4???0.4.

Abstract: Helium is introduced as an additive to any of the oxygen streams introduced into an ozone generator, such as a dielectric discharge (cold plasma) ozone generator, where the effluent of the generator is directed to an adsorption process for separating the ozone from the oxygen. Also disclosed is an improved PSA cycle, which is designed to reduce the amount of make-up helium and oxygen required to sustain the ozone generation and recovery process.

Abstract: This invention provides a metal complex having a gas adsorption capability, a gas storing capability, and a gas separation capability. The present invention attained the above object by a metal complex comprising: a dicarboxylic acid compound (I) represented by the following General Formula (I), wherein R1, R2, R3, and R4 are as defined in the specification; at least one metal ion selected from ions of a metal belonging to Group 2 and Groups 7 to 12 of the periodic table; and an organic ligand capable of bidentate binding to the metal ion, the organic ligand belonging to the D?h point group, having a longitudinal length of not less than 8.0 ? and less than 16.0 ?, and having 2 to 7 heteroatoms.

Abstract: A dehumidifying deoxidizer containing oxygen-deficient cerium oxide and a dehumidifier is provided. The oxygen-deficient cerium oxide is preferably doped with an element increasing the oxygen absorption of the cerium oxide. The oxygen absorption sites of the cerium oxide are preferably obstructed by a site obstructing factor. The cerium oxide preferably has a fluorite type superlattice structure. Also provided are a dehumidifying and deoxidizing packet having the dehumidifying deoxidizer sealed in a bag-shaped, gas permeable casing and a dehumidifying and deoxidizing resin composition containing the dehumidifying deoxidizer and a gas permeable resin.

Abstract: A method and apparatus for supplying oxygen to meet a user demand in which oxygen is separated from air by an electrically driven oxygen separation device to supply oxygen to meet the user demand and to charge an adsorbent bed with all or part of the separated oxygen. When a user demand exists, oxygen can be supplied from both the electrically driven oxygen separation device and from oxygen desorbed from the adsorbent bed.

Abstract: Systems and methods for producing an ozone destructor are disclosed herein. Generally, these systems and methods include an ozone destructor that has a housing defining an air passage duct. In some cases, this air passage duct includes a first chamber and a second chamber that are arranged so that air is able to flow into the first chamber, through the second chamber, and out of the destructor. In some cases, an air drying mechanism is disposed in the first and/or the second chamber. Additionally, in some cases, the ozone destructor further includes multiple mechanisms that reduce ozone to oxygen. In light of these features, the ozone destructor is capable of incrementally drying and reducing air and ozone, respectively, as they pass through the first chamber and the second chamber.

Abstract: A shipboard system provides dry, oil-free utility air and inert gas for use on a marine vessel. A compressor converts ambient air into a pressurized air stream. The air stream is cooled by heat exchange with sea water in the vicinity of the vessel. The air stream is then dried in a dehydration membrane module, and some of the product of the dehydration module is taken for use as utility air. The remainder of the dried air is passed through an air separation module which includes a polymeric membrane. The product of the air separation module includes a nitrogen-enriched gas which is used as an inert gas on the vessel. The compressor is the only mechanically moving component of the system.

Abstract: Solid nanoparticulate transition metal complexes of Co(II) salen exhibit reversible oxygen absorption in a near stoichiometric manner. In contrast, no measurable oxygen binding was observed with unprocessed Co(II) salen.

Abstract: A system and method is presented for reducing a concentration of ambient air used in a feed stream to form an inerting gas in a pressure swing adsorption system. The method includes introducing ambient air into a pressure swing adsorption system to form an inerting gas, introducing the inerting gas to a large volume of atmosphere, thereby inerting at least a portion of the large volume of atmosphere to form an inerted atmosphere, and removing a portion of the inerted atmosphere and introducing the portion of inerted atmosphere to the pressure swing adsorption system to form the inerting gas, thereby reducing an amount of ambient air utilized to form the inerting gas in the pressure swing adsorption system.

Abstract: A method includes using an element which includes a monoblock concrete body with a volume greater than 1 L and a surface porosity greater than 8%, which body includes in the body and/or on a surface thereof a compound having a BET specific surface greater than 100 m2/g, and which element does not include a photocatalytic agent, to absorb from the atmosphere a gas selected from the group consisting of nitrogen oxides, carbon oxides, sulphur oxides, and ozone, or a volatile organic compound.

Abstract: The invention relates to a method for achieving low oxygen levels in a natural gas stream without the use of a catalytic system. In one embodiment, the method comprises: membrane treatment for the removal of the bulk of CO2 and oxygen in the natural gas feed and the addition of a PSA system using a carbon molecular sieve adsorbent for the adsorption of residual oxygen.

Abstract: A method comprising (i) providing a metal organic framework formed by AlIII ions to which fumarate ions are coordinated to produce a porous framework structure, (ii) bringing a substance into contact with the metal organic framework such that the substance is uptaken by the porous metal organic framework to provide storage of or controlled release of, the substance.

Abstract: Methane product gas is produced from landfill gas and gob gas either by a three-stage process of PSA-TSA-PSA or PSA-PSA-PSA, or a two-stage process of PSA-PSA.

Abstract: The invention relates to the use of materials of mixed iron-manganese oxide type for high-temperature oxygen production, notably by separation of oxygen from air, and said materials can be reversibly reduced at high temperature when subjected to an oxygen partial pressure decrease and oxidized when the oxygen partial pressure is higher. The oxidized form of mixed iron-manganese oxides has a bixbyite and/or hematite structure.

Abstract: Systems and methods for producing an ozone destructor are disclosed herein. Generally, these systems and methods include an ozone destructor that has a housing defining an air passage duct. In some cases, this air passage duct includes a first chamber and a second chamber that are arranged so that air is able to flow into the first chamber, through the second chamber, and out of the destructor. In some cases, an air drying mechanism is disposed in the first and/or the second chamber. Additionally, in some cases, the ozone destructor further includes multiple mechanisms that reduce ozone to oxygen. In light of these features, the ozone destructor is capable of incrementally drying and reducing air and ozone, respectively, as they pass through the first chamber and the second chamber.

Abstract: A filter includes a metallocene for removing oxygen from a gas stream. The filter further includes a support for the metallocene.

Abstract: [Problem] To provide an oxygen-absorbing multilayer sheet which exhibits high oxygen-absorbability without the addition of a transition metal salt and which does not cause a problem of odors, a packaging material comprising the multilayer sheet, and a packaging container obtained by molding this packaging material. [Means for Dissolution] An oxygen-absorbing multilayer sheet having a thickness of 250 ?m or more that comprises a gas barrier material layer, an oxygen absorbent layer and a sealing material layer laminated in this order, wherein an oxygen absorbent constituting the subject oxygen absorbent layer comprises a cyclized product of a conjugated diene polymer. There are also disclosed a packaging material comprising this multilayer film and a packaging container obtained by molding this packaging material.