Ring Containing Organic Compound Patents (Class 96/13)
-
Patent number: 8394181Abstract: A permselective material has a polymer having an organosiloxane skeleton and containing a dispersed solid additive. When oxygen and nitrogen are passed through a membrane having the permselective material, the relation between the permeability coefficients [cm3·cm·sec?1·cm?2·cmHg?1] of oxygen and nitrogen at a temperature of 23±2° C. under a pressure difference of 1.05 atm to 1.20 atm through the membrane is expressed by Formula (1): 0.94 ? P ? ( O 2 ) P ? ( N 2 ) < 1 ( 1 ) where P(O2) denotes the permeability coefficient of oxygen, while P(N2) denotes the permeability coefficient of nitrogen.Type: GrantFiled: December 26, 2007Date of Patent: March 12, 2013Assignees: Shin-Etsu Polymer Co., Ltd., DENSO CORPORATION, Shin-Etsu Chemical Co., Ltd.Inventors: Junya Ishida, Katsunori Iwase, Akira Yamamoto, Masahiko Minemura
-
Patent number: 8394176Abstract: Disclosed are a gas separation membrane and a gas separation method in which at least one species of organic vapor is separated and recovered from an organic vapor mixture using the gas separation membrane. The gas separation membrane is made of an aromatic polyimide composed of a tetracarboxylic acid component consisting of an aromatic ring-containing tetracarboxylic acid and a diamine component comprising 10 to 90 mol % of a combination of (B1) 3,4?-diaminodiphenyl ether and (B2) 4,4?-diaminodiphenyl ether at a B1 to B2 molar ratio, B1/B2, ranging from 10/1 to 1/10, and 10 to 90 mol % of other aromatic diamine.Type: GrantFiled: February 4, 2009Date of Patent: March 12, 2013Assignee: Ube Industries, Ltd.Inventors: Tomonori Kanougi, Harutoshi Hoshino, Toshimune Yoshinaga, Yoji Kase, Kenji Fukunaga
-
Patent number: 8394182Abstract: A composition of and a method of making high performance crosslinked membranes are described. The membranes have a high resistance to plasticization by use of crosslinking. The preferred polymer material for the membrane is a polyimide polymer comprising covalently bonded ester crosslinks. The resultant membrane exhibits a high permeability of CO2 in combination with a high CO2/CH4selectivity. Another embodiment provides a method of making the membrane from a monesterified polymer followed by final crosslinking after the membrane is formed.Type: GrantFiled: December 17, 2010Date of Patent: March 12, 2013Assignees: The University of Texas System, Chevron U.S.A. Inc.Inventors: William J. Koros, David Wallace, John Wind, Claudia Staudt-Bickel, Stephen J. Miller
-
Patent number: 8382883Abstract: In one aspect, the present invention provides a curable composition useful in the preparation of a gas separation membrane. The curable composition comprises a polyvinyl alcohol; an aliphatic polyamine; a polyglycidyl ether; and a salt of a C2 to C4 heterocyclic amino acid. In another aspect the present invention provides a composition comprising a crosslinked polyvinyl alcohol comprising structural units derived from a polyglycidyl ether, a polyamine and the salt of a C2 to C4 heterocyclic amino acid. The compositions are useful in the preparation of gas separation membranes in which the C2 to C4 heterocyclic amino acid in the form of its salt functions as a mobile carrier of carbon dioxide.Type: GrantFiled: February 27, 2009Date of Patent: February 26, 2013Assignee: General Electric CompanyInventors: Gary William Yeager, Eric James Pressman, Scott Michael Miller, Cathryn Olsen
-
Patent number: 8377170Abstract: A CO2-facilitated transport membrane of excellent carbon dioxide permeability and CO2/H2 selectivity, which can be applied to a CO2 permeable membrane reactor, is stably provided. The CO2-facilitated transport membrane is formed such that a gel layer 1 obtained by adding cesium carbonate to a polyvinyl alcohol-polyacrylic acid copolymer gel membrane is supported by a hydrophilic porous membrane 2. More preferably, a gel layer supported by a hydrophilic porous membrane 2 is coated with hydrophilic porous membranes 3 and 4.Type: GrantFiled: May 2, 2012Date of Patent: February 19, 2013Assignee: Renaissance Energy Research CorporationInventors: Osamu Okada, Masaaki Teramoto, Reza Yegani, Hideto Matsuyama, Keiko Shimada, Kaori Morimoto
-
Patent number: 8366804Abstract: The present invention discloses a new type of polyimide membranes including hollow fiber and flat sheet membranes with high permeances for air separations and a method of making these membranes. The new polyimide hollow fiber membranes have O2 permeance higher than 300 GPU and O2/N2 selectivity higher than 3 at 60° C. under 308 kPa for O2/N2 separation. The new polyimide hollow fiber membranes also have CO2 permeance higher than 1000 GPU and single-gas selectivity for CO2/CH4 higher than 20 at 50° C. under 791 kPa for CO2/CH4 separation.Type: GrantFiled: May 28, 2010Date of Patent: February 5, 2013Assignee: UOP LLCInventors: Chunqing Liu, Raisa Minkov, Syed A. Faheem, Travis C. Bowen, Jeffrey J. Chiou
-
Patent number: 8328906Abstract: The present disclosure relates to a high molecular weight, monoesterified polyimide polymer. Such high molecular weight, monoesterified polyimide polymers are useful in forming crosslinked polymer membranes for the separation of fluid mixtures. According to its broadest aspect, the method of making a crosslinked membrane comprises the following steps: (a) preparing a polyimide polymer comprising carboxylic acid functional groups from a reaction solution comprising monomers and at least one solvent; (b) treating the polyimide polymer with a diol at esterification conditions in the presence of dehydrating conditions to form a monoesterified polyimide polymer; and (c) subjecting the monoesterified fiber to transesterification conditions to form a crosslinked fiber membrane, wherein the dehydrating conditions at least partially remove water produced during step (b). The crosslinked membranes can be used to separate at least one component from a feed stream including more than one component.Type: GrantFiled: November 28, 2011Date of Patent: December 11, 2012Assignees: Chevron U.S.A. Inc., Georgia Tech Research CorporationInventors: Stephen J. Miller, Imona C. Omole, William J. Kronos
-
Publication number: 20120297977Abstract: A composite membrane for separating a gas from a mixed gas stream includes a fibrous non-woven substrate including consolidated synthetic thermoplastic fibers, and coextensively disposed on a surface of the fibrous non-woven substrate a continuous polysulfide rubber film adhered thereto. A method of separating a gas component from a mixed gas stream includes 1) contacting a surface of the above-described composite membrane with the mixed gas stream under conditions such that a product gas enriched in the gas component diffuses through the composite membrane; and 2) collecting the product gas.Type: ApplicationFiled: May 22, 2012Publication date: November 29, 2012Inventor: Aaron Oken
-
Publication number: 20120297976Abstract: Provided is a gas separation membrane having superior gas permeability, separation selectivity and mechanical properties. A gas separation membrane to separate at least one acid gas from a mix gas, comprising in this order: a first layer that is porous; a second layer that is a separation-active layer containing a compound having a molecular weight of 150,000 or less and capable oft interacting with the acid gas; and a third layer having high gas permeability.Type: ApplicationFiled: February 10, 2011Publication date: November 29, 2012Inventor: Satoshi Sano
-
Patent number: 8317900Abstract: The invention relates to a method for producing membrane, in particular gas separation membrane, wherein the membrane comprises a selective separating layer. The following steps are carried out: a) a polymer solution is produced from at least one polymer and at least one polyglycol ether, b) the polymer solution is cast into a film, c) in a further step, the selective separating layer is produced from the film, preferably by drying. The invention, among other things, further relates to a membrane, in particular gas separation membrane, comprising a selective separating layer.Type: GrantFiled: December 22, 2010Date of Patent: November 27, 2012Assignee: Helmholtz-Zentrum Geesthacht Zentrum fur Material-und Kustenforschung GmbHInventors: Klaus-Viktor Peinemann, Grete Johannsen, Wilfredo Yave Rios, Anja Car
-
Patent number: 8262778Abstract: The invention relates to polymeric ultrafiltration or microfiltration membranes of, for instance, poly(ethylene chlorotrifluoroethylene) (HALAR®), PVDF or PP, incorporating PVME or vinyl methyl ether monomers. The PVME may be present as a coating on the membrane or dispersed throughout the membrane or both. The membranes are preferably hydrophilic with a highly asymmetric structure with a reduced pore size and/or absence of macrovoids as a result of the addition of PVME. The PVME maybe cross-linked. The invention also relates to methods of hydrophilising membranes and/or preparing hydrophilic membranes via thermal or diffusion induced phase separation processed.Type: GrantFiled: August 10, 2011Date of Patent: September 11, 2012Assignee: Siemens Industry, Inc.Inventors: Daniel Mullette, Joachim Muller, Neeta Patel
-
Patent number: 8206493Abstract: Problem to be Solved: To provide a gas separation membrane having an excellent performance balance (balance between gas permeation performance and gas separation ability) as a gas separation membrane. Solution: A gas separation membrane comprising a porous support member and a gas separating resin layer formed on the porous support member, wherein the porous support member has a mode diameter as measured by a mercury porosimeter of from 0.005 ?m to 0.3 ?m, and a pore size distribution index as measured by the mercury porosimeter of from 1 to 15.Type: GrantFiled: October 23, 2008Date of Patent: June 26, 2012Assignee: Asahi Kasei Chemicals CorporationInventors: Atsushi Shimizu, Masao Kondo, Junichi Yamamoto
-
Patent number: 8197576Abstract: A CO2-facilitated transport membrane of excellent carbon dioxide permeability and CO2/H2 selectivity, which can be applied to a CO2 permeable membrane reactor, is stably provided. The CO2-facilitated transport membrane is formed such that a gel layer 1 obtained by adding cesium carbonate to a polyvinyl alcohol-polyacrylic acid copolymer gel membrane is supported by a hydrophilic porous membrane 2. More preferably, a gel layer supported by a hydrophilic porous membrane 2 is coated with hydrophilic porous membranes 3 and 4.Type: GrantFiled: January 22, 2009Date of Patent: June 12, 2012Assignee: Renaissance Energy Research CorporationInventors: Osamu Okada, Masaaki Teramoto, Reza Yegani, Hideto Matsuyama, Keiko Shimada, Kaori Morimoto
-
Patent number: 8182590Abstract: A process for forming a porous nanoscale membrane is described. The process involves applying a nanoscale film to one side of a substrate, where the nanoscale film includes a semiconductor material; masking an opposite side of the substrate; etching the substrate, beginning from the masked opposite side of the substrate and continuing until a passage is formed through the substrate, thereby exposing the film on both sides thereof to form a membrane; and then simultaneously forming a plurality of randomly spaced pores in the membrane. The resulting porous nanoscale membranes, characterized by substantially smooth surfaces, high pore densities, and high aspect ratio dimensions, can be used in filtration devices, microfluidic devices, fuel cell membranes, and as electron microscopy substrates.Type: GrantFiled: May 1, 2006Date of Patent: May 22, 2012Assignee: University of RochesterInventors: Christopher C. Striemer, Philippe M. Fauchet, Thomas R. Gaborski, James L. McGrath
-
Patent number: 8167983Abstract: The present invention relates to compositions for producing membranes, the compositions comprising at least 0.1% by weight of highly branched polymer, at least 0.5% by weight of linear polymer and at least 30% by weight of solvent. The present invention additionally describes membranes obtainable from the compositions, and methods of producing these membranes.Type: GrantFiled: December 17, 2007Date of Patent: May 1, 2012Assignee: Evonik Degussa GmbHInventors: Matthias Seiler, Stefan Bernhardt, Rolf Schneider, Roland Wursche, Franz-Erich Baumann
-
Patent number: 8133306Abstract: A gas diffusion substrate includes a non-woven network of carbon fibres, the carbon fibres are graphitised but the non-woven network has not been subjected to a graphitisation process. A mixture of graphitic particles and hydrophobic polymer is disposed within the network. The longest dimension of at least 90% of the graphitic particles is less than 100 ?m. A process for manufacturing gas diffusion substrates includes depositing a slurry of graphitised carbon fibres onto a porous bed forming a wet fibre network, preparing a suspension of graphitic particles and hydrophobic polymer, applying onto, and pulling the suspension into, the network, and drying and firing the network. Another process includes mixing a first slurry of graphitic particles and hydrophobic polymer with a second slurry of graphitised carbon fibres and liquid forming a third slurry, depositing the third slurry onto a porous bed forming a fibre-containing layer, and drying and firing the layer.Type: GrantFiled: June 15, 2005Date of Patent: March 13, 2012Assignees: Johnson Matthey Public Limited Company, Technical Fibre Products LimitedInventors: George Thomas Quayle, Julia Margaret Rowe, Jonathan David Brereton Sharman, Julian Andrew Siodlak, Nigel Julian Walker, Andrew James Fletcher
-
Patent number: 8127937Abstract: In the present invention high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes and methods for making and using these membranes have been developed. The cross-linked polybenzoxazole and polybenzothiazole polymer membranes are prepared by: 1) first synthesizing polyimide polymers comprising pendent functional groups (e.g., —OH or —SH) ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone; 2) fabricating polyimide membranes from these polymers; 3) converting the polyimide membranes to polybenzoxazole or polybenzothiazole membranes by heating under inert atmosphere such as nitrogen or vacuum; and 4) finally converting the membranes to high performance cross-linked polybenzoxazole or polybenzothiazole membranes by a crosslinking treatment, preferably UV radiation. The membranes can be fabricated into any convenient geometry.Type: GrantFiled: March 27, 2009Date of Patent: March 6, 2012Assignee: UOP LLCInventors: Chunqing Liu, Man-Wing Tang, Raisa Serbayeva, Lubo Zhou
-
Patent number: 8110026Abstract: A gas diffusion barrier contains a polymer matrix and a functional graphene which displays no signature of graphite and/or graphite oxide, as determined by X-ray diffraction.Type: GrantFiled: October 6, 2006Date of Patent: February 7, 2012Assignee: The Trustees of Princeton UniversityInventors: Robert Prud'Homme, Christopher O'Neil, Bulent Ozbas, Ilhan Aksay, Richard Register, Douglas Adamson
-
Patent number: 8101009Abstract: This abstract discusses membranes needed to separate fluids for the production of oxygen-enriched air, nitrogen-enriched-air, for the separation of carbon dioxide from hydrocarbons, and the separation of hydrogen from various petrochemical and oil refining streams. Membranes are needed that provide a resistance to interaction with process components or contaminants, provide the mechanical strength required to withstand high membrane differential pressures and high process temperatures, and exhibit sufficient maximum strain such that membranes are not brittle and can easily be formed into desirable membrane forms. Membranes of polyimide polymers, particularly polyimide polymers sold under the trade name P-84, are annealed in a controlled annealing step to improve the mechanical properties of the polymers used to make separation membranes.Type: GrantFiled: September 8, 2008Date of Patent: January 24, 2012Assignee: L'Air Liquide Societe Anonyme pour l'Etude Et L'Exploitation des Procedes Georges ClaudeInventors: Okan Max Ekiner, John W. Simmons
-
Patent number: 8083834Abstract: The present invention discloses a new process of treating natural gas using high gas permeability polybenzoxazole polymer membranes operated at high temperatures that can provide sufficient dew point margin for the product gas. The high gas permeability polybenzoxazole polymer membranes can be used for a single stage membrane system or for the first stage membrane in a two stage membrane system for natural gas upgrading. Simulation study has demonstrated that a costly membrane pretreatment system such as a MemGuard™ system will not be required in the present new process. The new process can achieve significant capital cost saving and reduce the existing membrane footprint greater than 50%.Type: GrantFiled: May 7, 2008Date of Patent: December 27, 2011Assignee: UOP LLCInventors: Lubo Zhou, Chunqing Liu
-
Patent number: 8075669Abstract: There is described a composite material such as venting materials and vents containing said venting materials. The vents are air- or more generally gas-permeable venting composites that are oleophobic and liquid repellent.Type: GrantFiled: April 22, 2008Date of Patent: December 13, 2011Assignee: Gore Enterprise Holdings, Inc.Inventors: Klaus Meindl, Wolfgang Buerger
-
Patent number: 8066799Abstract: The present disclosure relates to a high molecular weight, monoesterified polyimide polymer. Such high molecular weight, monoesterified polyimide polymers are useful in forming crosslinked polymer membranes for the separation of fluid mixtures. According to its broadest aspect, the method of making a crosslinked membrane comprises the following steps: (a) preparing a polyimide polymer comprising carboxylic acid functional groups from a reaction solution comprising monomers and at least one solvent; (b) treating the polyimide polymer with a diol at esterification conditions in the presence of dehydrating conditions to form a monoesterified polyimide polymer; and (c) subjecting the monoesterified fiber to transesterification conditions to form a crosslinked fiber membrane, wherein the dehydrating conditions at least partially remove water produced during step (b). The crosslinked membranes can be used to separate at least one component from a feed stream including more than one component.Type: GrantFiled: January 10, 2008Date of Patent: November 29, 2011Assignees: Chevron U.S.A. Inc., Georgia Tech Research CorporationInventors: Stephen J. Miller, Imona C. Omole, William J. Kronos
-
Patent number: 8056731Abstract: A membrane structure is provided. The membrane structure includes a polymer layer having a plurality of pores; and a ceramic layer disposed on the polymer layer. The ceramic layer has a plurality of substantially unconnected pores. Each of the substantially unconnected pores is in fluid communication with at least one of the pores of the polymer layer. A method of manufacturing a membrane structure is provided. The method includes the steps of providing a polymer layer having a plurality of pores; and disposing a ceramic layer on the polymer layer. Disposing a ceramic layer includes depositing a metal layer on the polymer layer; and anodizing the metal layer to convert the metal layer into a porous layer. At least one of the depositing step and the anodizing step is performed as a continuous process. Alternatively, at least one of the depositing and the anodizing step is performed as a batch process.Type: GrantFiled: May 12, 2009Date of Patent: November 15, 2011Assignee: General Electric CompanyInventors: Vidya Ramaswamy, James Anthony Ruud, Anthony Yu-Chung Ku, William Hullinger Huber
-
Patent number: 8057574Abstract: The invention relates to polymeric ultrafiltration or microfiltration membranes of, for instance, Halar, PVDF or PP, incorporating PVME or vinyl methyl ether monomers. The PVME may be present as a coating on the membrane or dispersed throughout the membrane or both. The membranes are preferably hydrophilic with a highly asymmetric structure with a reduced pore size and/or absence of macrovoids as a result of the addition of PVME. The PVME maybe cross-linked. The invention also relates to methods of hydrophilising membranes and/or preparing hydrophilic membranes via thermal or diffusion induced phase separation processed.Type: GrantFiled: December 28, 2009Date of Patent: November 15, 2011Assignee: Siemens Industry, Inc.Inventors: Daniel Mullette, Joachim Muller, Neeta Patel
-
Patent number: 7964019Abstract: A membrane for gas separation includes a porous support layer and a separation layer. The separation layer comprises a mixture of one or more saccharide derivatives and one or more homopolymers. The saccharide derivative(s) may have a cyclic structure with five or six ring atoms, or a linear structure, or may include monosaccharide derivatives which are bound via glycoside bonds, and the number of monosaccharides bound in this manner may be 2 to 1,000. A membrane can be produced by preparing a homogeneous solution which comprises a saccharide derivative and a homopolymer in a solvent; and pouring the homogenous solution onto a support layer. The membrane may be used in a gas separation module the operation of which makes use of the membrane.Type: GrantFiled: March 19, 2009Date of Patent: June 21, 2011Assignee: GKSS-Forschungszentrum Geesthacht GmbHInventors: Jun Qiu, Klaus-Viktor Peinemann, Jan Wind, Holger Pingel
-
Patent number: 7938894Abstract: The invention discloses a composition comprising a hybrid composite organic-inorganic membrane. The hybrid organic-inorganic membrane according to the present invention may comprise an amorphous porous layer incorporating organic functionalities. The amorphous porous layer may be deposited on a porous alumina substrate by chemical vapor deposition (CVD). The amorphous porous layer may comprise a single top-layer (STL), multiple top-layers (MTL) or mixed top-layers (XTL). The substrate may comprise a single layer or multiple graded layers of alumina.Type: GrantFiled: February 28, 2008Date of Patent: May 10, 2011Assignees: ConocoPhillips Company, Virginia Tech Intellectual Properties, Inc.Inventors: Shigeo Ted Oyama, Yunfeng Gu, Joe D. Allison, Garry C. Gunter, Scott A. Scholten
-
Patent number: 7922795Abstract: A nanoscale membrane exposed on opposite sides thereof and having an average thickness of less than about 100 nm, and a lateral length to thickness aspect ratio that is more than 10,000 to 1 is disclosed. Also disclosed are methods of making such membranes, and use thereof in a number of devices including fuel cells, sensor devices, electrospray devices, and supports for examining a sample under electron microscopy.Type: GrantFiled: May 1, 2006Date of Patent: April 12, 2011Assignee: University of RochesterInventors: Christopher C. Striemer, Philippe M. Fauchet
-
Patent number: 7871456Abstract: A membrane for use in an implantable glucose sensor including at least one crosslinked substantially hydrophobic polymer and at least one crosslinked substantially hydrophilic polymer; wherein the first and second polymers are different polymers and substantially form an interpenetrating polymer network, semi-interpenetrating polymer network, polymer blend, or copolymer. The membranes are generally characterized by providing a permeability ratio of oxygen to glucose of about 1 to about 1000 in units of (mg/dl glucose) per (mmHg oxygen). Three methods of making membranes from hydrophobic and hydrophilic monomers formed into polymer networks are provided, wherein according to at least two of the methods, the monomers may be substantially immiscible with one another.Type: GrantFiled: August 10, 2006Date of Patent: January 18, 2011Assignee: The Regents of the University of CaliforniaInventors: David A. Gough, Joseph Y. Lucisano, Joe T. Lin, Hwai-Min Tsay, Drahoslav Lim, Jana Limova, legal representative
-
Patent number: 7867324Abstract: A fuel system includes a fuel deoxygenator for removing oxygen from a liquid fuel. A vaporizer is in fluid communication with the fuel deoxygenator. The vaporizer vaporizes at least a portion of the liquid fuel to produce vaporized fuel. At least a portion of the vaporized fuel pre-mixes with oxidizer to reduce formation of undesirable emissions.Type: GrantFiled: May 11, 2009Date of Patent: January 11, 2011Assignee: United Technologies CorporationInventors: Alexander G Chen, Jeffrey M. Cohen
-
Publication number: 20110000367Abstract: Disclosed are a gas separation membrane and a gas separation method in which at least one species of organic vapor is separated and recovered from an organic vapor mixture using the gas separation membrane. The gas separation membrane is made of an aromatic polyimide composed of a tetracarboxylic acid component consisting of an aromatic ring-containing tetracarboxylic acid and a diamine component comprising 10 to 90 mol % of a combination of (B1) 3,4?-diaminodiphenyl ether and (B2) 4,4?-diaminodiphenyl ether at a B1 to B2 molar ratio, B1/B2, ranging from 10/1 to 1/10, and 10 to 90 mol % of other aromatic diamine.Type: ApplicationFiled: February 4, 2009Publication date: January 6, 2011Applicant: UBE INDUSSTRIES, LTD.Inventors: Tomonori Kanougi, Harutoshi Hoshino, Toshimune Yoshinaga, Yoji Kase, Kenji Fukunaga
-
Publication number: 20100313759Abstract: The invention relates to an adsorption filter material with a multilayer construction, particularly with a permeable adsorptive barrier layer composite, preferably for ABC protective clothing, wherein the adsorption filter material has at least a first barrier layer having a plurality of openings and at least a second barrier layer having a plurality of openings, as well as an adsorption layer disposed between the first and second barrier layers, wherein the first and second barrier layers are disposed in such a manner, that the openings and the openings do not overlap and/or do not coincide. The adsorption filter material is very comfortable and, at the same time, offers excellent protection against chemical poisons.Type: ApplicationFiled: October 2, 2008Publication date: December 16, 2010Inventor: Benedikt Bones
-
Publication number: 20100307974Abstract: The invention relates to a polyaniline, comprising aniline units and organosulphur units, characterized in that the polyaniline is doped and has a number average degree of polymerization of approximately 5 to approximately 50. The scope of the invention also includes a process for the preparation of polyaniline, wherein aniline and at least one organosulphur unit are converted to a polyaniline derivative in an oxidative, acid-catalyzed polymerization reaction. A subject of the invention is also a coated substrate which is coated with the polyaniline according to the invention and also a process for the coating of the substrate. The scope of the invention furthermore also includes a coating composition which is suitable for the coating of the substrate. The invention thus also relates to a process for the preparation of the coating composition.Type: ApplicationFiled: November 20, 2008Publication date: December 9, 2010Applicant: SUD-CHEMIE AGInventors: Karl-Heinz Pettinger, Franz-Xaver Muller, Gerhard Illing, Mathias Ulbricht
-
Patent number: 7846238Abstract: Provided is a method of manufacturing a porous polytetrafluoroethylene (PTFE) membrane capable of achieving both a high collection efficiency and a low pressure drop, though it has a larger average pore size and a greater thickness than conventional porous PTFE membranes. This manufacturing method includes: stretching an unsintered polytetrafluoroethylene sheet by a factor of 5 to 30 in a predetermined direction at a temperature equal to or higher than the melting point of polytetrafluoroethylene; further stretching the stretched sheet by a factor of 5 to 40 in a direction different from the predetermined direction at a temperature lower than the melting point; and after the stretchings, heating the stretched sheet at a temperature equal to or higher than the melting point.Type: GrantFiled: March 23, 2007Date of Patent: December 7, 2010Assignee: Nitto Denko CorporationInventors: Masatoshi Suzuki, Youji Uchida
-
Patent number: 7837763Abstract: The invention under consideration concerns novel his-molecular-weight polyazoles, which are suitable for the production of fibers, films, membranes, and molded articles, on the basis of their high molecular weight, expressed as intrinsic viscosity, of at least 1.3 dl/g. Moreover, the invention under consideration describes a method for the production of high-molecular-weight polyazoles.Type: GrantFiled: March 12, 2007Date of Patent: November 23, 2010Inventors: Gordon Calundann, Oemer Uensal, Brian Benicewicz, Bobby G. Dawkins, J. Dean Baker, Rita H. Joiner
-
Patent number: 7833313Abstract: A process of producing an asymmetric membrane of multicomponent polyimide. The process includes the steps of (1) preparing a multicomponent polyimide blend solution by mixing a polyimide component A having a number-averaged polymerization index NA and a polyimide component B having a number-averaged polymerization index NB, wherein NA and NB satisfies equation 1: 2.35×NA?2.09<NB<450×NA?1.12??1 (2) subjecting the multicomponent polyimide blend solution to further polymerization and imidation reaction, and (3) causing a phase inversion in the resulting multicomponent polyimide blend solution to form an asymmetric membrane. The polyimide component A is raw materials of polyimide A containing a fluorine atom in the chemical structure thereof and/or a polymerization and imidation reaction product of the raw materials. The polyimide component B is raw materials of polyimide B and/or a polymerization and imidation reaction product of the raw materials.Type: GrantFiled: October 27, 2009Date of Patent: November 16, 2010Assignee: Ube Industries, Ltd.Inventors: Toshimune Yoshinaga, Kenji Fukunaga, Yoji Kase
-
Publication number: 20100269698Abstract: A gas separation membrane comprises a blend of polyethersulfone (PES) and aromatic polyimide polymers that may comprise a plurality of first repeating units of formula (I), wherein X1, X 2 and X3 are herein defined.Type: ApplicationFiled: April 22, 2009Publication date: October 28, 2010Inventors: STEPHEN YATES, REHAN ZAKI, AMBER ARZADON, CHUNQING LIU, JEFFREY CHIOU
-
Patent number: 7815712Abstract: The present invention discloses a novel method of making high performance mixed matrix membranes (MMMs) using stabilized concentrated suspensions of solvents, uniformly dispersed polymer stabilized molecular sieves, and at least two different types of polymers as the continuous blend polymer matrix. MMMs as dense films or asymmetric flat sheet or hollow fiber membranes fabricated by the method described in the current invention exhibit significantly enhanced permeation performance for separations over the polymer membranes made from the continuous blend polymer matrix. MMMs of the present invention are suitable for a wide range of gas, vapor, and liquid separations such as alcohol/water, CO2/CH4, H2/CH4, O2/N2, CO2/N2, olefin/paraffin, iso/normal paraffins, and other light gases separations.Type: GrantFiled: December 18, 2006Date of Patent: October 19, 2010Assignee: UOP LLCInventors: Chunqing Liu, Man-Wing Tang, Stephen T. Wilson, David A. Lesch
-
Patent number: 7811359Abstract: A membrane and method for separating carbon dioxide from a mixture of gases, where the membrane includes expanded polytetrafluoroethylene and polysiloxane. The membrane is highly stable and can separate carbon dioxide at high flux in harsh environments and high temperatures, such as exhaust gases from power plants.Type: GrantFiled: January 18, 2007Date of Patent: October 12, 2010Assignee: General Electric CompanyInventors: Kunj Tandon, Umakant Rapol, Ullash Kumar Barik, Rajappan Vetrivel
-
Publication number: 20100218680Abstract: In one aspect, the present invention provides a curable composition useful in the preparation of a gas separation membrane. The curable composition comprises a polyvinyl alcohol; an aliphatic polyamine; a polyglycidyl ether; and a salt of a C2 to C4 heterocyclic amino acid. In another aspect the present invention provides a composition comprising a crosslinked polyvinyl alcohol comprising structural units derived from a polyglycidyl ether, a polyamine and the salt of a C2 to C4 heterocyclic amino acid. The compositions are useful in the preparation of gas separation membranes in which the C2 to C4 heterocyclic amino acid in the form of its salt functions as a mobile carrier of carbon dioxide.Type: ApplicationFiled: February 27, 2009Publication date: September 2, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Gary William Yeager, Eric James Pressman, Scott Michael Miller, Cathryn Olsen
-
Publication number: 20100218681Abstract: In one aspect, the present invention provides a curable composition useful in the preparation of a gas separation membrane. The curable composition comprises a polyvinyl alcohol; an aliphatic polyamine; a polyglycidyl ether; and a salt of a C3-C5 amino cycloaliphatic acid. In another aspect the present invention provides a composition comprising a crosslinked polyvinyl alcohol comprising structural units derived from a polyglycidyl ether, a polyamine and the salt of a C3 to C5 amino cycloaliphatic acid. The compositions are useful in the preparation of gas separation membranes in which the C3 to C5 amino cycloaliphatic acid in the form of its salt functions as a mobile carrier of carbon dioxide.Type: ApplicationFiled: February 27, 2009Publication date: September 2, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Gary William Yeager, Eric James Pressman, Scott Michael Miller, Cathryn Olsen
-
Patent number: 7785397Abstract: In order to synthesize semi-interpenetrating polymer networks (semi-IPNs) with molecular sieve characteristics, polyetherimide/bismaleimide (PEI/BMI) chromophore composites were made through sol-gel technique. A tunable and compatible chemical structure with fine morphology was obtained through in situ controlled sol-gel polymerization, crosslinking, chemical modification and membrane fabrication. The novel semi-IPN, synthesized and assembled by using ethanol as polar protic modifier and pore former, had a superior structure and morphology suitable for making gas separation membranes. These semi-IPN membranes gave fifteen times higher gas flux without significant decrease in their gas permselectivity than membranes prepared from pure PEL The chemical structures of these novel semi-IPNs were characterized by using FTIR, XPS and SEM.Type: GrantFiled: March 10, 2006Date of Patent: August 31, 2010Assignee: National Research Council of CanadaInventors: Ashwani Kumar, Jamal Kurdi
-
Publication number: 20100212504Abstract: Problem to be Solved: To provide a gas separation membrane having an excellent performance balance (balance between gas permeation performance and gas separation ability) as a gas separation membrane. Solution: A gas separation membrane comprising a porous support member and a gas separating resin layer formed on the porous support member, wherein the porous support member has a mode diameter as measured by a mercury porosimeter of from 0.005 ?m to 0.3 ?m, and a pore size distribution index as measured by the mercury porosimeter of from 1 to 15.Type: ApplicationFiled: October 23, 2008Publication date: August 26, 2010Inventors: Atsushi Shimizu, Masao Kondo, Junichi Yamamoto
-
Patent number: 7771518Abstract: An asymmetric hollow-fiber gas separation membrane is made of a soluble aromatic polyimide that is composed of a specific repeating unit. The tetracarboxylic acid component of the unit has a diphenylhexafluoropropane structure and a biphenyl structure. The diamine component of the unit essentially contains diaminobenzoic acids and any of diaminodibenzothiophenes, diaminodibenzothiophene=5,5-dioxides, diaminothioxanthene-10,10-diones, and diaminothioxanthene-9,10,10-triones.Type: GrantFiled: January 19, 2006Date of Patent: August 10, 2010Assignee: Ube Industries, Ltd.Inventors: Toshimune Yoshinaga, Kenji Fukunaga, Yutaka Kanetsuki, Hiroshi Uchida, Minoru Shigemura, Nozomu Tanihara
-
Patent number: 7771521Abstract: It is an object of the present invention to provide a polyimide-based hybrid material which is industrially and advantageously utilized because of having better gas permeability, electric characteristics, heat resistance, mechanical strength, and the like as compared with the conventional polyimide-based hybrid materials, while keeping chemical resistance, forming characteristics (process characteristics), and the like inherently possessed by polyimide. Provided is a hyperbranched polyimide-based hybrid material constituted of an organic-inorganic polymer hybrid, wherein the organic-inorganic polymer hybrid has a hyperbranched polyimide moiety and an inorganic oxide moiety which are combining each other via covalent bond and constituting a composite structure.Type: GrantFiled: February 28, 2007Date of Patent: August 10, 2010Assignees: National University Corporation Nagoya Institute of Technology, Ibiden Co., Ltd.Inventors: Yasuharu Yamada, Tomoyuki Suzuki
-
Patent number: 7758679Abstract: A treating unit that comprises an absorber unit for contacting a regenerated solvent with a gas stream loaded with contaminants to yield a treated gas stream and a loaded solvent stream; a regenerator unit for stripping the loaded solvent stream to yield a loaded gas stream and the regenerated solvent; and a device for smoothing contaminant peak concentrations in the loaded solvent stream and for receiving the loaded solvent stream. The device comprises a first hold-up tank having a first inlet and a first outlet, a second hold-up tank having a second inlet and a second outlet, and an inlet distributor that is operatively connected to the first inlet and to the second inlet and that provides for directing flow of the loaded solvent stream to either the first hold-up tank or the second hold-up tank.Type: GrantFiled: August 13, 2009Date of Patent: July 20, 2010Assignee: Shell Oil CompanyInventors: Anders Carlsson, Gijsbert Jan Van Heeringen, Thijme Last
-
Patent number: 7717271Abstract: A membrane structure is provided. The membrane structure includes a first layer having a plurality of interconnected pores; and a second layer disposed on the first layer. The second layer has a plurality of unconnected pores. Each of the unconnected pores is in fluid communication with at least one of the interconnected pores of the first layer. A method of making a membrane structure is provided. The method includes the steps of providing a first layer having a plurality of interconnected pores; and disposing a second layer on the first layer. Disposing a second layer includes depositing a conducting layer on the first layer; and anodizing the conducting layer to convert the conducting layer into a porous layer.Type: GrantFiled: December 7, 2005Date of Patent: May 18, 2010Assignee: General Electric CompanyInventors: Vidya Ramaswamy, James Anthony Ruud, Melissa Suzanne Sander, Anthony Yu-Chung Ku, Mohan Manoharan, Milivoj Konstantin Brun, Seth Thomas Taylor
-
Patent number: 7708810Abstract: A gas permeable, carbon based, nanocomposite membrane comprises a nanoporous carbon matrix comprising a pyrolyzed polymer, and a plurality of nanoparticles of carbon or an inorganic compound disposed in the matrix. The matrix is prepared by pyrolyzing a polymer, and nanoparticles of the particulate material are disposed in the polymer prior to pyrolysis. The particles may be disposed in a precursor of the polymer, which precursor is subsequently polymerized, or in the polymer itself.Type: GrantFiled: July 18, 2006Date of Patent: May 4, 2010Assignee: The Penn State Research FoundationInventors: Henry C. Foley, Ramakrishnan Rajagopalan, Anna R. Merritt
-
Patent number: 7699911Abstract: Ozone resistant O2/N2 gas separation membranes comprise a polymer membrane and an ozone reacting component, such as an antioxidant. The antioxidant may be included in the support layer of a composite membrane or included in the entire structure of an asymmetric membrane. The antioxidants in the separation membrane reduce oxidation and deterioration of the actual separation layer of the membrane.Type: GrantFiled: May 3, 2007Date of Patent: April 20, 2010Assignee: Honeywell International Inc.Inventors: Shaojun J. Zhou, Stephen F. Yates
-
Patent number: 7662212Abstract: The invention relates to polymeric ultrafiltration or microfiltration membranes of, for instance, Halar, PVDF or PP, incorporating PVME or vinyl methyl ether monomers. The PVME may be present as a coating on the membrane or dispersed throughout the membrane or both. The membranes are preferably hydrophilic with a highly asymmetric structure with a reduced pore size and/or absence of macrovoids as a result of the addition of PVME. The PVME maybe cross-linked. The invention also relates to methods of hydrophilising membranes and/or preparing hydrophilic membranes via thermal or diffusion induced phase separation processed.Type: GrantFiled: July 8, 2004Date of Patent: February 16, 2010Assignee: Siemens Water Technologies Corp.Inventors: Daniel Mullette, Joachim Muller, Neeta Patel
-
Patent number: 7658784Abstract: Composite materials are provided. A representative material is configured as a composite membrane for gas separation, vapor separation, or pervaporation. The composite membrane comprises at least a first polymer and a second polymer. Processes for the production of composite materials, in particular composite membranes, also are provided.Type: GrantFiled: April 7, 2006Date of Patent: February 9, 2010Assignee: GKSS-Forschungszentrum GeesthachtInventors: Detlev Fritsch, Klaus-Viktor Peinemann, Dominique De Figueiredo Gomes