Abstract: Composite materials are provided. A representative material is configured as a composite membrane for gas separation, vapor separation, or pervaporation. The composite membrane comprises at least a first polymer and a second polymer. Processes for the production of composite materials, in particular composite membranes, also are provided.

Abstract: A membrane contactor system for removing a component from a gas, comprising a housing defining a gas flow path; a microporous membrane positioned in the housing to allow the gas to flow across the membrane, wherein the membrane comprises a structure of nodes connected by fibrils in which surfaces of the structure of nodes and fibrils define a plurality of interconnecting pores extending through the microporous membrane, wherein the plurality of interconnecting pores are configured to allow the component to diffuse therethrough; and an oleophobic coating disposed on the microporous membrane to form a coated membrane and configured to provide oleophobicity to the coated membrane without blocking the plurality of interconnecting pores.

Abstract: A face mask comprising a filter material being a fibrous substrate, especially non-woven polypropylene or polyester, having an acidic polymer, especially of the Carbopol or Gantres type, deposited on the fibres. The mask has an anti-viral activity against inhaled or exhaled air. A filter material suitable for such a mask, and a process for making it are also described.

Abstract: Metal-organic framework (MOF)-polymer mixed matrix membranes (MOF-MMMs) have been prepared by dispersing high surface area MOFs (e.g. IRMOF-1) into a polymer matrix (e.g. Matrimid 5218). The MOFs allow the polymer to infiltrate the pores of the MOFs, which improves the interfacial and mechanical properties of the polymer and in turn affects permeability. Pure gas permeation tests show the incorporation of 20 wt-% of IRMOF-1 in Matrimid 5218 polyimide matrix results in 280% improvement in CO2 permeability without a loss of CO2/CH4 selectivity compared to those of the pure Matrimid 5218 membrane. This type of MOF-MMMs has significantly improved gas separation performance with dramatically high CO2 permeability (>35 barrer) and higher than 29 CO2/CH4 selectivity at 50° C. under 100 psig pressure, which are attractive candidates for practical gas separation applications such as CO2 removal from natural gas.

Abstract: A process of producing an asymmetric membrane of multicomponent polyimide. The process includes the steps of (1) preparing a multicomponent polyimide blend solution by mixing a polyimide component A having a number-averaged polymerization index NA and a polyimide component B having a number-averaged polymerization index NB, wherein NA and NB satisfies equation 1: 2.35×NA?2.09<NB<450×NA?1.12??1 (2) subjecting the multicomponent polyimide blend solution to further polymerization and imidation reaction, and (3) causing a phase inversion in the resulting multicomponent polyimide blend solution to form an asymmetric membrane. The polyimide component A is raw materials of polyimide A containing a fluorine atom in the chemical structure thereof and/or a polymerization and imidation reaction product of the raw materials. The polyimide component B is raw materials of polyimide B and/or a polymerization and imidation reaction product of the raw materials.

Abstract: A fuel system for an energy conversion device includes a deoxygenator system with an oxygen permeable membrane formed from a multiple of layers. The layers include a sealant layer, an oxygen permeability layer and a porous backing layer. The layered composite oxygen permeable membrane maximizes the oxygen transfer rate and minimizes the fuel leakage rate.

Abstract: A liquid-gas separator for a direct liquid feed fuel cell includes: a housing having an open hole; a gas extracting membrane that covers the open hole and transmits only the gas; a liquid extracting member that defines a first chamber that contacts the gas extracting membrane and a second chamber that does not contact the gas extracting membrane, and selectively transmits the liquid in the first chamber to the second chamber; an inlet that guides the liquid and the gas into the housing; and an outlet that is connected to the second chamber and guides the liquid in the second chamber to the outside.

Abstract: A membrane for gas separation includes a porous support layer and a separation layer. The separation layer comprises a mixture of one or more saccharide derivatives and one or more homopolymers. The saccharide derivative(s) may have a cyclic structure with five or six ring atoms, or a linear structure, or may include monosaccharide derivatives which are bound via glycoside bonds, and the number of monosaccharides bound in this manner may be 2 to 1,000. A membrane can be produced by preparing a homogeneous solution which comprises a saccharide derivative and a homopolymer in a solvent; and pouring the homogenous solution onto a support layer. The membrane may be used in a gas separation module the operation of which makes use of the membrane.

Abstract: A carbon membrane laminated body includes: a porous substrate, a first porous carbon membrane as a carbon membrane underlayer disposed on a surface of the porous substrate, and a second porous carbon membrane as a carbon membrane separation layer disposed on a surface of the carbon membrane underlayer, having a smaller film thickness, and a smaller average pore diameter, compared with those of the carbon membrane underlayer. It is preferable to form the carbon membrane underlayer and the carbon membrane separation layer by carbonizing a carbon membrane underlayer precursor disposed on a surface of the porous substrate and the carbon membrane separation layer precursor disposed on a surface of the carbon membrane underlayer precursor at 400 to 1000° C. in a non-oxidation atmosphere. The carbon membrane laminated body is a separation membrane excellent in both separation performance and flux when it is used as a separation membrane of a mixture.

Abstract: The invention relates to gas separation, in particular to separation of CO2 from CO2-rich liquids, particularly from CO2 absorption liquids used in the removal of CO2 from off-gases or product flows, such as natural gas or synthesis gas. According to the invention, CO2 is separated from a CO2-rich liquid by a method comprising a step wherein, under elevated pressure, said liquid is contacted with a membrane based on polyacetylene substituted with trimethylsilyl groups such that the pressure across the membrane is at least 1 bar and that at least a part of the CO2 is transported from the liquid through the membrane.

Abstract: The invention discloses a composition comprising a hybrid composite organic-inorganic membrane. The hybrid organic-inorganic membrane according to the present invention may comprise an amorphous porous layer incorporating organic functionalities. The amorphous porous layer may be deposited on a porous alumina substrate by chemical vapor deposition (CVD). The amorphous porous layer may comprise a single top-layer (STL), multiple top-layers (MTL) or mixed top-layers (XTL). The substrate may comprise a single layer or multiple graded layers of alumina.

Abstract: A membrane 12 that exhibits superior condensation resistance regardless of the type of moisture-permeable resin, that has satisfactory adhesion between a porous film and a reinforcing member, and that can be manufactured in a simple manner. The membrane 12 is a laminated article 23 containing a porous film 20 and a reinforcing member 40, and the reinforcing member 40 has a moisture-permeable resin layer 30 on the side of an interface 50 with the porous film 20. To reliably form the moisture-permeable resin layer (moisture-permeable resin film) 30, the average pore diameter of the porous film 20 is preferably 0.01 to 10 ?m, and the porosity of the reinforcing member 40 is preferably 30 to 95%. According to the membrane 12 of the present invention, even if the moisture-permeable resin is water-soluble (for example, polyvinyl alcohol), condensation resistance is still satisfactory.

Abstract: There is provided an asymmetric integrally skinned membrane comprising a polyimide and another polymer selected from the group consisting of polyvinylpyrrolidone, sulfonated polyetheretherketones and mixtures thereof. The membrane which is substantially insoluble in an organic solvent and substantially defect-free can be useful as a separation membrane.

Abstract: A fuel system includes a fuel deoxygenator for removing oxygen from a liquid fuel. A vaporizer is in fluid communication with the fuel deoxygenator. The vaporizer vaporizes at least a portion of the liquid fuel to produce vaporized fuel. At least a portion of the vaporized fuel pre-mixes with oxidizer to reduce formation of undesirable emissions.

Abstract: The present invention includes a method, composition and apparatus for forming a nanoparticle filled polymer having similar gas selectivity and greater gas permeability than the native polymer. The nanoparticle filled polymer includes one or more polymeric materials and one or more nanoparticles dispersed within the one or more polymeric materials that increasing the permeability of the nanoparticle filled polymers relative to the permeability of the native polymer membrane.

Abstract: Methods for treating a gas mixture of at least propylene and propane, in order to separate the propylene from the propane. The gas mixture is brought into contact with a membrane enables the selective permeation of the propylene with respect to the propane. A propylene-enriched permeate and a propane-enriched retentate is formed. The propylene concentration of the permeate in the membrane is then reduced with a sweeping gas.

Abstract: There is provided a nanocomposite membrane comprising an Ag-nanoparticle/polymer nanocomposite, in which the Ag-particles are uniformly dispersed in the polymer matrix, and a support membrane for supporting the nanocomposite, as well as a process of preparing said membrane. The nanocomposite membrane of the present invention comprising a neutral Ag-nanoparticle as an olefin carrier, which is chemically stable, has excellent long-term operation performance characteristics as well as high selectivity and permeability. Thus, it can be advantageously used for the separation of olefin from an olefin/paraffin mixture.

Abstract: The present invention is for novel high performance cross-linkable and cross-linked mixed matrix membranes and the use of such membranes for separations such as for CO2/CH4, H2/CH4 and propylene/propane separations. More specifically, the invention involves the preparation of cross-linkable and cross-linked mixed matrix membranes (MMMs). The cross-linkable MMMs were prepared by incorporating microporous molecular sieves or soluble high surface area microporous polymers (PIMs) as dispersed microporous fillers into a continuous cross-linkable polymer matrix. The cross-linked MMMs were prepared by UV-cross-linking the cross-linkable MMMs containing cross-linkable polymer matrix such as BP-55 polyimide. Pure gas permeation test results demonstrated that both types of MMMs exhibited higher performance for CO2/CH4 and H2/CH4 separations than those of the corresponding cross-linkable and cross-linked pure polymer matrices.

Abstract: A filter system including a method for self cleaning the filter system of an electronic equipment enclosure where air flow is monitored either by monitoring fan performance of air flow velocity through the enclosure. The system includes two filters elements, an upstream ASHRAE or HEPA filter element to block particulate matter and a downstream PTFE filter element to block water vapor. The ASHRAE or HEPA filter element is relatively inexpensive and easy to clean. The PTFE filter element is more expensive and difficult to clean. Thus, the cheaper filter is used to protect the more expensive filter from contaminants and to increase its useful life.

Abstract: This abstract discusses membranes needed to separate fluids for the production of oxygen-enriched air, nitrogen-enriched-air, for the separation of carbon dioxide from hydrocarbons, and the separation of hydrogen from various petrochemical and oil refining streams. Membranes are needed that provide a resistance to interaction with process components or contaminants, provide the mechanical strength required to withstand high membrane differential pressures and high process temperatures, and exhibit sufficient maximum strain such that membranes are not brittle and can easily be formed into desirable membrane forms. Membranes of polyimide polymers, particularly polyimide polymers sold under the trade name P-84, are annealed in a controlled annealing step to improve the mechanical properties of the polymers used to make separation membranes.

Abstract: A deoxygenator includes a plurality of permeable membranes spirally wound about an exhaust tube for removing dissolved oxygen from a hydrocarbon fuel. The permeable membrane is spirally wrapped about the exhaust tube and defines fuel passages and exhaust passages. The fuel passages and exhaust passages alternate such that each fuel passage is bounded on each adjacent side by an exhaust passage. An oxygen partial pressure differential is generated across the permeable membrane to draw dissolved oxygen from fuel in the fuel passage. The dissolved oxygen is then communicated through openings about the circumference of the exhaust tube and out the deoxygenator.

Abstract: Membranes are used to separate fluids for the production of oxygen-enriched air, nitrogen-enriched-air, for the separation of carbon dioxide from hydrocarbons, and the separation of hydrogen from various petrochemical and oil refining streams. Membranes are discussed that provide a resistance to interaction with process components or contaminants, which can lead to plasticizing of the membrane, while providing the mechanical strength required to withstand high membrane differential pressures and high process temperatures. Membranes of blended polymers are used to improve the mechanical strength of the polymers used to make separation membranes. Specifically, polyimide polymers are combined with a blend polymer that is a polyamide and/or a polyamide-imde polymer. The resulting polymer mix is used to produce various forms of high strength, chemically resistant membranes, including hollow-fiber membranes that are suitable for high pressure, high temperature applications.

Abstract: Anisotropic hydrophobic/hydrophilic nanoporous membranes and methods of forming anisotropic hydrophobic/hydrophilic nanoporous membranes are disclosed. The method of forming the nanoporous membrane includes growing a nanoporous oxide film on a substrate. A nanoporous membrane having a top side and a bottom side can then be formed by partially separating the nanoporous oxide film from the substrate. A fluorocarbon film can be deposited on the top side of the nanoporous membrane by plasma polymerization. The disclosed anisotropic hydrophobic/hydrophilic nanoporous membranes can have extremely different hydrophobicity between the top side and the bottom side of the nanoporous membrane.

Abstract: A breather valve device for a container for an electronic control unit, includes a support structure including, a substantially planar wall having first and second surfaces intended to face outwardly and inwardly of the container respectively, and in which is formed an aperture, and a projecting, essentially cylindrical, tubular wall extending from the first surface of the planar wall, substantially around the aperture; an interceptor element having a smaller cross section than the passage cross section of the tubular wall and of the aperture; the interceptor element being disposed inside an axially intermediate portion of the tubular wall, spaced radially from the latter so as to define, with respect to the tubular wall, a narrow annular gap; the interceptor element being connected to the support structure by at least one connector formation. The support structure, the interceptor element and the connector formation are integrally formed in one piece of molded plastics material.

Abstract: A process for the manufacture of a polyimide hollow fibre comprising: (i) providing a dope solution comprising one or more polyimides dissolved in a solvent comprising 60-100 wt % N-methylpyrollidone and 0-40 wt % ethanol, (ii) providing a bore fluid, (iii) generating a tube of the dope solution filled with the bore fluid, (iv) bringing the product of step (iii) into contact with a coagulation solvent to form a hollow fiber.

Abstract: A separation membrane module having hollow fibers, wherein a plurality of hollow fibers are heated and melted to bond and thermally fuse the external surfaces of the hollow fibers with each other; and a method of manufacturing a separation membrane module having hollow fibers whereby the ends of a plurality of hollow fibers are inserted into a sheath, the sheath and the hollow fibers are tightly bonded together to form spaces, and the sheath portion into which hollow fibers have been inserted is heated up to the temperature at which the surfaces of the hollow fibers melt, with the spaces thus formed kept in a decompressed state, so that the exterior surfaces of the hollow fibers are thermally fused and integrated together.

Abstract: A semipermeable separation element includes (a) a porous substrate, and (b) a film formed on the microporous substrate; the film comprising a silicone elastomer and a nanoparticle filler. The film preferably has an oxygen enrichment selectivity of at least 30, or even 60, over nitrogen. Methods of making and using the same and filter cartridges incorporating the same are also described.

Abstract: A composition of and a method of making high performance hollow fiber membranes is described. The membranes have a high resistance to plasticization by use of a predetermined amount of crosslinking. The preferred polymer material for the membrane is a polyimide polymer comprising covalently bonded ester crosslinks. The resultant hollow fiber membrane exhibits a high permeability of CO2 in combination with a high CO2/CH4 selectivity. Another embodiment provides a method of making the hollow fiber membrane from a monesterified polymer followed by final crosslinking after hollow fiber formation.

Abstract: A method of supplying oxygen rich air to the passengers and crew on board a passenger aircraft by use of a highly permeable oxygen enrichment unit, wherein the fiber tubes of the hollow fiber membranes used to separate normal air into oxygen rich and nitrogen rich fractions in the oxygen enrichment unit are subjected to a modification technique before the tubes are coated with a selective polymer.

Abstract: A mixed matrix membrane is provided which comprises a continuous phase organic polymer and small pore molecular sieves dispersed therein. The molecular sieves have a largest minor crystallographic free diameter of 3.6 Angstroms or less. When these molecular sieves are properly interspersed with a continuous phase polymer, the membrane will exhibit a mixed matrix membrane effect, i.e., a selectivity increase of at least 10% relative to a neat membrane containing no molecular sieves. Finally, methods for making and using such mixed matrix membranes to separate gases from a mixture containing two or more gases are also disclosed.

Abstract: A method of producing composite, hollow fibre gas separation membranes, wherein external surfaces of the porous hollow fibre tubes used in the construction of the membranes are subjected to a modification technique before the external surfaces are coated with a thin layer of selective polymer so as to increase the number of pores in the fibre surface.

Abstract: A mixed matrix membrane is provided which comprises a continuous phase organic polymer and small pore alumina containing molecular sieves dispersed therein. The molecular sieves have a silica-to-alumina molar ratio of less than 1.0, more preferably, less than 0.3, and most preferably less than 0.1. In some cases, the molecular sieves have no appreciable amounts of silica. Exemplary compositions include aluminophosphates (AlPO) and silicoaluminophosphates (SAPO). When these molecular sieves are properly interspersed with a continuous phase polymer, the membrane will exhibit a mixed matrix membrane effect, i.e., a selectivity increase of at least 10% relative to a neat membrane containing no molecular sieves. The molecular sieves have pores with a largest minor crystallographic free diameter of 4.0 Angstroms or less. Finally, methods for making and using such mixed matrix membranes to separate gases from a mixture containing two or more gases are also disclosed.

Abstract: The present invention provides a culture container and a cap for a container having a ventilation filter medium or a medium similar thereto that can exchange carbon dioxide gas in the culture container with atmospheric air, and prevent the contamination of sterilized culture medium inside the culture container with fungi, mites, and the like. A culture bottle includes a bottle unit, and a cap that is mounted on an opening. The cap includes a cap unit, and a ventilation filter medium. A hole is provided in the cap unit. The ventilation filter medium includes a plurality of micropores having a pore diameter between 0.1 and 50 micrometers, and is mounted on the hole.

Abstract: A connector casing E required to have a sealing property includes a cover 2. The cover 2 has a cover main body 10 provided with a large vent hole H0 passing through the connector casing E in an inward and outward direction and having a predetermined inner diameter size. A permeable sheet S, which permits permeation of a gas and prevents permeation of a liquid and a solid, is integrally joined to an outside peripheral part of the large vent hole H0 so as to cover the large vent hole H0 from its outside. A cover insert member C is disposed outside the permeable sheet S to cover the permeable sheet from the outside, and a ring-shaped protrusion 22 is hermetically joined to the casing main body 10. The cover insert member C1 is provided with a small vent hole H1 which has an inner diameter smaller than the large vent hole H0 and communicates with the large vent hole H0 through the permeable sheet S.

Abstract: A polyphosphazene having a glass transition temperature (“Tg”) of approximately ?20° C. or less. The polyphosphazene has at least one pendant group attached to a backbone of the polyphosphazene, wherein the pendant group has no halogen atoms. In addition, no aromatic groups are attached to an oxygen atom that is bound to a phosphorus atom of the backbone. The polyphosphazene may have a Tg ranging from approximately ?100° C. to approximately ?20° C. The polyphosphazene may be selected from the group consisting of poly[bis-3-phenyl-1-propoxy)phosphazene], poly[bis-(2-phenyl-1-ethoxy)phosphazene], poly[bis-(dodecanoxypolyethoxy)-phosphazene], and poly[bis-(2-(2-(2-?-undecylenyloxyethoxy)ethoxy)ethoxy)phosphazene]. The polyphosphazene may be used in a separation membrane to selectively separate individual gases from a gas mixture, such as to separate polar gases from nonpolar gases in the gas mixture.

Abstract: A method of separating or concentrating hydrocarbon-containing gas mixtures such as hydrogen from hydrocarbons, carbon dioxide from hydrocarbons, nitrogen from hydrocarbons, and hydrocarbons from one another using a selectively permeable membrane. The method is well suited to separate hydrocarbon-containing mixtures such as those generated by petroleum refining industries, petrochemical industries, natural gas processing, and the like. The membranes exhibit extremely good resistance to plasticization by hydrocarbon components in the gas mixture under practical industrial process conditions.

Abstract: The present invention provides a selectively gas permeable membrane that has a superior combination of permeability and selectivity. The membrane composition includes a Type 1 copolyimide uniformly blended with a Type 2 copolyimide, which polymers are defined by chemical structure more specifically in this disclosure. The invention also provides a method of using the membrane of the copolyimide blend to separate components of gas mixtures.

Abstract: A cross-linked, supported polybenzimidazole membrane for gas separation is prepared by reacting polybenzimidazole (PBI) with the sulfone-containing crosslinking agent 3,4-dichloro-tetrahydro-thiophene-1,1-dioxide. The cross-linked reaction product exhibits enhanced gas permeability to hydrogen, carbon dioxide, nitrogen, and methane as compared to the unmodified analog, without significant loss of selectivity, at temperatures from about 20 degrees Celsius to about 400 degrees Celsius.

Abstract: A metal-coated, wire-reinforced polymer electrolyte membrane that is permeable only to protons and hydrogen is disclosed. The metal-coated, wire-reinforced polymer electrolyte membrane has a surface microstructure that prevents cracking of the metal coating during hydration. The metal-coated, wire-reinforced polymer electrolyte membrane can be used in liquid-type fuel cells to prevent crossover of fuel, gas and impurities.

Abstract: A cross-linked, supported polybenzimidazole membrane for gas separation is prepared by layering a solution of polybenzimidazole (PBI) and ?,??dibromo-p-xylene onto a porous support and evaporating solvent. A supported membrane of cross-linked poly-2,2?-(m-phenylene)-5,5?-bibenzimidazole unexpectedly exhibits an enhanced gas permeability compared to the non-cross linked analog at temperatures over 265° C.

Abstract: A method for fabricating a composite membrane includes coating a substrate, such as, for example, an asymmetrical porous hollow fiber substrate, with a solution which includes a perfluorinated polymer and a perfluorinated solvent. Prior to coating, the substrate is impregnated with an impregnation fluid which is immiscible with the perfluorinated solvent. The method of the invention further includes removing the perfluorinated solvent and the impregnation fluid. A composite membrane includes a porous asymmetric hollow fiber substrate having an outer surface coated with a perfluoropolymer coating. Separation devices which include composite membranes and methods of separating a fluid mixture into a fraction enriched in a first component and a fraction depleted in that component also are described.

Abstract: A membrane-based process for separating mixtures of target gases if the gas mixture also contains C3+ hydrocarbon vapors. The process uses gas-separation membranes having a base membrane and a coating layer. The base membrane incorporates a selective layer made from a polymer selective between the light gases to be separated. The coating layer comprises a fluorinated polymer capable of protecting the base membrane from C3+ hydrocarbon vapors and liquids.

Abstract: Gas separation membranes formed from polyester-polyether block copolymers which are useful for separating gases from gas mixtures. The membranes and processes are especially suited for separating polar gases from mixtures that contain polar and non-polar species. The novel membranes exhibit good permeability and permselectivity as well as durability, making them well suited for industrial applications such as removal of acid gases from natural gas and removal of carbon dioxide from synthesis gas.

Abstract: Gas separation membranes formed from polyether-urethane or polyether-urea block copolymers are useful for separating gases from gas mixtures. The membranes and processes are especially suited for separating polar gases from mixtures that contain polar and non-polar species. The novel membranes exhibit good permeability and permselectivity, as well as durability, making them well suited for industrial applications such as removal of acid gases from natural gas and removal of carbon dioxide from synthesis gas.

Abstract: A hollow fiber membrane gas separation apparatus of a compact design suitable for separation and purification of gases is disclosed. The apparatus comprises an outer housing that consists of a detachable bowl and a head closure, and a removable hollow fiber membrane cartridge positioned therein. The cartridge contains a concentric tubular inner core member and is surrounded by a shell and at least one end closure. The cartridge is attached by its first axial end in a sealed and removable manner to a gas flow conduit positioned coaxially in the housing closure wherein the conduit is in fluid communication with a gas inlet or product gas outlet port formed in the housing head closure and by its second axial end to a waste gas exit port in the bowl. The feed gas inlet port and the product gas outlet port in the head closure are spaced in a straight line for a short overall distance providing for a linear connection with other components of a gas separation system, which is a preferred system component packaging.

Abstract: Soluble polyamic acid salt (PAAS) precursors comprised of tertiary and quaternary amines, ammonium cations, sulfonium cations, or phosphonium cations, are prepared and fabricated into membranes that are subsequently imidized and converted into rigid-rod polyimide articles, such as membranes with desirable gas separation properties. A method of enhancing solubility of PAAS polymers in alcohols is also disclosed.

Abstract: The present invention is directed to a membrane contactor for debubbling (or degassing) a liguid. The membrane contactor comprises a perforated core tube, a plurality of hollow fiber membranes surrounding the tubes and having an end, a tube sheet affixing the end of the plurality of hollow fiber membranes to the core tube, and a shell surrounding the plurality of hollow fiber membranes and the tube sheet. A lumen side is defined by an internal surface of the membranes. A shell side is defined by the perforated core tube, an external surface of said membrane, and the shell. The membrane is a single layered, skinned, polymethylpentene hollow fiber microporous membrane. The skin is on the shell side.

Abstract: In a method for the separation of supercritical gas from substances dissolved in the gas with a membrane through which the gas passes while the substances dissolved in the gas is retained, a pore-free membrane of a polymer perfluoro-2,2-diemthyl-1,3-dioxole is used as a membrane in the separation process.

Abstract: A preferred gas separation membrane made from a blend of a copolymer of 2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole (BDD) and tetrafluoroethylene (TFE) with a 2,2,4-trifluoro-5-trifluoromethoxy-1,3-dioxide based polymer is disclosed, the membrane exhibiting an advantageous combination of gas separation and permeation properties for a number of gas separation applications. In particular, the membrane formed from the blend of these polymers exhibits unexpectedly high gas separation factors for separation of volatile organic hydrocarbon vapors (VOC) from air, compared to the component polymers that form the blends. Fabrication of composite membranes formed from perfluoropolymer blends is further disclosed.

Abstract: The invention relates to preparation and uses of novel polymeric materials, polyimide amic acid salts (PIAAS). The use of these materials for the fabrication of fluid separation membranes is further disclosed.