Abstract: The present disclosure relates to the present disclosure relates to a method of fabricating an aligned polymer containing a bonded substrate and related compositions. The method involved placing a polymer in solution which is capable of alignment wherein the polymer is also bound to a selected substrate. This may then be followed by placing the polymer solution in an electrochemical cell wherein the polymer solution is in contact with at least one electrode and applying an electric field/voltage to the polymer solution and generating a pH gradient wherein the polymer and bonded substrate positions at the isoelectric point of the polymer in solution.

Abstract: Tritiated planar carbon forms and their production are provided. Methods are provided for the stoichiometrically controlled labeling of planar carbon forms capitalizing on normal flaws of carboxylic acids ubiquitously present in commercial preparations of these planar carbon forms. Alternative methods include generation of a metallated intermediate whereby a metal is substituted for hydrogen on the carbon backbone of a planar carbon form. The metalized intermediate is then reacted with a tritium donor to covalently label the planar carbon form. The tritiated planar carbon forms produced are useful, for example, for determination of a biological property or environmental fate of planar carbon forms.

Abstract: According to one embodiment, a nonvolatile memory device includes a memory cell connected to a first interconnect and a second interconnect. The memory cell includes a plurality of layers. The plurality of layers includes a carbon-containing memory layer sandwiched between a first electrode film and a second electrode film and a carbon-containing barrier layer provided at least one of between the first electrode film and the memory layer and between the second electrode film and the memory layer. The barrier layer has lower electrical resistivity than the memory layer.

Abstract: The current application relates to a method for solubilizing (dispersing and debundling) of carbon nanotubes using a gemini surfactant, which has head groups and a spacer linking the head groups. The dispersion of nanotubes produced by said method can be used as a delivery system for biologically active agents to an organism.

Abstract: Dispersible single-walled and multi-walled carbon nanotubes (CNTs) are prepared by dissolving surfactants in water to form a solution; adding carbon nanotubes to the solution to form a mixture; sonicating and agitating the mixture to form a carbon-nanotube/water dispersion; centrifuging the dispersion to remove un-dispersed carbon nanotubes and impurities; repeatedly freezing and heating the CNT dispersion; and, sublimating water in the CNT dispersion by freezing and evacuating the dispersion to obtain carbon nanotubes coated with surfactant. The carbon nanotubes prepared by the method of the invention are dry, amphiphilic, and surfactant-coated powders that can be dispersed in both aqueous and organic solvents to form stable and uniform dispersions having a high concentration of carbon nanotubes.

Abstract: A hydrogen storage structure includes a plurality of graphene sheets arranged to form a stack with a plurality of spacers between adjacent graphene sheets in the stack. In one embodiment, the spacers are arranged to provide a distance ranging between 5 ? and 20 ? between adjacent graphene sheets. In one embodiment, the spacers are formed as graphene spheres having a diameter that ranges from 5 ? to 15 ?. In another embodiment, the spacers are formed as graphene single-walled nanontubes having a length that ranges from 5 ? to 20 ?. In a further embodiment, the spacers are formed as graphene sheets having a thickness that ranges from 5 ? to 20 ?. In one embodiment, the plurality of graphene sheets is doped with lithium. In one embodiment, the lithium doping concentration is a ratio of one lithium atom per three carbon atoms.

Abstract: Ultra-low power single metallic single-wall-nano-tube (SWNT) interconnects for sub-threshold circuits are provided. According to some embodiments, an interconnect structure for use in electronic circuits can generally comprise a first substrate, a second substrate, and an interconnect. The first substrate can be spaced apart from the second substrate. The interconnect is preferably a single wall carbon nanotube (SWNT) interconnect. The SWNT interconnect can be disposed between the first and second substrates to electrically connect the substrates. The substrates can form parts of electrical components (e.g., a transistor, processor, memory, filters, etc.) operating in a subthreshold operational state. Other aspects, features, and embodiments are claimed and described.

Abstract: An electrode for electrochemical analysis is described, the electrode comprising: an insulating surface; a three-dimensional network of carbon nanotubes situated on the insulating surface; and an electrically conducting material in electrical contact with the carbon nanotubes; wherein the carbon nanotubes are oriented substantially parallel to the insulating surface. Also described is a method of manufacturing the electrode, and a method of electrochemically analysing a solution using electrodes of this type, and an associated assay device or kit.

Abstract: An electrochemical gas sensor for detecting ozone or nitrogen dioxide in a gas sample has a measuring electrode (3) formed of carbon nanotubes (CNT) or a counterelectrode (8) in an electrolyte solution (9), which contains lithium chloride or lithium bromide in an aqueous solution.

Abstract: This invention relates to heterogenous pore polymer nanotube membranes useful in filtration, such as reverse osmosis desalination, nanofiltration, ultrafiltration and gas separation.

Abstract: In various embodiments, exfoliated carbon nanotubes are described in the present disclosure. The carbon nanotubes maintain their exfoliated state, even when not dispersed in a medium such as a polymer or a liquid solution. Methods for making the exfoliated carbon nanotubes include suspending carbon nanotubes in a solution containing a nanocrystalline material, precipitating exfoliated carbon nanotubes from the solution and isolating the exfoliated carbon nanotubes. Nanocrystalline materials may include nanorods, hydroxyapatite and various hydroxyapatite derivatives. In some embodiments, methods for making exfoliated carbon nanotubes include preparing a solution of carbon nanotubes in an acid and filtering the solution through a filter to collect exfoliated carbon nanotubes on the filter. In some embodiments, a concentration of carbon nanotubes in the acid is below the percolation threshold.

Abstract: An electrochemical gas sensor for detecting hydrocyanic acid in a gas sample has a measuring electrode (3) formed of carbon nanotubes (CNT) and a counterelectrode (8) in an electrolyte (9), which contains lithium bromide in an aqueous solution.

Abstract: A transparent electrically-conductive hard-coated substrate of the invention comprises a transparent base material; a deposited carbon nanotubes layer formed on the transparent base material; and a cured resin layer formed on the deposited carbon nanotubes layer, wherein the deposited carbon nanotubes layer has a thickness of 10 nm or less, the total thickness of the deposited carbon nanotubes layer and the cured resin layer is 1.5 ?m or more, and part of the deposited carbon nanotubes layer is diffused into the cured resin layer so that carbon nanotubes are present in the cured resin layer. The transparent electrically-conductive hard-coated substrate possesses high transparency and hard coating properties and also has electrical conductivity.

Abstract: A carbon nanotube (“CNT”) composition includes CNTs, a dispersing agent containing a reactive functional group, and at least one kind of dispersion medium. A CNT layer structure includes a substrate and a CNT layer disposed on the substrate, the CNT layer including the CNT composition including the CNTs arranged in a network-shape, and an organic material adsorbed to the CNTs and chemically bonded to the substrate. A liquid crystal display device includes the CNT layer structure. A method of manufacturing the CNT layer structure uses the CNT composition. A method of manufacturing the liquid crystal display device includes forming a pixel electrode on a passivation layer, by using the method of manufacturing the CNT layer structure.

Abstract: Compositions for sensor films used for detecting chemical analytes within sensors, such as polymer-absorption chemiresistors (i.e., conductometric sensors) are provided. Robust sensor film compositions that have low resistance, high conductivity, and greater temperature stability and sensitivity to chemical analytes are provided, as well as methods of making these sensor films. Such sensor film compositions include a matrix having a polymer resin and a plurality of conductive particles comprising an axial-geometry conductive particle. Exemplary axial-geometry conductive particles comprise graphene, such as a carbon nanotube. Blends of conductive particles are also contemplated, including blends of axial-geometry conductive particles, such as carbon nanotubes, and carbon black.

Abstract: A method for dispersing nanotubes, comprising contacting the nanotubes with an electronic liquid comprising a metal and an amine solvent, a solution of dispersed nanotuhes, comprising individual nanotuhes at a concentration of greater than about 0.01 mgml?1 and a solvent and a nanotube crystal comprising a close packed array of nanotubes, wherein the crystal has a thickness of 100 nm or more are described.

Abstract: Apparatus and methods according to various aspects of the present invention may operate in conjunction with composite matrix material and reinforcement material, such as nanostructures. The nanostructures may be evenly dispersed and/or aligned in the matrix material through application of an electromagnetic field, resulting in a nanocomposite material. In one embodiment, the nanocomposite material is suitable for large scale processing.

Abstract: A free standing film includes: i. a matrix layer having opposing surfaces, and ii. an array of nanorods, where the nanorods are oriented to pass through the matrix layer and protrude an average distance of at least 1 micrometer through one or both surfaces of the matrix layer. A method for preparing the free standing film includes (a) providing an array of nanorods on a substrate, optionally (b) infiltrating the array with a sacrificial layer, (c) infiltrating the array with a matrix layer, thereby producing an infiltrated array, optionally (d) removing the sacrificial layer without removing the matrix layer, when step (b) is present, and (e) removing the infiltrated array from the substrate to form the free standing film. The free standing film is useful as an optical filter, ACF, or TIM, depending on the type and density of nanorods selected.

Abstract: Provided are a CNT-mesoporous silica composite, a CNT-mesoporous carbon composite, a supported catalyst using the CNT-mesoporous carbon composite as a support, and a fuel cell using the supported catalyst as the anode, cathode, or both anode and cathode. The CNT-mesoporous carbon composite is prepared using the CNT-mesoporous silica composite. The CNT-mesoporous carbon composite has a high electrical conductivity due to the CNTs contained therein, and thus, when the CNT-mesoporous carbon composite is used in an electrode of a fuel cell, the fuel cell has a remarkably improved performance relative to the conventional catalyst support which does not contain CNTs.

Abstract: The invention relates to a method for introducing electrically conductive carbon particles into a surface layer comprising polyurethane. These carbon particles can in particular be carbon nanotubes. In the method according to the invention, a solution of non-aggregated carbon particles having a mean particle diameter of from 0.3 nm to 3000 nm acts in a solvent upon a surface layer comprising polyurethane. The solvent is able to cause the maceration of a surface layer comprising polyurethane. The dwell time is measured such that it is not sufficient to carry the polyurethane over into the solution. The invention furthermore relates to a polyurethane layer that comprises electrically conductive carbon particles and can be obtained by means of a method according to the invention. The invention likewise relates to a polyurethane object having surface layer comprising electrically conductive carbon particles, obtainable by a method according to the invention.

Abstract: A method is provided for functionalizing nanoscale fibers including reacting a plurality of nanoscale fibers with at least one epoxide monomer to chemically bond the at least one epoxide monomer to surfaces of the nanoscale fibers to form functionalized nanoscale fibers. Functionalized nanoscale fibers and nanoscale fiber films are also provided.

Abstract: The disclosed subject matter provides a techniques for precisely and/or functionally cutting carbon nanotubes, e.g., single walled carbon nanotubes (“SWNTs”) and integrating a single nucleic acid molecule (e.g., a DNA molecule) into a gap formed into the carbon nanotubes. In one aspect, a method of fabricating a molecular electronic device includes disposing a SWNT on a base layer, forming a gap in the SWNT using a lithographic process, and disposing a single DNA strand across the gap so that each end of the nucleic acid contacts a gap termini. The disclosed subject matter also provides techniques for measuring the electrical properties (charge transport) of a DNA molecule which is integrated into an SWNT. Furthermore, a molecular electronic device including an SWNT with an integrated nucleic acid molecule is disclosed.

Abstract: Systems and methods related to optical nanosensors comprising photoluminescent nanostructures are generally described.

Abstract: A catalyst free process for manufacturing carbon nanotubes by inducing an arc discharge from a carbon anode and a carbon cathode in an inert gas atmosphere contained in a closed vessel. The process is carried out at atmospheric pressure in the absence of external cooling mechanism for the carbon cathode or the carbon anode.

Abstract: This disclosure provides articles that include functionalized nanoscale fibers and methods for functionalizing nanoscale fibers. The functionalized nanoscale fibers may be made by oxidizing a network of nanoscale fibers, grafting one or more molecules or polymers to the oxidized nanoscale fibers, and cross-linking at least a portion of the molecules or polymers grafted to the oxidized nanoscale fibers. The functionalized nanoscale fibers may be used to make articles.

Abstract: A composition can include a complex, where the complex includes a photoluminescent nanostructure and a polymer free from selective binding to an analyte, the polymer adsorbed on the photoluminescent nanostructure, and a selective binding site associated with the complex.

Abstract: A process of producing a composite having carbon nanotubes is described where the carbon nanotube formation process of producing carbon nanotubes includes controlled heating of plant fiber materials in an oxygen-limited atmosphere. The plant fiber materials may be heated either cyclically or by rapid heating to produce the carbon nanotubes.

Abstract: Disclosed is a method for making graphene nanoribbons (GNRs) by controlled unzipping of structures such as carbon nanotubes (CNTs) by etching (e.g., argon plasma etching) of nanotubes partly embedded in a polymer film. The GNRs have smooth edges and a narrow width distribution (2-20 nm). Raman spectroscopy and electrical transport measurements reveal the high quality of the GNRs. Such a method of unzipping CNTs with well-defined structures in an array will allow the production of GNRs with controlled widths, edge structures, placement and alignment in a scalable fashion for device integration. GNRs may be formed from nanostructures in a controlled array to form arrays of parallel or overlapping structures. Also disclosed is a method in which the CNTs are in a predetermined pattern that is carried over and transferred to a substrate for forming into a semiconductor device.

Abstract: Provided herein composition and methods for nanoporous membranes comprising single walled, double walled, or multi-walled carbon nanotubes embedded in a matrix material. Average pore size of the carbon nanotube can be 6 nm or less. These membranes are a robust platform for the study of confined molecular transport, with applications in liquid and gas separations and chemical sensing including desalination, dialysis, and fabric formation.

Abstract: The present invention provides a method and system for monitoring external excitation on a surface using nanocomposite paint. The method comprises applying the nanocomposite paint on the surface, wherein the nanocomposite paint comprises a mixture of a plurality of carbon nanotubes and an epoxy resin along with a plurality of electrically conductive patterned electrodes. The electrical properties of the nanocomposite paint changes in response to the external excitation of the surface. The change in the electrical properties of the nanocomposite is measured by a measuring instrument, wherein the change in the electrical properties of the nanocomposite paint is directly proportional to the external excitation experienced by the surface.

Abstract: A precursor chiral nanotube with a specified chirality is grown using an epitaxial process and then cloned. A substrate is provided of crystal material having sheet lattice properties complementary to the lattice properties of the selected material for the nanotube. A cylindrical surface(s) having a diameter of 1 to 100 nanometers are formed as a void in the substrate or as crystal material projecting from the substrate with an orientation with respect to the axes of the crystal substrate corresponding to the selected chirality. A monocrystalline film of the selected material is epitaxially grown on the cylindrical surface that takes on the sheet lattice properties and orientation of the crystal substrate to form a precursor chiral nanotube. A catalytic particle is placed on the precursor chiral nanotube and atoms of the selected material are dissolved into the catalytic particle to clone a chiral nanotube from the precursor chiral nanotube.

Abstract: The present invention provides efficient methods for producing a superhydrophobic carbon nanotube (CNT) array. The methods comprise providing a vertically aligned CNT array and performing vacuum pyrolysis on the CNT array to produce a superhydrophobic CNT array. These methods have several advantages over the prior art, such as operational simplicity and efficiency. The invention also relates to superhydrophobic CNT arrays.

Abstract: A stiff layered polymer nanocomposite comprising a substrate adapted to receive a plurality of alternating layers of a first material and a second material; wherein the first material and second material are a polyelectrolyte, an organic polymer or an inorganic colloid and said first material and said second material have a chemical affinity for each other, said plurality of layers crosslinked using a chemical or physical crosslinking agent. Thin films that are consolidated and optionally crosslinked can be manufactured into hierarchical laminates with rigid and stress resistant properties.

Abstract: A UV curable intermediate transfer media, such as a belt, that includes a first supporting substrate, such as a polyimide substrate layer, and a second surface layer of a mixture of a carbon nanotube component, a photoinitiator component, and an organic inorganic hybrid component.

Abstract: A carbon nanotube slurry consists of carbon nanotubes, glass powder, and organic carrier. The field emission device includes an insulative substrate, a cathode conductive layer, and an electron emission layer. The cathode conductive layer is located on a surface of the insulative substrate. The electron emission layer is located on a surface of the cathode conductive layer. The electron emission layer consists of a glass layer and a plurality of carbon nanotubes electrically connected to the cathode conductive layer.

Abstract: There is provided a process for producing single-walled carbon nanotubes with an increased diameter, characterized in that it comprises a diameter-increasing treatment step of heating carbon nanotubes of a raw material at a degree of vacuum of 1.3×10?2 Pa or below and at a temperature ranging from 1500 to 2000° C., preferably 1700 to 2000° C.

Abstract: According to a method of manufacturing carbon nanotubes, minute concavities and convexities are formed at a surface of a substrate, a catalyst metal layer having a predetermined film thickness is formed on the surface having the concavities and convexities, the substrate is subject to a heat treatment at a predetermined temperature to change the catalyst metal layer into a plurality of isolated fine particles. The catalyst metal fine particles have a uniform particle diameter and uniform distribution. Then, the substrate supporting the plurality of fine particles is placed in a carbon-containing gas atmosphere to grow carbon nanotubes on the catalyst metal fine particles by a CVD method using the carbon-containing gas. The carbon nanotubes can be formed to have a desired diameter and a desired shell number with superior reproducibility.

Abstract: The disclosure generally relates to a dispersion of nanoparticles in a liquid medium. The liquid medium is suitably water-based and further includes an ionic liquid-based stabilizer in the liquid medium to stabilize the dispersion of nanoparticles therein. The stabilizer can be polymeric or monomeric and generally includes a moiety with at least one quaternary ammonium cation from a corresponding ionic liquid. The dispersion suitably can be formed by shearing or otherwise mixing a mixture/combination of its components. The dispersions can be used to form nanoparticle composite films upon drying or otherwise removing the liquid medium carrier, with the stabilizer providing a nanoparticle binder in the composite film. The films can be formed on essentially any desired substrate and can impart improved electrical conductivity and/or thermal conductivity properties to the substrate.

Abstract: A dispersant for a carbon nanotube and a composition comprising the same are provided, wherein the dispersant is comprised of a structure including a head part composed of an electron-rich atom and an aromatic ring having a high affinity for the carbon nanotube and a tail part having an affinity for a dispersion medium, and thus exhibits excellent stabilizing and dispersing effects of the carbon nanotube in a variety of dispersion media including organic solvents, water or mixtures thereof. Use of the dispersant in accordance with the present invention enables convenient preparation of carbon nanotube compositions necessary for a variety of industrial fields such as emitters of field emission displays (FEDs), carbon nanotube inks, printable carbon nanotubes and the like.

Abstract: Polymer fibers having therein at least one infrared attenuating agent is provided. The infrared attenuating agent is at least substantially evenly distributed throughout the polymeric material forming the polymer fibers. In exemplary embodiments, the infrared attenuating agents have a thickness in at least one dimension of less than about 100 nanometers. Alternatively, the polymer fibers are bicomponent fibers formed of a core and a sheath substantially surrounding the core and the infrared attenuating agent is at least substantially evenly distributed throughout the sheath. The modified polymer fibers may be used to form insulation products that utilize less polymer material and subsequently reduce manufacturing costs. The insulation products formed with the modified polymers have improved thermal properties compared to insulation products formed of only non-modified polymer fibers. Additionally, the insulation product is compatible with bio-based binders.

Abstract: Disclosed herein are an aromatic imide-based dispersant for CNTs and a carbon nanotube composition comprising the same. Having an aromatic ring structure advantageously realizing adsorption on carbon nanotubes, the dispersant, even if used in a small amount, can disperse a large quantity of carbon nanotubes.

Abstract: The present invention refers to a nanostructured material comprising nanoparticles bound to its surface. The nanostructured material comprises nanoparticles which are bound to the surface, wherein the nanoparticles have a maximal dimension of about 20 nm. Furthermore, the nanostructured material comprises pores having a maximal dimension of between about 2 nm to about 5 ?m. The nanoparticles bound on the surface of the nanostructured material are noble metal nanoparticles or metal oxide nanoparticles or mixtures thereof. The present invention also refers to a method of their manufacture and the use of these materials as electrode material.

Abstract: A two terminal memory device includes first and second conductive terminals and a nanotube article. The article has at least one nanotube, and overlaps at least a portion of each of the first and second terminals. The device also includes stimulus circuitry in electrical communication with at least one of the first and second terminals. The circuit is capable of applying first and second electrical stimuli to at least one of the first and second terminal(s) to change the relative resistance of the device between the first and second terminals between a relatively high resistance and a relatively low resistance. The relatively high resistance between the first and second terminals corresponds to a first state of the device, and the relatively low resistance between the first and second terminals corresponds to a second state of the device.

Abstract: A method of dispersing nanotubes and/or nanoplatelets in a polyolefin is provided, involving A) preparing a solution comprising nanotubes or nanoplatelets or both; B) stirring the resulting solution from step (A); C) dissolving at least one polymeric material in the stirred solution from step (B) and isolating precipitates from the solution; and D) melt-blending the precipitates with at least one polyolefin, along with the nanocomposites prepared thereby, and articles formed from the nanocomposites.

Abstract: Gate electrodes are formed on a semiconducting carbon nanotube, followed by deposition and patterning of a hole-inducing material layer and an electron inducing material layer on the carbon nanotube according to the pattern of a one dimensional circuit layout. Electrical isolation may be provided by cutting a portion of the carbon nanotube, forming a reverse biased junction of a hole-induced region and an electron-induced region of the carbon nanotube, or electrically biasing a region through a dielectric layer between two device regions of the carbon nanotube. The carbon nanotubes may be arranged such that hole-inducing material layer and electron-inducing material layer may be assigned to each carbon nanotube to form periodic structures such as a static random access memory (SRAM) array.

Abstract: An apparatus and method are disclosed for electrically directly detecting biomolecular binding in a semiconductor. The semiconductor can be based on electrical percolation of nanomaterial formed in the gate region. In one embodiment of an apparatus, a semiconductor includes first and second electrodes with a gate region there between. The gate region includes a multilayered matrix of electrically conductive material with capture molecules for binding target molecules, such as antibody, receptors, DNA, RNA, peptides and aptamer. The molecular interactions between the capture molecules and the target molecules disrupts the matrix's continuity resulting in a change in electrical resistance, capacitance or impedance. The increase in resistance, capacitance or impedance can be directly measured electronically, without the need for optical sensors or labels.

Abstract: The present invention provides a chemically bonded carbon nanotube-polymer hybrid and the nanocomposite thereof, having the following advantages: functionalizing carbon nanotubes and also effectively having the carbon nanotube covalently bonded with a wide variety of polymers, even for stable and non-reactive polymers, such as commercially available polymers and high performance engineering plastics. The nanocomposite material according to the invention, compared to its matrix polymer, has higher mechanical strength, conductivity, proton conductivity, and heat stability.

Abstract: According to an embodiment a method of making a fuser member is described. The method includes, obtaining a silicone layer disposed on a substrate and coating a primer composition including an aqueous dispersion of a fluorelastomer and a curing agent on the silicone layer. A topcoat composition is coated on the primer composition which includes a fluoroplastic dispersion. The primer composition and the topcoat composition are heated to form the fuser member.

Abstract: The present invention is generally directed to devices and methods for sensing a variety of biologically-related substances. In a device aspect, the present invention is directed to a multilayer device for sensing metal ions, biological molecules, or whole cells. The device comprises: a) one or more cavities that provide for the introduction of a sample to be analyzed and one or more channels that provide for exit of the sample, or one or more channels that provide for the introduction and exit of the sample; b) one or more single-walled carbon nanotubes presented to the one or more cavities or one or more channels; c) a plurality of electrodes electrically connected to the one or more single-walled carbon nanotubes; and, a reference gate electrode presented to the one or more cavities or one or more channels. In a method aspect, the present invention is directed to a method for sensing species such as a metal, biological cells, and one or more biological molecules using the device.

Abstract: Methods and articles providing for precise aligning, positioning, shaping, and linking of nanotubes and carbon nanotubes. An article comprising: a solid surface comprising at least two different surface regions including: a first surface region which comprises an outer boundary and which is adapted for carbon nanotube adsorption, and a second surface region which is adapted for preventing carbon nanotube adsorption, the second region forming an interface with the outer boundary of the first region, at least one carbon nanotube which is at least partially selectively adsorbed at the interface. The shape and size of the patterns on the surface and the length of the carbon nanotube can be controlled to provide for selective interfacial adsorption.