Carbon Nanotubes (cnts) Patents (Class 977/742)
  • Patent number: 11309100
    Abstract: An electrically conductive, flexible, strain resilient product is produced by mixing metal coated carbon nanotube networks with a liquid polymeric resin to produce a liquid mixture, and the mixture is cured to produce the product. The networks may include welded junctions between nanotubes formed by depositing and melting metal nanoparticles on the nanotubes to form the metal coating. After the mixing step the liquid mixture may be deposited on a flexible substrate in the form of an electrical circuit. The mixing step may further include mixing the composite with a volatile solvent to produce a selected viscosity. Then, a three-dimensional printer may be used to print the product, such as an electrical circuit, on a substrate. The product is cured in an atmosphere that absorbs the solvent. The conductivity of the mixture may be adjusted by adjusting the weight percentage of the metal coated carbon nanotube networks from 50% to 90%, but a preferred range is between 75% and 85%.
    Type: Grant
    Filed: September 10, 2020
    Date of Patent: April 19, 2022
    Assignee: United States of America as represented by the Secretary of the Air Force
    Inventors: Sabyasachi Ganguli, Ajit K Roy, Chenggang Chen
  • Patent number: 10640382
    Abstract: Provided herein are methods and devices for production of carbon nanotubes (CNTs) which have high structural uniformity and low levels of impurities. The device includes, for example, a module for depositing catalyst on a substrate, a module for forming CNTs, a module for separating CNTs from the substrate, a module for collecting the CNTs and a module for continuously and sequentially advancing the substrate through the above modules. The method includes, for example, the steps of depositing catalyst on a moving substrate, forming carbon nanotubes on the substrate, separating carbon nanotubes from the substrate and collecting the carbon nanotubes from the surface, where the substrate moves sequentially through the depositing, forming, separating and collecting steps.
    Type: Grant
    Filed: August 21, 2018
    Date of Patent: May 5, 2020
    Assignee: NTHERMA CORPORATION
    Inventor: Cattien V. Nguyen
  • Patent number: 10541067
    Abstract: The carbon nanotube pellets according to the present invention are produced by using only a small amount of solvent and have increased apparent density. The present invention can improve the problems of the change of the content generated by scattering of powders and safety issues by using carbon nanotubes in the form of pellet rather than carbon nanotubes in the form of powder in composite materials. And since the density of the pellet form is higher than that of the powder form, transport, transfer and improvement become easier. Therefore, it can be more effectively applied to the manufacturing of composite materials.
    Type: Grant
    Filed: October 17, 2016
    Date of Patent: January 21, 2020
    Assignee: LG CHEM, LTD.
    Inventors: Kyung Yeon Kang, Yelin Kim, Jihee Woo, Seungyong Lee, Hyungsik Jang, Dong Hyun Cho, Sang Hoon Choy
  • Patent number: 9375751
    Abstract: A method for manufacturing an inorganic-nano structure composite, a method for manufacturing a cabon nanotube composite by using the same, and a carbon nanotube composite manufactured by the same are provided. The method for manufacturing the inorganic-nano structure composite comprises a step of doping pentavalent elements on the nanostructure; and a step of growing the inorganic material from the doping points of the pentavalent elements by dipping the nanostructure on which the pentavalent elements are doped into a precursor solution of the inorganic material, and according to the present invention the pentavalent elements such as nitrogen are doped on the nanostructure and is utilized as the crystallization point of the inorganic material, instead of forming the separate coating layer to the organic-based nanostructure, or binding the binding group to the surface.
    Type: Grant
    Filed: November 29, 2011
    Date of Patent: June 28, 2016
    Assignee: KAIST (Korea Advanced Institute of Science and Technology)
    Inventors: Sang-Ouk Kim, Won-jun Lee, Duck-hyun Lee, Jin-ah Lee
  • Patent number: 9165825
    Abstract: The invention relates to an electronic device including electric connections extending along at least two different directions, said connections being essentially formed by means of bundles of carbon nanotubes (CNT) (8), Where at least two CNT bundles comprise a portion (8a) having its axis directed along a first direction and a portion (8b) having its axis redirected along a second direction, the connections between CNT bundles being achieved by overlapping of the portions (8b) of said at least two bundles to form a connection line (4).
    Type: Grant
    Filed: June 27, 2014
    Date of Patent: October 20, 2015
    Assignee: Commissariat A L'Energie Atomique Et Aux Energies Alternatives
    Inventor: Jean Dijon
  • Patent number: 9129723
    Abstract: In one embodiment, a bulk carbon nanotube and metallic composite is provided. The bulk carbon nanotube and metallic composite includes a bulk carbon nanotube material layer including a plurality of carbon nanotubes, and a metal film applied across the bulk carbon nanotube material layer. The metal film penetrates into the interstices between individual carbon nanotubes to reduce an electrical resistance between the plurality of carbon nanotubes.
    Type: Grant
    Filed: August 18, 2014
    Date of Patent: September 8, 2015
    Assignee: The Boeing Company
    Inventor: James Antoni Wasynczuk
  • Patent number: 9067201
    Abstract: A method for generating hydrogen is disclosed. The method includes substantially submersing nanowires having metallic nanoparticles into water, exposing the water submerged nanowires to light, and collecting hydrogen gas produced by photolysis from the exposure to light.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: June 30, 2015
    Assignee: The Board of Regents For Oklahoma State University
    Inventor: Ali Kaan Kalkan
  • Publication number: 20150146865
    Abstract: Provided are a field emission device and a method of manufacturing the same. The field emission device includes an anode electrode and a cathode electrode which are opposite to each other, a counter layer provided on the anode electrode, and a field emitter provided on the cathode electrode and facing the counter layer. Herein, the field emitter includes a carbon nanotube emitting cold electrons and a photoelectric material emitting photo electrons.
    Type: Application
    Filed: July 23, 2014
    Publication date: May 28, 2015
    Inventors: Jae-woo KIM, Yoon-Ho SONG, Jin Woo JEONG, Jun Tae KANG, Sungyoul CHOI, Jeong Yong CHOI
  • Patent number: 9040364
    Abstract: A method of creating a semiconductor device is disclosed. An end of a carbon nanotube is unzipped to provide a substantially flat surface. A contact of the semiconductor device is formed. The substantially flat surface of the carbon nanotube is coupled to the contact to create the semiconductor device. An energy gap in the unzipped end of the carbon nanotube may be less than an energy gap in a region of the carbon nanotube outside of the unzipped end region.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: May 26, 2015
    Assignee: International Business Machines Corporation
    Inventors: Damon B. Farmer, Aaron D. Franklin, Joshua T. Smith, George S. Tulevski
  • Patent number: 9041137
    Abstract: A light emitting diode includes a first semiconductor layer, an active layer, a second semiconductor layer, a first electrode, a second electrode. The second electrode includes a treated patterned carbon nanotube film. The treated patterned carbon nanotube film includes at least two carbon nanotube linear units spaced from each other; and carbon nanotube groups spaced from each other. The carbon nanotube groups are located between the at least two carbon nanotube linear units, and combined with the at least two carbon nanotube linear units.
    Type: Grant
    Filed: April 19, 2013
    Date of Patent: May 26, 2015
    Assignee: Beijing FUNATE Innovation Technology Co., LTD.
    Inventors: Chen Feng, Li Qian, Yu-Quan Wang
  • Publication number: 20150140264
    Abstract: A method for making a variable-density carbon nanotube film is provided. A drawn carbon nanotube film, including a number of carbon nanotubes aligned along an aligned direction, is prepared. A number of thin regions are formed in the drawn carbon nanotube film along the aligned direction by reducing density of carbon nanotubes in each of the plurality of thin regions. A variable-density carbon nanotube film is provided and includes a number of thin regions and at least one normal region having a density of carbon nanotubes greater than that of the thin regions. The at least one normal region includes a number of carbon nanotubes substantially aligned along an aligned direction. The thin regions are arranged in the form of at least one row extending along the aligned direction.
    Type: Application
    Filed: December 3, 2014
    Publication date: May 21, 2015
    Inventor: LIANG LIU
  • Patent number: 9034213
    Abstract: The separation of single-walled carbon nanotubes (SWNTs), by electronic type using centrifugation of compositions of SWNTs and surface active block copolymers in density gradient media.
    Type: Grant
    Filed: May 31, 2011
    Date of Patent: May 19, 2015
    Assignee: Northwestern University
    Inventors: Mark C. Hersam, Alexander L. Antaris, Alexander A. Green
  • Patent number: 9034212
    Abstract: An electron emission source includes nano-sized acicular materials and a cracked portion formed in at least one portion of the electron emission source. The acicular materials are exposed between inner walls of the cracked portion. A method for preparing the electron emission source, a field emission device including the electron emission source, and a composition for forming the electron emission source are also provided in the present invention.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: May 19, 2015
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Yong-chul Kim, In-taek Han, Ho-suk Kang
  • Patent number: 9034426
    Abstract: Structured films containing multi-walled carbon nanotubes (“MWCNTs”) have enhanced mechanical performance in terms of strength, fracture resistance, and creep recovery of polyimide (“PI”) films. Preferably, the loadings of MWCNTs can be in the range of 0.1 wt % to 0.5 wt %. The strength of the new PI films dried at 60° C. increased by 55% and 72% for 0.1 wt % MWCNT and 0.5 wt % MWCNT loadings, respectively, while the fracture resistance increased by 23% for the 0.1 wt % MWCNTs and then decreases at a loading of 0.5 wt % MWCNTs. The films can be advantageously be created by managing a corresponding shift in the annealing temperature at which the maximum strength occurs as the MWCNT loadings increase.
    Type: Grant
    Filed: November 16, 2012
    Date of Patent: May 19, 2015
    Assignee: Tuskegee University
    Inventor: Heshmat Aglan
  • Patent number: 9036115
    Abstract: A liquid crystal display module includes a liquid crystal module and a polarizer stacked with each other. The polarizer includes a polarizing layer, a transparent conductive layer and at least two driving-sensing electrodes. The polarizing layer and the transparent conductive layer are stacked with each other. The at least two driving-sensing electrodes are spaced from each other and electrically connected with the transparent conductive layer.
    Type: Grant
    Filed: April 25, 2013
    Date of Patent: May 19, 2015
    Assignee: TIANJIN FUNAYUANCHUANG TECHNOLOGY CO., LTD.
    Inventor: Ho-Chien Wu
  • Patent number: 9029841
    Abstract: A method of creating a semiconductor device is disclosed. An end of a carbon nanotube is unzipped to provide a substantially flat surface. A contact of the semiconductor device is formed. The substantially flat surface of the carbon nanotube is coupled to the contact to create the semiconductor device. An energy gap in the unzipped end of the carbon nanotube may be less than an energy gap in a region of the carbon nanotube outside of the unzipped end region.
    Type: Grant
    Filed: November 27, 2012
    Date of Patent: May 12, 2015
    Assignee: International Business Machines Corporation
    Inventors: Damon B. Farmer, Aaron D. Franklin, Joshua T. Smith, George S. Tulevski
  • Patent number: 9028791
    Abstract: A system and method for manufacturing carbon nanotubes using chemical vapor deposition. The system has a first chamber comprising at least one cathode and at least one anode, a gas supply source, at least one activation energy source, at least one alignment energy source, a second chamber situated within said first chamber, said second chamber comprising: a target growth plate, comprising a catalyst and a substrate, a second cathode configured to support said target growth plate, a movable platform configured to support said second cathode, and a gas permeable barrier vertically opposed from said second cathode.
    Type: Grant
    Filed: November 27, 2012
    Date of Patent: May 12, 2015
    Assignee: Dream Matter, LLC
    Inventor: Joel Maier
  • Publication number: 20150123043
    Abstract: An electrically conductive composition of the present invention contains an expanded graphite, carbon nanotubes, and a polymer compound. An amount of the expanded graphite to be contained is not less than 30 parts by weight and not more than 70 parts by weight with respect to 100 parts by weight of a total amount of the expanded graphite and the polymer compound. An amount of the carbon nanotubes to be contained is not less than 0.5 part by weight and not more than 10 parts by weight with respect to 100 parts by weight of the total amount of the expanded graphite and the polymer compound.
    Type: Application
    Filed: May 14, 2013
    Publication date: May 7, 2015
    Applicant: Zeon Corporation
    Inventors: Tsutomu Nagamune, Masahiro Shigeta, The Ban Hoang, Mitsugu Uejima
  • Patent number: 9025372
    Abstract: A monolithic three-dimensional memory array is provided that includes a first memory level and a second memory level disposed above or below the first memory level. The first memory level includes a plurality of vertically oriented p-i-n diodes that each include a bottom heavily doped p type region. The second memory level includes a plurality of vertically oriented p-i-n diodes that each include a bottom heavily doped n type region. Numerous other aspects are also provided.
    Type: Grant
    Filed: April 10, 2014
    Date of Patent: May 5, 2015
    Assignee: SanDisk 3D LLC
    Inventor: Scott Brad Herner
  • Patent number: 9024436
    Abstract: In an embodiment, a thermal interface material (TIM) is provided. The TIM includes first and a second layers of a first transition metal, and a third layer including a plurality of carbon nanotubes supported in a flexible polymer matrix and a second transition metal coupled to sidewalls of carbon nanotubes. The first and second metal layers are in contact with first and second ends of carbon nanotube. The TIM further includes fourth and fifth layers of an alloy material coupled to the first and second metal layers, respectively. The carbon nanotube based TIM including the layers with transition metal allow improved heat transfer from an integrated circuit die to a heat spreader.
    Type: Grant
    Filed: June 19, 2013
    Date of Patent: May 5, 2015
    Assignee: Broadcom Corporation
    Inventors: Sam Ziqun Zhao, Arpit Mittal, Rezaur Rahman Khan
  • Patent number: 9023251
    Abstract: The present disclosure provides a method for making carbon nanotube slurry. The method includes the following steps. First, a carbon nanotube array is provided on a substrate, the carbon nanotube array comprises a number of carbon nanotubes. Second, the carbon nanotube array is trimmed by a laser to obtain a trimmed carbon nanotube array comprising a plurality of trimmed carbon nanotubes having uniform lengths. Third, the trimmed carbon nanotube array is removed from the substrate to obtain the trimmed carbon nanotubes. Fourth, the trimmed carbon nanotubes are mixed with an inorganic binder and an organic carrier to obtain the carbon nanotube slurry.
    Type: Grant
    Filed: August 16, 2011
    Date of Patent: May 5, 2015
    Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.
    Inventors: Qi Cai, Duan-Liang Zhou, Peng Liu, Shou-Shan Fan
  • Patent number: 9023477
    Abstract: The present invention relates to a thermally conductive pad and a method for producing the same. The thermally conductive pad includes an array of carbon nanotubes and a polymer matrix. The array of carbon nanotubes has a density in the approximate range from 0.1 g/cm3 to 2.2 g/cm3. The array of carbon nanotubes is incorporated in the polymer matrix by way of polymerization of a pre-polymer of the polymer matrix in situ. Moreover, the method for producing the thermally conductive pad is also included.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: May 5, 2015
    Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.
    Inventors: Chun-Xiang Luo, Liang Liu, Kai-Li Jiang, Chang-Hong Liu, Shou-Shan Fan
  • Patent number: 9023175
    Abstract: A film adhesive for bonding adjacent composite structures.
    Type: Grant
    Filed: August 4, 2008
    Date of Patent: May 5, 2015
    Assignee: Lockheed Martin Corporation
    Inventor: Daniel H. Hecht
  • Patent number: 9017570
    Abstract: Disclosed is a hybrid filler for an electromagnetic shielding composite material and a method of manufacturing the hybrid filler, by which electromagnetic shielding and absorbing capabilities are improved and heat generated by electromagnetic absorption is effectively removed. The hybrid filler for an electromagnetic shielding composite material includes an expandable graphite (EG) having a plurality of pores, and magnetic particles integrated with a carbon nanotube (CNT) on outer surfaces thereof in a mixed manner, wherein the magnetic particles are inserted into the pores of the EG.
    Type: Grant
    Filed: July 24, 2012
    Date of Patent: April 28, 2015
    Assignee: Hyundai Motor Company
    Inventors: Jin Woo Kwak, Kyong Hwa Song, Han Saem Lee, Byung Sam Choi
  • Patent number: 9018616
    Abstract: A rectifying antenna device is disclosed. The device comprises a pair of electrode structures, and at least one nanostructure diode contacting at least a first electrode structure of the pair and being at least in proximity to a second electrode structure of the pair. At least one electrode structure of the pair receives AC radiation, and the nanostructure diode(s) at least partially rectifies a current generated by the AC radiation.
    Type: Grant
    Filed: July 23, 2009
    Date of Patent: April 28, 2015
    Assignee: Ramot at Tel-Aviv University Ltd.
    Inventors: Yael Hanein, Amir Boag, Jacob Scheuer, Inbal Friedler
  • Patent number: 9017808
    Abstract: A method of manufacturing a thermal interface material, comprising providing a sheet comprising nano-scale fibers, the sheet having at least one exposed surface; and stabilizing the fibers with a stabilizing material disposed in at least a portion of a void space between the fibers in the sheet. The fibers may be CNT's or metallic nano-wires. Stabilizing may include infiltrating the fibers with a polymerizable material. The polymerizable material may be mixed with nano- or micro-particles. The composite system may include two films, with the fibers in between, to create a sandwich. Each capping film may include two sub films: a palladium film closer to the stabilizing material to improve adhesion; and a nano-particle film for contact with a device to be cooled or a heat sink.
    Type: Grant
    Filed: March 12, 2009
    Date of Patent: April 28, 2015
    Assignee: The Research Foundation for The State University of New York
    Inventors: Hao Wang, Bahgat Sammakia, Yayong Liu, Kaikun Yang
  • Patent number: 9017813
    Abstract: Transparent conducting electrodes include a doped single walled carbon nanotube film and methods for forming the doped single walled carbon nanotube (SWCNT) by solution processing. The method generally includes depositing single walled carbon nanotubes dispersed in a solvent and a surfactant onto a substrate to form a single walled carbon nanotube film thereon; removing all of the surfactant from the carbon nanotube film; and exposing the single walled carbon nanotube film to a single electron oxidant in a solution such that one electron is transferred from the single walled carbon nanotubes to each molecule of the single electron oxidant.
    Type: Grant
    Filed: July 18, 2012
    Date of Patent: April 28, 2015
    Assignees: International Business Machines Corporation, Egypt Nanotechnology Center
    Inventors: Mostafa M. El-Ashry, Ali Afzali-Ardakani, Bhupesh Chandra, George S. Tulevski
  • Patent number: 9017580
    Abstract: The present invention relates to polymer composite materials, more particularly relates to composite materials with tailor made surface electrical resistivities in the range of 109 to 10?1 ?/sq. and process of making the same. The process for preparing Fiber Reinforced Polymeric (FRP) Composite, said process comprising acts of homogeneously mixing 1-30% by weight of different electrically conducting fillers in matrix resin system to obtain resin mix; wetting dry preforms using the resin mix; compacting the wetted preforms to obtain green composite; curing the green composite; and post-curing the cured composite to prepare the FRP Composite.
    Type: Grant
    Filed: November 22, 2010
    Date of Patent: April 28, 2015
    Assignee: The Director General, Defence Research & Development Organisation (DRDO)
    Inventors: Samudra Dasgupta, Madishetty Narayana Rao Jagdish Kumar, Sundaram Sankaran
  • Patent number: 9018088
    Abstract: Growing spin-capable multi-walled carbon nanotube (MWCNT) forests in a repeatable fashion will become possible through understanding the critical factors affecting the forest growth. Here we show that the spinning capability depends on the alignment of adjacent MWCNTs in the forest which in turn results from the synergistic combination of a high areal density of MWCNTs and short distance between the MWCNTs. This can be realized by starting with both the proper Fe nanoparticle size and density which strongly depend on the sheet resistance of the catalyst film. Simple measurement of the sheet resistance can allow one to reliably predict the growth of spin-capable forests. The properties of pulled MWCNTs sheets reflect that there is a relationship between their electrical resistance and optical transmittance. Overlaying either 3, 5, or 10 sheets pulled out from a single forest produces much more repeatable characteristics.
    Type: Grant
    Filed: April 1, 2013
    Date of Patent: April 28, 2015
    Assignee: Board of Regents, The University of Texas Systems
    Inventors: Jae Hak Kim, Gil Sik Lee, Kyung Hwan Lee, Lawrence J. Overzet
  • Patent number: 9017634
    Abstract: Mass production of carbon nanotubes (CNT) are facilitated by methods and apparatus disclosed herein. Advantageously, the methods and apparatus make use of a single production unit, and therefore provide for uninterrupted progress in a fabrication process. Embodiments of control systems for a variety of CNT production apparatus are included.
    Type: Grant
    Filed: August 17, 2012
    Date of Patent: April 28, 2015
    Assignee: FastCAP Systems Corporation
    Inventors: Nicolò Michele Brambilla, Riccardo Signorelli, Fabrizio Martini, Oscar Enrique Corripio Luna
  • Publication number: 20150111025
    Abstract: The present invention relates to a dispersion liquid of a carbon nanotube-containing composition which contains a carbon nanotube-containing composition, a dispersant with a weight-average molecular weight of 5,000 to 60,000 as determined by gel permeation chromatography, and an aqueous solvent. The present invention provides a dispersion liquid of a carbon nanotube-containing composition which shows high dispersibility on a base while maintaining high dispersibility for the carbon nanotube-containing composition.
    Type: Application
    Filed: June 21, 2013
    Publication date: April 23, 2015
    Inventors: Hidekazu Nishino, Kazunori Hondo, Naoki Imazu
  • Patent number: 9012946
    Abstract: A light emitting diode includes a patterned carbon nanotube layer, a first semiconductor layer, a second semiconductor layer, an active layer stacked on an epitaxial growth surface of a substrate in that sequence. A first portion of the patterned carbon nanotube layer is covered by the first semiconductor layer and a second portion of the patterned carbon nanotube layer is exposed. A first electrode is electrically connected with the second semiconductor layer. A second electrode electrically is electrically connected with the second portion of the patterned carbon nanotube layer.
    Type: Grant
    Filed: July 31, 2014
    Date of Patent: April 21, 2015
    Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.
    Inventors: Yang Wei, Shou-Shan Fan
  • Patent number: 9012534
    Abstract: A resin composition comprising a polyolefin, carbon nanotubes and poly(hydroxy carboxylic acid). The invention also covers a process for preparing a resin composition comprising a polyolefin, carbon nanotubes and poly(hydroxy carboxylic acid) by (i) blending a poly(hydroxy carboxylic acid) with carbon nanotubes to form a composite (ii) blending the composite with a polyolefin. The use of poly(hydroxy carboxylic acids) as a compatibilizer to blend carbon nanotubes into polyolefins is also claimed.
    Type: Grant
    Filed: April 28, 2014
    Date of Patent: April 21, 2015
    Assignee: Total Research & Technology Feluy
    Inventors: Guy Debras, Romain Luijkx
  • Patent number: 9012567
    Abstract: Supramolecular polymers having repeat units connected by hydrogen bonds, where the repeat units are monomers, macromers, oligomers or polymers where at least one on the monomers contains at least one 2,5-diketopiperazine group are described. Composition prepared from these supramolecular polymers and articles produced from these compositions are also described.
    Type: Grant
    Filed: July 30, 2010
    Date of Patent: April 21, 2015
    Assignee: Rhodia Operations
    Inventors: Thierry Badel, Stéphane Jeol, Franck Touraud
  • Patent number: 9006667
    Abstract: A material may include a medium and carbon nanotubes dispersed in the medium. Fluorescent moieties may be attached to functional groups on a first quantity of the carbon nanotubes. The fluorescent moieties may be in a concentration in the material sufficient to make the material fluoresce in the presence of radiation. The fluorescent moieties may have an emission wavelength that is in or below the visible spectrum. The carbon nanotubes may be dispersed in the medium in a concentration sufficient to make the material electrically conductive at or above the material's electrical percolation threshold. Any suitable product may include the material. Methods for verifying the authenticity of the product may include detecting emissive radiation, testing electrical conductivity, and determining the presence of a structural characteristic of the carbon nanotubes.
    Type: Grant
    Filed: March 30, 2012
    Date of Patent: April 14, 2015
    Assignee: International Business Machines Corporation
    Inventors: Dylan J. Boday, Jason T. Wertz
  • Patent number: 9006132
    Abstract: The present invention relates to a process for preparing catalyst composition for the synthesis of carbon nanotube with high yields using the spray pyrolysis method. More particularly, this invention relates to a process for preparing catalyst composition for the synthesis of carbon nanotube comprising the steps of i) dissolving multi-component metal precursors of catalyst composition in de-ionized water; ii) spraying obtained catalytic metal precursor solution into the high temperature reactor by gas atomization method; iii) forming the catalyst composition powder by pyrolysis of gas atomized material; and iv) obtaining the catalyst composition powder, wherein said catalyst composition comprises i) main catalyst selected from Fe or Co, ii) Al, iii) optional co-catalyst at least one selected from Ni, Cu, Sn, Mo, Cr, Mn, V, W, Ti, Si, Zr or Y, iv) inactive support of Mg. Further, the catalyst composition prepared by this invention has a very low apparent density of 0.01˜0.
    Type: Grant
    Filed: May 11, 2011
    Date of Patent: April 14, 2015
    Assignee: Korea Kumho Petrochemical Co., Ltd
    Inventors: Sang-Hyo Ryu, Hyun-Kyung Sung, Namsun Choi, Wan Sung Lee, Dong Hwan Kim, Youngchan Jang
  • Patent number: 9006327
    Abstract: The subject of the present invention is a process for preparing a precomposite based on nanotubes, comprising bringing said nanotubes into contact with at least one given plasticizing agent. It also relates to a precomposite thus obtained, and to its use for conferring at least one electrical, mechanical and/or thermal property on a polymer material. It also relates to the use of a given plasticizer for improving the dispersion and/or mechanical properties and/or electrical conductivity and/or thermal conductivity of nanotubes in a polymer matrix.
    Type: Grant
    Filed: May 21, 2008
    Date of Patent: April 14, 2015
    Assignee: Arkema France
    Inventors: Patrick Piccione, Alexander Korzhenko, Benoît Brule
  • Patent number: 8999285
    Abstract: A system that receives nanomaterials, forms nanofibrous materials therefrom, and collects these nanofibrous materials for subsequent applications. The system include a housing coupled to a synthesis chamber within which nanotubes are produced. A spindle may extend from within the housing, across the inlet, and into the chamber for collecting nanotubes and twisting them into a yarn. A body portion may be positioned at an intake end of the spindle. The body portion may include a pathway for imparting a twisting force onto the flow of nanotubes and guide them into the spindle for collection and twisting into the nanofibrous yarn. Methods and apparatuses for forming nanofibrous are also disclosed.
    Type: Grant
    Filed: July 26, 2011
    Date of Patent: April 7, 2015
    Assignee: Nanocomp Technologies, Inc.
    Inventors: David S. Lashmore, Joseph J. Brown, Jared K. Chaffee, Bruce Resnicoff, Peter Antoinette
  • Patent number: 8999820
    Abstract: There are provided a fabricating method of a carbon nanotube-based field effect transistor having an improved binding force with a substrate and a carbon nanotube-based field effect transistor fabricated by the fabricating method. The method includes forming an oxide film on a substrate, forming a photoresist pattern on the oxide film, forming a metal film on the entire surface of the oxide film having the photoresist pattern, removing the photoresist by lifting off, adsorbing carbon nanotubes on the substrate from which the photoresist is removed, performing an annealing process to the substrate to which the carbon nanotubes are adsorbed, and removing the metal film. Since an adhesive strength between a substrate and carbon nanotubes increases, stability and reliability of a field effect transistor can be improved. If the field effect transistor is applied to a liquid sensor or the like, a lifespan of the sensor can be extended and reliability of a measurement result obtained by the sensor can be improved.
    Type: Grant
    Filed: October 8, 2013
    Date of Patent: April 7, 2015
    Assignee: Korea Institute of Science and Technology
    Inventors: Young Tae Byun, Sun Ho Kim, Young Min Jhon, Eun Gyeong Kim, Jae Seong Kim, Deok Ha Woo
  • Publication number: 20150093576
    Abstract: Disclosed herein are carbon nanotubes and a method of manufacturing the same. The carbon nanotubes include at least one element selected from aluminum (Al), magnesium (Mg) and silicon (Si) and at least one metal selected from cobalt (Co), nickel (Ni), iron (Fe), manganese (Mn) and molybdenum (Mo), and have an intensity ratio (ID/IG) of about 1.10 or less as measured by Raman spectroscopy and a carbon purity of about 98% or higher. The carbon nanotubes prepared by the method can be controlled in terms of carbon purity and preparation yield while eliminating the need for post-refining treatment.
    Type: Application
    Filed: September 29, 2014
    Publication date: April 2, 2015
    Inventors: Seung Yong BAE, Yun Tack LEE, Byeong Yeol KIM, Joong In KIM, Sung Hee AHN
  • Publication number: 20150090662
    Abstract: A humidifier is provided that typically includes a water filtration unit and a pump that draws filtered water from the water filtration unit, typically a carbon nanotube filter. The humidifier further includes a nozzle having an outlet orifice, wherein the nozzle is connected to the pump, where the pump forces the filtered water through the nozzle, thereby expelling the filtered water into an atmosphere in the form of a purified vapor or mist.
    Type: Application
    Filed: November 5, 2010
    Publication date: April 2, 2015
    Inventor: Keith E. Boonstra
  • Patent number: 8993327
    Abstract: Systems and methods are described for parallel macromolecular delivery and biochemical/electrochemical interface to whole cells employing carbon nanostructures including nanofibers and nanotubes. A method includes providing a first material on at least a first portion of a first surface of a first tip of a first elongated carbon nanostructure; providing a second material on at least a second portion of a second surface of a second tip of a second elongated carbon nanostructure, the second elongated carbon nanostructure coupled to, and substantially parallel to, the first elongated carbon nanostructure; and penetrating a boundary of a biological sample with at least one member selected from the group consisting of the first tip and the second tip.
    Type: Grant
    Filed: April 7, 2003
    Date of Patent: March 31, 2015
    Assignee: UT-Battelle, LLC
    Inventors: Timothy E. McKnight, Anatoli V. Melechko, Guy D. Griffin, Michael A. Guillorn, Vladimir L. Merkulov, Michael L. Simpson
  • Patent number: 8992818
    Abstract: Described herein is a method of forming a seamless transfer member suitable for use with an image forming system. The method includes spray coating a UV curable polymer and conductive particles onto an inner surface of a rotating cylindrical mandrel. The UV curable polymer is cured with ultra violet energy. The cured UV polymer is removed from the cylindrical rotatable mandrel.
    Type: Grant
    Filed: July 13, 2010
    Date of Patent: March 31, 2015
    Assignee: Xerox Corporation
    Inventors: Satchidanand Mishra, Edward A. Domm, Jin Wu, Geoffrey M. T. Foley, Edward F. Grabowski
  • Patent number: 8992878
    Abstract: Disclosed is a composition containing carbon nanotubes which meets all of the following conditions (1) to (4). (1) When observed via transmission electron microscopy, at least 50 out of every 100 carbon nanotubes are double-walled carbon nanotubes. (2) The carbon nanotubes have an average outer diameter in the range of 1.0 to 3.0 nm. (3) During thermogravimetric analysis under atmosphere at a temperature increase rate of 10° C./minute, a high temperature combustion peak is at 700 to 850° C., and the relationship between low temperature weight loss (TG(L)) and high temperature weight loss (TG(H)) is TG(H)/(TG(L)+TG(H))?0.75. (4) The composition containing carbon nanotubes has a volume resistance value between 1.0×10?2 ?·cm and 1.0×10?4 ?·cm, inclusive. The disclosed composition containing carbon nanotubes primarily has double-walled carbon nanotubes with high electrical conductivity and high heat resistance.
    Type: Grant
    Filed: March 4, 2010
    Date of Patent: March 31, 2015
    Assignee: Toray Industries, Inc.
    Inventors: Hidekazu Nishino, Hajime Kato, Naoyo Okamoto, Shuko Ikeuchi, Kenichi Sato, Shiho Tanaka, Kazuyoshi Higuchi
  • Patent number: 8993448
    Abstract: A method of forming a plurality of nanotubes is disclosed. Particularly, a substrate may be provided and a plurality of recesses may be formed therein. Further, a plurality of nanotubes may be formed generally within each of the plurality of recesses and the plurality of nanotubes may be substantially surrounded with a supporting material. Additionally, at least some of the plurality of nanotubes may be selectively shortened and at least a portion of the at least some of the plurality of nanotubes may be functionalized. Methods for forming semiconductor structures intermediate structures, and semiconductor devices are disclosed. An intermediate structure, intermediate semiconductor structure, and a system including nanotube structures are also disclosed.
    Type: Grant
    Filed: November 26, 2013
    Date of Patent: March 31, 2015
    Assignee: Micron Technology, Inc.
    Inventors: Gurtej S. Sandhu, Terry L. Gilton
  • Patent number: 8992681
    Abstract: Disclosed is a system or method for efficiently manufacturing construction materials using carbon nanomaterials. In one or more embodiments, the method comprises creating a blend of carbon nanomaterials, wherein the blend of the carbon nanomaterials includes at least one of a carbon nanofiber, a carbon nanotube, a graphite nanoparticle and an amorphous carbon. The method also includes dispersing the carbon nanomaterials and adding a plasticizer and a sand to the dispersed mixture within 3 minutes. The method also includes adding at least one of water and a cement binding agent to the dispersed mixture after the plasticizer and the sand have been added.
    Type: Grant
    Filed: January 16, 2014
    Date of Patent: March 31, 2015
    Assignee: King Abdulaziz City for Science and Technology
    Inventors: Mohammed A. Binhussain, Turki Saud Mohammed Al-Saud, Siarhei Zhdanok, Andrei Krauklis, Petr Samtsou, Eduard Batsianouski
  • Publication number: 20150085224
    Abstract: A display comprises a first substrate, a second substrate opposite to the first substrate, an electrode structure, and a light-emitting combination (LEC) layer positioned between the first and second substrates, wherein the LEC layer comprises a light emitting material and a LC material, and a horizontal or vertical electric field is generated when a voltage is applied to that electrode structure. One of exemplified displays has an electrode structure comprising a first electrode and a second electrode oppositely disposed, and the LEC layer is positioned between the first and second electrodes, wherein a vertical electric field is generated when a voltage is applied. The device can further comprise an electron injection layer and a hole transport layer. Another exemplified display has an electrode structure arranged on one side of the first substrate, and a horizontal electric field is generated when a voltage is applied.
    Type: Application
    Filed: September 18, 2014
    Publication date: March 26, 2015
    Inventors: Hsu-Kuan Hsu, Chien-Hung Chen, Hong-Yuan Chen, Mei-Chi Hsu, Pi-Ying Chuang, Chu-Hong Lai
  • Publication number: 20150085384
    Abstract: A display apparatus including a display unit including at least one pixel area and a non-pixel area, the non-pixel area dividing the at least one pixel area; and a metamaterial structure that controls a path of light emitted from the at least one pixel area.
    Type: Application
    Filed: May 5, 2014
    Publication date: March 26, 2015
    Applicant: SAMSUNG DISPLAY CO., LTD.
    Inventors: Byeong-Hwa CHOI, Seung-Bae LEE, Eun-Jung LEE, Hak-Sun KIM
  • Patent number: 8986576
    Abstract: A material consisting essentially of a vinyl thermoplastic polymer, un-functionalized carbon nanotubes and hydroxylated carbon nanotubes dissolved in a solvent. Un-functionalized carbon nanotube concentrations up to 30 wt % and hydroxylated carbon nanotube concentrations up to 40 wt % can be used with even small concentrations of each (less than 2 wt %) useful in producing enhanced conductivity properties of formed thin films.
    Type: Grant
    Filed: September 1, 2011
    Date of Patent: March 24, 2015
    Assignee: Sandia Corporation
    Inventors: Gregory O'Bryan, Jack L. Skinner, Andrew Vance, Elaine Lai Yang, Thomas Zifer
  • Patent number: 8987581
    Abstract: A photoelectric cell includes at least one photoelectric conversion module. The photoelectric module includes a first photoelectric conversion element and a second photoelectric conversion element. The first photoelectric conversion element is made of a first thermoelectric material having positive thermoelectric coefficient and comprises a first absorbing part and a first non-absorbing part. The second photoelectric conversion element is made of a second thermoelectric material having negative thermoelectric coefficient and comprises a second absorbing part and a second non-absorbing part. The first absorbing part is electrically connected with the second absorbing part.
    Type: Grant
    Filed: September 7, 2010
    Date of Patent: March 24, 2015
    Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.
    Inventors: Chun-Hua Hu, Chang-Hong Liu, Shou-Shan Fan