Gas Phase Catalytic Growth (i.e., Chemical Vapor Deposition) Patents (Class 977/843)
  • Publication number: 20120282489
    Abstract: A method of preparing crystalline graphene includes performing a first thermal treatment including supplying heat to an inorganic substrate in a reactor, introducing a vapor carbon supply source into the reactor during the first thermal treatment to form activated carbon, and binding of the activated carbon on the inorganic substrate to grow the crystalline graphene.
    Type: Application
    Filed: May 7, 2012
    Publication date: November 8, 2012
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Hyeon-jin SHIN, Jae-young CHOI, Yun-sung WOO, Seon-mi YOON
  • Patent number: 8293204
    Abstract: A novel continuous process is used for production of carbon nanotubes (CNTs) by catalytic chemical vapor deposition (CCVD) of methane on iron floating catalyst in-situ deposited on MgO in a fluidized bed reactor. In the hot zone of the reactor, sublimed ferrocene vapors were contacted with MgO powder fluidized by methane feed to produce Fe/MgO catalyst in-situ. An annular tube was used to enhance the ferrocene and MgO contacting efficiency. Multi-wall as well as single-wall CNTs were grown on the Fe/MgO catalyst while falling down the reactor. The CNTs were continuously collected at the bottom of the reactor, only when MgO powder was used. The annular tube enhanced the contacting efficiency and improved both the quality and quantity of CNTs. The SEM and TEM micrographs of the products reveal that the CNTs are mostly entangled bundles with diameters of about 20 nm. Raman spectra show that the CNTs have low amount of amorphous carbon with IG/ID ratios as high as 10.2 for synthesis at 900° C.
    Type: Grant
    Filed: December 19, 2009
    Date of Patent: October 23, 2012
    Inventors: Abbas Ali Khodadadi, Yadollah Mortazavi
  • Publication number: 20120262809
    Abstract: A monolithic optical absorber and methods of making same. The monolithic optical absorber uses an array of mutually aligned carbon nanotubes that are grown using a PECVD growth process and a structure that includes a conductive substrate, a refractory template layer and a nucleation layer. Monolithic optical absorbers made according to the described structure and method exhibit high absorptivity, high site densities (greater than 109 nanotubes/cm2), very low reflectivity (below 1%), and high thermal stability in air (up to at least 400° C.). The PECVD process allows the application of such absorbers in a wide variety of end uses.
    Type: Application
    Filed: December 13, 2011
    Publication date: October 18, 2012
    Applicant: California Institute of Technology
    Inventors: Anupama B. Kaul, James B. Coles
  • Publication number: 20120262965
    Abstract: Methods and devices relating to diodes including single-wall carbon nanotubes (SWCNT) are disclosed according to embodiments of the present invention. According to one embodiment, a diode may include one or more SWCNTs. The SWCNTs may be grouped together in multiple bundles with the SWCNTs being generally aligned parallel to each other in the bundles.
    Type: Application
    Filed: April 9, 2012
    Publication date: October 18, 2012
    Applicant: U.S. Government as represented by the Secretary of the Army
    Inventors: Shashi P. Karna, Mark Griep, Govind Mallick
  • Patent number: 8287678
    Abstract: A method for fabricating a carbon nanotube film is disclosed. A carbon nanotube array is contacted by an adhesive device having an inclined surface to adhere the carbon nanotubes. The adhesive device is then moved away from the substrate.
    Type: Grant
    Filed: December 3, 2009
    Date of Patent: October 16, 2012
    Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.
    Inventors: Chen Feng, Kai-Li Jiang, Liang Liu, Shou-Shan Fan
  • Patent number: 8287836
    Abstract: Methods of preparing single walled carbon nanotubes are provided. Carbon containing gas is contacted with a supported metal catalyst under reaction conditions to yield at least 90% single walled carbon nanotubes and at least 1 gram single walled carbon nanotubes/gram metal catalyst. The support material may be calcined at temperatures between 150 and 600° C., and may have at least one oxidized planar surface. Reaction conditions include less than 10 atmospheres pressure and less than 800° C.
    Type: Grant
    Filed: August 20, 2007
    Date of Patent: October 16, 2012
    Assignee: Hyperion Catalysis International, Inc.
    Inventors: Xinjie Zhang, Jun Ma, Howard Tennent, Robert Hoch
  • Publication number: 20120255494
    Abstract: A method for synthesizing carbon nanotubes (CNT) comprises the steps of providing a growth chamber, the growth chamber being heated to a first temperature sufficiently high to facilitate a growth of carbon nanotubes; and passing a substrate through the growth chamber; and introducing a feed gas into the growth chamber pre-heated to a second temperature sufficient to dissociate at least some of the feed gas into at least free carbon radicals to thereby initiate formation of carbon nanotubes onto the substrate.
    Type: Application
    Filed: June 19, 2012
    Publication date: October 11, 2012
    Applicant: Applied Nanostructured Solutions, LLC
    Inventors: Harry C. Malecki, Tushar K. Shah
  • Publication number: 20120251432
    Abstract: Disclosed herein is a scaled method for producing substantially aligned carbon nanotubes by depositing onto a continuously moving substrate, (1) a catalyst to initiate and maintain the growth of carbon nanotubes, and (2) a carbon-bearing precursor. Products made from the disclosed method, such as monolayers of substantially aligned carbon nanotubes, and methods of using them are also disclosed.
    Type: Application
    Filed: February 6, 2008
    Publication date: October 4, 2012
    Inventors: Christopher H. Cooper, Hai-Feng Zhang, Richard Czerw
  • Publication number: 20120251433
    Abstract: An industrial process and an apparatus for fabricating carbon nanotubes (CNTs) is provided, comprising synthesis of the carbon nanotubes by decomposing a carbon source brought into contact, in a fluidized-bed reactor, whereby the carbon nanotubes synthesized in the reactor and fixed onto the grains of catalytic substrate in the form of an entangled three-dimensional network, forming agglomerates constituting the CNT powder, are recovered sequentially by discharging them while hot, that is to say at the reaction temperature for synthesizing the CNTs, at the foot of the reactor, the sequence in which the discharges are carried out corresponding to the frequency of filling of the reactor.
    Type: Application
    Filed: March 20, 2012
    Publication date: October 4, 2012
    Applicant: Arkema France
    Inventors: Patrice Gaillard, Serge Bordere
  • Patent number: 8277770
    Abstract: Carbon atoms are fed to a catalytic metal particle 10 having a atomic arrangement of triangular lattices in a round (or partly round) of a side wall, and a graphen sheet 18 having a six-membered structure reflecting the atomic arrangement of the triangular lattices is consecutively formed by the metal catalyst, whereby a tubular structure of the carbon atoms is formed. Thus, the chirality of the tubular structure can be controlled by the growth direction of the graphen sheet with respect to the direction of the triangular lattices, and the diameter of the tubular structure can be controlled by the size of the catalytic metal particle.
    Type: Grant
    Filed: August 1, 2007
    Date of Patent: October 2, 2012
    Assignees: Fujitsu Limited, Meijo University Educational Foundation
    Inventors: Yuji Awano, Shigeya Naritsuka, Akio Kawabata, Takahiro Maruyama
  • Publication number: 20120237436
    Abstract: Methods and processes for synthesizing single-wall carbon nanotubes are provided. A carbon precursor gas is contacted with metal catalysts deposited on a support material. The metal catalysts are preferably nanoparticles having diameters less than about 3 nm. The reaction temperature is selected such that it is near the eutectic point of the mixture of metal catalyst particles and carbon. Further, the rate at which hydrocarbons are fed into the reactor is equivalent to the rate at which the hydrocarbons react for given synthesis temperature. The methods produce carbon single-walled nanotubes having longer lengths.
    Type: Application
    Filed: March 23, 2012
    Publication date: September 20, 2012
    Applicants: THE OHIO STATE UNIVERSITY RESEARCH FOUNDATION, HONDA MOTOR CO., LTD.
    Inventors: Avetik R. Harutyunyan, Toshio Tokune, Elena Mora
  • Publication number: 20120238021
    Abstract: Methods for synthesizing macroscale 3D heteroatom-doped carbon nanotube materials (such as boron doped carbon nanotube materials) and compositions thereof. Macroscopic quantities of three-dimensionally networked heteroatom-doped carbon nanotube materials are directly grown using an aerosol-assisted chemical vapor deposition method. The porous heteroatom-doped carbon nanotube material is created by doping of heteroatoms (such as boron) in the nanotube lattice during growth, which influences the creation of elbow joints and branching of nanotubes leading to the three dimensional super-structure. The super-hydrophobic heteroatom-doped carbon nanotube sponge is strongly oleophilic and an soak up large quantities of organic solvents and oil. The trapped oil can be burnt off and the heteroatom-doped carbon nanotube material can be used repeatedly as an oil removal scaffold.
    Type: Application
    Filed: March 19, 2012
    Publication date: September 20, 2012
    Applicant: William Marsh Rice University
    Inventors: Daniel Paul Hashim, Pulickel M. Ajayan, Mauricio Terrones
  • Publication number: 20120237680
    Abstract: A method for elaborating carbon nanotubes on a substrate is provided. The method may comprise a step for growing on the substrate the nanotubes by chemical vapor deposition by having a stream comprising a carbon source, a precursor source of an oxide compound and, optionally a catalyst source, pass over the substrate.
    Type: Application
    Filed: November 10, 2010
    Publication date: September 20, 2012
    Applicant: commissariat a l'energie atomique et aux energies alternatives
    Inventors: Cyrine Brahim, Hicham Maskrot
  • Patent number: 8268281
    Abstract: Methods, processes, and apparatuses for the continuous synthesis of carbon nanostructures are provided. Metal catalysts having small diameter and narrow distribution of particle sizes are prepared and continuously injected as aerosols into a reactor. The metal catalysts are supported on supports that are substantially free of carbon. The metal catalyst, in the form of a powder, is placed on a fluidized bed and aerosolized using an inert gas. The powder entrailed in the gas is injected near the top of a vertical reactor for the synthesis of SWNTs.
    Type: Grant
    Filed: May 12, 2006
    Date of Patent: September 18, 2012
    Assignee: Honda Motor Co., Ltd.
    Inventors: Avetik Harutyunyan, Toshio Tokune
  • Publication number: 20120230908
    Abstract: A substrate for growing carbon nanotubes capable of elongating single-walled carbon nanotubes of an average diameter of less than 2 nm is provided. The substrate for growing carbon nanotubes 1 is equipped with a reaction prevention layer 3 formed on a base material 2, a catalyst material layer 4 formed on the reaction prevention layer 3, a dispersion layer 5 formed on the catalyst material layer 4, and a dispersion promotion layer 6 formed on the dispersion layer 5.
    Type: Application
    Filed: March 7, 2012
    Publication date: September 13, 2012
    Applicants: WASEDA UNIVERSITY, HONDA MOTOR CO., LTD.
    Inventors: Toshiyuki OHASHI, Toshio TOKUNE, Masahiro OTA, Hidefumi NIKAWA, Hiroshi KAWARADA, Takumi OCHIAI
  • Publication number: 20120231270
    Abstract: A method of implementing a carbon nanotube thermal interface material onto a heat sink that includes growing carbon nanotubes on said heat sink by chemical vapor deposition and compressing the carbon nanotubes onto metallic surfaces to increase a contact surface area between the carbon nanotubes and the metallic surfaces. The increase in the contact surface area is the area of the carbon nanotubes that is in contact with the metallic surfaces.
    Type: Application
    Filed: November 5, 2010
    Publication date: September 13, 2012
    Inventors: Ali Dhinojwala, Sunny Sethi
  • Publication number: 20120231163
    Abstract: A method and an apparatus for efficiently producing a high-purity CNT assembly of a high specific surface area are provided in which a feedstock gas is contacted to a catalyst in an optimum form for CNT growth. A carbon nanotube producing apparatus of the present invention includes: a synthesis furnace; a gas supply pipe and a gas exhaust pipe in communication with the synthesis furnace; heating means that heats inside of the synthesis furnace to a predetermined temperature; and gas blowing means that blows a feedstock gas into the synthesis furnace after the feedstock gas is supplied through the gas supply pipe. The feedstock gas supplied through the gas supply pipe is supplied into a heating region of the synthesis furnace heated by the heating means, so as to produce a carbon nanotube from a surface of a catalyst layer provided on a base. The feedstock gas is evacuated through the gas exhaust pipe.
    Type: Application
    Filed: June 17, 2010
    Publication date: September 13, 2012
    Inventors: Kenji Hata, Satoshi Yasuda, Don N. Futaba, Motoo Yumura
  • Patent number: 8257678
    Abstract: Systems and methods for the formation of carbon-based nanostructures are generally described. In some embodiments, the nanostructures may be formed on a nanopositor. The nanopositor can comprise, in some embodiments, at least one of metal atoms in a non-zero oxidation state and metalloid atoms in a non-zero oxidation state. For example, the nanopositor may comprise a metal oxide, a metalloid oxide, a metal chalcogenide, a metalloid chalcogenide, and the like. The carbon-based nanostructures may be grown by exposing the nanopositor, in the presence or absence of a growth substrate, to a set of conditions selected to cause formation of carbon-based nanostructures on the nanopositor. In some embodiments, metal or metalloid atoms in a non-zero oxidation state are not reduced to a zero oxidation state during the formation of the carbon-based nanostructures. In some cases, metal or metalloid atoms in a non-zero oxidation state do not form a carbide during the formation of the carbon-based nanostructures.
    Type: Grant
    Filed: July 30, 2010
    Date of Patent: September 4, 2012
    Assignee: Massachusetts Institute of Technology
    Inventors: Stephen A. Steiner, III, Brian L. Wardle
  • Patent number: 8258060
    Abstract: The sheet structure includes a plurality of linear structure bundles including a plurality of linear structures of carbon atoms arranged at a first gap, and arranged at a second gap larger than the first gap, a graphite layer formed in a region between the plurality of linear structure bundles and connected to the plurality of linear structure bundles, and a filling layer filled in the first gap and the second gap and retaining the plurality of linear structure bundles and the graphite layer.
    Type: Grant
    Filed: August 13, 2010
    Date of Patent: September 4, 2012
    Assignee: Fujitsu Limited
    Inventors: Daiyu Kondo, Taisuke Iwai, Yoshitaka Yamaguchi, Ikuo Soga
  • Publication number: 20120219489
    Abstract: Methods and apparatus to generate carbon nanostructures from organic materials are described. Certain embodiments provide solid waste materials into a furnace, that pyrolyzes the solid waste materials into gaseous decomposition products, which are then converted to carbon nanostructures. Methods and apparatuses described herein provide numerous advantages over conventional methods, such as cost savings, reducion of handling risks, optimization of process conditions, and the like.
    Type: Application
    Filed: March 26, 2010
    Publication date: August 30, 2012
    Applicant: Northeastern University
    Inventors: Yiannis Levendis, Henning Richter, Chuanwei Zhuo
  • Publication number: 20120219490
    Abstract: A method for simultaneously producing carbon nanotubes and hydrogen according to the present invention is a method for simultaneously producing carbon nanotubes and hydrogen, in which using a carbon source containing carbon atoms and hydrogen atoms and being decomposed in a heated state, and a catalyst for producing carbon nanotubes and H2 from the carbon source, the above carbon nanotubes are synthesized on a support in a heated state, placed in a reactor, and simultaneously, the above H2 is synthesized from the above carbon source, the method comprising a synthesis step of flowing a source gas comprising the above carbon source over the above support, on which the above catalyst is supported, to synthesize the above carbon nanotubes on the above support and simultaneously synthesize the above H2 in a gas flow.
    Type: Application
    Filed: September 9, 2010
    Publication date: August 30, 2012
    Inventors: Suguru Noda, Dong Young Kim, Toshio Osawa, Hisashi Sugime, Kei Hasegawa, Eisuke Haba
  • Patent number: 8252713
    Abstract: Methods and systems of preparing a catalyst to be used in the synthesis of carbon nanotubes through Chemical Vapor Depositions are disclosed. The method may include a mixture comprising at least one of an iron catalyst source and a catalyst support. In another aspect, a method of synthesizing multi-walled carbon nanotubes using the catalyst is disclosed. The method may include driving a reaction in a CVD furnace and generating at least one multi-walled carbon nanotube through the reaction. The method also includes depositing the catalyst on the CVD furnace and driving a carbon source with a carrier gas to the CVD furnace. The method further includes decomposing the carbon source in the presence of the catalyst under a sufficient gas pressure for a sufficient time to grow at least one multi-walled carbon nanotube.
    Type: Grant
    Filed: November 10, 2010
    Date of Patent: August 28, 2012
    Assignee: King Abdulaziz City Science and Technology
    Inventors: Mohammed Abdullah Bahattab, Ibrahim M Al-Najjar, Abdulaziz A Bagabas
  • Patent number: 8252405
    Abstract: The present invention provides single-walled carbon nanotubes and systems and methods for their preparation.
    Type: Grant
    Filed: October 26, 2006
    Date of Patent: August 28, 2012
    Assignee: The Board of Trustees of the Leland Stanford Junior University
    Inventors: Hongjie Dai, David Mann, Guangyu Zhang
  • Patent number: 8252264
    Abstract: A process for the production of carbon nanostructures by an oxidation-reduction method is described. The growth of carbon nanorods, nanotubes, and nanoclusters on planar and non planar substrates, and free standing is demonstrated. In one embodiment a reactive gas is generated in situ and reacted with a carbide while the byproducts are removed, thereby adjusting the equilibrium to favor the formation of the carbon nanostructured product.
    Type: Grant
    Filed: April 7, 2009
    Date of Patent: August 28, 2012
    Assignee: Riehl-Johnson Holdings, LLC
    Inventors: Bill L. Riehl, Jim R. Riehl, Lee R. Riehl
  • Publication number: 20120213691
    Abstract: According to one embodiment, there is provided a graphite nano-carbon fiber provided by using an apparatus having a reactor capable of keeping a reducing atmosphere inside thereof, a metal substrate arranged as a catalyst in the reactor, a heater heating the metal substrate, a pyrolysis gas source supplying pyrolysis gas obtained by thermally decomposing a wood material in a reducing atmosphere to the reactor, a scraper scraping carbon fibers produced on the metal substrate, a recovery container recovering the scraped carbon fibers, and an exhaust pump discharging exhaust gas from the reactor. The carbon fibers are linear carbon fibers with a diameter of 25 to 250 nm formed with layers of graphenes stacked in a longitudinal direction.
    Type: Application
    Filed: August 5, 2011
    Publication date: August 23, 2012
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventors: Katsuki Ide, Tetsuya Mine, Jun Yoshikawa, Tsuyoshi Noma, Masao Kon, Kazutaka Kojo
  • Patent number: 8246886
    Abstract: A method and system for aligning nanotubes within an extensible structure such as a yarn or non-woven sheet. The method includes providing an extensible structure having non-aligned nanotubes, adding a chemical mixture to the extensible structure so as to wet the extensible structure, and stretching the extensible structure so as to substantially align the nanotubes within the extensible structure. The system can include opposing rollers around which an extensible structure may be wrapped, mechanisms to rotate the rollers independently or away from one another as they rotate to stretch the extensible structure, and a reservoir from which a chemical mixture may be dispensed to wet the extensible structure to help in the stretching process.
    Type: Grant
    Filed: July 9, 2008
    Date of Patent: August 21, 2012
    Assignee: Nanocomp Technologies, Inc.
    Inventors: David S. Lashmore, Robert Braden, Anastasios John Hart, John Welch
  • Patent number: 8246927
    Abstract: A chemical vapor deposition (CVD) device is equipped with a reaction vessel tube and a small vessel substrate in an electric furnace and with a heater and a thermocouple at the periphery thereof. A gas supply portion is connected to one of the reaction vessel tubes, and a pressure adjusting valve and an exhaust portion are connected to the other of the reaction vessel tubes, controlled by a control section such that the exhaust portion vacuum-exhausts the reaction vessel tube interior, the heater sublimates the small vessel substrate interior by rising temperature of catalyst iron chloride, and the gas supply portion bleeds an acetylene gas into the reaction vessel tube. As a result, iron chloride and the acetylene gas vapor-phase-react, a silicon oxide surface layer is formed to form growth nucleus of carbon nanotubes, and carbon nanotubes are grown so as to be oriented vertically.
    Type: Grant
    Filed: February 24, 2009
    Date of Patent: August 21, 2012
    Assignee: National University Corporation Shizuoka University
    Inventors: Yoku Inoue, Morihiro Okada
  • Publication number: 20120204890
    Abstract: Highly-ordered nanostructure arrays and methods of preparation of the highly-ordered nanostructure arrays for adsorption of pollutants are disclosed. The highly-ordered nanostructure arrays can be vertically aligned metal oxide nanotube arrays having metal-deposited carbon nanotubes within the nanostructures. The metal-deposited carbon nanotubes within the nanostructures increase the adsorption of the pollutants, as discussed in greater detail below. The highly-ordered nanostructure arrays can be included in various filters, such as cigarette filters, to adsorb carcinogens and pollutants from the tobacco smoke.
    Type: Application
    Filed: April 19, 2012
    Publication date: August 16, 2012
    Inventors: ALIMORAD RASHIDI, KHEIROLLAH JAFARI JOZANI, MAHNAZ POURKHALIL, MAHDI MOHAJERI, HAMZEH GHORBANI, MARYAM RASHTCHI
  • Publication number: 20120205834
    Abstract: The present invention provides apparatus and methods for growing fullerene nanotube forests, and forming nanotube films, threads and composite structures therefrom. In some embodiments, an interior-flow substrate includes a porous surface and one or more interior passages that provide reactant gas to an interior portion of a densely packed nanotube forest as it is growing. In some embodiments, a continuous-growth furnace is provided that includes an access port for removing nanotube forests without cooling the furnace substantially. In other embodiments, a nanotube film can be pulled from the nanotube forest without removing the forest from the furnace. A nanotube film loom is described. An apparatus for building layers of nanotube films on a continuous web is described.
    Type: Application
    Filed: April 24, 2012
    Publication date: August 16, 2012
    Inventors: Alexander B. Lemaire, Charles A. Lemaire, Leif T. Stordal, Dale J. Thomforde
  • Patent number: 8241602
    Abstract: Method for the manufacture of carbon nanotubes by thermal decomposition of at least one gaseous hydrocarbon (14) in the presence of a solid catalyst in a reactor (4) into which the catalyst is introduced via an inlet lock chamber (17) flushed by an inert gas (21, 22, 25, 26) and from which the carbon nanotubes are withdrawn via an outlet lock chamber (37) which is flushed with a flow of inert gas (39, 40).
    Type: Grant
    Filed: August 4, 2005
    Date of Patent: August 14, 2012
    Assignee: Universite de Liege, Interface Enterprises-Universite
    Inventors: Jean-Paul Pirard, Christophe Bossuot, Patrick Kreit
  • Patent number: 8236272
    Abstract: Methods and systems of preparing a catalyst to be used in the synthesis of carbon nanotubes through Chemical Vapor Depositions are disclosed. The method may include a mixture comprising at least one of an iron catalyst source and a catalyst support. In another aspect, a method of synthesizing multi-walled carbon nanotubes using the catalyst is disclosed. The method may include driving a reaction in a CVD furnace and generating at least one multi-walled carbon nanotube through the reaction. The method also includes depositing the catalyst on the CVD furnace and driving a carbon source with a carrier gas to the CVD furnace. The method further includes decomposing the carbon source in the presence of the catalyst under a sufficient gas pressure for a sufficient time to grow at least one multi-walled carbon nanotube.
    Type: Grant
    Filed: June 2, 2011
    Date of Patent: August 7, 2012
    Assignee: King Abdulaziz City for Science and Technology
    Inventors: Mohammed Abdullah Bahattab, Ibrahim M Al-Najjar, Abdulaziz A Bagabas
  • Patent number: 8236271
    Abstract: The present invention relates to a process for the production of hydrogen gas and carbon nanotubes from catalytic decomposition of ethanol. More particularly, the invention relates to a process for preparing hydrogen gas and carbon nanotubes from catalytic decomposition of bioethanol over Ni/La203 catalyst is obtainable by H2 reduction of a LaNi03 perovskite catalyst precursor. Additionally, the present invention relates to the use of a Ni/La203 catalyst obtainable by H2 reduction of a LaNi03 perovskite catalyst precursor in the manufacture of hydrogen gas and carbon nanotubes from gaseous ethanol.
    Type: Grant
    Filed: July 2, 2008
    Date of Patent: August 7, 2012
    Assignees: Centre National de la Recherche Scientifique, Universite de Poitiers, University of Antioquia
    Inventors: Catherine Dupeyrat-Batiot, Jean-Michel Tatibouet, Joël Barrault, Fanor Mondragon-Pérez, Jaime Andres Gallego Marin, German-Alberto Sierra Gallego
  • Patent number: 8236389
    Abstract: A method for making a carbon nanotube film, the method comprising the following steps of: (a) supplying a substrate; (b) forming at least one strip-shaped catalyst film on the substrate, a width of the strip-shaped catalyst films ranging from approximately 1 micrometer to 20 micrometers; (c) growing at least one strip-shaped carbon nanotube array on the substrate using a chemical vapor deposition method; and (d) causing the at least one strip-shaped carbon nanotube array to fold along a direction parallel to a surface of the substrate, thus forming at least one carbon nanotube film.
    Type: Grant
    Filed: November 6, 2008
    Date of Patent: August 7, 2012
    Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.
    Inventors: Kai-Li Jiang, Qun-Qing Li, Liang Liu, Shou-Shan Fan
  • Publication number: 20120195820
    Abstract: A method of producing carbon nanotubes, comprising, in a reaction chamber: evaporating at least a partially melted electrode comprising a catalyst by an electrical arc discharge; condensing the evaporated catalyst vapors to form nanoparticles comprising the catalyst; and decomposing gaseous hydrocarbons in the presence of the nanoparticles to form carbon nanotubes on the surface of the nanoparticles. Also a system for producing carbon nanotubes, comprising: a reactor comprising two electrodes, wherein at least one of the electrodes is at least a partially melted electrode comprising a catalyst, the reactor adapted for evaporating the at least partially melted electrode by an electrical arc discharge and for condensing its vapors to form nanoparticles comprising the catalyst, wherein the electrodes are disposed in a reaction chamber for decomposing gaseous hydrocarbons in the presence of the nanoparticles to form carbon nanotubes on the surface of the nanoparticles.
    Type: Application
    Filed: January 30, 2011
    Publication date: August 2, 2012
    Applicant: MCD TECHNOLOGIES S.A R.L.
    Inventors: Mikhail Rudolfovich Predtechensky, Oleg Mikhailovich Tukhto, Ilya Yurievich Koval
  • Publication number: 20120192931
    Abstract: Disclosed is a carbonaceous nanocomposite including: a substrate; a graphene sheet formed on a top surface of the substrate in parallel with the substrate; and a carbonaceous nanomaterial provided on another surface of the graphene sheet, the nanomaterial having an aspect ratio of 2 to 75,000 to make a predetermined angle with the graphene sheet. The carbonaceous nanocomposite according to the present disclosure has excellent adhesivity to the substrate and can be attached to the substrate without undergoing a pasting process. Since a two-directional current flow is generated, the electrical resistance of the graphene and carbon nanotube is considerably reduced. In addition, the graphene allows the carbon nanotube to have a high current density and a high specific surface area, thereby accelerating a redox reaction. The excellent heat-radiating property of the graphene sheet allows fast transfer of heat generated in the carbon nanotube to outside, thereby avoiding degradation of the carbon nanotube.
    Type: Application
    Filed: May 20, 2009
    Publication date: August 2, 2012
    Inventors: Min-Hyon Jeon, Hyon-Kwang Choi, Sook-Hyun Hwang, Hyun-Kook Kim
  • Publication number: 20120189530
    Abstract: A system for producing hydrogen and a carbon nanoproduct includes a hydrocarbon feed gas supply configured to supply a hydrocarbon feed gas at a selected flow rate, a reactor having a hollow reactor cylinder with an enclosed inlet adapted to continuously receive the hydrocarbon feed gas, a reaction chamber in fluid communication with the inlet, and an enclosed outlet in fluid communication with the reaction chamber adapted to discharge a product gas comprised of hydrogen and unreacted hydrocarbon feed gas, along with the carbon nanoproduct. The system also includes a catalyst transport system adapted to move a selected amount of a metal catalyst through the reaction chamber at a rate dependent on the flow rate of the hydrocarbon feed gas to form the product gas. The system also includes a carbon separator adapted to separate the carbon product from the product gas and from the metal catalyst.
    Type: Application
    Filed: January 19, 2012
    Publication date: July 26, 2012
    Applicant: Eden Energy Ltd.
    Inventors: Roger W. Marmaro, Max A. Schmid, Justin Fulton, Gary Lee Anderson, Gregory Solomon
  • Patent number: 8226902
    Abstract: Provided are an apparatus for manufacturing carbon nanotubes and a method of manufacturing carbon nanotubes with the apparatus. A plurality of carbon-nanotube-synthesizing units are disposed in series to continuously perform a carbon-nanotube-synthesizing process. Thus, carbon nanotubes having a uniform quality can be synthesized.
    Type: Grant
    Filed: September 25, 2008
    Date of Patent: July 24, 2012
    Assignee: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Suk-Won Jang, Ho-Soo Hwang
  • Publication number: 20120177808
    Abstract: Direct resistive heating is used to grow nanotubes out of carbon and other materials. A growth-initiated array of nanotubes is provided using a CVD or ion implantation process. These processes use indirect heating to heat the catalysts to initiate growth. Once growth is initiated, an electrical source is connected between the substrate and a plate above the nanotubes to source electrical current through and resistively heat the nanotubes and their catalysts. A material source supplies the heated catalysts with carbon or another material to continue growth of the array of nanotubes. Once direct heating has commenced, the source of indirect heating can be removed or at least reduced. Because direct resistive heating is more efficient than indirect heating the total power consumption is reduced significantly.
    Type: Application
    Filed: April 14, 2008
    Publication date: July 12, 2012
    Inventors: DELMAR L. BARKER, Mead M. Jordan, William R. Owens
  • Publication number: 20120171106
    Abstract: A system and method for growing nanotubes out of carbon and other materials using CVD uses a catalytic transmembrane to separate a feedstock chamber from a growth chamber and provide catalytic material with separate catalytic surfaces to absorb carbon atoms from the feedstock chamber and to grow carbon nanotubes in the growth chamber. The catalytic transmembrane provides for greater flexibility to independently control both the gas environment and pressure in the chambers to optimize absorption and carbon growth and to provide instrumentation in the growth chamber for in-situ control of defects or observation of the carbon nanotube growth.
    Type: Application
    Filed: January 4, 2008
    Publication date: July 5, 2012
    Inventors: Delmar L. Barker, W. Howard Poisl, Brian J. Zelinski, Jon N. Leonard
  • Publication number: 20120171107
    Abstract: The present invention relates to a method of forming single-walled carbon nanotubes. The method comprises contacting a gaseous carbon source with mesoporous TUD-1 silicate at suitable conditions. The mesoporous TUD-1 silicate comprises a metal of groups 3-13 of the Periodic Table of the Elements.
    Type: Application
    Filed: July 5, 2010
    Publication date: July 5, 2012
    Applicant: NANYANG TECHNOLOGICAL UNIVERSITY
    Inventors: Yuan Chen, Yanhui Yang
  • Patent number: 8207658
    Abstract: A chemical vapor deposition (CVD) method using a vapor phase catalyst of directly growing aligned carbon nanotubes on a metal surfaces. The method allows for fabrication of carbon nanotube containing structures that exhibit a robust carbon nanotube metal junction without a pre-growth application of solid catalytic materials to the metal surface or the use of solder or adhesives in a multi-step fabrication process.
    Type: Grant
    Filed: August 25, 2006
    Date of Patent: June 26, 2012
    Assignee: Rensselaer Polytechnic Institute
    Inventors: Saikat Talapatra, Swastik Kar, Sunil Pal, Robert Vajtai, Pulickel Ajayan
  • Publication number: 20120156124
    Abstract: The present disclosure provides for systems and methods for producing carbon nanotubes. More particularly, the present disclosure provides for improved systems and methods for producing single wall carbon nanotubes (SWNTs) by chemical vapor deposition (CVD) using a carbon source in the presence of a catalyst. In exemplary embodiments, the present disclosure provides for improved systems and methods for producing single wall carbon nanotubes (SWNTs) by chemical vapor deposition (CVD) using carbon monoxide (CO) disproportionation in the presence of a catalyst composition on a catalyst support material. In one embodiment, the present disclosure provides for systems and methods for producing single wall carbon nanotubes (SWNTs) by chemical vapor deposition (CVD) using carbon monoxide (CO) disproportionation with CO pressure from about 0.20 atm to about 1.0 atm in the presence of a cobalt/molybdenum catalyst composition on a magnesium oxide catalyst support.
    Type: Application
    Filed: February 12, 2008
    Publication date: June 21, 2012
    Applicant: NEW JERSEY INSTITUTE OF TECHNOLOGY
    Inventors: Amit Goyal, Iqbal Zafar
  • Patent number: 8202505
    Abstract: An aligned carbon nanotube bulk structure capable of attaining high density and high hardness not found so far. The aligned carbon nanotube bulk structure has a plurality of carbon nanotubes (CNTs) applied with a density-increasing treatment, and having alignment in a predetermined direction, the structure has a degree of anisotropy of 1:3 or more between the direction of alignment and the direction vertical to the direction of alignment, and the intensity by irradiating X-rays along the direction of alignment is higher than the intensity by irradiating X-rays from the direction vertical to the direction of alignment at a (002) peak in X-ray diffraction data, and the degree of alignment thereof satisfies predetermined conditions.
    Type: Grant
    Filed: August 25, 2009
    Date of Patent: June 19, 2012
    Assignee: National Institute of Advanced Industrial Science and Technology
    Inventors: Kenji Hata, Don N. Futaba, Motoo Yumura, Sumio Iijima
  • Patent number: 8202818
    Abstract: The present invention relates to a catalyst composition for preparing carbon nanotube and a process for preparing carbon nanotube using the same. More particularly, this invention relates to a process for preparing carbon nanotube by the chemical vapor deposition method through the decomposition of lower saturated or unsaturated hydrocarbons using a multi-component metal catalyst composition containing active metal catalyst from Co, V, Al and inactive porous support. Further, the present invention affords the carbon nanotube having 5˜30 nm of diameter and 100˜10,000 of aspect ratio in a high catalytic yield.
    Type: Grant
    Filed: May 26, 2009
    Date of Patent: June 19, 2012
    Assignee: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Hyun-Kyung Sung, Wan Sung Lee, Namsun Choi, Dong Hwan Kim, Youngchan Jang
  • Publication number: 20120148475
    Abstract: Apparatus to produce carbon nanotubes (CNTs) of arbitrary length using a chemical vapor deposition (CVD) process reactor furnace is described, where the CNTs are grown axially along a portion of the length of the furnace. The apparatus includes a spindle and a mechanism for rotating the spindle. The spindle located within a constant temperature region of the furnace and operable to collect the CNT around the rotating spindle as the CNT is grown within the furnace.
    Type: Application
    Filed: December 14, 2010
    Publication date: June 14, 2012
    Inventors: Keith Daniel Humfeld, Venkatacha Parameswaran
  • Publication number: 20120145999
    Abstract: Provided are semiconductor devices and methods of manufacturing the same. The semiconductor device includes a substrate including a first top surface, a second top surface lower in level than the first top surface, and a first perpendicular surface disposed between the first and second top surfaces, a first source/drain region formed under the first top surface, a first nanowire extended from the first perpendicular surface in one direction and being spaced apart from the second top surface, a second nanowire extended from a side surface of the first nanowire in the one direction, being spaced apart from the second top surface, and including a second source/drain region, a gate electrode on the first nanowire, and a dielectric layer between the first nanowire and the gate electrode.
    Type: Application
    Filed: July 29, 2011
    Publication date: June 14, 2012
    Applicant: ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTE
    Inventors: Dongwoo Suh, Sung Bock Kim, Hojun Ryu
  • Publication number: 20120148474
    Abstract: The invention is directed to a method of positioning nanoparticles on a patterned substrate. The method comprises providing a patterned substrate with selectively positioned recesses, and applying a solution or suspension of nanoparticles to the patterned substrate to form a wetted substrate. A wiper member is dragged across the surface of the wetted substrate to remove a portion of the applied nanoparticles from the wetted substrate, and leaving a substantial number of the remaining portion of the applied nanoparticles disposed in the selectively positioned recesses of the substrate. The invention is also directed to a method of making carbon nanotubes from the positioned nanoparticles.
    Type: Application
    Filed: February 17, 2012
    Publication date: June 14, 2012
    Applicant: International Business Machines Corporation
    Inventors: Charles T. Black, Christopher B. Murray, Robert L. Sandstrom
  • Publication number: 20120149551
    Abstract: A catalyst material for preparing nanotubes, especially carbon nanotubes, said material being in the form of solid particles, said particles including a porous substrate supporting two superposed catalytic layers, a first layer, directly positioned on the substrate, including at least one transition metal from column VIB of the Periodic Table, preferably molybdenum, and a second catalytic layer, positioned on the first layer, comprising iron. Also, a process for preparing same and to a process for the synthesis of nanotubes using this catalyst material.
    Type: Application
    Filed: August 16, 2010
    Publication date: June 14, 2012
    Applicants: INSTITUT NATIONAL POLYTECHNIQUE DE TOULOUSE (INPT), ARKEMA FRANCE
    Inventors: Patrice Gaillard, Serge Bordere, Philippe Serp, Brigitte Caussat, Julien Beausoleil
  • Publication number: 20120149824
    Abstract: The invention relates to a method for producing carbon nanotubes in the agglomerated form and thus obtained novel carbon nanotube agglomerates.
    Type: Application
    Filed: August 7, 2010
    Publication date: June 14, 2012
    Applicant: BAYER MATERIALSCIENCE AG
    Inventors: Heiko Hocke, Ralph Weber, Elmar Bramer-Weger
  • Publication number: 20120148476
    Abstract: Disclosed is a method for continuously and stably producing a CNT assembly having a high specific surface area in a catalyst activating substance-containing, high-carbon-concentration environment. Specifically disclosed is a method for growing a carbon nanotube by contacting a feedstock gas and a catalyst-activating substance to a catalyst on a base.
    Type: Application
    Filed: June 17, 2010
    Publication date: June 14, 2012
    Inventors: Kenji Hata, Don N. Futaba, Motoo Yumura