With Group Viii Metal Or Metal Oxide (i.e., Iron, Or Platinum Group Metal, Or Oxide Thereof) Patents (Class 208/111.35)
  • Patent number: 7087152
    Abstract: A waxy hydrocarbon feed is catalytically dewaxed with a catalyst that has been selectively activated. The selective activation of the catalyst involves contacting the dewaxing catalyst with a feed mixture containing waxy hydrocarbon and at least one oxygenate. The process results in improved catalyst performance resulting in improved yield of isomerate at equivalent pour.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: August 8, 2006
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ian A. Cody, William J. Murphy, Sylvain Hantzer
  • Patent number: 7077948
    Abstract: Process for the catalytic dewaxing of a hydrocarbon oil feed including waxy molecules and more than 500 ppmw of sulphur or sulphur containing compounds by contacting the oil feed under catalytic dewaxing conditions with a catalyst composition comprising at least a hydrogenation component, dealuminated aluminosilicate zeolite crystallites and a low acidity refractory oxide binder material which is essentially free of alumina.
    Type: Grant
    Filed: November 16, 1999
    Date of Patent: July 18, 2006
    Assignee: Shell Oil Company
    Inventors: Guy Barre, Jean-Paul Darnanville, Laurent Georges Huve
  • Patent number: 7048845
    Abstract: Increased yields of middle distillate products are obtained in a hydrocracking process by the use of a catalyst containing a Beta zeolite which has been hydrothermally treated to adjust the distribution of relatively weak and strong acid sites. The number of strong acid sites is reduced, preferably by steaming at a temperature above 750° C. for at least one hour, with the acidity distribution being measured by pyridine IR adsorption values taken at 150° C., and 300° C., and 450° C.
    Type: Grant
    Filed: November 7, 2001
    Date of Patent: May 23, 2006
    Assignee: UOP LLC
    Inventor: Lorenz J. Bauer
  • Patent number: 7041866
    Abstract: A catalyst and process is disclosed to selectively upgrade a paraffinic feedstock to obtain an isoparaffin-rich product for blending into gasoline. The catalyst comprises a support of a sulfated oxide or hydroxide of a Group IVB (IUPAC 4) metal, a first component comprising at least one Group III A (IUPAC 13) component, and at least one platinum-group metal component which is preferably platinum.
    Type: Grant
    Filed: October 8, 2002
    Date of Patent: May 9, 2006
    Assignee: UOP LLC
    Inventor: Ralph D. Gillespie
  • Patent number: 7037422
    Abstract: A process for producing a high RON naphtha which comprises contacting a hydrocarbon feed stream comprising a mixture of the isomers of C5 and C6 paraffins with a CFI zeolite, such as CIT-5, in an adsorption zone, whereby the branched isomers of the C5 and C6 paraffins are preferentially adsorbed by the CFI zeolite as compared to the straight chain isomers, and recovering a naphtha product from the adsorption zone having a higher RON than the hydrocarbon feed stream, also including a hydroisomerization process and a hydrocracking process.
    Type: Grant
    Filed: February 25, 2003
    Date of Patent: May 2, 2006
    Assignee: Chevron U.S.A. Inc
    Inventors: Theo Maesen, Tom Harris
  • Patent number: 7029572
    Abstract: A process for producing a high RON naphtha which comprises contacting a hydrocarbon feed stream comprising a mixture of the isomers of C5 and C6 paraffins with ATS zeolite, such as SSZ-55, in an adsorption zone, whereby the branched isomers of the C5 and C6 paraffins are preferentially adsorbed by the ATS zeolite as compared to the straight chain isomers, and recovering a naphtha product from the adsorption zone having a higher RON than the hydrocarbon feed stream, also including a hydroisomerization process and a hydrocracking process.
    Type: Grant
    Filed: February 25, 2003
    Date of Patent: April 18, 2006
    Assignee: Chevron U.S.A. Inc
    Inventors: Theo Maesen, Tom Harris
  • Patent number: 7005059
    Abstract: The invention relates to a catalyst for the transformation of hydrocarbon-containing feedstocks, in particular hydrotreatment, comprising at least one metal of group VIIB and at least one hydro-dehydrogenating metal (of the non-noble metals of group VIII and/or the metals of group VIB, preferably molybdenum or tungsten) and at least one porous matrix, generally of the amorphous oxide or poorly crystallized type. The catalyst also contains silicon, boron, or phosphorus. It can also optionally contain at least one halogen.
    Type: Grant
    Filed: November 7, 1997
    Date of Patent: February 28, 2006
    Assignee: Institut Francais du Petrole
    Inventors: Juliette Quartararo, Samuel Mignard, Slavie Kasztelan
  • Patent number: 6984309
    Abstract: The invention pertains to a catalyst that consists of a substrate made of at least one matrix and at least one zeolite that is selected from the group composed of the zeolites ZSM-48, EU-11, and ZBM-30, whereby, at the level of the zeolite, at least one noble metal of Group VIII is deposited on said substrate. The noble metal is preferably located on the outer surfaces of the zeolite crystals, and more preferable at the mouths of pores. The invention also pertains to a process for preparing the catalyst and utilizing the catalyst to treat hydrocarbon feedstocks, and especially for improving their pour points.
    Type: Grant
    Filed: March 2, 2001
    Date of Patent: January 10, 2006
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Nathalie Marchal-George, Johan Martens, Marion Claude
  • Patent number: 6977322
    Abstract: A catalyst and process is disclosed to selectively upgrade a paraffinic feedstock to obtain an isoparaffin-rich product for blending into gasoline. The catalyst comprises a support of a tungstated oxide or hydroxide of a Group IVB (IUPAC 4) metal, a first component of at least one lanthanide element, yttrium or mixtures thereof, which is preferably ytterbium or holmium, and at least one platinum-group metal component which is preferably platinum.
    Type: Grant
    Filed: July 19, 2004
    Date of Patent: December 20, 2005
    Assignee: UOP LLC
    Inventor: Ralph D. Gillespie
  • Patent number: 6949181
    Abstract: Method for impregnating a Group VIII metal on a molecular sieve—binder extrudate wherein the binder comprises a low acidity refractory oxide binder material, which is essentially free of alumina, by a) contacting the molecular sieve—binder extrudate with an aqueous solution of a corresponding Group VIII metal nitrate salt having a pH of below 8, wherein the molar ratio between the Group VIII metal cations in the solution and the number of sorption sites present in the extrudate is equal to or larger than 1, and b) drying the molecular sieve—binder extrudate obtained from step a).
    Type: Grant
    Filed: October 21, 2003
    Date of Patent: September 27, 2005
    Assignee: Shell Oil Company
    Inventors: Thomas Joris Remans, Ingrid Maria Van Vegchel
  • Patent number: 6902664
    Abstract: A catalyst composition comprising a minor amount of a low acidity, highly dealuminated ultra stable Y zeolite having an Alpha value of less than about 5, preferable less than about 3 and Broensted acidity measured by FT-IR from about 1 to about 20, preferably from about 1-10, micro mole/g of, a homogeneous, amorphous silica-alumina cracking component having an SB ratio of from about 0.7 to about 1.3, wherein a crystalline alumina phase is present in an amount of no greater than about 10%, preferably no greater than 5% and a catalytic amount of hydrogenation component selected from the group consisting of a Group VI metal, a Group VIII metal, and mixtures thereof is disclosed. The present invention provides for a process for converting hydrocarbonaceous oils comprising contacting the hydrocarbonaceous oils with the catalyst under suitable hydrocarbon conversion conditions.
    Type: Grant
    Filed: November 8, 2002
    Date of Patent: June 7, 2005
    Assignee: Chevron U.S.A. Inc.
    Inventor: Hye Kyung C. Timken
  • Patent number: 6893553
    Abstract: The invention pertains to a hydroprocessing catalyst comprising a Group VIB hydrogenation metal component, a non-noble Group VIII hydrogenation metal component, an alkali metal component, and silica. The catalyst has a specific surface area, total pore volume and pore size distribution. The invention also pertains to the use of this catalyst in hydroprocessing of heavy hydrocarbon feedstocks, e.g, in an ebullated bed process.
    Type: Grant
    Filed: January 20, 2000
    Date of Patent: May 17, 2005
    Assignees: Akzo Nobel N.V., Nippon Ketjen Co., Ltd.
    Inventors: Satoshi Abe, Yasuhito Takahashi, Akira Hino, Mark De Boer
  • Patent number: 6863803
    Abstract: A two stage hydrodesulfurizing process for producing low sulfur distillates. A distillate boiling range feedstock containing in excess of about 3,000 wppm sulfur is hydrodesulfurized in a first hydrodesulfurizing stage containing one or more reaction zones in the presence of hydrogen and a hydrodesulfurizing catalyst. The liquid product stream thereof is passed to a first separation stage wherein a vapor phase product stream and a liquid product stream are produced. The liquid product stream, which has a substantially lower sulfur and nitrogen content than the original feedstream is passed to a second hydrodesulfurizing stage also containing one or more reaction zones where it is reacted in the presence of hydrogen and a second hydrodesulfurizing catalyst at hydrodesulfurizing conditions. The catalyst in any one or more reaction zones is a bulk multimetallic catalyst comprised of at lease one Group VIII non-noble metal and at least two Group VIB metals.
    Type: Grant
    Filed: January 14, 2000
    Date of Patent: March 8, 2005
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Kenneth Lloyd Riley, Darlene Schuette, Stuart Leon Soled, Sabato Miseo, William Lee Schuette
  • Patent number: 6860986
    Abstract: A catalyst composition comprising a low acidity, highly dealuminated ultra stable Y zeolite having an Alpha value of less than about 3 and Broensted acidity measured by FT-IR from about 1 to about 20, preferably from about 1-10, micro mole/g of, an amorphous cracking component and a catalytic amount of hydrogenation component selected from the group consisting of a Group VI metal, a Group VIII metal, and mixtures thereof is disclosed. The present invention provides for a process for converting hydrocarbonaceous oils comprising contacting the hydrocarbonaceous oils with the catalyst under suitable hydrocarbon conversion conditions. Such processes in include, but are not limited to, single stage hydrocracking, two-stage hydrocracking, series-flow hydrocracking, mild hydrocracking, lube hydrocracking, hydrotreating, lube hydrofinishing, hydrodesulphurization, hydrodenitrification, catalytic dewaxing and catalytic cracking.
    Type: Grant
    Filed: November 8, 2002
    Date of Patent: March 1, 2005
    Assignee: Chevron U.S.A. Inc.
    Inventors: Hye Kyung C. Timken, Lucy Melinda Bull, Thomas V. Harris
  • Patent number: 6860987
    Abstract: The present invention pertains to a process for the hydroprocessing of hydrocarbon feedstocks wherein said hydrocarbon feedstocks are contacted, at hydroprocessing conditions, with a catalyst composition comprising at least one Group VIII non-noble metal component and at least two Group VIB metal components. The catalyst composition further comprises at least about 0.01 mole of an organic oxygen-containing additive per mole of the total of Group VIB metals and Group VIII non-noble metals present in the catalyst composition. The total of the Group VIII and Group VIB metal components, calculated as oxides, make up at least about 50 wt. % of the catalyst composition, calculated on dry weight.
    Type: Grant
    Filed: April 15, 2003
    Date of Patent: March 1, 2005
    Assignee: Akzo Nobel N.V.
    Inventors: Frans Lodewijk Plantenga, Sonja Eijsbouts, Marinus Bruce Cerfontain
  • Patent number: 6858128
    Abstract: A catalytic hydrocracking process wherein a hydrocarbonaceous feedstock and a liquid recycle stream is contacted with hydrogen in a hydrocracking reaction zone at elevated temperature and pressure to obtain conversion to lower boiling hydrocarbons. A liquid hydrocarbonaceous stream produced from the effluent of the hydrocracking reaction zone is fractionated in a first zone of a divided-wall fractionation zone to produce at least one liquid hydrocarbonaceous product stream and a liquid hydrocarbonaceous stream containing hydrocarbons boiling at a temperature in the boiling range of the feedstock and heavy polynuclear aromatic compounds. At least a portion of the liquid hydrocarbonaceous stream containing heavy polynuclear aromatic compounds is introduced into a second zone of the divided-wall fractionation zone to produce a stream rich in polynuclear aromatic compounds.
    Type: Grant
    Filed: January 22, 2002
    Date of Patent: February 22, 2005
    Assignee: UOP LLC
    Inventors: Richard K. Hoehn, Bradford L. Bjorklund
  • Publication number: 20040245147
    Abstract: A process to produce base oils through the use of fractionation, solvent extraction, dewaxing, and hydrofinishing
    Type: Application
    Filed: April 16, 2004
    Publication date: December 9, 2004
    Inventor: Heather A. Boucher Ashe
  • Publication number: 20040238411
    Abstract: The present invention pertains to a catalyst comprising 7-20 wt. % of a Group VIB metal component, calculated as trioxide on the weight of the catalyst, and 0.5 to 6 wt. % of a Group VIII metal component, calculated as oxide on the weight of the catalyst, on a porous inorganic carrier. The catalyst has a specific surface area of 100-180 m2/g, a total pore volume of at least 0.55 ml/g, at least 50% of the total pore volume in pores with a diameter of at least 20 nm (200 Π), 10-30% of the total pore volume in pores with a diameter of at least 200 nm (2000 Π), and 0-1% of the total pore volume in pores with a diameter above 1000 nm (10000 Π). The catalyst is particularly suitable for the hydroprocessing of heavy hydrocarbon feeds of which at least 50 wt. % boils above 538° C. (1000° F.). It is especially advantageous for the hydroprocessing of feedstocks of which at least 80 wt. % boils above 538° C. (1000° F.).
    Type: Application
    Filed: July 7, 2004
    Publication date: December 2, 2004
    Inventors: Satoshi Abe, Akira Hino, Masafumi Shimokawe, Katsuhisa Fujita
  • Publication number: 20040232047
    Abstract: A hydrocracking catalyst containing at least one matrix, at least one zeolite chosen from the group formed by the zeolites ZBM-30, ZSM-48, EU-2, and EU-11, at least one Y zeolite, at least one hydro-dehydrogenating metal chosen from the group formed by the metals from Group VIB and Group VIII of the periodic table, optionally at least one element chosen from the group formed by phosphorus, boron and silicon, optionally at least one element from Group VIIA, and optionally at least one element from Group VIIB is used in a process of hydrocracking/hydroconversion of hydrocarbon charges.
    Type: Application
    Filed: March 24, 2004
    Publication date: November 25, 2004
    Inventors: Eric Benazzi, Emmanuelle Guillon, Johan Martens
  • Publication number: 20040232048
    Abstract: A catalyst comprising at least one ZBM-30 zeolite, synthesized in the presence of a particular structuring agent such as triethylenetetramine, at least one porous mineral matrix, at least one hydro-dehydrogenating element, preferably chosen from the elements of Group VIB and Group VIII of the periodic table, is used in order to improve the pour point of charges containing long (more than 10 carbon atoms) linear and/or slightly branched paraffins, in particular in order to convert, with a good yield, charges having high pour points to at least one cut having a low pour point and a high viscosity index for oil bases.
    Type: Application
    Filed: March 24, 2004
    Publication date: November 25, 2004
    Inventors: Eric Benazzi, Emmanuelle Guillon, Johan Martens
  • Publication number: 20040226860
    Abstract: Hydrocracking process for the conversion of a hydrocarbon feedstock that comprises a hydrorefining stage, in which the feedstock is brought into contact with the hydrogen in the presence of a hydrorefining catalyst at a temperature T1, a separation stage in which at least a portion of the converted products that are formed during the hydrorefining stage and a fraction that comprises the unconverted products are separated, and a hydrocracking stage in which the fraction that comprises the unconverted products is at least in part brought into contact with hydrogen in the presence of an amorphous hydrocracking catalyst that comprises a substrate, palladium and platinum, at a temperature T2 that is less than T1, whereby the difference between T1 and T2 is between 5 and 50° C., preferably between 10 and 40° C., and more preferably between 15 and 30° C.
    Type: Application
    Filed: February 20, 2004
    Publication date: November 18, 2004
    Inventors: Patrick Bourges, Eric Benazzi, Patrick Euzen
  • Patent number: 6808620
    Abstract: The present invention relates to new crystalline molecular sieve SSZ-64 prepared using a N-cyclobutylmethyl-N-ethylhexamethyleneiminium cation or N-cyclobutylmethyl-N-ethylheptamethyleneiminium cation structure directing agent, and processes employing SSZ-64 in a catalyst.
    Type: Grant
    Filed: August 1, 2002
    Date of Patent: October 26, 2004
    Assignee: Chevron U.S.A. Inc.
    Inventor: Saleh Elomari
  • Patent number: 6802958
    Abstract: The invention pertains to a process for preparing spherical oxide particles comprising the steps of shaping a starting material comprising an oxide hydrate into particles of substantially constant length by leading the material to a set of two rolls rotating towards each other followed by leading the material to a roll equipped with grooves to form rod-type shapes, cutting the rod-type shapes into particles of substantially constant length, converting the thus formed particles into spheres, and heating the particles to convert the oxide hydrate into an oxide. The process results in particles in which there is substantially no difference in density between the core portion and the shell portion of the particles, which results in a high abrasion resistance. The particles prepared by the claimed process are particularly suitable for the preparation of hydroprocessing catalysts, more in particular for the preparation of hydroprocessing catalysts suitable for the hydroprocessing of heavy hydrocarbon feeds.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: October 12, 2004
    Assignees: Nippon Ketjen Co., Ltd., Akzo Nobel NV
    Inventors: Nobuhito Matsumoto, Eiichi Yano, Masafumi Shimowake, Tetsuro Kamo
  • Patent number: 6783661
    Abstract: A process for producing oils with high viscosity indices from oil distillates or effluents from a conversion unit comprises the following steps: a) catalytic hydrotreatment of the feed in the presence of hydrogen and a non zeolitic catalyst; b) fractionation of at least a portion of the effluent from step a) or step d) described below to an oil residue; c) fractionation by thermal diffusion of at least a portion of the oil residue obtained from step b) into oil fractions with different compositions and viscosity indices. Step b) can be preceded by a step d) for hydrocracking the effluent obtained from step a) in the presence of hydrogen and a zeolitic catalyst.
    Type: Grant
    Filed: August 24, 2000
    Date of Patent: August 31, 2004
    Assignee: Institut Francais du Petrole
    Inventors: Patrick Briot, Christophe Gueret, Jean-Claude Hipeaux, Eric Benazzi, Pierre Marion, Alain Billon
  • Publication number: 20040163999
    Abstract: The present invention pertains to a process for hydroprocessing a heavy hydrocarbon oil, comprising contacting a heavy hydrocarbon oil in the presence of hydrogen with a mixture of hydroprocessing catalyst I and hydroprocessing catalyst II. The process of the invention combines high contaminant removal with high conversion, low sediment formation, and high process flexibility.
    Type: Application
    Filed: December 8, 2003
    Publication date: August 26, 2004
    Inventors: Frans Lodewijk Plantenga, Katsuhisa Fujita, Satoshi Abe
  • Publication number: 20040159581
    Abstract: Process for transforming a gas-oil fraction that makes it possible to produce a fuel that has a quality according to stringent requirements in terms of sulfur content, aromatic compound content, cetane number, boiling point, T95, of 95% of the compounds and density, d15/4, at 15° C. This process comprises a hydrorefining stage and a hydrocracking stage, whereby the latter uses a catalyst that contains at least one zeolite. The conversion of products that have a boiling point of less than 150° C. is, throughout the two stages of hydrocracking and hydrorefining, less than 40% by weight and, for the hydrorefining stage, between 1 and 15% by weight. The temperature, TR2, of the hydrocracking stage is less than the temperature, TR1, of the hydrorefining stage, and the variation between temperatures TR1 and TR2 is between 0 and 80° C.
    Type: Application
    Filed: February 19, 2003
    Publication date: August 19, 2004
    Applicant: Institut Francais du Petrole
    Inventors: Eric Benazzi, Patrick Bourges, Christophe Gueret, Pierre Marion
  • Publication number: 20040138059
    Abstract: This invention relates to silico-aluminum substrates, catalysts, and the hydrocracking and hydrotreatment processes that use them.
    Type: Application
    Filed: October 30, 2003
    Publication date: July 15, 2004
    Inventors: Patrick Euzen, Carole Bobin, Magalie Roy-Auberger, Eric Benazzi, Patrick Bourges, Christophe Gueret
  • Publication number: 20040129604
    Abstract: Catalytic dewaxing of paraffin containing feeds, preferably feeds produced from syn gas using a non-shifting Fischer-Tropsch catalyst, is accomplished at relatively low hydrogen partial pressures without substantial effect on the life of the dewaxing catalyst having a certain pore structure.
    Type: Application
    Filed: August 29, 2003
    Publication date: July 8, 2004
    Inventors: William Berlin Genetti, Zhaozhong Jiang, Daniel Francis Ryan, Adeana Richelle Bishop, Loren Leon Ansell, Jack Wayne Johnson, Nancy Marie Page
  • Publication number: 20040092385
    Abstract: A catalyst composition comprising a minor amount of a low acidity, highly dealuminated ultra stable Y zeolite having an Alpha value of less than about 5, preferable less than about 3 and Broensted acidity measured by FT-IR from about 1 to about 20, preferably from about 1-10, micro mole/g of, a homogeneous, amorphous silica-alumina cracking component having an SB ratio of from about 0.7 to about 1.3, wherein a crystalline alumina phase is present in an amount of no greater than about 10%, preferably no greater than 5% and a catalytic amount of hydrogenation component selected from the group consisting of a Group VI metal, a Group VIII metal, and mixtures thereof is disclosed. The present invention provides for a process for converting hydrocarbonaceous oils comprising contacting the hydrocarbonaceous oils with the catalyst under suitable hydrocarbon conversion conditions.
    Type: Application
    Filed: November 8, 2002
    Publication date: May 13, 2004
    Inventor: Hye Kyung C. Timken
  • Publication number: 20040092384
    Abstract: A catalyst composition comprising a low acidity, highly dealuminated ultra stable Y zeolite having an Alpha value of less than about 3 and Broensted acidity measured by FT-IR from about 1 to about 20, preferably from about 1-10, micro mole/g of, an amorphous cracking component and a catalytic amount of hydrogenation component selected from the group consisting of a Group VI metal, a Group VIII metal, and mixtures thereof is disclosed. The present invention provides for a process for converting hydrocarbonaceous oils comprising contacting the hydrocarbonaceous oils with the catalyst under suitable hydrocarbon conversion conditions. Such processes in include, but are not limited to, single stage hydrocracking, two-stage hydrocracking, series-flow hydrocracking, mild hydrocracking, lube hydrocracking, hydrotreating, lube hydrofinishing, hydrodesulphurization, hydrodenitrification, catalytic dewaxing and catalytic cracking.
    Type: Application
    Filed: November 8, 2002
    Publication date: May 13, 2004
    Inventors: Hye Kyung C. Timken, Lucy Melinda Bull, Thomas V. Harris
  • Patent number: 6733658
    Abstract: The invention concerns a process for improving the pour point of a feed comprising paraffins containing more than 10 carbon atoms, in which process the feed to be treated is brought into contact with a catalyst comprising an EU-1 zeolite and at least one hydro-dehydrogenating element, at a temperature which is in the range 170° C. to 500° C., a pressure in the range 1 to 250 bar and an hourly space velocity in the range 0.05 to 100 h−1, in the presence of hydrogen in a proportion of 50 to 2000 l/l of feed. The oils obtained have good pour points and high viscosity indices (VI). The process is also applicable to gas oils and other feeds requiring a reduction of pour point. The invention also concerns an EU-1 zeolite from which a portion of elements T (Al, Ga, Fe or B) have been removed and which has an Si/T atomic ratio of at least 10.
    Type: Grant
    Filed: June 24, 1998
    Date of Patent: May 11, 2004
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Nathalie George-Marchal, Christophe Gueret, Patrick Briot, Alain Billon, Pierre Marion
  • Publication number: 20040072676
    Abstract: Fischer-Tropsch hydrocarbon synthesis using a noncobalt catalyst is used to produce waxy fuel and lubricant oil hydrocarbons from synthesis gas derived from natural gas. The waxy hydrocarbons are hydrodewaxed, with reduced conversion to lower boiling hydrocarbons, by contacting the waxy hydrocarbons, in the presence of hydrogen, with an unsulfided hydrodewaxing catalyst that has been reduced and then treated by contacting it with a stream containing one or more oxygenates.
    Type: Application
    Filed: August 29, 2003
    Publication date: April 15, 2004
    Inventors: Adeana Richelle Bishop, William Berlin Genetti, Jack Wayne Johnson, Loren Leon Ansell, Nancy Marie Page
  • Patent number: 6719895
    Abstract: The present invention relates to a hydrocracking process including contacting a hydrocarbon feed with a catalyst which is carried out at a pressure of at least 2 MPa, a temperature of at least 230° C., using a quantity of hydrogen of at least 100 Nl hydrogen/l of feed and with an hourly space velocity of 0.1-10 h−1. The catalyst includes 0.1-99.7% by weight of at least one alumina matrix; 0.1-80% by weight of at least one globally non dealuminated Y zeolite with a lattice parameter of more than 2.438 nm, a global SiO2/Al2O3 mole ratio of less than 8, and a framework SiO2/Al2O3 mole ratio of less than 21 and more than the global SiO2/Al2O3 mole ratio; 0.1-30% by weight of at least one group VIII metal and/or 1-40% by weight of at least one group VIB metal (% oxide); 0.1-20% by weight of at least one promoter element selected from the group formed by boron and silicon (% oxide); 0-20% by weight of at least one group VIIA element; 0-20% by weight of phosphorous (% oxide); and 0.
    Type: Grant
    Filed: October 1, 2001
    Date of Patent: April 13, 2004
    Assignee: Institut Français du Pétrole
    Inventors: Samuel Mignard, Nathalie George-Marchal, Slavik Kasztelan
  • Patent number: 6716337
    Abstract: The invention pertains to a carrier composition comprising (a) at least 30 wt % of a synthetic cracking component, based on the total weight of the carrier composition, which comprises oxidic compounds of one or more trivalent metallic elements, tetravalent metallic elements, and divalent metallic elements, said cracking component comprising elemental clay platelets with an average diameter of 1 &mgr;m or less and an average degree of stacking of 20 platelets per stack or less, and/or comprising a cogel with a saponite content CA of less than 60%, in which the total of sodium and potassium amounts to less than 1 wt %, based on the total weight of the cogel, and (b) 1-25 wt % of a zeolite Y, based on the total weight of the carrier composition, with a unit cell size below 24.35 Å. The invention further pertains to a catalyst comprising said carrier composition and at least a hydrogenation metal, and a process for converting heavy feedstock into middle distillates using said catalyst.
    Type: Grant
    Filed: January 31, 2001
    Date of Patent: April 6, 2004
    Assignee: Akzo Nobel NV
    Inventors: Jan Nieman, Johannes Wilhelmus Maria Sonnemans, Bas De Kroes
  • Patent number: 6712953
    Abstract: The invention relates to a catalyst that contains at least one matrix, at least one zeolite and at least one hydro-dehydrogenating element that is located at the matrix (deposited on the catalyst or contained in the matrix), in which the zeolite contains in its porous network at least one element of group VIB and/or group VIII. Said hydro-dehydrogenating element preferably belongs to group VIB and/or to group VIII of the periodic table. The catalyst contains at least one promoter element)phosphorus, boron, silicon).
    Type: Grant
    Filed: October 16, 2000
    Date of Patent: March 30, 2004
    Assignee: Institut Francais du Pétrole
    Inventors: Slavik Kasztelan, Nathalie Marchal-George, Tivadar Cseri, Pierre Leyrit, Philippe Dascotte, Elisabeth Rosenberg
  • Patent number: 6709570
    Abstract: A method for preparing a catalyst comprising a zeolite and a low acidity refractory oxide binder which is essentially free of alumina which method comprises: (a) preparing an extrudable mass comprising a substantially homogenous mixture of zeolite, water, a source of the low acidity refractory oxide binder present which comprises an acid sol, and an amine compound, (b) extruding the extrudable mass resulting from step (a), (c) drying the extrudate resulting from step (b); and, (d) calcining the dried extrudate resulting from step (c).
    Type: Grant
    Filed: September 18, 2000
    Date of Patent: March 23, 2004
    Assignee: Shell Oil Company
    Inventors: Maria Barbara Hendrica Van Crijnen-Beers, Jean-Paul Darnanville, Carolus Matthias Anna Maria Mesters, Thomas Joris Remans
  • Patent number: 6709571
    Abstract: This invention is directed to an extinction recycle naphtha hydrocracking processes. Large pore zeolite catalysts with Constraint Indices less than 2, such as USY or beta, which are loaded with noble metals such as Pt or Pd or with transition metals such as Ni in combination with Mo or W are employed. Preferably, low hydrogen partial pressures, and a feedstock relatively rich in hydrogen and low in aromatics content, are used, in order to extend catalyst cycle length.
    Type: Grant
    Filed: July 20, 1999
    Date of Patent: March 23, 2004
    Assignee: Mobil Oil Corporation
    Inventors: Kenneth J. Del Rossi, David A. Pappal, Brenda H. Rose
  • Publication number: 20040050753
    Abstract: The invention concerns a process for moderate pressure hydrocracking (i.e., at a hydrogen partial pressure of more than 70 bars and at most 100 bars) with a conversion of at least 80% by volume, of a feed with a T5 temperature in the range 250° C. to 400° C. and a T95 temperature of at most 470° C. (T5 and T95 measured in accordance with ASTM-D2887), to produce a diesel with a 95% distillation point of less than 360° C., a sulphur content of at most 50 ppm and a cetane number of more than 51. The process operates with or without a recycle of the liquid effluent. Highly advantageously, it can be integrated into a refinery layout comprising catalytic cracking.
    Type: Application
    Filed: September 22, 2003
    Publication date: March 18, 2004
    Inventors: Pierre Marion, Eric Benazzi, Didier Duee, Christophe Gueret, Alain Billon
  • Publication number: 20040045871
    Abstract: Increased yields of middle distillate products are obtained in a hydrocracking process by the use of a catalyst containing a Beta zeolite which has been hydrothermally treated to adjust the distribution of relatively weak and strong acid sites. The number of strong acid sites is reduced, preferably by steaming at a temperature above 750° C. for at least one hour, with the acidity distribution being measured by pyridine IR adsorption values taken at 150° C., and 300° C., and 450° C.
    Type: Application
    Filed: November 7, 2001
    Publication date: March 11, 2004
    Inventor: Lorenz J. Bauer
  • Publication number: 20040040888
    Abstract: This invention relates to an improved process for hydrocracking into a stage of hydrocarbon feedstocks, using in a first reaction zone a pretreatment catalyst that exhibits a low acidity according to a standard activity test and an amorphous acid catalyst for hydrocracking that is free of zeolite in a second reaction zone that is located downstream from the first.
    Type: Application
    Filed: June 6, 2003
    Publication date: March 4, 2004
    Inventors: Eric Benazzi, Patrick Bourges, Christophe Gueret, Tivadar Cseri, Hugues Dulot
  • Publication number: 20040031727
    Abstract: Cationic layered materials, a process for their preparation and their use in hydrocarbon conversion, purification, and synthesis processes, such as fluid catalytic cracking. Cationic layered materials are especially suitable for the reduction of SOx and NOx emissions and the reduction of the sulfur and nitrogen content in fuels like gasoline and diesel. The new preparation process avoids the use of metal salts and does not require the formation of anionic clay as an intermediate.
    Type: Application
    Filed: June 24, 2003
    Publication date: February 19, 2004
    Inventors: Paul O'Conner, William Jones, Dennis Stamires
  • Patent number: 6682650
    Abstract: A catalyst support including a zeolite having an Al/Si atomic ratio of 0.01-0.1 and mesopores having a pore diameter in the range of 5-30 nm, and ultrafine particles composited to inside walls of the mesopores. The superfine particles are those of an oxide of a metal selected from Ti, Zr and Hf.
    Type: Grant
    Filed: June 5, 2001
    Date of Patent: January 27, 2004
    Assignees: Japan Cooperation Center, Petroleum, National Institute of Advanced Industrial Science and Technology
    Inventors: Kosaku Honna, Yasuhiro Araki, Yasuo Miki, Hiromichi Shimada
  • Patent number: 6660157
    Abstract: The invention relates to a new and improved heavy oil hydrocracking process using a multimetallic liquid catalyst in a slurry-bed reactor, particularly an improvement of lightweight treatment of heavy oil in the petroleum processing technology. According to the present invention, a slurry-bed hydrocracking reactor and a highly dispersed multimetallic liquid catalyst are mainly applied during the process. A fixed-bed hydrotreating reactor is also used on line to enhance lightweight oil yield from heavy oil under normal pressure.
    Type: Grant
    Filed: November 2, 2001
    Date of Patent: December 9, 2003
    Assignees: PetroChina Company Limited, University of Petroleum
    Inventors: Guohe Que, Cungui Men, Chunxu Meng, An Ma, Jiashun Zhou, Wenan Deng, Zongxian Wang, Baoquan Mu, Chenguang Liu, Dong Liu, Shichang Liang, Bin Shi
  • Patent number: 6652735
    Abstract: A process for isomerization dewaxing of a hydrocarbon feed which includes contacting the hydrocarbon feed with a large pore size, small crystal size, crystalline molecular sieve and an intermediate pore size, small crystal size, crystalline molecular sieve to produce a dewaxed product with a reduced pour point and a reduced cloud point. In a preferred embodiment, the feed is contacted with the molecular sieves sequentially, first with the large pore sieve followed by the intermediate pore sieve.
    Type: Grant
    Filed: April 26, 2001
    Date of Patent: November 25, 2003
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Thomas F. Degnan, Philip J. Angevine
  • Patent number: 6652738
    Abstract: The invention pertains to a process for the hydroprocessing of a hydrocarbon feedstock wherein said feedstock is contacted at hydroprocessing conditions with a catalyst composition which comprises bulk catalyst particles which comprise at least one Group VIII non-noble metal and at least two Group VIB metals. The Group VIII and Group VIB metals comprise from about 50 wt. % to about 100 wt. %, calculated as oxides, of the total weight of the bulk catalyst particles. The metals are present in the catalyst composition in their oxidic and/or sulfidic state. The catalyst composition has an X-ray diffraction pattern in which the characteristic full width at half maximum does not exceed 2.5° when the Group VIB metals are molybdenum, tungsten, and, optionally, chromium, or does not exceed 4.0° when the Group VIB metals are molybdenum and chromium or tungsten and chromium.
    Type: Grant
    Filed: January 16, 2003
    Date of Patent: November 25, 2003
    Assignee: Akzo Nobel N.V.
    Inventors: Sonja Eijsbouts, Bob Gerardus Oogjen, Harmannus Willem Homan Free, Marinus Bruce Cerfontain, Kenneth Lloyd Riley, Stuart Leon Soled, Sabato Miseo
  • Patent number: 6635792
    Abstract: Disclosed are a process for producing aromatic hydrocarbon compounds and liquefied petroleum gas (LPG) from a hydrocarbon feedstock having boiling points of 30-250° C. and a catalyst useful therefor. In the presence of said catalyst, aromatic components in the hydrocarbon feedstock are converted to BTX-enriched components of liquid phase through hydrodealkylation and/or transalkylation, and non-aromatic components are converted to LPG-enriched gaseous materials through hydrocracking. The products of liquid phase may be separated as benzene, toluene, xylene, and C9 or higher aromatic compounds, respectively according to their different boiling points, while LPG is separated from the gaseous products, in a distillation tower.
    Type: Grant
    Filed: November 20, 2001
    Date of Patent: October 21, 2003
    Assignee: SK Corporation
    Inventors: Sun Choi, Seung-Hoon Oh, Yong-Seung Kim, Beung-Soo Lim, Kyeong-Hak Seong
  • Publication number: 20030178344
    Abstract: The present invention pertains to a process for the hydroprocessing of hydrocarbon feedstocks wherein said hydrocarbon feedstocks are contacted, at hydroprocessing conditions, with a catalyst composition comprising at least one Group VIII non-noble metal component and at least two Group VIB metal components. The catalyst composition further comprises at least about 0.01 mole of an organic oxygen-containing additive per mole of the total of Group VIB metals and Group VIII non-noble metals present in the catalyst composition. The total of the Group VIII and Group VIB metal components, calculated as oxides, make up at least about 50 wt. % of the catalyst composition, calculated on dry weight.
    Type: Application
    Filed: April 15, 2003
    Publication date: September 25, 2003
    Inventors: Frans Lodewijk Plantenga, Sonja Eijsbouts, Marinus Bruce Cerfontain
  • Publication number: 20030173252
    Abstract: The invention concerns a catalyst for the hydrogenation, hydroisomerisation, hydrocracking and/or hydrodesulfurisation, of hydrocarbon feedstocks, said catalyst consisting of a substantially binder free bead type support material obtained through a sol-gel method, and a catalytically active component selected from precious metals, the support comprising 5 to 50 wt. % of at least one molecular sieve material and 50 to 95 wt. % of silica-alumina.
    Type: Application
    Filed: February 5, 2003
    Publication date: September 18, 2003
    Inventor: Marius Vaarkamp
  • Publication number: 20030173256
    Abstract: A catalyst for hydrotreating gas oil, which comprises an inorganic oxide support having provided thereon: at least one selected from metals in the Group 6 of the periodic table at from 10 to 30% by weight, at least one selected from metals in the Group 8 of the periodic table at from 1 to 15% by weight, phosphorus at from 1.5 to 6% by weight, and carbon at from 2 to 14% by weight, each in terms of a respective oxide amount based on the catalyst, wherein the catalyst has a specific surface area of from 220 to 300 m2/g, a pore volume of from 0.35 to 0.6 ml/g, and an average pore diameter of about from 65 to 95 Å; a process for producing the catalyst; and a method for hydrotreating gas oil, which comprises subjecting a gas oil fraction to a catalytic reaction in the presence of the catalyst under conditions at a hydrogen partial pressure of from 3 to 8 MPa, a temperature of from 300 to 420° C., and a liquid hourly space velocity of from 0.3 to 5 hr−1.
    Type: Application
    Filed: February 11, 2003
    Publication date: September 18, 2003
    Inventors: Takashi Fujikawa, Takayuki Osaki, Hiroshi Kimura, Hirofumi Mizuguchi, Minoru Hashimoto, Hiroyasu Tagami, Masahiro Kato
  • Publication number: 20030173253
    Abstract: The invention provides an amorphous hydrocracking catalyst for conversion of a hydrocarbon feed having a fraction above the diesel boiling range to diesel and a process using said catalyst. The catalyst includes Al2O3—SiO2 support, a noble catalytically active metal which is active for hydrocracking of a hydrocarbon above the diesel boiling range and a transition metal oxide selected from group V, VI and VII.
    Type: Application
    Filed: April 3, 2003
    Publication date: September 18, 2003
    Inventors: Aubin-Maurice Liwanga-Ehumbu, Jacobus Lucas Visagie, Dieter Otto Leckel