With Group Viii Metal Or Metal Oxide (i.e., Iron, Or Platinum Group Metal, Or Oxide Thereof) Patents (Class 208/111.35)
  • Patent number: 6179994
    Abstract: A high VI and low pour point lubricant base stock is made by hydroisomerizing a high purity, waxy, paraffinic Fischer-Tropsch synthesized hydrocarbon fraction having an initial boiling point in the range of 650-750° F., followed by catalytically dewaxing the hydroisomerate using a dewaxing catalyst comprising a catalytic platinum component and an H-mordenite component. The hydrocarbon fraction is preferably synthesized by a slurry Fischer-Tropsch using a catalyst containing a catalytic cobalt component. This combination of the process, high purity, waxy paraffinic feed and the Pt/H-mordenite dewaxing catalyst, produce a relatively high yield of premium lubricant base stock.
    Type: Grant
    Filed: September 4, 1998
    Date of Patent: January 30, 2001
    Assignee: Exxon Research and Engineering Company
    Inventors: Janet R. Clark, Robert J. Wittenbrink, Daniel F. Ryan, Albert E. Schweizer
  • Patent number: 6174429
    Abstract: The invention relates to a hydrocracking catalyst that contains at least one metal of group VIB, and/or at least one metal of group VIII of the periodic table, an alumina matrix, phosphorus, optionally at least one element from group VIIA (fluorine), and a zeolite Y that is not fully dealuminificated, with a crystalline parameter that is greater than 2,438 nm, an overall SiO2/Al2O3 ratio that is less than 8, and a framework SiO2/Al2O3 ratio that is less than 21 and greater than the overall SiO2/Al2O3 ratio. The invention also relates to a process for hydrocracking with this catalyst, in particular at low pressure of 7.5 to 11 MPa.
    Type: Grant
    Filed: October 20, 1998
    Date of Patent: January 16, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Nathalie George-Marchal, Samuel Mignard, Slavik Kasztelan
  • Patent number: 6174430
    Abstract: A noble metal hydrocracking catalyst which has high selectivity for naphtha range products is provided. The hydrocracking catalyst comprises: a) from about 70 to about 90 weight percent of a Y zeolite, based on the catalyst having a silica to alumina mole ratio of from about 4.8 to less than 6.0, a unit cell constant within the range of about 24.50 to about 24.57, a Na2O level of less than or equal to about 0.2 weight percent; b) from about 10 to about 30 weight percent, based on the catalyst of an alumina having a mercury intrusion pore volume within the range from about 0.55 to about 0.85 cc/g; and c) from about 0.5 to 1 weight percent, based on the catalyst of a noble metal wherein said hydrocracking catalyst have a dispersivity of the noble metal of equal or greater than about 50% by hydrogen chemisorption measurement, a surface area of greater than or equal to 700 m2/g by BET surface area measurement, a compacted bulk density within the range of from about 0.40 to 0.
    Type: Grant
    Filed: March 28, 2000
    Date of Patent: January 16, 2001
    Assignee: Shell Oil Company
    Inventors: Bruce Herman Charles Winquist, David Allen Cooper
  • Patent number: 6171474
    Abstract: Useful for example, for the hydrocracking of hydrocarbons is a catalyst comprising a matrix, at least one Y zeolite which is dealuminated and has a lattice parameter in the range 2.424 nm to 2.455 nm, a global SiO2/Al2O3 mole ratio is more than 8, the quantity of alkaline-earth metal cations or alkali metal cations and/or rare earth metal cations is such that the atomic ratio (n×Mn+)/Al is less than 0.8, the specific surface area, determined using the BET method, is more than 400 m2/g, and the water adsorption capacity is more than 6% by weight for P/P0 =0.2 at 25° C., said catalyst also comprising silicon deposited on the catalyst.
    Type: Grant
    Filed: May 5, 1999
    Date of Patent: January 9, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Slavik Kasztelan, Nathalie George-Marchal, Eric Benazzi