By Polymerization Patents (Class 430/137.15)
  • Publication number: 20140065535
    Abstract: The present invention provides a magnetic carrier for an electrophotographic developer which has an excellent durability and a stable charging property and is free from occurrence of spent toner thereonto, and a two-component system developer comprising the magnetic carrier for an electrophotographic developer and a toner. The present invention relates to a core material of a magnetic carrier for an electrophotographic developer comprising spherical composite particles comprising at least ferromagnetic iron oxide fine particles and a cured phenol resin and having an average particle diameter of 1 to 100 ?m, a resin index of the spherical composite particles being within the range of 35 to 80%, and a magnetic carrier obtained by coating a surface of respective particles of the magnetic carrier core material with a resin.
    Type: Application
    Filed: April 12, 2012
    Publication date: March 6, 2014
    Applicant: TODA KOGYO CORPORATION
    Inventors: Kaori Kinoshita, Eiichi Kurita
  • Patent number: 8663890
    Abstract: Provided is an electrostatic charge image developing toner, each toner particle including a core portion, a first shell layer, and a second shell layer, wherein the core portion contains a first polyester resin, a colorant, and a release agent, the first shell layer contains a second polyester resin and covers the core portion, the second shell layer contains a polymer of an aromatic vinyl monomer and a third polyester resin having an ethylenic unsaturated double bond that is polymerizable with the aromatic vinyl monomer, and covers the first shell layer, and a total amount of the first shell layer and the second shell layer is within a range of from 16% by weight to 40% by weight of the toner particle.
    Type: Grant
    Filed: July 3, 2012
    Date of Patent: March 4, 2014
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Shinpei Takagi, Soichiro Kitagawa, Shinya Sakamoto, Tomohiro Shinya
  • Publication number: 20140057202
    Abstract: The present invention provides a toner that exhibits an excellent chromogenicity and provides a method of producing a toner that has an excellent particle size distribution and an excellent chromogenicity, in which a toner containing a binder resin and a colorant that contains a coloring compound with general formula (1), and a method of producing this toner.
    Type: Application
    Filed: August 20, 2013
    Publication date: February 27, 2014
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Akiko Kitao, Ryuji Higashi, Taichi Shintou, Takeshi Miyazaki
  • Publication number: 20140057203
    Abstract: The present invention provides a toner having superior color development property and a method of producing a toner having favorable particle size distribution and color development property, in which the toner containing a binder resin and a colorant that contains a phthalocyanine pigment represented by general formula (1), and the method for producing the toner.
    Type: Application
    Filed: August 20, 2013
    Publication date: February 27, 2014
    Applicant: Canon Kabushiki Kaisha
    Inventors: Ryuji Higashi, Akiko Kitao, Taichi Shintou, Takeshi Miyazaki
  • Patent number: 8647801
    Abstract: A natural oil-based toner resin for producing toner in developing electrophotographic image comprising a copolymer of unsaturated polyester resins and vinyl monomers, wherein the polyester resins have a molecular weight of 500 to 30000 and obtained from polycondensation between a polycarboxylic acid, a natural oil or derivative thereof and a polyol. The toner resin in emulsion form is mixed with fine suspensions or emulsions of a colorant and a charge control agent; and a flocculating agent is incorporated therein to induce aggregation for forming particles of desired sizes, and subsequently the temperature is suitably raised to cause coalescence to produce raw toner particles of regular shape and smooth surface. The raw toner particles are washed and dried, and treated with suitable additives to produce the finished product of chemically produced toner.
    Type: Grant
    Filed: June 1, 2010
    Date of Patent: February 11, 2014
    Assignees: Universiti Malaya, Jadi Imaging Technologies SDN. BHD.
    Inventor: Seng Neon Gan
  • Patent number: 8614044
    Abstract: To provide a toner which can achieve both low-temperature fixing performance and dot reproducibility and further can obtain images on which any density non-uniformity has been kept from coming about, the toner has toner particles, each of the toner particles has a toner base particle containing a binder resin, a colorant and a release agent, and an inorganic fine powder; the toner having: (1) an average circularity of 0.960 or more; (2) a number-average molecular weight Mn(25° C.) of from 500 or more to 3,000 or less in measuring a tetrahydrofuran-soluble matter at 25° C. of the toner by SEC-MALLS; and (3) a value of Mn(135° C.)/Mn(25° C.) of from 25 or more to 50 or less which is the ratio of number-average molecular weight Mn(135° C.) in measuring an o-dichlorobenzene-soluble matter at 135° C. of the toner by SEC-MALLS to number-average molecular weight Mn(25° C.) in measuring a tetrahydrofuran-soluble matter at 25° C. of the toner by SEC-MALLS.
    Type: Grant
    Filed: June 13, 2011
    Date of Patent: December 24, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takashi Matsui, Michihisa Magome, Yusuke Hasegawa, Tomohisa Sano, Shuichi Hiroko, Yoshitaka Suzumura, Shotaro Nomura, Atsuhiko Ohmori
  • Patent number: 8603719
    Abstract: A method for producing an electrophotographic toner including forming a toner base particle by emulsifying or dispersing a solution or dispersion of a toner material comprising a colorant, and any one of a binder resin and a binder resin precursor in an aqueous medium, and adding crystalline organic fine particles having an acid value of 20 mgKOH/g to 80 mgKOH/g into the aqueous medium, before, during or after the forming so as to attach the crystalline organic fine particles onto a surface of the toner base particle.
    Type: Grant
    Filed: June 20, 2011
    Date of Patent: December 10, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroshi Yamashita, Yuichi Shirasu, Masaki Watanabe, Tomoki Murayama
  • Patent number: 8586274
    Abstract: A toner for developing an electrostatic charge image, which satisfies both low temperature fixing property and blocking resistance and which is excellent in the fixed image strength and further excellent in the production stability and is capable of presenting a constant quality, and a process for its production, which toner comprises a binder resin containing a crystalline resin, and wax, and which has, in its DSC curve measured by a differential scanning calorimeter, an endothermic peak of from 0.01 to 10 mJ/mg at a temperature of at most 45° C. during its temperature rise.
    Type: Grant
    Filed: May 27, 2011
    Date of Patent: November 19, 2013
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Tetsuharu Yuge, Yuqing Xu
  • Publication number: 20130280648
    Abstract: A toner composition including at least one phosphorescent pigment that absorbs energy released by natural or artificial light, and is able to be seen in a dark environment through luminescence of a certain color created by the energy released as light, and a method of forming and using the toner are described. The phosphorescent toner has a particle size in the range of about 15-40 microns, which allows the toner to have the ability to absorb and then release the needed amount of light energy to be noticeable in a dark environment.
    Type: Application
    Filed: April 18, 2012
    Publication date: October 24, 2013
    Applicant: TROY GROUP, INC.
    Inventors: Carrie A. Gilson, Kevin L. Heilman, Michael R. Rlley
  • Patent number: 8563206
    Abstract: A negatively chargeable developer includes: negatively chargeable toner mother particles including at least binding resin and colorant; and an external additive that is externally added to a surface of the toner mother particles, wherein the external additive includes polymethyl methacrylate that is within a range from approximately 0.4 parts by weight to approximately 0.8 parts by weight inclusive per 100 parts by weight of the toner mother particles and that has positive chargeability.
    Type: Grant
    Filed: August 30, 2011
    Date of Patent: October 22, 2013
    Assignee: Oki Data Corporation
    Inventor: Yuki Matsuura
  • Publication number: 20130273470
    Abstract: The present invention relates to a toner for electrophotography including core-shell particles as a resin binder each including a core portion containing an amorphous resin (A) having a softening point of 105° C. or lower which is obtained by polycondensing a carboxylic acid component containing an alkenyl succinic acid with an alcohol component; and a shell portion containing an amorphous resin (B) obtained by polycondensing an alcohol component containing an aliphatic diol having 2 to 6 carbon atoms with a carboxylic acid component containing a trivalent or higher-valent polycarboxylic acid compound in an amount of 20 mol % or less. The toner for electrophotography according to the present invention is excellent in heat resistant storage property, low-temperature fusing property and durability.
    Type: Application
    Filed: March 14, 2013
    Publication date: October 17, 2013
    Applicant: Kao Corporation
    Inventors: Norihiro Fukuri, Osamu Yamashita, Hiroki Kubo, Shoichi Murata, Takahiro Yoshikawa
  • Patent number: 8557497
    Abstract: A method of manufacturing toner including preparing a first liquid by dissolving or dispersing toner components including one or both of a binder resin and a precursor thereof in an organic solvent; preparing a second liquid by dispersing the first liquid in a first aqueous medium including a dispersant; producing primary particles by removing the organic solvent from the second liquid; washing the primary particles; preparing a third liquid by dispersing the washed primary particles in a second aqueous medium and heating the second aqueous medium while or after dispersing the washed primary particles therein; and producing toner particles by adding a charge controlling agent to the third liquid. This method satisfies the following inequation: 0.60?Sb/Sa?1.00 wherein Sa represents a BET specific surface area of the primary particles included in the third liquid and Sb represents that of the toner particles stored for 2 weeks at 40° C., 70% RH.
    Type: Grant
    Filed: December 6, 2010
    Date of Patent: October 15, 2013
    Assignee: Ricoh Company, Limited
    Inventors: Junichi Watanabe, Kenichi Uehara, Junya Koeda, Daisuke Misawa, Keisuke Tada, Miyuki Hirata
  • Patent number: 8546056
    Abstract: A toner including a colorant and a binder resin is provided. The binder resin includes a polyester resin having a glass transition temperature of 18 to 40° C., a weight average molecular weight of 10,000 to 100,000, and a flow beginning temperature of 70 to 120° C. The toner has a volume average particle diameter of 3 to 10 ?m.
    Type: Grant
    Filed: March 5, 2012
    Date of Patent: October 1, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Susumu Chiba, Hiroshi Yamashita, Masaki Watanabe, Satoyuki Sekiguchi, Daisuke Asahina
  • Patent number: 8530132
    Abstract: A method for preparing a toner including toner particles is provided. The toner preparation method includes preparing a toner component liquid including at least a binder resin, a colorant and an organic solvent; mixing a resin A having a solubility of less than 2.0 g/100 g in water having a pH of 3.0 at 25° C. while having a solubility of not less than 2.0 g/100 g, a basic material, and water to prepare an aqueous phase liquid, in which the resin A is dissolved; forming droplets of the toner component liquid in the aqueous phase liquid; and removing the organic solvent from the droplets of the toner component liquid to prepare the toner particles.
    Type: Grant
    Filed: March 3, 2011
    Date of Patent: September 10, 2013
    Assignee: Ricoh Company, Limited
    Inventors: Atsushi Yamamoto, Tsuyoshi Nozaki, Chiyoshi Nozaki
  • Patent number: 8530128
    Abstract: The present invention relates to a polymerized toner including a low molecular weight polymer having a weight average molecular weight of 3000 to 30,000 and a method for preparing the same, wherein the polymerized toner can realize excellent gloss and offset feature and can also can exhibit excellent performance in the applications of high speed copying, development of transferred photos, etc.
    Type: Grant
    Filed: February 23, 2011
    Date of Patent: September 10, 2013
    Assignee: LG Chem, Ltd.
    Inventors: Wook Jang, Chang-Soon Lee
  • Patent number: 8530127
    Abstract: A process for preparing toner and a polymerized toner prepared thereby are provided. The process for preparing toner comprises: forming an aqueous dispersion medium comprising calcium phosphate; forming a monomer mixture of a polymer charge control agent having weight average molecular weight of about 10,000 to 20,000, pigment, and a monomer for a binder resin; dispersing the monomer mixture in the aqueous dispersion in the form of droplets; and suspension-polymerizing the monomer mixture dispersed in the form of droplets, wherein about 2 to 6 parts by weight of the calcium phosphate and about 0.6 to 10 parts by weight of the charge control agent are used, on the basis of 100 parts by weight of the monomer mixture.
    Type: Grant
    Filed: July 23, 2010
    Date of Patent: September 10, 2013
    Assignee: LG Chem, Ltd.
    Inventors: Wook Jang, Chang-Soon Lee
  • Patent number: 8493648
    Abstract: Provided are a method of fabricating an electrophoretic ink, the electrophoretic ink formed using the method, and an electrophoretic display having the same. The method of fabricating an electrophoretic ink includes dispersing pigment particles into a dielectric fluid; adding at least one monomer and an initiator into the dielectric fluid; and forming polymeric membranes surrounding the pigment particles in the dielectric fluid. Since the pigment particle surrounded by the polymeric membrane and the dielectric fluid in which the pigment particle is dispersed can be utilized as the electrophoretic ink as they are without a follow-up cleaning process, the method of fabricating the electrophoretic ink is simplified.
    Type: Grant
    Filed: April 22, 2010
    Date of Patent: July 23, 2013
    Assignee: Electronics and Telecommunications Research Institute
    Inventors: Chul Am Kim, Hyeonjung Yoo, Kyung Soo Suh, Seung Youl Kang
  • Patent number: 8492065
    Abstract: Processes for continuously forming latex emulsions useful in preparing toners are provided which do not require the use of solvents.
    Type: Grant
    Filed: March 27, 2008
    Date of Patent: July 23, 2013
    Assignee: Xerox Corporation
    Inventors: Joo T. Chung, Zhen Lai, Chieh-Min Cheng, Joseph L. Leonardo, Yuhua Tong, Timothy L. Lincoln, Samir Kumar, Christine Louise DeMay
  • Patent number: 8470508
    Abstract: Disclosed is a toner manufacturing method, comprising: dispersing a polyester resin prepared by condensing a polyol and a polycarboxylic acid into an aqueous medium and adjusting a polyester resin particle dispersion liquid, wherein the polyol includes an unsaturated polyol, or the polycarboxylic acid includes an unsaturated polycarboxylic acid; and adding a radical polymerization initiator to the polyester resin particle dispersion liquid to cause a radical polymerization reaction, and adjusting the obtained dispersion liquid of polyester resin particles.
    Type: Grant
    Filed: October 6, 2010
    Date of Patent: June 25, 2013
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Kenji Hayashi, Mikio Kouyama, Hiroaki Obata, Noriyuki Kinpara, Yasuhiko Muramatsu
  • Patent number: 8455171
    Abstract: The present disclosure provides processes for reducing the particle size of latex resins and toners produced with such resins. In embodiments, a carboxylic acid may be added to materials utilized to produce a latex and reduce the particle size of the resulting latex particles and toner particles. In accordance with the present disclosure, one may be able to utilize materials for the production of latex resins and toners which may otherwise produce particles that are too large in the absence of the carboxylic acid.
    Type: Grant
    Filed: May 31, 2007
    Date of Patent: June 4, 2013
    Assignee: Xerox Corporation
    Inventors: Robert D. Bayley, Timothy L. Lincoln, Kevin F. Marcell, Grazyna E. Kmiecik-Lawrynowicz, Maura A. Sweeney, Daniel W. Asarese, Chieh-Min Cheng, Zhen Lai
  • Patent number: 8450039
    Abstract: Provided is a binder resin for color toners which comprises at least a carboxyl group-containing vinyl resin (C), a glycidyl group-containing vinyl resin (E) and a reaction product thereof, wherein the storage modulus G? at 160 degrees centigrade is not less than 20 and less than 800 Pa measured at a frequency of 6.28 rad/sec, the tetrahydrofuran (THF) soluble portion in the binder resin has a main peak in the molecular weight region of not less than 20,000 and less than 40,000 in the molecular weight distribution measured by gel permeation chromatography (GPC), and the binder resin contains at least one of releasing agents having a melting point of not lower than 60 and not higher than 120 degrees centigrade in an amount of not less than 3.5 and not more than 12 mass % based on 100 mass % of the total amount of the carboxyl group-containing vinyl resin (C), the glycidyl group-containing vinyl resin (E) and a reaction product thereof.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: May 28, 2013
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hiroshi Matsuoka, Kazuya Sakata, Hiroyuki Takei, Kenji Uchiyama, Ichirou Sasaki
  • Patent number: 8431322
    Abstract: A method of manufacturing a toner is provided which is excellent in low temperature fixation property, whose fixable temperature width is large, as well as excellent in durability while giving consideration to the global environment conservation. The method of manufacturing a toner includes a step of producing a polyester resin by a reaction of dicarboxylic acid and diol, and a step of producing a toner base particle having the polyester resin and a colorant. The dicarboxylic acid is a biomass monomer having carboxyl groups introduced into ends of one, or two or more monocarboxylic acids selected from pimaric acid, isopimaric acid, and sandaracopimaric acid.
    Type: Grant
    Filed: January 6, 2011
    Date of Patent: April 30, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventor: Nobuhiro Maezawa
  • Patent number: 8426096
    Abstract: A capsule toner in which fine solid particles constituting a shell layer are less likely to become detached from the surfaces of toner particles in spite of a long-term use within an image forming apparatus and which is capable of prevention of occurrence of filming on a photoreceptor drum, and a method of manufacturing the capsule toner are provided. The capsule toner includes core particle and shell layers for covering the surface of the core particle. The shell layer is formed of a plurality of fine polyester resin particles. The polyester resins contained in the fine polyester resin particles, respectively, are cross-linked to each other by a cross-linking agent.
    Type: Grant
    Filed: April 14, 2010
    Date of Patent: April 23, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventor: Nobuhiro Maezawa
  • Publication number: 20130078566
    Abstract: Disclosed are a low-environmental load toner for electrostatic image development and a production process of the toner. The toner for electrostatic image development includes toner particles containing a resin. The resin contains a vinyl polymer having a structural unit represented by the following general formula (1): [in the general formula (1), R1 is a hydrogen atom, —CH2OH, —CH2OR2, or —CH2O(C?O)R3, and R2 and R3 are each an alkyl group having 1 to 8 carbon atoms].
    Type: Application
    Filed: September 12, 2012
    Publication date: March 28, 2013
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Mikio KOUYAMA, Ken OHMURA
  • Publication number: 20130052579
    Abstract: The present invention relates to a polymerized toner including a low molecular weight polymer having a weight average molecular weight of 3000 to 30,000 and a method for preparing the same, wherein the polymerized toner can realize excellent gloss and offset feature and can also can exhibit excellent performance in the applications of high speed copying, development of transferred photos, etc.
    Type: Application
    Filed: February 23, 2011
    Publication date: February 28, 2013
    Applicant: LG CHEM, LTD.
    Inventors: Wook Jang, Chang-Soon Lee
  • Patent number: 8377619
    Abstract: Disclosed is a toner comprising at least a resin and a coloring agent, wherein the resin comprises toner particles in which a polyester resin unit is cross-linked by a diatomic cross-linking group expressed by a following general formula (1): —X1Y1X1— [wherein in the formula, X1 denotes a linking group; and Y1 denotes a radical polymer unit having a number average molecular weight Mn ranging from 5000 or more to 50000 or less, and a ratio Mw/Mn ranging from 1.0 or more to 1.2 or less, wherein Mw denotes a weight average molecular weight, and Mn denotes the number average molecular weight].
    Type: Grant
    Filed: June 28, 2010
    Date of Patent: February 19, 2013
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Kenji Hayashi, Mikio Kouyama, Hiroaki Obata, Noriyuki Kinpara, Yasuhiko Muramatsu
  • Patent number: 8372573
    Abstract: A toner in which, in a loss tangent (tan ?) curve obtained by a dynamic viscoelasticity test, the tan ? shows a maximal value ?a in the temperature region of 28.0-60.0° C., which maximal value ?a is 0.50 or more, and shows a minimal value ?b in the temperature region of 45.0-85.0° C., which minimal value ?b is 0.60 or less, where the difference between the maximal value ?a and the minimal value ?b is 0.20 or more; and, where the temperature that affords the maximal value ?a is represented by Ta (° C.) and the temperature that affords the minimal value ?b is represented by Tb (° C.), the difference between the Ta and the Tb is 5.0-45.0° C.; and the toner having, in a storage elastic modulus (G?) curve obtained by the dynamic viscoelasticity test, a value G?a of a storage elastic modulus at the Ta, of 1.00×106-5.00×107 Pa.
    Type: Grant
    Filed: March 19, 2012
    Date of Patent: February 12, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasukazu Ayaki, Atsushi Tani, Tsuneyoshi Tominaga
  • Publication number: 20130029261
    Abstract: The present invention relates to a polymerized toner prepared by suspension polymerization. In particular, the polymerized toner comprises a plurality of toner particles that each comprising a binder resin, a pigment, a pigment stabilizer, a charge control agent, and a wax. The polymerized toner maintains a ratio of toner particles containing at least two wax domains per particle within a defined range. Thereby, the polymerized toner achieves high glossiness and good transfer efficiency.
    Type: Application
    Filed: July 26, 2012
    Publication date: January 31, 2013
    Applicant: LG CHEM, LTD.
    Inventors: Wook JANG, Chang-Soon LEE, Woo-Cheul JUNG, Joo-Yong PARK
  • Patent number: 8343704
    Abstract: Spherical-shaped liquid droplets are made by dispersing oil phase containing: a resin with an acid group, a first hydrophobic solvent effecting dissolution of the resin, a colorant, and a charge control agent which is positively charged in an aqueous dispersion medium in the presence of a base; and the liquid particles are solidified to be solid particles by removing the first solvent from the liquid droplets. The solid particles obtained in this manner are washed with a second solvent. As the second solvent, a solvent which dissolves the charge control agent and but does not dissolve the resin such as alcohol is selected. Accordingly, the charge control agent in the solid particles are made to elute to the outer surface layer of the solid particles, thereby improving the positive chargeability of the solid particles.
    Type: Grant
    Filed: June 16, 2006
    Date of Patent: January 1, 2013
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Jun Ikama, Masateru Kawamura
  • Patent number: 8343715
    Abstract: A method for producing a photochromic polyester, the method including: a) providing a reaction solution having at least one ester monomer, a photochromic compound having or functionalized to have at least one hydroxyl group, and a metal-free catalyst; b) reacting the at least one ester monomer and the photochromic compound using the metal-free catalyst to produce a polymeric product, where the polymeric product has a photochromic polyester; and c) separating the polymeric product from the reaction solution. A photochromic polyester includes a photochromic compound covalently linked to a polyester and the polyester is obtained by polymerizing a lactone.
    Type: Grant
    Filed: November 3, 2010
    Date of Patent: January 1, 2013
    Assignee: Xerox Corporation
    Inventors: Santiago Faucher, Gabriel Iftime, Kentaro Morimitsu, Adela Goredema, Jordan H. Wosnick
  • Patent number: 8343703
    Abstract: An electrostatic image developing toner, includes: a block copolymer that contains: a block A that has a glass transition temperature of about 60° C. or more; and a crystalline block B that has a melting point of about 25° C. or more derived from an ethylenically unsaturated compound, wherein the block copolymer satisfies the following equations (1) to (3): 30° C.?[T(0.5 MPa)?T(30 MPa)]?80° C.??(1) 60° C.?T(0.5 MPa)??(2) T(30 MPa)?80° C.??(3) wherein T(0.5 MPa) represents a temperature at which a viscosity of the block copolymer is 104 Pa·s when a pressure applied by a flow tester is 0.5 MPa; and T(30 MPa) represents a temperature at which a viscosity of the block copolymer is 104 Pa·s when a pressure applied by a flow tester is 30 MPa.
    Type: Grant
    Filed: August 7, 2009
    Date of Patent: January 1, 2013
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Hideo Maehata, Yasuo Matsumura, Takashi Imai
  • Publication number: 20120328979
    Abstract: A toner is provided which has toner particles and an inorganic fine powder; the toner particles being obtained by suspension polymerization using a specific polar resin. The toner is a toner in which; where, in displacement levels found in a micro-compression test in which a force is applied to a toner single particle at a loading rate of 9.8×10?6 N/sec to measure a displacement level (?m) at a point of time where the force has reached a maximum force of 4.90×10?4 N, the displacement level of the toner at a measurement temperature of 25° C. is represented by X(25) and the displacement level of the toner at a measurement temperature of 50° C. by X(50), and the number average particle diameter of the toner is represented by D (?m), the X(25), X(50) and D satisfies the relations: 0.10?X(25)/D?0.35??(1) 30?[X(50)?X(25)]/X(25)×100?150??(2).
    Type: Application
    Filed: March 28, 2011
    Publication date: December 27, 2012
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Kazumi Yoshizaki, Shinya Yachi, Yasushi Katsuta, Kenichi Nakayama, Takeshi Kaburagi
  • Publication number: 20120308926
    Abstract: A polyester resin toner binder which gives a toner with good anti-blocking property at high temperature and high humidity and good low-temperature fixing ability. The present invention is directed to a toner binder for developing electrostatic charge images, which binder comprises a condensation-polymerization polyester resin, the polyester resin being a product formed in the presence of a catalyst (a) represented by the following general formula (I): Ti(—X)m(—OR)n??(I) wherein R, X, m and n are as defined herein.
    Type: Application
    Filed: May 24, 2012
    Publication date: December 6, 2012
    Applicant: Sanyo Chemical Industries, Ltd.
    Inventors: Takashi Ono, Yoko Sakurai
  • Patent number: 8313881
    Abstract: A toner for an electrophotographic image forming process or an electrostatic printing process, and a polyester resin for the toner are disclosed. The polyester resin comprises: acid components including 70 to 96 mol % of aromatic dibasic acid component, 3 to 20 mol % of cycloaliphatic dibasic acid component, and 1 to 10 mol % of trivalent or higher acid component; alcohol components including 10 to 50 mol % of cycloaliphatic diol component, 2 to 20 mol % of trihydric or higher alcohol component, and 30 to 88 mol % of aliphatic diol component; and a heat stabilizer.
    Type: Grant
    Filed: July 10, 2008
    Date of Patent: November 20, 2012
    Assignee: SK Chemicals Co., Ltd.
    Inventors: Young-Man Yoo, Jae-Kyoung Roh, Kye-Yune Lee, Tae-Woong Lee
  • Patent number: 8304158
    Abstract: A method for manufacturing a toner includes a pre-mixing step and a coating step. In the pre-mixing step, a secondary aggregate of the fine resin particles is disaggregated, while toner base particles and fine resin particles are mixed and stirred using a rotary stirring apparatus. Thus obtained disaggregated fine resin particles are fixed to the surface of the toner base particle. Thus, a fine resin particle-fixed toner is obtained. The rotary stirring apparatus includes a rotary stirring section, a temperature regulation section, a circulating section, and a spraying section. In the coating step, a liquid is sprayed to the fine resin particle-fixed toner with the spraying section using the rotary stirring apparatus. Thus, a film of the fine resin particles is formed. In the pre-mixing step and the coating step, temperature regulation is conducted in the temperature regulation section.
    Type: Grant
    Filed: December 14, 2009
    Date of Patent: November 6, 2012
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Yoshinori Mutoh, Yoshiaki Akazawa, Yoshitaka Kawase, Yoritaka Tsubaki, Keiichi Kikawa, Takashi Hara
  • Patent number: 8304157
    Abstract: A toner for an electrophotography and its manufacturing method are disclosed. The toner comprises toner particles containing a cross-linked polymer having two-valent crosslinking group represented by Formula (1), wherein, R1 is a hydrogen atom or a chlorine atom, R2 is a hydrogen atom, a chlorine atom or a methoxy group. The toner satisfies storage durability against heat as well as sufficient low temperature fixing ability.
    Type: Grant
    Filed: June 10, 2010
    Date of Patent: November 6, 2012
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Mikio Kouyama, Ken Ohmura, Kenji Hayashi, Yukio Hosoya, Hiroaki Obata, Koji Shibata
  • Publication number: 20120276480
    Abstract: This present invention relates to a method of preparing a polymerized toner, which comprises the steps of: preparing an aqueous dispersion medium containing calcium phosphate; preparing a monomer mixture including a styrene-based pigment stabilizer having a weight average molecular weight of 2,000 to 200,000, a charge control agent, a pigment, and a monomer for binder resin; dispersing the monomer mixture in the form of droplets in the aqueous dispersion medium; and performing suspension polymerization for the monomer mixture dispersed in the form of droplets, and calcium phosphate is used in an amount of 2 to 6 parts by weight based on 100 parts by weight of the monomer mixture. Also, a polymerized toner produced using this method is provided.
    Type: Application
    Filed: October 28, 2010
    Publication date: November 1, 2012
    Applicant: LG CHEM, LTD.
    Inventors: Wook Jang, Chang-Soon Lee, Woo-Cheul Jung
  • Patent number: 8299190
    Abstract: A method for producing colored polymer particles, including adding a colorant-containing composition containing a radically polymerizable monomer and a colorant in a supercritical fluid or a subcritical fluid and polymerizing the radically polymerizable monomer, so as to produce colored polymer particles which are insoluble in the supercritical fluid or subcritical fluid, wherein the supercritical fluid or subcritical fluid is a supercritical fluid or subcritical fluid in which at least the radically polymerizable monomer is soluble, but polymer particles resulted from polymerization of the radically polymerizable monomer are insoluble, and wherein the colorant is at least one selected from the group consisting of a pigment, a dye and a polymer dye.
    Type: Grant
    Filed: December 18, 2008
    Date of Patent: October 30, 2012
    Assignees: National University Corporation Shizuoka University, Ricoh Company, Ltd.
    Inventors: Takeshi Sako, Idzumi Okajima, Takahiro Yamashita, Satoyuki Sekiguchi, Chiaki Tanaka, Shogo Suzuki, Ryota Inoue
  • Patent number: 8293447
    Abstract: An object of the present invention is to provide a toner which allows fixation at low temperatures, which is excellent in anti-offset ability, and which provides a high quality image at high and low humidities in a stable manner without causing any image defect over time. Provided is a toner, containing at least a binder resin and a colorant in which: the binder resin in the toner contains 60% by mass or more of a styrene/acryl resin and a THF-insoluble fraction A which is an extraction residue obtained by carrying out Soxhlet extraction with tetrahydrofuran (THF) for 16 hours; the THF-insoluble fraction A contains a TOL-insoluble fraction B which is an extraction residue obtained by carrying out Soxhlet extraction with toluene (TOL) for 16 hours; and a mass ratio (B/A) between the THF-insoluble fraction A and the TOL-insoluble fraction B is in the range of 0.1?B/A?0.5.
    Type: Grant
    Filed: June 22, 2011
    Date of Patent: October 23, 2012
    Assignee: Canon Kabushiki Kaisha
    Inventors: Katsuhisa Yamazaki, Masami Fujimoto, Masaaki Taya
  • Patent number: 8288071
    Abstract: A resin particle liquid dispersion for an electrostatic image developing toner, comprising: an aqueous medium; and a resin particle dispersed in the aqueous medium to have a median diameter of 0.05 to 2.0 ?m, the resin particle comprising a polycondensable polymer obtained by polycondensing polycondensable monomers, wherein a storage modulus GL(30) of the resin particle at 30° C. is 1×107 Pa or more, and a melting point of the polycondensable polymer is from 45 to 110° C.
    Type: Grant
    Filed: May 26, 2009
    Date of Patent: October 16, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yuki Sasaki, Satoshi Hiraoka, Fumiaki Mera, Hirotaka Matsuoka, Yasuo Matsumura
  • Patent number: 8283098
    Abstract: A preparation method of a toner comprising a binder resin and a colorant is disclosed, comprising forming resin particles containing a resin formed by allowing a styrene monomer, a (meth)acryl monomer and a polymer represented by the formula (1) to react, and mixing the resin particles with colorant particles which were dispersed and allowing the resin particles and the colorant particle to coagulate and fuse to form toner particles, X—(Y)n—X??formula (1) wherein X is at least one of an acryloyl group and a methacryloyl group, Y is a radical polymerizable monomer unit and n is an integer of 25 to 1000.
    Type: Grant
    Filed: October 26, 2009
    Date of Patent: October 9, 2012
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Mikio Kouyama, Kenji Hayashi, Hiroaki Obata, Noriyuki Kimpara, Hiroshi Nagasawa
  • Patent number: 8283097
    Abstract: To provide a process for efficiently producing a toner for developing an electrostatic charge image, which is scarcely susceptible to aggregation of the toner and free from blocking during the storage or from soiling the image forming apparatus and which is excellent in image characteristics. A process for producing a toner for developing an electrostatic charge image, characterized by supplying a monomer into a dispersion containing wax and a polymerizable monomer having a C8-100 hydrocarbon group, carrying out the polymerization, followed by flocculation treatment.
    Type: Grant
    Filed: November 21, 2005
    Date of Patent: October 9, 2012
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masatoshi Maruyama, Hiroya Kodama, Masaya Oota, Shiho Sano
  • Patent number: 8278020
    Abstract: The present disclosure provides methods for modifying polymeric resin materials after polymerization to make fine adjustments in the chemical or physical properties of the resin, or in modifying the structure of the polymer chains. The resulting resins may be useful in forming toner particles. In embodiments, a polymeric resin may have epoxy groups added to its backbone to increase its melting point. The resulting polymer, sometimes referred to herein as an epoxidized polymer, may, in turn, be reacted with wax-like components, to increase the compatibility of the polyester with waxes utilized in forming toner particles. In other embodiments, the resulting epoxidized polymer may be reacted with components possessing carboxylic acid groups to adjust the acid value and weight average molecular weight of the resin.
    Type: Grant
    Filed: September 10, 2008
    Date of Patent: October 2, 2012
    Assignee: Xerox Corporation
    Inventor: Jordan H. Wosnick
  • Patent number: 8273518
    Abstract: An electrophotographic toner which is thermally stable in storage or as an image after being fixed and exhibits a sufficiently low melt viscosity and a high fluidity when heated during fixing is disclosed, comprising a colorant and a binder resin, wherein the binder resin contains a poly-branched resin composition in an amount of 0.5 to 20% by mass. There is also disclosed a method of producing the electrophotographic toner.
    Type: Grant
    Filed: February 13, 2009
    Date of Patent: September 25, 2012
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Mikio Kouyama, Kenji Hayashi, Hiroaki Obata
  • Patent number: 8257988
    Abstract: A method of making a light emitting diode (LED) having an optical element is provided, comprising: providing a curable liquid polysiloxane/TiO2 composite, which exhibits a refractive index of >1.61 to 1.7 and which is a liquid at room temperature and atmospheric pressure; providing a semiconductor light emitting diode die having a face, wherein the semiconductor light emitting diode die emits light through the face; contacting the semiconductor light emitting diode die with the curable liquid polysiloxane/TiO2 composite; and, curing the curable liquid polysiloxane/TiO2 composite to form an optical element; wherein at least a portion of the optical element is adjacent to the face.
    Type: Grant
    Filed: May 17, 2011
    Date of Patent: September 4, 2012
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Paul Joseph Popa, Garo Khanarian, Weijun Zhou, John R. Ell
  • Patent number: 8247154
    Abstract: The present invention is to provide a method for producing a toner capable of sufficiently decreasing the percentage of moisture content of a wet cake in the process of obtaining colored resin particles in wet state (wet cake), capable of reducing the workload in the following drying process, and thus excellent in productivity.
    Type: Grant
    Filed: October 1, 2009
    Date of Patent: August 21, 2012
    Assignee: Zeon Corporation
    Inventors: Hisashi Kurokawa, Rei Katsuyama, Fuminari Oyama, Hiroto Kidokoro
  • Patent number: 8247147
    Abstract: A toner including toner particles containing at least a binder resin and a colorant. The binder resin is a vinyl-based resin. The toner contains a THF insoluble matter in a quantity of 0.0 mass % or more to less than 16.0 mass %. The toner has a main peak in a molecular weight domain Dr1 ranging from 5,000 to 80,000 in measurement of THF soluble matter of the toner with a gel permeation chromatogram (GPC)-differential refractive index detector (RI), and the toner has a main peak in a molecular weight domain Dm1 ranging from 10,000 to 120,000 and at least one peak in a molecular weight domain Dm2 ranging from 300,000 to 7,000,000 in the GPC-RI measurement in measurement with a GPC-multi-angle laser light scattering detector (MALLS).
    Type: Grant
    Filed: June 25, 2007
    Date of Patent: August 21, 2012
    Assignee: Canon Kabushiki Kaisha
    Inventors: Koji Abe, Shinya Yachi, Satoshi Handa, Kazumi Yoshizaki, Emi Tosaka, Yasuhiro Hashimoto, Nobuhisa Abe, Yushi Mikuriya
  • Patent number: 8227168
    Abstract: The present disclosure provides processes for the production of block copolymer polyester resins suitable for use in manufacturing toners. In embodiments, the copolymers include both a crystalline block and an amorphous block, which can self-assemble to form nanoparticles suitable for use in forming toners.
    Type: Grant
    Filed: July 14, 2009
    Date of Patent: July 24, 2012
    Assignee: Xerox Corporation
    Inventors: Karen Ann Moffat, Jordan H. Wosnick
  • Patent number: 8216756
    Abstract: A polymerized toner is provided. The polymerized toner has cores containing a wax with a polydispersity of 1.05 to 1.1. The fixability of the polymerized toner is improved by the presence of the wax. Further provided is a method of producing the polymerized toner.
    Type: Grant
    Filed: November 18, 2009
    Date of Patent: July 10, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Wook Jang, Chang Soon Lee, Woo Cheul Jung
  • Patent number: 8216761
    Abstract: Disclosed is a method for producing a polymerized toner. In the method, a mixture of colloidal silica as an aqueous dispersant and a polyvinylpyrrolidone is used during suspension polymerization. The amount of polyvinylpyrrolidone/colloidal silica aggregates having a diameter smaller than 100 nm is also limited to 1% by weight or less, based on the total weight of all aggregates. A polymerized toner produced by the method has a volume average particle diameter (dv) of 5 to 10 ?m and a volume average particle diameter/number average particle diameter ratio (dv/dp) of 1.5 or less. The polymerized toner is consumed in a small amount during printing. According to the method, the formation of emulsion particles having a size smaller than 0.5 ?m is inhibited.
    Type: Grant
    Filed: October 8, 2008
    Date of Patent: July 10, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Wook Jang, Chang Soon Lee, Woo Cheul Jeong, Ji Hoon Lee