By Polymerization Patents (Class 430/137.15)
-
Publication number: 20100239970Abstract: A toner for an electrophotographic image forming process or an electrostatic printing process, and a polyester resin for the toner are disclosed. The polyester resin comprises: acid components including 70 to 96 mol % of aromatic dibasic acid component, 3 to 20 mol % of cycloaliphatic dibasic acid component, and 1 to 10 mol % of trivalent or higher acid component; alcohol components including 10 to 50 mol % of cycloaliphatic diol component, 2 to 20 mol % of trihydric or higher alcohol component, and 30 to 88 mol % of aliphatic diol component; and a heat stabilizer.Type: ApplicationFiled: July 10, 2008Publication date: September 23, 2010Inventors: Young-Man Yoo, Jae-Kyoung Roh, Kye-Yune Lee, Tae-Woong Lee
-
Publication number: 20100232837Abstract: A toner has a core-shell structure including a toner core portion having a resin with an active hydrogenactive hydrogen containing group, a colorant and at least one additive, and a toner shell portion surrounding the toner core portion, wherein the toner shell portion includes a cross-linked resin prepared by reaction of at least a portion of the active hydrogen containing group and the cross-linking agent.Type: ApplicationFiled: October 22, 2008Publication date: September 16, 2010Applicant: SAMSUNG FINE CHEMICALS CO., LTDInventors: Dae Il Hwang, Woo Young Yang, Keon Il Kim, Il Hyuk Kim, Jae Bum Park, Il Sun Hwang, Jae Kwang Hwang, Dae Woong Choi, Dong Won Kim, Duck Kyun Ahn
-
Patent number: 7785760Abstract: A toner is provided including a binder resin, a colorant, and a release agent, which has a volume average particle diameter (Dv) of from 3 to 9 ?m, and wherein the binder resin and the release agent form a sea-island structure in which the island formed of the release agent is dispersed in the sea formed of the binder resin in a cross-sectional image of the toner obtained by a transmission electron microscope (TEM), and the following relationships are satisfied: IB>IA and IB>IC, wherein each of IA, IB, and IC represents an area ratio (%) of the island in an outermost region (A) of the cross-sectional image of the toner, an intermediate region (B) thereof located under the outermost region (A), and an innermost region (C) thereof located under the intermediate region (B); and a method of preparing the toner.Type: GrantFiled: January 18, 2007Date of Patent: August 31, 2010Assignee: Ricoh Company LimitedInventors: Atsushi Yamamoto, Chiyoshi Nozaki, Tsuyoshi Nozaki, Minoru Nakamura, Yoshimichi Ishikawa
-
Publication number: 20100209837Abstract: Provided is a binder resin for color toners which comprises at least a carboxyl group-containing vinyl resin (C), a glycidyl group-containing vinyl resin (E) and a reaction product thereof, wherein the storage modulus G? at 160 degrees centigrade is not less than 20 and less than 800 Pa measured at a frequency of 6.28 rad/sec, the tetrahydrofuran (THF) soluble portion in the binder resin has a main peak in the molecular weight region of not less than 20,000 and less than 40,000 in the molecular weight distribution measured by gel permeation chromatography (GPC), and the binder resin contains at least one of releasing agents having a melting point of not lower than 60 and not higher than 120 degrees centigrade in an amount of not less than 3.5 and not more than 12 mass % based on 100 mass % of the total amount of the carboxyl group-containing vinyl resin (C), the glycidyl group-containing vinyl resin (E) and a reaction product thereof.Type: ApplicationFiled: August 27, 2008Publication date: August 19, 2010Applicant: Mitsui Chemicals, Inc.Inventors: Hiroshi Matsuoka, Kazuya Sakata, Hiroyuki Takei, Kenji Uchiyama, Ichirou Sasaki
-
Publication number: 20100203442Abstract: Disclosed is a manufacturing method of a magenta toner including the steps of dispersing an oil phase containing a radical polymerizable monomer for forming the binder resin and the colorant in an aqueous medium to form dispersion liquid in which the oil phase is dispersed in a form of droplets in the aqueous medium, and polymerizing the radical polymerizable monomer in the droplets in dispersion liquid to form resin particles containing colorant, in which the colorant comprises C.I. Solvent Red 48.Type: ApplicationFiled: February 2, 2010Publication date: August 12, 2010Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Ken OHMURA, Hiroshi YAMAZAKI
-
Patent number: 7767375Abstract: In a process for producing a polymerized toner, comprising Step 1 of preparing a polymerizable monomer composition and Step 2 of polymerizing the polymerizable monomer composition with a polymerization initiator to form colored polymer particles, Step 1 comprises Step A of finely dispersing the colorant in a liquid mixture containing the polymerizable monomer and the colorant, and further Step A comprises Step A1 of feeding a liquid mixture containing a polymerizable monomer and a colorant, which has a volume average particle diameter of 20 ?m or larger and/or contains particles having a particle diameter of 51 ?m or larger in a volume percentage of 20% or higher, to a dispersing machine of the type that mechanical shearing force is applied by rotation of an agitating blade to preliminarily disperse the colorant, and Step A2 of feeding the liquid mixture containing the colorant preliminarily dispersed in Step A1 to a media type dispersing machine equipped with a media-separating screen to more finely disperseType: GrantFiled: June 22, 2005Date of Patent: August 3, 2010Assignee: Zeon CorporationInventor: Hisashi Kurokawa
-
Publication number: 20100190103Abstract: Disclosed is a method for producing a polymerized toner. In the method, a mixture of colloidal silica as an aqueous dispersant and a polyvinylpyrrolidone is used during suspension polymerization. The amount of polyvinylpyrrolidone/colloidal silica aggregates having a diameter smaller than 100 nm is also limited to 1% by weight or less, based on the total weight of all aggregates. A polymerized toner produced by the method has a volume average particle diameter (dv) of 5 to 10 ?m and a volume average particle diameter/number average particle diameter ratio (dv/dp) of 1.5 or less. The polymerized toner is consumed in a small amount during printing. According to the method, the formation of emulsion particles having a size smaller than 0.5 ?m is inhibited.Type: ApplicationFiled: October 8, 2008Publication date: July 29, 2010Applicant: LG CHEM LTD.Inventors: Wook Jang, Chang Soon Lee, Woo Cheul Jeong, Ji Hoon Lee
-
Patent number: 7763409Abstract: The present invention relates to a binder resin for a toner which is used in electrophotography and the like. An objective of the present invention is to obtain a binder resin for a toner containing a crystalline resin which satisfies both excellent low temperature fixing property and excellent offset resistance, a method for producing the binder resin, and a toner using the binder resin. The objective can be achieved by using a binder resin for a toner that is produced by subjecting an amorphous resin and a crystalline resin to melting, kneading and reaction, and is characterized in that it includes a network structure which includes a crystalline resin.Type: GrantFiled: May 18, 2005Date of Patent: July 27, 2010Assignee: Mitsui Chemicals, Inc.Inventor: Yoshihito Hirota
-
Patent number: 7754409Abstract: The present invention is a method of manufacturing toner particles that includes providing a first emulsion of a first aqueous phase comprising a pore stabilizing hydrocolloid dispersed in an organic solution containing a polymer. The first emulsion is dispersed in a second aqueous phase to form a second emulsion that is sheared in the presence of a stabilizing agent to form droplets of the first emulsion in the second aqueous phase. The organic solution is evaporated from the droplets to form porous toner particles.Type: GrantFiled: January 18, 2007Date of Patent: July 13, 2010Assignee: Eastman Kodak CompanyInventors: Mridula Nair, David C. Boris, Charles P. Lusignan, Dennis J. Massa, Tamara K. Jones, Anita M. Fees
-
Patent number: 7754410Abstract: To provide a method for producing a toner for developing an electrostatic charge image, which is capable of producing toner host particles in good yield and which is excellent in image characteristics, image quality, scratch resistance of a developing device and toner consumption, and a screen device which is capable of screening continuously without clogging. A method for producing a toner for developing an electrostatic charge image, which comprises a step of screening a dispersion of toner host particles by a screen, characterized in that when the above step is carried out, Y?{1/(M2+r2+2Mr)}×108×0.Type: GrantFiled: August 23, 2006Date of Patent: July 13, 2010Assignee: Mitsubishi Chemical CorporationInventors: Shingo Ishiyama, Nobuyuki Aoyagi
-
Publication number: 20100167195Abstract: A chemical toner is described as well as methods of preparing the same.Type: ApplicationFiled: November 24, 2009Publication date: July 1, 2010Inventors: Anne K. Shim, Eugene N. Step, Agathagelos Kyrlidis
-
Patent number: 7745089Abstract: A process for producing a toner by subjecting a polymer and a resin component containing a cross-linkable polymer capable of cross-linkingly reacting with the polymer, to cross-linking reaction in the presence of a first wax to form a wax-containing cross-linked polymer composition; mixing the wax-containing cross-linked polymer composition with at least a colorant and a second wax, followed by melt-kneading to form a toner composition; and pulverizing the toner composition to produce toner particles. Also disclosed is a toner produced by this process. The toner thus obtained is a toner whose fixing performance and anti-offset properties are well balanced and also which makes it possible to afford images having less fog and high quality, over a long period of time in environments of from low temperature and low humidity to high temperature and high humidity, and is highly durable without causing any contamination of members with which the toner comes into contact.Type: GrantFiled: September 20, 2007Date of Patent: June 29, 2010Assignee: Canon Kabushiki KaishaInventors: Nobuyuki Okubo, Tsutomu Onuma, Shuhei Moribe, Shinichiro Abe, Koji Nishikawa
-
Patent number: 7732115Abstract: The present invention relates to toner compositions comprising a resin and a colorant. Various embodiments of the colorant used in the toner compositions are disclosed, including a modified pigment comprising a pigment having attached at least one organic group having the formula -X-I, wherein X, which is directly attached to the pigment, represents an arylene or heteroarylene group, or an alkylene group, and I represents a non-polymeric group comprising at least one ionic group or at least one ionizable group. Processes for preparing toner compositions are also described.Type: GrantFiled: December 16, 2009Date of Patent: June 8, 2010Assignee: Cabot CorporationInventors: Eugene N. Step, Agathagelos Kyrlidis
-
Publication number: 20100124713Abstract: A toner comprising: a polymer matrix comprising carbon nanotubes dispersed in a polymer; optionally one or more colorants; and optionally one or more waxes.Type: ApplicationFiled: November 17, 2008Publication date: May 20, 2010Applicant: XEROX CORPORATIONInventors: Valerie M. FARRUGIA, Yu QI, Paul J. GERROIR, Rosa M. DUQUE, Biritawit ASFAW, Michael S. HAWKINS
-
Publication number: 20100119965Abstract: The present invention provides a method for producing a toner that can suppress the production of the decomposition products derived from a polymerization initiator, and can suppress the remaining presence, in the toner particles, of the unreacted polymerizable monomer and decomposition product residues. On the basis of this method, the present invention provides a toner that is excellent in triboelectric charging stability and can yield stable images over a long term.Type: ApplicationFiled: May 16, 2008Publication date: May 13, 2010Applicant: CANON KABUSHIKI KAISHAInventors: Atsushi Tani, Norikazu Fujimoto, Hitoshi Itabashi
-
Publication number: 20100112473Abstract: A preparation method of a toner comprising a binder resin and a colorant is disclosed, comprising forming resin particles containing a resin formed by allowing a styrene monomer, a (meth)acryl monomer and a polymer represented by the formula (1) to react, and mixing the resin particles with colorant particles which were dispersed and allowing the resin particles and the colorant particle to coagulate and fuse to form toner particles, X—(Y)n—X??formula (1) wherein X is at least one of an acryloyl group and a methacryloyl group, Y is a radical polymerizable monomer unit and n is an integer of 25 to 1000.Type: ApplicationFiled: October 26, 2009Publication date: May 6, 2010Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Mikio KOUYAMA, Kenji HAYASHI, Hiroaki OBATA, Noriyuki KIMPARA, Hiroshi NAGASAWA
-
Patent number: 7709171Abstract: The present invention provides a charge control agent, adapted to control charging ability of resins or compositions containing resins, comprising a copolymer that comprises a polymer block A and a polymer block B, the polymer block A is prepared by copolymerizing a maleimide, which being unsubstituted or substituted for a hydrogen atom of an imide group by an electron-donating group, and styrene or a styrene derivative, and the polymer block B is formed of a polymer of styrene or a styrene derivative.Type: GrantFiled: July 18, 2007Date of Patent: May 4, 2010Assignee: Ricoh Company, Ltd.Inventors: Atsushi Yamamoto, Chiyoshi Nozaki, Tsuyoshi Nozaki, Mitsuyo Matsumoto, Katsunori Kurose
-
Patent number: 7709176Abstract: A method for producing a polymerized toner comprising a step of polymerizing a polymerizable monomer composition in an aqueous dispersion medium in the presence of a polymerization initiator to obtain a dispersion liquid of colored polymer particles and a stripping step of injecting a gas comprised of air or an inert gas into the dispersion liquid of the colored polymer particles while stirring the dispersion liquid in an evaporator and the flow rate of the gas injected per weight of the colored polymer particles being 0.05 to 4 L/(hr·kg), the pressure of the vapor phase of the evaporator being 5 to 80 kPa.Type: GrantFiled: August 29, 2006Date of Patent: May 4, 2010Assignee: Zeon CorporationInventors: Junichi Takashima, Takashi Iga, Keita Sensui
-
Publication number: 20100099040Abstract: The present invention relates to toner compositions comprising a resin and a colorant. Various embodiments of the colorant used in the toner compositions are disclosed, including a modified pigment comprising a pigment having attached at least one organic group having the formula ?X-I, wherein X, which is directly attached to the pigment, represents an arylene or heteroarylene group, or an alkylene group, and I represents a non-polymeric group comprising at least one ionic group or at least one ionizable group. Processes for preparing toner compositions are also described.Type: ApplicationFiled: December 16, 2009Publication date: April 22, 2010Inventors: Eugene N. Step, Agathagelos Kyrlidis
-
Patent number: 7695886Abstract: A process for producing a resin particle liquid dispersion for an electrostatic image developing toner, the process comprising: polycondensing a polycondensable monomer by utilizing an acid having a surface activating effect as a polycondensation catalyst, so as to obtain a polycondensed resin; and dispersing the polycondensed resin in an aqueous medium to which a base is added, so as to obtain a resin particle liquid dispersion in which a median diameter of resin particles is from 0.05 to 2.0 ?m, or the process comprising: polycondensing a polycondensable monomer by utilizing an acid having a surface activating effect as a polycondensation catalyst in a co-presence of a polycondensed resin, so as to obtain a polycondensed resin-containing material; and dispersing the polycondensed resin-containing material in an aqueous medium, so as to obtain a resin particle liquid dispersion in which a median diameter of resin particles is from 0.05 to 2.0 ?m.Type: GrantFiled: September 21, 2005Date of Patent: April 13, 2010Assignee: Fuji Xerox Co., Ltd.Inventors: Yasuo Matsumura, Hirotaka Matsuoka, Satoshi Hiraoka, Yuki Sasaki, Fumiaki Mera, Hideo Maehata
-
Publication number: 20100081075Abstract: A magenta toner, produced by a method including suspending an oily liquid comprising a binder resin and a colorant in an aqueous medium, wherein the colorant comprises a naphthol pigment and a quinacridone pigment, and the quinacridone pigment comprises a pigment having a specific formula.Type: ApplicationFiled: September 28, 2009Publication date: April 1, 2010Inventors: Naohiro WATANABE, Shinichi WAKAMATSU, Naohito SHIMOTA, Hiroshi YAMASHITA, Tsuyoshi SUGIMOTO, Masaki WATANABE, Tsuneyasu NAGATOMO
-
Patent number: 7682768Abstract: A process for producing a polymerized toner, comprising the step of polymerizing a polymerizable monomer composition containing a polymerizable monomer and a colorant in the presence of a polymerization initiator in an aqueous dispersion medium to form colored polymer particles, the process comprising the steps of mixing the polymerizable monomer with the colorant to prepare a polymerizable monomer mixture having an initial viscosity of 10 to 3,000 mPa·s or 0.3 to 1 mPa·s as measured at 25° C. by a Brookfield type viscometer, and then feeding the polymerizable monomer mixture to a media type dispersing machine to finely disperse the colorant by the media type dispersing machine, thereby preparing a dispersed polymerizable monomer mixture having a viscosity after the dispersion, the ratio of increase in viscosity of which is 1.0 to 10 times or 100 to 2,000 times as high as the initial viscosity.Type: GrantFiled: January 27, 2006Date of Patent: March 23, 2010Assignee: Zeon CorporationInventor: Hisashi Kurokawa
-
Patent number: 7670741Abstract: A toner containing a toner particle manufactured by dispersing an organic solvent in which a component comprising a polymer having a portion reactive with an active hydrogen group is dispersed or dissolved in an aqueous medium; and reacting the polymer with a compound having at least one active hydrogen group, where the polymer is prepared by reacting an aliphatic polyol, a polyester resin and a diisocyanate compound and has an isocyanate group on at least one end of the polymer.Type: GrantFiled: March 16, 2007Date of Patent: March 2, 2010Assignee: Ricoh Company, Ltd.Inventors: Masahide Yamada, Akinori Saitoh, Masahiro Ohki
-
Publication number: 20100047708Abstract: A method for producing a toner is provided. The method comprises the steps of (1) dispersing a water-soluble polyvinyl alcohol having a degree of polymerization of 1,500 to 2,500 and a degree of saponification of 75 to 98% in an aqueous medium to prepare an aqueous dispersion of the polyvinyl alcohol, (2) preparing a mixture of monomers, (3) mixing the aqueous dispersion with the monomer mixture, and (4) polymerizing the monomers.Type: ApplicationFiled: March 17, 2008Publication date: February 25, 2010Inventors: Wook Jang, Chang Soon Lee
-
Patent number: 7655372Abstract: The present invention relates to toner compositions comprising a resin and a colorant. Various embodiments of the colorant used in the toner compositions are disclosed, including a modified pigment comprising a pigment having attached at least one organic group having the formula —X—I, wherein X, which is directly attached to the pigment, represents an arylene or heteroarylene group, or an alkylene group, and I represents a non-polymeric group comprising at least one ionic group or at least one ionizable group. Processes for preparing toner compositions are also described.Type: GrantFiled: January 24, 2006Date of Patent: February 2, 2010Assignee: Cabot CorporationInventors: Eugene N. Step, Agathagelos Kyrlidis
-
Patent number: 7652128Abstract: A composition including an initiator and an unsaturated sulfopolyester amine resin, and processes for preparing and using thereof.Type: GrantFiled: November 5, 2004Date of Patent: January 26, 2010Assignee: Xerox CorporationInventors: Guerino Sacripante, Ke Zhou
-
Publication number: 20100009278Abstract: A toner is provided which has toner particles and a fine silica powder mixed by external addition to the toner particles. The toner has a weight average particle diameter of 4.0 to 9.0 ?m. The fine silica powder is subjected to hydrophobic treatment with dimethylsilicone oil, and has, in particle size distribution based on volume, a peak at which cumulative frequency is largest, in the measurement range of 0.02 ?m to 1,000.00 ?m; the cumulative frequency of 0.10 ?m to less than 1.00 ?m being 7.0% or less, and, the fine silica powder fulfills the following conditions: 1) A+B?93.0; 2) 0.45?A/B?6.00; and 3) the value of [(carbon content of the treated fine silica powder)/(BET specific surface area of fine silica powder before hydrophobic treatment)] is 0.030 or more to 0.055 or less.Type: ApplicationFiled: September 21, 2009Publication date: January 14, 2010Applicant: CANON KABUSHIKI KAISHAInventors: Naotaka Ikeda, Shinya Yachi, Katsuyuki Nonaka, Emi Watanabe, Koji Abe, Nobuhisa Abe
-
Publication number: 20090280430Abstract: There is provided a method for manufacturing a toner capable of providing a toner having excellent low-temperature fixing property and anti-offset property by adjusting a molecular weight distribution of a polymerization toner to a narrow distribution range. The method is characterized in that a toner is polymerized using a reversible addition-fragmentation chain transfer polymerization (RAFT) method by adding a dithioacetate, xanthate or dithioester-based chain transfer agent in the polymerization of a toner.Type: ApplicationFiled: January 30, 2008Publication date: November 12, 2009Inventors: Hui Je Lee, Woo Cheul Jung, Ji Hoon Lee, Yu Na Kim, Jung Woo Kim
-
Publication number: 20090280429Abstract: The present disclosure provides for enzymatic polymerization to produce polyester resins suitable for use in manufacturing toners.Type: ApplicationFiled: May 8, 2008Publication date: November 12, 2009Applicant: XEROX CORPORATIONInventors: Valerie M. Farrugia, Jordan H. Wosnick, Kristin M. Pouw, Paul J. Gerroir
-
Patent number: 7611816Abstract: In a process for producing toner particles through granulation by a wet process, a process for producing toner particles is provided that enables reduction of water content in wet toner particle cakes obtained by separating toner particles from a toner particle dispersion in a good efficiency, followed by washing, and enables efficient wash-away of impurities remaining on the toner particle surfaces so as to promise superior image characteristics. The toner particles are produced through a filtering step in which a slurry which contains toner particles is subjected to solid-liquid separation by means of a belt filter having a pressing aeration means which carries out aeration with pressing, to form wet toner particle cakes.Type: GrantFiled: July 24, 2006Date of Patent: November 3, 2009Assignee: Canon Kabushiki KaishaInventors: Yoshinori Tuji, Hidekazu Fumita, Minoru Omura
-
Publication number: 20090269691Abstract: Disclosed is a toner which is excellent in low-temperature fixability, high-temperature offset resistance, storage stability and durability, while having a wide range of fixing temperature. Also disclosed is a polyester resin used for such a toner. The polyester resin is one of the following polyester resin (A)-(E) for toners.Type: ApplicationFiled: September 20, 2006Publication date: October 29, 2009Applicant: Mitsubishi Rayon Co., Ltd.Inventors: Shinya Yamato, Tetsuya Ochiai, Hideyuki Fujii
-
Publication number: 20090246681Abstract: The present teaching provides a method for producing a positive charging toner that can exhibit stable charge characteristics. According to the present teaching, a positive charging toner is produced by preparing a base particle suspension having a conductivity not higher than 70 ?S/cm and comprising base particles that are obtained by mixing and emulsifying an aqueous medium and a resin solution containing the polyester resin; producing toner base particles by mixing the base particle suspension with a charge control resin microparticle suspension containing charge control resin microparticles; causing the charge control resin microparticles to adhere to the surfaces of the base particles; and washing the toner base particles.Type: ApplicationFiled: March 31, 2009Publication date: October 1, 2009Applicant: Brother Kogyo Kabushiki KaishaInventors: Masateru KAWAMURA, Yasutomo Imai
-
Publication number: 20090226832Abstract: The invention is related to a toner of static charge image and a method for manufacturing such a toner of static charge image, which solve the problems of existing toner of static charge image, namely easy detachment of colorant, the pollution of carriers and developing sleeves and low durability. For the toner of static charge image obtained by aggregation of at least polymer particles, the polymer particles at least contain polymer particles A with inner wax and polymer particles B with inner colorant. The toner of static charge image of the invention exhibits good effect of fixing characteristics, not causing the pollution of carriers and developing sleeves, and could maintain long-term stable performance.Type: ApplicationFiled: April 30, 2008Publication date: September 10, 2009Applicant: HUBEI DINGLONG CHEMICAL CO., LTD.Inventors: Shunquan ZHU, Xiukui WANG, Yubin WANG
-
Patent number: 7585608Abstract: A method of preparing a toner includes: preparing high molecular weight latex particles by polymerizing a toner composition including a macromonomer having a hydrophilic group, a hydrophobic group and at least one reactive functional group, at least one polymerizable monomer, a colorant and wax; aggregating the high molecular latex particles in the absence of an emulsifier, a colorant, and wax; and separating and drying the aggregated high molecular weight latex particles. A toner is prepared using the method described above. An image forming method using the toner and an image forming apparatus employing the toner are also provided. Using the method described above, polymerizable toner particles can be prepared using a simplified process and the colorant and was inside the toner can be easily dispersed.Type: GrantFiled: November 13, 2006Date of Patent: September 8, 2009Assignee: Samsung Electronics Co., Ltd.Inventors: Chang-kook Hong, Kyung-yol Yon, Jun-young Lee, Min-young Cheong
-
Publication number: 20090220880Abstract: Pigment particles with at least one metal oxide surface additive, wherein the at least one metal oxide surface additive is a metal oxide particle covalently bonded with at least one polycondensation polymer, wherein the pigment particle is a pearlescent or metallic pigment.Type: ApplicationFiled: March 3, 2008Publication date: September 3, 2009Applicant: XEROX CORPORATIONInventors: Karen A. MOFFAT, Valerie M. FARRUGIA, Ke ZHOU, Richard P.N. VEREGIN, Cuong VONG, Eric M. STROHM, Wafa F. BASHIR
-
Publication number: 20090214976Abstract: A liquid developer comprised of toner particles having excellent fixing properties to a recording medium is provided, and a liquid developer in which toner particles having uniform shape and small particle size distribution are dispersed is also provided, and further a method of producing a liquid developer capable of producing such a liquid developer efficiently is also provided. In particular, a producing method capable of producing such a liquid developer as described above in a method harmless to the environment is provided.Type: ApplicationFiled: January 12, 2006Publication date: August 27, 2009Applicant: SEIKO EPSON CORPORATIONInventors: Takashi Teshima, Satoru Miura
-
Patent number: 7575843Abstract: A toner is manufactured by way of a coarse particle preparing step, a slurry preparing step, a pulverizing step, a cooling step, and a depressurizing step. Slurry of toner coarse particles obtained by way of the coarse particle preparing step and the slurry preparing step is made to pass under heat and pressure through a pressure-resistant nozzle whereby toner coarse particles are pulverized into diameter-reduced toner particles. By providing the cooling step immediately after the pulverizing step, dispersion of wax component into the toner particles is promoted. And by further providing the depressurizing step, bubbling and coarsening of the toner particles due to the bubbling are prevented. By so doing, there is obtained a diameter-reduced toner particle in which wax is evenly dispersed and which does not cause bleeding out.Type: GrantFiled: January 12, 2007Date of Patent: August 18, 2009Assignee: Sharp Kabushiki KaishaInventors: Katsuru Matsumoto, Yasuhiro Shibai
-
Patent number: 7572566Abstract: According to the method of producing toner, toner is produced by (i) forming particles of a pigmented resin by applying shear stress to a mixture of a pigmented resin composition, an organic solvent, a polymer dispersing agent, and a hydrophobic medium, the organic solvent being capable of reducing viscosity of the pigmented resin composition, and said polymer dispersing agent having a glass transition point in a range of 50° C. to 80° C. and an SP value in a range of 8.5 to 10, (ii) distilling off the organic solvent, and (iii) separating the toner from the hydrophobic medium and drying the toner. With the above arrangement, the method makes it possible to (i) easily downsize toner particle without causing thermal decomposition of a resin or separation of a release agent, and (ii) produce toner that is small in particle size, excellent in humidity-resistance, and less likely to aggregate.Type: GrantFiled: July 20, 2006Date of Patent: August 11, 2009Assignee: Sharp Kabushiki KaishaInventors: Yasuhiro Shibai, Katsuru Matsumoto
-
Publication number: 20090191477Abstract: Provided is a method for producing a toner including the steps of: preparing a resin liquid by mixing at least a binder resin made of polyester resin and a colorant with an ester organic solvent represented by the following general formula (1); dispersing the resin liquid in an aqueous medium to form an emulsion; and removing the ester organic solvent from the emulsion to produce a toner, in which the ester organic solvent before the preparation of the resin liquid contains water in an amount of not less than 1% by weight and up to the saturation solubility at 25° C. to the ester organic solvent. (in which R1 is a hydrogen atom or a methyl group, and R2 is an alkyl group having 1 to 4 carbon atoms).Type: ApplicationFiled: January 22, 2009Publication date: July 30, 2009Applicant: Brother Kogyo Kabushiki KaishaInventors: Masateru KAWAMURA, Jun IKAMI, Takanori UNO, Tomoaki HATTORI
-
Patent number: 7560213Abstract: A resin particle liquid dispersion for an electrostatic image developing toner comprises: a terminal addition-polymerized polyester having an acid value of from about 5 to about 70 mg·KOH/g, and the terminal addition-polymerized polyester is obtained by a process comprising: polycondensing a polycondensable monomer having a composition comprising the components (a) to (c) described in the specification to obtain a polyester having an addition-polymerizable unsaturated group at a terminal; and addition-polymerizing the addition-polymerizable unsaturated group of the polyester having an addition-polymerizable unsaturated group at a terminal.Type: GrantFiled: May 31, 2006Date of Patent: July 14, 2009Assignee: Fuji Xerox Co., LtdInventors: Hirotaka Matsuoka, Yuki Sasaki, Yasuo Matsumura, Fumiaki Mera, Satoshi Hiraoka
-
Publication number: 20090162780Abstract: A dry toner for developing an electrostatic image, including a toner binder containing a urea-modified polyester. The toner has an average sphericity of 0.96 or more and contains no more than 30% by weight of particles having a sphericity of less than 0.95.Type: ApplicationFiled: February 12, 2009Publication date: June 25, 2009Inventors: Hiroshi Yamashita, Tsunemi Sugiyama, Shigeru Emoto, Masami Tomita
-
Publication number: 20090162770Abstract: A method for producing colored polymer particles, including adding a colorant-containing composition containing a radically polymerizable monomer and a colorant in a supercritical fluid or a subcritical fluid and polymerizing the radically polymerizable monomer, so as to produce colored polymer particles which are insoluble in the supercritical fluid or subcritical fluid, wherein the supercritical fluid or subcritical fluid is a supercritical fluid or subcritical fluid in which at least the radically polymerizable monomer is soluble, but polymer particles resulted from polymerization of the radically polymerizable monomer are insoluble, and wherein the colorant is at least one selected from the group consisting of a pigment, a dye and a polymer dye.Type: ApplicationFiled: December 18, 2008Publication date: June 25, 2009Inventors: Takeshi Sako, Idzumi Okajima, Takahiro Yamashita, Satoyuki Sekiguchi, Chiaki Tanaka, Shogo Suzuki, Ryota Inoue
-
Publication number: 20090142685Abstract: An image forming method including charging an image bearing member by applying combination of DC voltage and AC voltage with frequency of 6.5 to 8.5 cycle/mm; irradiating the image bearing member with light to form an electrostatic image; developing the electrostatic image with a developer including toner to form a toner image; transferring the toner image onto a receiving material; fixing the toner image; cleaning the image bearing member with a blade; then applying a lubricant to the image bearing member; and then spreading the lubricant with a spreading member countering the image bearing member. The toner includes toner particles granulated in an aqueous medium; and at least three kinds of external additives including a first particulate hydrophobic silica, a particulate hydrophobic titanium oxide and a second particulate hydrophobic silica respectively having BET specific surface areas of 20 to 40 m2/g, 40 to 80 m2/g, and 130 to 300 m2/g.Type: ApplicationFiled: November 24, 2008Publication date: June 4, 2009Inventors: Tsuneyasu NAGATOMO, Toyoshi Sawada, Satoshi Kojima
-
Publication number: 20090136862Abstract: A process for producing a binder resin for electrostatic charge image developing toner, including the step (1) of mixing in combination with a raw material containing a low-molecular-weight resin and a high-molecular-weight resin and the step (2) of simultaneously therewith and/or thereafter removing a volatile component, characterized in that the raw material of the step (1) further contains a wax. Further, there is provided a process for producing an electrostatic charge image developing toner, characterized in that the above binder resin for toner is further loaded with the colorant.Type: ApplicationFiled: June 6, 2005Publication date: May 28, 2009Applicant: NIPPON CARBIDE KOGYO KABUSHIKI KAISHAInventors: Takashi Terabayashi, Kazuhiro Masuko
-
Publication number: 20090130578Abstract: [Problems] To provide a toner superior in shelf stability, not giving off an offensive odor and degrading the surrounding environment when used for printing, and superior in durability at the time of use for continuous printing under high temperature, high humidity conditions. [Means for Solving Problems] A process of production of a toner containing colored polymer particles obtained by polymerizing a polymerizable monomer composition containing a polymerizable monomer and colorant in an aqueous medium in the presence of a polymerization initiator, wherein the polymerization initiator is an organic peroxide having a molecular weight of 205 or less, and a purity of 90% or more.Type: ApplicationFiled: July 13, 2006Publication date: May 21, 2009Applicant: ZEON CORPORATIONInventor: Keita Sensui
-
Patent number: 7534542Abstract: Disclosed is a binder resin for a toner which contains a styrene-acrylic resin having a gel component and a small amount of a volatile component. Also disclosed are a method for producing the binder resin and a toner employing the binder resin. A binder resin (A) for a toner contains a styrene-acrylic resin having a structure derived from a carboxyl group and a structure derived from a glycidyl group, wherein the content (AIS) of a gel component is 1 mass %?AIS?50 mass % and the content (AVO) of a volatile component in the resin is AVO?200 ppm.Type: GrantFiled: September 24, 2004Date of Patent: May 19, 2009Assignee: Mitsui Chemicals, Inc.Inventors: Takeshi Yoshida, Kazuya Sakata
-
Publication number: 20090123862Abstract: The present disclosure provides toners including amorphous resins and crystalline resins. Toners with high glass transition temperatures and little plasticization may be obtained in accordance with the present disclosure.Type: ApplicationFiled: November 14, 2007Publication date: May 14, 2009Inventors: Mark E. Mang, Timothy L. Lincoln, Yuhua Tong, Kevin F. Marcell
-
Publication number: 20090117487Abstract: To provide a method for producing a toner for developing an electrostatic charge image, which is capable of producing toner host particles in good yield and which is excellent in image characteristics, image quality, scratch resistance of a developing device and toner consumption, and a screen device which is capable of screening continuously without clogging. A method for producing a toner for developing an electrostatic charge image, which comprises a step of screening a dispersion of toner host particles by a screen, characterized in that when the above step is carried out, Y?{1/(M2+r2+2Mr)}×108×0.Type: ApplicationFiled: August 23, 2006Publication date: May 7, 2009Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Shingo Ishiyama, Nobuyuki Aoyagi
-
Publication number: 20090117485Abstract: A toner for electrophotography, containing a resin binder containing a polyester-based resin (A) and a polyester-based resin (B) having a softening point of a temperature higher than the polyester-based resin (A) by 10° C. or more, wherein at least one of the polyester-based resins (A) and (B) is a resin derived from a (meth)acrylic acid-modified rosin, having a polyester unit obtainable by polycondensing an alcohol component and a carboxylic acid component containing a (meth)acrylic acid-modified rosin, and a method for producing the toner. The toner for electrophotography of the present invention is usable in, for example, developing or the like latent images formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.Type: ApplicationFiled: May 30, 2007Publication date: May 7, 2009Applicant: KAO CORPORATIONInventors: Yoshitomo Kimura, Yasunori Inagaki, Yoshihiro Ueno, Katsutoshi Aoki
-
Patent number: 7524602Abstract: Provided are a latex process and a toner process, both of which include the preparation of a latex having weight average molecular weight of from about 12×103 to about 24×103. The latex is manufactured under monomer-starved polymerization condition such as monomer feeding rate equal to or less than 0.516% per minute by weight of the monomer(s) to be fed. The toners prepared according to the present disclosure have gained improved properties such as gloss, fusing performance, crease performance, stripping performance, document offset, vinyl offset, and parent charging etc.Type: GrantFiled: June 20, 2005Date of Patent: April 28, 2009Assignee: Xerox CorporationInventors: Daryl Vanbesien, Karen A. Moffat, Emily L. Moore, Kimberly D. Nosella, David J. Sanders, Christine Anderson, Cuong Vong