By Polymerization Patents (Class 430/137.15)
  • Publication number: 20100239970
    Abstract: A toner for an electrophotographic image forming process or an electrostatic printing process, and a polyester resin for the toner are disclosed. The polyester resin comprises: acid components including 70 to 96 mol % of aromatic dibasic acid component, 3 to 20 mol % of cycloaliphatic dibasic acid component, and 1 to 10 mol % of trivalent or higher acid component; alcohol components including 10 to 50 mol % of cycloaliphatic diol component, 2 to 20 mol % of trihydric or higher alcohol component, and 30 to 88 mol % of aliphatic diol component; and a heat stabilizer.
    Type: Application
    Filed: July 10, 2008
    Publication date: September 23, 2010
    Inventors: Young-Man Yoo, Jae-Kyoung Roh, Kye-Yune Lee, Tae-Woong Lee
  • Publication number: 20100232837
    Abstract: A toner has a core-shell structure including a toner core portion having a resin with an active hydrogenactive hydrogen containing group, a colorant and at least one additive, and a toner shell portion surrounding the toner core portion, wherein the toner shell portion includes a cross-linked resin prepared by reaction of at least a portion of the active hydrogen containing group and the cross-linking agent.
    Type: Application
    Filed: October 22, 2008
    Publication date: September 16, 2010
    Applicant: SAMSUNG FINE CHEMICALS CO., LTD
    Inventors: Dae Il Hwang, Woo Young Yang, Keon Il Kim, Il Hyuk Kim, Jae Bum Park, Il Sun Hwang, Jae Kwang Hwang, Dae Woong Choi, Dong Won Kim, Duck Kyun Ahn
  • Patent number: 7785760
    Abstract: A toner is provided including a binder resin, a colorant, and a release agent, which has a volume average particle diameter (Dv) of from 3 to 9 ?m, and wherein the binder resin and the release agent form a sea-island structure in which the island formed of the release agent is dispersed in the sea formed of the binder resin in a cross-sectional image of the toner obtained by a transmission electron microscope (TEM), and the following relationships are satisfied: IB>IA and IB>IC, wherein each of IA, IB, and IC represents an area ratio (%) of the island in an outermost region (A) of the cross-sectional image of the toner, an intermediate region (B) thereof located under the outermost region (A), and an innermost region (C) thereof located under the intermediate region (B); and a method of preparing the toner.
    Type: Grant
    Filed: January 18, 2007
    Date of Patent: August 31, 2010
    Assignee: Ricoh Company Limited
    Inventors: Atsushi Yamamoto, Chiyoshi Nozaki, Tsuyoshi Nozaki, Minoru Nakamura, Yoshimichi Ishikawa
  • Publication number: 20100209837
    Abstract: Provided is a binder resin for color toners which comprises at least a carboxyl group-containing vinyl resin (C), a glycidyl group-containing vinyl resin (E) and a reaction product thereof, wherein the storage modulus G? at 160 degrees centigrade is not less than 20 and less than 800 Pa measured at a frequency of 6.28 rad/sec, the tetrahydrofuran (THF) soluble portion in the binder resin has a main peak in the molecular weight region of not less than 20,000 and less than 40,000 in the molecular weight distribution measured by gel permeation chromatography (GPC), and the binder resin contains at least one of releasing agents having a melting point of not lower than 60 and not higher than 120 degrees centigrade in an amount of not less than 3.5 and not more than 12 mass % based on 100 mass % of the total amount of the carboxyl group-containing vinyl resin (C), the glycidyl group-containing vinyl resin (E) and a reaction product thereof.
    Type: Application
    Filed: August 27, 2008
    Publication date: August 19, 2010
    Applicant: Mitsui Chemicals, Inc.
    Inventors: Hiroshi Matsuoka, Kazuya Sakata, Hiroyuki Takei, Kenji Uchiyama, Ichirou Sasaki
  • Publication number: 20100203442
    Abstract: Disclosed is a manufacturing method of a magenta toner including the steps of dispersing an oil phase containing a radical polymerizable monomer for forming the binder resin and the colorant in an aqueous medium to form dispersion liquid in which the oil phase is dispersed in a form of droplets in the aqueous medium, and polymerizing the radical polymerizable monomer in the droplets in dispersion liquid to form resin particles containing colorant, in which the colorant comprises C.I. Solvent Red 48.
    Type: Application
    Filed: February 2, 2010
    Publication date: August 12, 2010
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Ken OHMURA, Hiroshi YAMAZAKI
  • Patent number: 7767375
    Abstract: In a process for producing a polymerized toner, comprising Step 1 of preparing a polymerizable monomer composition and Step 2 of polymerizing the polymerizable monomer composition with a polymerization initiator to form colored polymer particles, Step 1 comprises Step A of finely dispersing the colorant in a liquid mixture containing the polymerizable monomer and the colorant, and further Step A comprises Step A1 of feeding a liquid mixture containing a polymerizable monomer and a colorant, which has a volume average particle diameter of 20 ?m or larger and/or contains particles having a particle diameter of 51 ?m or larger in a volume percentage of 20% or higher, to a dispersing machine of the type that mechanical shearing force is applied by rotation of an agitating blade to preliminarily disperse the colorant, and Step A2 of feeding the liquid mixture containing the colorant preliminarily dispersed in Step A1 to a media type dispersing machine equipped with a media-separating screen to more finely disperse
    Type: Grant
    Filed: June 22, 2005
    Date of Patent: August 3, 2010
    Assignee: Zeon Corporation
    Inventor: Hisashi Kurokawa
  • Publication number: 20100190103
    Abstract: Disclosed is a method for producing a polymerized toner. In the method, a mixture of colloidal silica as an aqueous dispersant and a polyvinylpyrrolidone is used during suspension polymerization. The amount of polyvinylpyrrolidone/colloidal silica aggregates having a diameter smaller than 100 nm is also limited to 1% by weight or less, based on the total weight of all aggregates. A polymerized toner produced by the method has a volume average particle diameter (dv) of 5 to 10 ?m and a volume average particle diameter/number average particle diameter ratio (dv/dp) of 1.5 or less. The polymerized toner is consumed in a small amount during printing. According to the method, the formation of emulsion particles having a size smaller than 0.5 ?m is inhibited.
    Type: Application
    Filed: October 8, 2008
    Publication date: July 29, 2010
    Applicant: LG CHEM LTD.
    Inventors: Wook Jang, Chang Soon Lee, Woo Cheul Jeong, Ji Hoon Lee
  • Patent number: 7763409
    Abstract: The present invention relates to a binder resin for a toner which is used in electrophotography and the like. An objective of the present invention is to obtain a binder resin for a toner containing a crystalline resin which satisfies both excellent low temperature fixing property and excellent offset resistance, a method for producing the binder resin, and a toner using the binder resin. The objective can be achieved by using a binder resin for a toner that is produced by subjecting an amorphous resin and a crystalline resin to melting, kneading and reaction, and is characterized in that it includes a network structure which includes a crystalline resin.
    Type: Grant
    Filed: May 18, 2005
    Date of Patent: July 27, 2010
    Assignee: Mitsui Chemicals, Inc.
    Inventor: Yoshihito Hirota
  • Patent number: 7754409
    Abstract: The present invention is a method of manufacturing toner particles that includes providing a first emulsion of a first aqueous phase comprising a pore stabilizing hydrocolloid dispersed in an organic solution containing a polymer. The first emulsion is dispersed in a second aqueous phase to form a second emulsion that is sheared in the presence of a stabilizing agent to form droplets of the first emulsion in the second aqueous phase. The organic solution is evaporated from the droplets to form porous toner particles.
    Type: Grant
    Filed: January 18, 2007
    Date of Patent: July 13, 2010
    Assignee: Eastman Kodak Company
    Inventors: Mridula Nair, David C. Boris, Charles P. Lusignan, Dennis J. Massa, Tamara K. Jones, Anita M. Fees
  • Patent number: 7754410
    Abstract: To provide a method for producing a toner for developing an electrostatic charge image, which is capable of producing toner host particles in good yield and which is excellent in image characteristics, image quality, scratch resistance of a developing device and toner consumption, and a screen device which is capable of screening continuously without clogging. A method for producing a toner for developing an electrostatic charge image, which comprises a step of screening a dispersion of toner host particles by a screen, characterized in that when the above step is carried out, Y?{1/(M2+r2+2Mr)}×108×0.
    Type: Grant
    Filed: August 23, 2006
    Date of Patent: July 13, 2010
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Shingo Ishiyama, Nobuyuki Aoyagi
  • Publication number: 20100167195
    Abstract: A chemical toner is described as well as methods of preparing the same.
    Type: Application
    Filed: November 24, 2009
    Publication date: July 1, 2010
    Inventors: Anne K. Shim, Eugene N. Step, Agathagelos Kyrlidis
  • Patent number: 7745089
    Abstract: A process for producing a toner by subjecting a polymer and a resin component containing a cross-linkable polymer capable of cross-linkingly reacting with the polymer, to cross-linking reaction in the presence of a first wax to form a wax-containing cross-linked polymer composition; mixing the wax-containing cross-linked polymer composition with at least a colorant and a second wax, followed by melt-kneading to form a toner composition; and pulverizing the toner composition to produce toner particles. Also disclosed is a toner produced by this process. The toner thus obtained is a toner whose fixing performance and anti-offset properties are well balanced and also which makes it possible to afford images having less fog and high quality, over a long period of time in environments of from low temperature and low humidity to high temperature and high humidity, and is highly durable without causing any contamination of members with which the toner comes into contact.
    Type: Grant
    Filed: September 20, 2007
    Date of Patent: June 29, 2010
    Assignee: Canon Kabushiki Kaisha
    Inventors: Nobuyuki Okubo, Tsutomu Onuma, Shuhei Moribe, Shinichiro Abe, Koji Nishikawa
  • Patent number: 7732115
    Abstract: The present invention relates to toner compositions comprising a resin and a colorant. Various embodiments of the colorant used in the toner compositions are disclosed, including a modified pigment comprising a pigment having attached at least one organic group having the formula -X-I, wherein X, which is directly attached to the pigment, represents an arylene or heteroarylene group, or an alkylene group, and I represents a non-polymeric group comprising at least one ionic group or at least one ionizable group. Processes for preparing toner compositions are also described.
    Type: Grant
    Filed: December 16, 2009
    Date of Patent: June 8, 2010
    Assignee: Cabot Corporation
    Inventors: Eugene N. Step, Agathagelos Kyrlidis
  • Publication number: 20100124713
    Abstract: A toner comprising: a polymer matrix comprising carbon nanotubes dispersed in a polymer; optionally one or more colorants; and optionally one or more waxes.
    Type: Application
    Filed: November 17, 2008
    Publication date: May 20, 2010
    Applicant: XEROX CORPORATION
    Inventors: Valerie M. FARRUGIA, Yu QI, Paul J. GERROIR, Rosa M. DUQUE, Biritawit ASFAW, Michael S. HAWKINS
  • Publication number: 20100119965
    Abstract: The present invention provides a method for producing a toner that can suppress the production of the decomposition products derived from a polymerization initiator, and can suppress the remaining presence, in the toner particles, of the unreacted polymerizable monomer and decomposition product residues. On the basis of this method, the present invention provides a toner that is excellent in triboelectric charging stability and can yield stable images over a long term.
    Type: Application
    Filed: May 16, 2008
    Publication date: May 13, 2010
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Atsushi Tani, Norikazu Fujimoto, Hitoshi Itabashi
  • Publication number: 20100112473
    Abstract: A preparation method of a toner comprising a binder resin and a colorant is disclosed, comprising forming resin particles containing a resin formed by allowing a styrene monomer, a (meth)acryl monomer and a polymer represented by the formula (1) to react, and mixing the resin particles with colorant particles which were dispersed and allowing the resin particles and the colorant particle to coagulate and fuse to form toner particles, X—(Y)n—X??formula (1) wherein X is at least one of an acryloyl group and a methacryloyl group, Y is a radical polymerizable monomer unit and n is an integer of 25 to 1000.
    Type: Application
    Filed: October 26, 2009
    Publication date: May 6, 2010
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Mikio KOUYAMA, Kenji HAYASHI, Hiroaki OBATA, Noriyuki KIMPARA, Hiroshi NAGASAWA
  • Patent number: 7709171
    Abstract: The present invention provides a charge control agent, adapted to control charging ability of resins or compositions containing resins, comprising a copolymer that comprises a polymer block A and a polymer block B, the polymer block A is prepared by copolymerizing a maleimide, which being unsubstituted or substituted for a hydrogen atom of an imide group by an electron-donating group, and styrene or a styrene derivative, and the polymer block B is formed of a polymer of styrene or a styrene derivative.
    Type: Grant
    Filed: July 18, 2007
    Date of Patent: May 4, 2010
    Assignee: Ricoh Company, Ltd.
    Inventors: Atsushi Yamamoto, Chiyoshi Nozaki, Tsuyoshi Nozaki, Mitsuyo Matsumoto, Katsunori Kurose
  • Patent number: 7709176
    Abstract: A method for producing a polymerized toner comprising a step of polymerizing a polymerizable monomer composition in an aqueous dispersion medium in the presence of a polymerization initiator to obtain a dispersion liquid of colored polymer particles and a stripping step of injecting a gas comprised of air or an inert gas into the dispersion liquid of the colored polymer particles while stirring the dispersion liquid in an evaporator and the flow rate of the gas injected per weight of the colored polymer particles being 0.05 to 4 L/(hr·kg), the pressure of the vapor phase of the evaporator being 5 to 80 kPa.
    Type: Grant
    Filed: August 29, 2006
    Date of Patent: May 4, 2010
    Assignee: Zeon Corporation
    Inventors: Junichi Takashima, Takashi Iga, Keita Sensui
  • Publication number: 20100099040
    Abstract: The present invention relates to toner compositions comprising a resin and a colorant. Various embodiments of the colorant used in the toner compositions are disclosed, including a modified pigment comprising a pigment having attached at least one organic group having the formula ?X-I, wherein X, which is directly attached to the pigment, represents an arylene or heteroarylene group, or an alkylene group, and I represents a non-polymeric group comprising at least one ionic group or at least one ionizable group. Processes for preparing toner compositions are also described.
    Type: Application
    Filed: December 16, 2009
    Publication date: April 22, 2010
    Inventors: Eugene N. Step, Agathagelos Kyrlidis
  • Patent number: 7695886
    Abstract: A process for producing a resin particle liquid dispersion for an electrostatic image developing toner, the process comprising: polycondensing a polycondensable monomer by utilizing an acid having a surface activating effect as a polycondensation catalyst, so as to obtain a polycondensed resin; and dispersing the polycondensed resin in an aqueous medium to which a base is added, so as to obtain a resin particle liquid dispersion in which a median diameter of resin particles is from 0.05 to 2.0 ?m, or the process comprising: polycondensing a polycondensable monomer by utilizing an acid having a surface activating effect as a polycondensation catalyst in a co-presence of a polycondensed resin, so as to obtain a polycondensed resin-containing material; and dispersing the polycondensed resin-containing material in an aqueous medium, so as to obtain a resin particle liquid dispersion in which a median diameter of resin particles is from 0.05 to 2.0 ?m.
    Type: Grant
    Filed: September 21, 2005
    Date of Patent: April 13, 2010
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yasuo Matsumura, Hirotaka Matsuoka, Satoshi Hiraoka, Yuki Sasaki, Fumiaki Mera, Hideo Maehata
  • Publication number: 20100081075
    Abstract: A magenta toner, produced by a method including suspending an oily liquid comprising a binder resin and a colorant in an aqueous medium, wherein the colorant comprises a naphthol pigment and a quinacridone pigment, and the quinacridone pigment comprises a pigment having a specific formula.
    Type: Application
    Filed: September 28, 2009
    Publication date: April 1, 2010
    Inventors: Naohiro WATANABE, Shinichi WAKAMATSU, Naohito SHIMOTA, Hiroshi YAMASHITA, Tsuyoshi SUGIMOTO, Masaki WATANABE, Tsuneyasu NAGATOMO
  • Patent number: 7682768
    Abstract: A process for producing a polymerized toner, comprising the step of polymerizing a polymerizable monomer composition containing a polymerizable monomer and a colorant in the presence of a polymerization initiator in an aqueous dispersion medium to form colored polymer particles, the process comprising the steps of mixing the polymerizable monomer with the colorant to prepare a polymerizable monomer mixture having an initial viscosity of 10 to 3,000 mPa·s or 0.3 to 1 mPa·s as measured at 25° C. by a Brookfield type viscometer, and then feeding the polymerizable monomer mixture to a media type dispersing machine to finely disperse the colorant by the media type dispersing machine, thereby preparing a dispersed polymerizable monomer mixture having a viscosity after the dispersion, the ratio of increase in viscosity of which is 1.0 to 10 times or 100 to 2,000 times as high as the initial viscosity.
    Type: Grant
    Filed: January 27, 2006
    Date of Patent: March 23, 2010
    Assignee: Zeon Corporation
    Inventor: Hisashi Kurokawa
  • Patent number: 7670741
    Abstract: A toner containing a toner particle manufactured by dispersing an organic solvent in which a component comprising a polymer having a portion reactive with an active hydrogen group is dispersed or dissolved in an aqueous medium; and reacting the polymer with a compound having at least one active hydrogen group, where the polymer is prepared by reacting an aliphatic polyol, a polyester resin and a diisocyanate compound and has an isocyanate group on at least one end of the polymer.
    Type: Grant
    Filed: March 16, 2007
    Date of Patent: March 2, 2010
    Assignee: Ricoh Company, Ltd.
    Inventors: Masahide Yamada, Akinori Saitoh, Masahiro Ohki
  • Publication number: 20100047708
    Abstract: A method for producing a toner is provided. The method comprises the steps of (1) dispersing a water-soluble polyvinyl alcohol having a degree of polymerization of 1,500 to 2,500 and a degree of saponification of 75 to 98% in an aqueous medium to prepare an aqueous dispersion of the polyvinyl alcohol, (2) preparing a mixture of monomers, (3) mixing the aqueous dispersion with the monomer mixture, and (4) polymerizing the monomers.
    Type: Application
    Filed: March 17, 2008
    Publication date: February 25, 2010
    Inventors: Wook Jang, Chang Soon Lee
  • Patent number: 7655372
    Abstract: The present invention relates to toner compositions comprising a resin and a colorant. Various embodiments of the colorant used in the toner compositions are disclosed, including a modified pigment comprising a pigment having attached at least one organic group having the formula —X—I, wherein X, which is directly attached to the pigment, represents an arylene or heteroarylene group, or an alkylene group, and I represents a non-polymeric group comprising at least one ionic group or at least one ionizable group. Processes for preparing toner compositions are also described.
    Type: Grant
    Filed: January 24, 2006
    Date of Patent: February 2, 2010
    Assignee: Cabot Corporation
    Inventors: Eugene N. Step, Agathagelos Kyrlidis
  • Patent number: 7652128
    Abstract: A composition including an initiator and an unsaturated sulfopolyester amine resin, and processes for preparing and using thereof.
    Type: Grant
    Filed: November 5, 2004
    Date of Patent: January 26, 2010
    Assignee: Xerox Corporation
    Inventors: Guerino Sacripante, Ke Zhou
  • Publication number: 20100009278
    Abstract: A toner is provided which has toner particles and a fine silica powder mixed by external addition to the toner particles. The toner has a weight average particle diameter of 4.0 to 9.0 ?m. The fine silica powder is subjected to hydrophobic treatment with dimethylsilicone oil, and has, in particle size distribution based on volume, a peak at which cumulative frequency is largest, in the measurement range of 0.02 ?m to 1,000.00 ?m; the cumulative frequency of 0.10 ?m to less than 1.00 ?m being 7.0% or less, and, the fine silica powder fulfills the following conditions: 1) A+B?93.0; 2) 0.45?A/B?6.00; and 3) the value of [(carbon content of the treated fine silica powder)/(BET specific surface area of fine silica powder before hydrophobic treatment)] is 0.030 or more to 0.055 or less.
    Type: Application
    Filed: September 21, 2009
    Publication date: January 14, 2010
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Naotaka Ikeda, Shinya Yachi, Katsuyuki Nonaka, Emi Watanabe, Koji Abe, Nobuhisa Abe
  • Publication number: 20090280430
    Abstract: There is provided a method for manufacturing a toner capable of providing a toner having excellent low-temperature fixing property and anti-offset property by adjusting a molecular weight distribution of a polymerization toner to a narrow distribution range. The method is characterized in that a toner is polymerized using a reversible addition-fragmentation chain transfer polymerization (RAFT) method by adding a dithioacetate, xanthate or dithioester-based chain transfer agent in the polymerization of a toner.
    Type: Application
    Filed: January 30, 2008
    Publication date: November 12, 2009
    Inventors: Hui Je Lee, Woo Cheul Jung, Ji Hoon Lee, Yu Na Kim, Jung Woo Kim
  • Publication number: 20090280429
    Abstract: The present disclosure provides for enzymatic polymerization to produce polyester resins suitable for use in manufacturing toners.
    Type: Application
    Filed: May 8, 2008
    Publication date: November 12, 2009
    Applicant: XEROX CORPORATION
    Inventors: Valerie M. Farrugia, Jordan H. Wosnick, Kristin M. Pouw, Paul J. Gerroir
  • Patent number: 7611816
    Abstract: In a process for producing toner particles through granulation by a wet process, a process for producing toner particles is provided that enables reduction of water content in wet toner particle cakes obtained by separating toner particles from a toner particle dispersion in a good efficiency, followed by washing, and enables efficient wash-away of impurities remaining on the toner particle surfaces so as to promise superior image characteristics. The toner particles are produced through a filtering step in which a slurry which contains toner particles is subjected to solid-liquid separation by means of a belt filter having a pressing aeration means which carries out aeration with pressing, to form wet toner particle cakes.
    Type: Grant
    Filed: July 24, 2006
    Date of Patent: November 3, 2009
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yoshinori Tuji, Hidekazu Fumita, Minoru Omura
  • Publication number: 20090269691
    Abstract: Disclosed is a toner which is excellent in low-temperature fixability, high-temperature offset resistance, storage stability and durability, while having a wide range of fixing temperature. Also disclosed is a polyester resin used for such a toner. The polyester resin is one of the following polyester resin (A)-(E) for toners.
    Type: Application
    Filed: September 20, 2006
    Publication date: October 29, 2009
    Applicant: Mitsubishi Rayon Co., Ltd.
    Inventors: Shinya Yamato, Tetsuya Ochiai, Hideyuki Fujii
  • Publication number: 20090246681
    Abstract: The present teaching provides a method for producing a positive charging toner that can exhibit stable charge characteristics. According to the present teaching, a positive charging toner is produced by preparing a base particle suspension having a conductivity not higher than 70 ?S/cm and comprising base particles that are obtained by mixing and emulsifying an aqueous medium and a resin solution containing the polyester resin; producing toner base particles by mixing the base particle suspension with a charge control resin microparticle suspension containing charge control resin microparticles; causing the charge control resin microparticles to adhere to the surfaces of the base particles; and washing the toner base particles.
    Type: Application
    Filed: March 31, 2009
    Publication date: October 1, 2009
    Applicant: Brother Kogyo Kabushiki Kaisha
    Inventors: Masateru KAWAMURA, Yasutomo Imai
  • Publication number: 20090226832
    Abstract: The invention is related to a toner of static charge image and a method for manufacturing such a toner of static charge image, which solve the problems of existing toner of static charge image, namely easy detachment of colorant, the pollution of carriers and developing sleeves and low durability. For the toner of static charge image obtained by aggregation of at least polymer particles, the polymer particles at least contain polymer particles A with inner wax and polymer particles B with inner colorant. The toner of static charge image of the invention exhibits good effect of fixing characteristics, not causing the pollution of carriers and developing sleeves, and could maintain long-term stable performance.
    Type: Application
    Filed: April 30, 2008
    Publication date: September 10, 2009
    Applicant: HUBEI DINGLONG CHEMICAL CO., LTD.
    Inventors: Shunquan ZHU, Xiukui WANG, Yubin WANG
  • Patent number: 7585608
    Abstract: A method of preparing a toner includes: preparing high molecular weight latex particles by polymerizing a toner composition including a macromonomer having a hydrophilic group, a hydrophobic group and at least one reactive functional group, at least one polymerizable monomer, a colorant and wax; aggregating the high molecular latex particles in the absence of an emulsifier, a colorant, and wax; and separating and drying the aggregated high molecular weight latex particles. A toner is prepared using the method described above. An image forming method using the toner and an image forming apparatus employing the toner are also provided. Using the method described above, polymerizable toner particles can be prepared using a simplified process and the colorant and was inside the toner can be easily dispersed.
    Type: Grant
    Filed: November 13, 2006
    Date of Patent: September 8, 2009
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Chang-kook Hong, Kyung-yol Yon, Jun-young Lee, Min-young Cheong
  • Publication number: 20090220880
    Abstract: Pigment particles with at least one metal oxide surface additive, wherein the at least one metal oxide surface additive is a metal oxide particle covalently bonded with at least one polycondensation polymer, wherein the pigment particle is a pearlescent or metallic pigment.
    Type: Application
    Filed: March 3, 2008
    Publication date: September 3, 2009
    Applicant: XEROX CORPORATION
    Inventors: Karen A. MOFFAT, Valerie M. FARRUGIA, Ke ZHOU, Richard P.N. VEREGIN, Cuong VONG, Eric M. STROHM, Wafa F. BASHIR
  • Publication number: 20090214976
    Abstract: A liquid developer comprised of toner particles having excellent fixing properties to a recording medium is provided, and a liquid developer in which toner particles having uniform shape and small particle size distribution are dispersed is also provided, and further a method of producing a liquid developer capable of producing such a liquid developer efficiently is also provided. In particular, a producing method capable of producing such a liquid developer as described above in a method harmless to the environment is provided.
    Type: Application
    Filed: January 12, 2006
    Publication date: August 27, 2009
    Applicant: SEIKO EPSON CORPORATION
    Inventors: Takashi Teshima, Satoru Miura
  • Patent number: 7575843
    Abstract: A toner is manufactured by way of a coarse particle preparing step, a slurry preparing step, a pulverizing step, a cooling step, and a depressurizing step. Slurry of toner coarse particles obtained by way of the coarse particle preparing step and the slurry preparing step is made to pass under heat and pressure through a pressure-resistant nozzle whereby toner coarse particles are pulverized into diameter-reduced toner particles. By providing the cooling step immediately after the pulverizing step, dispersion of wax component into the toner particles is promoted. And by further providing the depressurizing step, bubbling and coarsening of the toner particles due to the bubbling are prevented. By so doing, there is obtained a diameter-reduced toner particle in which wax is evenly dispersed and which does not cause bleeding out.
    Type: Grant
    Filed: January 12, 2007
    Date of Patent: August 18, 2009
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Katsuru Matsumoto, Yasuhiro Shibai
  • Patent number: 7572566
    Abstract: According to the method of producing toner, toner is produced by (i) forming particles of a pigmented resin by applying shear stress to a mixture of a pigmented resin composition, an organic solvent, a polymer dispersing agent, and a hydrophobic medium, the organic solvent being capable of reducing viscosity of the pigmented resin composition, and said polymer dispersing agent having a glass transition point in a range of 50° C. to 80° C. and an SP value in a range of 8.5 to 10, (ii) distilling off the organic solvent, and (iii) separating the toner from the hydrophobic medium and drying the toner. With the above arrangement, the method makes it possible to (i) easily downsize toner particle without causing thermal decomposition of a resin or separation of a release agent, and (ii) produce toner that is small in particle size, excellent in humidity-resistance, and less likely to aggregate.
    Type: Grant
    Filed: July 20, 2006
    Date of Patent: August 11, 2009
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Yasuhiro Shibai, Katsuru Matsumoto
  • Publication number: 20090191477
    Abstract: Provided is a method for producing a toner including the steps of: preparing a resin liquid by mixing at least a binder resin made of polyester resin and a colorant with an ester organic solvent represented by the following general formula (1); dispersing the resin liquid in an aqueous medium to form an emulsion; and removing the ester organic solvent from the emulsion to produce a toner, in which the ester organic solvent before the preparation of the resin liquid contains water in an amount of not less than 1% by weight and up to the saturation solubility at 25° C. to the ester organic solvent. (in which R1 is a hydrogen atom or a methyl group, and R2 is an alkyl group having 1 to 4 carbon atoms).
    Type: Application
    Filed: January 22, 2009
    Publication date: July 30, 2009
    Applicant: Brother Kogyo Kabushiki Kaisha
    Inventors: Masateru KAWAMURA, Jun IKAMI, Takanori UNO, Tomoaki HATTORI
  • Patent number: 7560213
    Abstract: A resin particle liquid dispersion for an electrostatic image developing toner comprises: a terminal addition-polymerized polyester having an acid value of from about 5 to about 70 mg·KOH/g, and the terminal addition-polymerized polyester is obtained by a process comprising: polycondensing a polycondensable monomer having a composition comprising the components (a) to (c) described in the specification to obtain a polyester having an addition-polymerizable unsaturated group at a terminal; and addition-polymerizing the addition-polymerizable unsaturated group of the polyester having an addition-polymerizable unsaturated group at a terminal.
    Type: Grant
    Filed: May 31, 2006
    Date of Patent: July 14, 2009
    Assignee: Fuji Xerox Co., Ltd
    Inventors: Hirotaka Matsuoka, Yuki Sasaki, Yasuo Matsumura, Fumiaki Mera, Satoshi Hiraoka
  • Publication number: 20090162780
    Abstract: A dry toner for developing an electrostatic image, including a toner binder containing a urea-modified polyester. The toner has an average sphericity of 0.96 or more and contains no more than 30% by weight of particles having a sphericity of less than 0.95.
    Type: Application
    Filed: February 12, 2009
    Publication date: June 25, 2009
    Inventors: Hiroshi Yamashita, Tsunemi Sugiyama, Shigeru Emoto, Masami Tomita
  • Publication number: 20090162770
    Abstract: A method for producing colored polymer particles, including adding a colorant-containing composition containing a radically polymerizable monomer and a colorant in a supercritical fluid or a subcritical fluid and polymerizing the radically polymerizable monomer, so as to produce colored polymer particles which are insoluble in the supercritical fluid or subcritical fluid, wherein the supercritical fluid or subcritical fluid is a supercritical fluid or subcritical fluid in which at least the radically polymerizable monomer is soluble, but polymer particles resulted from polymerization of the radically polymerizable monomer are insoluble, and wherein the colorant is at least one selected from the group consisting of a pigment, a dye and a polymer dye.
    Type: Application
    Filed: December 18, 2008
    Publication date: June 25, 2009
    Inventors: Takeshi Sako, Idzumi Okajima, Takahiro Yamashita, Satoyuki Sekiguchi, Chiaki Tanaka, Shogo Suzuki, Ryota Inoue
  • Publication number: 20090142685
    Abstract: An image forming method including charging an image bearing member by applying combination of DC voltage and AC voltage with frequency of 6.5 to 8.5 cycle/mm; irradiating the image bearing member with light to form an electrostatic image; developing the electrostatic image with a developer including toner to form a toner image; transferring the toner image onto a receiving material; fixing the toner image; cleaning the image bearing member with a blade; then applying a lubricant to the image bearing member; and then spreading the lubricant with a spreading member countering the image bearing member. The toner includes toner particles granulated in an aqueous medium; and at least three kinds of external additives including a first particulate hydrophobic silica, a particulate hydrophobic titanium oxide and a second particulate hydrophobic silica respectively having BET specific surface areas of 20 to 40 m2/g, 40 to 80 m2/g, and 130 to 300 m2/g.
    Type: Application
    Filed: November 24, 2008
    Publication date: June 4, 2009
    Inventors: Tsuneyasu NAGATOMO, Toyoshi Sawada, Satoshi Kojima
  • Publication number: 20090136862
    Abstract: A process for producing a binder resin for electrostatic charge image developing toner, including the step (1) of mixing in combination with a raw material containing a low-molecular-weight resin and a high-molecular-weight resin and the step (2) of simultaneously therewith and/or thereafter removing a volatile component, characterized in that the raw material of the step (1) further contains a wax. Further, there is provided a process for producing an electrostatic charge image developing toner, characterized in that the above binder resin for toner is further loaded with the colorant.
    Type: Application
    Filed: June 6, 2005
    Publication date: May 28, 2009
    Applicant: NIPPON CARBIDE KOGYO KABUSHIKI KAISHA
    Inventors: Takashi Terabayashi, Kazuhiro Masuko
  • Publication number: 20090130578
    Abstract: [Problems] To provide a toner superior in shelf stability, not giving off an offensive odor and degrading the surrounding environment when used for printing, and superior in durability at the time of use for continuous printing under high temperature, high humidity conditions. [Means for Solving Problems] A process of production of a toner containing colored polymer particles obtained by polymerizing a polymerizable monomer composition containing a polymerizable monomer and colorant in an aqueous medium in the presence of a polymerization initiator, wherein the polymerization initiator is an organic peroxide having a molecular weight of 205 or less, and a purity of 90% or more.
    Type: Application
    Filed: July 13, 2006
    Publication date: May 21, 2009
    Applicant: ZEON CORPORATION
    Inventor: Keita Sensui
  • Patent number: 7534542
    Abstract: Disclosed is a binder resin for a toner which contains a styrene-acrylic resin having a gel component and a small amount of a volatile component. Also disclosed are a method for producing the binder resin and a toner employing the binder resin. A binder resin (A) for a toner contains a styrene-acrylic resin having a structure derived from a carboxyl group and a structure derived from a glycidyl group, wherein the content (AIS) of a gel component is 1 mass %?AIS?50 mass % and the content (AVO) of a volatile component in the resin is AVO?200 ppm.
    Type: Grant
    Filed: September 24, 2004
    Date of Patent: May 19, 2009
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Takeshi Yoshida, Kazuya Sakata
  • Publication number: 20090123862
    Abstract: The present disclosure provides toners including amorphous resins and crystalline resins. Toners with high glass transition temperatures and little plasticization may be obtained in accordance with the present disclosure.
    Type: Application
    Filed: November 14, 2007
    Publication date: May 14, 2009
    Inventors: Mark E. Mang, Timothy L. Lincoln, Yuhua Tong, Kevin F. Marcell
  • Publication number: 20090117487
    Abstract: To provide a method for producing a toner for developing an electrostatic charge image, which is capable of producing toner host particles in good yield and which is excellent in image characteristics, image quality, scratch resistance of a developing device and toner consumption, and a screen device which is capable of screening continuously without clogging. A method for producing a toner for developing an electrostatic charge image, which comprises a step of screening a dispersion of toner host particles by a screen, characterized in that when the above step is carried out, Y?{1/(M2+r2+2Mr)}×108×0.
    Type: Application
    Filed: August 23, 2006
    Publication date: May 7, 2009
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Shingo Ishiyama, Nobuyuki Aoyagi
  • Publication number: 20090117485
    Abstract: A toner for electrophotography, containing a resin binder containing a polyester-based resin (A) and a polyester-based resin (B) having a softening point of a temperature higher than the polyester-based resin (A) by 10° C. or more, wherein at least one of the polyester-based resins (A) and (B) is a resin derived from a (meth)acrylic acid-modified rosin, having a polyester unit obtainable by polycondensing an alcohol component and a carboxylic acid component containing a (meth)acrylic acid-modified rosin, and a method for producing the toner. The toner for electrophotography of the present invention is usable in, for example, developing or the like latent images formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.
    Type: Application
    Filed: May 30, 2007
    Publication date: May 7, 2009
    Applicant: KAO CORPORATION
    Inventors: Yoshitomo Kimura, Yasunori Inagaki, Yoshihiro Ueno, Katsutoshi Aoki
  • Patent number: 7524602
    Abstract: Provided are a latex process and a toner process, both of which include the preparation of a latex having weight average molecular weight of from about 12×103 to about 24×103. The latex is manufactured under monomer-starved polymerization condition such as monomer feeding rate equal to or less than 0.516% per minute by weight of the monomer(s) to be fed. The toners prepared according to the present disclosure have gained improved properties such as gloss, fusing performance, crease performance, stripping performance, document offset, vinyl offset, and parent charging etc.
    Type: Grant
    Filed: June 20, 2005
    Date of Patent: April 28, 2009
    Assignee: Xerox Corporation
    Inventors: Daryl Vanbesien, Karen A. Moffat, Emily L. Moore, Kimberly D. Nosella, David J. Sanders, Christine Anderson, Cuong Vong