By Polymerization Patents (Class 430/137.15)
  • Publication number: 20120164571
    Abstract: A polymerized toner is provided. The polymerized toner comprises a reactive anionic surfactant having at least one reactive functional group. The reactive anionic surfactant is added simultaneously with a dispersant to prepare an aqueous dispersion or is added within 2 hour after a polymerization reaction of a monomer mixture is initiated in an aqueous dispersion. This simultaneous or rapid addition allows the reactive anionic surfactant to be dispersed on the surface of the toner particles. The reactive anionic surfactant is located over the entire surface of the toner particles to increase the surface charge density of the toner, achieving good charge stability and excellent imaging characteristics.
    Type: Application
    Filed: February 29, 2012
    Publication date: June 28, 2012
    Inventors: Dong Jin PARK, Chang Soon Lee, Wook Jang, Yu Na Kim, Jung Woo Kim
  • Patent number: 8192907
    Abstract: A toner including toner particles containing at least a binder resin and a colorant. The binder resin is a vinyl-based resin. The toner contains a THF insoluble matter in a quantity of 0.0 mass % or more to less than 16.0 mass %. The toner has a main peak in a molecular weight domain Dr1 ranging from 5,000 to 80,000 in measurement of THF soluble matter of the toner with a gel permeation chromatogram (GPC)-differential refractive index detector (RI), and the toner has a main peak in a molecular weight domain Dm1 ranging from 10,000 to 120,000 and at least one peak in a molecular weight domain Dm2 ranging from 300,000 to 7,000,000 in the GPC-RI measurement in measurement with a GPC-multi-angle laser light scattering detector (MALLS).
    Type: Grant
    Filed: June 25, 2007
    Date of Patent: June 5, 2012
    Assignee: Canon Kabushiki Kaisha
    Inventors: Koji Abe, Shinya Yachi, Satoshi Handa, Kazumi Yoshizaki, Emi Tosaka, Yasuhiro Hashimoto, Nobuhisa Abe, Yushi Mikuriya
  • Patent number: 8192909
    Abstract: The present invention provides a porous toner. The porous toner has a porosity of greater that 20 percent. The toner can include vinyl polymers, copolymers of styrene monomers and polyesters. In addition a method of manufacture of the toner particles is provided.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: June 5, 2012
    Assignee: Eastman Kodak Company
    Inventors: Xin Jin, Jason Morgan, Charles T. Havens
  • Publication number: 20120135344
    Abstract: The present invention is to provide a toner for developing electrostatic images having a low minimum fixing temperature, and high hot offset resistance and high heat-resistant shelf stability, and a method for producing the toner. Also, the present invention is to provide a toner for developing electrostatic images, comprising a binder resin, a colorant, a release agent and a retention aid, wherein the retention aid is a copolymer of 70 to 98% by weight styrene and 2 to 30% by weight (meth)alkyl acrylate, and the copolymer has a glass transition temperature of 5 to 60° C.
    Type: Application
    Filed: November 23, 2011
    Publication date: May 31, 2012
    Applicant: ZEON CORPORATION
    Inventor: Azusa Wada
  • Publication number: 20120129094
    Abstract: A toner prepared by a method comprising granulating while polymerizing a ring-opening polymerizable monomer with a catalyst under the presence of a surfactant and a colorant in a compressible fluid.
    Type: Application
    Filed: October 27, 2011
    Publication date: May 24, 2012
    Inventors: Yoshitaka Yamauchi, Chiaki Tanaka, Taichi Nemoto
  • Patent number: 8178268
    Abstract: A magenta toner, produced by a method including suspending an oily liquid comprising a binder resin and a colorant in an aqueous medium, wherein the colorant comprises a naphthol pigment and a quinacridone pigment, and the quinacridone pigment comprises a pigment having a specific formula.
    Type: Grant
    Filed: September 28, 2009
    Date of Patent: May 15, 2012
    Assignee: Ricoh Company, Limited
    Inventors: Naohiro Watanabe, Shinichi Wakamatsu, Naohito Shimota, Hiroshi Yamashita, Tsuyoshi Sugimoto, Masaki Watanabe, Tsuneyasu Nagatomo
  • Patent number: 8178275
    Abstract: The present invention provides a method for producing a toner that can suppress the production of the decomposition products derived from a polymerization initiator, and can suppress the remaining presence, in the toner particles, of the unreacted polymerizable monomer and decomposition product residues. On the basis of this method, the present invention provides a toner that is excellent in triboelectric charging stability and can yield stable images over a long term.
    Type: Grant
    Filed: May 16, 2008
    Date of Patent: May 15, 2012
    Assignee: Canon Kabushiki Kaisha
    Inventors: Atsushi Tani, Norikazu Fujimoto, Hitoshi Itabashi
  • Patent number: 8178276
    Abstract: A method of manufacturing a toner including granulating mother toner particles in an aqueous medium to obtain a slurry containing the mother toner particles and adjusting a size distribution of the mother toner particles by screening coarse mother toner particles from the slurry with a screen to obtain the toner containing mother toner particulates.
    Type: Grant
    Filed: March 6, 2009
    Date of Patent: May 15, 2012
    Assignee: Ricoh Company Limited
    Inventors: Osamu Uchinokura, Akinori Saitoh, Junichi Awamura, Masahide Yamada, Hiroshi Yamada
  • Publication number: 20120107736
    Abstract: The present invention relates to a process for preparing a polymerized toner, and in particular to a process for preparing a polymerized toner and a polymerized toner prepared therefrom, wherein a certain block copolymer and copper phthalocyanine are used within a predetermined range of the amounts for a carbon black dispersant during a suspension polymerization, thereby making it possible to realize a narrow particle sizes distribution, high transcription efficiency, and an enhanced image concentration.
    Type: Application
    Filed: September 23, 2011
    Publication date: May 3, 2012
    Applicant: LG CHEM, LTD
    Inventors: Wook JANG, Chang-Soon LEE, Dong-Jin PARK, Jung-Woo KIM
  • Publication number: 20120082931
    Abstract: Disclosed is a producing method of a decolorizable toner, comprising dispersing a mixed composition containing encapsulated colorant particles which are particles containing a color developable compound and a color developing agent and coated with an outer shell, a polymerizable monomer, and a release agent in an aqueous medium, and subjecting the polymerizable monomer to suspension polymerization in the aqueous medium.
    Type: Application
    Filed: August 31, 2011
    Publication date: April 5, 2012
    Applicant: TOSHIBA TEC KABUSHIKI KAISHA
    Inventors: Tsuyoshi Itou, Takahito Kabai, Takayasu Aoki, Masahiro Ikuta
  • Patent number: 8142976
    Abstract: A method of manufacturing a double emulsion with narrow dispersed phase particle size distribution comprising: providing an organic phase comprising solid hydrocolloid particles dispersed in an organic solvent; and dispersing the organic phase in an aqueous phase in the presence of a controlled amount of stabilizing agent to form an emulsion of droplets of the organic phase dispersed in the external aqueous phase, wherein the hydrocolloid particles in the organic phase droplets are swelled with water from the external aqueous phase to form internal droplets of an aqueous phase in the organic phase droplets, thereby forming a double emulsion comprising droplets of the organic phase of controlled narrow particle size distribution in the external aqueous phase, where the organic phase droplets contain internal droplets of an aqueous phase.
    Type: Grant
    Filed: December 3, 2009
    Date of Patent: March 27, 2012
    Assignee: Eastman Kodak Company
    Inventor: Xiqiang Yang
  • Publication number: 20120052432
    Abstract: A negatively chargeable developer includes: negatively chargeable toner mother particles including at least binding resin and colorant; and an external additive that is externally added to a surface of the toner mother particles, wherein the external additive includes polymethyl methacrylate that is within a range from approximately 0.4 parts by weight to approximately 0.8 parts by weight inclusive per 100 parts by weight of the toner mother particles and that has positive chargeability.
    Type: Application
    Filed: August 30, 2011
    Publication date: March 1, 2012
    Applicant: Oki Data Corporation
    Inventor: Yuki MATSUURA
  • Patent number: 8124308
    Abstract: Toner and a developer which are excellent in cleaning property and fixing property at low temperature, and capable of forming images with high quality are provided, along with a method for their production. A toner producing method involves dispersing and/or emulsifying an oil phase or a monomer phase containing a toner composition and/or a toner composition precursor in a water-based medium to granulate, wherein the toner has an average circularity of 0.925 to 0.970, and the toner composition and/or the toner composition precursor has a layered inorganic material in which at least a part of interlayer ions in the layered inorganic material has been exchanged with organic ions.
    Type: Grant
    Filed: December 13, 2010
    Date of Patent: February 28, 2012
    Assignee: Ricoh Company. Ltd.
    Inventors: Naohiro Watanabe, Shigeru Emoto, Yohichiroh Watanabe, Masahide Yamada, Tsunemi Sugiyama, Masahiro Ohki, Akinori Saitoh, Ryota Inoue, Osamu Uchinokura, Junichi Awamura
  • Patent number: 8119319
    Abstract: The present teaching provides a method for producing a positive charging toner that can exhibit stable charge characteristics. According to the present teaching, a positive charging toner is produced by preparing a base particle suspension having a conductivity not higher than 70 ?S/cm and comprising base particles that are obtained by mixing and emulsifying an aqueous medium and a resin solution containing the polyester resin; producing toner base particles by mixing the base particle suspension with a charge control resin microparticle suspension containing charge control resin microparticles; causing the charge control resin microparticles to adhere to the surfaces of the base particles; and washing the toner base particles.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: February 21, 2012
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Masateru Kawamura, Yasutomo Imai
  • Publication number: 20120021353
    Abstract: Disclosed is a method for producing toner, comprising (1) mixing, with an aqueous medium, a resin solution of an organic solvent in which amorphous polyester resin having unsaturated dicarboxylic acid monomer units is dissolved, and forming an amorphous polyester resin particle dispersion; (2) adding a radical polymerization initiator to the amorphous polyester resin particle dispersion obtained in (1), cross-linking the amorphous polyester resin, and forming a cross-linked amorphous polyester resin particle dispersion; and (3) mixing at least the cross-linked amorphous polyester resin particle dispersion obtained in (2), with a crystalline polyester resin particle dispersion, aggregating cross-linked amorphous polyester resin particles and crystalline polyester resin particles, and forming toner particles.
    Type: Application
    Filed: July 19, 2011
    Publication date: January 26, 2012
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Hiroshi NAGASAWA, Mikio KOUYAMA, Kenji HAYASHI, Hiroaki OBATA
  • Patent number: 8092975
    Abstract: Provided is a method for producing a toner for developing electrostatic image which inhibits the generation of small diameter microparticles as a by-product in the polymerization for the toner, which includes easy or simple washing treatment (washing/filtration/dehydration), and which is excellent in productivity. The method is a method for producing a toner for developing electrostatic image comprising a suspending step of suspending a polymerizable monomer composition containing at least a polymerizable monomer and a colorant into an aqueous dispersion medium containing a dispersion stabilizer to yield a suspension wherein droplets of the polymerizable monomer composition are dispersed, and a step of subjecting the suspension to suspension polymerization in the presence of a polymerization initiator to yield colored resin particles, wherein the colorant is a metal-containing organic pigment, and when the suspension polymerization is performed, the suspension contains 0.
    Type: Grant
    Filed: June 26, 2008
    Date of Patent: January 10, 2012
    Assignee: Zeon Corporation
    Inventor: Hisashi Kurokawa
  • Patent number: 8092973
    Abstract: The present disclosure provides processes for reducing the particle size of latex resins and toners produced with such resins. In embodiments, a gel latex may be formed as a seed particle and then utilized to form latex resins and toner particles. In accordance with the present disclosure, one may be able to utilize materials for the production of latex resins and toners which may otherwise produce particles that are too large in the absence of the gel latex.
    Type: Grant
    Filed: April 21, 2008
    Date of Patent: January 10, 2012
    Assignee: Xerox Corporation
    Inventors: Zhen Lai, Chieh-Min Cheng, Robert D. Bayley, Grazyna E. Kmiecik-Lawrynowicz, Maura A. Sweeney, Daniel G. Marsh, Emily L. Moore, Shigang Qiu, Tie Hwee Ng
  • Patent number: 8092974
    Abstract: A production method of a toner includes a suspension process in which a polymerizable monomer composition is dispersed in an aqueous dispersion medium; and a polymerization process in which suspension polymerization is performed with the suspension in the presence of a polymerization initiator to obtain colored resin particles. In the suspension process an inhibitor of small diameter microparticle production is contained in the aqueous dispersion medium. A minimum reaction activation energy Emin of the inhibitor of small diameter microparticle production is 7 kcal/mol or less and an octanol-water partition coefficient log P is 2 or less.
    Type: Grant
    Filed: September 27, 2007
    Date of Patent: January 10, 2012
    Assignee: Zeon Corporation
    Inventors: Hisashi Kurokawa, Michito Horie
  • Publication number: 20110305984
    Abstract: A toner having a toner particle including a core particle obtained by polymerizing a polymerizable monomer composition containing at least a polymerizable monomer, a colorant, a release agent, a polar resin, and a crystalline polyester in an aqueous medium and an outer shell formed by fixing resin fine particles to the surface of the core particle, wherein the resin constituting the resin fine particles is an amorphous resin and the acid value of the resin fine particles is 4.0 to 50.0 mgKOH/g.
    Type: Application
    Filed: June 9, 2011
    Publication date: December 15, 2011
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Tsuneyoshi Tominaga, Ryoichi Fujita, Tsutomu Shimano
  • Publication number: 20110305989
    Abstract: A method of stably producing a toner is provided. This method provides a long-term stabilization of material dispersion in a colorant-dispersed solution and inhibits segregation of the material and provides a more microfine and more uniform dispersion of the colorant in the toner, and moreover produces a toner that has a sharp toner particle diameter distribution. This method of producing toner has at least a colorant dispersion step of obtaining a colorant-dispersed solution by dispersing a pigment-containing colorant in a liquid mixture that contains the colorant and a dissolved resin solution or a polymerizable monomer, wherein the liquid mixture contains a nonionic surfactant and the nonionic surfactant has at least an oxyalkylene group and has a hydrophile-lipophile balance value (HLB value) of 9.0 or more and 17.0 or less.
    Type: Application
    Filed: June 3, 2011
    Publication date: December 15, 2011
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Naoya Isono, Katsuyuki Nonaka, Yasuhiro Hashimoto, Akira Sugiyama, Yuhei Terui
  • Patent number: 8076051
    Abstract: A method for preparing a particulate image forming material such as toner, which includes providing a particulate material including a chain transfer agent; and contacting the particulate material with at least one of a supercritical fluid and a sub-critical fluid under pressure to remove the chain transfer agent from the particulate material. A toner prepared by the method. A toner container containing the toner. A developer including the toner. An image forming method including preparing an electrostatic latent image and developing the latent image with the developer. An image forming apparatus including an image bearing member configured to bear an electrostatic latent image, a developing device configured to develop the electrostatic latent image with the developer to form a toner image on the surface of the image bearing member, a transfer device, a fixing device, and a cleaner configured to clean the image bearing member.
    Type: Grant
    Filed: June 14, 2005
    Date of Patent: December 13, 2011
    Assignee: Ricoh Company Limited
    Inventors: Takuya Saito, Chiaki Tanaka, Masayuki Ishii, Naohiro Watanabe, Kei Naitoh
  • Patent number: 8073376
    Abstract: Processes for producing emulsion aggregation toners are provided. In embodiments, methods of the present disclosure may be utilized to produce toners suitable for low melt applications, including use in flexible packaging applications, where low pile height is desired for low cost and flexibility. In embodiments, the EA toners may be prepared by optimizing the particle size of the emulsion, the choice of and amount of aggregating agent utilized, and the solids content of the emulsion.
    Type: Grant
    Filed: May 8, 2009
    Date of Patent: December 6, 2011
    Assignee: Xerox Corporation
    Inventors: Guerino G. Sacripante, Nathan C. Dyck, Daryl W. Vanbesien, Edward G. Zwartz, Cuong Vong
  • Publication number: 20110294063
    Abstract: To provide a toner for developing an electrostatic charge image, which satisfies both low temperature fixing property and blocking resistance and which is excellent in the fixed image strength and further excellent in the production stability and is capable of presenting a constant quality, and a process for its production. A toner for developing an electrostatic charge image, which comprises a binder resin containing a crystalline resin, and wax, and which has, in its DSC curve measured by a differential scanning calorimeter, an endothermic peak of from 0.01 to 10 mJ/mg at a temperature of at most 45° C. during its temperature rise.
    Type: Application
    Filed: May 27, 2011
    Publication date: December 1, 2011
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Tetsuharu YUGE, Yuqing Xu
  • Publication number: 20110294061
    Abstract: The present invention relates to a crystalline resin for toners which includes a composite resin including a polycondensation-based resin component obtained by polycondensing an alcohol component containing an aliphatic diol having 2 to 10 carbon atoms with a carboxylic acid component containing an aromatic dicarboxylic acid, and a styrene-based resin component; a resin binder containing the crystalline resin and a non-crystalline resin; and a toner for electrophotography which contains the resin binder. According to the present invention, there are provided a crystalline resin for toners which is capable of producing a toner that is excellent in not only low-temperature fixing ability but also gloss of images and anti-filming property, a resin binder, and a toner for electrophotography.
    Type: Application
    Filed: December 9, 2009
    Publication date: December 1, 2011
    Applicant: Kao Corporation
    Inventors: Eiji Shirai, Tetsuya Ueno
  • Patent number: 8067140
    Abstract: A toner for developing electrostatic image which has a reduced residual amount of a decomposed product of a polymerization initiator remaining in the toner upon production (mainly an ether component) and an unreacted polymerizable monomer (mainly styrene), less odor produced upon fixing so as to avoid deteriorating surrounding environment, an excellent shelf stability at high temperature upon storing or anti-blocking property, and an excellent printing durability under both N/N environment and H/H environment upon printing is provided. A toner for developing electrostatic image comprising a colored resin particle which is obtained by polymerizing a polymerizable monomer composition containing a polymerizable monomer, a colorant and a charge control resin in an aqueous dispersion medium in the presence of a polymerization initiator, wherein the charge control resin is a quaternary ammonium base containing copolymer having a glass transition temperature “Tg” in the range from 70 to 100° C.
    Type: Grant
    Filed: January 30, 2008
    Date of Patent: November 29, 2011
    Assignee: Zeon Corporation
    Inventor: Keita Sensui
  • Patent number: 8067144
    Abstract: The present invention relates to a polyester having an excellent hydrolysis resistance even when used in a process for producing a toner for electrophotography which includes a step of forming a raw material into particles in an aqueous medium, and a toner for electrophotography which contains the polyester and is excellent in storage stability and fixing property. There are provided a polyester for a toner for electrophotography which is used in a process for producing a toner including a step of forming a raw material component into particles in an aqueous medium or a solution, and produced by polycondensing an alcohol component with a carboxylic acid component containing at least one compound selected from the group consisting of an alkyl succinic acid and an alkenyl succinic acid, as well as a toner for electrophotography which contains the polyester.
    Type: Grant
    Filed: April 24, 2008
    Date of Patent: November 29, 2011
    Assignee: Kao Corporation
    Inventors: Hiroshi Mizuhata, Takashi Kubo, Takashi Mukai, Hidehito Ikebata, Katsutoshi Aoki
  • Publication number: 20110256477
    Abstract: A toner includes toner particles each containing a binder resin, a colorant, and a carboxy-containing styrene-based resin, in which the toner particles are produced in an aqueous medium, each of the toner particles has a styrene-acrylic-based resin component content of 50.0% by mass or more, cyclohexane-insoluble matter A obtained by subjecting the toner to Soxhlet extraction with cyclohexane for 4 hours is 70.0% by mass or more, and cyclohexane-insoluble matter B obtained by subjecting the toner to Soxhlet extraction with cyclohexane for 24 hours is 40.0% by mass or less, and wherein when the z-average molecular weight and the weight-average molecular weight of tetrahydrofuran-soluble matter of the carboxy-containing styrene-based resin determined by gel permeation chromatography measurement are represented by Mz and Mw, respectively, Mz and Mw satisfy the following expressions: 10,000?Mw?30,000, and 1.62?Mz/Mw?5.00.
    Type: Application
    Filed: April 12, 2011
    Publication date: October 20, 2011
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Hideki Kaneko, Shinya Yachi, Kenichi Nakayama, Takeshi Kaburagi, Shiro Kuroki
  • Patent number: 8034528
    Abstract: Provided according to some embodiments of the present invention are hybrid chemically-produced toners produced by a method including forming a resin component including a) at least one of a water reducible acrylic resin and a water dispersible polyester resin; and b) an epoxy; subjecting the resin component to conditions sufficient to form a hybrid resin component; and dispersing the hybrid resin component into water.
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: October 11, 2011
    Assignee: Reichhold, Inc.
    Inventors: Yongning Liu, Eric Dumain
  • Publication number: 20110236819
    Abstract: Provided is a toner containing toner particles containing a polyester resin which has a structure part represented by Formula (1): wherein, “A” represents a polyester structure unit having at least one linking group; R1 represents a hydrogen atom, or a chlorine atom; R2 represents a hydrogen atom, a chlorine atom, or a methoxy group; and “L” represents a divalent organic group.
    Type: Application
    Filed: March 17, 2011
    Publication date: September 29, 2011
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Mikio KOUYAMA, Ken OHMURA, Kenji HAYASHI, Hiroaki OBATA, Koji SHIBATA
  • Publication number: 20110217644
    Abstract: A method for preparing a toner including toner particles is provided. The toner preparation method includes preparing a toner component liquid including at least a binder resin, a colorant and an organic solvent; mixing a resin A having a solubility of less than 2.0 g/100 g in water having a pH of 3.0 at 25° C. while having a solubility of not less than 2.0 g/100 g, a basic material, and water to prepare an aqueous phase liquid, in which the resin A is dissolved; forming droplets of the toner component liquid in the aqueous phase liquid; and removing the organic solvent from the droplets of the toner component liquid to prepare the toner particles.
    Type: Application
    Filed: March 3, 2011
    Publication date: September 8, 2011
    Inventors: Atsushi Yamamoto, Tsuyoshi Nozaki, Chiyoshi Nozaki
  • Patent number: 8013074
    Abstract: The present disclosure relates to a toner process comprising providing a resin miniemulsion comprising polymeric particles comprising at least one free radical polymerizable monomer compound and at least one alkylene anhydride; blending the miniemulsion with at least one colorant, at least one amine, and optionally at least one wax; heating the resulting mixture below or about equal to the glass transition temperature (Tg) of the resin emulsion; and heating the resulting mixture above or about equal to the glass transition temperature (Tg) of the resin emulsion.
    Type: Grant
    Filed: April 29, 2008
    Date of Patent: September 6, 2011
    Assignee: Xerox Corporation
    Inventors: Barkev Keoshkerian, Raj Patel, Edward G. Zwartz, Cuong Vong
  • Patent number: 7998649
    Abstract: Pigment particles with at least one metal oxide surface additive, wherein the at least one metal oxide surface additive is a metal oxide particle covalently bonded with at least one polycondensation polymer, wherein the pigment particle is a pearlescent or metallic pigment.
    Type: Grant
    Filed: March 3, 2008
    Date of Patent: August 16, 2011
    Assignee: Xerox Corporation
    Inventors: Karen A. Moffat, Valerie M. Farrugia, Ke Zhou, Richard P. N. Veregin, Cuong Vong, Eric M. Strohm, Wafa F. Bashir
  • Patent number: 7989134
    Abstract: To provide a toner manufacturing method including: dissolving or dispersing a toner material into an organic solvent to prepare a toner solution, the toner material containing at least an active hydrogen group-containing compound, polymer reactive with the active hydrogen group-containing compound, binder resin, releasing agent and coloring agent; emulsifying or dispersing the toner solution into an aqueous medium to prepare an emulsified dispersion; reacting the active hydrogen group-containing compound with the polymer reactive with the active hydrogen group-containing compound in the aqueous medium produce an adhesive base material in the form of particle; and removing the organic solvent, wherein time X (hour) from a point where the organic solvent starts to be removed to a point where the concentration of the organic solvent reaches less than 12% by mass and temperature T (° C.) of the emulsified dispersion at the time X satisfy the relationship 5{exp(?0.2X)+1}?T?50X?0.2.
    Type: Grant
    Filed: January 24, 2008
    Date of Patent: August 2, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Toshihiko Usami, Masashi Miyakawa
  • Publication number: 20110183256
    Abstract: A method of manufacturing a toner is provided which is excellent in low temperature fixation property, whose fixable temperature width is large, as well as excellent in durability while giving consideration to the global environment conservation. The method of manufacturing a toner includes a step of producing a polyester resin by a reaction of dicarboxylic acid and diol, and a step of producing a toner base particle having the polyester resin and a colorant. The dicarboxylic acid is a biomass monomer having carboxyl groups introduced into ends of one, or two or more monocarboxylic acids selected from pimaric acid, isopimaric acid, and sandaracopimaric acid.
    Type: Application
    Filed: January 6, 2011
    Publication date: July 28, 2011
    Inventor: Nobuhiro MAEZAWA
  • Patent number: 7985526
    Abstract: The present disclosure provides methods for incorporating a dye into latex particles via a supercritical fluid microencapsulation technique, in order to achieve improved dispersion of a colorant in the latex and an increase in color gamut.
    Type: Grant
    Filed: August 25, 2009
    Date of Patent: July 26, 2011
    Assignee: Xerox Corporation
    Inventors: Maura A. Sweeney, Grazyna Kmiecik-Lawrynowicz, Robert D. Bayley
  • Publication number: 20110165511
    Abstract: A method for producing an electrostatic image developing toner by: a) adding a free radical polymerizable monomer to an aqueous medium comprising dispersed wax particles containing a colorant, b) polymerizing the free radical polymerizable monomer to yield a resin particle comprising the wax and colorant, and c) agglutinating and fusing the resin particle in the aqueous medium to yield a toner. The resultant toner exhibits uniform particle size, high roll viscosity resistance, and high durability.
    Type: Application
    Filed: July 8, 2010
    Publication date: July 7, 2011
    Inventors: Shunquan ZHU, Yunfeng LI
  • Publication number: 20110136052
    Abstract: A method of manufacturing toner including preparing a first liquid by dissolving or dispersing toner components including one or both of a binder resin and a precursor thereof in an organic solvent; preparing a second liquid by dispersing the first liquid in a first aqueous medium including a dispersant; producing primary particles by removing the organic solvent from the second liquid; washing the primary particles; preparing a third liquid by dispersing the washed primary particles in a second aqueous medium and heating the second aqueous medium while or after dispersing the washed primary particles therein; and producing toner particles by adding a charge controlling agent to the third liquid. This method satisfies the following inequation: 0.60?Sb/Sa?1.00 wherein Sa represents a BET specific surface area of the primary particles included in the third liquid and Sb represents that of the toner particles stored for 2 weeks at 40° C., 70% RH.
    Type: Application
    Filed: December 6, 2010
    Publication date: June 9, 2011
    Inventors: Junichi WATANABE, Kenichi Uehara, Junya Koeda, Daisuke Misawa, Keisuke Tada, Miyuki Hirata
  • Patent number: 7955772
    Abstract: The invention relates to a dry toner, containing a platelet-type metal effect pigment or a plurality of platelet-type metal effect pigments and at least one resinous constituent, wherein the metal effect pigment or the metal effect pigments is/are additionally provided with a coating preferably suitable for improving the mechanical stability, and that this coating is additionally modified with at least one organic layer, which organic layer is selected from the group consisting of organofunctional silanes, organofunctional titanates, organofunctional zirconates, phosphonic acids, and phosphonates. The invention further relates to processes for the production of the dry toner and to the use thereof. Furthermore, the invention relates to a toner cartridge and to printed products.
    Type: Grant
    Filed: November 22, 2005
    Date of Patent: June 7, 2011
    Assignee: Eckart GmbH
    Inventors: Thomas Schuster, Hans-Jörg Kremitzl
  • Publication number: 20110091806
    Abstract: Disclosed is a toner manufacturing method, comprising: dispersing a polyester resin prepared by condensing a polyol and a polycarboxylic acid into an aqueous medium and adjusting a polyester resin particle dispersion liquid, wherein the polyol includes an unsaturated polyol, or the polycarboxylic acid includes an unsaturated polycarboxylic acid; and adding a radical polymerization initiator to the polyester resin particle dispersion liquid to cause a radical polymerization reaction, and adjusting the obtained dispersion liquid of polyester resin particles.
    Type: Application
    Filed: October 6, 2010
    Publication date: April 21, 2011
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Kenji HAYASHI, Mikio KOUYAMA, Hiroaki OBATA, Noriyuki KINPARA, Yasuhiko MURAMATSU
  • Publication number: 20110086306
    Abstract: A toner having charge control agents which impart excellent triboelectric charging characteristics. In embodiments, the charge control agents include copolymers formed by an emulsion polymerization process.
    Type: Application
    Filed: October 8, 2009
    Publication date: April 14, 2011
    Applicant: XEROX CORPORATION
    Inventors: Robert D. Bayley, Yuhua Tong, Timothy L. Lincoln, Grazyna E. Kmiecik-Lawrynowicz, Maura A. Sweeney, Daniel W. Asarese, Susan J. LaFica, Mark E. Mang
  • Publication number: 20110081611
    Abstract: Disclosed is a toner manufacturing method, comprising: dispersing a polyester resin prepared by condensing a polyol and an unsaturated polycarboxylic acid into an aqueous medium and preparing a polyester resin particle dispersion liquid; adding a vinyl polymerizable monomer and a radical polymerization initiator to the polyester resin particle dispersion liquid to cause a radical polymerization reaction, followed by preparing a dispersion liquid of resin particles made of a resin in which vinyl polymerizable monomers react with the polyester resin; and mixing at least the resin particles made of the resin in which the vinyl polymerizable monomers react with the polyester resin, and a dispersion liquid of coloring agent particles, and forming toner particles by making the resin particles and the coloring agent particles cohere.
    Type: Application
    Filed: September 29, 2010
    Publication date: April 7, 2011
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Kenji HAYASHI, Mikio KOUYAMA, Hiroaki OBATA, Noriyuki KINPARA, Yasuhiko MURAMATSU
  • Patent number: 7910280
    Abstract: The present invention provides a method of producing a polymerized toner which removes a by-product microparticle generated as a by-product upon polymerization in a by-product microparticle removing step, efficiently obtains a wet colored resin particle which has low moisture content (wet cake) by decreasing clogs caused at filter element in a dewatering step, enhances a drying efficiency (shorten the drying time) in a drying step, has an excellent productivity and a printing ability.
    Type: Grant
    Filed: October 29, 2008
    Date of Patent: March 22, 2011
    Assignee: Zeon Corporation
    Inventor: Fuminari Oyama
  • Patent number: 7906266
    Abstract: A magnetic toner is disclosed including magnetic toner particles containing at least a binder resin and a magnetic powder. The magnetic powder contains a specific amount of phosphorus elements, and a specific amount of silicon elements, based on the iron element, with the ratio of the phosphorous element to the silicon elements being in a specific range, and has a specific volume-average particle diameter, a specific saturation magnetization in a specific magnetic field, and a specific residual magnetization. The magnetic toner can realize high image density and reduce fog and spots around line images regardless of environmental variation, and is superior in durability, and besides, can achieve small toner consumption.
    Type: Grant
    Filed: May 16, 2005
    Date of Patent: March 15, 2011
    Assignee: Canon Kabushiki Kaisha
    Inventors: Michihisa Magome, Eriko Yanase, Tatsuya Nakamura
  • Patent number: 7901860
    Abstract: The present invention provides dry toner particles comprising at least a radiation curable resin, and a colouring agent, wherein the circularity of the toner particles is between 0.95 and 0.99 and a charge control agent in a concentration between 0.025% and 1.0% by weight is present preferably as an external additive. The toners of this invention are useful for printing any substrate and for use in any form of printing or marking device.
    Type: Grant
    Filed: December 7, 2007
    Date of Patent: March 8, 2011
    Assignee: Xeikon IP BV
    Inventors: Lode Deprez, Werner Op De Beeck
  • Publication number: 20110008726
    Abstract: Provided is a process for producing a toner comprising steps of: dispersing a polymerizable monomer composition containing a polymerizable monomer, a polar resin, a colorant, and a wax component in a aqueous dispersion medium to granulate the polymerizable monomer composition; and polymerizing the polymerizable monomer, wherein the polymerizable monomer is a vinyl-based polymerizable monomer, the polar resin is a styrene-methacrylic acid copolymer or styrene-acrylic acid copolymer; the polymerizable monomer composition contains 0.0050 to 0.025 mass % of divinylbenzene; and the toner has a glass transition temperature (TgA) measured with a differential scanning calorimeter (DSC) of 40° C. or higher and 60° C. or lower and a peak temperature (P1) of a highest endothermic peak measured with the DSC of 70° C. or higher and 110° C. or lower, and P1 and TgA satisfy a relationship of 15° C.?(P1?TgA)?70° C.
    Type: Application
    Filed: September 22, 2010
    Publication date: January 13, 2011
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Yasushi Katsuta, Koji Inaba, Ken-ichi Nakayama, Kenta Kamimura
  • Publication number: 20110003242
    Abstract: Disclosed is a toner comprising at least a resin and a coloring agent, wherein the resin comprises toner particles in which a polyester resin unit is cross-linked by a diatomic cross-linking group expressed by a following general formula (1): —X1?Y1?X1— [wherein in the formula, X1 denotes a linking group; and Y1 denotes a radical polymer unit having a number average molecular weight Mn ranging from 5000 or more to 50000 or less, and a ratio Mw/Mn ranging from 1.0 or more to 1.2 or less, wherein Mw denotes a weight average molecular weight, and Mn denotes the number average molecular weight].
    Type: Application
    Filed: June 28, 2010
    Publication date: January 6, 2011
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Kenji HAYASHI, Mikio KOUYAMA, Hiroaki OBATA, Noriyuki KINPARA, Yasuhiko MURAMATSU
  • Publication number: 20100304287
    Abstract: The present disclosure provides processes for the production of block copolymer polyester resins suitable for use in manufacturing toners. In embodiments, the copolymers include both a crystalline block and an amorphous block, which can self-assemble to form nanoparticles suitable for use in forming toners.
    Type: Application
    Filed: May 26, 2009
    Publication date: December 2, 2010
    Applicant: Xerox Corporation
    Inventors: Jordan H. Wosnick, Karen Ann Moffat
  • Patent number: 7842449
    Abstract: A method of preparing a toner includes: preparing a toner composition including a macromonomer having a hydrophilic group, a hydrophobic group and at least one reactive functional group, at least one polymerizable monomer, and a colorant; emulsion-polymerizing the toner composition in a medium; and separating and drying the polymerized toner. A toner is prepared using the method. An image forming method using the toner, and an image forming apparatus using the toner are also provided. According to the method, the size, distribution and configuration of toner particles are easily controlled. In addition, the method does not involve the use of or minimizes the use of a surfactant, and decreases polluted water and waste water, which is very advantageous environmentally.
    Type: Grant
    Filed: July 10, 2006
    Date of Patent: November 30, 2010
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Chang-kook Hong, Kyung-yol Yon, Jun-young Lee, Min-young Cheong
  • Publication number: 20100279222
    Abstract: A melt phase process for making a polyester polymer melt phase product by adding an antimony containing catalyst to the melt phase, polycondensing the melt containing said catalyst in the melt phase until the It.V. of the melt reaches at least 0.75 dL/g. Polyester polymer melt phase pellets containing antimony residues and having an It.V. of at least 0.75 dL/g are obtained without solid state polymerization. The polyester polymer pellets containing antimony residues and having an It.V. of at least 0.70 dL/g obtained without increasing the molecular weight of the melt phase product by solid state polymerization are fed to an extruder, melted to produce a molten polyester polymer, and extruded through a die to form shaped articles. The melt phase products and articles made thereby have low b* color and/or high L* brightness, and the reaction time to make the melt phase products is short.
    Type: Application
    Filed: July 14, 2010
    Publication date: November 4, 2010
    Applicant: EASTMAN CHEMICAL COMPANY
    Inventors: Mary Therese Jernigan, Michael Paul Ekart, Richard Gill Bonner
  • Patent number: 7820350
    Abstract: A toner containing a colorant, and a binder resin, wherein the toner is prepared by dissolving or dispersing a colorant, a precursor of the binder resin having a site capable of reacting with an active hydrogen group-containing compound, the active hydrogen group-containing compound, in an organic solvent, to prepare a toner constituent mixture liquid, dispersing or emulsifying the toner constituent mixture liquid, in an aqueous medium while subjecting the precursor to a reaction with the active hydrogen group-containing compound, to prepare a toner dispersion, and removing the organic solvent from the toner dispersion; the binder resin contains a modified polyester having an isocyanate-derived binding site; the Sn content in the toner is 800 ppm or less; the content of a metal which is non Sn and derived from a polyesterified catalyst is 10 ppm to 200 ppm; and the content of a metal which is non Sn and derived from an isocyanated catalyst is 10 ppm to 200 ppm.
    Type: Grant
    Filed: March 16, 2007
    Date of Patent: October 26, 2010
    Assignee: Ricoh Company, Ltd.
    Inventors: Masahide Yamada, Shigeru Emoto, Naohiro Watanabe, Masahiro Ohki, Akinori Saitoh, Shinichi Wakamatsu