From Aldehyde Or Derivative Thereof As Reactant Patents (Class 528/230)
  • Patent number: 5958398
    Abstract: The present invention relates to biodegradable biocompatible polyacetals, methods for their preparation, and methods for treating mammals by administration of biodegradable biocompatible polyacetals. A method for forming the biodegradable biocompatible polyacetals combines a glycol-specific oxidizing agent with a polysaccharide to form an aldehyde intermediate which is combined with a reducing agent to form the biodegradable biocompatible polyacetal. The resultant biodegradable biocompatible polyacetals can be chemically modified to incorporate additional hydrophilic moieties. A method for treating mammals includes the administration of the biodegradable biocompatible polyacetal in which biologically active compounds or diagnostic labels can be disposed.
    Type: Grant
    Filed: December 7, 1998
    Date of Patent: September 28, 1999
    Assignee: The General Hospital Corporation
    Inventor: Mikhail I. Papisov
  • Patent number: 5939515
    Abstract: Condensation of products obtained by condensation of a mixture comprising(A) from 90 to 99.9 mol % of a mixture consisting essentially of(a) from 30 to 100 mol % of melamine and(b) from 0 to 70 mol % of a substituted melamine of the formula I ##STR1## where X, X' and X" are as defined in the specification, or mixtures of melamines I, and(c) from 1 to 70 mol %, based on (a)+(b), of a substituted triazine of the formula II ##STR2## where R", Z' and Z" are as defined in the specification, or mixtures of triazines II, and(B) from 0.1 to 10 mol %, based on (A) (a), (A) (b) and (B), of phenols which are unsubstituted or are substituted by radicals selected from the group consisting of C.sub.1 -C.sub.9 -alkyl and hydroxyl, C.sub.1 -C.sub.4 -alkanes substituted by two or three phenol groups, di(hydroxyphenyl)sulfones or mixtures of these phenols,withformaldehyde or formaldehyde-supplying compounds in a molar ratio of melamine, substituted melamine I and triazine II to formaldehyde within the range from 1:1.15 to 1:4.
    Type: Grant
    Filed: January 29, 1998
    Date of Patent: August 17, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Erhard Guenther, Wolfgang Reuther
  • Patent number: 5929191
    Abstract: One of the objects of the present invention is to offer novolak type phenolic resins which use phenols and aldehydes as raw materials and give narrow molecular weight distributions.The novolak type phenolic resins of the present invention are those obtained by condensation reaction of phenols with aldehydes in the presence of an oxycarboxylic acid having carboxyl groups, --COOH, and alcoholic hydroxyl groups, --OH, in one molecule. Thus, obtained novolak type phenolic resins show narrow molecular weight distributions, lower viscosity in molten state and, as a consequence, uniformity in curing time.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: July 27, 1999
    Assignee: Gun Ei Chemical Industry Co., Ltd.
    Inventors: Yoshiaki Kurimoto, Akiyuki Kojima, Yukio Abe, Tsuyoshi Fukuda, Kaori Hasegawa
  • Patent number: 5889134
    Abstract: An organozinc species, useful in the reactions of aldehydes and ketones, is a reaction product of a) a biphenyl compound having one or more hindered 2,2'-substituted biphenyl subunits and b) an organozinc compound, such as diethylzinc. The organozinc species catalyzes the reduction of a ketone by a borane, as well as the epoxidation of .alpha.,.beta.-unsaturated compounds by an oxidizing agent, such as O.sub.2 or an alkyl hydroperoxide. The biphenyl compound may be chiral and may catalyze the formation of optically active reaction products.
    Type: Grant
    Filed: August 26, 1997
    Date of Patent: March 30, 1999
    Assignee: North Dakota State University
    Inventors: Lin Pu, Wei-Sheng Huang, Qiao-Sheng Hu
  • Patent number: 5886110
    Abstract: Branched, dendrimeric macromolecules having a central nucleus and a series of polyoxaalkylene chains that radiate from the nucleus and spread into the surrounding space branching a cascade fashion until the desired size results. Molecules formed in this manner are free of excessive functional crowding on their outer surfaces. Synthetic methods of preparing these molecules and their uses are described.
    Type: Grant
    Filed: April 30, 1998
    Date of Patent: March 23, 1999
    Assignee: Dibra S.p.A.
    Inventors: Luigia Gozzini, Monica Muttoni, Christoph De Haen
  • Patent number: 5874179
    Abstract: The invention relates to nitrogen-containing polymers containing structural units of formula (I), ##STR1## where the symbols and indices have the following meanings: Ar.sup.1, Ar.sup.2, Ar.sup.3 are, identically or differently, mono- and/or polynuclear and/or condensed aryl and/or heteroaryl groups which may or may not be linked via one or more bridges carbon atoms, which may or may not be substituted;X is a single bond, --O--, --S--, --SO--, --SO.sub.2, NR.sup.3, --CR.sup.4 R.sup.5 --, --CO--, --CR.sup.6 .dbd.CR.sup.7, CR.sup.8 R.sup.9 --CR.sup.10 R.sup.11 or SiR.sup.12 R.sup.13 ;R.sup.1 -R.sup.13 are, identically or differently, H, a hydrocarbon radical having from 1 to 22 carbon atoms or Ar.sup.4, where Ar.sup.4, identical with or different from Ar.sup.1, has the same meanings as Ar.sup.1 ;n=1, 2 or 3.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: February 23, 1999
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Willi Kreuder, Hans-Heinrich Horhold, Henning Rost
  • Patent number: 5869184
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo?2.2.l!heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclo-hexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: February 14, 1997
    Date of Patent: February 9, 1999
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Satoshi Furusawa, Hiroshi Ono, Kazuo Sugazaki
  • Patent number: 5866670
    Abstract: A process for producing a polyacetal copolymer, which is extremely heat-stable and is extremely reduced in the quantity of unstable terminals even in a high polymerization yield in which trioxane as the principal monomer, comprises copolymerization of trioxane as the principal monomer with a cyclic ether or cyclic formal having at least one carbon-to-carbon bond as the comonomer by using a specific heteropoly-acid or acid salt thereof as a polymerization catalyst until the content of the remaining monomers is lowered to at most 10% by weight based on all the monomers fed, adding 0.01 to 10% by weight, based on the resulting crude polymer, of a solution containing a catalyst deactivator, or contacting a basic gas as the deactivator to deactivate the catalyst, and subjecting the crude polymer as such to heat melting treatment without washing thereof.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: February 2, 1999
    Assignee: Polyplastics Co., Ltd.
    Inventors: Akira Nakai, Kaoru Yamamoto, Eiji Masuda, Hiroyuki Kanai
  • Patent number: 5863879
    Abstract: The use of polymers which are preparable by reaction of(a) polymers that contain vinylamine units, with(b) compounds that contain aldehyde or keto groups, and optionally(c) NH- and/or OH-containing compoundsand which contain aminal, hemiaminal and/or aminal-acetal structures with or without unconverted vinylamine units, as detergent additive for inhibiting dye transfer during the wash, and polymers containing aminal, hemiaminal and/or aminal-acetal structures, obtainable by reaction of(a) polymers that contain vinylamine units, with(b) compounds that contain aldehyde or keto groups, and(c) NH- and/or OH-containing compounds,and detergents which contain the abovementioned polymers in amounts from 0.05 to 10% by weight.
    Type: Grant
    Filed: October 17, 1996
    Date of Patent: January 26, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Zirnstein, Wolfgang Trieselt, Knut Oppenlander, Claudia Nilz, Michael Kroner, Wolfgang Gunther
  • Patent number: 5859168
    Abstract: One of the objects of the present invention is to offer novolak type phenolic resins which use phenols and aldehydes as raw materials and give narrow molecular weight distributions.The novolak type phenolic resins of the present invention are those obtained by condensation reaction of phenols with aldehydes in the presence of an oxycarboxylic acid having carboxyl groups, --COOH, and alcoholic hydroxyl groups, --OH, in one molecule. Thus obtained novolak type phenolic resins show narrow molecular weight distributions, lower viscosity in molten state and, as a consequence, uniformity in curing time.
    Type: Grant
    Filed: November 22, 1996
    Date of Patent: January 12, 1999
    Assignee: Gun Ei Chemical Industry Co., Ltd.
    Inventors: Yoshiaki Kurimoto, Akiyuki Kojima, Yukio Abe, Tsuyoshi Fukuda, Kaori Hasegawa
  • Patent number: 5849808
    Abstract: A polymer which is insoluble in aqueous-alkaline developer solutions, and comprises structural units of the formula (I): ##STR1## in which R.sub.2 is hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.10 cycloalkyl, C.sub.5 -C.sub.14 aryl, C.sub.6 -C.sub.30 aralkyl, R.sub.3 is C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.10 cycloalkyl, C.sub.5 -C.sub.14 aryl, or C.sub.6 -C.sub.30 aralkyl, it being possible for the alkyl, cycloalkyl, aryl, or aralkyl groups to be substituted if desired by one or more hydroxyl groups or nitro groups or by one or more halogen atoms, and X is a k+1 valent organic radical, k being a number from 1 to 5, and 1 is a number from 0 to 4, in a quantity such that the cleavage products obtained by reaction with an acid are soluble in aqueous-alkaline developer solutions, is suitable as a binder for DUV photoresists of high processing stability, high contrast, and good resolution.
    Type: Grant
    Filed: April 19, 1996
    Date of Patent: December 15, 1998
    Assignee: Olin Microelectronic Chemicals, Inc.
    Inventors: Hans-Thomas Schacht, Norbert Muenzel
  • Patent number: 5849858
    Abstract: Furfuryl alcohol/formaldehyde resins exhibiting high water compatibility and low amounts of volatile organic compounds such as furfuryl alcohol.
    Type: Grant
    Filed: April 2, 1998
    Date of Patent: December 15, 1998
    Assignee: QO Chemicals, Inc.
    Inventors: George S. Everett, George R. MacLennan, Michael C. Chen
  • Patent number: 5844059
    Abstract: To prepare a thermally very stable polyacetal copolymer containing a very small amount of unstable parts in a high yield according to a simple process wherein an isopolyacid or an acid salt thereof is used as the polymerization catalyst in the copolymerization of trioxane as the principal monomer with a comonomer copolymerizable therewith, and wherein deactivation of the catalyst can be effected simply without fail through contact with a basic gas after polymerization without the necessity for any washing step. In the preparation of a polyacetal copolymer by the copolymerization of trioxane as the principal monomer with a cyclic ether or cyclic formal having at least one carbon--carbon bond as a comonomer, the copolymerization is effected using an isopolyacid or an acid salt thereof as the polymerization catalyst, followed by contact with a basic gas as a deactivator to deactivate the catalyst, and subsequent heat-melting treatment of the resulting crude polymer intact without washing thereof.
    Type: Grant
    Filed: January 27, 1997
    Date of Patent: December 1, 1998
    Assignee: Polyplastics Co., Ltd.
    Inventors: Kaoru Yamamoto, Hiroyuki Kanai
  • Patent number: 5811511
    Abstract: Disclosed is a method for stabilizing unstable terminals of a crude oxymethylene copolymer, wherein use is made of an extruder comprising a casing having a supply inlet and an extrusion outlet which casing has at least two rotation shafts extending longitudinally through the extruder in which a melting zone, a terminal stabilization reaction zone and a volatile matter exhaustion zone are consecutively arranged from the supply inlet toward the extrusion outlet, wherein the terminal stabilization zone has a plurality of kneading elements having a thickness of from 0.1D to 0.
    Type: Grant
    Filed: August 7, 1996
    Date of Patent: September 22, 1998
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Yukio Tanigawa, Hirohisa Morishita
  • Patent number: 5811510
    Abstract: The present invention relates to biodegradable biocompatible polyacetals, methods for their preparation, and methods for treating mammals by administration of biodegradable biocompatible polyacetals. A method for forming the biodegradable biocompatible polyacetals combines a glycol-specific oxidizing agent with a polysaccharide to form an aldehyde intermediate which is combined with a reducing agent to form the biodegradable biocompatible polyacetal. The resultant biodegradable biocompatible polyacetals can be chemically modified to incorporate additional hydrophilic moieties. A method for treating mammals includes the administration of the biodegradable biocompatible polyacetal in which biologically active compounds or diagnostic labels can be disposed.
    Type: Grant
    Filed: April 14, 1995
    Date of Patent: September 22, 1998
    Assignee: General Hospital Corporation
    Inventor: Mikhail I. Papisov
  • Patent number: 5795934
    Abstract: A water-soluble urea-extended phenol-formaldehyde resole resin stabilized with an alkanolamine alone or combined with a monosaccharide or disaccharide, methods of manufacturing the resin and using it, and products prepared using the resin.
    Type: Grant
    Filed: May 20, 1997
    Date of Patent: August 18, 1998
    Assignee: Georgia-Pacific Resins, Jr.
    Inventor: Claude Phillip Parks
  • Patent number: 5763560
    Abstract: A method of producing styrene derivatives expressed the general formula (2) by reacting a benzaldehyde derivative expressed by the general formula (1) with dibromomethane under the existence of zinc metal as well as an active chloride for producing various types of oxystyrene which are polymerized monomers as a photoresist material used in a high density integrated circuit process from easily available materials which also can easily be handled: ##STR1## (wherein R indicates a an alkyl group, alkoxyalkyl group, an alkylcarbonyl group, an alkoxycarbonyl group, a 5 or 6-atom heterocylclic groups, or an alkylsilyl group); ##STR2## (wherein R indicates any of the same substituents as those described above.
    Type: Grant
    Filed: May 3, 1996
    Date of Patent: June 9, 1998
    Assignees: Honshu Chemical Industry Co., Ltd., Osaka Municipal Government
    Inventors: Kenzo Tsujimoto, Yoshiharu Ayabe, Fujihisa Matsunaga, Ikuzo Nishiguchi, Yoshio Ishino
  • Patent number: 5756594
    Abstract: Polymers which contain polyacetal blocks are obtainable by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the polymers with at least bifunctional crosslinking agents in the presence of acids or Lewis acids and, if required hydrolyzing the ester groups present as polymerized units, process for the preparation of the polymers containing polyacetal blocks by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the resulting polyacetals containing terminal hydroxyl groups with at least bifunctional crosslinking agents in the presence of acids or Lewis acids, and the use of the resulting polymers as additives in phosphate-free and reduced phosphate detergents and cleaning agents, as scale inhibitors and as dispersants for pigments.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: May 26, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Angelika Funhoff, Dieter Boeckh, Matthias Kroner, Richard Baur, Alexander Kud, Gunnar Schornick, Volker Schwendemann
  • Patent number: 5750632
    Abstract: A water insoluble, aqueous alkali soluble novolak resin, process for producing such a novolak resin, a photoresist containing such a novolak resin, and a method for producing a semiconductor device, wherein the resin is isolated by sub surface forced steam distillation.
    Type: Grant
    Filed: December 30, 1994
    Date of Patent: May 12, 1998
    Assignee: Clariant Finance (BVI) Limited
    Inventors: M. Dalil Rahman, Daniel Aubin
  • Patent number: 5744504
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo?2.2.1!heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: February 14, 1997
    Date of Patent: April 28, 1998
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Satoshi Furusawa, Hiroshi Ono
  • Patent number: 5728798
    Abstract: In preparing a polyacetal copolymer through copolymerization of trioxane as the principal monomer with a cyclic ether or cyclic formal having at least one carbon-carbon bond as the comonomer, 0.05 to 100 ppm (on the weight basis), based on the total amount of the monomers, of a heteropoly-acid or an acidic salt thereof is used as a polymerization catalyst, and a liquid mixture preliminarily prepared by mixing at least part or the whole of the comonomer with the polymerization catalyst is added to trioxane to effect copolymerization. According to such the process, the polymerization yield and the degree of polymerization (molecular weight) are enhanced, and a polyacetal copolymer having an improved stability can be obtained.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: March 17, 1998
    Assignee: Polyplastics Co., Ltd.
    Inventors: Akira Nakai, Kaoru Yamamoto
  • Patent number: 5728797
    Abstract: A suspension of finally divided hardened aminoplast or phenoplast resin, particularly melamine-formaldehyde resin, is prepared by mixing an aqueous solution of the resin or its precursors with a water-insoluble stabilizing agent, particularly microcrystalline cellulose; sufficient water is provided to exceed the water tolerance level of the resin and thus form a uniform emulsion or suspension of resin particles in water. Cure of the resin is then advanced such as by heating to form partially or fully cured resin particles of relatively uniform particle size.
    Type: Grant
    Filed: August 18, 1995
    Date of Patent: March 17, 1998
    Assignee: International Paper
    Inventors: Robin D. O'Dell, Jayesh Shah, Alice M. Simon
  • Patent number: 5693743
    Abstract: The invention relates to aminoplastics, which are created by reacting comnds that contain amide groups with glutaric dialdehyde, and to a process for their preparation and to their use. The aminoplastic according to the invention is free of formaldehyde and can be hardened without difficulty by acidic catalysis or thermal processes. The aminoplastic is prepared by polycondensation of compounds that contain amide groups with glutaric dialdehyde in aqueous solution.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: December 2, 1997
    Assignee: Fraunhofer Gesellschaft zur Forderung der Angewandten Forschung e.V.
    Inventors: Rudolf Nastke, Gerald Rafler
  • Patent number: 5693725
    Abstract: Novel polymers of general formula: ##STR1## wherein where n is a whole number from 2 to 10; R is a spacing group comprising (a) at least one of m methylene units where m is a whole number from 1 to 20, m' methine units where m' is a whole number from 0 to 20, a mixture of m methylene units and m' methine units where m+m'.ltoreq.20, and units of formula --(CH.sub.2 -CHX-O).sub.m" --, where m" is a whole number from 0 to 200 and X is H, CH.sub.3 or C.sub.2 H.sub.5, or (b) an aromatic ring having one, two or three members; R' is H, an alkyl group having no more than 20 carbon atoms, an aryl group having no more than three rings, or a combination thereof; R" is a group containing at least two active hydrogen atoms and having at least two but no more than 20 carbon atoms; and R'" is a group containing at least two active hydrogen atoms and is selected from the group consisting of alkyl, aryl and mixed alkyl-aryl species having from 1 to 200 carbon atoms; polyalkylene oxides; and urea formaldehyde resin.
    Type: Grant
    Filed: August 29, 1995
    Date of Patent: December 2, 1997
    Assignees: Lifesource International, Ltd., Jojani, Inc.
    Inventor: Nicholas M. Irving
  • Patent number: 5668224
    Abstract: Poly(alkylene dicarboxylate) polymers and copolymers having tetraalkyl- or trialkylammonium ion end groups and methods of synthesis, thereof. The methylene-containing copolymers, in general, adhere to glass and metals, including aluminum, iron, and copper. Poly(methylene-co-ethylene terephthalate) is a clear film useful in the protection of metals or glass from corrosion or scratching. Glass may be bound to glass or to metal using the polymers of the present invention or metal to metal seals may be made.
    Type: Grant
    Filed: November 22, 1994
    Date of Patent: September 16, 1997
    Assignee: Baylor University
    Inventors: A. G. Pinkus, Rajan Hariharan
  • Patent number: 5665851
    Abstract: Aminoplastic resin based on one or more amino derivatives and one or more aldehydes in which the amino derivative is melamine, glycoluril or their mixture in variable proportions and that the aldehyde is a product of formula (I) R--CHO where R=a dialkoxymethyl, 1,3-dioxolan 2-yl group optionally substituted on the vertex 4 and/or 5 by one or more alkyl groups or a 1,3-dioxan 2-yl group optionally substituted on vertices 4, 5 and/or 6 by one or more alkyl groups, optionally mixed with glyoxal, preparation process and use as a crosslinking agent for cellulose.
    Type: Grant
    Filed: August 21, 1995
    Date of Patent: September 9, 1997
    Assignee: Sequa Chemicals, Inc.
    Inventors: Didier Wilhelm, Alain Blanc, William C. Floyd
  • Patent number: 5659002
    Abstract: The invention is a process for preparing alkylated tannin Mannich polymers by reacting a tannin Mannich condensation polymer, prepared from a condensed tannin, and amine, and formaldehyde, with an alkylating agent at a pH between 5 and 14. Optionally, the alkylated tannin Mannich polymer may be reacted further with formaldehyde to increase its viscosity.The invention further comprises a method of removing color form waste water utilizing the alkylated tannin Mannich polymer produced by the above process.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: August 19, 1997
    Assignee: Nalco Chemical Company
    Inventors: Peter E. Reed, Martha R. Finck
  • Patent number: 5651817
    Abstract: When a cement dispersant comprising a polymer which is obtained by co-condensating monomers comprising monomer (A) and monomer (B) with formaldehyde, or a salt obtained by neutralizing the polymer, wherein the monomer (A) is an aromatic compound having, on the average, 1 to 300 mol per molecule of at least one member selected from the group consisting of oxyethylene group and oxypropylene group, and the monomer (B) is an aromatic compound having a carboxyl group; or another cement dispersant comprising a polymer which is obtained by co-condensating monomers comprising the above-described monomer (A), the above-described monomer (B) and monomer (C) which is an aromatic compound having a sulfonic acid group with formaldehyde, or a salt obtained by neutralizing the polymer is used as one component of a hydraulic composition, the fluidity of the hydraulic composition is maintained for a long time. Therefore, no trouble on transportation is caused during the force feeding of the hydraulic composition with a pump.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: July 29, 1997
    Assignee: Kao Corporation
    Inventors: Fuzio Yamato, Haruyuki Satoh
  • Patent number: 5650478
    Abstract: A liquid binding agent comprised of a phenolic resin, thinning agents and a curing agent, characterized in that the phenolic resin is produced by condensation catalyzed under alkaline conditions of a phenol and formaldehyde in a molar ratio of phenolic compound to formaldehyde in the range of 1:0.05 to 1.
    Type: Grant
    Filed: June 26, 1995
    Date of Patent: July 22, 1997
    Assignee: Bakelite AG
    Inventors: Achim Hansen, Michael Konig, Stephan Schroter, Josef Suren
  • Patent number: 5648446
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: July 15, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono
  • Patent number: 5646218
    Abstract: The present invention relates to a water insoluble, aqueous alkali soluble novolak resin blend, wherein the resin blend comprises two novolaks having dissimilar relative molecular weights and similar dissolution rates, a process for producing such a resin blend, a photoresist containing such a resin blend and a method for producing a semi-conductor device utilizing such a photoresist.
    Type: Grant
    Filed: August 5, 1996
    Date of Patent: July 8, 1997
    Assignee: Hoechst-Celanese Corp.
    Inventors: Thomas J. Lynch, Chester J. Sobodacha, Dana L. Durham
  • Patent number: 5646240
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: July 8, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono
  • Patent number: 5639396
    Abstract: A process for producing an oil soluble interpolymer polymer of 1,2-alkylenediamine such as N-ethyl ethylenediamine, aldehyde-provider such as formaldehyde, and ortho-unsubstituted hydroxyaromatics such as 4-polyalkylene phenol is disclosed. The decyclized Mannich Base monomer units provide a higher viscosity material which is suitably substituted with a long chain hydrocarbyl para substituent such as polyisobutylene or ethylene/alpha-olefin polymer. Various ortho-substituted hydroxyaromatics such as o-cresol may be used to control the degree of polymerization. The polymers are useful as dispersants or other lubricant additives.
    Type: Grant
    Filed: June 26, 1996
    Date of Patent: June 17, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Warren A. Thaler, Stephen Zushma, Antonio Gutierrez
  • Patent number: 5637652
    Abstract: An electroconductive polymer comprising a repeating unit having a chemical structure represented by formula (I): ##STR1## or, formula (II): ##STR2## as defined herein, and a process for producing the same.
    Type: Grant
    Filed: June 6, 1994
    Date of Patent: June 10, 1997
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Junya Kato, Yoshihiro Saida, Yoshiaki Ikenoue, Reiko Ichikawa
  • Patent number: 5637671
    Abstract: 1) Disclosed herein are new fluorine-containing compounds having polyacetalic structure, of general formula:[Rf.sub.m --CH.sub.2 O(CH.sub.2 O).sub.c --CH.sub.2 --.brket close-st..sub.n (I)where:Rf=a perfluorooxyalkylene chain having Mn from 500 to 5,000;m=4-25;c=1-10;n=2-100.2) A process for preparing them which comprises carrying out the polycondensation of diols having formula:HORfOH (II)with formaldehyde, in mass or in the presence of solvents, in an acid medium. The compounds of formula (I) can be oligomeric compounds (polymerization degree x.sub.n from 2 to about 20) or polymeric compounds (x.sub.n from about 20 to about 100). They exhibit a high stability to heat and to chemical agents, and Tg values slightly different from the ones of the diols utilized for preparing them.
    Type: Grant
    Filed: October 12, 1995
    Date of Patent: June 10, 1997
    Assignee: Ausimont S.p.A.
    Inventors: Ferdinando Danusso, Ezio Strepparola, Marinella Levi, Claudio Tonelli, Stefano Turri
  • Patent number: 5635583
    Abstract: Disclosed is a binder composition for binding substrates such as wood furnish for particleboard manufacture. The binder comprises a mixture of a first aqueous solution, comprising a buffering salt catalyst and preferably an acid, with a second aqueous solution comprising urea and formaldehyde. Methods of using the buffering salts as catalyst for curing urea-formaldehyde resins are also disclosed.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: June 3, 1997
    Assignee: Borden Chemical, Inc.
    Inventors: William K. Motter, Nick K. Daisy, William D. Detlefsen
  • Patent number: 5629373
    Abstract: A coating composition containing a linear aminoplast-ether copolymer of the formula: ##STR1## where the divalent R.sub.01 contains a divalent alkyleneoxy containing moiety, Amp is the skeletal residue of an aminoplast, R is hydrogen, alkyl containing 1 to about 4 carbon atoms, and acyl containing 1 to about 4 carbon atoms, p is a positive number that is equal to the free valence of Amp minus 2, RO is bonded to alkylene units of Amp, and a is a number greater than 1.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 13, 1997
    Assignee: United Catalysts, Inc.
    Inventors: Charles W. Glancy, Alan L. Steinmetz
  • Patent number: 5627232
    Abstract: A water-containing composition containing a linear aminoplast-ether copolymer of the formula: ##STR1## where the divalent R.sub.01 contains a divalent alkyleneoxy containing moiety, Amp is the skeletal residue of an aminoplast, R is hydrogen, alkyl containing 1 to about 4 carbon atoms, and acyl containing 1 to about 4 carbon atoms, p is a positive number that is equal to the free valence of Amp minus 2, RO is bonded to alkylene units of Amp, and a is a number greater than 1.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 6, 1997
    Assignee: United Catalysts, Inc.
    Inventors: Charles W. Glancy, Alan L. Steinmetz
  • Patent number: 5612443
    Abstract: Low molecular weight polyaldehydes are prepared by converting the acetal groups of the low molecular weight polyacetal to aldehyde groups or by reacting an aldehyde-containing reagent (e.g., glyoxal) with a polyamide.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: March 18, 1997
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Gary T. Martino, Martin M. Tessler
  • Patent number: 5608029
    Abstract: A process for producing an oil soluble interpolymer polymer of 1,2-alkylenediamine such as N-ethyl ethylenediamine, aldehyde-provider such as formaldehyde, and ortho-unsubstituted hydroxyaromatics such as 4-polyalkylene phenol is disclosed. The decyclized Mannich Base monomer units provide a higher viscosity material which is suitably substituted with a long chain hydrocarbyl para substituent such as polyisobutylene or ethylene/alpha-olefin polymer. Various ortho-substituted hydroxyaromatics such as o-cresol may be used to control the degree of polymerization. The polymers are useful as dispersants or other lubricant additives.
    Type: Grant
    Filed: March 10, 1995
    Date of Patent: March 4, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Warren A. Thaler, Stephen Zushma, Antonio Gutierrez
  • Patent number: 5606011
    Abstract: Condensation compounds obtained by means of the polymerization of polyami compositions essentially constituted by derivatives of 2,4,6-triamino-1,3,5-triazine, having the general formula (I): ##STR1## with aldehydes, preferably formaldehyde.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: February 25, 1997
    Assignee: Ministero Dell'Universita' e Della Ricerca Scientifica e Tecnologica
    Inventors: Roberto Cipolli, Roberto Oriani, Enrico Masarati, Gilberto Nucida
  • Patent number: 5597557
    Abstract: A process for making solid colored particles by preparing a reaction solution in water comprising formaldehyde, urea, a cyclic polyamine functional triazine compound, and acid. A dye can be incorporated into the reaction solution if a color other than white is desired. Particles are formed having an average particle size between 1 and 70 microns without the need to resort to crushing to break up agglomerates. Particles made by this process provide excellent color and are easily washable from a substrate when incorporated into a washable formulation.Additionally, it has been found that the incorporation of colored microcapsules of average size of 1-70 microns where the color is located primarily on or in the shell of the microcapsule also provides excellent washable compositions when incorporated into a washable formulation.
    Type: Grant
    Filed: May 1, 1995
    Date of Patent: January 28, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kanta Kumar, Robert A. Davis, Sheila M. Nichols, Howard J. Buttery
  • Patent number: 5596039
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: February 24, 1994
    Date of Patent: January 21, 1997
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi
  • Patent number: 5587478
    Abstract: The present invention provides novel sapphyrin dimers, trimers, oligomers and polymers, which multimers may include repeating units of sapphyrin or sapphyrin derivatives alone, or may further incorporate other units such as nucleobases.
    Type: Grant
    Filed: March 15, 1995
    Date of Patent: December 24, 1996
    Assignee: Board of Regents, The University of Texas System
    Inventors: Jonathan L. Sessler, Vladimir Kr al, Andrei Andrievsky
  • Patent number: 5576391
    Abstract: Ammonium polyphosphate having the general formula (I):(NH.sub.4).sub.n+2 P.sub.n O.sub.3n+1 (I)microencapsulated with condensation compounds obtained by means of the polymerization of polyaminic compositions essentially constituted by derivatives of 2,4,6-triamino-1,3,5-triazine, having the general formula (II): ##STR1## with aldehydes, preferably formaldehyde.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: November 19, 1996
    Assignee: Ministero Dell'Universita' E Della Ricerca Scientifica E Tecnologica
    Inventors: Roberto Cipolli, Roberto Oriani, Enrico Masarati, Gilberto Nucida
  • Patent number: 5554718
    Abstract: Cationic urea/formaldehyde resins are obtainable by condensing urea and formaldehyde in a molar ratio of from 1:1.5 to 1:3 in the presence of polymers which contain not less than 1 mol % of polymerized vinylamine units and have Fikentscher K values of from 5 to 300, in an amount of from 5 to 50 g per mole of urea in the end product, where the mixture is first a) precondensed at a pH of from 8 to 14, then acidified and b) condensed at a pH of from 1 to 5 until gel formation begins, c) then from 0.3 to 1.5 moles of formaldehyde are added per mole of urea used, d) post-condensation is carried out and e) the resin solution is subsequently neutralized. The resins thus obtained are used in papermaking as assistants for increasing the dry and wet strength of paper and result in less dulling of the whiteness of the paper.
    Type: Grant
    Filed: November 6, 1991
    Date of Patent: September 10, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Flory, Andreas Stange, Michael Kroener, Norbert Sendhoff
  • Patent number: 5552184
    Abstract: A coating agent with a viscosity of 100-1000 mPa.s, measured by rotational viscometry at 70.degree. C. and a shear rate of 235 s.sup.-1, containing45-85 wt % of one or more polyesters, that have a branched structure and are essentially free from aromatic structural units, with a number-average molecular weight (M.sub.n) of 350-3000 and a polydispersity of less than 3.5,10-40 wt % of one or more cross-linkers based on aminoplastic resins and/or blocked di- and/or polyisocyanates,0-20 wt % of one or more reactive diluents, and 0-10 wt % of one or more organic solvents.They are particularly suitable as hot-sprayable clear coats for multicoat lacquer finishes.
    Type: Grant
    Filed: December 16, 1994
    Date of Patent: September 3, 1996
    Assignee: Herberts GmbH
    Inventors: Peter Klostermann, Hans-Martin Schonrock, Klaus Schroter, Thomas Kutzner
  • Patent number: 5545702
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: October 3, 1995
    Date of Patent: August 13, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi, Kazunori Kamada, Shigeru Nakahata, Katsumi Sakamoto, Tatsunobu Nakashima, Akito Watanabe, Jin Suzuki, Kouhei Ohkawa, Satoshi Furusawa, Hiroshi Ono, Kazuo Sugazaki
  • Patent number: 5545825
    Abstract: The present invention relates to furan resins having low levels of VOCs. The claimed furan resins are the reaction product of a source of ammonia and a first reaction product, said first reaction product being derived from the reaction between a source of reactable formaldehyde, a formaldehyde scavenger, and an acidic furan resin resulting from the polymerization reaction wherein at least one reagent is selected from the group consisting of the furan containing molecule having the general formula ##STR1## and its saturated analogs thereof having zero to one carbon-carbon double bonnets, wherein X and Y are independently comprised of organic molecular groups.
    Type: Grant
    Filed: January 6, 1995
    Date of Patent: August 13, 1996
    Assignee: Schuller International, Inc.
    Inventors: Thomas J. Taylor, William H. Kielmeyer, Carl A. Rude
  • Patent number: 5536795
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: July 16, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi