From Aldehyde Or Derivative Thereof As Reactant Patents (Class 528/230)
  • Patent number: 5532332
    Abstract: Provided are light-absorbing polymers useful for imparting color and/or ultraviolet light screening properties to thermoplastic resins. The polymeric colorants or UV absorbers may be added during the formation of the uncolored thermoplastic polymer or melt or solution blended with other thermoplastic polymers.
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: July 2, 1996
    Inventors: Max A. Weaver, James J. Krutak, Clarence A. Coates, Wayne P. Pruett, Samuel D. Hilbert
  • Patent number: 5530031
    Abstract: Water-insoluble condensation products, obtained by the condensation of a mixture containing as essential components(A) from 80 to 99.9 mol %, based on the sum of (A), (B) and (C), of a mixture consisting essentially of(a) from 30 to 99 mol % of melamine and(b) from 1 to 70 mol % of a substituted melamine of the formula I ##STR1## where X, X' and X" are each selected from the group consisting of --NH.sub.2, --NHR and --NRR', and X, X' and X" are not all --NH.sub.2 at one and the same time, and R and R' are each selected from the group consisting of hydroxy-C.sub.2 -C.sub.10 -alkyl, hydroxy-C.sub.2 -C.sub.4 -alkyl-(oxa-C.sub.2 -C.sub.4 -alkyl).sub.n, where n is from 1 to 5, and amino-C.sub.2 -C.sub.12 -alkyl, or mixtures of melamines I,(B) from 0.
    Type: Grant
    Filed: September 9, 1994
    Date of Patent: June 25, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Erhard Guenther, Wolfgang Reuther, Uwe Kirchgassner
  • Patent number: 5512652
    Abstract: Fluorinated aldehydes are made by reacting a fluorinated acyl chloride with a silicon hydride in the presence of palladium. Also disclosed are fluorinated ether aldehydes and their polymers, a process for making fluorinated aldehydes polymers using titanium or aluminum alkoxide catalysts, and a process for endcapping fluorinated polymers using perfluoroallyl fluorosulfate or fluorine.
    Type: Grant
    Filed: February 14, 1995
    Date of Patent: April 30, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: William B. Farnham
  • Patent number: 5512608
    Abstract: A multi-part composition is provided which is suitable for use as an adhesive, a potting compound, a coating or a sealant. It consists of a polymerizable acrylate formulation and an activating formulation, the latter usually comprising an amine-aldehyde condensation product diluted with a liquid vinyl ether; liquid epoxides may also be included as diluents in the activating formulation.
    Type: Grant
    Filed: January 27, 1995
    Date of Patent: April 30, 1996
    Assignee: Dymax Corporation
    Inventors: Andrew G. Bachmann, Stephen E. Cantor
  • Patent number: 5506332
    Abstract: A process for preparing polyacetals by copolymerization of glyoxylic esters with other copolymerizable monomers in the presence of anionic or cationic polymerization initiators, with or without the introduction of stable end groups and with or without hydrolysis of the copolymerized units of glyoxylic ester present in the copolymer comprises using as monomers cyclic formals derived from diols, homopolymers of formaldehyde, trioxepane or mixtures thereof, although up to 50% by weight of this group of monomers may be replaced by other customary copolymerizable monomers, and the poly(acetal-carboxylate)s thus obtainable are useful as additives in reduced-phosphate and phosphate-free detergents and cleaners, as water treatment agents and as dispersants for finely divided substances.
    Type: Grant
    Filed: February 2, 1995
    Date of Patent: April 9, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Angelika Funhoff, Graham E. McKee, Heinrich Hartmann, Richard Baur, Alexander Kud, Volker Schwendemann
  • Patent number: 5500477
    Abstract: A moulding composition based on linear polyoxymethylene copolymers and customary additives with a melt index MFI (2,16 kg, 190.degree. C.) of .ltoreq.0,8, preferably .ltoreq.0,5 and especially .ltoreq.0,2 g/10 min has an extraordinary high toughness, which eliminates an addition of elastomer modifiers. In its preparation Lewis acids or protonic acids are used as initiators.
    Type: Grant
    Filed: April 26, 1995
    Date of Patent: March 19, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gerhard Reuschel, Dietrich Fleischer, Kaoru Yamamoto, Shuichi Chino
  • Patent number: 5492998
    Abstract: Novel polymers of general formula: ##STR1## wherein R is an alkyl or aryl group that contains an active hydrogen atom (as determined by the Zerewitinoff test); A is a spacing group having at least one carbon atom; B is a spacing group having at least two carbon atoms; and R and R' are alkyl or aryl groups. The polymer is synthesized via the Mannich pathway, involving formation of an imine intermediate.
    Type: Grant
    Filed: January 20, 1995
    Date of Patent: February 20, 1996
    Assignees: Lifesource International, Ltd., Jojani Inc.
    Inventor: Nicholas M. Irving
  • Patent number: 5478656
    Abstract: Cationic urea/formaldehyde resins are obtainable by condensing urea and formaldehyde in a molar ratio of from 1:1.5 to 1:3 in the presence of polymers which contain not less than 1 mol % of polymerized vinylamine units and have Fikentscher K values of from 5 to 300, in an amount of from 5 to 50 g per mole of urea in the end product, where the mixture is first a) precondensed at a pH of from 8 to 14, then acidified and b) condensed at a pH of from 1 to 5 until gel formation begins, c) then from 0.3 to 1.5 moles of formaldehyde are added per mole of urea used, d) post-condensation is carried out and e) the resin solution is subsequently neutralized. The resins thus obtained are used in papermaking as assistants for increasing the dry and wet strength of paper and result in less dulling of the whiteness of the paper.
    Type: Grant
    Filed: March 22, 1995
    Date of Patent: December 26, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Flory, Andreas Stange, Michael Kroener, Norbert Sendhoff
  • Patent number: 5478374
    Abstract: The nitrogen in amides of aldonic and aldaric acids having 5 or 6 carbon atoms in the carbohydrate residue is available to support plant growth, i.e. the materials act as nitrogen fertilizers.
    Type: Grant
    Filed: June 3, 1994
    Date of Patent: December 26, 1995
    Inventor: Donald E. Kiely
  • Patent number: 5476918
    Abstract: 1) New fluorine-containing compounds having polyacetalic structure, of general formula:(I)[Rf.sub.m --CH.sub.2 O(CH.sub.2 O).sub.c --CH.sub.2 ].sub.nwhere:Rf=a perfluorooxyalkylene chain having Mn from 500 to 5,000;m=4-25;c=1-10;n=2-100.2) A process for preparing them, which comprises carrying out the polycondensation of diols having formula:(II) HORfOHwith formaldehyde, in mass or in the presence of solvents, in an acid medium. The compounds of formula (I) can be oligomeric compounds (polymerization degree x.sub.n from 2 to about 20) or polymeric compounds (x.sub.n from about 20 to about 100). They exhibit a high stability to heat and to chemical agents, and Tg values slightly different from the ones of the diols utilized for preparing them.
    Type: Grant
    Filed: May 5, 1993
    Date of Patent: December 19, 1995
    Assignee: Ausimont, S.p.A.
    Inventors: Ferdinando Danusso, Ezio Strepparola, Marinella Levi, Claudio Tonelli, Stefano Turri
  • Patent number: 5466771
    Abstract: The present invention is directed to coating compositions which have long pot lives, may be rapidly cured under ambient conditions to provide coatings with improved optical properties and contain as bindera) a polyisocyanate component containingi) 5 to 100 % by weight of a monoallophanate andii) 0 to 95% by weight of another polyisocyanate adduct, andb) an aldimine based on the reaction product of a polyamine having 2 or more primary amino groups with an aldehyde corresponding to the formula:O.dbd.CHCH(R.sub.1)(R.sub.2)wherein R.sub.1 and R.sub.2 may be the same or different and represent optionally substituted hydrocarbon radicals, or R.sub.1 and R.sub.2 together with the .beta.-carbon atom form a cycloaliphatic or heterocyclic ring,wherein components a) and b) are present in an amount sufficient to provide an equivalent ratio of isocyanate groups to aldimine groups of 0.5:1 to 20:1.
    Type: Grant
    Filed: December 21, 1993
    Date of Patent: November 14, 1995
    Assignee: Bayer Corporation
    Inventors: Sharon D. Hicks, Douglas A. Wicks, John H. Hunter
  • Patent number: 5457155
    Abstract: A process for preparing a controlled functional density poly(secondary amine) comprising: (a) contacting a polymer containing olefinic unsaturation with carbon monoxide in hydrogen under hydroformylation conditions in the presence of a hydroformylation catalyst to produce a controlled functional density polyaldehyde containing reactive carbon-carbon double bonds, and (b) contacting the polyaldehyde with hydrogen and a primary amine under reductive amination conditions in the presence of a ruthenium-containing imine hydrogenation catalyst or (b.sup.1) contacting the polyaldehyde with a sterically hindered aliphatic or cycloaliphatic primary amine or an aromatic primary amine under reductive amination conditions in the presence of an alkali metal borohydride to produce poly(secondary amine) having a substantially equivalent ratio of secondary amine groups to reactive carbon-carbon double bonds as the ratio of aldehyde groups to reactive carbon-carbon double bonds in the polyaldehyde.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: October 10, 1995
    Assignee: Monsanto Company
    Inventors: Martin P. McGrath, Samuel J. Tremont
  • Patent number: 5457147
    Abstract: A process for preparing a controlled functional density poly(secondary amine) comprising: (a) contacting a polymer containing olefinic unsaturation with carbon monoxide in hydrogen under hydroformylation conditions in the presence of a hydroformylation catalyst to produce a controlled functional density polyaldehyde containing reactive carbon-carbon double bonds, and (b) contacting the polyaldehyde with hydrogen and a primary amine under reductive amination conditions in the presence of a ruthenium-containing imine hydrogenation catalyst or (b.sup.1) contacting the polyaldehyde with a sterically hindered aliphatic or cycloaliphatic primary amine or an aromatic primary amine under reductive amination conditions in the presence of an alkali metal borohydride to produce poly(secondary amine) having a substantially equivalent ratio of secondary amine groups to reactive carbon-carbon double bonds as the ratio of aldehyde groups to reactive carbon-carbon double bonds in the polyaldehyde.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: October 10, 1995
    Assignee: Monsato Company
    Inventors: Martin P. McGrath, Samuel J. Tremont
  • Patent number: 5434236
    Abstract: This invention relates to a polyester comprising repeating units having the structure: ##STR1## wherein R.sup.1 is selected from the group consisting of hydrogen, alkyl having 1 to 6 carbon atoms and aryl having 6 to 10 carbon atoms and R.sup.2 is selected from the group consisting of hydrogen, alkyl having 1 to 6 carbon atoms, and aryl having 6 to 10 carbon atoms.
    Type: Grant
    Filed: October 3, 1994
    Date of Patent: July 18, 1995
    Inventors: Alan W. White, Joseph R. Zoeller
  • Patent number: 5415926
    Abstract: In a process for the preparation of N-alkylol amide monomers wherein a polymerizable amide is reacted with an aldehyde, the improvement which comprises adjusting the pH of the resulting N-alkylol amide monomer to pH 10-11 and adding thereto an alkali or alkali earth metal borohydride at a temperature of -10.degree. to 20.degree. C. so as to convert the residual free aldehyde in the equilibrium mixture to the corresponding alcohol.
    Type: Grant
    Filed: February 25, 1993
    Date of Patent: May 16, 1995
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: John C. Leighton, Rama S. Chandran
  • Patent number: 5411802
    Abstract: A process for making solid colored particles by preparing a reaction solution in water comprising formaldehyde, urea, a cyclic polyamine functional triazine compound, and acid. A dye can be incorporated into the reaction solution if a color other than white is desired. Particles are formed having an average particle size between 1 and 70 microns without the need to resort to crushing to break up agglomerates. Particles made by this process provide excellent color and are easily washable from a substrate when incorporated into a washable formulation.Additionally, it has been found that the incorporation of colored microcapsules of average size of 1-70 microns where the color is located primarily on or in the shell of the microcapsule also provides excellent washable compositions when incorporated into a washable formulation.
    Type: Grant
    Filed: October 29, 1993
    Date of Patent: May 2, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kanta Kumar, Robert A. Davis, Sheila M. Nichols, Howard J. Buttery
  • Patent number: 5380789
    Abstract: A catalyst selected from a perfluorosulfonic acid and an anhydride thereof enables a non-conjugated drying oil to react with a phenol to form a phenol-added vegetable oil without causing hydrolysis of the non-conjugated drying oil. The phenol-added vegetable oil is allowed to react with an aldehyde to form a vegetable oil-modified phenolic resin. A laminate produced by impregnating paper with the vegetable oil-modified phenolic resin and laminating and molding the impregnated paper is excellent in low temperature punching quality and electrical properties and is free from low molecular weight components oozing out the surface of the laminate.
    Type: Grant
    Filed: August 10, 1993
    Date of Patent: January 10, 1995
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Ken Nanaumi, Takeshi Horiuchi, Masahiro Nomoto, Mitsuhiro Inoue
  • Patent number: 5378795
    Abstract: Soluble, amorphous, aromatic polyazomethine polymers and copolymers were prepared by reacting a dialdehyde monomer with a diamine monomer containing trifluoromethylbenzene and various combinations thereof in a solvent, such as N,N-dimethylacetamide. The reaction was heated to reflux yielding a polyazomethine which, after cooling to room temperature, was precipitated. These polymers and copolymers may be used to make films, coatings, composites and adhesives.
    Type: Grant
    Filed: July 30, 1993
    Date of Patent: January 3, 1995
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventor: Robert G. Bryant
  • Patent number: 5376650
    Abstract: Provided are light-absorbing polymers which contain backbone unsaturations and which are produced by knoevenagel condensation and which are useful for imparting color and/or ultraviolet light screening properties to thermoplastic resins. The polymeric colorants or UV absorbers may be added during the formation of the uncolored thermoplastic polymer or melt or solution blended with other thermoplastic polymers.
    Type: Grant
    Filed: March 3, 1994
    Date of Patent: December 27, 1994
    Assignee: Eastman Chemical Company
    Inventors: Max A. Weaver, James J. Krutak, Clarence A. Coates, Wayne P. Pruett, Samuel D. Hilbert
  • Patent number: 5374681
    Abstract: Polyacetals useful as reduced-phosphate or phosphate-free detergent and cleaner additives are obtainable by cationically initiated polyaddition of(a) divinyl ethers and(b) dihydroxy compounds and also, optionally,(c) monohydroxy compoundsand have K values of from 8 to 100.
    Type: Grant
    Filed: January 5, 1994
    Date of Patent: December 20, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Richard Baur, Volker Schwendemann, Hans-Ulrich Jaeger, Johannes Perner
  • Patent number: 5374485
    Abstract: A polyacetal resin composition which comprises a polyacetal resin (as component A) and one or more members selected from the group consisting of an isocyanate compound, isothiocyanate compound, and modified product thereof (as component B) in an amount of 0.1-15 wt % of the composition, said polyacetal resin composition exhibiting good adhesion properties when bonded with a curable reactive resin adhesive. The present invention also relates to a part comprising a combination of the mold consisting of the composition and the adhesive.
    Type: Grant
    Filed: June 15, 1993
    Date of Patent: December 20, 1994
    Assignee: Polyplastics Co., Ltd.
    Inventors: Sei Wakatsuka, Jun Fukasawa
  • Patent number: 5371140
    Abstract: A emulsifiable, phenolic-resole-resin-based composition comprising a low salt, urea-extended phenol aldehyde resin and an emulsifying agent, wherein the resin has a water dilutability ranging from about 2:1 to about 10:1 v/v water to resin prior to neutralization and aldehyde scavenger addition, and the method for making the same.
    Type: Grant
    Filed: April 1, 1994
    Date of Patent: December 6, 1994
    Assignee: Georgia-Pacific Resins, Inc.
    Inventor: Claude P. Parks
  • Patent number: 5371171
    Abstract: A poly(methylene oxalate) polymer [poly(oxy(1,2-dioxo-1,2-ethanediyl)oxymethylene)], a bis(tetrabutylammonium) oxalate salt, methods of synthesis thereof and methods of use. Poly(methylene oxalate) is insoluble in all common organic solvents, does not melt and is resistant to fire. Applications are as a light-weight material for use at high temperatures, e.g. as a structural material in aircraft and space vehicles, as a binder for brake systems, and as an insulator for microelectronic components.
    Type: Grant
    Filed: March 5, 1993
    Date of Patent: December 6, 1994
    Assignee: Baylor University
    Inventors: A. G. Pinkus, Rajan Hariharan
  • Patent number: 5364958
    Abstract: The hue of a methylene-crosslinked polyphenylene polyisocyanate continuously produced by the reaction with phosgene in an inert solvent of a polyamine mixture obtained by condensation of aniline and formaldehyde in the presence of an acid catalyst is improved by first removing any residual phosgene followed by heat treatment in the presence of hydrogen chloride gas.
    Type: Grant
    Filed: June 22, 1993
    Date of Patent: November 15, 1994
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Noritoshi Ishida, Zunzi Tashima, Naoki Sato, Michiya Takasaki, Masaaki Iijima, Kazuyuki Kuroda, Kazunari Nitta
  • Patent number: 5356566
    Abstract: Disclosed are a polyester compound having a repeating unit represented by the formula--OC--A--COO--BO-- (1)wherein A is a 1,3:2,4-dibenzylidenesorbitol or 1,3:2,4-dibenzylidenexylitol residue of the formula ##STR1## wherein t is 1 or 0, and B is a residue formed by removal of two hydroxyl groups from a polyhydric alcohol, and an organic gelling agent comprising the polyester compound.
    Type: Grant
    Filed: June 18, 1993
    Date of Patent: October 18, 1994
    Assignee: New Japan Chemical Co., Ltd.
    Inventors: Toshiaki Kobayashi, Sachio Kitagawa
  • Patent number: 5344909
    Abstract: A latent catalyzed phenolic resin composition is provided containing a thermosetting phenolic resole resin and a latent catalyst consisting essentially of a primary or secondary amine salt of a strong acid.
    Type: Grant
    Filed: June 3, 1993
    Date of Patent: September 6, 1994
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: David A. Hutchings, Ted M. McVay, Richard F. Pennock
  • Patent number: 5344874
    Abstract: A process for producing a condensed resin dispersion, which comprises subjecting an aldehyde and a compound condensable with the aldehyde, or their precondensate, to a condensation reaction in a dispersion medium consisting essentially of water and/or an organic solvent, to precipitate fine condensed resin particles which hardly settle in said dispersion medium, and then replacing the water and/or the organic solvent by an active hydrogen-containing compound having at least two active hydrogen-containing groups reactive with isocyanate groups.
    Type: Grant
    Filed: July 8, 1991
    Date of Patent: September 6, 1994
    Assignee: Asahi Glass Company Ltd.
    Inventors: Takao Doi, Noriko Itaya, Masami Yamashita, Nobuaki Kunii
  • Patent number: 5328978
    Abstract: The present invention relates to a triazine/formaldehyde resin which contains a compound of the general formula I ##STR1## wherein R.sup.1 and R.sup.2 are defined as stated in claim 1, a process for its preparation and its use as a curing agent in surface coating systems.
    Type: Grant
    Filed: October 28, 1993
    Date of Patent: July 12, 1994
    Assignee: Cassella AG
    Inventors: Manfred Schon, Jurgen Ott, Uwe Kubillus, Elif Tas
  • Patent number: 5322915
    Abstract: A condensation polymer, obtainable by condensation of a mixture containing, as chief components,(A) from 90 to 99.9% molar of a mixture substantially consisting of(a) from 30 to 99% molar of melamine and(b) from 1 to 70% molar of a substituted melamine of the general formula I ##STR1## in which X, X', and X" are selected from the group consisting of --NH.sub.2, --NHR, and --NRR', and only one or two of X, X', and X" denote(s) --NH.sub.2, and R and R' are selected from the group consisting of hydroxy-C.sub.2 -C.sub.10 -alkyl, hydroxy-C.sub.2 -C.sub.4 -alkyl-(oxa-C.sub.2 -C.sub.4 -alkyl).sub.n, where n is an integer from 1 to 5, and amino-C.sub.2 -C.sub.12 -alkyl, or mixtures of melamines I, and(B) from 0.1 to 10% molar, based on (A) and (B), of unsubstituted phenols or phenols substituted by radicals selected from the group consisting of C.sub.1 -C.sub.9 -alkyl and hydroxy, or of C.sub.1 -C.sub.
    Type: Grant
    Filed: July 8, 1992
    Date of Patent: June 21, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Weiser, Wolfgang Reuther, Rolf Fikentscher, Wolfgang Fath, Heinz Berbner, Hans D. Zettler, Heinz Voelker
  • Patent number: 5306783
    Abstract: An aqueous resin solution for the impregnation of paper webs contains 2-40 parts by weight of a polyurea composed of urea and of a polyamine per 100 parts by weight of a melamine/formaldehyde precondensate. The impregnated paper webs are suitable for coating woodbase materials, especially chipboard.
    Type: Grant
    Filed: December 4, 1992
    Date of Patent: April 26, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Uwe Kirchgaessner, Jakob Decher, Christof Jaeckh, Otto Wittmann, Manfred Niessner, Harro Petersen
  • Patent number: 5300593
    Abstract: A binding agent for molding compositions and molded bodies produced by reacting a low molecular weight lignin from the Organosolv process with phenol in a weight ratio of 1:20 to 3:1 at 100.degree. to 180.degree. C., adjusting the pH to an acidic value and condensing the mixture with 0.2 to 0.9 moles of formaldehyde per mole of phenol at 60.degree. to 120.degree. C. to form the binding agent useful for producing curable molding compositions, high-temperature molding compositions, refractory products, textile fleeces and friction coatings as well as carbon materials.
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: April 5, 1994
    Assignee: Rutgerswerke Aktiengesellschaft AG
    Inventors: Arno Gardziella, Achim Hansen, Stephan Schroter, Josef Suren
  • Patent number: 5294352
    Abstract: A composition for the detackification and clarification of acid and alkaline paint and lacquer waste waters and paint spray booth wastes, comprising:an inorganic-organic and/or organic adduct alloy polymer composition having the formula:A.multidot.B.sup.+ .multidot.D.sup.+wherein:A=[(SiO.sub.2 /Me.sup.I.sub.2 O).sub.u Me.sup.II.sub.m Me.sub.m.sup.III(OH) p.sup.(SO 4.sup.) y.sup.(Aci) (2m+3n)-p-2y].sub.4wherer=1 to 98% bw;u=0 to 10% bw; ##STR1## where: x=0 to 98% bw; Z is a divalent substituted or unsubstituted aliphatic, cycloaliphatic, heterocyclic or aromatic radicalD.sup.+ (PQAM).sub.wwherew=2 to 98% b.w. of polyquaternized polymer (PQAM)Me.sub.m.sup.II is selected from the divalent cationic group comprising: Mg, Zn, Ca, and Fe.sup.2+m=0 to 5Me.sub.n.sup.III is a tri-or more valent metal selected from the group comprising: Fe, Al, and Al-Zn complexes;n=1 to 20Aci is selected from the monovalent anionic group comprising Cl.sup.-, Br.sup.-, I.sup.-, NO.sub.3 --, H.sub.2 PO.sub.4 --, CH.sub.3 COO.sup.-, OH.
    Type: Grant
    Filed: April 15, 1993
    Date of Patent: March 15, 1994
    Inventor: John J. Waldmann
  • Patent number: 5288804
    Abstract: A composition comprising a first component including a compound comprising at least two acetoacetate groups, and a second component including a compound comprising at least two groups which will react with an acetoacetate group, at least one of which is an aromatic aldimine group having a relatively low reactivity with water when compared with its reactivity with an acetoacetate group.The components may be premixed in water prior to application.The invention further includes a product comprising a cured blend of the two components. The product of the invention is usually a coating or film.
    Type: Grant
    Filed: January 3, 1992
    Date of Patent: February 22, 1994
    Assignee: Reichhold Chemicals, Inc.
    Inventors: Kyu-Jun Kim, Roy C. Williams
  • Patent number: 5286808
    Abstract: Crosslinked elastomeric acetal polymers are made by the copolymerization of 1,3-dioxolane with a smaller amount of one or more bifunctional monomers. The two functional groups of the bifunctional monomer react under the same cationic polymerization conditions as the 1,3-dioxolane. The elastomeric acetal polymer does not crystallize even when the temperature is as low as -50.degree. C. The elastomeric acetal polymer is particularly useful for blending with crystalline acetal polymers to yield a composition with improved impact resistance.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: February 15, 1994
    Assignee: Hoechst Celanese Corporation
    Inventors: George L. Collins, William M. Pleban, Paul Zema
  • Patent number: 5276130
    Abstract: According to the present invention, a .beta.-dicarbonyl functionality, an .alpha.,.beta.-unsaturation functionality, or a vinylogous amide functionality is incorporated into an aminoplast resin or an aminoplast resin precursor.
    Type: Grant
    Filed: October 30, 1991
    Date of Patent: January 4, 1994
    Assignee: BASF Corporation
    Inventors: Christopher J. Bradford, Adriana E. Ticu, Richard E. De Schepper
  • Patent number: 5274074
    Abstract: This invention relates to medical devices formed totally or in part from homopolymers or copolymers comprising recurring carbonate moieties.
    Type: Grant
    Filed: July 22, 1992
    Date of Patent: December 28, 1993
    Assignee: United States Surgical Corporation
    Inventors: Reginald T. Tang, Frank Mares, William J. Boyle, Jr., Tin-Ho Chiu, Kundanbhai M. Patel
  • Patent number: 5270355
    Abstract: A paper coated resin has been provided which simultaneousy provides coated papers with improved ink receptivity, water resistance and blister resistance in a good balance. The resin is obtainable by introducing alicyclic amino and/or alicyclic epoxy compounds into a polyalkylenepolyamine-urea-aldehyde(epihalohydrin) resin or by introducing alicyclic amino and/or alicyclic epoxy compounds into a polyalkylenepolyamine-urea-aldehyde(epihalohydrin) resin and/or an amine-epihalohydrin resin and reacting or mixing these resins.
    Type: Grant
    Filed: January 13, 1992
    Date of Patent: December 14, 1993
    Assignee: DIC-Hercules Chemicals, Inc.
    Inventors: Hiroharu Kawano, Satoshi Takizawa, Hiroki Owaki, Haruka Hirayama
  • Patent number: 5266675
    Abstract: Energetic dihydroxy-terminated copolyformals which are formed from formalyde and dinitraminediol and fluorodiol comonomers wherein the dinitraminediol isHOCH.sub.2 N(NO.sub.2)CH.sub.2 N(NO.sub.2)CH.sub.2 N(NO.sub.2)CH.sub.2 OH,HOCH.sub.2 N(NO.sub.2)CH.sub.2 N(NO.sub.2)CH.sub.2 N(NO.sub.2)CH.sub.2 N(NO.sub.2)CH.sub.2 OH,or mixtures thereof, and wherein the fluorodiol isHOCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH,HOCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH,HOCH.sub.2 CF(CF.sub.3)OCF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH,HOCH.sub.2 CF.sub.2 OCF.sub.2 CF.sub.2 OCF.sub.2 CH.sub.2 OH,HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.2 CH.sub.2 CH.sub.2 OH,HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.4 CH.sub.2 CH.sub.2 OH,HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.6 CH.sub.2 CH.sub.2 OH,HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.8 CH.sub.2 CH.sub.2 OH,HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.10 CH.sub.2 CH.sub.2 OH,or mixtures thereof andwherein the terminal functional groups are fluorodiol monomer hydroxy groups.
    Type: Grant
    Filed: July 13, 1992
    Date of Patent: November 30, 1993
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Horst G. Adolph, Donna M. Cason-Smith
  • Patent number: 5260405
    Abstract: A binding agent for molding compositions and molded bodies produced by reacting a low molecular weight lignin from the Organosolv process with phenol in a weight ratio of 1:20 to 3:1 at 100.degree. to 180.degree. C., adjusting the pH to an acidic value and condensing the mixture with 0.2 to 0.9 moles of formaldehyde per mole of phenol at 60.degree. to 120.degree. C. to form the binding agent useful for producing curable molding compositions, high-temperature molding compositions, refractory products, textile fleeces and friction coatings as well as carbon materials.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: November 9, 1993
    Assignee: Rutgerswerke Aktiengesellschaft AG
    Inventors: Arno Gardziella, Achim Hansen, Stephan Schroter, Josef Suren
  • Patent number: 5256764
    Abstract: This invention relates to medical devices formed totally or in part from homopolymers or copolymers comprising recurring carbonate moieties.
    Type: Grant
    Filed: July 22, 1992
    Date of Patent: October 26, 1993
    Assignee: United States Surgical Corporation
    Inventors: Reginald T. Tang, Frank Mares, William J. Boyle, Jr., Tin-Ho Chiu, Kundanbhai M. Patel
  • Patent number: 5254665
    Abstract: Ammeline-melamine-formaldehyde resins (AMFR) containing from 5-100% ammeline were synthesized by the polymerization of the sodium salt of ammeline, which must be made in advance, melamine, and formaldehyde in basic medium (pH=9.2-10.0). In this copolymerization, it is possible to make uniform random AMFR resins with any mole ratio of ammeline salt to melamine. Preferably the AMFR resin will contain from 5-10% ammeline. As an "ionomer" or a "polyelectrolyte," both the solid and solution properties of these resins (such as melting temperature, solubility, solution stability, etc.) depended directly on the mole ratio of ammeline to melamine and formaldehyde, and/or on the pH value of the medium in which the AMFR resin was present. The pH value controlled the ammeline rings/ammeline's salt groups and also the ratio of unprotonated to protonated amino groups on both the melamine and ammeline rings.
    Type: Grant
    Filed: August 24, 1992
    Date of Patent: October 19, 1993
    Assignee: Melamine Chemicals, Inc.
    Inventors: George M. Crews, Shen Ji, Charles U. Pittman, Jr., Ruicheng Ran
  • Patent number: 5254625
    Abstract: Provided are polymers containing methine linkages. Also provided are shaped or formed articles comprised of the light absorbing polymers either alone or admixed with other thermoplastic polymers to form a light absorbing thermoplastic polymer composition.
    Type: Grant
    Filed: May 26, 1992
    Date of Patent: October 19, 1993
    Assignee: Eastman Kodak Company
    Inventors: Max A. Weaver, James J. Krutak, Clarence A. Coates, Wayne P. Pruett, Samuel D. Hilbert
  • Patent number: 5254639
    Abstract: A binding agent for molded bodies and molding compositions produced by prereacting a mixture of 5 to 60% by weight of lignin or a lignin fraction produced by the Organosolv process and 40 to 95% by weight of a phenol novolac resin and subjecting the latter to high shear forces in a kneader or extruder and optionally mixing the same with a curing agent useful in molding compositions and high temperature-stable molded products such as refractory products, friction coatings, textile fleeces and carbon or graphite materials.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: October 19, 1993
    Assignee: Rutgerswerke Aktiengesellschaft AG
    Inventors: Arno Gardziella, Achim Hansen, Stephan Schroter, Josef Suren
  • Patent number: 5252698
    Abstract: The present invention relates to porphyrin and metal ion-containing monomers and polymers. The monomers ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently selected from H, alkyl having 1 to 6 carbon atoms, phenyl or phenyl substituted with 1 to 3 alkyl groups each having 1 to 6 carbons or with 1 to 3 halogen atoms and A is a metal atom, are used with a diamine or a dialdehyde respectively to produce a porphyrin polymer or a metal ion containing porphyrin polymer. These polymers are useful as electrical conductors and as liquid crystal polymers.
    Type: Grant
    Filed: October 9, 1992
    Date of Patent: October 12, 1993
    Assignee: SRI International
    Inventors: Tilak R. Bhardwaj, Susanna C. Ventura, Subhash C. Narang
  • Patent number: 5248762
    Abstract: Cyclic polyoxymethylene having a number-average molecular weight of 500 to 5,000 is obtained by solid state cyclization reaction of an alkalidegradative linear oxymethylene homopolymer in the presence of a medium containing a cationic catalyst.The cyclization is effected at 10.degree. to 150.degree. C. for 1 to 500 minutes in an organic liquid medium.The reaction mixture obtained by the cyclization is treated with an alkaline medium to hydrolyze and remove away unreacted linear polyoxymethylene homopolymer, and isolate the cyclic polyoxymethylene.The product has a sharp molecular weight distribution and is useful as a resin improver.
    Type: Grant
    Filed: March 30, 1992
    Date of Patent: September 28, 1993
    Assignee: Polyplastics Co., Ltd.
    Inventors: Kaoru Yamamoto, Toshio Shiwaku
  • Patent number: 5243015
    Abstract: A latent catalyzed phenolic resin composition is provided containing a thermosetting phenolic resole resin and a latent catalyst consisting essentially of a primary or secondary amine salt of a strong acid.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: September 7, 1993
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: David A. Hutchings, Ted M. McVay, Richard F. Pennock
  • Patent number: 5223323
    Abstract: The present invention relates to a process for coating finish foils and endless edges, wherein an acid-curing aqueous coating composition, on the basis of aminoplast resin/compound containing hydroxyl groups/self-crosslinking acrylate dispersion, is applied and baked in. The coating composition used contains 5 to 20% by weight of one or more fillers of a mean particle size from 0.015 to 10 .mu.m, a maximum particle size of .ltoreq.40 .mu.m and a density of .ltoreq.2.9 g/cm.sup.3.The invention also relates to the coating compositions positions used in the process and to finish foils and endless edges produced by the process, which especially have the advantage of an extremely low formaldehyde emission, particularly as a composite with a low-formaldehyde chipboard.
    Type: Grant
    Filed: September 30, 1991
    Date of Patent: June 29, 1993
    Assignee: BASF Corporation
    Inventors: Karl-Heinz Dickerhof, Joachim Roll, Wilhelm Moss, Thomas Schwalm
  • Patent number: 5219979
    Abstract: New polyoxazolidines can be defined with the general formula: ##STR1## where R, R.sub.1, R.sub.2 and n have the meaning specified in the description. These polyoxazolidines are useful cross-linking agents for hydrocuring systems based on polyisocyanates, acrylate polymers and polyepoxides, in compositions for paints, coatings, sealants and adhesives.
    Type: Grant
    Filed: February 10, 1992
    Date of Patent: June 15, 1993
    Assignee: Enichem Synthesis S.p.A.
    Inventor: Alberto Greco
  • Patent number: 5215828
    Abstract: Curable binders obtained by simultaneous reaction ofA) urethanes or ureas,B) acrylic or methacrylic compounds containing hydroxyl groups,C) paraformaldehyde andD) if appropriate, polyols,wherein, in the case where no polyol D) is also reacted, the reaction is carried out in the presence of an acid ion exchanger, and in the case where a polyol D) is also reacted, the reaction is carried out in the presence of an acid ion exchanger or a strong acid.These binders are suitable as coating compositions which can be cured by electron beams or by UV light.
    Type: Grant
    Filed: August 19, 1992
    Date of Patent: June 1, 1993
    Assignee: Hoechst AG
    Inventors: Gerhard Brindoepke, Inge Kurth, Michael Schwab, Gerd Walz
  • Patent number: H1339
    Abstract: This invention relates to an aqueous process for recycling polyacetal, and moldings thereof, into formaldehyde monomer solution, said process occurring at elevated temperature and pressure and in the presence of an acid decomposition catalyst, such as sulfuric acid. The resultant formaldehyde monomer solution can be reacted to form trioxane and then be cycled into a trioxane-based polyacetal manufacturing process or, alternatively, it can be further treated and then be cycled into a formaldehyde-monomer-based polyacetal manufacturing process.
    Type: Grant
    Filed: June 3, 1992
    Date of Patent: July 5, 1994
    Inventor: Leslie M. Blair