Abstract: A method for coating a textile includes applying a substantially water-free, energy-curable, polymer-forming composition to the textile and exposing the textile and composition to a source of energy under such conditions as to generate chemically active sites on the surface of the textile and polymerize the composition. The resulting polymer is grafted onto the textile. Preferably, the energy is derived from electron beam radiation. The composition includes an epoxy oligomer having at least two ethylenically unsaturated moieties, and at least one alkoxylated polyol monomer having at least two ethylenically unsaturated moieties and capable of being copolymerized with the epoxy oligomer. Preferably, the composition also includes a surface active agent capable of rendering the uncured composition dispersible in water. Optionally, the composition can contain a colorant, and photoinitiator. The composition is especially suitable for use as a screen printing ink and coating material for textiles.
Abstract: An improved process for the extraction of a metal from an aqueous ammoniacal solution comprising:
(i) contacting the aqueous ammoniacal solution with an extraction reagent comprised of a water insoluble extractant for the metal, to provide an organic phase, now containing metal values, and an aqueous phase from which metal values have been extracted;
(ii) contacting the organic phase with an aqueous stripping solution to provide an aqueous strip phase, now containing metal values, and an organic phase from which metal values have been stripped; and
(iii) recovering the metal values from the aqueous stripping solution;
the improvement wherein (a) the extraction reagent contains an ammonia antagonist having only hydrogen bond acceptor properties; (b) the stripping solution is an aqueous highly acidic solution; and (c) the organic phase is washed with a weakly acidic aqueous solution prior to stripping with the highly acidic aqueous stripping solution.
Type:
Grant
Filed:
November 21, 1997
Date of Patent:
April 3, 2001
Assignee:
Henkel Corporation
Inventors:
Michael J. Virnig, Gary A. Kordosky, George A. Wolfe, J. Murdoch MacKenzie
Abstract: A pearlescent concentrate containing: (a) from 30 to 80% by weight of an alkyl ether sulfatef; (b) from 5 to 20% by weight of a surfactant selected from the group consisting of a betaine, an alkyl and/or alkenyl oligoglycoside, and mixtures thereof; and (c) from 1 to 10% by weight of an (oligo)ethylene glycol mono- and/or difatty acid ester, all weights being based on the total weight of the composition, and wherein the concentrate is polyol-free.
Type:
Grant
Filed:
May 12, 1999
Date of Patent:
April 3, 2001
Assignees:
Henkel Kommanditgesellschaft auf Aktien, Wella Aktiengesellschaft Wella AG
Inventors:
Josef Wilhelm, Rudolf Bimczok, Werner Kohl, Achim Ansmann, Rolf Kawa
Abstract: The invention relates to multiphase lubricant concentrates with improved properties for use in aqueous fluids for geological exploration by drilling which contain organic lubricating components which are solid and/or liquid at room temperature (O phase) together with emulsifiers finely dispersed in a continuous aqueous phase (W phase). These concentrates are characterized in that the system of O phase/W phase and emulsifiers has a phase inversion temperature (PIT) above room temperature and has been produced by heating the multiphase system to temperatures equal to or above the PIT and subsequent cooling to temperatures below the PIT.
The present invention also relates to the use of the multiphase lubricant concentrates as an additive in water-based fluids for use in geological exploration by drilling and for the subsequent treatment of the resulting boreholes.
Type:
Grant
Filed:
June 1, 1999
Date of Patent:
April 3, 2001
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Claus-Peter Herold, Heinz Mueller, Thomas Foerster, Stephan Von Tapavicza, Marcus Claas
Abstract: A sun protection composition, in an oil-in-water microemulsion form, containing: (a) an oil component; (b) a monoglyceride (ether) sulfate; and (c) at least one ultraviolet filter.
Type:
Grant
Filed:
March 19, 1999
Date of Patent:
March 27, 2001
Assignee:
Cognis Deutschland GmbH
Inventors:
Werner Seipel, Bernd Fabry, Joerg Kahre
Abstract: A method for protecting the body against oxidation of low density lipoproteins by the oral administration of a protective amount of a natural tocopherol and tocopherol acetate or tocopherol succinate.
Abstract: The invention relates to spinning finishes containing a lubricant of improved biodegradability, the lubricant consisting of block copolyesters. The block copolyesters are produced from hydrophilic polyethylene glycols and hydrophobic diols selected from the group of polypropylene glycols, polytetrahydrofurans, polycaprolactone diols, hydrogenation products of ricinoleic acid esters, 1,2-alkanediols, &agr;,&ohgr;-alkanediols and/or dimeric diols and dicarboxylic acids containing 2 to 36 carbon atoms connecting the blocks A) and B), anhydrides thereof, esters thereof with lower alcohols containing 1 to 8 carbon atoms and/or carbonic diesters of lower alcohols containing 1 to 8 carbon atoms.
Type:
Grant
Filed:
September 7, 1993
Date of Patent:
March 20, 2001
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Ulrich Eicken, Raymond Mathis, Norbert Bialas
Abstract: A process for preparing alkyl polysaccharides comprising introducing a mixture of a hydrous saccharide in a first portion of fatty alcohol, introducing a second portion of fatty alcohol, agitating the mixture, allowing it to crystallize, reducing water content, contacting the reduced water content dispersion containing solid particles with an effective amount of acid catalyst and reacting the aliphatic alcohol with the saccharide source to form an alkylpolyglycoside.
Type:
Grant
Filed:
June 8, 1999
Date of Patent:
March 20, 2001
Assignee:
Henkel Corporation
Inventors:
C. Deane Roth, Frank L. Edwards, Patrick McCurry, Jr.
Abstract: Polymers that have limiting viscosities, measured in tetrahydrofuran at 20° C., of at least about 200 mL/g and that can be made by addition polymerization of a mixture of monomers containing:
A. from 100—about 30 wt % of esters of acrylic acid and methacrylic acid with monohydric saturated aliphatic alcohols which contain from 1-22 C atoms; and
B. up to about 70 wt % of monomers selected from the group consisting of:
(1) unsaturated aliphatic carboxylic acids with 3-5 C atoms and their amides,
(2) styrene and alkylstyrenes with 1-4 C atoms in their alkyl residues,
(3) acrylonitrile,
(4) vinyl esters of aliphatic C1-18 carboxylic acids, and
(5) amino substituted esters of acrylic acid and methacrylic acid with monohydric alcohols having from 2-6 carbon atoms
are highly effective anti-sling additives for textile lubricants.
Type:
Grant
Filed:
December 29, 1993
Date of Patent:
March 13, 2001
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Ulrich Eicken, Andreas Botulinski, Heidi Fiedler, Manfred Gorzinski, Issac Fleming, Charles G. Dewitt, Jeffrey T. Langley
Abstract: The process of recovering precious metals from ores containing precious metals, such as gold and silver, from an aqueous ammoniacal thiosulfate leach solution to provide a significant practical and economical process for the recovery of gold or silver. After leaching of the ore with an aqueous ammoniacal thiosulfate solution, the leach solution is contacted with a precious metal extraction reagent to extract the precious metal values from the leach solution, after which the precious metal values are stripped from the extraction reagent to form a concentrated solution of the precious metal values from which the precious metals may be recovered by conventional methods such as electrolysis. The extraction reagents are those having guanidyl functionality or a quaternary amine functionality mixed with a weak organic acid such as a phenol.
In the process, novel thiosulfate complexes of the precious metals are formed with the quanidyl or the quaternary amine extractants.
Type:
Grant
Filed:
April 26, 1999
Date of Patent:
March 6, 2001
Assignee:
Henkel Corporation
Inventors:
Michael J. Virnig, J. Michael Sierakoski
Abstract: A polymer useful as an inorganic pigment dispersant is provided. The polymer is derived from monomers consisting essentially of an ethylenically unsaturated aromatic monomer, an ethylenically unsaturated dicarboxylic acid monomer, and an ethylenically unsaturated monocarboxylic acid monomer. The total amount of said ethylenically unsaturated acid monomers is sufficient to permit said polymer to associate with an inorganic pigment in an aqueous medium in a manner which disperses said inorganic pigment in said aqueous medium to form a stable aqueous dispersion of said inorganic pigment, and the amount of said ethylenically unsaturated aromatic monomer is sufficient to reduce the water sensitivity of a dried coating of a latex paint comprised of said stable aqueous dispersion of said inorganic pigment. A process of preparing a polymer useful as an inorganic pigment dispersant and a method of preparing an inorganic pigment dispersion useful in the preparation of latex paints are also provided.
Type:
Grant
Filed:
September 13, 1996
Date of Patent:
March 6, 2001
Assignee:
Henkel Corporation
Inventors:
Stephen A. Fischer, Michael S. Wiggins, Bruce Matta, Eric Nowicki
Abstract: Ester base stocks for two-cycle gasoline engine lubricant compositions are disclosed which produce lower amounts of observable smoke in the exhaust emitted as a result of combustion in a two-cycle gasoline engine, require no miscibility-enhancing solvents, have a viscosity of 3.0 cSt to 20.0 cSt at 100° C. and a smoke index of at least 75. Some of the esters are biodegradable.
Abstract: A process for hydrophilically finishing synthetic fibers or nonwoven substrates containing synthetic fibers involving applying an effective amount of a finish composition onto the fibers or nonwoven substrates, the finish composition containing from 75 to 100% by weight, based on the weight of the composition, of at least one monoester of glycerol and a fatty acid having from 6 to 14 carbon atoms.
Abstract: A process for producing solid detergent granular materials is presented involving (a) forming an aqueous surfactant paste of an anionic surfactant, an amphoteric surfactant or mixtures thereof, and (b) drying and granulating the aqueous paste in a horizontal thin-layer evaporator or dryer having rotating fittings, wherein the drying is carried out at a temperature of 120° C. to 130° C. The process produces granules having a bulk density greater than 600 grams/liter and a uniform particle size distribution.
Type:
Grant
Filed:
August 25, 1999
Date of Patent:
February 20, 2001
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Thomas Lueder, Konstantinos Scholinakis, Bernhard Gutsche, Christoph Breucker, Norbert Wrede
Abstract: A dimeric fatty acid and/or dimeric fatty ester product having a low residual content of interesters is obtained by hydrolyzing the interesters to provide monomeric unsaturated fatty acids and alcohols as the hydrolysates and thereafter removing the hydrolysates from the dimeric fatty acid and/or dimeric fatty ester product.
Abstract: A water-based manual dishwashing detergent composition containing
(a) monoglyceride sulfates or monoglyceride ether sulfates corresponding to formula (I):
in which R1CO is a linear or branched acyl group containing 6 to 22 carbon atoms, x, y and z together stand for 0 or a number from 1 to 30 and X is an alkali metal or alkaline earth metal cation,
(b) anionic surfactants other than component (a), and
(c) amphoteric or zwitterionic surfactants and optionally
(d) nonionic surfactants.
Abstract: An antistatic composition containing a crosslinked thermosetting resin formed by reacting, in the presence of a water-soluble solvent, (a) a polyaminoamide having unreacted primary and secondary amine groups and (b) a polychlorohydrin derivative.
Type:
Grant
Filed:
March 18, 1998
Date of Patent:
February 13, 2001
Assignee:
Henkel Corporation
Inventors:
Michael J. Incorvia, Stephen A. Fischer
Abstract: A two-step process comprising as a first step draining a refrigerant heat transfer fluid made of molecules containing at least one chlorine atom per molecule and mineral oil lubricant dissolved therein from an unflushable compressor and associated piping in a vehicle air conditioner, thereby leaving a mineral oil residue. The second step comprises replacing the refrigerant heat transfer fluid in all parts of the vehicle air conditioner designed to contain such fluid with a replacement heat transfer fluid. The replacement fluid consists essentially of 1,1,1,2-tetrafluorethane and a composition of matter suitable for serving as the lubricant or lubricant base stock. The composition of matter is capable of forming a soluble clear solution with a mineral oil residue in a weight ratio of mineral oil to composition of at least 25:100 and forming a single phase with 1,1,1,2-tetrafluoroethane between −55° C. and +71° C.
Abstract: The invention relates to the use of oil-soluble oleophilic organic liquid phases—flowable at temperatures of 0 to 10° C.—from the classes of corresponding monocarboxylic and/or polycarboxylic acid esters, carbonic acid esters, fatty alcohols and their oligoalkoxides and/or ethers as the at least predominant part of the liquid phase in storage-stable homogeneous mixtures with guar and/or water-soluble guar derivatives for their use in water-based borehole servicing fluids.
Type:
Grant
Filed:
December 28, 1998
Date of Patent:
January 30, 2001
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Heinz Mueller, Claus-Peter Herold, Stephan von Tapavicza
Abstract: A process for making synthetic triglycerides involving: (a) providing a reaction component selected from the group consisting of glycerol, a triglyceride, and mixtures thereof; (b) providing a fatty acid mixture containing at least 50% by weight, based on the weight of the fatty acid mixture, of conjugated linoleic acid; (c) providing an inert gas atmosphere; (d) combining the reaction component with the fatty acid mixture, in the inert atmosphere, to form a reaction mixture; and (e) heating the reaction mixture to a temperature of from 180 to 240° C., at a heating rate of from 0.5 to 3 K per minute, thus forming the synthetic triglyceride.
Type:
Grant
Filed:
October 29, 1999
Date of Patent:
January 23, 2001
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Franz Timmermann, Rolf Gaupp, Juergen Gierke, Rainer Von Kries, Wolfgang Adams, Andreas Sander