Patents Represented by Attorney, Agent or Law Firm John E. Drach
  • Patent number: 6036817
    Abstract: The efficiency by which pulp cooking liquor components penetrate the wood and enable lignin and resins to be removed from the cellulosic materials is increased by contacting wood chips and the like with a liquid mixture comprised of white liquor containing at least one surfactant selected from the group consisting of a polymethylalkylsiloxane; a co- and terpolymer of silicone and a polyhydric alcohol; an alkoxylated aryl phosphate; an alkoxylated branched alkyl phosphate; an alkoxylated branched alcohol; an alkyl polyglycoside, an alkoxylated alkyl polyglycoside; a mixture of alkali metal salts of alkyl aromatic sulfate, a sulfosuccinate and a silicone; and combinations thereof; for a residence time effective to extract resinous components without substantial degradation of cellulose and thereafter heating at least a portion of the resulting mixture and wood chips.
    Type: Grant
    Filed: November 17, 1997
    Date of Patent: March 14, 2000
    Assignee: Henkel Corporation
    Inventors: Marie-Esther Saint Victor, David I. Devore, Barbara Balos Bowker, John J. Palmer, Vincent T. Stine
  • Patent number: 6030937
    Abstract: A process for the production of surfactant granules by contacting an alkyl or alkenyl oligosaccharide paste with a zeolite or a water glass under conditions in which the mixture is simultaneously granulated and dried.
    Type: Grant
    Filed: March 12, 1998
    Date of Patent: February 29, 2000
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hans-Friedrich Kruse, Volker Bauer, Georg Assmann
  • Patent number: 6002049
    Abstract: Latexes are thickened by compounds of the formula ##STR1## wherein R.sup.1 is an aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical having a valence of from 2 to 8; each of B.sub.1 -B.sub.8 is independently an ester, amide, amine, ether, sulfide, disulfide, thiocarbamate, urea, thiourea, urethane, sulfate, phosphate, carbonyl, methylene, thioamide, carbonate, or imide linkage; each of X.sup.1 -X.sup.8 is independently --A.sub.1 --R.sup.2 --A.sub.2 -- or --A.sub.1 -- wherein each of A.sub.1 and A.sub.2 is independently an ester, amide, amine, ether, sulfide, disulfide, urethane, thiocarbamate, urea, thiourea, sulfate, phosphate, carbonyl, methylene, thioamide, carbonate, or imide linkage and R.sup.2 is a divalent aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical with the proviso that only one of B.sub.1 -B.sub.8 is urethane and that when one of B.sub.1 -B.sub.8 is urethane, one of A.sub.1 and A.sub.
    Type: Grant
    Filed: June 12, 1997
    Date of Patent: December 14, 1999
    Assignee: Henkel Corporation
    Inventors: Michael S. Wiggins, Reuben H. Grinstein, Stephen A. Fischer
  • Patent number: 5997854
    Abstract: A hair conditioning shampoo composition containing: (a) a quaternary ammonium component; (b) an emulsifier component; (c) an amphoteric surfactant component; (d) an alkyl polyglycoside of formula I:R.sub.1 O(R.sub.2 O).sub.b (Z).sub.a Iwherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is a divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6; (e) an emollient component; (f) water; (g) an anionic surfactant component; (h) an amide component; and (i) an electrolyte component.
    Type: Grant
    Filed: December 10, 1996
    Date of Patent: December 7, 1999
    Assignee: Henkel Corporation
    Inventor: Peter von Mallek
  • Patent number: 5993371
    Abstract: Transparent soap bars having improved lathering and foaming characteristics contain (1) an alkanolamine; (2) an alkyl polyglycoside of the formula IR.sub.1 (R.sub.2 O).sub.b (Z).sub.a (I)wherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6: (3) a polyol; (4) a fatty acid which is at least 70% neutralized by sodium hydroxide, and; (5) water wherein the water to free alkanolamine weight ratio is greater than 1.0 and the ratio of the weight of the polyol to the sum of the weights of free alkanolamine+alkyl polyglycoside+polyol+water is less than about 0.4.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: November 30, 1999
    Assignee: Henkel Corporation
    Inventors: J. Matthew White, Donald V. Kinsman
  • Patent number: 5990072
    Abstract: A terpene-free hard surface cleaning composition containing: (a) a nonionic surfactant; (b) an anionic surfactant; (c) a primary solvent consisting of a C.sub.6 -C.sub.14 methyl ester; (d) a short-chain cosurfactant; and (e) water, all weights being based on the total weight of the composition.
    Type: Grant
    Filed: February 8, 1999
    Date of Patent: November 23, 1999
    Assignee: Henkel Corporation
    Inventors: Stephen F. Gross, Martin J. Barabash, J. Frederick Hessel
  • Patent number: 5985639
    Abstract: Mutant B. lentus DSM 5483 proteases are derived by the replacement of at least one amino acid residue of the mature form of the B. lentus DSM 5483 alkaline protease. The mutant proteases are expressed by genes which are mutated by site-specific mutagenesis. The amino acid sites selected for replacement are identified by means of a computer based method which compares the three dimensional structure of the wild-type protease and a reference protease.
    Type: Grant
    Filed: March 19, 1996
    Date of Patent: November 16, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Teresa Christianson, Dean Goddette, Beth Frances Ladin, Maria R. Lau, Christian Paech, Robert B. Reynolds, Charles R. Wilson, Shiow-Shong Yang
  • Patent number: 5981452
    Abstract: The invention relates to new syndet soaps which contain alkyl and/or alkenyl oligoglycosides as surfactant component and starch as builder. The products are distinguished by a particularly rich and creamy foam and by an optimized feeling on the skin.
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: November 9, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karlheinz Schrader, Hermann Hensen, Werner Seipel, Mirella Rottmann
  • Patent number: 5962285
    Abstract: Aliphatic polycarboxylic acids are made by a process comprising the steps of: (1) fermenting a beta-oxidation blocked C. tropicalis cell wherein both copies of the chromosomal POX5 gene and the chromosomal POX4A and POX4B genes are disrupted in a culture medium comprised of a nitrogen source, an organic substrate and a cosubstrate wherein the substrate is an unsaturated aliphatic compound having at least one internal carbon--carbon double bond and at least one terminal methyl group, a terminal carboxyl group and/or a terminal functional group which is oxidizable to a carboxyl group by biooxidation; (2) reacting the product of step (1) with an oxidizing agent to produce one or more polycarboxylic acids.
    Type: Grant
    Filed: June 23, 1998
    Date of Patent: October 5, 1999
    Assignee: Henkel Corporation
    Inventors: Kevin W. Anderson, J. Douglas Wenzel, Richard G. Fayter, Kenneth R. McVay
  • Patent number: 5962624
    Abstract: A linear polyester is made by a process reacting polyols comprising at least two primary alcohol groups and at least one secondary alcohol or amino group and a dicarboxylic acid or a dicarboxylic acid ester in the presence of an effective amount of a lipase derived from Candida cylindracea, Candida lipolytica, Candida rugosa, Candida antarctica, Candida utilis, Chromobacterium viscosum, Geotrichum viscosum, Geotrichum candidum, Mucor javanicus, Mucor miehei, Porcine pancreas, Pseudomonas species, specifically Pseudomonas fluorescens, Pseudomonas cepacia, Pseudomonas pseudoalkaligenes, Pseudomonas alkaligenes, Thermomyces species, Rhizopus arrhizus, Rhizopus delemar, Rhizopus niveus, Rhizopus oryzae, Rhizopus javanicus, Aspergillus niger, Penicillium roquefortii, Penicillium camembertii or an esterase derived from Bacillus species, specifically Bacillus thermoglucosidasius; Mucor miehei, Horse liver, Saccharomyces cerevisiae, Pigs liver or combinations thereof.
    Type: Grant
    Filed: March 10, 1998
    Date of Patent: October 5, 1999
    Assignee: Hendel Kommanditgesellschaft auf Aktien
    Inventors: Anja Vonderhagen, Jeffrey A. Gates, Karlheinz Hill, Martin Lagarden, Holger Tesmann
  • Patent number: 5962663
    Abstract: The invention relates to new cationic biopolymers with an average molecular weight of 800,000 to 1,200,000 Dalton, a Brookfield viscosity (1% by weight in glycolic acid) below 5,000 mPas, a degree of deacetylation of 80 to 88% and an ash content of less than 0.3% by weight which are obtained by repeatedly subjecting crustacean shells to alternate acidic and alkaline degradation under defined conditions. Compared with known cationic biopolymers of the chitosan type, the new biopolymers form clear solutions and, at the same time, show excellent film-forming properties, despite their high molecular weight.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: October 5, 1999
    Assignees: Henkel Kommanditgesellschaft auf Aktien, Norwegian Institute of Fisheries and Aquaculture Ltd.
    Inventors: Rolf Wachter, Holger Tesmann, Ronald Svenning, Ragnar Olsen, Even Stenberg
  • Patent number: 5959101
    Abstract: A continuous process for the production of polycarboxylic acids or salts thereof from polysaccharides involving contacting a polysaccharide with an oxidizing agent selected from the group consisting of nitrogen dioxide, dinitrogen tetroxide, or an equilibrium mixture thereof in the absence of oxygen at a temperature above 80 .degree.C. and at a pressure of from about 3 bar to about 15 bar absolute and for a tirne period of from about 1 to about 30 minutes to form a reducd gaseous product and a polysaccharide product wherein the primary alcohol groups of said polysaccharide product are at least partially converted to carboxyl groups.
    Type: Grant
    Filed: March 18, 1997
    Date of Patent: September 28, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Konrad Engelskirchen, Herbert Fischer
  • Patent number: 5939081
    Abstract: A process for thickening a water-in-oil and oil-in-water emulsion involving adding to the emulsion a thickening agent consisting of an alkyl or alkenyl oligoglucoside ester formed by esterifying an alkyl or alkenyl oligoglycoside corresponding to formula I:R.sup.1 O--?G!.sub.p (I)wherein R.sup.1 is an alkyl or alkenyl oligoglucoside containing from about 4 to about 22 carbon atoms, G is a sugar unit containing from 5 to 6 carbon atoms, and p is a number having a value of from 1 to about 10, with a fatty acid corresponding to formula II:R.sup.2 CO--OH (II)wherein R.sup.2 CO is an aliphatic acyl radical containing from about 6 to about 22 carbon atoms, and up to about 3 double bonds.
    Type: Grant
    Filed: February 26, 1997
    Date of Patent: August 17, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Achim Ansmann, Rolf Kawa, Annette Kreisig, Norman Milstein
  • Patent number: 5936107
    Abstract: Fatty acid polyethylene glycol esters of the formula (I):R.sup.1 CO(CH.sub.2 CH.sub.2 O).sub.n H (I)wherein R.sup.1 CO is a linear or branched, aliphatic, saturated and/or unsaturated acyl group having from about 6 to about 22 carbon atoms and n is a number from 0.5 to 1.5 are made by reacting ethylene oxide and a fatty acid in the presence of an alkanolamine in a homogeneous reaction medium.
    Type: Grant
    Filed: December 9, 1996
    Date of Patent: August 10, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hans-Christian Raths, Ansgar Behler, Norman Milstein
  • Patent number: 5932535
    Abstract: Light-colored, low-viscosity surfactant concentrates, are made by mixing: mixing: (a) a sugar surfactant selected from the group consisting of an alkyl and/or alkenyl oligoglycoside, a fatty acid-N-alkyl polyhydroxyalkylamide and a combination thereof and, (b) a betaine in a ratio by weight of (a) to (b) of from about 90:10 to about 10:90, with the proviso that components (a) and (b)are present in the gel phase.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: August 3, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Michael Neuss, Karl Heinz Schmid, Andrea Borntraeger
  • Patent number: 5925602
    Abstract: Ester base stocks for two-cycle gasoline engine lubricant compositions are disclosed which produce lower amounts of observable smoke in the exhaust emitted as a result of combustion in a two-cycle gasoline engine, require no miscibility-enhancing solvents, have a viscosity of 3.0 cSt to 20.0 cSt at 100.degree. C. and a smoke index of at least 75. Some of the esters are biodegradable.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: July 20, 1999
    Assignee: Henkel Corporation
    Inventors: Eugene R. Zehler, Bruce J. Beimesch
  • Patent number: 5912214
    Abstract: Ester base stocks for two-cycle gasoline engine lubricant compositions are disclosed which produce lower amounts of observable smoke in the exhaust emitted as a result of combustion in a two-cycle gasoline engine, require no miscibility-enhancing solvents, have a viscosity of 3.0 cSt to 20.0 cSt at 100.degree. C. and a smoke index of at least 75. Some of the esters are biodegradable.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: June 15, 1999
    Assignee: Henkel Corporation
    Inventors: Eugene R. Zehler, Bruce J. Beimesch
  • Patent number: 5910476
    Abstract: A soap bar useful for removing heavy amounts of soil from the skin is comprised of a fatty acid soap, a fatty acid ester of an isethionate salt, a nonionic sugar surfactant selected from the group consisting of an alkyl glucose ester, an aldobionamide, a gluconamide, a glyceramide, a glyceroglycolipid, a polyhydroxy fatty acid amide, an alkyl polyglycoside, and combinations thereof, an abrasive and, water.
    Type: Grant
    Filed: June 3, 1997
    Date of Patent: June 8, 1999
    Assignee: Henkel Corporation
    Inventors: Donald V. Kinsman, Timothy J. Cassady, J. Matthew White
  • Patent number: 5908928
    Abstract: A novel surfactant of formula I:R.sub.1 O(R.sub.2 O).sub.b (Z).sub.a OCH.sub.2 COO.sup.- X.sup.+Iwherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6; and X is an alkali metal ion.
    Type: Grant
    Filed: November 10, 1997
    Date of Patent: June 1, 1999
    Assignee: Henkel Corporation
    Inventors: Norman Milstein, Barry A. Salka
  • Patent number: 5907067
    Abstract: Alkoxylated alcohols containing no insoluble matter which would prevent the spray application of such materials are obtained by reacting an alcohol and epoxide in the presence of a catalytic amount of a calcined hydrotalcite catalyst to form a crude alkoxylated product. The crude product is then passed through silica gel to remove insoluble by-products.
    Type: Grant
    Filed: April 9, 1997
    Date of Patent: May 25, 1999
    Assignee: Henkel Corporation
    Inventors: Jeffrey A. Barnhorst, A. Frederick Elsasser, Jr., C. William Blewett